JP2007191444A5 - - Google Patents
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- Publication number
- JP2007191444A5 JP2007191444A5 JP2006012634A JP2006012634A JP2007191444A5 JP 2007191444 A5 JP2007191444 A5 JP 2007191444A5 JP 2006012634 A JP2006012634 A JP 2006012634A JP 2006012634 A JP2006012634 A JP 2006012634A JP 2007191444 A5 JP2007191444 A5 JP 2007191444A5
- Authority
- JP
- Japan
- Prior art keywords
- solid acid
- acid catalyst
- catalyst
- propylene
- producing propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims description 51
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 39
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 39
- 239000011973 solid acid Substances 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000011148 porous material Substances 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 7
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 230000001172 regenerating effect Effects 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims 2
- 229910021536 Zeolite Inorganic materials 0.000 claims 2
- 239000001273 butane Substances 0.000 claims 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- 238000011144 upstream manufacturing Methods 0.000 claims 2
- 239000010457 zeolite Substances 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 150000002500 ions Chemical class 0.000 description 17
- 239000000571 coke Substances 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006012634A JP5330635B2 (ja) | 2006-01-20 | 2006-01-20 | プロピレンの製造方法、触媒の再生方法、固体酸触媒 |
| US12/161,218 US20100222203A1 (en) | 2006-01-20 | 2007-01-18 | Production method for propylene, restoration method for catalyst, and solid acid catalyst |
| BRPI0706663-5A BRPI0706663A2 (pt) | 2006-01-20 | 2007-01-18 | método de produção de propileno, método de regeneração de catalisador, e catalisador sólido ácido |
| EP07700524A EP1976813A2 (en) | 2006-01-20 | 2007-01-18 | Production method for propylene, restoration method for catalyst, and solid acid catalyst |
| PCT/IB2007/000191 WO2007083241A2 (en) | 2006-01-20 | 2007-01-18 | Production method for propylene, restoration method for catalyst, and solid acid catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006012634A JP5330635B2 (ja) | 2006-01-20 | 2006-01-20 | プロピレンの製造方法、触媒の再生方法、固体酸触媒 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007191444A JP2007191444A (ja) | 2007-08-02 |
| JP2007191444A5 true JP2007191444A5 (enExample) | 2009-03-05 |
| JP5330635B2 JP5330635B2 (ja) | 2013-10-30 |
Family
ID=38120356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006012634A Expired - Fee Related JP5330635B2 (ja) | 2006-01-20 | 2006-01-20 | プロピレンの製造方法、触媒の再生方法、固体酸触媒 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20100222203A1 (enExample) |
| EP (1) | EP1976813A2 (enExample) |
| JP (1) | JP5330635B2 (enExample) |
| BR (1) | BRPI0706663A2 (enExample) |
| WO (1) | WO2007083241A2 (enExample) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200918487A (en) * | 2007-09-06 | 2009-05-01 | Asahi Kasei Chemicals Corp | Process for production of propylene |
| TW200918486A (en) * | 2007-09-18 | 2009-05-01 | Asahi Kasei Chemicals Corp | Process for production of propylene |
| JP5497667B2 (ja) * | 2008-02-07 | 2014-05-21 | トタル リサーチ アンド テクノロジー フエリユイ | 結晶性シリケート上でのアルコールの脱水 |
| EP2108635A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol |
| EP2238092A1 (en) * | 2008-02-07 | 2010-10-13 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol |
| EP2108637A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol. |
| KR101227221B1 (ko) * | 2008-02-07 | 2013-01-28 | 토탈 리서치 앤드 테크놀로지 펠루이 | 에탄올로부터의 올레핀의 제조 방법 |
| JP5229882B2 (ja) * | 2008-07-04 | 2013-07-03 | 独立行政法人産業技術総合研究所 | エタノールからの炭素数３以上のオレフィン類の製造方法 |
| EP2196444A1 (en) | 2008-12-11 | 2010-06-16 | Total Petrochemicals Research Feluy | Process to make alpha olefins from ethanol |
| CN102361693A (zh) * | 2009-01-23 | 2012-02-22 | 西格纳化学有限责任公司 | 使用纯相的、经煅烧的单位点及多位点多相催化剂对醇进行催化脱水 |
| WO2010101121A1 (ja) * | 2009-03-02 | 2010-09-10 | 旭化成ケミカルズ株式会社 | プロピレンの製造方法 |
| JP5499918B2 (ja) * | 2009-06-05 | 2014-05-21 | 三菱化学株式会社 | 触媒の再生方法 |
| CN102470354A (zh) | 2009-08-11 | 2012-05-23 | 三菱化学株式会社 | 催化剂的制造方法 |
| JP5685870B2 (ja) * | 2009-09-14 | 2015-03-18 | 三菱化学株式会社 | プロピレンの製造方法 |
| WO2011135785A1 (en) | 2010-04-30 | 2011-11-03 | Toyota Jidosha Kabushiki Kaisha | Propylene production method |
| SG186715A1 (en) * | 2010-06-23 | 2013-02-28 | Agency Science Tech & Res | Method of producing alkenes by dehydration of a mixture of alcohols |
| JP2012045505A (ja) * | 2010-08-27 | 2012-03-08 | Idemitsu Kosan Co Ltd | 軽質オレフィン類製造用触媒、その製造方法及びそれを用いた軽質オレフィン類の製造方法 |
| JP5729150B2 (ja) * | 2011-06-08 | 2015-06-03 | トヨタ自動車株式会社 | Ｃ２−３オレフィンの製造方法及び製造装置 |
| US9604888B2 (en) | 2011-07-07 | 2017-03-28 | Ineos Europe Ag | Process and apparatus for producing olefins with heat transfer from steam cracking to alcohol dehydration process |
| US9133079B2 (en) | 2012-01-13 | 2015-09-15 | Siluria Technologies, Inc. | Process for separating hydrocarbon compounds |
| US9969660B2 (en) | 2012-07-09 | 2018-05-15 | Siluria Technologies, Inc. | Natural gas processing and systems |
| WO2014089479A1 (en) | 2012-12-07 | 2014-06-12 | Siluria Technologies, Inc. | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| US10047020B2 (en) | 2013-11-27 | 2018-08-14 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| US10301234B2 (en) | 2014-01-08 | 2019-05-28 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| CA3225180A1 (en) | 2014-01-09 | 2015-07-16 | Lummus Technology Llc | Oxidative coupling of methane implementations for olefin production |
| US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| JP2016098149A (ja) * | 2014-11-21 | 2016-05-30 | 三菱化学株式会社 | Ａｅｉ型ゼオライトの製造方法 |
| JP2016150931A (ja) * | 2015-02-19 | 2016-08-22 | 出光興産株式会社 | 軽質オレフィンの製造方法 |
| US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
| US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
| US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
| US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| EP3362425B1 (en) | 2015-10-16 | 2020-10-28 | Lummus Technology LLC | Separation methods and systems for oxidative coupling of methane |
| JP6600082B2 (ja) * | 2016-04-11 | 2019-10-30 | 旭化成株式会社 | 低級オレフィンの製造方法 |
| EP4071131A1 (en) | 2016-04-13 | 2022-10-12 | Lummus Technology LLC | Apparatus and method for exchanging heat |
| US20180169561A1 (en) | 2016-12-19 | 2018-06-21 | Siluria Technologies, Inc. | Methods and systems for performing chemical separations |
| WO2018217924A1 (en) * | 2017-05-23 | 2018-11-29 | Siluria Technologies, Inc. | Integration of oxidative coupling of methane processes |
| KR20200051583A (ko) | 2017-07-07 | 2020-05-13 | 루머스 테크놀로지 엘엘씨 | 메탄의 산화적 커플링를 위한 시스템 및 방법 |
| AU2022340529A1 (en) | 2021-08-31 | 2024-02-29 | Lummus Technology Llc | Methods and systems for performing oxidative coupling of methane |
| JP2024051654A (ja) * | 2022-09-30 | 2024-04-11 | 旭化成株式会社 | エタノールの変換方法、炭化水素の製造方法、プロピレンの製造方法、芳香族化合物の製造方法、並びに、エタノールの変換装置 |
| CN119657213B (zh) * | 2023-09-21 | 2025-10-31 | 中国石油化工股份有限公司 | 一种合成生物质丙烯的催化剂及其制备方法和应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4499327A (en) * | 1982-10-04 | 1985-02-12 | Union Carbide Corporation | Production of light olefins |
| JPS6333342A (ja) * | 1986-07-29 | 1988-02-13 | Agency Of Ind Science & Technol | 合成ガスからのエチレンの製造法 |
| FR2740056B1 (fr) * | 1995-10-20 | 1997-12-05 | Inst Francais Du Petrole | Catalyseur supporte contenant du rhenium et de l'aluminium, procede de preparation et application a la metathese des olefines |
| US5962762A (en) * | 1995-12-13 | 1999-10-05 | Sun; Hsian-Ning | Use of transition metal containing small pore molecular sieve catalysts in oxygenate conversion |
| US6316683B1 (en) * | 1999-06-07 | 2001-11-13 | Exxonmobil Chemical Patents Inc. | Protecting catalytic activity of a SAPO molecular sieve |
| US6437208B1 (en) * | 1999-09-29 | 2002-08-20 | Exxonmobil Chemical Patents Inc. | Making an olefin product from an oxygenate |
| WO2005051872A1 (en) * | 2003-11-19 | 2005-06-09 | Exxonmobil Chemical Patents Inc. | Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process |
| JP4826707B2 (ja) * | 2003-12-12 | 2011-11-30 | 三菱化学株式会社 | プロピレンの製造方法 |
| US7192987B2 (en) * | 2004-03-05 | 2007-03-20 | Exxonmobil Chemical Patents Inc. | Processes for making methanol streams and uses for the streams |
| US7405337B2 (en) * | 2004-09-21 | 2008-07-29 | Uop Llc | Conversion of oxygenate to propylene with selective hydrogen treatment of heavy olefin recycle stream |
-
2006
- 2006-01-20 JP JP2006012634A patent/JP5330635B2/ja not_active Expired - Fee Related
-
2007
- 2007-01-18 WO PCT/IB2007/000191 patent/WO2007083241A2/en not_active Ceased
- 2007-01-18 EP EP07700524A patent/EP1976813A2/en not_active Withdrawn
- 2007-01-18 US US12/161,218 patent/US20100222203A1/en not_active Abandoned
- 2007-01-18 BR BRPI0706663-5A patent/BRPI0706663A2/pt not_active IP Right Cessation
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