JP2008510033A - 非塩化濃縮オールインワン酸性清浄剤およびその使用方法 - Google Patents
非塩化濃縮オールインワン酸性清浄剤およびその使用方法 Download PDFInfo
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- JP2008510033A JP2008510033A JP2007525722A JP2007525722A JP2008510033A JP 2008510033 A JP2008510033 A JP 2008510033A JP 2007525722 A JP2007525722 A JP 2007525722A JP 2007525722 A JP2007525722 A JP 2007525722A JP 2008510033 A JP2008510033 A JP 2008510033A
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- 238000000034 method Methods 0.000 title claims abstract description 29
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- 238000004140 cleaning Methods 0.000 claims abstract description 96
- 239000002253 acid Substances 0.000 claims abstract description 82
- -1 alkyl sulfonic acid Chemical compound 0.000 claims abstract description 72
- 150000003839 salts Chemical class 0.000 claims abstract description 35
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- 125000000217 alkyl group Chemical group 0.000 claims description 27
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- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 9
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- 239000003795 chemical substances by application Substances 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
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- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 4
- 108010059892 Cellulase Proteins 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000805 Polyaspartic acid Polymers 0.000 claims description 4
- 229920000388 Polyphosphate Polymers 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- 239000001361 adipic acid Substances 0.000 claims description 4
- 235000011037 adipic acid Nutrition 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 4
- 229940061720 alpha hydroxy acid Drugs 0.000 claims description 4
- 150000001280 alpha hydroxy acids Chemical class 0.000 claims description 4
- 235000003704 aspartic acid Nutrition 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
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- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
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- 108010064470 polyaspartate Proteins 0.000 claims description 4
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- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 claims description 3
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 claims description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 3
- 102000003992 Peroxidases Human genes 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 229960003260 chlorhexidine Drugs 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
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- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical group [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 3
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- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 2
- VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 claims description 2
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 claims description 2
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- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims description 2
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
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- NIFDAHUNJVFZAY-UHFFFAOYSA-N 1-nitropropane-1,3-diol Chemical compound OCCC(O)[N+]([O-])=O NIFDAHUNJVFZAY-UHFFFAOYSA-N 0.000 claims 1
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
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- OBMBUODDCOAJQP-UHFFFAOYSA-N 2-chloro-4-phenylquinoline Chemical compound C=12C=CC=CC2=NC(Cl)=CC=1C1=CC=CC=C1 OBMBUODDCOAJQP-UHFFFAOYSA-N 0.000 abstract description 6
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- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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Abstract
【選択図】なし
Description
以下の実施例の多くは本発明に係る酸清浄剤の洗浄評価に関するものである。試料の洗浄有効性は、市販のクロロアルカリ清浄剤と比較した。これらの洗浄テストでは、大きさが3”x6” x 0.0037”(7.6cm x 15.2cm x 0.0094cm)で、一端に1/4”(0.6cm)の穴を有する304ステンレススチール、プラスチック、またはガラスのパネルを最初に粉末クロロアルカリ清浄剤で洗浄し、水ですすぎ、キシレンで拭き、次にイソプロパノールで拭き、その後、炉乾燥(100〜110℃で10〜15分間)し、溶剤を完全に蒸発させた。剛性のワイヤハンガーをパネルの穴に取り付けることによって、パネルを炉内に吊るし、炉または炉内の他の品目に接触しないようにした。次に乾燥したパネルを炉から取り出し、20分以上冷却させた。次にパネルを汚物源に接触しないように丁寧に取扱い、各パネルの初期重量を0.1mg単位で記録した。
本発明の液体組成物は酸性であり、有機酸または無機酸、またはその両方を含有する。これらの酸は当業者に公知の任意の有機酸または無機酸であってよいが、強弱両方の有機酸(すなわち、クエン酸とメタンスルホン酸)、および強弱両方の無機酸(すなわち、硝酸、硫酸、およびリン酸)の混合物またはこれらの任意の組み合わせを用いることが好ましい。クエン酸および硫酸およびメタンスルホン酸の組み合わせの結果、洗浄有効性が驚異的に増加する。
酸清浄剤の結果を考慮し、次に同様の調合物を、酸活性または酸抵抗性酵素を用いて、酸組成物の洗浄性能が向上するかどうかをテストした。酵素は、洗浄清浄剤に用いるにあたり、多くの利点を示す。特に、低温における洗浄機能を提供し、ステンレススチール装置に対して腐蝕性がなく、硬水で比較的安定性があり、生物分解性能を有する。酵素は、化学的選択性が高く、システムが使用するpHおよび温度を酵素のそれらと合致させることができれば、非常に効率的になり、最大限に活性する。したがって、本発明に関しては、牛乳汚物に対して有効であり、消毒およびスケール除去に用いる有機酸および無機酸において安定性の高い酸活性または酸抵抗性タンパク質分解酵素を特定することが重要である。
脂肪族アルキル−1,3−ジアミノプロパンは、アルキル−1,3−プロピレンジアミン、アルキル−1,3−プロピレンジアミン、およびアルキル−1,3−トリメチレンジアミンとしても知られ、一般に下記式で表される。
R−NH−CH2CH2CH2NH2
式中、RはC4〜C22脂肪族アルキルラジカル基、およびより好ましくはC8〜C18脂肪族アルキルラジカル基である。
界面活性剤は、清浄剤の重要な成分であり、例えば、湿潤、界面張力の低減、および洗浄補助などの重要で有益な特性を清浄剤に付加する。しかし、多くの界面活性剤は撹拌されると発泡する傾向がある。CIPシステムでは、洗浄時間を可能な限り短くしたいので、過度の発泡、または長時間の発泡は非常に望ましくない。CIPシステムは、特に、洗浄用清浄剤の撹拌およびスラッグ動作により、泡立ちやすい。また、タンパク質汚物は一般に発泡しやすい。従って、これらのシステムでは発泡性のない、または発泡性の非常に低い界面活性剤を選ぶことが重要である。
迅速な洗浄およびすすぎサイクルが重要となるシステム、特に洗浄サイクルがおよそ6〜8分のCIPシステムでは、清浄剤の発泡性が問題となる。清浄剤の調合物に関連する発泡性を最適化する(すなわち、発泡のレベルを可能な限り低減する)ために、一連の実験を実施した。
上述のように、本発明に係る調合物は、オールインワン清浄剤として、抗菌機能を有することが好ましい。食品処理業界では、特に、乳製品業界では、乳製品を汚染する可能性のあるグラム陽性およびグラム陰性バクテリア(例えば、緑膿菌、大腸菌、黄色ブドウ球菌、腸球菌)などの潜在的に有害な微生物種の堆積を防止するために、食品処理装置を消毒することが重要である。
ポリ(ヘキサメチレン ビグアニド)塩酸塩(PHMB)
以下の実施例では、本発明に係り製造されたいくつかの清浄剤調合物の殺菌有効性を、Basic Bactericidal Activity−European Standard(基礎殺菌活性―欧州規格)EN1040および、Bactericidal Activity of Chemical Disinfectants and Antiseptics used in Food, Industrial, Domestic, and Industrial Areas−European Standard(食品用、工業用、家庭用、および工業分野に用いられる化学消毒剤および防腐剤の殺菌活性―欧州規格)EN1276によって測定した。
2種類の清浄剤調合物(表10の調合物136および139)を各種テスト条件でテストした。結果を表22に示す。
水の軟化、または処理、また析出物や他の塩の生成の防止を目的として、清浄組成物に、金属イオン封鎖剤、ビルダー、およびキレート剤を用いる。一般に金属イオン封鎖剤は、水道水に通常見られる金属イオンを錯体化、または調整し、それによって金属イオンが組成物中の清浄成分の機能を邪魔しないようにする。
一定の温度範囲において溶液中の短鎖脂肪酸および、非イオン界面活性剤などの分散可能な他の有機材料を可溶化するために、ヒドロトロープまたは可溶化剤を用いることができる。ヒドロトロープ、または可溶化剤成分は、非イオン、または陰イオン材料であることが好ましい。好ましい陰イオン界面活性剤には、アルカリ金属アルカン スルホネートおよびジスルホネートなどのアルカン スルホネート、アルキル スルフェート、直鎖アルキル ベンゼンまたはナフタレン スルホネート、α−オレフィン スルホネート、第二級アルカン スルホネート、アルキル エーテル スルフェートまたはスルホネート、アルキル ホスフェートまたはホスホネート、ジアルカイルスルホスクシネート、ジアルキルスルホコハク酸エステル、およびソルビタン エステルおよびC8〜C10 アルキル グルコシドなどの糖エステルがある。C8、C10、C12アルキルスルホネート誘導体などの発泡性の高いヒドロトロープでも、ある程度の発泡が許容される場合に、用いることができる。
過剰な発泡を避けたい用途(すなわち、CIPシステム)では、主要な界面活性剤を補助して、発泡を低減する、または発泡した泡を短時間で破壊するために、消泡剤または脱泡剤を用いる。好ましい脱泡剤には、脂肪族またはアルキル芳香族疎水性化合物で親水性アルキレン オキシド基を濃縮して生成された化合物がある。脱泡剤の例としては、エチレンオキシドを用いるアルコールまたはアルキルフェノールのポリエチレンオキシド縮合体(例えば、アルコールまたは、およそ5〜15の直鎖、または分岐鎖構造の炭素原子を含むアルキル基を有する、アルキルフェノールの濃縮物)が挙げられる。エチレンオキシドは、アルコールまたはアルキルフェノールの1モルに対して10〜60モル存在することが好ましい。これらの化合物のアルキ置換基は、重合化、プロピレン、ブチレン、イソブチレン、およびジイソブチレンから生成される。
本発明の清浄剤(100重量%とする)の残りの部分は水、好ましくは脱イオン水である。アルコール、グリコール、ポリエチレン グリコール、ポリプロピレン グリコールなどの有機溶剤は非水系、または水系で水と組み合わせて用いることができる。しかし、香料/芳香剤、保存料、着色料、溶剤、バッファ、安定剤、遊離基捕捉剤、汚物懸濁剤、結晶成長阻止剤、汚物分離剤、分散剤、染料、および顔料は、高酸性環境において安定しているものに限り、含有することができる。
Claims (52)
- 濃縮液体清浄組成物であって、
無機酸、有機酸、およびそれらの混合物からなる群から選択される酸と、一般式R−NH−CH2CH2CH2NH2(式中RはC4〜C22アルキル基)で表される脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩とを含有する組成物。 - Rは置換または非置換、直鎖または分岐鎖、および飽和または不飽和である請求項1の組成物。
- 前記脂肪族アルキル−1,3−ジアミノプロパンはココナツ、大豆、牛脂、またはオレオソースから抽出される請求項1の組成物。
- 前記脂肪族アルキル−1,3−ジアミノプロパンに酢酸を添加することにより形成される脂肪族アルキル−1,3−ジアミノプロパン酢酸塩を含有する請求項1の組成物。
- 前記有機酸は一般式R´−SO3H(式中R´はC1〜C16アルキル基)で表される請求項1の組成物。
- 界面活性剤系を更に含有する請求項1の組成物。
- 前記界面活性剤系は陰イオン、非イオン、陽イオン、両性、および両性イオン系の界面活性剤およびその混合物からなる群から選択される請求項6の組成物。
- 前記界面活性剤系はアルコキシル化直鎖脂肪アルコールを含有する請求項7の組成物。
- 前記界面活性剤系はエトキシル化およびプロポキシル化直鎖脂肪アルコールまたはそれらのエーテル誘導体を含有する請求項7の組成物。
- 2つ以上の異なる界面活性剤を含有する界面活性剤系を含む請求項1の組成物。
- 抗菌剤または抗菌剤の混合物を更に含有する請求項1の組成物。
- 前記抗菌剤はC4〜C15脂肪酸、クロロフェノール、一価および多価アルコール、芳香族および脂肪族アルコール、α−ヒドロキシ酸、クロロヘキシジンおよびそれらの塩、過酸化水素、過酸素酸、2−ブロモ−2−ニトロ−1,3−プロパンジオール、ビグアニド化合物、抗菌無機塩、キレート剤、グルタルアルデヒド、第四級アンモニウム化合物、およびそれらの組み合わせからなる群から選択される請求項11の組成物。
- 前記抗菌剤は脂肪族C6〜C12脂肪酸である請求項12の組成物。
- 前記抗菌剤はグリコール酸および乳酸からなる群から選択される請求項12の組成物。
- 前記有機および無機酸は、それぞれおよそ1〜80重量%のレベルで存在する請求項1の組成物。
- 前記無機酸はリン酸、硝酸、塩酸、硫酸、およびスルファミン酸およびそれらの混合物からなる群から選択される鉱酸を含有する請求項1の組成物。
- 前記組成物は、有機酸または有機酸の混合物を、およそ40重量%以下含有し、前記有機酸または有機酸の混合物はC1〜C16アルキルスルホン酸を含有する請求項1の組成物。
- 前記有機酸はクエン酸、メタンスルホン酸、エタンスルホン酸、プロパンスルホン酸、ブタンスルホン酸、酢酸、ヒドロキシ酢酸、プロピオン酸、ヒドロキシプロピオン酸、a−ケトプロピオン酸、酪酸、マンデル酸、吉草酸、コハク酸、酒石酸、リンゴ酸、シュウ酸、フマル酸、アジピン酸、マレイン酸、ソルビン酸、安息香酸、コハク酸、グルタル酸、アジピン酸、α−ヒドロキシ酸、エチレンジアミン四酢酸(EDTA)、ホスホン酸、オクチル ホスホン酸、アクリル酸、ポリアクリル酸、アスパラギン酸、ポリアスパラギン酸、p−ヒドロキシ安息香酸、イミノ酢酸、およびそれらの混合物からなる群から選択される請求項1の組成物。
- 酸で活性化する、または酸に抵抗性がある酵素または酵素の混合物をおよそ20重量%以下、更に含有する請求項1の組成物。
- 前記酵素は、酸で活性化する、または酸に抵抗性があるタンパク質分解酵素、酸リポラーゼ酵素、リパーゼ酵素、酸に抵抗性があるアミラーゼ酵素、セルラーゼ酵素、酸ペルオキシダーゼ、およびそれらの組み合わせからなる群から選択される請求項19の組成物。
- およそ0〜50重量%のヒドロトロピー剤を更に含有する請求項1の組成物。
- 前記ヒドロトロピー剤は、アルカン スルホネート、アルカン ジスルホネート、アリール スルホネート、アリール ジスルホネート、α−オレフィン スルホネート、第二級アルカン スルホネート、アルキル スルフェート、アルキル エーテル スルフェート、アルキル エーテル スルホネート、アルキル ホスフェート、アルキル ホスホネート、ジアルキルスルホスクシネート、ジアルキルスルホコハク酸エステル、糖エステル、およびそれらの組み合わせからなる群から選択される請求項21の組成物。
- 金属イオン封鎖剤、ビルダー、およびキレート剤からなる群から選択される1つ、またはそれ以上の成分を更に含有する請求項1の組成物。
- 前記ビルダーは、アルカリ金属 ポリホスフェート、水不溶性、結晶および非結晶アルミノケイ酸塩、結晶および非結晶ゼオライト、ポリカルボン酸およびニトリロ酢酸およびこれらのアルカリ金属塩、非架橋ポリアクリレートおよびこれらの塩、およびそれらの組み合わせからなる群から選択される請求項23の組成物。
- 前記キレート剤は、ホスホネートキレート剤、アミノ ホスホネート化合物、アミノ カルボキシレート化合物、シトレート化合物、アクリレート、ポリアクリレート、EDTA−Na4およびそれらの混合物からなる群から選択される請求項23の組成物。
- pHがおよそ4未満である請求項1の組成物。
- pHがおよそ0.1〜4.0の間である請求項1の組成物。
- およそ0.01〜15重量%の脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩を含有する請求項1の組成物。
- 食品で汚れた表面の洗浄、消毒、およびスケール除去を単一工程で行うことができる、請求項1の組成物。
- 酸で活性化する、または酸に抵抗性がある酵素と、一般式R−NH−CH2CH2CH2NH2(式中RはC4〜C22アルキル基)で表される脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩とを含有する酸性清浄組成物。
- 前記酵素は、酸で活性化する、または酸に抵抗性があるタンパク質分解酵素、酸リポラーゼ酵素、リパーゼ酵素、酸に抵抗性があるアミラーゼ酵素、セルラーゼ酵素、酸ペルオキシダーゼ、およびそれらの組み合わせからなる群から選択される請求項30の組成物。
- 抗菌剤または抗菌剤の混合物を更に含有する請求項30の組成物。
- pHがおよそ4未満である請求項30の組成物。
- およそ40重量%以下のC1〜C16アルキルスルホン酸を更に含有する請求項30の組成物。
- およそ0.01〜15重量%の脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩を含有する請求項30の組成物。
- 一般式R−NH−CH2CH2CH2NH2(式中RはC4〜C22アルキル基およびC1〜C16アルキルスルホン酸)で表される脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩とを含有する酸性清浄組成物。
- 前記アルキルスルホン酸はメタンスルホン酸である請求項36の組成物。
- およそ40重量%以下のメタンスルホン酸を含有する請求項37の組成物。
- 請求項1の組成物を表面に適用する工程を含む表面洗浄方法。
- 前記適用工程の前に前記組成物を希釈して使用溶液を生成する工程を更に含む請求項39の方法。
- 前記表面は牛乳取扱いシステム、食品処理工場、食品、または飲料処理装置の表面である請求項39の方法。
- 前記表面は定置洗浄システムの表面である請求項39の方法。
- 前記表面は食品、牛乳、または飲料の汚物で汚れている請求項39の方法。
- 一般式R−NH−CH2CH2CH2NH2(式中RはC4〜C22アルキル基)で表される脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩を含有する酸性清浄剤の発泡を低減する方法であって、前記清浄剤に2つ以上の異なる界面活性剤を含む界面活性剤系を添加する工程を含む方法。
- 前記界面活性剤は陰イオン、非イオン、陽イオン、両性、および両性イオン系の界面活性剤およびそれらの混合物からなる群から独立して選択される請求項44の方法。
- 前記界面活性剤はアミン オキシド、ホスフィン オキシド、スルホキシド、スルホネート、スルフェート、ベタイン、第一級アルキル スルフェート、アルキルスルホネート、アリールアルキルスルホネート、第二級アルキルスルホネート、ポリ低アルコキシ化高級アルコールおよびエーテル、アルコキシル化直鎖脂肪アルコール、アルキル多糖、第四級アンモニウム化合物、第一級、第二級、および第三級脂肪族アミンの塩、およびそれらの組み合わせからなる群から独立して選択される請求項45の方法。
- およそ1重量部の請求項1の組成物と、およそ10〜300重量部の水とを含有する液体清浄使用溶液。
- 界面活性剤系を更に含有する請求項47の使用溶液。
- 前記界面活性剤系は陰イオン、非イオン、陽イオン、両性、および両性イオン系の界面活性剤およびそれらの混合物からなる群から選択される請求項48の使用溶液。
- 抗菌剤または抗菌剤の混合物を更に含有する請求項47の使用溶液。
- 酸で活性化する、または酸に抵抗性がある酵素を更に含有する請求項47の使用溶液。
- pHがおよそ0.1〜6である請求項47の使用溶液。
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JP2011528231A (ja) * | 2008-07-17 | 2011-11-17 | デラヴァル ホールディング エービー | 食品および飲料の製造および取扱い設備の洗浄方法 |
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JP2015074668A (ja) * | 2013-10-07 | 2015-04-20 | 株式会社Adeka | 酸性cip用洗浄剤組成物およびそれを用いたcip洗浄方法 |
JP2017527599A (ja) * | 2014-09-17 | 2017-09-21 | ロンザ インコーポレーテッド | 活性化された過酸化水素消毒剤組成物 |
JP2017043644A (ja) * | 2015-08-24 | 2017-03-02 | 株式会社Adeka | 酸性cip用洗浄剤組成物およびcip洗浄方法 |
KR20200037416A (ko) * | 2017-09-26 | 2020-04-08 | 에코랍 유에스에이 인코퍼레이티드 | 산/음이온성 항균 및 살바이러스 조성물 및 이의 용도 |
JP2020535155A (ja) * | 2017-09-26 | 2020-12-03 | エコラボ ユーエスエー インコーポレイティド | 酸性/アニオン性抗菌および殺ウイルス組成物ならびにその使用 |
US11026422B2 (en) | 2017-09-26 | 2021-06-08 | Ecolab Usa Inc. | Acid/anionic antimicrobial and virucidal compositions and uses thereof |
KR102437623B1 (ko) * | 2017-09-26 | 2022-08-26 | 에코랍 유에스에이 인코퍼레이티드 | 산/음이온성 항균 및 살바이러스 조성물 및 이의 용도 |
US11937602B2 (en) | 2017-09-26 | 2024-03-26 | Ecolab Usa Inc. | Solid acid/anionic antimicrobial and virucidal compositions and uses thereof |
US11950595B2 (en) | 2017-09-26 | 2024-04-09 | Ecolab Usa Inc. | Acid/anionic antimicrobial and virucidal compositions and uses thereof |
JP2020059859A (ja) * | 2020-01-07 | 2020-04-16 | 株式会社Adeka | 酸性cip用洗浄剤組成物およびcip洗浄方法 |
Also Published As
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CN101031634A (zh) | 2007-09-05 |
AU2005272935B2 (en) | 2011-08-18 |
CA2576999A1 (en) | 2006-02-23 |
MX2007001762A (es) | 2007-07-11 |
RU2374313C2 (ru) | 2009-11-27 |
NZ589023A (en) | 2012-05-25 |
EP1791941A4 (en) | 2009-12-16 |
WO2006020608A2 (en) | 2006-02-23 |
RU2007108540A (ru) | 2008-09-20 |
NZ553326A (en) | 2010-11-26 |
EP1791941B1 (en) | 2013-03-13 |
US7494963B2 (en) | 2009-02-24 |
WO2006020608A3 (en) | 2006-10-05 |
US20060035808A1 (en) | 2006-02-16 |
BRPI0513333B1 (pt) | 2019-04-02 |
JP5165373B2 (ja) | 2013-03-21 |
AU2005272935A8 (en) | 2010-07-22 |
BRPI0513333A (pt) | 2008-05-06 |
AU2005272935A1 (en) | 2006-02-23 |
EP1791941A2 (en) | 2007-06-06 |
PL1791941T3 (pl) | 2013-10-31 |
US7501027B2 (en) | 2009-03-10 |
CA2576999C (en) | 2014-09-30 |
US20080015134A1 (en) | 2008-01-17 |
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