BRPI0703114A - processo para hidrodessulfurizar cortes de gasolina contendo enxofre e olefinas na presença de um catalisador compreendendo pelo menos um suporte, um elemento do grupo viii e um do grupo vib - Google Patents

processo para hidrodessulfurizar cortes de gasolina contendo enxofre e olefinas na presença de um catalisador compreendendo pelo menos um suporte, um elemento do grupo viii e um do grupo vib

Info

Publication number
BRPI0703114A
BRPI0703114A BRPI0703114-9A BRPI0703114A BRPI0703114A BR PI0703114 A BRPI0703114 A BR PI0703114A BR PI0703114 A BRPI0703114 A BR PI0703114A BR PI0703114 A BRPI0703114 A BR PI0703114A
Authority
BR
Brazil
Prior art keywords
group vib
support
catalyst
group
sulfur
Prior art date
Application number
BRPI0703114-9A
Other languages
English (en)
Inventor
Elodie Devers
Christophe Bouchy
Nathalie Marchal-George
Florent Picard
Original Assignee
Inst Francais Du Petrole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Publication of BRPI0703114A publication Critical patent/BRPI0703114A/pt
Publication of BRPI0703114B1 publication Critical patent/BRPI0703114B1/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

PROCESSO PARA HIDRODESSULFURIZAR CORTES DE GASOLINA CONTENDO ENXOFRE E OLEFINAS NA PRESENçA DE UM CATALISADOR COMPREENDENDO PELO MENOS UM SUPORTE, UM ELEMENTO DO GRUPO VIII E UM DO GRUPO VIB. A presente invenção refere-se a um catalisador compreendendo pelo menos um suporte, pelo menos um elemento do grupo VIII, pelo menos um elemento do grupo VIB e fósforo, em que a densidade dos elementos do grupo VIB por área de superfície de unidade do suporte é na faixa de (limites inclusos) 2 x 10¬-4¬ a 18 x 10~-4~ de óxidos dos elementos do grupo VIB por m¬2¬ de suporte em que a razão molar de fósforo para o elemento do grupo VIB é na faixa de 0,27 a 2,00, e em que a quantidade dos elementos do grupo VIB é na faixa de (limites inclusos) 1 % a 20 % em peso de óxidos dos elementos do grupo VIB e em que o suporte tem uma área de superfície específica de menos de 135 m¬2¬/g. A invenção refere-se também a processo para hidrodessulfurizar cortes de gasolina contendo enxofre e olefinas na presença deste catalisador.
BRPI0703114A 2006-07-28 2007-07-26 processo para hidrodessulfurizar cortes de gasolina contendo enxofre e olefinas na presença de um catalisador compreendendo pelo menos um suporte, um elemento do grupo viii e um do grupo vib e catalisador calcinado BRPI0703114B1 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0607057A FR2904242B1 (fr) 2006-07-28 2006-07-28 Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des elements des groupes viii et vib

Publications (2)

Publication Number Publication Date
BRPI0703114A true BRPI0703114A (pt) 2008-03-25
BRPI0703114B1 BRPI0703114B1 (pt) 2017-05-02

Family

ID=37736494

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0703114A BRPI0703114B1 (pt) 2006-07-28 2007-07-26 processo para hidrodessulfurizar cortes de gasolina contendo enxofre e olefinas na presença de um catalisador compreendendo pelo menos um suporte, um elemento do grupo viii e um do grupo vib e catalisador calcinado

Country Status (7)

Country Link
US (1) US7981828B2 (pt)
EP (1) EP1892039B1 (pt)
JP (2) JP2008030036A (pt)
CN (2) CN104959157A (pt)
BR (1) BRPI0703114B1 (pt)
DK (1) DK1892039T3 (pt)
FR (1) FR2904242B1 (pt)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
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FR2953740B1 (fr) * 2009-12-16 2012-01-13 Inst Francais Du Petrole Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib sauf le couple cobalt-molybdene, et preparation avec de l'acide acetique et du succinate de dialkyle c1-c4
FR2953739B1 (fr) * 2009-12-16 2012-01-13 Inst Francais Du Petrole Catalyseur utilisable en hydrotraitement comprenant du cobalt et du molybdene, son procede de preparation avec de l'acide acetique et du succinate de dialkyle c1-c4
KR101788700B1 (ko) * 2009-12-16 2017-10-20 토탈 라피나쥬 프랑스 Ⅷ 및 ⅵｂ 족 금속을 포함하는, 수소화처리에서 사용될 수 있는 촉매 및 아세트산과 디알킬 숙시네이트 ｃ1-ｃ4 를 이용하는 제조방법
FR2984762B1 (fr) 2011-12-21 2014-04-25 IFP Energies Nouvelles Adsorbant catalytique pour la captation de l'arsenic et l'hydrodesulfuration selective des essences de craquage catalytique
FR2998488B1 (fr) * 2012-11-29 2015-02-06 Ifp Energies Now Catalyseur d hydrotraitement a partir d alumine gel et methode de preparation d un tel catalyseur
FR3004969B1 (fr) * 2013-04-26 2016-01-29 IFP Energies Nouvelles Adsorbant catalytique pour la captation de l'arsenic et l'hydrodesulfuration selective des essences.
FR3023184B1 (fr) * 2014-07-04 2019-12-27 IFP Energies Nouvelles Catalyseur d'hydrotraitement a densite de molybdene elevee et methode de preparation.
CN105562019B (zh) * 2014-10-14 2018-09-14 中国石油化工股份有限公司 硫醇硫醚化的催化剂
FR3035117B1 (fr) 2015-04-15 2019-04-19 IFP Energies Nouvelles Procede d'adoucissement en composes du type sulfure d'une essence olefinique
WO2016194686A1 (ja) * 2015-05-29 2016-12-08 Ｊｘエネルギー株式会社 水素化処理油の製造方法及び接触分解油の製造方法
FR3049955B1 (fr) 2016-04-08 2018-04-06 IFP Energies Nouvelles Procede de traitement d'une essence
US10537883B2 (en) 2016-10-07 2020-01-21 King Fahd University Of Petroleum And Minerals Method for producing a hydrodesulfurization catalyst
FR3057578B1 (fr) 2016-10-19 2018-11-16 IFP Energies Nouvelles Procede d'hydrodesulfuration d'une essence olefinique.
FR3090006B1 (fr) 2018-12-18 2021-07-30 Ifp Energies Now Procédé d’hydrodésulfuration de coupes essence oléfinique contenant du soufre mettant en œuvre un catalyseur réjuvéné à un composé organique.
FR3089824B1 (fr) 2018-12-18 2021-05-07 Ifp Energies Now Procédé de réjuvénation d’un catalyseur usé et régénéré d’un procédé d'hydrodésulfuration d'essences.
FR3090005B1 (fr) 2018-12-18 2021-07-30 Ifp Energies Now Procédé d’hydrodésulfuration de coupes essence oléfinique contenant du soufre mettant en œuvre un catalyseur régénéré.
FR3089825B1 (fr) 2018-12-18 2021-05-07 Ifp Energies Now Procédé de réjuvénation d’un catalyseur usé non régénéré d’un procédé d'hydrodésulfuration d'essences.
FR3116827A1 (fr) 2020-11-27 2022-06-03 IFP Energies Nouvelles Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur contenant un matériau graphitique caractérisé par spectroscopie RMN13C MAS
FR3116826B1 (fr) 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrodesulfuration mettant en œuvre un catalyseur comprenant un support d’alumine flash
FR3116829B1 (fr) 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrodesulfuration en presence d’un catalyseur sur support meso-macroporeux
FR3116830B1 (fr) 2020-11-27 2023-11-03 Ifp Energies Now Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur contenant un matériau graphitique caractérisé par son rapport H/C
FR3116825A1 (fr) 2020-11-27 2022-06-03 IFP Energies Nouvelles Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur ayant une porosité bimodale particulière
FR3116828A1 (fr) * 2020-11-27 2022-06-03 IFP Energies Nouvelles Procédé de captation d'impuretés organométalliques mettant en œuvre une masse de captation à base de cobalt et de molybdène et contenant du carbone
FR3116740A1 (fr) 2020-11-27 2022-06-03 IFP Energies Nouvelles Procédé de préparation d’un catalyseur d’hydrodésulfuration d’une coupe essence comprenant un métal du groupe VIB, un métal du groupe VIII et du carbone graphitique
FR3142362A1 (fr) * 2022-11-30 2024-05-31 IFP Energies Nouvelles Catalyseur d’hydrodésulfuration de finition comprenant un métal du groupe VIB, un métal du groupe VIII et du phosphore sur support alumine alpha

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JP4220495B2 (ja) * 2005-06-17 2009-02-04 千代田化工建設株式会社 酸化チタン乾燥物

Also Published As

Publication number Publication date
JP5529917B2 (ja) 2014-06-25
JP2008030036A (ja) 2008-02-14
JP2012176403A (ja) 2012-09-13
EP1892039A1 (fr) 2008-02-27
BRPI0703114B1 (pt) 2017-05-02
US20080053872A1 (en) 2008-03-06
FR2904242B1 (fr) 2012-09-28
US7981828B2 (en) 2011-07-19
DK1892039T3 (da) 2019-06-24
FR2904242A1 (fr) 2008-02-01
EP1892039B1 (fr) 2019-03-27
CN104959157A (zh) 2015-10-07
CN101134909A (zh) 2008-03-05

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
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