JP2006238880A - Nursery bed for paddy rice and method for preparing nursery bed for paddy field - Google Patents

Nursery bed for paddy rice and method for preparing nursery bed for paddy field Download PDF

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JP2006238880A
JP2006238880A JP2006020343A JP2006020343A JP2006238880A JP 2006238880 A JP2006238880 A JP 2006238880A JP 2006020343 A JP2006020343 A JP 2006020343A JP 2006020343 A JP2006020343 A JP 2006020343A JP 2006238880 A JP2006238880 A JP 2006238880A
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paddy rice
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JP4781829B2 (en
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Shigetoshi Kimoto
成年 木元
Atsushi Sakamoto
淳 坂本
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JNC Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a nursery bed for paddy rice capable of rearing healthy seedlings having good rooting after transplantation, in a method for applying fertilizer to a nursery box in which a fertilizer component necessary for paddy field culture after transplantation to paddy field, etc., can be fed and to provide a method for preparing the nursery bed and a culturing method using the nursery bed. <P>SOLUTION: The nursery bed for paddy rices is obtained by forming a delayed release fertilizer layer by uniformly applying granular fertilizer containing a chemically synthesized delayed release fertilizer as a fertilizer component from the upper part of a bed soil layer, fertilizer and a seed layer and a covering layer. The culturing method is carried out by using the nursery bed. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は水稲用苗床に関する。詳しくは、全栽培期間中の施肥量及び施肥回数を少なくできるような積層構造を有する水稲用苗床、苗床の作製方法及び苗床を用いた水稲の栽培方法に関する。   The present invention relates to a nursery for paddy rice. Specifically, the present invention relates to a paddy rice seedbed having a layered structure that can reduce the amount of fertilization and the number of times of fertilization during the entire cultivation period, a method for preparing the seedbed, and a method for cultivating paddy rice using the seedbed.

近年、新しい農業技術が開発され、それに伴って農業機械、農業資材などの技術革新が進んだ結果、農作業の大幅な省力化が実現されている。水稲栽培においては、時限溶出型の溶出機能を有する被覆肥料が開発され、全量基肥施肥法が実用化した。更に、育苗期間の肥料の溶出を極少に抑制した被覆肥料を用いた育苗箱全量施肥法が新たに開発され、普及しつつある(例えば、特許文献1、非特許文献1参照)。   In recent years, new agricultural technologies have been developed, and along with this, technological innovations such as agricultural machinery and agricultural materials have advanced. As a result, significant labor savings in agricultural work have been realized. In paddy rice cultivation, a coated fertilizer having a time-elution type elution function was developed, and a whole-basis fertilization method was put to practical use. Furthermore, a seedling box full-volume fertilization method using a coated fertilizer that minimizes the elution of fertilizer during the seedling period has been newly developed and is becoming widespread (see, for example, Patent Document 1 and Non-Patent Document 1).

種子と同時に施用できる肥料は、少なくとも育苗期間、肥料の溶出を極少に抑制する必要がある。このとき、溶出量が育苗時に必要な肥料の量を超えると発芽障害などの生育遅延が発生し、苗が枯死する場合がある。高度な時限溶出機能の付与を達成して流通する被覆肥料であっても、溶出を抑える技術と溶出させる技術が相反するため、溶出が開始しても溶出速度が上がりにくい(緩慢である)傾向がある。このため、育苗中の苗の生育は、従来の追肥を行う育苗方法と比べて、葉色が淡く軟弱になりやすい。また、移植後も、十分な肥料成分が被覆肥料からすぐに溶出するわけではなく、移植前から活着するまでの間は、養分の供給が少ない低栄養状態で環境ストレスに弱い状態が持続することから、冷害、風水害などを受けやすく、活着不良などによる欠株となりやすいことがある。   Fertilizers that can be applied at the same time as seeds need to minimize the elution of fertilizers at least during the seedling period. At this time, if the amount of elution exceeds the amount of fertilizer required for raising seedlings, growth delay such as germination failure may occur and the seedlings may die. Even with coated fertilizers that are distributed with a high level of elution function, the elution rate tends to be difficult (slow) even if elution starts because the technology to suppress elution and the elution technology conflict. There is. For this reason, the growth of seedlings during raising seedlings tends to be soft and weak in leaf color as compared with the conventional seedling raising method for topdressing. In addition, even after transplanting, sufficient fertilizer components do not elute from the coated fertilizer immediately, and the state of being weakly susceptible to environmental stress is maintained in a low-nutrient state with little nutrient supply until transplantation before the transplantation. Therefore, it is easy to suffer from cold damage, storm and flood damage, etc.

特開平7−236352号公報Japanese Patent Laid-Open No. 7-236352 庄子貞雄編集、金田吉弘著「新農法への挑戦―生産・資源・環境との調和―」博友社、1995年3月20日発行、p.203−220Edited by Sadao Shoko, Yoshihiro Kaneda, "Challenge to New Farming-Harmony with Production, Resources, and the Environment", Hirotomo, published March 20, 1995, p. 203-220

本発明は、本田などへ移植した後の水稲栽培に必要な肥料成分を供給できる育苗箱施肥法において、例えば、移植後の活着が良好な健苗を育成することができる水稲用苗床、及びその作製方法、それを用いた栽培方法を提供することなどを課題とする。   The present invention relates to a seedling box fertilization method that can supply fertilizer components necessary for rice cultivation after transplanting to Honda etc., for example, a nursery for paddy rice that can grow healthy seedlings with good survival after transplanting, and its An object is to provide a production method and a cultivation method using the production method.

本発明者らは、前述の課題を解決するため鋭意研究を重ねた。その結果、(a)化学合成緩効性窒素肥料を含有し、(b)粒子径0.5mm以上の粒子を70質量%以上含有し、最大粒子径が2.0mm以下であり、(c)速効性窒素含有率が粒状肥料中の全窒素成分に対して10%以下であり、(d)一粒あたりの平均質量が0.1〜5mgである粒状肥料を用いて、床土層、肥料・種子層、覆土層から形成される層の上に緩効性肥料層を形成させた水稲用苗床、及びそれを用いた栽培方法によって、前記課題が解決されることを見出し、その知見に基づいて本発明を完成した。   The inventors of the present invention have made extensive studies to solve the above-described problems. As a result, (a) containing a chemically synthesized slow-release nitrogen fertilizer, (b) containing 70% by mass or more of particles having a particle size of 0.5 mm or more, and a maximum particle size of 2.0 mm or less, (c) Using a granular fertilizer having a fast-acting nitrogen content of 10% or less with respect to the total nitrogen components in the granular fertilizer, and (d) an average mass per grain of 0.1 to 5 mg, a bed soil layer and a fertilizer -It has been found that the above problems can be solved by a seedbed for paddy rice in which a slow-release fertilizer layer is formed on a layer formed from a seed layer and a cover layer, and a cultivation method using the seedbed, and based on that knowledge The present invention has been completed.

1. 床土層、床土層の上に位置して時限溶出型の被覆窒素肥料と種子とを含有する肥料・種子層、肥料・種子層の上に位置する覆土層、及び覆土層の上に位置する緩効性肥料層を有する積層構造の水稲栽培用の苗床であり、緩効性肥料層が、下記の条件を満たす粒状肥料を含有する層である水稲用苗床。
(a)化学合成緩効性窒素肥料を含有する。
(b)粒子径0.5mm以上の粒子が70質量%以上であり、最大粒子径が2.0mm以下である。
(c)速効性窒素含有率が粒状肥料中の全窒素成分に対して10%以下である。
(d)一粒あたりの平均質量が0.1〜5mgである。
1. A bed soil layer, a fertilizer / seed layer containing a time-dissolved coated nitrogen fertilizer and seeds located on the bed soil layer, a soil covering layer located on the fertilizer / seed layer, and a soil covering layer A nursery for paddy rice, which is a seedbed for cultivating paddy rice having a slow-release fertilizer layer, and the slow-release fertilizer layer is a layer containing granular fertilizer that satisfies the following conditions.
(A) Contains a chemically synthesized slow-release nitrogen fertilizer.
(B) Particles having a particle size of 0.5 mm or more are 70% by mass or more, and the maximum particle size is 2.0 mm or less.
(C) The fast acting nitrogen content is 10% or less with respect to the total nitrogen components in the granular fertilizer.
(D) The average mass per grain is 0.1 to 5 mg.

2. 化学合成緩効性窒素肥料が、脂肪族アルデヒド縮合尿素、オキサミド、及び硫酸グアニル尿素の群から選ばれた少なくとも1つである項1記載の水稲用苗床。
3. 化学合成緩効性窒素肥料が、アセトアルデヒド縮合尿素、イソブチルアルデヒド縮合尿素、ホルムアルデヒド加工尿素肥料、グリオキサール縮合尿素、及びメチロール尿素重合肥料の群から選ばれた少なくとも1つである項1記載の水稲用苗床。
4.
化学合成緩効性窒素肥料が、アセトアルデヒド縮合尿素である項1記載の水稲用苗床。
5. 粒状肥料が、難水溶性リン酸肥料及び/または撥水性物質を含有する項1〜4のいずれか1項記載の水稲用苗床。
2. Item 2. The paddy rice nursery according to Item 1, wherein the chemically synthesized slow-release nitrogenous fertilizer is at least one selected from the group consisting of aliphatic aldehyde condensed urea, oxamide, and guanylurea sulfate.
3. The nursery for paddy rice according to Item 1, wherein the chemically synthesized slow-release nitrogenous fertilizer is at least one selected from the group consisting of acetaldehyde condensed urea, isobutyraldehyde condensed urea, formaldehyde processed urea fertilizer, glyoxal condensed urea, and methylol urea polymerized fertilizer. .
4).
Item 2. The paddy rice nursery according to Item 1, wherein the chemically synthesized slow-release nitrogenous fertilizer is acetaldehyde condensed urea.
5. Item 5. The paddy rice nursery according to any one of Items 1 to 4, wherein the granular fertilizer contains a poorly water-soluble phosphate fertilizer and / or a water-repellent substance.

6. 時限溶出型の被覆窒素肥料が、その累積窒素成分溶出率が施用した時点から10%に達する迄の期間をd1(日)とし、その累積窒素成分溶出率が10%を超えて80%に達する迄の期間をd2(日)とした場合、d1が育苗期間と等しく、かつd1/d2が0.2以上である溶出パターンを有する項1記載の水稲用苗床。
7. 肥料・種子層または緩効性肥料層が浸透移行性の殺虫作用及び/または殺菌作用を有する粒剤を含有する項1〜6のいずれか1項記載の水稲用苗床。
6). The period from when the timed elution-type coated nitrogen fertilizer reaches 10% from the point of application of the cumulative nitrogen component elution rate is d1 (day), and the cumulative nitrogen component elution rate exceeds 10% and reaches 80%. Item 2. The paddy rice nursery according to item 1, wherein the bed has a dissolution pattern in which d1 is equal to the nursery period and d1 / d2 is 0.2 or more, where d2 is the period up to.
7). Item 7. The paddy rice nursery according to any one of Items 1 to 6, wherein the fertilizer / seed layer or the slow-acting fertilizer layer contains a granule having an osmotic and insecticidal action and / or a bactericidal action.

8. 床土層を形成し、床土層の上に時限溶出型の被覆窒素肥料と種子とを含有する肥料・種子層を形成し、肥料・種子層の上に覆土層を形成し、次いで、覆土層を形成した直後から苗の移植直前までのいずれかの時期に、(a)化学合成緩効性窒素肥料を含有し、(b)粒子径0.5mm以上の粒子を70質量%以上含有し、最大粒子径が2.0mm以下であり、(c)速効性窒素含有率が粒状肥料中の全窒素成分に対して10%以下であり、(d)一粒あたりの平均質量が0.1〜5mgである粒状肥料を用いて覆土層の上に緩効性肥料層を形成する水稲用苗床の作製方法。
9. 緩効性肥料層を形成する時期が、苗の移植10日前から移植直前までのいずれかの時期である項8記載の水稲用苗床の作製方法。
10. 粒状肥料と殺虫作用及び/または殺菌作用を有する粒剤を用いて、緩効性肥料層を形成する項8または項9記載の水稲用苗床の作製方法。
11. 項1〜7のいずれか1項記載の水稲用苗床を用いる水稲の栽培方法。
8). A bed soil layer is formed, a fertilizer / seed layer containing a time-dissolved nitrogen fertilizer and seeds is formed on the bed soil layer, a cover layer is formed on the fertilizer / seed layer, and then At any time from immediately after forming the layer to immediately before transplanting the seedling, (a) containing a chemically synthesized slow-release nitrogenous fertilizer, and (b) containing 70% by mass or more of particles having a particle diameter of 0.5 mm or more. The maximum particle diameter is 2.0 mm or less, (c) the fast acting nitrogen content is 10% or less with respect to the total nitrogen components in the granular fertilizer, and (d) the average mass per grain is 0.1 A method for producing a seedbed for paddy rice in which a slow-acting fertilizer layer is formed on a soil covering layer using a granular fertilizer of ˜5 mg.
9. Item 9. The method for producing a paddy rice seedbed according to Item 8, wherein the slow-acting fertilizer layer is formed at any time from 10 days before transplanting of the seedling to immediately before transplanting.
10. Item 10. A method for producing a seedbed for paddy rice according to Item 8 or 9, wherein a slow-acting fertilizer layer is formed using granular fertilizer and a granule having an insecticidal and / or bactericidal activity.
11. Item 8. A method for cultivating paddy rice using the seedbed for paddy rice according to any one of items 1 to 7.

本発明の水稲用苗床では、苗の生育および移植後の活着に必要な肥料成分を、片寄ることなくかつ十分に施用できるので、葉色良好な健苗を育成でき、移植後の活着も良好である他、分げつの確保が期待できる。本発明で使用する粒状肥料は、小粒ながら苗の生育に悪影響を与えないように制御された肥効を長時間維持できることから、苗の倒伏がおこりにくい。更に、本発明の苗床は肥料と農薬を同時に処理できるため省力化栽培に好適である。   In the paddy rice nursery of the present invention, fertilizer components necessary for seedling growth and post-transplantation can be applied sufficiently without shifting, so that healthy seedlings with good leaf color can be grown, and post-transplantation is also good In addition, we can expect to secure a tiller. Since the granular fertilizer used in the present invention can maintain a controlled fertilization effect for a long period of time so as not to adversely affect the growth of the seedlings even though it is small, it is difficult for the seedlings to fall down. Furthermore, since the nursery of the present invention can treat fertilizer and agricultural chemicals simultaneously, it is suitable for labor-saving cultivation.

本発明の水稲用苗床は、床土層、床土層の上に位置して時限溶出型の被覆窒素肥料と種子とを含有する肥料・種子層、肥料・種子層の上に位置する覆土層、及び覆土層の上に位置する緩効性肥料層を有する積層構造になっている。緩効性肥料層に用いる粒状肥料は、化学合成緩効性窒素肥料を、該粒状肥料中の窒素肥料成分の主成分(最も多い成分)として含有する。該粒状肥料は、粒子径0.5mm以上の粒子を70質量%以上、好ましくは90質量%以上含有し、かつ該粒状肥料の最大粒子径が2.0mm以下、好ましくは1.5mm以下である。粒子径が上記の範囲であれば、主成分である化学合成緩効性窒素肥料が適度の速度で溶出して緩効性肥料として機能する。該粒状肥料は比較的小粒であり、比較的均一であるため、種籾当たりの施肥粒数が確保でき、施肥量のばらつきも少ない。   The seedbed for paddy rice of the present invention is a bed soil layer, a fertilizer / seed layer containing a time-eluting type coated nitrogen fertilizer and seeds located on the bed soil layer, a soil covering layer located on the fertilizer / seed layer And a laminated structure having a slow-acting fertilizer layer located on the soil covering layer. The granular fertilizer used for the slow-release fertilizer layer contains chemically synthesized slow-release nitrogen fertilizer as the main component (most component) of the nitrogen fertilizer component in the granular fertilizer. The granular fertilizer contains 70% by mass or more, preferably 90% by mass or more of particles having a particle size of 0.5 mm or more, and the maximum particle size of the granular fertilizer is 2.0 mm or less, preferably 1.5 mm or less. . When the particle diameter is in the above range, the chemically synthesized slow-release nitrogen fertilizer as the main component is eluted at an appropriate rate and functions as a slow-release fertilizer. Since the granular fertilizer is relatively small and relatively uniform, the number of fertilized grains per seed potato can be secured, and the amount of fertilizer applied is small.

本発明で用いられる粒状肥料は、苗が本田へ移植された後、稲の根元に1株当たり1粒以上保持されることにより、肥料成分が効率よく稲に吸収され、高い肥効を発揮できるようにするため、粒状肥料1粒あたりの平均質量は0.1〜5mg、好ましくは1〜3mgである。粒状肥料1粒あたりの平均質量が上記の範囲であれば、肥効制御が容易で、苗1株(または種子1粒)当たり適度の施用粒数にすることが容易であるため、施肥量にばらつきが出にくく、均一で安定した肥効が発揮される。ここで、粒状肥料1粒あたりの平均質量は、100粒の質量を計量して求めた平均値である。   In the granular fertilizer used in the present invention, after the seedlings are transplanted to Honda, one or more grains per strain are held at the root of the rice, so that the fertilizer components are efficiently absorbed into the rice and can exert a high fertilizing effect. Therefore, the average mass per granular fertilizer is 0.1 to 5 mg, preferably 1 to 3 mg. If the average mass per granular fertilizer is in the above range, fertilization effect control is easy, and it is easy to obtain an appropriate number of applied grains per seedling (or one seed). Difficult to occur and uniform and stable fertilization effect is demonstrated. Here, the average mass per granular fertilizer is an average value obtained by measuring the mass of 100 grains.

本発明では床土層及び覆土層に培土や培地(以下、培地という)が用いられる。培地の基材(以下、培地基材という)は、育苗に要する水分を保持し得るものであれば何れの材料であっても使用することができる。具体的には、土壌の他、軽量かつ保水性に優れる植物性繊維材料や、鉱物系材料を挙げることができる。   In the present invention, a soil or a culture medium (hereinafter referred to as a culture medium) is used for the floor soil layer and the soil covering layer. As the medium base material (hereinafter referred to as the medium base material), any material can be used as long as it can retain moisture necessary for raising seedlings. Specific examples include vegetable fiber materials and mineral materials that are lightweight and excellent in water retention in addition to soil.

土壌としては、沖積土、洪積土、火山性土、鹿沼土、ボラ土(日向土)、及び腐植土などの天然の土壌及び浄水場発生土を挙げることができる。本発明においては、これらを熱などで殺菌した殺菌土が好ましい。このような殺菌土としては、赤玉土((株)ソイール製、赤土系殺菌土)や黒玉土((株)ソイール製、黒土系殺菌土)、殺菌ボラ土を挙げることができる。   Examples of soil include natural soil such as alluvial soil, diluvial soil, volcanic soil, Kanuma soil, Bora soil (Hyuga soil), and humus soil, and soil generated from water treatment plants. In the present invention, sterilized soil obtained by sterilizing these with heat or the like is preferable. Examples of such sterilized soil include red ball soil (manufactured by Soyle Co., Ltd., red soil type sterilized soil), black ball soil (manufactured by Soyle Co., Ltd., black soil type sterilized soil), and sterilized bora soil.

植物性繊維材料としては、ピートモスやヤシガラ(ヤシの果皮から外果皮及び内果皮を除去し取り出された中果皮から更に剛長繊維及び中短繊維を取り出した残滓物など)、樹皮、木材パルプ、もみ殻、大鋸屑などが挙げられる。鉱物系材料としては、例えば、焼成バ−ミキュライト、ベントナイト、ゼオライトなどが挙げられる。また、バーミキュライトを焼成する際に残存する焼成残渣を用いても構わない。更に、これらの混合物でも構わない。   Examples of plant fiber materials include peat moss and coconut husks (residues obtained by removing rigid and medium fibers from the mesocarp obtained by removing the outer skin and inner skin from the palm skin), bark, wood pulp, Rice husks, large sawdust, etc. Examples of the mineral material include calcined vermiculite, bentonite, and zeolite. Moreover, you may use the baking residue which remains when baking a vermiculite. Furthermore, a mixture thereof may be used.

培地基材には、必要に応じて粒状綿などの人工繊維、木炭、くん炭などの有機物の炭化物、パーライト、尿素樹脂発泡体などの土壌改良材を配合することもできる。水稲用苗床に含まれる培地基材の割合は、特に限定されないが、苗床に対して、10〜70質量%の範囲であることが好ましい。尚、培地基材のかさ密度は、特に限定されないが、0.2〜0.7g/cmであると育苗箱の軽量化するうえで好ましい。水稲用苗床における床土層と覆土層の割合は、特に限定されないが、苗床に対してそれぞれ5〜90容量%と90〜5容量%であって、かつ床土層と覆土層の容量の和が50〜95容量%の範囲であることが望ましい。 The medium base material can be blended with artificial fibers such as granular cotton, organic carbides such as charcoal and charcoal, and soil improvement materials such as pearlite and urea resin foam as necessary. The ratio of the medium base material contained in the paddy rice seed bed is not particularly limited, but is preferably in the range of 10 to 70% by mass with respect to the seed bed. In addition, although the bulk density of a culture medium base material is not specifically limited, When reducing the weight of a seedling box, it is preferable that it is 0.2-0.7 g / cm < 3 >. The ratio of the bed soil layer and the cover soil layer in the paddy rice seed bed is not particularly limited, but is 5 to 90% by volume and 90 to 5% by volume with respect to the seed bed, respectively, and the sum of the capacity of the bed soil layer and the cover soil layer Is preferably in the range of 50 to 95% by volume.

本発明で用いられる培地基材には、必要に応じて窒素(N)、リン酸(P)、加里(KO)などの成分を含有するの肥料を添加することができる。添加量の目安は、慣行育苗培土に準ずるが、培地基材における含有量がそれぞれ1g/L以下である。 A fertilizer containing components such as nitrogen (N), phosphoric acid (P 2 O 5 ), and potassium (K 2 O) can be added to the medium base material used in the present invention as necessary. Although the standard of addition amount is based on the customary seedling cultivation soil, the content in the medium base material is 1 g / L or less.

培地基材には、育苗期間に培地基材由来の病虫害や、種子や植物体によって持ち込まれた病虫害、徒長抑止などへの対応や、培地の物理性や化学性を改善するなどの目的で、殺菌剤、殺虫剤、植物成長調節剤、界面活性剤、pH調節剤などを本発明の効果を阻害しない範囲において適量を含有させることもできる。   For the purpose of improving the physical and chemical properties of the medium, the medium base material responds to diseases and pest damage derived from the medium base material during seedling, seeds and plant bodies, suppression of the chief, etc. Appropriate amounts of bactericides, insecticides, plant growth regulators, surfactants, pH regulators and the like can be contained as long as the effects of the present invention are not impaired.

本発明において、肥料・種子層は、床土層の上に位置し、時限溶出型の被覆窒素肥料及び種子を含有する。肥料・種子層は、何れの手順によって形成されてもよく、例えば、時限溶出型の被覆窒素肥料と種子の混合物を、床土層の上に積層させて形成されてもよく、床土層の上に先ず時限溶出型の被覆窒素肥料を積層させ、次いでその上に播種することにより形成されてもよく、または、床土層の上に先ず播種し、次いでその上に時限溶出型の被覆窒素肥料を積層させることにより形成されてもよい。   In the present invention, the fertilizer / seed layer is located on the floor soil layer and contains a time-eluting type coated nitrogen fertilizer and seeds. The fertilizer / seed layer may be formed by any procedure, for example, it may be formed by laminating a mixture of time-eluting type coated nitrogen fertilizer and seed on the floor soil layer. It may be formed by first laminating a time-dissolved coated nitrogen fertilizer and then sowing on it, or by first sowing on the bed soil layer and then time-eluting coated nitrogen It may be formed by laminating fertilizers.

本発明で用いられる時限溶出型の被覆窒素肥料は、樹脂を有効成分とする被膜材料によって窒素肥料を含有する芯材を被覆したものである。樹脂としては、オレフィン系樹脂、ジエン系樹脂、ワックス類、ポリエステル、石油樹脂、天然樹脂、油脂及びその変性物などの熱可塑性樹脂、及び該樹脂から選ばれた2種以上の混合物、ウレタン系樹脂、アルキド系樹脂などの熱硬化性樹脂などを挙げることができる。これら樹脂にタルクなどの無機粉体、澱粉などの有機粉体、界面活性剤、充填材、添加剤を被膜材料として添加してもよい。   The time-dissolved coated nitrogen fertilizer used in the present invention is obtained by coating a core material containing nitrogen fertilizer with a coating material containing a resin as an active ingredient. Examples of the resin include olefin resins, diene resins, waxes, polyesters, petroleum resins, natural resins, oils and fats and modified products thereof, and mixtures of two or more selected from the resins, urethane resins. And thermosetting resins such as alkyd resins. An inorganic powder such as talc, an organic powder such as starch, a surfactant, a filler, or an additive may be added to these resins as a coating material.

芯材の窒素肥料としては、硫酸アンモニウム、尿素、硝酸アンモニウムの他、イソブチルアルデヒド縮合尿素、アセトアルデヒド縮合尿素などが挙げられ、これらの中でも、肥料成分当たりの単価が安い尿素が好ましい。芯材には、窒素肥料のほかに必要に応じて他の肥料を含有させてもよい。他の肥料とは、例えば、リン酸肥料、加里肥料の他、植物必須要素のカルシウム、マグネシウム、硫黄、鉄、微量要素やケイ素などを含有する肥料である。また、芯材には硝酸化成抑制材や農薬を含有させてもよい。   Examples of the nitrogen fertilizer of the core material include ammonium sulfate, urea, ammonium nitrate, isobutyraldehyde condensed urea, acetaldehyde condensed urea, and the like. Among these, urea having a low unit price per fertilizer component is preferable. In addition to nitrogen fertilizer, the core material may contain other fertilizer as required. Other fertilizers are, for example, fertilizers containing calcium, magnesium, sulfur, iron, trace elements, silicon, and the like as plant essential elements in addition to phosphate fertilizer and potassium fertilizer. Further, the core material may contain a nitrification inhibitor and an agrochemical.

好ましい時限溶出型の被覆窒素肥料の例は、特開平6−78684号公報、特開平4−202078号公報、特開平4−202079号公報などに記載されている。具体的な商品名は、チッソ旭肥料(株)製の苗箱まかせとLPコートSとLPコートSS、三菱化学アグリ(株)製のエムコートS、住友化学(株)製のスーパーSRコート、セントラル合同肥料(株)製のセラコートUとセラコートR、宇部興産(株)製のユーコート、などである。特に好ましいのはチッソ旭肥料(株)製の苗箱まかせである。   Examples of preferable time-dissolved coated nitrogen fertilizers are described in JP-A-6-78684, JP-A-4-202078, JP-A-4-202079, and the like. Specific product names are: Seed box entrusted by Chisso Asahi Fertilizer Co., Ltd., LP Coat S and LP Coat SS, Mitsubishi Chemical Agri Co., Ltd. M Coat S, Sumitomo Chemical Co., Ltd. Super SR Coat, Central Ceracoat U and Ceracoat R manufactured by Joint Fertilizer Co., Ltd., and Ucoat manufactured by Ube Industries, Ltd. A seedling box manufactured by Chisso Asahi Fertilizer Co., Ltd. is particularly preferable.

時限溶出型の被覆窒素肥料の累積窒素成分溶出率は以下の方法にて求めることが可能である。被覆窒素肥料10gを200mL水中に浸漬して25℃に静置し、所定期間経過後に被覆窒素肥料と水とに分け、水中に溶出した窒素成分の溶出累計量を定量分析により求める。さらに、上記被覆窒素肥料10g中の全窒素量を定量し、該全窒素量に対する上記溶出累計量の割合を百分率で示したものを累積窒素成分溶出率とする。具体的には、特開2005−319417号公報に記載の方法が例示できる。   The cumulative nitrogen component elution rate of the time-dissolved coated nitrogen fertilizer can be determined by the following method. 10 g of the coated nitrogen fertilizer is immersed in 200 mL of water and allowed to stand at 25 ° C. After a predetermined period of time, the coated nitrogen fertilizer is divided into the coated nitrogen fertilizer and water, and the total elution amount of nitrogen components eluted in the water is determined by quantitative analysis. Further, the total nitrogen amount in 10 g of the coated nitrogen fertilizer is quantified, and the ratio of the cumulative elution amount to the total nitrogen amount as a percentage is defined as the cumulative nitrogen component elution rate. Specifically, the method described in JP-A-2005-319417 can be exemplified.

測定はこの方法にしたがった。すなわち、被覆窒素肥料10gと予め25℃に調整をしておいた蒸留水200mLとを250mLのポリ容器に投入し、25℃設定のインキュベーターに静置した。3日後該容器から水を全て抜き取り、抜き取った水に含まれる溶出累計窒素成分量(窒素成分累計溶出量)を定量分析により求めた。定量分析は、例えば、肥料分析法(例えば、農林水産省農業環境技術研究所著,「肥料分析法(1992年版)」、(財)日本肥糧検定協会発行,1992年12月,p.15−22、山添文雄ら著,「詳解肥料分析法 改訂第1版」,養賢堂発行,1973年1月,p.35−62、に記載された方法に準じて行った。累積窒素成分溶出率は被覆窒素肥料10g中の全窒素量に対する上記溶出累計窒素成分量の割合を百分率で示したものである。   The measurement followed this method. That is, 10 g of coated nitrogen fertilizer and 200 mL of distilled water adjusted to 25 ° C. in advance were put into a 250 mL plastic container and left in an incubator set at 25 ° C. Three days later, all the water was extracted from the container, and the total amount of nitrogen components eluted (total amount of nitrogen components eluted) contained in the extracted water was determined by quantitative analysis. Quantitative analysis is, for example, a fertilizer analysis method (for example, “Agricultural Environment Technology Institute, Ministry of Agriculture, Forestry and Fisheries”, “Fertilizer Analysis Method (1992)”, published by Japan Fertilizer Testing Association, December 1992, p. 15). -22, Fumio Yamazoe et al., “Detailed Analysis of Fertilizer Analysis, 1st Edition”, published by Yokendo, January 1973, p.35-62. The rate indicates the percentage of the total amount of the eluted nitrogen component with respect to the total amount of nitrogen in 10 g of the coated nitrogen fertilizer as a percentage.

時限溶出型の被覆窒素肥料は、水中または土壌中に施用した時点から一定期間溶出が抑制される溶出抑制期間と、一定期間経過後速やかな溶出を開始する溶出期間とからなる溶出パターンを有する。上記被覆窒素肥料は、累積窒素成分溶出率が施用した時点(0%)から10%に達する迄の期間をd1(日)とし、累積窒素成分溶出率が10%を超えて80%に達する迄の期間をd2(日)とした場合、d1/d2が0.2以上となる溶出パターンを有する。d1/d2は、0.3以上であることが好ましい。育苗期間中の累積窒素成分溶出率は、10%以下であることが好ましく、より好ましくは5%以下であり、特に好ましくは3%以下である。育苗期間中の累積窒素成分溶出率が小さい被覆窒素肥料を用いた場合には、育苗後期に生育障害や生育過多が発生する可能性が低くなる。累積窒素成分溶出率が極めて小さい被覆窒素肥料は、製造が容易でないのでコスト高になりやすい。   The time-dissolved coated nitrogen fertilizer has an elution pattern consisting of an elution suppression period in which elution is suppressed for a certain period from the time it is applied in water or soil, and an elution period in which elution is started immediately after the elapse of the certain period. In the above-mentioned coated nitrogen fertilizer, the period from when the cumulative nitrogen component elution rate is applied (0%) to 10% is d1 (day), until the cumulative nitrogen component elution rate exceeds 10% and reaches 80%. When the period is d2 (days), the elution pattern has d1 / d2 of 0.2 or more. d1 / d2 is preferably 0.3 or more. The cumulative nitrogen component elution rate during the seedling raising period is preferably 10% or less, more preferably 5% or less, and particularly preferably 3% or less. When a coated nitrogen fertilizer with a small cumulative nitrogen component elution rate during the seedling period is used, the possibility of occurrence of growth failure or overgrowth in the later stage of seedling is reduced. A coated nitrogen fertilizer with a very low cumulative nitrogen component elution rate is not easy to produce and is likely to be expensive.

水稲苗の育苗期間は、稚苗(葉齢2〜3葉)で移植する場合は15〜25日であり、中苗(葉齢4葉以上)で移植する場合は30〜35日であり、成苗(葉齢5〜6葉)で移植する場合は35〜40日である。被覆窒素肥料は、育苗期間における地温を基に、肥料成分の溶出挙動を予測することができるため、例年の平均地温のデータがあれば、ある程度、育苗期間中の累積窒素成分溶出率やd1を予測することができる。したがって、平均地温における被覆窒素肥料の溶出挙動のデータがあれば、育苗期間中における望ましい累積窒素成分溶出率またはd1を有する被覆窒素肥料を選択して使用することが可能である。   The seedling raising period of paddy rice seedlings is 15 to 25 days when transplanted with young seedlings (2 to 3 leaves), and 30 to 35 days when transplanted with medium seedlings (4 or more leaves), When transplanted with adult seedlings (5 to 6 leaves), it is 35 to 40 days. Since coated nitrogen fertilizer can predict the elution behavior of fertilizer components based on the soil temperature during the seedling period, if there is data on the average soil temperature of the average year, the accumulated nitrogen component elution rate and d1 during the seedling period can be calculated to some extent. Can be predicted. Therefore, if there is data on the elution behavior of the coated nitrogen fertilizer at the average soil temperature, it is possible to select and use the coated nitrogen fertilizer having a desirable cumulative nitrogen component elution rate or d1 during the raising seedling period.

肥料・種子層の形成に当たり、上記の被覆窒素肥料の施用量は、一例を挙げると窒素保証成分40%の被覆尿素の場合、標準的な育苗箱(300mm(縦)×600mm(横)×30mm(深さ))当たり400g〜1200gが実用上好ましい。   In the formation of fertilizer / seed layer, the application rate of the above-mentioned coated nitrogen fertilizer is, for example, a standard nursery box (300 mm (vertical) x 600 mm (horizontal) x 30 mm) in the case of coated urea with a nitrogen guarantee component of 40%. 400g to 1200g per (depth) is practically preferable.

時限溶出型の被覆窒素肥料には温度依存性がある。d1の温度依存性を示す係数が、1.1〜3.5の範囲であることが好ましく、更には1.5〜3.0の範囲であることが好ましい。温度依存性とは、温度の変化に伴いd1が変動することであり、その指標としては温度が10℃変化した際のd1の変動割合(温度依存係数(Q10))で示される。例えば、温度が10℃上昇若しくは下降して、d1が1/2もしくは2倍になった場合には、温度依存係数が2であると云う。従って温度依存係数の最小値は1である。 Time-eluting coated nitrogen fertilizer is temperature dependent. The coefficient indicating the temperature dependence of d1 is preferably in the range of 1.1 to 3.5, and more preferably in the range of 1.5 to 3.0. The temperature dependence means that d1 fluctuates with a change in temperature, and an index thereof is indicated by a fluctuation ratio (temperature dependence coefficient (Q 10 )) of d1 when the temperature changes by 10 ° C. For example, when the temperature rises or falls by 10 ° C. and d1 becomes ½ or double, the temperature dependence coefficient is said to be 2. Therefore, the minimum value of the temperature dependence coefficient is 1.

化学合成緩効性窒素肥料は、有効成分の溶出が、肥料が受ける化学分解の速度に依存する肥料である。具体的には、財団法人農林統計協会発行の「ポケット肥料要覧 2004」(p.104)に記載されている、アセトアルデヒド縮合尿素、イソブチルアルデヒド縮合尿素、ホルムアルデヒド加工尿素肥料、グリオキサール縮合尿素、やメチロール尿素重合肥料などの脂肪族アルデヒド縮合尿素や、オキサミド、硫酸グアニル尿素などである。これらの中では脂肪族アルデヒド縮合尿素が好ましい。   Chemically synthesized slow-release nitrogenous fertilizers are fertilizers whose elution of active ingredients depends on the rate of chemical degradation that the fertilizer undergoes. Specifically, acetaldehyde condensed urea, isobutyraldehyde condensed urea, formaldehyde processed urea fertilizer, glyoxal condensed urea, and methylol urea described in “Pocket Fertilizer Manual 2004” (p.104) published by the Agricultural and Forestry Statistics Association Aliphatic aldehyde condensed urea such as polymer fertilizer, oxamide, guanyl sulfate, and the like. Among these, aliphatic aldehyde condensed urea is preferable.

脂肪族アルデヒド縮合尿素は、特に限定されず、直鎖状、分岐のある鎖状、環状などの何れの分子構造を持つ脂肪族アルデヒド縮合尿素であっても使用することができる。具体的には、肥料取締法(普通肥料の公定規格、肥料の種類)に記載のアセトアルデヒド縮合尿素(CDUまたはOMU)、イソブチルアルデヒド縮合尿素(IBDU)、メチロール尿素重合肥料、ホルムアルデヒド加工尿素肥料、グリオキサール縮合尿素などを挙げることができる。本発明においては、これらのうち1つ以上を任意に選択し使用すればよい。好ましくはアセトアルデヒド縮合尿素の1種である2−オキソ−4−メチル−6−ウレイドヘキサヒドロピリミジン(以下、「CDU」という)、イソブチルアルデヒド縮合尿素、メチロール尿素重合肥料であり、特に好ましくはCDUである。   The aliphatic aldehyde condensed urea is not particularly limited, and any aliphatic aldehyde condensed urea having any molecular structure such as linear, branched chain, or cyclic can be used. Specifically, acetaldehyde condensed urea (CDU or OMU), isobutyraldehyde condensed urea (IBDU), methylol urea polymerized fertilizer, formaldehyde processed urea fertilizer, glyoxal described in the fertilizer control law (official standard of fertilizer, type of fertilizer) Examples include condensed urea. In the present invention, one or more of these may be arbitrarily selected and used. Preferred are 2-oxo-4-methyl-6-ureidohexahydropyrimidine (hereinafter referred to as “CDU”), which is a kind of acetaldehyde-condensed urea, isobutyraldehyde-condensed urea, and methylol urea polymerized fertilizer, particularly preferably CDU. is there.

化学合成緩効性窒素肥料は、アンモニア態窒素、硝酸態窒素、及び尿素態窒素の窒素成分を含むことがある。この窒素成分を速効性窒素という。粒状肥料に含まれる速効性窒素含有率は、粒状肥料に含まれる全窒素成分に対し、窒素換算で10%以下である。速効性窒素の含有率が上記の範囲であれば、粒状肥料の量が多過ぎた場合であっても、生育の遅れ、葉色異常、枯死などの生育障害が起こり難いので、化学合成緩効性窒素肥料の特徴を損なうことが少ない。この傾向は、化学合成緩効性窒素肥料として脂肪族アルデヒド縮合尿素を用いた場合に顕著である。速効性窒素を含有しない化学合成緩効性窒素肥料は、合成後に精製工程が必要となるのでコスト高になりやすい。このことを考慮して粒状肥料に含まれる速効性窒素の割合は、0.1〜10%であることが好ましく、1〜10%または1〜8%であることがより好ましい。   A chemically synthesized slow-release nitrogen fertilizer may contain nitrogen components of ammonia nitrogen, nitrate nitrogen, and urea nitrogen. This nitrogen component is called fast acting nitrogen. The fast acting nitrogen content contained in the granular fertilizer is 10% or less in terms of nitrogen with respect to the total nitrogen components contained in the granular fertilizer. If the content of fast-acting nitrogen is in the above range, even if the amount of granular fertilizer is too much, growth disorders such as growth delay, leaf color abnormality, and death are unlikely to occur. Less damage to the characteristics of nitrogen fertilizer. This tendency is remarkable when an aliphatic aldehyde condensed urea is used as a chemically synthesized slow-release nitrogen fertilizer. Chemically synthesized slow-acting nitrogen fertilizers that do not contain fast-acting nitrogen tend to be costly because a purification step is required after synthesis. Considering this, the ratio of fast-acting nitrogen contained in the granular fertilizer is preferably 0.1 to 10%, more preferably 1 to 10% or 1 to 8%.

速効性窒素の割合(百分率)は、公知の肥料分析法に準拠して測定し求めることができる。例えば、農林水産省農業環境技術研究所著「肥料分析法(1992年版)」((財)日本肥糧検定協会発行、1992年12月、p.15−22)に記載の方法を挙げることができる。   The ratio (percentage) of fast acting nitrogen can be measured and determined according to a known fertilizer analysis method. For example, mention may be made of the method described in “Agricultural Environment Technology Research Institute, Ministry of Agriculture, Forestry and Fisheries”, “Fertilizer Analysis Method (1992)” (published by Japan Fertilizer Examination Association, December 1992, p. 15-22). it can.

本発明の粒状肥料は、化学合成緩効性窒素肥料のほかにリン酸成分、加里成分などを含有してもよい。粒状肥料の中に化学合成緩効性窒素肥料とリン酸肥料とが共存する場合、リン酸の含有量によっては肥効の調節が不安定になるおそれがある。化学合成緩効性窒素肥料として脂肪族アルデヒド縮合尿素を用いた場合、この傾向が特に強い。このため、粒状肥料に含まれるリン酸の全含有率(全リン酸含有率ともいう)は、化学合成緩効性窒素肥料に対してP換算で0.01〜5%の範囲であることが好ましい。この範囲であれば、化学合成緩効性窒素肥料の肥効を制御できる。なお、全リン酸含有量はキノリン重量法(第2改訂詳解肥料分析法、養賢堂発行、に記載の方法)で測定することができる。 The granular fertilizer of the present invention may contain a phosphoric acid component, a potassium component and the like in addition to the chemically synthesized slow-release nitrogenous fertilizer. When chemically synthesized slow-release nitrogenous fertilizer and phosphate fertilizer coexist in the granular fertilizer, the regulation of fertilization may become unstable depending on the phosphoric acid content. This tendency is particularly strong when aliphatic aldehyde condensed urea is used as a chemically synthesized slow-release nitrogen fertilizer. For this reason, the total content of phosphoric acid contained in the granular fertilizer (also referred to as the total phosphoric acid content) is within a range of 0.01 to 5% in terms of P 2 O 5 with respect to the chemically synthesized slow-release nitrogen fertilizer. Preferably there is. If it is this range, the fertilization effect of a chemically synthesized slow-release nitrogen fertilizer can be controlled. The total phosphoric acid content can be measured by the quinoline weight method (the method described in the second revised detailed fertilizer analysis method, published by Yokendo).

リン酸肥料は水溶性よりも難水溶性の方が好ましい。難水溶性のリン酸成分はク溶性リン酸から水溶性リン酸を除いた成分である。該成分を多く含む肥料として、具体的にはリン鉱石、熔成リン肥などである。有機肥料に含有されるリン酸成分のうち、難水溶性のものは好ましく用いることができる。上記のク溶性リン酸、水溶性リン酸は、肥料分析法(例えば、農林水産省農業環境技術研究所著,「肥料分析法(1992年版)」,(財)日本肥糧検定協会発行,1992年12月,p.28−37)によって測定できる。   Phosphate fertilizer is preferably less water-soluble than water-soluble. The sparingly water-soluble phosphoric acid component is a component obtained by removing water-soluble phosphoric acid from co-soluble phosphoric acid. Specific examples of fertilizers containing a large amount of the components include phosphorus ore and molten phosphorus fertilizer. Of the phosphoric acid components contained in the organic fertilizer, those that are poorly water-soluble can be preferably used. The above-mentioned soluble phosphoric acid and water-soluble phosphoric acid are fertilizer analysis methods (for example, “Agricultural Environment Technology Research Institute, Ministry of Agriculture, Forestry and Fisheries”, “Fertilizer analysis method (1992 version)”, published by Japan Fertilizer Testing Association, 1992. December, p. 28-37).

水溶性リン酸成分が過剰に存在すると、化学合成緩効性窒素肥料の肥効制御が損なわれる場合がある。化学合成緩効性窒素肥料として脂肪族アルデヒド縮合尿素を用いた場合、この傾向が特に強い。そこで粒状肥料中の水溶性リン酸成分の割合は、化学合成緩効性窒素肥料に対して、P換算で0.5%以下であることが好ましい。水溶性リン酸成分を含有するリン酸肥料、普通化成肥料、二成分複合化成肥料、高度化成肥料、有機質肥料などの肥料を、粒状肥料の造粒助剤の用途などに用いるときは、水溶性リン酸成分の含有量と、水に対する溶解度を考慮して使用することが好ましい。 If the water-soluble phosphate component is present in excess, fertilization control of the chemically synthesized slow-release nitrogen fertilizer may be impaired. This tendency is particularly strong when aliphatic aldehyde condensed urea is used as a chemically synthesized slow-release nitrogen fertilizer. Therefore, the ratio of the water-soluble phosphate component in the granular fertilizer is preferably 0.5% or less in terms of P 2 O 5 with respect to the chemically synthesized slow-release nitrogenous fertilizer. When using fertilizers such as phosphate fertilizers, ordinary chemical fertilizers, two-component compound fertilizers, advanced chemical fertilizers, and organic fertilizers that contain water-soluble phosphate components for applications such as granulation aids for granular fertilizers, they are water-soluble. It is preferable to use it in consideration of the content of the phosphoric acid component and the solubility in water.

難水溶性リン酸肥料は、難水溶性リン酸肥料を下記式で示される質量比で30℃の2質量%クエン酸水溶液に浸漬後、含有するリン酸成分の80%が該クエン酸水溶液に溶出するのに要する時間が0.1〜2000分の範囲である溶出特性を有するものである。
式:難水溶性リン酸肥料/2質量%クエン酸水溶液(質量比)=0.013
The poorly water-soluble phosphate fertilizer is prepared by immersing the poorly water-soluble phosphate fertilizer in a 2% by mass citric acid aqueous solution at 30 ° C. in a mass ratio represented by the following formula, and 80% of the phosphoric acid component contained in the citric acid aqueous solution. It has elution characteristics in which the time required for elution is in the range of 0.1 to 2000 minutes.
Formula: Slightly water-soluble phosphate fertilizer / 2 mass% citric acid aqueous solution (mass ratio) = 0.013

上記の溶出時間は具体的には次のような方法で測定することができる。300mL容のポリ瓶に難水溶性リン酸肥料2gと30℃に加熱した2質量%クエン酸水溶液150mLを入れ、30℃の振とう恒温槽中で振とうする。経時的に該クエン酸水溶液の上澄みを少量ずつ取り、水で希釈後、希釈液中のリン酸成分をイオンクロマトグラフィーによって定量する。この測定値から溶出曲線を作成することにより、難水溶性リン酸肥料が含有するリン酸成分の80%が溶出するまでに要した時間を求めることができる。   Specifically, the elution time can be measured by the following method. In a 300 mL plastic bottle, 2 g of a poorly water-soluble phosphate fertilizer and 150 mL of a 2% by mass citric acid solution heated to 30 ° C. are placed and shaken in a 30 ° C. shaking thermostat. The supernatant of the citric acid aqueous solution is taken little by little over time, diluted with water, and the phosphoric acid component in the diluted solution is quantified by ion chromatography. By creating an elution curve from this measured value, the time required until 80% of the phosphoric acid component contained in the poorly water-soluble phosphate fertilizer is eluted can be obtained.

該溶出時間が0.1〜2000分の範囲であれば、化学合成緩効性窒素肥料、その中でも特に脂肪族アルデヒド縮合尿素の無機化速度を容易に制御することが可能である。難水溶性リン酸肥料の該溶出時間が0.1〜2000分の範囲であるためには、該難水溶性リン酸肥料は水に対する溶解度が低く、単一の結晶で構成されていることが好ましい。更に、形状が粒子状である場合には粒子内に空隙が少ないものであることが好ましい。   If the elution time is in the range of 0.1 to 2000 minutes, the mineralization rate of the chemically-synthesized slow-release nitrogenous fertilizer, particularly the aliphatic aldehyde condensed urea can be easily controlled. In order for the elution time of the poorly water-soluble phosphate fertilizer to be in the range of 0.1 to 2000 minutes, the poorly water-soluble phosphate fertilizer has a low solubility in water and is composed of a single crystal. preferable. Furthermore, when the shape is particulate, it is preferable that there are few voids in the particles.

難水溶性リン酸肥料の溶出時間を0.1〜2000分の範囲に調節する方法は、特に限定されないが、例えば、次のような方法である。難水溶性リン酸肥料を粒子状としその粒子径を調節する方法、粒子状の難水溶性リン酸肥料の表面を水不溶性あるいは疎水性の物質で被覆する方法、難水溶性リン酸肥料の微粉末と該リン酸肥料以外の水不溶性あるいは疎水性の微粉末とを混合し造粒する方法などが例示される。   Although the method of adjusting the elution time of a slightly water-soluble phosphate fertilizer to the range of 0.1-2000 minutes is not specifically limited, For example, it is the following method. A method of adjusting the particle diameter of the slightly water-soluble phosphate fertilizer in a particulate form, a method of coating the surface of the particulate slightly water-soluble phosphate fertilizer with a water-insoluble or hydrophobic substance, Examples thereof include a method of mixing and granulating powder and water-insoluble or hydrophobic fine powder other than the phosphate fertilizer.

そのうち、難水溶性リン酸肥料を粒子状としその粒子径を調節する方法は、比較的簡便に実施可能であり好ましい。その際の粒子径は使用する難水溶性リン酸肥料の種類や、要求される溶出時間によって異なるが、製造面、或いは尿素−脂肪族アルデヒド縮合物の無機化速度調節の面から0.01〜0.5mmの範囲であることが好ましい。   Among them, the method of adjusting the particle diameter of the poorly water-soluble phosphate fertilizer in a particulate form is preferable because it can be carried out relatively easily. The particle size at that time varies depending on the kind of poorly water-soluble phosphate fertilizer to be used and the required elution time, but from the viewpoint of production or the adjustment of the mineralization rate of the urea-aliphatic aldehyde condensate, 0.01 to A range of 0.5 mm is preferable.

化学合成緩効性窒素肥料の肥効調節を目的として、粒状肥料に撥水性物質を含有させることができる。撥水性物質の添加により、化学合成緩効性窒素肥料や難水溶性リン酸肥料の土壌中における溶解を抑制し、化学合成緩効性窒素肥料の肥効を広い範囲で制御することが可能となる。この撥水性物質の粒状肥料の添加効果は、化学合成緩効性窒素肥料が脂肪族アルデヒド縮合尿素である場合に顕著である。   For the purpose of controlling the fertilization effect of chemically synthesized slow-acting nitrogen fertilizer, a water-repellent substance can be contained in the granular fertilizer. By adding water-repellent substances, it is possible to control the dissolution of chemically synthesized slow-release nitrogenous fertilizer and poorly water-soluble phosphate fertilizer in the soil, and to control the fertilization effect of chemically synthesized slow-release nitrogenous fertilizer in a wide range Become. The effect of adding the granular fertilizer of this water-repellent substance is remarkable when the chemically synthesized slow-release nitrogenous fertilizer is an aliphatic aldehyde condensed urea.

撥水性物質としては、天然ワックス、合成ワックスから選ばれた1種以上を適宜使用するのが好ましい。天然ワックスとしては、キャデリンワックス、カルナウバワックス、ライスワックス、木ろう、ホホバ油などの植物系ワックス、みつろう、ラノリン、鯨ろうなどの動物系ワックス、モンタンワックス、オゾケライト、セレシンなどの鉱物系ワックス、パラフィンワックス、マイクロクリスタリンワックス、ペトロラタムなどの石油ワックスが挙げられる。合成ワックスとしては、フィッシャー・トロプシュワックス、ポリエチレンワックス、ポリプロピレンワックスなどの合成炭化水素、モンタンワックス誘導体、パラフィンワックス誘導体、マイクロクリスタリンワックス誘導体などの変性ワックス、硬化ひまし油、硬化ひまし油誘導体などの水素化ワックス、12−ヒドロキシステアリン酸、ステアリン酸アミド、無水フタル酸イミド、塩素化炭化水素などが挙げられる。この中でも、硬化ひまし油及びその誘導体が化学合成緩効性窒素肥料の無機化速度を制御するのに効果的である。   As the water repellent substance, it is preferable to appropriately use one or more selected from natural wax and synthetic wax. Natural waxes include plant waxes such as cadrine wax, carnauba wax, rice wax, wax, jojoba oil, animal waxes such as beeswax, lanolin and sperm wax, and mineral waxes such as montan wax, ozokerite and ceresin. And petroleum waxes such as paraffin wax, microcrystalline wax and petrolatum. Synthetic waxes include synthetic hydrocarbons such as Fischer-Tropsch wax, polyethylene wax and polypropylene wax, modified waxes such as montan wax derivatives, paraffin wax derivatives and microcrystalline wax derivatives, hydrogenated waxes such as hardened castor oil and hardened castor oil derivatives, Examples thereof include 12-hydroxystearic acid, stearamide, phthalic anhydride imide, and chlorinated hydrocarbon. Among these, hydrogenated castor oil and derivatives thereof are effective in controlling the mineralization rate of chemically synthesized slow-release nitrogenous fertilizer.

粒状肥料中の撥水性物質の割合は、化学合成緩効性窒素肥料、および必要に応じて含有される難水溶性リン酸肥料や水溶性成分の総質量に対して0.1〜20質量%の範囲であることが好ましく、更に好ましくは1〜15質量%の範囲である。撥水性物質の割合が上記の範囲であれば、撥水性物質の効果が十分であり、且つ製造コストの上昇が少ない。   The ratio of the water-repellent substance in the granular fertilizer is 0.1 to 20% by mass with respect to the total mass of the chemically synthesized slow-release nitrogenous fertilizer and the poorly water-soluble phosphate fertilizer and water-soluble components contained as necessary. It is preferable that it is the range of this, More preferably, it is the range of 1-15 mass%. When the ratio of the water repellent material is within the above range, the effect of the water repellent material is sufficient and the manufacturing cost is not increased.

粒状肥料は、特開2003−212682号公報、特開2005−67923号公報などに記載された方法により製造することが可能である。例えば、化学合成緩効性窒素肥料、リン酸成分、加里成分、水溶性成分、撥水性物質、造粒助剤、結合材、水などを混合し、転動造粒法、圧縮型造粒法、攪拌型造粒法、押出造粒法などを用いて造粒する。必要に応じ、撥水性物質の融点以上500?以下の気体を用いて造粒された粒子の乾燥を行う。このようにして得られた粒子を振動篩機などで分級して粒度分布を調整することにより粒状肥料が得られる。   The granular fertilizer can be produced by a method described in JP2003-212682A, JP2005-67923A, or the like. For example, chemical synthetic slow-release nitrogen fertilizer, phosphoric acid component, potassium component, water-soluble component, water-repellent substance, granulation aid, binder, water, etc. are mixed, rolling granulation method, compression granulation method Granulation is performed using a stirring granulation method, an extrusion granulation method, or the like. If necessary, the granulated particles are dried using a gas having a melting point of not less than 500 and not more than 500? Granule fertilizer can be obtained by classifying the particles thus obtained with a vibration sieve to adjust the particle size distribution.

本発明においては、本発明の効果を損なわない範囲であれば、粒状肥料は化学合成緩効性窒素肥料のほかに、速効性窒素、難水溶性リン酸肥料、撥水性物質、その他の肥料、各種造粒助剤、結合材など含有してもよい。その他の肥料は、リン酸(P)成分や加里(KO)成分を含有する肥料、骨粉、油かす、肉かすなどの有機質肥料、石灰質肥料、苦土質肥料、ケイ酸質肥料、微量要素肥料などの無機肥料、などを挙げることができる。 In the present invention, the granular fertilizer is a fast acting nitrogen, a poorly water-soluble phosphate fertilizer, a water repellent substance, other fertilizers, in addition to the chemically synthesized slow-release nitrogen fertilizer, as long as the effects of the present invention are not impaired. You may contain various granulation adjuvants, binders, etc. Other fertilizers include fertilizers containing phosphoric acid (P 2 O 5 ) and potassium (K 2 O) components, organic fertilizers such as bone meal, oil grounds and meat grounds, calcareous fertilizers, bitter soil fertilizers, siliceous fertilizers And inorganic fertilizers such as trace element fertilizers.

造粒助剤としては、ベントナイト、クレイ、カオリン、セリサイト、タルク、酸性白土、軽石、珪砂、珪石、ゼオライト、パーライト、バーミキュライトなどの鉱物質、モミガラ、オガクズ、木質粉、パルプフロック、大豆粉などの植物質などを挙げることができる。本発明においては必要に応じてそれら造粒助剤の中から1種以上を選択して用いればよい。   Granulation aids include bentonite, clay, kaolin, sericite, talc, acid clay, pumice, quartz sand, quartzite, zeolite, perlite, vermiculite and other minerals, rice straw, sawdust, wood flour, pulp floc, soybean flour, etc. Can be mentioned. In the present invention, one or more kinds of granulation aids may be selected and used as necessary.

結合材としては、アラビアゴム、アルギン酸ナトリウム、グリセリン、ゼラチン、糖蜜、微結晶セルロース、ピッチ、カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ポリアクリル酸ナトリウム、ポリビニルピロリドン、アルミナゾル、セメント、ポリリン酸ナトリウム、リグニンスルホン酸塩、ポリビニルアルコール、ポリエチレングリコール、界面活性剤、デンプン、熱硬化性樹脂原料などを挙げることができる。本発明においては必要に応じてそれら結合剤の中から1種以上を選択して用いればよい。   Binders include gum arabic, sodium alginate, glycerin, gelatin, molasses, microcrystalline cellulose, pitch, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, sodium polyacrylate, polyvinylpyrrolidone, alumina sol, cement, sodium polyphosphate, lignin Examples thereof include sulfonates, polyvinyl alcohol, polyethylene glycol, surfactants, starch, thermosetting resin raw materials, and the like. In the present invention, one or more of these binders may be selected and used as necessary.

本発明の水稲用苗床では、主として移植後の病虫害防除に用いられる農薬を含有させてもよい。具体的には、肥料・種子層または緩効性肥料層に殺虫作用及び/または殺菌作用を有する粒剤を含有させることができる。農薬は肥料・種子層に予め混合してもよいし、播種や施肥に合わせて施用してもよい。農薬活性成分は浸透移行性を有するものであることが好ましい。このような農薬の具体例を下記に挙げるがこれらはあくまでも例示であり限定されるものではない。農薬活性成分は1種であっても、2種以上の複合成分からなるものであってもよい。農薬活性成分としては植物によって合成され、植物体内に蓄積する低分子の抗菌性物質であるファイトアレキシンを誘導する物質も例示できる。   The paddy rice nursery of the present invention may contain an agrochemical mainly used for pest control after transplanting. Specifically, a fertilizer / seed layer or a slow-release fertilizer layer can contain a granule having an insecticidal action and / or a bactericidal action. The agrochemical may be mixed in advance with the fertilizer / seed layer, or may be applied according to sowing or fertilization. The pesticidal active ingredient is preferably one having osmotic transferability. Specific examples of such agrochemicals are listed below, but these are merely examples and are not limited. The agrochemical active ingredient may be one type or may be composed of two or more composite components. Examples of the pesticidal active ingredient include substances that induce phytoalexin, which is a low-molecular antibacterial substance that is synthesized by a plant and accumulates in the plant body.

殺虫作用のある農薬の例は、(E)−N1−〔(6−クロロ−3−ピリジル)メチル〕−N2−シアノ−N1−メチルアセトアミジン(一般名:アセタミプリド)、1−(6−クロロ−3−ピリジルメチル)−N−ニトロイミダゾリジン−2−イリデンアミン(一般名:イミダクロプリド)、O,O−ジエチル−S−2−(エチルチオ)エチルホスホロジチオエート(一般名:エチルチオメトン)、1,3−ビス(カルバモイルチオ)−2−(N,N−ジメチルアミノ)プロパン塩酸塩(一般名:カルタップ)、などである。   Examples of pesticides with insecticidal action are (E) -N1-[(6-chloro-3-pyridyl) methyl] -N2-cyano-N1-methylacetamidine (generic name: acetamiprid), 1- (6-chloro -3-pyridylmethyl) -N-nitroimidazolidin-2-ylideneamine (generic name: imidacloprid), O, O-diethyl-S-2- (ethylthio) ethyl phosphorodithioate (generic name: ethylthiomethone), 1,3- Bis (carbamoylthio) -2- (N, N-dimethylamino) propane hydrochloride (generic name: Cartap), and the like.

別の例は、2,3−ジヒドロ−2,2−ジメチル−7−ベンゾ〔b〕フラニル=N−ジブチルアミノチオ−N−メチルカルバマート(一般名:カルボスルファン)、(2−イソプロピル−4−メチルピリミジル−6)−ジエチルチオホスフェート(一般名:ダイアジノン)、5−ジメチルアミノ −1,2,3−トリチアンシュウ酸塩(一般名:チオシクラム)、(E)−N−(6−クロロ−3−ピリジルメチル)−N−エチル−N’−メチル−2−ニトロビニリデンジアミン(一般名:ニテンピラム)、(±)−5−アミノ−1−(2,6−ジクロロ−α,α,α−トリフルオロ−p−トルイル)−4−トリフルオロメチルスルフィニルピラゾール−3−カルボニトリル(一般名:フィプロニル)、O,O−ジプロピル−O−4−メチルチオフェニルホスフェート(一般名:プロバホス)、などである。   Another example is 2,3-dihydro-2,2-dimethyl-7-benzo [b] furanyl = N-dibutylaminothio-N-methylcarbamate (generic name: carbosulfan), (2-isopropyl- 4-methylpyrimidyl-6) -diethylthiophosphate (generic name: diazinon), 5-dimethylamino-1,2,3-trithian oxalate (generic name: thiocyclam), (E) -N- (6-chloro -3-pyridylmethyl) -N-ethyl-N′-methyl-2-nitrovinylidenediamine (generic name: nitenpyram), (±) -5-amino-1- (2,6-dichloro-α, α, α -Trifluoro-p-toluyl) -4-trifluoromethylsulfinylpyrazole-3-carbonitrile (generic name: fipronil), O, O-dipropyl-O-4-methylthiol Niruhosufeto (generic name: Purobahosu), and the like.

別の例は、5−ブロモ−3−セコンダリ−ブチル−6−メチルウラシル(一般名:ブロマシル)、エチル=N−〔2,3−ジヒドロ−2,2−ジメチルベンゾフラン−7−イルオキシカルボニル(メチル)アミノチオ〕−N−イソプロピル−β−アラニナート(一般名:ベンフラカルブ)、2−クロロ−4,6−ビス(エチルアミノ)−1,3,5−トリアジン(一般名:CAT)、3−(3,4−ジクロロフェニル)−1,1−ジメチル尿素(一般名:DCMU)、1−ナフチル−N−メチルカーバメート(一般名:NAC)、2−イソプロポキシフェニル−N−メチルカーバメート(一般名:PHC)、などである。   Another example is 5-bromo-3-secondary-butyl-6-methyluracil (generic name: bromacil), ethyl = N- [2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl ( Methyl) aminothio] -N-isopropyl-β-alaninate (generic name: benfuracarb), 2-chloro-4,6-bis (ethylamino) -1,3,5-triazine (generic name: CAT), 3- ( 3,4-dichlorophenyl) -1,1-dimethylurea (generic name: DCMU), 1-naphthyl-N-methylcarbamate (generic name: NAC), 2-isopropoxyphenyl-N-methylcarbamate (generic name: PHC) ), Etc.

殺菌作用のある農薬の例は、ジイソプロピル−1,3−ジチオラン−2−イリデン−マロネート(一般名:イソプロチオラン)、(1RS,3SR)−2,2−ジクロロ−N−[1−(4−クロロフェニル)エチル]−1−エチル−3−メチルシクロプロパンカルボキサミド(一般名:カルプロパミド)、(RS)−2−シアノ−N−[(R)−1−(2,4−ジクロロフェニル)エチル]−3,3−ジメチルブチラミド(一般名:ジクロシメット)、5−メチル−1,2,4−トリアゾロ〔3,4−b〕ベンゾチアゾール(一般名:トリシクラゾール)、などである。   Examples of pesticides with bactericidal action include diisopropyl-1,3-dithiolane-2-ylidene-malonate (generic name: isoprothiolane), (1RS, 3SR) -2,2-dichloro-N- [1- (4-chlorophenyl) ) Ethyl] -1-ethyl-3-methylcyclopropanecarboxamide (generic name: carpropamide), (RS) -2-cyano-N-[(R) -1- (2,4-dichlorophenyl) ethyl] -3, 3-dimethylbutyramide (generic name: diclocimet), 5-methyl-1,2,4-triazolo [3,4-b] benzothiazole (generic name: tricyclazole), and the like.

別の例は、2’,6’−ジブロモ−2−メチル−4−トリフルオロメトキシ−4−トリフルオロメチル−1,3−チアゾール−5−カルボキスアニリド(一般名:チフルザミド)、1,2,5,6テトラヒドロピロロ〔3,2,1−ij〕キノリン−4−オン(一般名:ピロキロン)、N−(1−シアノ−1,2−ジメチルプロピル)−2−(2,4−ジクロロフェノキシ)プロピオンアミド(一般名:フェノキサニル)、3−アリルオキシ−1,2−ベンゾイソチアゾール−1,1−ジオキシド(一般名:プロベナゾール)、(E)−2−メトキシイミノ−N−メチル−2−(2−フェノキシフェニル)アセトアミド(一般名:メトミノストロビン)、などである。   Another example is 2 ′, 6′-dibromo-2-methyl-4-trifluoromethoxy-4-trifluoromethyl-1,3-thiazole-5-carboxanilide (generic name: tifluzamide), 1,2 , 5,6 Tetrahydropyrrolo [3,2,1-ij] quinolin-4-one (generic name: pyroxylone), N- (1-cyano-1,2-dimethylpropyl) -2- (2,4-dichloro) Phenoxy) propionamide (generic name: phenoxanyl), 3-allyloxy-1,2-benzisothiazole-1,1-dioxide (generic name: probenazole), (E) -2-methoxyimino-N-methyl-2- (2-phenoxyphenyl) acetamide (generic name: metminostrobin), and the like.

本発明の水稲用苗床は、床土層を形成し、床土層の上に時限溶出型の被覆窒素肥料と種子とを含有する肥料・種子層を形成し、肥料・種子層の上に覆土層を形成し、次いで、覆土層の上に覆土層を形成した直後から、苗の移植直前までのいずれかの時期に、(a)化学合成緩効性窒素肥料を含有し、(b)粒子径0.5mm以上の粒子を70質量%以上含有し、最大粒子径が2.0mm以下であり、(c)速効性窒素含有率が粒状肥料中の全窒素成分に対して10%以下であり、(d)一粒あたりの平均質量が0.1〜5mgである粒状肥料を用いて緩効性肥料層を形成することによって作製することができる。   The seedbed for paddy rice of the present invention forms a bed soil layer, forms a fertilizer / seed layer containing a time-dissolved nitrogen fertilizer and seeds on the bed soil layer, and covers the soil on the fertilizer / seed layer. Forming a layer, and then immediately after forming the covering layer on the covering layer, immediately before transplanting the seedling, (a) containing chemically synthesized slow-release nitrogenous fertilizer, (b) particles 70% by mass or more of particles having a diameter of 0.5 mm or more, a maximum particle diameter of 2.0 mm or less, and (c) a fast acting nitrogen content of 10% or less with respect to the total nitrogen components in the granular fertilizer (D) It can produce by forming a slow release fertilizer layer using the granular fertilizer whose average mass per grain is 0.1-5 mg.

粒状肥料を施用するのは、上記のように育苗開始直後から移植直前までのいずれの時期でもよいが、移植10日前から移植直前までのいずれかの時期が好ましく、移植10日前から移植前日がより好ましい。これは、移植直前は作業が忙しく、均一に施用するのが困難であるからである。また、育苗開始日に近いほど、本田における緩効性肥料層の肥料の肥効持続期間が短くなるため、育苗期間別の対応が必要となる。従来の箱処理用殺虫作用及び/または殺菌作用を有する粒剤は、粒状肥料と同時期に施用できるため、ほとんど作業時間はかからない。   As described above, the granular fertilizer may be applied at any time from immediately after the start of raising seedling to immediately before transplanting, but any time from 10 days before transplanting to just before transplanting is preferable, and 10 days before transplanting to the day before transplanting is more preferred. preferable. This is because the work is busy immediately before transplantation and it is difficult to apply uniformly. In addition, the closer to the seedling start date, the shorter the duration of fertilization of the slow-release fertilizer layer in Honda. Since the conventional granule having an insecticidal action and / or bactericidal action for box treatment can be applied at the same time as the granular fertilizer, it takes almost no work time.

本発明の苗床を用いた水稲の栽培方法は、従来の育苗箱全量施肥法における栽培方法に準じて栽培すれば、従来技術の移植前後における水稲苗の環境耐性を強化することができ、栽培管理がより容易になるため好ましい。   The cultivation method of paddy rice using the seedbed of the present invention can enhance the environmental tolerance of rice seedlings before and after transplanting according to the conventional technique, if cultivated according to the cultivation method in the conventional seedling box full-volume fertilization method, and cultivation management Is preferable because it becomes easier.

以下実施例によって本発明を更に詳しく説明するが、本発明はこれら実施例により限定されない。   Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples.

用いた試験方法は下記の通りである。
(1)被覆窒素肥料の溶出挙動
実施例及び比較例の被覆窒素肥料を10gとあらかじめ25℃に調整をしておいた蒸留水200mLとを250mLの蓋付きポリ容器に投入し、25℃設定のインキュベーターに静置した。7日後、該容器から水を全て抜き取り、抜き取った水に含まれる尿素量(尿素溶出量)を定量分析(ジメチルアミノベンズアルデヒド法 「詳解肥料分析法 第二改訂版」養賢堂)により求めた。水を抜き取った後のサンプルは再度該容器に入れ、該容器に再度蒸留水を200mL投入し同様に静置した。尿素溶出率の累積値が80%に達する迄この操作を繰り返した。
The test methods used are as follows.
(1) Elution behavior of coated nitrogen fertilizer 10 g of the coated nitrogen fertilizer of Examples and Comparative Examples and 200 mL of distilled water adjusted to 25 ° C. in advance are put into a 250 mL plastic container with a lid and set at 25 ° C. It was left in an incubator. Seven days later, all the water was extracted from the container, and the amount of urea contained in the extracted water (urea elution amount) was determined by quantitative analysis (dimethylaminobenzaldehyde method “detailed fertilizer analysis method second revised edition” Yokendo). The sample after draining water was put into the container again, and 200 mL of distilled water was put into the container again and left in the same manner. This operation was repeated until the cumulative value of urea elution rate reached 80%.

その後該被覆窒素肥料を乳鉢で磨りつぶし、その内容物を水200mLに溶解後上記と同様の方法で尿素残量を定量分析した。累積尿素溶出量と尿素残量を加えた量を尿素全量とし、水中に溶出した尿素の溶出累計と日数の関係をグラフ化して溶出速度曲線を作成し、累積窒素成分溶出率10%及び80%に至る日数を求めた。累積窒素成分溶出率が溶出測定開始から10%に至る迄の日数を「d1」、それ以降に溶出率が80%に至る迄の日数を「d2」とし、d1/d2を算出した。   Thereafter, the coated nitrogen fertilizer was ground in a mortar, and the content was dissolved in 200 mL of water, and then the amount of urea remaining was quantitatively analyzed in the same manner as described above. The total amount of urea dissolved and the amount of urea remaining is added as the total amount of urea, and the relationship between the total amount of urea eluted in water and the number of days is graphed to create an elution rate curve. Cumulative nitrogen component elution rates are 10% and 80%. The number of days to reach was determined. D1 / d2 was calculated by setting “d1” as the number of days until the cumulative elution rate of nitrogen components reached 10% from the start of elution measurement, and “d2” as the number of days until the dissolution rate reached 80%.

脂肪族アルデヒド縮合物尿素(CDU)の合成例
尿素60gを水60mLに溶解し、濃塩酸8.5mLを加え、氷冷下にアセトアルデヒド30gを滴下し、50℃で4時間攪拌しながら反応させ析出した結晶を濾過し、水で洗浄した後に減圧乾燥してCDU(純度99.9質量%以上)を得た。得られたCDUを篩い、目開き150μmの篩いの目をパスした粉粒体を以下の試験に用いた。尚、CDU粉粒体の速効性窒素含有率は、0.05質量%以下であった(薄層クロマトグラフ法による)。
Example of synthesis of aliphatic aldehyde condensate urea (CDU) 60 g of urea was dissolved in 60 mL of water, 8.5 mL of concentrated hydrochloric acid was added, 30 g of acetaldehyde was added dropwise under ice cooling, and the mixture was reacted at 50 ° C. with stirring for 4 hours to precipitate. The obtained crystals were filtered, washed with water, and then dried under reduced pressure to obtain CDU (purity 99.9% by mass or more). The obtained CDU was sieved, and a granular material that passed through a sieve having an opening of 150 μm was used in the following test. The fast acting nitrogen content of the CDU powder was 0.05% by mass or less (by thin layer chromatography).

粒状肥料1〜6の製造例
前記のCDU粉粒体、及び尿素(20℃の純水に対する溶解度が107.7g/100mL)を表1に示した割合で投入量の合計が20kgとなるように、容量50Lの球形混合機に投入し5分間混合して、混合物を得た。
次に、該混合物1kgを直径120cmの回転皿型パン造粒機に入れ、40r/minの回転速度で該混合物を転動させながら水及び混合物を少量ずつ添加し、平均粒子径が1.3mm程度になるまで造粒した。造粒後、熱風循環乾燥機を用い120℃の条件下で6時間乾燥し、更に、振動篩で分級して粒子径が1.2〜1.4mmの粒状肥料1を得た。また、粒状肥料1の場合と同様に、表1の割合で投入量の合計が20kgとなるようにして粒状肥料2〜4を得た。
更に、粒状肥料1の製造時に、振動篩で分級して粒子径が2.5〜4.1mmである粒状肥料5、および粒子径が0.5mm未満の粒状肥料6を得た。粒状肥料1〜6は振動篩(小型振動篩い器VSS-50、筒井理化学器械製)を用いて粒度を調製した。
Production example of granular fertilizers 1 to 6 The above-mentioned CDU granular material and urea (solubility in pure water at 20 ° C. is 107.7 g / 100 mL) so that the total input amount becomes 20 kg at the ratio shown in Table 1. The mixture was put into a spherical mixer with a capacity of 50 L and mixed for 5 minutes to obtain a mixture.
Next, 1 kg of the mixture is put into a rotating dish pan granulator having a diameter of 120 cm, water and the mixture are added little by little while rolling the mixture at a rotation speed of 40 r / min, and the average particle size is 1.3 mm. Granulated to a degree. After granulation, it was dried for 6 hours at 120 ° C. using a hot air circulating drier, and further classified with a vibrating sieve to obtain a granular fertilizer 1 having a particle size of 1.2 to 1.4 mm. Similarly to the case of granular fertilizer 1, granular fertilizers 2 to 4 were obtained so that the total amount of input was 20 kg at the ratio shown in Table 1.
Furthermore, when manufacturing the granular fertilizer 1, the granular fertilizer 5 which was classified with the vibration sieve and the particle diameter was 2.5-4.1 mm, and the granular fertilizer 6 whose particle diameter was less than 0.5 mm were obtained. The granular fertilizers 1 to 6 were prepared using a vibrating sieve (small vibrating sieve VSS-50, manufactured by Tsutsui Scientific Instruments).

粒状肥料7の製造例
市販のホルムアルデヒド加工尿素肥料(商品名「ホルム窒素2号」、三井東圧肥料(株)製)を篩い分けて粒子径が1.0〜2.0mmの粒状肥料7を得た。粒状肥料7の窒素成分含有率は41.3%、速効性窒素含有率は11.1%であった。1粒あたりの質量(n=100)は2.4mgであった。なお、上記ホルムアルデヒド加工尿素肥料は振動篩(小型振動篩い器VSS-50、筒井理化学器械製)を用いて粒度を調製した。
Production Example of Granular Fertilizer 7 Commercially available formaldehyde processed urea fertilizer (trade name “Form Nitrogen No. 2”, manufactured by Mitsui Toatsu Fertilizer Co., Ltd.) is sieved to obtain a granular fertilizer 7 having a particle size of 1.0 to 2.0 mm. Obtained. Granular fertilizer 7 had a nitrogen content of 41.3% and a fast acting nitrogen content of 11.1%. The mass per grain (n = 100) was 2.4 mg. The formaldehyde-processed urea fertilizer was adjusted in particle size using a vibrating sieve (compact vibrating sieve VSS-50, manufactured by Tsutsui Chemical).

粒状肥料8の製造例
市販のメチロール尿素重合肥料(商品名「ミクレア」、三菱レイヨン(株)製)を篩い分けて粒子径が1.0〜2.0mmの粒状肥料8を得た。粒状肥料8の窒素成分含有率は29.0%、速効性窒素含有率は1.4%であった。1粒あたりの質量(n=100)は6.2mgであった。なお、上記メチロール尿素重合肥料は振動篩(小型振動篩い器VSS-50、筒井理化学器械製)を用いて粒度を調製した。
Production Example of Granular Fertilizer 8 Commercially available methylol urea polymerization fertilizer (trade name “Mikurea”, manufactured by Mitsubishi Rayon Co., Ltd.) was sieved to obtain a granular fertilizer 8 having a particle size of 1.0 to 2.0 mm. Granular fertilizer 8 had a nitrogen content of 29.0% and a fast acting nitrogen content of 1.4%. The mass per grain (n = 100) was 6.2 mg. The methylol urea polymerization fertilizer was prepared with a particle size using a vibrating sieve (small vibrating sieve VSS-50, manufactured by Tsutsui Riken Kikai Co., Ltd.).

製造例1〜3で製造した粒状肥料の原料組成、窒素成分含有率、速効性窒素含有率、および1粒あたりの質量を表1にまとめた。なお、粒状肥料1〜3を後述の実施例1〜6に使用し、粒状肥料4〜8を後述の比較例1〜5に使用した。粒状肥料1は比較例6にも使用した。   Table 1 summarizes the raw material composition, nitrogen component content, fast-acting nitrogen content, and mass per grain of the granular fertilizers produced in Production Examples 1 to 3. In addition, the granular fertilizers 1-3 were used for the below-mentioned Examples 1-6, and the granular fertilizers 4-8 were used for the below-mentioned Comparative Examples 1-5. Granular fertilizer 1 was also used in Comparative Example 6.

Figure 2006238880
Figure 2006238880

表1の脚注:窒素成分含量は、肥料分析法(硫酸法)による測定値である。速効性窒素含有率は、粒状肥料の全窒素成分に対する速効性窒素(アンモニア態窒素、硝酸態窒素、及び尿素態窒素の和)の割合から算出した。熔成リン肥は、南九州化学工業(株)製、くみあい熔リン20−15−20(商品名)の篩分品である。目開きが180μmである篩いを通り、150μmの篩いを通らない粒子を使用した。尿素は、関東化学(株)製、試薬特級である。撥水性物質は、カスターワックスFP(商品名)、小倉合成工業(株)製、硬化ひまし油、融点81℃、である。1粒あたりの質量は、100粒の質量より求めた平均値である。   Footnotes in Table 1: Nitrogen component content is measured by fertilizer analysis (sulfuric acid method). The fast-acting nitrogen content was calculated from the ratio of fast-acting nitrogen (sum of ammonia nitrogen, nitrate nitrogen, and urea nitrogen) to the total nitrogen component of the granular fertilizer. The molten phosphorus fertilizer is a sieving product of Kumiai molten phosphorus 20-15-20 (trade name) manufactured by Minami Kyushu Chemical Co., Ltd. Particles that passed through a sieve having an opening of 180 μm and did not pass through a 150 μm sieve were used. Urea is a reagent grade manufactured by Kanto Chemical Co., Inc. The water repellent material is Custer Wax FP (trade name), manufactured by Ogura Gosei Kogyo Co., Ltd., hardened castor oil, melting point 81 ° C. The mass per grain is an average value obtained from the mass of 100 grains.

実施例1
市販の水稲用育苗箱(300mm(縦)×600mm(横)×30mm(深さ))に培地基材(保水材)として市販の水稲育苗用V床土(商品名、チッソ旭肥料(株)製、窒素0mg/L、リン酸0mg/L、加里 0mg/L、pH4.5〜5.5)を深さ約2cmとなるように充填、床土層を形成後、被覆窒素肥料1として市販の苗箱まかせN400・100タイプ(商品名、チッソ旭肥料(株)製、窒素成分含有率40%、d1=33日、d2=70日、d1/d2=0.47)を600gと水稲催芽種籾(品種「ヒノヒカリ」)120gを順に均一施用して肥料・種子層を形成させた。続いて前記市販培地基材を用いて覆土層を形成した後、移植7日前に粒状肥料1を50g均一施用して緩効性肥料層を形成させて本発明苗床を得た。被覆窒素肥料1の21日目の累積溶出率は2.8%であった。
Example 1
Commercially available paddy rice seedling boxes (300 mm (vertical) x 600 mm (horizontal) x 30 mm (depth)) as a medium base material (water retaining material), commercially available paddy rice seedling V floor soil (trade name, Chisso Asahi Fertilizer Co., Ltd.) Made of nitrogen, 0 mg / L of nitrogen, 0 mg / L of phosphoric acid, 0 mg / L of potassium, pH 4.5 to 5.5) to a depth of about 2 cm, after forming a floor soil layer, commercially available as coated nitrogen fertilizer 1 Rice seedling box N400 / 100 type (trade name, manufactured by Chisso Asahi Fertilizer Co., Ltd., nitrogen content 40%, d1 = 33 days, d2 = 70 days, d1 / d2 = 0.47) 120 g of seed meal (variety “Hinohikari”) was uniformly applied in order to form a fertilizer / seed layer. Subsequently, after forming a covering layer using the above-mentioned commercially available medium base material, 50 g of granular fertilizer 1 was uniformly applied 7 days before transplantation to form a slow-acting fertilizer layer to obtain a nursery bed of the present invention. The cumulative dissolution rate of the coated nitrogen fertilizer 1 on the 21st day was 2.8%.

実施例2
実施例1の粒状肥料1の代わりに粒状肥料2を使用する他は実施例1と同様にして本発明苗床を得た。
Example 2
A nursery of the present invention was obtained in the same manner as in Example 1 except that the granular fertilizer 2 was used instead of the granular fertilizer 1 of Example 1.

実施例3
実施例1の粒状肥料1の代わりに粒状肥料3を使用する他は実施例1と同様にして本発明苗床を得た。
Example 3
A nursery of the present invention was obtained in the same manner as in Example 1 except that the granular fertilizer 3 was used in place of the granular fertilizer 1 of Example 1.

実施例4
実施例1の粒状肥料1の施用を移植前2日にする他は実施例1と同様にして本発明苗床を得た。
Example 4
A nursery of the present invention was obtained in the same manner as in Example 1 except that the granular fertilizer 1 of Example 1 was applied on the 2nd day before transplantation.

実施例5
実施例4で粒状肥料1と市販の殺虫殺菌粒剤のウィンアドマイヤー箱粒剤(商品名、バイエルクロップサイエンス(株)製、カルプロパミド4%、イミダクロプリド2%)を各50g施用する他は同様にして本発明苗床を得た。
Example 5
Same as Example 4 except that 50 g of granular fertilizer 1 and commercially available insecticidal fungicide Wyndmeier box granule (trade name, manufactured by Bayer CropScience Co., Ltd., carpropamide 4%, imidacloprid 2%) were applied. The present invention nursery was obtained.

実施例6
実施例1で床土層を形成後、市販の殺虫殺菌粒剤のデラウスプリンス粒剤10(商品名、住友化学(株)製、ジクロシメット3%、フィプロニル1%)を50g施用後、被覆窒素肥料1を600gと水稲催芽種籾(品種「ヒノヒカリ」)180gを順に均一施用して肥料・種子層を形成させる他は同様にして本発明苗床を得た。
Example 6
After forming the floor soil layer in Example 1, 50 g of a commercially available insecticidal fungicide, Deleus Prince Granule 10 (trade name, manufactured by Sumitomo Chemical Co., Ltd., diclocimet 3%, fipronil 1%) was applied, and then coated nitrogen A nursery of the present invention was obtained in the same manner except that 600 g of fertilizer 1 and 180 g of paddy rice germination seed varieties (variety “Hinohikari”) were uniformly applied in order to form a fertilizer / seed layer.

比較例1〜5
実施例1の粒状肥料1の代わりに粒状肥料4〜8を使用する他は実施例1と同様に水稲用苗床を製造し、それぞれ比較例1〜5の結果を得た。
Comparative Examples 1-5
Rice seedling beds were produced in the same manner as in Example 1 except that granular fertilizers 4 to 8 were used instead of the granular fertilizer 1 of Example 1, and the results of Comparative Examples 1 to 5 were obtained.

比較例6
実施例1で被覆窒素肥料1を被覆窒素肥料2にする他は同様に水稲用苗床を製造し、比較例6とした。被覆窒素肥料2は市販のくみあいLPコート100(商品名、チッソ旭肥料(株)製、窒素成分含有率42%、d1=12日、d2=88日、d1/d2=0.14)を使用した。
Comparative Example 6
A nursery for paddy rice was produced in the same manner as Example 1 except that the coated nitrogen fertilizer 1 was changed to the coated nitrogen fertilizer 2 in Example 1. Covered nitrogen fertilizer 2 uses commercially available Kumiai LP coat 100 (trade name, manufactured by Chisso Asahi Fertilizer Co., Ltd., nitrogen content 42%, d1 = 12 days, d2 = 88 days, d1 / d2 = 0.14) did.

栽培試験
実施例1〜6、比較例1〜6で製造した苗床を用いて21日間育苗を行い、その様子を調査した。育苗期間中は育苗箱上方より十分な潅水を行うと同時に底面の加温を行い、床土の温度が10℃未満にならないように管理した。育苗は無加温の透明ポリオレフィンフイルム(商品名:アグリトップハイパワー、チッソ(株)製)を展張した温室内で慣行法に従って行った。育苗後は本田に移植し、慣行法に準じて栽培を行った。
Cultivation test The seedlings produced in Examples 1 to 6 and Comparative Examples 1 to 6 were grown for 21 days, and the state was investigated. During the seedling period, sufficient irrigation was performed from above the seedling box, and the bottom surface was heated at the same time, and the temperature of the floor soil was controlled so as not to be less than 10 ° C. The seedlings were grown according to the customary method in a greenhouse where an unheated transparent polyolefin film (trade name: Agritop High Power, manufactured by Chisso Corporation) was spread. After raising seedlings, they were transplanted to Honda and cultivated according to the customary method.

栽培試験結果を表2に示す。実施例1〜6の本発明の苗床を用いて育成された苗は生育が揃い、根張り、葉色共に良好であり、本田に容易に移植できた。移植後の活着も良好であったことから粒状肥料由来の肥効が効果的だったものと思われる。特に粒状肥料1を用いた実施例1、4、5、6は長期間の肥効を持続した。 The cultivation test results are shown in Table 2. The seedlings grown using the seedbeds of the present invention in Examples 1 to 6 grew well, had good rooting and leaf color, and could be easily transplanted to Honda. Since the survival after transplantation was good, it seems that the fertilization effect derived from granular fertilizer was effective. In particular, Examples 1, 4, 5, and 6 using the granular fertilizer 1 maintained a long-term fertilization effect.

Figure 2006238880
Figure 2006238880

表2の脚注:被覆窒素肥料1はチッソ旭肥料(株)製の苗箱まかせN400・100タイプ(商品名)である。被覆窒素肥料2はチッソ旭肥料(株)製のくみあいLPコート100(商品名)である。施用時期は移植前の日数を表す。実施例5では殺虫殺菌粒剤であるバイエルクロップサイエンス(株)製のウィンアドマイヤー箱粒剤(商品名)を粒状肥料と同時に施用した。実施例6では殺虫殺菌粒剤である住友化学(株)製のデラウスプリンス粒剤10(商品名)を粒状肥料と同時に施用した。培地基材(保水材)はすべてチッソ旭肥料(株)製の水稲育苗用V床土(商品名)を使用した。 Footnotes in Table 2: Coated nitrogen fertilizer 1 is a seedling box entrusted N400 / 100 type (trade name) manufactured by Chisso Asahi Fertilizer Co., Ltd. The coated nitrogen fertilizer 2 is Kumiai LP Coat 100 (trade name) manufactured by Chisso Asahi Fertilizer Co., Ltd. Application time represents the number of days before transplantation. In Example 5, an insecticide sterilizing granule, Wyner Meyer box granule (trade name) manufactured by Bayer CropScience Co., Ltd. was applied simultaneously with the granular fertilizer. In Example 6, Delousse Prince granule 10 (trade name) manufactured by Sumitomo Chemical Co., Ltd., which is an insecticidal disinfectant granule, was applied simultaneously with the granular fertilizer. As the medium base material (water retaining material), V-bed soil (trade name) for paddy rice raising seedling manufactured by Chisso Asahi Fertilizer Co., Ltd. was used.

これらのことから、本発明の苗床が苗の生育に必要な肥料成分を均一にそして十分に含有し、かつ苗床の速効性窒素が種子の発芽や苗の生育に悪影響を与えないことがわかり、更に粒状肥料1、2を用いた実施例は、含有している脂肪族アルデヒド縮合尿素の分解(無機化)が制御されたことが観察された。実施例5、6では農薬との併用も良好に推移し、農作業の省力化が見込まれる。   From these, it can be seen that the nursery of the present invention uniformly and sufficiently contains the fertilizer components necessary for seedling growth, and that the fast-acting nitrogen of the nursery does not adversely affect seed germination and seedling growth, Furthermore, it was observed that the examples using the granular fertilizers 1 and 2 controlled the decomposition (mineralization) of the contained aliphatic aldehyde condensed urea. In Examples 5 and 6, the combined use with agricultural chemicals is also good, and labor saving in agricultural work is expected.

比較的大粒の粒状肥料5、8を用いた比較例2、5は同一育苗箱内での生育が不揃いであった。苗床培地中の速効性窒素量を測定(「土壌養分分析法」、養賢堂、1970年12月発行、アンモニア態、亜硝酸態、硝酸態窒素の同時浸出定量法(p.197−p.200))したところ、生育不良の部位は良好な部位と比べて窒素成分量が少なく、施肥量のばらつきを反映したものと思われる。   In Comparative Examples 2 and 5 using relatively large granular fertilizers 5 and 8, the growth in the same seedling box was uneven. Measurement of fast-acting nitrogen content in nursery medium ("Soil Nutrient Analysis Method", Yokendo, published in December 1970, simultaneous leaching quantification method of ammonia, nitrite and nitrate nitrogen (p.197-p. 200)), the poorly grown part has a smaller amount of nitrogen component than the good part, which seems to reflect the variation in fertilizer application amount.

速効性窒素含有率の大きい粒状肥料4、7を用いた比較例1、4の苗床を用いて苗を育成した試験区は速効性窒素による濃度障害が原因で生育障害が発生した。粉末に近い粒状肥料6を用いた比較例3についても生育障害が発生した。これは、肥料の粒子が小さすぎるためにCDUの分解(無機化)が速すぎ、多量の速効性窒素が生じたためと思われる。時限溶出型の溶出パターンを有しない被覆窒素肥料を使用した比較例6では、発芽障害が発生した。   In the test plot where seedlings were grown using the seedbeds of Comparative Examples 1 and 4 using the granular fertilizers 4 and 7 having a high fast-acting nitrogen content, a growth disorder occurred due to a concentration disorder due to the fast-acting nitrogen. Growth failure also occurred in Comparative Example 3 using granular fertilizer 6 close to powder. This is presumably because the fertilizer particles were too small and the decomposition (mineralization) of the CDU was too fast, resulting in a large amount of fast-acting nitrogen. In Comparative Example 6 in which the coated nitrogen fertilizer having no timed elution pattern was used, germination damage occurred.

Claims (11)

床土層、床土層の上に位置して時限溶出型の被覆窒素肥料と種子とを含有する肥料・種子層、肥料・種子層の上に位置する覆土層、及び覆土層の上に位置する緩効性肥料層を有する積層構造の水稲栽培用の苗床であり、緩効性肥料層が、下記の条件を満たす粒状肥料を含有する層である水稲用苗床。
(a)化学合成緩効性窒素肥料を含有する。
(b)粒子径0.5mm以上の粒子が70質量%以上であり、最大粒子径が2.0mm以下である。
(c)速効性窒素含有率が粒状肥料中の全窒素成分に対して10%以下である。
(d)一粒あたりの平均質量が0.1〜5mgである。
A bed soil layer, a fertilizer / seed layer containing a time-dissolved coated nitrogen fertilizer and seeds located on the bed soil layer, a soil covering layer located on the fertilizer / seed layer, and a soil covering layer A nursery for paddy rice, which is a seedbed for cultivating paddy rice having a slow-release fertilizer layer, and the slow-release fertilizer layer is a layer containing granular fertilizer that satisfies the following conditions.
(A) Contains a chemically synthesized slow-release nitrogen fertilizer.
(B) Particles having a particle size of 0.5 mm or more are 70% by mass or more, and the maximum particle size is 2.0 mm or less.
(C) The fast acting nitrogen content is 10% or less with respect to the total nitrogen components in the granular fertilizer.
(D) The average mass per grain is 0.1 to 5 mg.
化学合成緩効性窒素肥料が、脂肪族アルデヒド縮合尿素、オキサミド、及び硫酸グアニル尿素の群から選ばれた少なくとも1つである請求項1記載の水稲用苗床。   The seedbed for paddy rice according to claim 1, wherein the chemically synthesized slow-release nitrogenous fertilizer is at least one selected from the group of aliphatic aldehyde condensed urea, oxamide, and guanylurea sulfate. 化学合成緩効性窒素肥料が、アセトアルデヒド縮合尿素、イソブチルアルデヒド縮合尿素、ホルムアルデヒド加工尿素肥料、グリオキサール縮合尿素、及びメチロール尿素重合肥料の群から選ばれた少なくとも1つである請求項1記載の水稲用苗床。   The chemically synthesized slow-release nitrogenous fertilizer is at least one selected from the group consisting of acetaldehyde condensed urea, isobutyraldehyde condensed urea, formaldehyde processed urea fertilizer, glyoxal condensed urea, and methylol urea polymerized fertilizer. Nursery. 化学合成緩効性窒素肥料が、アセトアルデヒド縮合尿素である請求項1記載の水稲用苗床。   The nursery bed for paddy rice according to claim 1, wherein the chemically synthesized slow-release nitrogenous fertilizer is acetaldehyde condensed urea. 粒状肥料が、難水溶性リン酸肥料及び/または撥水性物質を含有する請求項1〜4のいずれか1項記載の水稲用苗床。   The seedbed for paddy rice according to any one of claims 1 to 4, wherein the granular fertilizer contains a poorly water-soluble phosphate fertilizer and / or a water-repellent substance. 時限溶出型の被覆窒素肥料が、その累積窒素成分溶出率が施用した時点から10%に達する迄の期間をd1(日)とし、その累積窒素成分溶出率が10%を超えて80%に達する迄の期間をd2(日)とした場合、d1が育苗期間と等しく、かつd1/d2が0.2以上である溶出パターンを有する請求項1記載の水稲用苗床。   The period from when the timed elution-type coated nitrogen fertilizer reaches 10% from the point of application of the cumulative nitrogen component elution rate is d1 (day), and the cumulative nitrogen component elution rate exceeds 10% and reaches 80%. The seedling bed for paddy rice according to claim 1, which has an elution pattern in which d1 is equal to the seedling raising period and d1 / d2 is 0.2 or more, where d2 (days) is the period up to. 肥料・種子層または緩効性肥料層が浸透移行性の殺虫作用及び/または殺菌作用を有する粒剤を含有する請求項1〜6のいずれか1項記載の水稲用苗床。   The seedbed for paddy rice according to any one of claims 1 to 6, wherein the fertilizer / seed layer or the slow-acting fertilizer layer contains a granule having an osmotic transfer insecticidal action and / or bactericidal action. 床土層を形成し、床土層の上に時限溶出型の被覆窒素肥料と種子とを含有する肥料・種子層を形成し、肥料・種子層の上に覆土層を形成し、次いで、覆土層を形成した直後から苗の移植直前までのいずれかの時期に、(a)化学合成緩効性窒素肥料を含有し、(b)粒子径0.5mm以上の粒子を70質量%以上含有し、最大粒子径が2.0mm以下であり、(c)速効性窒素含有率が粒状肥料中の全窒素成分に対して10%以下であり、(d)一粒あたりの平均質量が0.1〜5mgである粒状肥料を用いて覆土層の上に緩効性肥料層を形成する水稲用苗床の作製方法。   A bed soil layer is formed, a fertilizer / seed layer containing a time-dissolved nitrogen fertilizer and seeds is formed on the bed soil layer, a cover layer is formed on the fertilizer / seed layer, and then At any time from immediately after forming the layer to immediately before transplanting the seedling, (a) containing a chemically synthesized slow-release nitrogenous fertilizer, and (b) containing 70% by mass or more of particles having a particle diameter of 0.5 mm or more. The maximum particle diameter is 2.0 mm or less, (c) the fast acting nitrogen content is 10% or less with respect to the total nitrogen components in the granular fertilizer, and (d) the average mass per grain is 0.1 A method for producing a seedbed for paddy rice in which a slow-acting fertilizer layer is formed on a soil covering layer using a granular fertilizer of ˜5 mg. 緩効性肥料層を形成する時期が、苗の移植10日前から移植直前までのいずれかの時期である請求項8記載の水稲用苗床の作製方法。   The method for producing a paddy rice nursery bed according to claim 8, wherein the slow-acting fertilizer layer is formed at any time from 10 days before transplanting of the seedling to immediately before transplanting. 粒状肥料と殺虫作用及び/または殺菌作用を有する粒剤を用いて、緩効性肥料層を形成する請求項8または9に記載の水稲用苗床の作製方法。   The method for producing a seedbed for paddy rice according to claim 8 or 9, wherein a slow-acting fertilizer layer is formed using granular fertilizer and a granule having an insecticidal and / or bactericidal action. 請求項1〜7のいずれか1項記載の水稲用苗床を用いる水稲の栽培方法。   The cultivation method of the paddy rice using the seedbed for paddy rice of any one of Claims 1-7.
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