JP2008030036A - 少なくとも１種の担体と、少なくとも１種の第ｖｉｉｉ族元素と、少なくとも１種の第ｖｉｂ族元素とを含む触媒の存在下に硫黄およびオレフィンを含有するガソリン留分を水素化脱硫する方法 - Google Patents
少なくとも１種の担体と、少なくとも１種の第ｖｉｉｉ族元素と、少なくとも１種の第ｖｉｂ族元素とを含む触媒の存在下に硫黄およびオレフィンを含有するガソリン留分を水素化脱硫する方法 Download PDFInfo
- Publication number
- JP2008030036A JP2008030036A JP2007196982A JP2007196982A JP2008030036A JP 2008030036 A JP2008030036 A JP 2008030036A JP 2007196982 A JP2007196982 A JP 2007196982A JP 2007196982 A JP2007196982 A JP 2007196982A JP 2008030036 A JP2008030036 A JP 2008030036A
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- Prior art keywords
- catalyst
- support
- group vib
- group
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 title claims abstract description 84
- 238000000034 method Methods 0.000 title claims abstract description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 26
- 239000011593 sulfur Substances 0.000 title claims abstract description 26
- 229910021472 group 8 element Inorganic materials 0.000 title claims abstract description 25
- 230000008569 process Effects 0.000 title claims abstract description 17
- 150000001336 alkenes Chemical class 0.000 title abstract description 19
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 27
- 239000011574 phosphorus Substances 0.000 claims abstract description 27
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- 229910052750 molybdenum Inorganic materials 0.000 claims description 18
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 17
- 239000011733 molybdenum Substances 0.000 claims description 17
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 230000007704 transition Effects 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 238000004523 catalytic cracking Methods 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000004939 coking Methods 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 238000004230 steam cracking Methods 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 4
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical group [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract description 8
- 230000009467 reduction Effects 0.000 abstract description 4
- 125000003396 thiol group Chemical class [H]S* 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 20
- 238000004231 fluid catalytic cracking Methods 0.000 description 17
- 230000000694 effects Effects 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 150000003573 thiols Chemical class 0.000 description 5
- 239000002243 precursor Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- WGLLSSPDPJPLOR-UHFFFAOYSA-N 2,3-dimethylbut-2-ene Chemical compound CC(C)=C(C)C WGLLSSPDPJPLOR-UHFFFAOYSA-N 0.000 description 2
- QENGPZGAWFQWCZ-UHFFFAOYSA-N 3-Methylthiophene Chemical compound CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 230000008034 disappearance Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- -1 olefin compounds Chemical class 0.000 description 2
- 125000001741 organic sulfur group Chemical group 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical class C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
- 102100023055 Neurofilament medium polypeptide Human genes 0.000 description 1
- 101710109612 Neurofilament medium polypeptide Proteins 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- VLXBWPOEOIIREY-UHFFFAOYSA-N dimethyl diselenide Natural products C[Se][Se]C VLXBWPOEOIIREY-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/301—Boiling range
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0607057A FR2904242B1 (fr) | 2006-07-28 | 2006-07-28 | Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des elements des groupes viii et vib |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012098668A Division JP5529917B2 (ja) | 2006-07-28 | 2012-04-24 | 少なくとも１種の担体と、少なくとも１種の第ｖｉｉｉ族元素と、少なくとも１種の第ｖｉｂ族元素とを含む触媒の存在下に硫黄およびオレフィンを含有するガソリン留分を水素化脱硫する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008030036A true JP2008030036A (ja) | 2008-02-14 |
| JP2008030036A5 JP2008030036A5 (https=) | 2010-09-16 |
Family
ID=37736494
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007196982A Pending JP2008030036A (ja) | 2006-07-28 | 2007-07-30 | 少なくとも１種の担体と、少なくとも１種の第ｖｉｉｉ族元素と、少なくとも１種の第ｖｉｂ族元素とを含む触媒の存在下に硫黄およびオレフィンを含有するガソリン留分を水素化脱硫する方法 |
| JP2012098668A Active JP5529917B2 (ja) | 2006-07-28 | 2012-04-24 | 少なくとも１種の担体と、少なくとも１種の第ｖｉｉｉ族元素と、少なくとも１種の第ｖｉｂ族元素とを含む触媒の存在下に硫黄およびオレフィンを含有するガソリン留分を水素化脱硫する方法 |
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| JP2012098668A Active JP5529917B2 (ja) | 2006-07-28 | 2012-04-24 | 少なくとも１種の担体と、少なくとも１種の第ｖｉｉｉ族元素と、少なくとも１種の第ｖｉｂ族元素とを含む触媒の存在下に硫黄およびオレフィンを含有するガソリン留分を水素化脱硫する方法 |
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| US (1) | US7981828B2 (https=) |
| EP (1) | EP1892039B1 (https=) |
| JP (2) | JP2008030036A (https=) |
| CN (2) | CN104959157A (https=) |
| BR (1) | BRPI0703114B1 (https=) |
| DK (1) | DK1892039T3 (https=) |
| FR (1) | FR2904242B1 (https=) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101788700B1 (ko) | 2009-12-16 | 2017-10-20 | 토탈 라피나쥬 프랑스 | Ⅷ 및 ⅵｂ 족 금속을 포함하는, 수소화처리에서 사용될 수 있는 촉매 및 아세트산과 디알킬 숙시네이트 ｃ1-ｃ4 를 이용하는 제조방법 |
| FR2953739B1 (fr) * | 2009-12-16 | 2012-01-13 | Inst Francais Du Petrole | Catalyseur utilisable en hydrotraitement comprenant du cobalt et du molybdene, son procede de preparation avec de l'acide acetique et du succinate de dialkyle c1-c4 |
| FR2953740B1 (fr) * | 2009-12-16 | 2012-01-13 | Inst Francais Du Petrole | Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib sauf le couple cobalt-molybdene, et preparation avec de l'acide acetique et du succinate de dialkyle c1-c4 |
| FR2984762B1 (fr) | 2011-12-21 | 2014-04-25 | IFP Energies Nouvelles | Adsorbant catalytique pour la captation de l'arsenic et l'hydrodesulfuration selective des essences de craquage catalytique |
| FR2998488B1 (fr) * | 2012-11-29 | 2015-02-06 | Ifp Energies Now | Catalyseur d hydrotraitement a partir d alumine gel et methode de preparation d un tel catalyseur |
| FR3004969B1 (fr) * | 2013-04-26 | 2016-01-29 | IFP Energies Nouvelles | Adsorbant catalytique pour la captation de l'arsenic et l'hydrodesulfuration selective des essences. |
| FR3023184B1 (fr) * | 2014-07-04 | 2019-12-27 | IFP Energies Nouvelles | Catalyseur d'hydrotraitement a densite de molybdene elevee et methode de preparation. |
| CN105562019B (zh) * | 2014-10-14 | 2018-09-14 | 中国石油化工股份有限公司 | 硫醇硫醚化的催化剂 |
| FR3035117B1 (fr) | 2015-04-15 | 2019-04-19 | IFP Energies Nouvelles | Procede d'adoucissement en composes du type sulfure d'une essence olefinique |
| KR20180013844A (ko) * | 2015-05-29 | 2018-02-07 | 제이엑스티지 에네루기 가부시키가이샤 | 수소화 처리유의 제조 방법 및 접촉 분해유의 제조 방법 |
| FR3049955B1 (fr) | 2016-04-08 | 2018-04-06 | IFP Energies Nouvelles | Procede de traitement d'une essence |
| US10537883B2 (en) | 2016-10-07 | 2020-01-21 | King Fahd University Of Petroleum And Minerals | Method for producing a hydrodesulfurization catalyst |
| FR3057578B1 (fr) | 2016-10-19 | 2018-11-16 | IFP Energies Nouvelles | Procede d'hydrodesulfuration d'une essence olefinique. |
| FR3089825B1 (fr) | 2018-12-18 | 2021-05-07 | Ifp Energies Now | Procédé de réjuvénation d’un catalyseur usé non régénéré d’un procédé d'hydrodésulfuration d'essences. |
| FR3090006B1 (fr) | 2018-12-18 | 2021-07-30 | Ifp Energies Now | Procédé d’hydrodésulfuration de coupes essence oléfinique contenant du soufre mettant en œuvre un catalyseur réjuvéné à un composé organique. |
| FR3090005B1 (fr) | 2018-12-18 | 2021-07-30 | Ifp Energies Now | Procédé d’hydrodésulfuration de coupes essence oléfinique contenant du soufre mettant en œuvre un catalyseur régénéré. |
| FR3089824B1 (fr) | 2018-12-18 | 2021-05-07 | Ifp Energies Now | Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences. |
| FR3116825A1 (fr) | 2020-11-27 | 2022-06-03 | IFP Energies Nouvelles | Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur ayant une porosité bimodale particulière |
| FR3116740A1 (fr) | 2020-11-27 | 2022-06-03 | IFP Energies Nouvelles | Procédé de préparation d’un catalyseur d’hydrodésulfuration d’une coupe essence comprenant un métal du groupe VIB, un métal du groupe VIII et du carbone graphitique |
| FR3116826B1 (fr) | 2020-11-27 | 2023-11-03 | Ifp Energies Now | Procede d’hydrodesulfuration mettant en œuvre un catalyseur comprenant un support d’alumine flash |
| FR3116829B1 (fr) | 2020-11-27 | 2023-11-03 | Ifp Energies Now | Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux |
| FR3116830B1 (fr) | 2020-11-27 | 2023-11-03 | Ifp Energies Now | Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur contenant un matériau graphitique caractérisé par son rapport H/C |
| FR3116828A1 (fr) * | 2020-11-27 | 2022-06-03 | IFP Energies Nouvelles | Procédé de captation d'impuretés organométalliques mettant en œuvre une masse de captation à base de cobalt et de molybdène et contenant du carbone |
| FR3116831B1 (fr) * | 2020-11-27 | 2023-11-03 | Ifp Energies Now | Procede d’hydrogenation selective d’une essence en presence d’un catalyseur sur support meso-macroporeux |
| FR3116827A1 (fr) | 2020-11-27 | 2022-06-03 | IFP Energies Nouvelles | Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur contenant un matériau graphitique caractérisé par spectroscopie RMN13C MAS |
| FR3125437A1 (fr) * | 2021-07-22 | 2023-01-27 | IFP Energies Nouvelles | Catalyseur d’hydrodésulfuration avec répartition en croûte de la phase active |
| FR3142362A1 (fr) * | 2022-11-30 | 2024-05-31 | IFP Energies Nouvelles | Catalyseur d’hydrodésulfuration de finition comprenant un métal du groupe VIB, un métal du groupe VIII et du phosphore sur support alumine alpha |
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- 2007-07-17 DK DK07290894.0T patent/DK1892039T3/da active
- 2007-07-17 EP EP07290894.0A patent/EP1892039B1/fr active Active
- 2007-07-26 BR BRPI0703114A patent/BRPI0703114B1/pt active IP Right Grant
- 2007-07-27 US US11/878,929 patent/US7981828B2/en active Active
- 2007-07-30 JP JP2007196982A patent/JP2008030036A/ja active Pending
- 2007-07-30 CN CN201510046903.8A patent/CN104959157A/zh active Pending
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| JPH08224484A (ja) * | 1994-11-03 | 1996-09-03 | Shell Internatl Res Maatschappij Bv | 触媒及び水素処理方法 |
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Also Published As
| Publication number | Publication date |
|---|---|
| US7981828B2 (en) | 2011-07-19 |
| US20080053872A1 (en) | 2008-03-06 |
| JP2012176403A (ja) | 2012-09-13 |
| BRPI0703114A (pt) | 2008-03-25 |
| CN104959157A (zh) | 2015-10-07 |
| BRPI0703114B1 (pt) | 2017-05-02 |
| FR2904242A1 (fr) | 2008-02-01 |
| DK1892039T3 (da) | 2019-06-24 |
| EP1892039B1 (fr) | 2019-03-27 |
| EP1892039A1 (fr) | 2008-02-27 |
| CN101134909A (zh) | 2008-03-05 |
| FR2904242B1 (fr) | 2012-09-28 |
| JP5529917B2 (ja) | 2014-06-25 |
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