JP5165373B2 - 非塩化濃縮オールインワン酸性清浄剤およびその使用方法 - Google Patents
非塩化濃縮オールインワン酸性清浄剤およびその使用方法 Download PDFInfo
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- JP5165373B2 JP5165373B2 JP2007525722A JP2007525722A JP5165373B2 JP 5165373 B2 JP5165373 B2 JP 5165373B2 JP 2007525722 A JP2007525722 A JP 2007525722A JP 2007525722 A JP2007525722 A JP 2007525722A JP 5165373 B2 JP5165373 B2 JP 5165373B2
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- acid
- composition
- cleaning
- alkyl
- diaminopropane
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
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- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 5
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- 125000003118 aryl group Chemical group 0.000 claims description 4
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- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/08—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3209—Amines or imines with one to four nitrogen atoms; Quaternized amines
-
- C11D2111/20—
Description
以下の実施例の多くは本発明に係る酸清浄剤の洗浄評価に関するものである。試料の洗浄有効性は、市販のクロロアルカリ清浄剤と比較した。これらの洗浄テストでは、大きさが3”x6” x 0.0037”(7.6cm x 15.2cm x 0.0094cm)で、一端に1/4”(0.6cm)の穴を有する304ステンレススチール、プラスチック、またはガラスのパネルを最初に粉末クロロアルカリ清浄剤で洗浄し、水ですすぎ、キシレンで拭き、次にイソプロパノールで拭き、その後、炉乾燥(100〜110℃で10〜15分間)し、溶剤を完全に蒸発させた。剛性のワイヤハンガーをパネルの穴に取り付けることによって、パネルを炉内に吊るし、炉または炉内の他の品目に接触しないようにした。次に乾燥したパネルを炉から取り出し、20分以上冷却させた。次にパネルを汚物源に接触しないように丁寧に取扱い、各パネルの初期重量を0.1mg単位で記録した。
本発明の液体組成物は酸性であり、有機酸または無機酸、またはその両方を含有する。これらの酸は当業者に公知の任意の有機酸または無機酸であってよいが、強弱両方の有機酸(すなわち、クエン酸とメタンスルホン酸)、および強弱両方の無機酸(すなわち、硝酸、硫酸、およびリン酸)の混合物またはこれらの任意の組み合わせを用いることが好ましい。クエン酸および硫酸およびメタンスルホン酸の組み合わせの結果、洗浄有効性が驚異的に増加する。
酸清浄剤の結果を考慮し、次に同様の調合物を、酸活性または酸抵抗性酵素を用いて、酸組成物の洗浄性能が向上するかどうかをテストした。酵素は、洗浄清浄剤に用いるにあたり、多くの利点を示す。特に、低温における洗浄機能を提供し、ステンレススチール装置に対して腐蝕性がなく、硬水で比較的安定性があり、生物分解性能を有する。酵素は、化学的選択性が高く、システムが使用するpHおよび温度を酵素のそれらと合致させることができれば、非常に効率的になり、最大限に活性する。したがって、本発明に関しては、牛乳汚物に対して有効であり、消毒およびスケール除去に用いる有機酸および無機酸において安定性の高い酸活性または酸抵抗性タンパク質分解酵素を特定することが重要である。
脂肪族アルキル−1,3−ジアミノプロパンは、アルキル−1,3−プロピレンジアミン、アルキル−1,3−プロピレンジアミン、およびアルキル−1,3−トリメチレンジアミンとしても知られ、一般に下記式で表される。
R−NH−CH2CH2CH2NH2
式中、RはC4〜C22脂肪族アルキルラジカル基、およびより好ましくはC8〜C18脂肪族アルキルラジカル基である。
界面活性剤は、清浄剤の重要な成分であり、例えば、湿潤、界面張力の低減、および洗浄補助などの重要で有益な特性を清浄剤に付加する。しかし、多くの界面活性剤は撹拌されると発泡する傾向がある。CIPシステムでは、洗浄時間を可能な限り短くしたいので、過度の発泡、または長時間の発泡は非常に望ましくない。CIPシステムは、特に、洗浄用清浄剤の撹拌およびスラッグ動作により、泡立ちやすい。また、タンパク質汚物は一般に発泡しやすい。従って、これらのシステムでは発泡性のない、または発泡性の非常に低い界面活性剤を選ぶことが重要である。
迅速な洗浄およびすすぎサイクルが重要となるシステム、特に洗浄サイクルがおよそ6〜8分のCIPシステムでは、清浄剤の発泡性が問題となる。清浄剤の調合物に関連する発泡性を最適化する(すなわち、発泡のレベルを可能な限り低減する)ために、一連の実験を実施した。
上述のように、本発明に係る調合物は、オールインワン清浄剤として、抗菌機能を有することが好ましい。食品処理業界では、特に、乳製品業界では、乳製品を汚染する可能性のあるグラム陽性およびグラム陰性バクテリア(例えば、緑膿菌、大腸菌、黄色ブドウ球菌、腸球菌)などの潜在的に有害な微生物種の堆積を防止するために、食品処理装置を消毒することが重要である。
ポリ(ヘキサメチレン ビグアニド)塩酸塩(PHMB)
以下の実施例では、本発明に係り製造されたいくつかの清浄剤調合物の殺菌有効性を、Basic Bactericidal Activity−European Standard(基礎殺菌活性―欧州規格)EN1040および、Bactericidal Activity of Chemical Disinfectants and Antiseptics used in Food, Industrial, Domestic, and Industrial Areas−European Standard(食品用、工業用、家庭用、および工業分野に用いられる化学消毒剤および防腐剤の殺菌活性―欧州規格)EN1276によって測定した。
2種類の清浄剤調合物(表10の調合物136および139)を各種テスト条件でテストした。結果を表22に示す。
水の軟化、または処理、また析出物や他の塩の生成の防止を目的として、清浄組成物に、金属イオン封鎖剤、ビルダー、およびキレート剤を用いる。一般に金属イオン封鎖剤は、水道水に通常見られる金属イオンを錯体化、または調整し、それによって金属イオンが組成物中の清浄成分の機能を邪魔しないようにする。
一定の温度範囲において溶液中の短鎖脂肪酸および、非イオン界面活性剤などの分散可能な他の有機材料を可溶化するために、ヒドロトロープまたは可溶化剤を用いることができる。ヒドロトロープ、または可溶化剤成分は、非イオン、または陰イオン材料であることが好ましい。好ましい陰イオン界面活性剤には、アルカリ金属アルカン スルホネートおよびジスルホネートなどのアルカン スルホネート、アルキル スルフェート、直鎖アルキル ベンゼンまたはナフタレン スルホネート、α−オレフィン スルホネート、第二級アルカン スルホネート、アルキル エーテル スルフェートまたはスルホネート、アルキル ホスフェートまたはホスホネート、ジアルカイルスルホスクシネート、ジアルキルスルホコハク酸エステル、およびソルビタン エステルおよびC8〜C10 アルキル グルコシドなどの糖エステルがある。C8、C10、C12アルキルスルホネート誘導体などの発泡性の高いヒドロトロープでも、ある程度の発泡が許容される場合に、用いることができる。
過剰な発泡を避けたい用途(すなわち、CIPシステム)では、主要な界面活性剤を補助して、発泡を低減する、または発泡した泡を短時間で破壊するために、消泡剤または脱泡剤を用いる。好ましい脱泡剤には、脂肪族またはアルキル芳香族疎水性化合物で親水性アルキレン オキシド基を濃縮して生成された化合物がある。脱泡剤の例としては、エチレンオキシドを用いるアルコールまたはアルキルフェノールのポリエチレンオキシド縮合体(例えば、アルコールまたは、およそ5〜15の直鎖、または分岐鎖構造の炭素原子を含むアルキル基を有する、アルキルフェノールの濃縮物)が挙げられる。エチレンオキシドは、アルコールまたはアルキルフェノールの1モルに対して10〜60モル存在することが好ましい。これらの化合物のアルキ置換基は、重合化、プロピレン、ブチレン、イソブチレン、およびジイソブチレンから生成される。
本発明の清浄剤(100重量%とする)の残りの部分は水、好ましくは脱イオン水である。アルコール、グリコール、ポリエチレン グリコール、ポリプロピレン グリコールなどの有機溶剤は非水系、または水系で水と組み合わせて用いることができる。しかし、香料/芳香剤、保存料、着色料、溶剤、バッファ、安定剤、遊離基捕捉剤、汚物懸濁剤、結晶成長阻止剤、汚物分離剤、分散剤、染料、および顔料は、高酸性環境において安定しているものに限り、含有することができる。
Claims (30)
- 濃縮液体清浄組成物であって、
硫酸、硝酸、塩酸、メタンスルホン酸、エタンスルホン酸、プロパンスルホン酸、ブタンスルホン酸、シュウ酸、エチレンジアミン四酢酸(EDTA)、ホスホン酸、およびそれらの混合物からなる群から選択される酸と、
一般式R−NH−CH2CH2CH2NH2(式中RはC4〜C22アルキル基)で表される脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩とを含有し、
pHが4未満である、組成物。 - 1重量部の請求項1の組成物と、10〜300重量部の水とを含有する液体清浄使用溶液組成物。
- 無機酸、有機酸、およびそれらの混合物からなる群から選択される酸と、
0.00003−0.0075重量%の一般式R−NH−CH 2 CH 2 CH 2 NH 2 (式中RはC4〜C22アルキル基)で表される脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩とを含有し、
pHが0.1−5である液体清浄使用溶液組成物。 - 前記脂肪族アルキル−1,3−ジアミノプロパンはココナツ、大豆、牛脂、またはオレオソースから抽出される請求項1〜3のいずれかに記載の組成物。
- 前記脂肪族アルキル−1,3−ジアミノプロパンに酢酸を添加することにより形成される脂肪族アルキル−1,3−ジアミノプロパン酢酸塩を含有する請求項1〜4のいずれかに記載の組成物。
- 前記有機酸が一般式R’−SO3H(式中R’はC1〜C16アルキル基)で表される請求項3〜5のいずれかに記載の組成物。
- 前記有機酸がメタンスルホン酸である請求項6に記載の組成物。
- 陰イオン、非イオン、陽イオン、両性、および両性イオン系の界面活性剤およびその混合物からなる群から選択される界面活性剤を含有する請求項1〜7のいずれかに記載の組成物。
- 前記界面活性剤系はアルコキシル化直鎖脂肪アルコールを含有する請求項8に記載の組成物。
- 少なくとも2種の界面活性剤系を含む請求項1〜9のいずれかに記載の組成物。
- 抗菌剤または抗菌剤の混合物を更に含有する請求項1〜10のいずれかに記載の組成物。
- 前記抗菌剤はC4〜C15脂肪酸、クロロフェノール、一価および多価アルコール、芳香族および脂肪族アルコール、α−ヒドロキシ酸、クロロヘキシジンおよびそれらの塩、過酸化水素、過酸素酸、2−ブロモ−2−ニトロ−1,3−プロパンジオール、ビグアニド化合物、抗菌無機塩、キレート剤、グルタルアルデヒド、第四級アンモニウム化合物、およびそれらの組み合わせからなる群から選択される請求項11に記載の組成物。
- 前記抗菌剤はグリコール酸、乳酸またはそれらの組み合わせを含む請求項12に記載の組成物。
- 前記無機酸はリン酸、硝酸、塩酸、硫酸、およびスルファミン酸およびそれらの混合物からなる群から選択される鉱酸を含有する請求項3〜13のいずれかに記載の組成物。
- 前記有機酸はクエン酸、メタンスルホン酸、エタンスルホン酸、プロパンスルホン酸、ブタンスルホン酸、酢酸、ヒドロキシ酢酸、プロピオン酸、ヒドロキシプロピオン酸、a−ケトプロピオン酸、酪酸、マンデル酸、吉草酸、コハク酸、酒石酸、リンゴ酸、シュウ酸、フマル酸、アジピン酸、マレイン酸、ソルビン酸、安息香酸、グルタル酸、アジピン酸、α−ヒドロキシ酸、エチレンジアミン四酢酸(EDTA)、ホスホン酸、オクチル ホスホン酸、アクリル酸、ポリアクリル酸、アスパラギン酸、ポリアスパラギン酸、p−ヒドロキシ安息香酸、イミノ酢酸、およびそれらの混合物からなる群から選択される請求項3〜13のいずれかに記載の組成物。
- 酸で活性化する、または酸に抵抗性がある酵素、ヒドロトロピー剤、金属イオン封鎖剤、ビルダー、およびキレート剤からなる群から選択される1つ、またはそれ以上の成分を更に含有する請求項1〜13のいずれかに記載の組成物。
- 前記組成物のpHが2.0−5である請求項3に記載の組成物。
- 前記組成物が、0.00003−0.005重量%の前記脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩を含有する請求項3に記載の組成物。
- 前記組成物が、0.01〜15重量%の前記脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩を含有する請求項1に記載の組成物。
- 無機酸、有機酸およびそれらの混合物からなる群から選択される酸と、一般式R−NH−CH 2 CH 2 CH 2 NH 2 (式中RはC4〜C22アルキル基)で表される脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩とを含有し、pHが0.1−5である液体清浄剤を、
定置洗浄システムの表面と接触させる工程を含む、
定置洗浄(CIP)システムの洗浄方法。 - 前記接触工程の前に、前記清浄剤の組成物を希釈して使用溶液を生成する工程を更に含む請求項20に記載の方法。
- 前記使用溶液が、0.00003−0.0075重量%の前記脂肪族アルキル−1,3−ジアミノプロパンまたはそれらの塩を含有する請求項21に記載の方法。
- 前記CIPシステムが、牛乳取扱いシステム、食品処理工場、食品または飲料処理装置である請求項20〜22のいずれかに記載の方法。
- 前記接触工程の前、前記CIPシステムの表面が、食品、牛乳、または飲料の汚物で汚れている請求項20〜23のいずれかに記載の方法。
- 前記方法は、前記CIPシステムの表面の洗浄、消毒、およびスケール除去を単一工程の洗浄サイクルで行う請求項20〜24のいずれかに記載の方法。
- 前記脂肪族アルキル−1,3−ジアミノプロパンが、ココナツ、大豆、牛脂、またはオレオソースから抽出される請求項20〜25のいずれかに記載の方法。
- 前記有機酸が、クエン酸、メタンスルホン酸、エタンスルホン酸、プロパンスルホン酸、ブタンスルホン酸、酢酸、ヒドロキシ酢酸、プロピオン酸、ヒドロキシプロピオン酸、a−ケトプロピオン酸、酪酸、マンデル酸、吉草酸、コハク酸、酒石酸、リンゴ酸、シュウ酸、フマル酸、アジピン酸、マレイン酸、ソルビン酸、安息香酸、グルタル酸、アジピン酸、α−ヒドロキシ酸、エチレンジアミン四酢酸(EDTA)、ホスホン酸、オクチル ホスホン酸、アクリル酸、ポリアクリル酸、アスパラギン酸、ポリアスパラギン酸、p−ヒドロキシ安息香酸、イミノ酢酸、およびそれらの混合物からなる群から選択される請求項20〜26のいずれかに記載の方法。
- 前記有機酸が一般式R’−SO 3 H(式中R’はC1〜C16アルキル基)で表される請求項20〜27のいずれかに記載の方法。
- 前記清浄剤が、陰イオン、非イオン、陽イオン、両性、および両性イオン系の界面活性剤およびその混合物からなる群から選択される界面活性剤を含有する請求項20〜28のいずれかに記載の方法。
- 前記清浄剤が、酸で活性化する、または酸に抵抗性がある酵素、ヒドロトロピー剤、金属イオン封鎖剤、ビルダー、およびキレート剤からなる群から選択される1つ、またはそれ以上の成分を更に含有する請求項20〜29のいずれかに記載の方法。
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US10/916,147 | 2004-08-11 | ||
US10/916,147 US7494963B2 (en) | 2004-08-11 | 2004-08-11 | Non-chlorinated concentrated all-in-one acid detergent and method for using the same |
PCT/US2005/028215 WO2006020608A2 (en) | 2004-08-11 | 2005-08-08 | Non-chlorinated concentrated all-in-one acid detergent and method for using the same |
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JP2008510033A JP2008510033A (ja) | 2008-04-03 |
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EP (1) | EP1791941B1 (ja) |
JP (1) | JP5165373B2 (ja) |
CN (1) | CN101031634A (ja) |
AU (1) | AU2005272935B2 (ja) |
BR (1) | BRPI0513333B1 (ja) |
CA (1) | CA2576999C (ja) |
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RU (1) | RU2374313C2 (ja) |
WO (1) | WO2006020608A2 (ja) |
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- 2005-08-08 MX MX2007001762A patent/MX2007001762A/es active IP Right Grant
- 2005-08-08 WO PCT/US2005/028215 patent/WO2006020608A2/en active Application Filing
- 2005-08-08 EP EP05793069A patent/EP1791941B1/en active Active
- 2005-08-08 AU AU2005272935A patent/AU2005272935B2/en not_active Ceased
- 2005-08-08 BR BRPI0513333-5A patent/BRPI0513333B1/pt active IP Right Grant
- 2005-08-08 PL PL05793069T patent/PL1791941T3/pl unknown
- 2005-08-08 CA CA2576999A patent/CA2576999C/en active Active
- 2005-08-08 CN CNA200580032217XA patent/CN101031634A/zh active Pending
- 2005-08-08 NZ NZ589023A patent/NZ589023A/en not_active IP Right Cessation
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2007
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Also Published As
Publication number | Publication date |
---|---|
EP1791941B1 (en) | 2013-03-13 |
CA2576999A1 (en) | 2006-02-23 |
MX2007001762A (es) | 2007-07-11 |
US20060035808A1 (en) | 2006-02-16 |
PL1791941T3 (pl) | 2013-10-31 |
EP1791941A4 (en) | 2009-12-16 |
BRPI0513333B1 (pt) | 2019-04-02 |
US7494963B2 (en) | 2009-02-24 |
WO2006020608A3 (en) | 2006-10-05 |
CA2576999C (en) | 2014-09-30 |
AU2005272935A8 (en) | 2010-07-22 |
WO2006020608A2 (en) | 2006-02-23 |
US20080015134A1 (en) | 2008-01-17 |
US7501027B2 (en) | 2009-03-10 |
EP1791941A2 (en) | 2007-06-06 |
RU2007108540A (ru) | 2008-09-20 |
JP2008510033A (ja) | 2008-04-03 |
RU2374313C2 (ru) | 2009-11-27 |
BRPI0513333A (pt) | 2008-05-06 |
AU2005272935B2 (en) | 2011-08-18 |
NZ589023A (en) | 2012-05-25 |
CN101031634A (zh) | 2007-09-05 |
NZ553326A (en) | 2010-11-26 |
AU2005272935A1 (en) | 2006-02-23 |
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