JP2007501300A5 - - Google Patents

Download PDF

Info

Publication number
JP2007501300A5
JP2007501300A5 JP2006522288A JP2006522288A JP2007501300A5 JP 2007501300 A5 JP2007501300 A5 JP 2007501300A5 JP 2006522288 A JP2006522288 A JP 2006522288A JP 2006522288 A JP2006522288 A JP 2006522288A JP 2007501300 A5 JP2007501300 A5 JP 2007501300A5
Authority
JP
Japan
Prior art keywords
temperature
reaction
mol
solvent
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
JP2006522288A
Other languages
English (en)
Other versions
JP2007501300A (ja
Filing date
Publication date
Application filed filed Critical
Priority claimed from PCT/EP2004/008438 external-priority patent/WO2005014691A2/en
Publication of JP2007501300A publication Critical patent/JP2007501300A/ja
Publication of JP2007501300A5 publication Critical patent/JP2007501300A5/ja
Ceased legal-status Critical Current

Links

Description

触媒は、チオフェン遊離体の０．１〜５ｍｏｌ％、好ましくは０．５〜２ｍｏｌ％の量で添加するのが好ましい。
次に、随意的に反応混合物を攪拌および／または熱しつつ、重合（グリニャールメタセシス）反応を十分な時間進行させて、ポリマー（３）を得る。
本発明による方法は、十分な転換率を提供する任意の温度において実施することができる。反応は、−５℃と溶媒の還流温度の間の温度で、特に、本明細書に特定した温度で実施するのが好ましい。用語「還流温度」とは、溶媒の沸点、またはそれより僅かに低い温度を含む。
JP2006522288A 2003-08-06 2004-07-28 位置規則性ポリマーの製造方法 Ceased JP2007501300A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP03017920 2003-08-06
US49345103P 2003-08-08 2003-08-08
PCT/EP2004/008438 WO2005014691A2 (en) 2003-08-06 2004-07-28 Process of preparing regioregular polymers

Publications (2)

Publication Number Publication Date
JP2007501300A JP2007501300A (ja) 2007-01-25
JP2007501300A5 true JP2007501300A5 (ja) 2007-09-20

Family

ID=56290586

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006522288A Ceased JP2007501300A (ja) 2003-08-06 2004-07-28 位置規則性ポリマーの製造方法

Country Status (5)

Country Link
EP (1) EP1654298B1 (ja)
JP (1) JP2007501300A (ja)
KR (1) KR101120303B1 (ja)
AT (1) ATE409715T1 (ja)
WO (1) WO2005014691A2 (ja)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7262264B2 (en) * 2005-01-12 2007-08-28 Honeywell International Inc. Halogenated thiophene monomer for the preparation of regioregular polythiophenes
ATE502969T1 (de) 2005-02-11 2011-04-15 Merck Patent Gmbh Verfahren zur herstellung von regioregulären polymeren
JP4731942B2 (ja) * 2005-02-16 2011-07-27 住友化学株式会社 ポリチオフェン
JP2006232986A (ja) * 2005-02-24 2006-09-07 Mitsubishi Chemicals Corp 導電性高分子並びにそれを用いた有機電子デバイス及び電界効果トランジスタ
CN101213234B (zh) * 2005-04-01 2011-12-07 卡内基·梅隆大学 包括立体规则性聚合物、聚噻吩和嵌段共聚物的导电聚合物的活性合成
JP5376947B2 (ja) * 2005-07-18 2013-12-25 リーケ メタルズ インコーポレイテッド 置換ポリチオフェンポリマーのための改良プロセス
DE112006002830T5 (de) * 2005-11-24 2008-09-25 Merck Patent Gmbh Verfahren zur Herstellung regioregulärer Polymere
WO2007059849A1 (en) * 2005-11-24 2007-05-31 Merck Patent Gmbh Regioregular polyselenophenes
JP2007172984A (ja) * 2005-12-21 2007-07-05 Fujitsu Ltd 有機導電膜、透明有機導電フィルム及び座標入力装置
JP2009544772A (ja) 2006-07-21 2009-12-17 メルク パテント ゲーエムベーハー インデノフルオレンとチオフェンのコポリマー
TW200911873A (en) * 2007-05-15 2009-03-16 Plextronics Inc Mixed halogen polymerization
TW200916498A (en) * 2007-05-15 2009-04-16 Plextronics Inc Aryl-substituted conjugated polymers
DE102007033343A1 (de) * 2007-07-09 2009-01-15 Bayer Technology Services Gmbh Verfahren zur Synthese von Oligo/Polythiophenen nach einem "Eintopf"-Syntheseweg
DE102007036593A1 (de) * 2007-08-02 2009-02-05 Bayer Technology Services Gmbh Verfahren zur Herstellung von Poly- und Oligothiophenen in technischem Maßstab
JP2009209259A (ja) 2008-03-04 2009-09-17 Nec Tokin Corp 導電性高分子およびそれを用いた固体電解コンデンサ
JP2010248487A (ja) * 2009-03-24 2010-11-04 Sanyo Chem Ind Ltd 導電性コーティング組成物及び導電性コーティング膜の製造方法
KR20120022897A (ko) * 2009-04-10 2012-03-12 플렉스트로닉스, 인크 탈할로겐화
GB2469498B (en) 2009-04-16 2012-03-07 Cambridge Display Tech Ltd Polymer and polymerisation method
US8653227B2 (en) * 2009-06-15 2014-02-18 Basf Se Process for preparing regioregular poly-(3-substituted) thiophenes, selenophenes, thiazoles and selenazoles
JPWO2011090026A1 (ja) * 2010-01-19 2013-05-23 株式会社クラレ レジオレギュラーポリチオフェン類及びその製造方法
JP5651240B2 (ja) 2011-05-27 2015-01-07 綜研化学株式会社 環状共役系ポリマーの製造方法および環状共役系ポリマー重合用触媒
JP5742705B2 (ja) * 2011-12-22 2015-07-01 コニカミノルタ株式会社 有機光電変換素子
WO2013094456A1 (ja) * 2011-12-22 2013-06-27 コニカミノルタ株式会社 有機光電変換素子
JP5930090B2 (ja) * 2015-03-09 2016-06-08 コニカミノルタ株式会社 有機光電変換素子
KR101927636B1 (ko) * 2017-09-08 2019-03-12 한국과학기술원 구조 규칙성 제어를 이용한 블록 공중합체의 제조방법

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5939447B2 (ja) * 1982-02-26 1984-09-22 東京工業大学長 線状ポリ（３−アルキル２、５−チエニレン）重合体およびその製造方法
WO1993015086A1 (en) * 1992-02-04 1993-08-05 Board Of Regents Of The University Of Nebraska Highly reactive forms of zinc and reagents thereof
JP2000017057A (ja) * 1998-04-30 2000-01-18 Fuji Photo Film Co Ltd スチリル系化合物及びその製造方法並びにそれを用いた有機発光素子
US6166172A (en) * 1999-02-10 2000-12-26 Carnegie Mellon University Method of forming poly-(3-substituted) thiophenes
JP2001196664A (ja) * 2000-01-12 2001-07-19 Japan Science & Technology Corp 立体規則性ポリチオフェン誘導体から成る光電変換素子用光キャリアー生成および輸送材料薄膜
JP2002293888A (ja) * 2001-03-29 2002-10-09 Fuji Photo Film Co Ltd 新規重合体、それを利用した発光素子用材料および発光素子
US7074886B2 (en) * 2001-05-07 2006-07-11 E. I. Du Pont De Memours And Company Electroactive fluorene polymers having perfluoroalkyl groups, process for preparing such polymers and devices made with such polymers
ATE409714T1 (de) * 2001-07-25 2008-10-15 Merck Patent Gmbh Mono-, oligo and poly-3-(1,1- difluoroalkyl)thiophene und ihre verwendung als ladungstransportmaterial
US6602974B1 (en) * 2001-12-04 2003-08-05 Carnegie Mellon University Polythiophenes, block copolymers made therefrom, and methods of forming the same
EP1398336B1 (en) * 2002-09-14 2005-10-26 MERCK PATENT GmbH Mono-, Oligo- and Poly(3-alkynylthiophenes) and their Use as Charge Transport Materials
ATE307840T1 (de) * 2002-09-14 2005-11-15 Merck Patent Gmbh Mono-,oligo- und poly(3-alkynylthiophene) und ihre verwendung als ladungstransportmaterialien

Similar Documents

Publication Publication Date Title
JP2007501300A5 (ja)
Primer et al. Enabling the cross-coupling of tertiary organoboron nucleophiles through radical-mediated alkyl transfer
JP2008513567A5 (ja)
Nanashima et al. Synthesis of well-defined Poly (2-alkoxypyridine-3, 5-diyl) via Ni-catalyst-transfer condensation polymerization
Friis et al. Silacarboxylic acids as efficient carbon monoxide releasing molecules: synthesis and application in palladium-catalyzed carbonylation reactions
Kawakami et al. Catalytic C–H imidation of aromatic cores of functional molecules: ligand-accelerated Cu catalysis and application to materials-and biology-oriented aromatics
Leone et al. Ring-walking in catalyst-transfer polymerization
JP2010536961A5 (ja)
Sontag et al. π-Complexation in nickel-catalyzed cross-coupling reactions
JP2012526168A5 (ja)
Doubina et al. Effect of initiators on the Kumada catalyst-transfer polycondensation reaction
Tilstam et al. Activation of Mg metal for safe formation of Grignard reagents on plant scale
Liautard et al. Free-radical carboalkynylation and carboalkenylation of olefins
JP2006523595A5 (ja)
JP2008540709A5 (ja)
JP2010513612A5 (ja)
JP2008223027A5 (ja)
Shi et al. Kinetics of Bromine− Magnesium Exchange Reactions in Heteroaryl Bromides
Ye et al. Isolation of living conjugated polymer chains
Zhao et al. Computational mechanism for initiation and growth of poly (3-hexylthiophene) using palladium N-heterocyclic carbene precatalysts
Yamane et al. Magnesium bisamide-mediated halogen dance of bromothiophenes
JP2006045523A5 (ja)
Chen et al. Supramolecular template-directed synthesis of soluble quadruple-chain ladder polyphenylsiloxane (Ph-QCLP) with high molecular weight
Ito et al. Isolated Monomeric and Dimeric Mixed Diorganocuprates Based on the Size-Controllable Bulky “Rind” Ligands
JP2006518407A5 (ja)