JP2008143838A - Cosmetic containing surface-treated powder - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a means for preventing localization with time of a specific function powder in a powder-containing cosmetic. <P>SOLUTION: The cosmetic comprises (1) surface-treated powder prepared by the surface treatment with a perfluoroalkylsilane represented by general formula (I), and, (2) one or more kinds selected from the group consisting of sericite titania, silica/iron oxide-coated sericite titania, titanium dioxide-coated silica, a fiber having a length of 10-1,000 μm, tubular titanium dioxide, cleaved talc, cleaved sericite, iris foil, hydroxyapatite-treated powder and a metal ion clathrate clay mineral. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a cosmetic, and more particularly to a cosmetic containing a surface-treated powder.

  In cosmetics, the powder has a function of covering undesired localization of pigments such as skin spots and freckles, etc., and making them inconspicuous due to its optical effect. Such an optical effect is often cultivated by a special functional powder such as a powder that exhibits an effect only in a specific direction and a powder that has a concealing power but does not feel due to a surface diffusion effect. Special functional powders exhibit a remarkable optical effect even in a small amount. For this reason, in cosmetics containing such powders, localization of the special functional powders is essential. This is a significant problem for powder cosmetics. Such a powder localization phenomenon in powder cosmetics is regarded as “decoration of makeup” along with changes in liquid wetting. Causes of localization include reduced skin adhesion due to sweat, movement and vibration of powder due to fluid effects, and movement and dropout of powder due to physical adaptability such as wind. As a means for preventing this, a method of coating the surface of a powder with various surface treatment agents is also known in “localization suppression” and “liquid wetting suppression”. Baking of methylsiloxane, silylation with a silane coupling agent, coating with perfluoroalkyl phosphate, coating with N-acyl glutamate, coating with phospholipid, etc. are known. Among these, the coating with a surface treatment agent having a perfluoroalkyl group has both water and oil repellency, so it can prevent both localization due to sweat and sebum, thereby improving the durability of the makeup. For example, perfluoroalkylsiloxanes such as penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane are used as the technology using such a compound having a perfluoro group, which is a useful technology. Technology (for example, see Patent Literature 1, Patent Literature 2, and Patent Literature 3), technology using a phosphoric ester salt having a perfluoroalkyl group (eg, see Patent Literature 4 and Patent Literature 5), perfluoro Alkyl polyoxyalkylene co-modified organopolysiloxane (see, for example, Patent Document 6) or alkylsilane is carbon Has 6 to 30 alkyl group, treatment with a silane coupling agent number fluorocarbons perfluoroalkyl silane is from 1 to 30 (e.g., see Patent Document 7) or the like exists. However, there are cases where surface treatment with such a compound having a perfluoroalkyl group sometimes exhibits only the same long-lasting makeup as that of the non-treated one, and the development of a technology that can stably realize the goodness of long-lasting makeup. Was desired.

  Examples of the special functional powder include sericite titania (see, for example, Patent Document 8), silica / iron oxide-coated sericite titania (see, for example, Patent Document 9), and titanium dioxide-coated silica (for example, Patent Document). 10), fibers having a length of 10 to 1000 μm (for example, see Patent Document 11), tubular titanium dioxide (for example, see Patent Document 12), cleaved talc (for example, see Patent Document 13), cleaved seri Site (for example, see Patent Document 13), iris foil (for example, see Patent Document 14), hydroxyapatite-treated powder (for example, see Patent Document 15) or metal ion clathrate clay mineral (for example, Patent Document 16) These are already used as raw materials for cosmetics.

  On the other hand, 1) a surface-treated powder obtained by treating the surface with a perfluoroalkylsilane represented by the following general formula (1) and 2) a powder selected from the following A There are no known cosmetics containing two or more kinds, and it is not known that such cosmetics have excellent makeup.

JP 2005-289831 A JP 2003-40738 A JP-A-2005-213250 Japanese Patent Laid-Open No. 2004-189652 JP 2002-338429 A JP 2002-114663 A JP 2002-80748 A JP-A-6-157262 JP 2000-229808 A WO98 / 11865 JP 2002-47120 A JP 2004-35362 A JP-A-6-9337 Japanese Patent Laid-Open No. 10-17438 Japanese Patent Laid-Open No. 2002-20218 Japanese Patent Laid-Open No. 10-87420

一般式（Ｉ）
（但し、式中ｎは２〜７の整数を表し、ｍは１〜３の整数を表し、ａは１〜３の整数を表し、Ｒは炭素数１〜３のアルキル基を表す。）

Formula (I)
(In the formula, n represents an integer of 2 to 7, m represents an integer of 1 to 3, a represents an integer of 1 to 3, and R represents an alkyl group having 1 to 3 carbon atoms.)

  The present invention has been made under such circumstances. In powder-containing cosmetics, sericite titania, silica / iron oxide-coated sericite titania, titanium dioxide-coated silica, and fibers having a length of 10 to 1000 μm. It is an object of the present invention to provide means for preventing localization of special functional powders such as tubular titanium dioxide, cleaved talc, cleaved sericite, iris foil, hydroxyapatite-treated powder, and metal ion clathrate clay mineral over time. .

In view of such a situation, the present inventors have found that in powder-containing cosmetics, sericite titania, silica / iron oxide-coated sericite titania, titanium dioxide-coated silica, fibers having a length of 10 to 1000 μm, tubular Intensive research efforts to find a means to prevent the localization of special functional powders such as titanium dioxide, cleaved talc, cleaved sericite, iris foil, hydroxyapatite-treated powder, and metal ion clathrate clay mineral over time As a result, it was found that such localization can be prevented by coexisting with the surface-treated powder obtained by treating the surface with the perfluoroalkylsilane represented by the general formula (1), and the invention has been completed. I came to let you. That is, the present invention is as follows.
(1) 1) 1 type thru | or selected from the surface treatment powder formed by treating the surface with the perfluoroalkylsilane represented by the general formula (1), and 2) the powder shown in the following A Contains 2 or more types of cosmetics.
(A) Sericite titania, silica / iron oxide coated sericite titania, titanium dioxide coated silica, 10 to 1000 μm long fiber, tubular titanium dioxide, cleaved talc, cleaved sericite, iris foil, hydroxyapatite treated powder, metal Ion clathrate clay mineral (2) The perfluoroalkylsilane represented by the general formula (I) is triethoxy (-8,8,8,7,7,6,6,5,5,4,4,3). , 3-Tridecafluorooctyl) silane, diethoxybis (-8,8,8,7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) silane or ethoxytris The makeup according to (1), which is (-8,8,8,7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) silane. Fee.
(3) The cosmetic according to (1) or (2), wherein the powder to be treated is selected from sericite, mica and talc.
(4) The cosmetic according to any one of (1) to (3), further comprising a spherical powder not classified into the essential component group A.
(5) The spherical powder may have a hollow structure acrylic resin powder, polyethylene powder, anhydrous silicic acid, alumina, methylsiloxane network polymer, methylpolysiloxane resin, calcium silicate, magnesium silicate, calcium carbonate And cosmetics according to any one of (1) to (4), wherein the cosmetic is selected from magnesium carbonate.
(6) The cosmetic according to any one of (1) to (5), wherein the content of the spherical powder is 10 to 30% by mass with respect to the total amount of the cosmetic.
(7) Containing perfluoropolyether, high viscosity silicone oil, polyalkylene oxide-modified methyl polysiloxane, glycerin-modified methyl polysiloxane, dimer acid diester, malic acid diester, N-acyl glutamic acid diester as an oil agent. Cosmetics given in any 1 paragraph of (1)-(6) characterized by these.

  According to the present invention, in powder-containing cosmetics, sericite titania, silica / iron oxide-coated sericite titania, titanium dioxide-coated silica, fibers having a length of 10 to 1000 μm, tubular titanium dioxide, cleaved talc, cleaved seri It is possible to provide means for preventing localization of special function powders such as sites, iris foils, hydroxyapatite-treated powders, and metal ion clathrate clay minerals over time.

(1) Surface-treated powder that is an essential component of the cosmetic of the present invention The cosmetic of the present invention is obtained by subjecting powder to a surface treatment with perfluoroalkylsilane represented by the general formula (1) as an essential component. It is contained as an essential component. As the powder, a powder selected from sericite, mica and talc and treated with the general formula (1) is particularly preferable. This is because sericite, mica and talc all have a fat-soluble part and a water-soluble part, and have a plate-like structure, so that they are water-based components such as sweat and oily components such as sebum. This is because the probability of breaking the localization is particularly high. By subjecting such a powder to a surface treatment with the compound of the general formula (1), such cosmetic breakup can be remarkably reduced. In this way, when the powder is treated with the perfluoroalkylsilane represented by the general formula (1), it may be performed according to a normal silane coupling method. For example, the powder is diluted with a solvent or the like. It can be obtained by coating with perfluoroalkylsilane of the general formula (1) and baking at 100 to 300 ° C. while reducing the pressure as desired. Examples of the compound represented by the general formula (1) include triethoxy (-8,8,8,7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) silane, Diethoxybis (-8,8,8,7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) silane or ethoxytris (-8,8,8,7,7) , 6,6,5,5,4,4,3,3-tridecafluorooctyl) silane. There are already commercially available perfluoroalkylsilanes represented by the general formula (1), and such a commercially available product can be purchased and subjected to the treatment. As a commercially available product of perfluoroalkylsilane represented by the general formula (1), Dynasylan (trademark) F8261 (triethoxy (-8,8,8,7,7,6,6,5,5,4,4,4) 3,3-Tridecafluorooctyl) silane) can be preferably exemplified. The perfluoroalkylsilane represented by the general formula (1), which is such a silane coupling agent, can be used alone for surface treatment or in combination of two or more. The amount ratio of the preferable powder and perfluoroalkylsilane is 1:99 to 30:70, more preferably 2:98 to 10:90. After the perfluoroalkylsilane is uniformly coated with an appropriate solvent such as chloroform or methylene chloride in an amount of 1 to 100 times, silane coupling may be performed by heat treatment and dealcoholization reaction. Such a treated powder can be adjusted in this way, or a commercially available treated powder can be purchased and used. Examples of commercially available treated powder include FHS sericite (97 parts by mass of sericite sold by Daito Kasei Kogyo Co., Ltd., triethoxy (-8,8,8,7,7,6,6, 5,5,4,4,3,3-tridecafluorooctyl) silane powder treated with 3 parts by mass of silane), FHS mica (97 parts by mass of mica, triethoxy (-8,8,8, 7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) silane powder with 3 parts by mass of silane), FHS talc (97 parts by mass of talc, triethoxy) (-8,8,8,7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) powder treated with 3 parts by mass of silane) Can be illustrated. Such a powder can contain only one species or a combination of two or more species. The preferable content of the powder is preferably 5 to 50% by mass, more preferably 10 to 40% by mass, based on the total amount of the cosmetic. Such a treatment can prevent sericite, talc, and mica from breaking down especially due to sweat and sebum. Further, these powders having a large surface area in contact with the skin and having a high friction reducing effect by the perfluoroalkylsilane do not show a significant friction reducing effect, thereby preventing physical falling off. Thereby, the localization or dropping of the special function powder, which is another essential component, can be prevented. For this reason, it is possible to prevent makeup collapse, which is a significant change in the makeup effect.

(2) Special functional powder which is an essential component of the cosmetic of the present invention The cosmetic of the present invention is a surface-treated powder obtained by surface-treating the powder with the perfluoroalkylsilane represented by the general formula (1). In addition, it is characterized by containing one or more selected from the powder shown in A below.

(A) Sericite titania, silica / iron oxide coated sericite titania, titanium dioxide coated silica, 10 to 1000 μm long fiber, tubular titanium dioxide, cleaved talc, cleaved sericite, iris foil, hydroxyapatite treated powder, metal Ionic clathrate clay mineral

  Each of these powders has a characteristic and remarkable optical effect. Sericite titania exhibits an unobtrusive covering power of white, silica / iron oxide coated sericite titania embodies a natural skin texture finish, and titanium dioxide coated silica does not feel thick The fiber has the effect of reproducing the beautiful texture of the skin, the tubular titanium dioxide expresses the covering power with a feeling of bare skin, the iris foil reproduces the goodness of the blood color, hydroxyapatite-treated powder, metal ion Clathrate clay minerals absorb excess fatty acids in the skin and suppress the occurrence of eczema. The preferable content of these powders may be a content that can exhibit the above-mentioned special function, and specifically, 0.1 to 10% by mass of each of them based on the total amount of the cosmetic. Is more preferable, and 0.5 to 5% by mass is more preferable.

  Sericite titania is obtained by coating the surface of sericite with titanium dioxide, and the amount of the titanium dioxide is preferably 5 to 30% by mass with respect to sericite serving as a substrate. It can be obtained by dispersing the site in an aqueous solution of titania chloride, neutralizing it with a weak alkali, depositing titania hydroxide on sericite, firing it and oxidizing it to titanium dioxide. Such sericite titania already has a commercially available product, and such a commercial product can be purchased and used. Examples of such commercially available products include “Coverleaf” series sold by Catalytic Chemical Industry Co., Ltd. Such sericite titania can be contained in cosmetics as it is, or can be contained by treating the surface. The surface treatment is not particularly limited as long as it is usually used in cosmetic powders. For example, hydrogen methylpolysiloxane baking treatment (sometimes simply referred to as silicone treatment), methylpolysiloxane baking treatment Preferable examples include silyl coupling treatment, perfluoroalkyl phosphate diethanolamine salt coating treatment, lecithin coating treatment, N-acyl glutamate coating treatment, and metal soap coating treatment such as aluminum stearate. Of course, in the present invention, the surface treatment with the perfluoroalkylsilane represented by the general formula (1) is not excluded.

  Silica / iron oxide-coated sericite titania is dispersed in ferric chloride aqueous solution and neutralized by adding sodium silicate aqueous solution to form a mixed precipitate of silica and iron hydroxide. It can be manufactured by firing and oxidation. Silica is preferably 1 to 20% by mass with respect to the mass of sericite titania, and iron oxide is preferably 1 to 20% by mass with respect to the mass of sericite, and the mass ratio of silica and iron oxide is 1: 2 to 2: 1 are particularly preferred. Examples of such silica / iron oxide-coated sericite titania include “Derma Real Leaf” sold by Catalyst Kasei Kogyo Co., Ltd. Such powder can also be contained in cosmetics as it is, or can be contained by treating the surface. The surface treatment is not particularly limited as long as it is usually used in cosmetic powders. For example, hydrogen methylpolysiloxane baking treatment (sometimes simply referred to as silicone treatment), methylpolysiloxane baking treatment Preferable examples include silyl coupling treatment, perfluoroalkyl phosphate diethanolamine salt coating treatment, lecithin coating treatment, N-acyl glutamate coating treatment, and metal soap coating treatment such as aluminum stearate. Of course, in the present invention, the surface treatment with the perfluoroalkylsilane represented by the general formula (1) is not excluded.

  Titanium dioxide-coated silica can be produced by depositing titanium hydroxide on the surface of a silica or methylpolysiloxane network polymer and baking it. Such deposition is carried out by dispersing silica or methylpolysiloxane network polymer in an aqueous solution of a water-soluble titanium salt such as titanium chloride, and then adding an alkali and neutralizing to precipitate titanium hydroxide. The firing temperature at which the precipitate can be deposited on a silica or methylpolysiloxane network polymer is preferably 500 to 1000 ° C. Such powders have commercial products, and such commercial products can be purchased and used. Preferable examples of commercially available products include “multiple beads” manufactured by Catalyst Kasei Kogyo Co., Ltd.

  The fiber having a length of 10 to 1000 μm, more preferably 20 to 500 μm, is not particularly limited as long as the material is usually used in cosmetics. For example, synthesis of nylon, acrylic resin, polyester, etc. Examples thereof include natural fibers such as fibers, hemp, jute, and silk, semi-synthetic fibers such as rayon and acetylcellulose, and particularly preferable are synthetic fibers, and nylon fibers are particularly preferable. The cross-sectional shape of the fiber may be circular, or it may be a cross-shaped shape such as a cross-beam shape, a gourd shape, a cross shape, or a polygonal shape such as a hexagon or a triangle that may have a hollow structure. A preferred shape is a modified cross section, and a cross-beam shape is particularly preferred. The color may be generated, and red, blue, purple, yellow, green, and the like may be used. Such a fiber can be produced by cutting a commercially available fiber into an appropriate length.

  As the tubular titanium, a hollow cylindrical titanium dioxide can be preferably exemplified, and the tubular hollow titanium is produced by coating a combustible fiber with titanium hydroxide and firing the coating composition at 500 to 1000 ° C. I can do it. Such tubular titanium already exists on the market and can be purchased and used. As a preferable commercial item, for example, “hollow titanium oxide fiber” sold by Catalytic Chemical Industry Co., Ltd. can be preferably exemplified. Such tubular titanium can embody a cover force that is not stubborn. It can also show the skin texture beautifully.

  Cleaved sericite and cleaved talc are powders that have been refined while preserving flatness by applying stress in the direction of the crystals after swelling with sufficient water in the sericite and talc ore. The aspect ratio is higher than that of commercially available sericite or talc, and thus has the characteristic of exhibiting excellent gloss. Such cleaved sericite and cleaved mica are commercially available, and such commercial products can be purchased and used. Examples of the commercially available products are “Cleaved Sericite” and “Cleaved Talc” sold by Yodogawa Mining Co., Ltd., particularly preferably.

  Iris foil means a titanium mica with a covering ratio in which interference colors such as red, blue, green, and purple appear, and this appears differently depending on the width of the diffraction grating that titanium oxide forms on the mica. Such an iris foil already has a commercial product. Preferred examples of commercially available products include “Flamenco” series such as “Flamenco Red”, “Flamenco Green”, “Flamenco Blue”, “Flamenco Violet”, etc., manufactured by Engelhard Corporation.

  Hydroxyapatite-coated powder is a powder with hydroxyapatite coated on the surface, which is dispersed in an aqueous solution of soluble calcium salt, and then an aqueous solution of phosphoric acid is added to precipitate hydroxyapatite. A method of depositing it as a precipitate on the surface of the powder, or adding phosphoric acid to an aqueous solution of a soluble calcium salt to precipitate fine hydroxyapatite, adding powder to this, adding phosphoric acid, and then adding hydroxyapatite It can be manufactured by fixing microcrystals while precipitating. Such hydroxyapatite-coated powders are commercially available, and such commercially available products can be purchased and used. Preferable examples of commercially available products include “Powder Lavie” sold by Miyoshi Kasei Kogyo Co., Ltd. and “Hydoxyapatite-coated talc” manufactured by Sekisui Kasei Kogyo Co., Ltd. Such powders have the property of absorbing lipids, thereby preventing makeup collapse.

  The metal ion clathrate clay mineral is preferably exemplified by a clay mineral in which an amphoteric metal ion such as aluminum ion or zinc ion is included between layers of a clay mineral such as bentonite. It can be produced by immersing an aqueous solution of the water-soluble salt of the amphoteric metal in a mineral and then firing it. As such clathrate clay minerals, those already on the market exist, and such commercial products can be purchased and used. As such a commercially available product, for example, “oil sensor powder” sold by Daito Kasei Kogyo Co., Ltd. can be suitably exemplified.

(3) Cosmetics of this invention The cosmetics of this invention contain the said essential component, It is characterized by the above-mentioned. The cosmetic of the present invention can be applied without particular limitation as long as it is a type of cosmetic that can normally contain powder, such as under-makeup cosmetics, control colors, foundations, and pressed powders. Base makeup cosmetics such as loose powder, point makeup cosmetics such as lip color, concealer, highlight, cheek color, eyeliner, eye color, eyebrow, mascara, sun care compact, sun care block, sun care milk, etc. Protective cosmetics and the like can be suitably exemplified. The dosage form can be applied without particular limitation as long as it is a conventionally known dosage form such as solid powder cosmetics, oil gel cosmetics, emulsified cosmetics, and fluid medium-dispersed cosmetics.

  Moreover, in the cosmetics of this invention, the arbitrary component normally used by cosmetics other than the said essential component can be contained. Such optional components include, for example, cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyl decanol, Higher alcohols such as isostearyl alcohol, 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12- Hydroxy stearic acid, palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentae Acid, isohexadecanoic acid, antiisohenicosanoic acid, long chain branched fatty acid, dimer acid, hydrogenated dimer acid and other higher fatty acids and metals such as aluminum salts, calcium salts, magnesium salts, zinc salts and potassium salts Soaps and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum Carbides such as solid paraffin; candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fish Waxes such as Jatrobsch wax, polyethylene wax, ethylene propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil , Macadamia nut oil, hazelnut oil, cucumber nut oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil Vegetable oils such as rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil, etc. Animal fats and oils; animal waxes such as whale wax, lanolin, orange luffy oil; liquid lanolin, reduced Lanolins such as phosphorus, adsorption-purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phospholipids such as phosphatidic acid, lysolecithin; hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid Phospholipid derivatives such as partially hydrogenated egg yolk phospholipids; cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phyto Sterols such as terol and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl) N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), N- Acyl sarcosine alkyl esters such as lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut fatty acid cholesteryl, macadamia nut oil Sterol esters such as itosteryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipid / cholesterol complex, phospholipid / phytosterol complex, etc. Lipid complex: octyldodecyl myristate, hexyl decyl myristate, octyl dodecyl isostearate, cetyl paritate, octyl dodecyl palmitate, cetyl octanoate, hexyl decyl octanoate, isotridecyl isononanoate, isononyl isononanoate, isononanoate Isotridecyl acid, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, neodecanoic acid Cutyldecyl, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid hydrogenated castor oil, ethyl oleate, ethyl avocado oil, isopropyl myristate , Isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate, etc. Monoalcohol carboxylic acid esters; cetyl lactate, diisostearyl malate, monoisoste Oxyacid esters such as hydrogenated castor oil; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, tri (caprylic / capric) glyceryl, tri (caprylic / capric / myristin) Acid / stearic acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl glycol dioctanoate , Neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentae tetraoctanoate Srityl, hydrogenated rosin pentaerythrityl, triethylhexanoic acid ditrimethylolpropane, (isostearic acid / sebacic acid) ditrimethylolpropane, triethylhexanoic acid pentaerythrityl, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diisostearic acid di Glyceryl, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (ethylene glycol distearate) Polyhydric alcohol fatty acid esters such as dimer diisopropyl dilinoleate, dimer diisolate dilinoleate Allyl, dimer dilinoleic acid di (isostearyl / phytosteryl), dimer dilinoleic acid (phytosteryl / behenyl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid dimer dilinoleyl, diisostearic acid dimer dilinoleyl, dimer Dilinoleyl hydrogenated rosin condensate, dimer dilinoleic acid hydrogenated castor oil, hydroxyalkyl dimer dimer acid or dimer diol derivative such as dilinoleyl ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA) ), Lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid Fatty acid alkanolamides such as acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), palm oil fatty acid methylethanolamide (cocamidomethyl MEA); Siloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, stearoxypropyldimethylamine, (aminoethylaminopropylmethicone) / Dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, aminopropi Amino-modified silicone such as rubimethicone and amodimethicone, polyether-modified silicone such as cation-modified silicone and dimethicone copolyol, polyglycerin-modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphoric acid-modified silicone, sulfuric acid-modified silicone, alkyl-modified Silicone, fatty acid modified silicone, alkyl ether modified silicone, amino acid modified silicone, peptide modified silicone, fluorine modified silicone, cation modified and polyether modified silicone, amino modified and polyether modified silicone, alkyl modified and polyether modified silicone, polysiloxane Silicones such as oxyalkylene copolymers; fluorinated oils such as perfluorodecane, perfluorooctane, and perfluoropolyether Kind it may be mentioned as preferred.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. Sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid , Glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin and modified cyclodextrins such as maltosylation, hydroxyalkylation, etc.), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabino Sugars and derivatives thereof such as galactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer; hyaluronic acid, hyal Sodium ronate; sodium chondroitin sulfate; mucoitin sulfate, caroline sulfate, keratosulfate, dermatan sulfate; white jellyfish extract, white jellyfish polysaccharide; fucoidan; tuberose polysaccharide, naturally-occurring polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and the like Urea; 2-pyrrolidone-5-carboxylic acid and its sodium salt; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine , Glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and other amino acids and salts thereof; collagen, fish Collagen, atelocollagen, gelatin, elastin, collagen degrading peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, keratin degrading peptide, hydrolyzing keratin, conchiolin degrading peptide, hydrolyzing conchiolin, silk proteolytic peptide, hydrolyzing Degraded silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, wheat proteolytic peptide, hydrolyzed wheat protein, casein degrading peptide, acylated peptide, and other peptide peptides; palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetra Acylated peptides such as peptides; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hipotauri , Sesame lignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, liquorice extract, comfrey extract, silk extract, Animal and plant extract ingredients such as Izayoi rose extract, Achillea millefolium extract, Eucalyptus extract, Merirot extract, natural ceramide (type 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide and Ceramides such as sugar-ceramide-containing extracts are preferred.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB.
Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium phosphate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine; polyoxyethylene alkyl ethers such as sodium laureth acetate Acetic acid salt; Succinic acid ester salt such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylate; Acyl lactate; Polyoxyethylene fatty amine sulfate; Fatty acid alkanolamide sulfate; Hardened coconut oil fatty acid sodium glyceryl sulfate Fatty acid glyceride sulfate such as alkylbenzene polyoxyethylene sulfate; α-olefin Olefin sulfonates such as sodium sulfonate; alkylsulfosuccinates such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, lauryl polypropylene glycol sulfosuccinic acid Alkyl ether sulfosuccinates such as sodium; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and tetraethanolamine tetraethanol; alkylnaphthalenesulfonates; alkanesulfonates; α-sulfo fatty acid methyl ester salts; Acyl isethionate; alkyl glycidyl ether sulfonate; alkyl sulfoacetate; laurethrin Alkyl ether phosphates such as sodium, sodium dilaureth phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphate; fatty acid amide ether phosphorus Acid salts; phospholipids such as phosphatidylglycerol, phosphatidylinositol, and phosphatidic acid; silicone-based anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone, and sulfate-modified silicone;
Nonionic surfactants include laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), behenes (polyoxyethylene behenyl ether), isosteares (poly Polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers such as oxyethylene isostearyl ether), octyldecesses (polyoxyethylene octyldodecyl ether); polyoxyethylene alkylphenyl ether; polyoxyethylene hydrogenated castor oil, poly Oxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil mono Polyglutamic acid monoisostearic acid diester, castor oil and hardened castor oil derivatives such as polyoxyethylene hydrogenated castor oil maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene lanolin; Lanolin; polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene・ Polyoxyethylene such as polyoxypropylene glycerin ether ・ Polyoxypropylene alkyl ether; Polyoxyethylene Polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl coconut oil fatty acid, mono cottonseed oil fatty acid Glycerin fatty acid partial esters such as glycerin, glyceryl monoerucate, glyceryl sesquioleate, glycerin α, α'-oleic acid pyroglutamate, glyceryl monostearate, malic acid monostearate; polyglyceryl-2 stearate, 3, 4, 4 , 6, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate, polyglyceryl decastearate-10, polyglyceryl isostearate -2, 3, 4, 5, 6, 8, 10, diglycostyl diisostearate (diglyceryl diisostearate), 3, 10, polyglyceryl triisostearate, polyglyceryl tetraisostearate -2, deglycisostearate polyglyceryl-10, oleic acid polyglyceryl-2, the same 3, the same 4, the same 6, the same 8, the same 10, the dioleic acid polyglyceryl-6, the trioleic acid polyglyceryl-2, the dekaoleic acid polyglyceryl Polyglycerol fatty acid ester such as -10; ethylene glycol mono fatty acid ester such as ethylene glycol monostearate; propylene glycol mono fatty acid ester such as propylene glycol monostearate; pentaerythritol partial fatty acid ester; sorbitol Maltitol partial fatty acid ester; maltitol partial fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, penta Sorbitan fatty acid esters such as 2-ethylhexyl diglycerol sorbitan and tetra-2-ethylhexyl diglycerol sorbitan; Sucrose fatty acid esters, methyl glucoside fatty acid esters, sugar derivatives partial esters such as undecylenic acid trehalose; alkyls such as caprylyl glucoside Alkyl polyglycoside; Lanolin alcohol; Reduced lanolin; Polyoxyethylene distearate, Polyethylene glycol di Polyoxyethylene fatty acid mono- and diesters such as isostearate, polyoxyethylene monooleate, polyoxyethylene dioleate; polyoxyethylene propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoiso Polyoxyethylene glycerin fatty acid esters such as stearate, polyoxyethylene glycerin triisostearate, etc .; polyoxyethylene glycerin fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate , Polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol Polyoxyethylene sorbitol fatty acid esters such as monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid ester; polyoxyethylene alkyl ether fatty acid Esters; Polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol beeswax; Alkyl glyceryl ethers such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol, and batyl alcohol; Polyhydric alcohol alkyl ether; Polyoxyethylene alkylamine; Tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; saponin, sophoro Natural surfactants such as Pid; polyoxyethylene fatty acid amide; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (Lauramide DEA), fatty acid alkanolamides such as lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) Alkyl dimethyl amine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, and behenamine oxide; alkyl ethoxy dimethyl amine oxide Xoxide; polyoxyethylene alkyl mercaptan; polyether-modified silicone such as dimethicone copolyol, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone, sugar-modified silicone and other nonionic surfactants;
Cationic surfactants include alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; distearyldimonium chloride, Dialkyldimethylammonium chloride such as dicocodimonium chloride; fatty acid amidoamines such as stearamidepropyldimethylamine and stearamideethyldiethylamine and salts thereof; alkyl ether amines such as stearoxypropyldimethylamine and salts or quaternary salts thereof; Chain-branched fatty acid (12-31) aminopropylethyldimethylammonium, ethyl sulfate lanolin fatty acid aminopropylethyldi Fatty acid amide type quaternary ammonium salts such as tilammonium; polyoxyethylene alkylamine and its salts or quaternary salts; alkylamine salts; fatty acid amidoguanidinium salts; alkyl etheraminemonium salts; Benzethonium salts; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; alkylisoquinolinium salts; dialkyl morpholinium salts; polyamine fatty acid derivatives; amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cations Silicone-based cationic surfactants such as modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone;
In amphoteric surfactants, N-alkyl-N, N-dimethylamino acid betaines such as laurylbetaine (lauryldimethylaminoacetic acid betaine); fatty acid amidoalkyl-N, N-dimethylamino acids such as cocamidopropylbetaine and lauramidopropylbetaine Betaines; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; phosphate-type betaines such as alkyldimethylaminoethanol phosphate; Sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated Soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipids, phospholipids such as hydroxylated lecithin; silicone amphoteric surfactants;
Among the polymeric surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, acrylic acid / alkyl methacrylate copolymer; various silicone surfactants are preferable.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, Chitin, chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypro Cellulose, carboxymethylcellulose and its sodium salts, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch , Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinic acid corn starch aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA) , Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ester Ter; polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymers; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; poly Acrylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationic cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquatani -47 and other acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer, chloromethacrylic acid choline ester polymer; cationized polysaccharide such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride ; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacryl alkyl ester emulsion , Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride , Fumed silica (ultrafine silica), magnesium magnesium silicate, sodium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester Is preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Preservatives and antibacterial agents include hydroxybenzoic acid such as methylparaben, ethylparaben, propylparaben, and butylparaben and salts or esters thereof; salicylic acid; sodium benzoate; phenoxyethanol; 1,2-pentanediol, 1,2-hexane 1,2-diols such as diols; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides , Quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, Kichioru; phenol, isopropyl phenol, cresol, thymol, p-chlorophenol, phenylphenol, other phenols such as phenylphenol sodium; phenylethyl alcohol, photosensitive Motorui, be mentioned as antibacterial zeolite, silver ion. Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  As powders, in addition to the powders described above, mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, phlogopite, biotite, permiculite, magnesium carbonate, calcium carbonate , Aluminum silicate, Barium silicate, Calcium silicate, Magnesium silicate, Strontium silicate, Metal tungstate, Magnesium, Zeolite, Barium sulfate, Calcinated calcium sulfate, Calcium phosphate, Fluorine apatite, Hydroxyapatite, Ceramic powder, Bentonite, Smectite, clay, mud, metal soap (for example, zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide Fine and ultrafine titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, Fine particle composite powder, inorganic powder of various sizes and shapes such as gold and aluminum, and various surface treatments such as silicone such as hydrogen silicone and cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powder such as powder hydrophobized or hydrophilized by treatment with an agent; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, Polyester powder, benzoguanamine resin powder, polyethylene terephthalate Organic powders and surface-treated powders of various sizes and shapes such as polyurethane powder, polymethylmethacrylate laminated powder, polyethylene terephthalate / aluminum / epoxy laminated powder, urethane powder, silicone powder, Teflon (registered trademark) powder, Organic-inorganic composite powder is preferred. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid-based purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxy Cinnamic acid-based ultraviolet absorbers such as namate, ferulic acid and derivatives thereof; 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone -5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc. Benzophenone purple External line absorber; 3- (4′-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2′-hydroxy-5- 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole; 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5- (3 , 3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- 3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, etc., hydantoin derivatives, phenylbenzimidazolazolesulfonic acid, terephthalylidene dicamphor Preferred are sulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and derivatives thereof, oryzanol and derivatives thereof.

Examples of whitening agents include hydroquinone glycosides such as arbutin and α-arbutin and esters thereof; ascorbic acid phosphate salts such as ascorbic acid, sodium ascorbate phosphate and magnesium ascorbate phosphate, ascorbic acid Ascorbic acid fatty acid esters such as tetraisopalmitic acid ester, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and fatty acid esters thereof, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylreso Shinoru, oil-soluble Kamomiraekisu, oil-soluble licorice extract, Nishikawa willow extract, be mentioned as saxifrage extract, and the like plant extracts are preferred.

Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene, astaxanthin Antioxidants and active oxygen scavengers such as catechins; flavones such as quercetin; Flavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; Licorice extract-related substances such as glabrizine, glabrene, liquiritin, isoliquiritin; lactoferrin; gingerol; fragrance substances such as menthol, camphor, cedrol and derivatives thereof; capsaicin, vanillin, and derivatives; A complex of a physiologically active substance and cyclodextrins is preferable.

Plant / animal / microbe extracts include iris extract, ashitaba extract, asunaro extract, asparagus extract, avocado extract, achacha extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylus resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damassenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute, Vanillin Basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, perubalsum, vetiver oil, vetiverol, peppermint oil, pepper oil, Heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonone, lime oil, lavender oil, D-limonene Synthetic and natural fragrances such as linalool, rillar, rigliall, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances are preferred. It is cited as the.

As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 No. 1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202- No. 1, yellow 202-2, yellow 203, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, yellow 406 Legal dyes such as Yellow No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Base dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4- Nitro dyes such as hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, and Basic Blue 26; disperse dyes; inorganic white such as titanium dioxide and zinc oxide Pigments: Inorganic red pigments such as iron oxide (Bengara) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and loess; Black iron oxide, low-order titanium oxide, etc. Inorganic pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica; Titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, pearl pigments such as fish scale foil; gold such as aluminum powder, copper powder, gold Surface treated inorganic and metal powder pigments: Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204 No., Yellow 205, Yellow 401, Blue 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Organic pigments such as zirconium, barium or aluminum lake such as yellow 5, yellow 202, yellow 203, green 3 and blue 1; surface treatment organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene , Catenal, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochinie Natural pigments and dyes such as naphthoquinones such as shikonin, bixin, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, Or intermediates and couplers of oxidation dyes such as p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and their salts; autooxidation of indoline, etc. Type dyes; dihydroxyacetone is preferred.

Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and / or A61K8. ) And the like, known cosmetic ingredients, pharmaceutical ingredients, food ingredients, and the like can be contained in known combinations, blending ratios and blending amounts.

  The cosmetic of the present invention can be produced by treating these essential components and optional components according to a conventional method.

  Hereinafter, the present invention will be described in more detail with reference to examples, but it is needless to say that the present invention is not limited to such examples.

  A foundation (solid powder cosmetic) as a cosmetic of the present invention was produced according to the formulation shown below. In other words, the component a was mixed with a Henschel mixer, pulverized with a palverizer equipped with a 1 mm round hole screen, sprayed and coated with the component B while mixed with a Henschel mixer, and then pulverized with a 1 mm herringbone screen. The foundation 1 was obtained by pulverization, filling in a metal pan, and pressure molding. Similarly, Comparative Example 1 in which FHS sericite is replaced with normal sericite and FHS talc is replaced with normal talc, FHS sericite is converted into normal silicone-treated sericite, and FHS talc is processed into normal silicone. Comparative Example 2 in which talc was substituted, Comparative Example 3 in which FHS sericite was replaced with ordinary perfluoroalkyl phosphate diethanolamine salt-coated sericite, and FHS talc was replaced with ordinary perfluoroalkyl phosphate diethanolamine salt-covered talc. Comparative Example 4 in which “Derma Real Leaf” was replaced with sericite was also prepared in the same manner.

<Test Example 1>
Using three professional panelists, Foundation 1 and Comparative Examples 1 to 4 were subjected to comparative evaluation under actual use conditions for “naturalness of makeup finish”, “covering power”, and “makeup lasting”. The test period was set for one month, and each cosmetic was actually used at least three times during the test period. If necessary, the cosmetics were used again and evaluated according to the standard scores shown below. The results are shown in Table 2 as the number of examples. All panelists recognized that the cosmetics of the present invention containing the surface-treated powder of the present invention have an excellent make-up effect. This is considered to be because the powder has a special optical effect, which is an essential component, and has a large optical effect, and the change becomes more actual due to the localization (disintegration) of the powder.
(Score criteria)
Score 1: Unsatisfactory score 2: Slightly unsatisfactory score 3: Slightly unacceptable Score 4: Slightly excellent score 5: Excellent

<Test Example 2>
Since it was found from Test Example 1 that the effect of the present invention appears more clearly in “makeup holding”, it was examined whether or not makeup holding could not be measured as device measurement data. The color difference meter made by Konica Minolta Co., Ltd. was used to measure the color (color difference with respect to a standard white plate) immediately after application and when spent for 4 hours in a normal lifestyle, and the color change over time (color difference ( ΔE) was calculated. The results are shown in Table 3. From this, it was found that the cosmetic of the present invention has a small ΔE, and the value of ΔE is highly consistent with the evaluation of cosmetics, and can be used as a substitute value for cosmetics.

  In the same manner as in Example 1, the types of high-functional powders were changed and foundations 2 to 2 were produced and evaluated in the same manner as in Test Example 2. The results are shown in Table 5. As a result, each foundation had a good makeup-holding effect, and the effect of the present invention was confirmed.

  A water-in-oil emulsifier type UV protective agent 1 was prepared according to the formulation shown below. That is, among the components of A, “Benton 38V” and polyhydric alcohol are kneaded to form a gel, the remaining component of A is included in the gel, and the temperature is adjusted to 80 ° C. Ingredients were dispersed with a disper, and the temperature adjusted to 80 ° C. in advance was gradually added and emulsified with stirring. The mixture was cooled with stirring to obtain a water-in-oil type UV protective agent 1. As for this thing, (DELTA) E was 0.59 by evaluation of Test Example 2, and the effect was able to be confirmed similarly.

  The present invention can be applied to powder-containing cosmetics such as makeup cosmetics.

Claims (7)

1) a surface-treated powder obtained by treating the surface with a perfluoroalkylsilane represented by the following general formula (1), and 2) a powder selected from the following A: Cosmetics containing 2 or more types.

Formula (I)
(In the formula, n represents an integer of 2 to 7, m represents an integer of 1 to 3, a represents an integer of 1 to 3, and R represents an alkyl group having 1 to 3 carbon atoms.)
(A) Sericite titania, silica / iron oxide coated sericite titania, titanium dioxide coated silica, 10 to 1000 μm long fiber, tubular titanium dioxide, cleaved talc, cleaved sericite, iris foil, hydroxyapatite treated powder, metal Ionic clathrate clay mineral The perfluoroalkylsilane represented by the general formula (I) is triethoxy (-8,8,8,7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl). ) Silane, diethoxybis (-8,8,8,7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) silane or ethoxytris (-8,8,8, The cosmetic according to claim 1, wherein the cosmetic is 7,7,6,6,5,5,4,4,3,3-tridecafluorooctyl) silane. The cosmetic according to claim 1 or 2, wherein the powder to be treated is selected from sericite, mica and talc. The cosmetic according to any one of claims 1 to 3, further comprising a spherical powder not classified into the essential component group A. The spherical powder may have a hollow structure, such as acrylic resin powder, polyethylene powder, anhydrous silicic acid, alumina, methylsiloxane network polymer, methylpolysiloxane resin, calcium silicate, magnesium silicate, calcium carbonate and magnesium carbonate. The cosmetic according to any one of claims 1 to 4, wherein the cosmetic is selected from the following. The cosmetic according to any one of claims 1 to 5, wherein the content of the spherical powder is 10 to 30% by mass with respect to the total amount of the cosmetic. It contains perfluoropolyether, high viscosity silicone oil, polyalkylene oxide-modified methyl polysiloxane, glycerin-modified methyl polysiloxane, dimer acid diester, malic acid diester, N-acyl glutamic acid diester as an oil agent. The cosmetic according to any one of claims 1 to 6.