JP7429932B2 - Slow-release granular fertilizer formulation containing pesticides - Google Patents

Description

The present invention relates to a slow-release granular fertilizer formulation containing pesticides and a method for using the same.

There are many types of fertilizers, and there are many ways to classify them, but they can be broadly classified into organic fertilizers and inorganic fertilizers. There are also compound fertilizers that are a mixture of both, but although the ingredients of the two are very different, they have in common that the water-soluble components of inorganic compounds are absorbed by plants, and various improvements have been made to provide nutrients for plants. There is.
Among existing chemical fertilizers, a representative example of a slow-release granular fertilizer is a composition in which potassium magnesium phosphate and ammonium magnesium phosphate are intimately mixed in a predetermined ratio (Patent Document 1).

Japanese Unexamined Patent Publication No. 2008-133267 (Patent Document 2) discloses a method for suppressing damage to paddy rice plants caused by sap-sucking pests, in which neonicotinoid insecticides and silicic acid fertilizers are applied to paddy fields to which paddy rice has been transplanted. It is stated that it can be applied on the water surface. The silicic acid fertilizer is defined as a fertilizer in which the amount of soluble silicic acid in the fertilizer composition, such as calcium silicate, potassium silicate, liquid potassium silicate, etc. is 10% by weight or more, but from the viewpoint of workability during application. It is used as a pesticide-fertilizer mixture mixed with pesticide formulations.

WO2014/098203 (Patent Document 3) describes a pesticide-containing fertilizer in which one or more pesticide components are impregnated into a granular fertilizer or attached to the surface of the granular fertilizer, and the number of particles per gram is in the range of 15 to 80. A method for applying a pesticide-containing granular fertilizer is described, which includes applying a granular fertilizer composition to soil using a fertilizer applicator (see claim 1). The pesticide-containing granular fertilizer composition used in this application method is obtained by adding a predetermined amount of a pesticide component containing a neonicotinoid insecticide to an organic solvent such as coating oil to a commercially available ordinary chemical fertilizer raw material. It is characterized in that it is obtained by mixing a mixed liquid with the chemical fertilizer, and specifically, it is obtained by mixing a mixed liquid of coating oil (Examples 1 to 3, Example 5) or C10-11 alkylbenzene (Example 4). Agrochemical components such as clothianidin (Examples 1 to 3), fenitrothion (Example 4), or furametopyr (Example 5) are mixed with a solvent to obtain a mixture, and the resulting mixture is used as the chemical fertilizer. It is manufactured by mixing with.

Special Publication No. 44-18891 Japanese Patent Application Publication No. 2008-133267 WO2014/098203

However, the silicic acid fertilizer used in Patent Document 2 and the chemical fertilizer used in Patent Document 3 are ordinary soluble chemical fertilizers.

Conventional chemical fertilizers have the problem that their fertilizing effects do not last long, resulting in excessive fertilization efforts, including additional fertilization. On the other hand, slow-release fertilizers have a long-lasting fertilizing effect, which is not only effective in reducing fertilizer application labor and efficiently using fertilizer components, but also has less impact on the environment, so the demand for them has steadily increased in recent years. It's growing.
However, at present, slow-release granular fertilizers containing pesticides obtained by treating slow-release fertilizers with pesticides are completely unknown.
An object of the present invention is to produce a slow-release granular fertilizer containing an agricultural chemical that can simultaneously apply a slow-release granular fertilizer and an agricultural chemical component to plants, and which does not have any adverse effects such as phytotoxicity on the plants.

After conducting intensive studies to solve the above problems, the present inventors developed a slow-release granular fertilizer containing pesticides and fertilizers using a non-petroleum solvent to dissolve the pesticide components. After preparing a formulation, the inventors discovered that the slow-release granular fertilizer formulation did not have any adverse effects on plants, such as phytotoxicity, and completed the present invention.

That is, the present invention includes the following aspects.
(1) A slow-release granular fertilizer formulation containing pesticides, containing a non-petroleum solvent and an active pesticide ingredient.

(2) The formulation according to (1), wherein the non-petroleum solvent has a water solubility of 100 ppm or more.

(3) Non-petroleum solvents include ether solvents, nitrile solvents, alcohol solvents, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, and amine solvents. The formulation according to (1) or (2), which is a solvent, an aldehyde-based solvent, a fatty acid ester-based solvent, a nitrogen-containing carrier-based solvent, or a glycol ether-based solvent.

(4) The formulation according to any one of (1) to (3), wherein the non-petroleum solvent is a glycol ether solvent.

(5) The formulation according to any one of (1) to (4), further containing water and/or liquid or liquid fertilizer.

(6) The pesticide is a carbamate acetylcholinesterase (AChE) inhibitor, an organophosphorus acetylcholinesterase (AChE) inhibitor, a cyclic diene organochlorine GABAergic chloride channel antagonist, or a phenylpyrazole (fiprole) GABAergic Chloride channel antagonists, pyrethroid and pyrethrin sodium channel modulators, sodium channel modulators, neonicotinoids nicotinic acetylcholine receptor (nAChR) agonists, butenolides nicotinic acetylcholine receptor (nAChR) agonists, butenolides nicotinic acetylcholine receptor (nAChR) agonists, nAChR) agonists, spinosyn-based nicotinic acetylcholine receptor (nAChR) allosteric modulators, avermectin-based and milbemycin-based chloride channel activators, juvenile hormone analogues, nonspecific (multisite) inhibitors, chordotonal organ modulators, mites Growth inhibitor, microbial-derived insect midgut lining disruptor, mitochondrial ATP synthase inhibitor, oxidative phosphorylation uncoupler, nelystoxin analog nicotinic acetylcholine receptor (nAChR) channel blocker, benzoyl urea chitin biomolecule synthesis inhibitor (type 0), chitin biosynthesis inhibitor (type 1), fly insect molting inhibitor, diacyl-hydrazine molting hormone (ecdysone) receptor agonist, octopamine receptor agonist, mitochondrial electron transport system complex III inhibitor, mitochondrial electron transport chain complex I inhibitor (METI), voltage-dependent sodium channel blocker, tetronic acid and tetramate derivative acetyl-CoA carboxylase inhibitor, phosphine-based mitochondrial electron transport system complex IV inhibitor, cyanide-based mitochondrial Electron transport system complex IV inhibitor, β-ketonitrile derivative mitochondrial electron transport system complex II inhibitor, diamide-based ryanodine receptor modulator, natural enemy insect/mite/nematode biopesticide, microbial biopesticide, spiracle blocker Pesticides, pheromone agents, azadirachtin, benzomate (benzoximate), bifenazate, fenisobromolate (bromopropylate), quinoxalines (quinomethionate), sodium aluminum fluoride, kersen (such as dicofol), pyridalyl, pyrifluquinazone, sulfur, an insecticide selected from the group consisting of ferric phosphate agents, metaldehyde and 1,3-dichloropropene;
Acylalanine-based PA fungicides (phenylamides), oxazolidinone-based PA fungicides (phenylamides), butyrolactone-based PA fungicides (phenylamides), hydroxy(2-amino-)pyrimidines, isoxazole-based aromatic hetero Rings, isothiaron aromatic heterocycles, carboxylic acids, benzimidazole MBC fungicides (methylbenzimidazole carbamate), thiophanate MBC fungicides (methylbenzimidazole carbamate), N-phenyl carbamates, toluamide benzamides, Ethylaminothiazole carboxamide type thiazole carboxamides, phenyl ureas, pyridinylmethylbenzamide type benzamides, pyrimidine amines, pyrazole carboxamides, phenylbenzamide type SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furancarboxamide SDHI (succinate dehydrogenase inhibitor), oxathiine carboxamide SDHI (succinate dehydrogenase inhibitor), Acid dehydrogenase inhibitor), thiazole carboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridine carboxamide SDHI (succinate dehydrogenase inhibitor) methoxyacrylate QoI fungicides (Qo inhibitors), methoxyacetamide QoI fungicides (Qo inhibitors), methoxycarbamate QoI fungicides (Qo inhibitors), oxyiminoacetic acid QoI fungicides (Qo inhibitors) , oxyiminoacetamide QoI fungicides (Qo inhibitors), oxazolidinedione QoI fungicides (Qo inhibitors), dihydrodioxazine QoI fungicides (Qo inhibitors), imidazolinone QoI fungicides (Qo inhibitors) , benzyl carbamate QoI fungicides (Qo inhibitors), cyanoimidazole QiI fungicides (Qi inhibitors), sulfamoyltriazole QiI fungicides (Qi inhibitors), dinitrophenylcrotonic acids, 2,6-dinitroaniline triphenyltin compounds, organotin compounds, thiophene carboxamides, triazolopyrimidylamine QoSI fungicides (Qo inhibitors, stigmatellin binding type), anilinopyrimidine AP fungicides (anilinopyrimidines), enopyranuronic acid Antibiotics, hexopyranosyl antibiotics, glucopyranosyl antibiotics, tetracycline antibiotics, allyloxyquinoline aza-naphthalenes, quinazolinone aza-naphthalenes, phenylpyrrole PP fungicides (phenylpyrroles), dicarboximides, phosphoro Thiolates, dithiolanes, aromatic hydrocarbon-based AH fungicides (including aromatic hydrocarbons, chlorophenyls, and nitroanilines), 1,2,4-thiadiazole-based heteroaromatics, carbamates, Bacillus genus and production fungicidal lipopeptide-based microorganisms (Bacillus genus), terpene hydrocarbons and terpene alcohol-based plant extracts, piperazine-based DMI fungicides (demethylation inhibitors, SBI: class I), pyridine-based DMI fungicides (demethylation inhibitors, SBI: class I), Methylation inhibitors, SBI: Class I), pyrimidine-based DMI fungicides (demethylation inhibitors, SBI: Class I), imidazole-based DMI fungicides (demethylation inhibitors, SBI: Class I), triazole-based DMI Bactericidal agents (demethylation inhibitors, SBI: Class I), triazolithione DMI fungicides (demethylation inhibitors, SBI: Class I), morpholine amines (morpholines, SBI: Class II) , piperidine-based amines (morpholines, SBI: class II), spiroketal amine-based amines (morpholines, SBI: class II), hydroxyanilides (SBI: class III), aminopyrazolinone-based compounds ( SBI: class III), thiocarbamates (SBI: class IV), allylamines (SBI: class IV), glucopyranosyl antibiotics, peptidylpyrimidine nucleoside polyoxins, cinnamic acid amide-based CAA fungicides (carboxylic acid amides), Valinamide carbamate-based CAA fungicide (carboxylic acid amide), mandelic acid amide-based CAA fungicide (carboxylic acid amide), isobenzofuranone-based MBI-R (melanin biosynthesis inhibitor - reductase), pyrroloquinolinone-based MBI- R (melanin biosynthesis inhibitor - reductase), triazolobenzothiazole MBI-R (melanin biosynthesis inhibitor - reductase), cyclopropane carboxamide MBI-D (melanin biosynthesis inhibitor - dehydratase), carboxamide MBI-D (melanin biosynthesis inhibitor - dehydratase), propionamide MBI-D (melanin biosynthesis inhibitor - dehydratase), benzothiadiazoles, benzisothiazoles, thiadiazole carboxamides, polysaccharide natural products, Plant extracts, cyanoacetamidoximes, ethylphosphonate phosphonates, phosphonates, phthalamic acids, benzotriazines, benzenesulfonamides, pyridazinones, thiocarbamate compounds, phenylacetamide compounds, benzophenone allyl phenyl ketone compounds, benzoyl Pyridine-based allyl phenyl ketone compounds, guanidines, cyanomethylenethiazolidine-based thiazolidine compounds, pyrimidinone hydrazones, piperidinylthiazole isoxazolines, 4-quinoline acetate compounds, inorganic compounds, dithiocarbamates and their analogs, phthalimides , chloronitriles (phthalonitriles), sulfamides, guanidines, triazines, quinones (anthraquinones), quinoxalines, maleimides, physical inhibitors, bicarbonate agents, silver agents, organic copper agents, and soil a disinfectant selected from the group consisting of disinfectants;
or allyloxypropionate-based acetyl-CoA carboxylase (ACCase) inhibitor, cyclohexanedione-based acetyl-CoA carboxylase (ACCase) inhibitor, phenylpyrazoline-based acetyl-CoA carboxylase (ACCase) inhibitor, sulfonylurea-based acetolactate synthase (ALS) Inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), imidazolinone-based acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), triazolopyrimidine-based acetolactate synthase (ALS) ) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), pyrimidinyl (thio)benzoate acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), sulfonylaminocarbonyltriazolinones acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), triazine-based photosynthesis (photosystem II) inhibitors, triazinone-based photosynthesis (photosystem II) inhibitors, triazolinones-based photosynthesis (photosystem II) inhibitors, System II) inhibitors, uracil photosynthesis (photosystem II) inhibitors, pyridazinone photosynthesis (photosystem II) inhibitors, phenylcarbamate photosynthesis (photosystem II) inhibitors, urea photosynthesis (photosystem II) inhibitors , amide photosynthesis (photosystem II) inhibitors, nitrile photosynthesis (photosystem II) inhibitors, benzothiadiazinone photosynthesis (photosystem II) inhibitors, phenylpyridazine photosynthesis (photosystem II) inhibitors, bipyridylium photosystem I electron conversion agents, diphenyl ether-based protoporphyrinogen oxidase (PPO) inhibitors, phenylpyrazole-based protoporphyrinogen oxidase (PPO) inhibitors, N-phenylphthalimide-based protoporphyrinogen oxidase (PPO) inhibitors, PPO) inhibitors, thiadiazole protoporphyrinogen oxidase (PPO) inhibitors, oxadiazole protoporphyrinogen oxidase (PPO) inhibitors, triazolinones protoporphyrinogen oxidase (PPO) inhibitors, oxazolidine Dione-based protoporphyrinogen oxidase (PPO) inhibitors, pyrimidinedione-based protoporphyrinogen oxidase (PPO) inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, pyridazinone-based phytoene desaturase system (PDS) ) carotenoid biosynthesis inhibitors, pyridine carboxamide-based phytoene desaturase system (PDS) carotenoid biosynthesis inhibitors, phytoene desaturase system (PDS) carotenoid biosynthesis inhibitors, triketone-based 4-hydroxyphenyl Pyruvate dioxygenase enzyme (4-HPPD) inhibitor, isoxazole-based 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor, pyrazole-based 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor, triazole carotenoid biosynthesis (target site unknown) inhibitor, isoxazolidinone carotenoid biosynthesis (target site unknown) inhibitor, urea carotenoid biosynthesis inhibitor synthesis (target site unknown) inhibitor, diphenyl ether carotenoid biosynthesis (target site unknown) inhibitor, glycine-based EPSP synthase inhibitor, phosphinic acid-based glutamine synthase inhibitor, carbamate-based DHP (dihydropteroic acid) synthase Inhibitors, dinitroaniline-based microtubule polymerization inhibitors, phosphoramidate-based microtubule polymerization inhibitors, pyridine-based microtubule polymerization inhibitors, benzamide-based microtubule polymerization inhibitors, benzoic acid-based microtubule polymerization inhibitors, carbamate-based microtubule polymerization inhibitors Mitosis/microtubule formation inhibitor, chloroacetamide VLCFA inhibitor (cell division inhibitor), acetamide VLCFA inhibitor (cell division inhibitor), oxyacetamide VLCFA inhibitor (cell division inhibitor) , tetrazolinone VLCFA inhibitor (cell division inhibitor), VLCFA inhibitor (cell division inhibitor), nitrile cell wall (cellulose) synthesis inhibitor, benzamide cell wall (cellulose) synthesis inhibitor, triazolocarboxamide cell wall (cellulose) synthesis inhibitor, quinolinecarboxylic acid-based cell wall (cellulose) synthesis inhibitor, dinitrophenol-based uncoupling (membrane breaking) agent, thiocarbamate-based lipid synthesis inhibitor (non-ACCase inhibitor), phosphorodithioate-based lipid Synthesis inhibitor (non-ACCase inhibitor), benzofuran-based lipid synthesis inhibitor (non-ACCase inhibitor), chlorocarbonate-based lipid synthesis inhibitor (non-ACCase inhibitor), phenoxycarboxylic acid-based indole acetate-like active (synthetic auxin) agent, benzoic acid Indoleacetic acid-like active (synthetic auxin) agents, pyridinecarboxylic acid-based indoleacetic acid-like active (synthetic auxins) agents, quinolinecarboxylic acid-based indoleacetic acid-like active (synthetic auxins) agents, indoleacetic acid-like active (synthetic auxins) agents, phthalamates auxin transfer inhibitors, semicarbazone type auxin transfer inhibitors, arylaminopropionic acid compounds, pyrazolium compounds, organic arsenic compounds, microorganisms, bromobutide, (chlor)-flurenol, synmethylin, cumyluron, dazomet, daimuron, methyldaimeron, A herbicide selected from the group consisting of ethobenzanide, fosamine, indanophane, carbam/carbam sodium salt, oxadiclomefon, oleic acid, pelargonic acid, pyributicarb, chlorate and cyanate; The formulation according to any one of the above.

(6-1) Pesticides include carbamate acetylcholinesterase (AChE) inhibitors, organophosphate acetylcholinesterase (AChE) inhibitors, phenylpyrazole (fiprole) GABAergic chloride channel antagonists, pyrethroid and pyrethrin sodium Channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, spinosyn nicotinic acetylcholine receptor (nAChR) allosteric modulators, avermectin and milbemycin chloride channel activators, chordotonal organ modulators, oxidative phosphorylation dephosphorylation Coupling agent, mitochondrial electron transport chain complex III inhibitor, mitochondrial electron transport chain complex I inhibitor (METI), voltage-dependent sodium channel blocker, tetronic acid and tetramic acid derivative acetyl-CoA carboxylase inhibitor, diamide-based ryanodine receptor an insecticide selected from the group consisting of modulators, quinoxalines (quinomethionates), pyridalyl and metaldehyde;
Or acylalanine-based PA fungicides (phenylamides), oxazolidinone-based PA fungicides (phenylamides), butyrolactone-based PA fungicides (phenylamides), isoxazole-based aromatic heterocycles, benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), N-phenyl carbamates, phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furancarboxamide-based SDHI (succinate dehydrogenase inhibitor), oxathiin carboxamide-based SDHI (succinate dehydrogenase inhibitor), thiazole carboxamide-based SDHI (succinate dehydrogenase inhibitor) (inhibitor), pyrazole-4-carboxamide-based SDHI (succinate dehydrogenase inhibitor), pyridine carboxamide-based SDHI (succinate dehydrogenase inhibitor), methoxyacrylate-based QoI fungicide (Qo inhibitor), methoxyacetamide-based SDHI QoI fungicides (Qo inhibitors), methoxycarbamate-based QoI fungicides (Qo inhibitors), oximinoacetic acid-based QoI fungicides (Qo inhibitors), oxyiminoacetamide-based QoI fungicides (Qo inhibitors), oxazolidinedione-based QoI Fungicides (Qo inhibitors), dihydrodioxazine QoI fungicides (Qo inhibitors), imidazolinone QoI fungicides (Qo inhibitors), benzyl carbamate QoI fungicides (Qo inhibitors), cyanoimidazole QiI fungicides (Qi inhibitors), sulfamoyltriazole-based QiI fungicides (Qi inhibitors), 2,6-dinitroanilines, anilinopyrimidine-based AP fungicides (anilinopyrimidines), phenylpyrrole-based PP fungicides ( phenylpyrroles), dicarboximides, piperazine-based DMI fungicides (demethylation inhibitors, SBI: Class I), pyridine-based DMI fungicides (demethylation inhibitors, SBI: Class I), pyrimidine-based DMI fungicides (demethylation inhibitor, SBI: Class I), imidazole-based DMI fungicide (demethylation inhibitor, SBI: Class I), triazole-based DMI fungicide (demethylation inhibitor, SBI: Class I) , triazolinthione DMI fungicide (demethylation inhibitor, SBI: Class I), isobenzofuranone MBI-R (melanin biosynthesis inhibitor - reductase), pyrroloquinolinone MBI-R (melanin biosynthesis inhibitor) - reductase), triazolobenzothiazole MBI-R (melanin biosynthesis inhibitor - reductase), cyclopropane carboxamide MBI-D (melanin biosynthesis inhibitor - dehydratase), carboxamide MBI-D (melanin biosynthesis inhibitor - dehydratase), Synthesis inhibitor - dehydratase), propionamide MBI-D (melanin biosynthesis inhibitor - dehydratase), benzothiadiazoles, benzisothiazoles, thiadiazole carboxamides, cyanoacetamide oximes, benzenesulfonamides, pyridazinones The preparation according to any one of (1) to (6)) is a fungicide selected from the group consisting of , guanidines, and quinoxalines.

(6-2) Pesticides include carbamate-based acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, phenylpyrazole-based (fiprole-based) GABAergic chloride channel antagonists, pyrethroid-based and pyrethrin-based sodium From the group consisting of channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, oxidative phosphorylation uncouplers, avermectin and milbemycin chloride channel activators, chordotonal organ modulators, and diamide ryanodine receptor modulators Insecticide selected;
or isoxazole-based aromatic heterocycles, benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), phenylbenzamide-based SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide-based SDHI (succinate dehydrogenase inhibitor), inhibitor), pyridinylethylbenzamide-based SDHI (succinate dehydrogenase inhibitor), furancarboxamide-based SDHI (succinate dehydrogenase inhibitor), oxathiincarboxamide-based SDHI (succinate dehydrogenase inhibitor), Thiazole carboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridine carboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxyacetamide-based QoI fungicide (Qo inhibitor), methoxycarbamate-based QoI fungicide (Qo inhibitor), oximinoacetic acid-based QoI fungicide (Qo inhibitor), oxyiminoacetamide-based QoI fungicide ( QoI fungicides), oxazolidinedione QoI fungicides (Qo inhibitors), dihydrodioxazine QoI fungicides (Qo inhibitors), imidazolinone QoI fungicides (Qo inhibitors), benzyl carbamate QoI fungicides (Qo inhibitor), piperazine-based DMI fungicide (demethylation inhibitor, SBI: Class I), pyridine-based DMI fungicide (demethylation inhibitor, SBI: Class I), pyrimidine-based DMI fungicide (demethylation inhibitor) (demethylation inhibitor, SBI: class I), imidazole-based DMI fungicide (demethylation inhibitor, SBI: class I), triazole-based DMI fungicide (demethylation inhibitor, SBI: class I), and triazolethione-based DMI fungicide The formulation according to any one of (1) to (6-1), which is a bactericidal agent selected from the group consisting of demethylation inhibitors (demethylation inhibitors, SBI: class I).

(6-3) Pesticides include aldicarb, bendiocarb, butocarboxime, butoxycarboxime, NAC (carbaryl), carbofuran, ethiofencarb, BPMC (fenobucarb), formanate, MIPC (isoprocarb), methomyl, MTMC (metolcarb), Oxamyl, pirimicarb, PHC (propoxur), thiophanox, triazamate, XMC, MPMC (xylylcarb), acephate, azamethyphos, casusafos, CVP (chlorfenvinphos), dimethone-S-methyl, DDVP (dichlorvos), dicrotophos, dimethoate , dimethylvinphos, ethoprofos, fenamiphos, fosthiazate, heptenophos, marathon (malathion), mecarbam, methamidophos, DMTP (methidathion), mevinphos, monocrotophos, omethoate, oxydimethone methyl, phosphamidon, propetamphos, thiometone, DEP (trichlorfon), vamidothione , flumethrin, fipronil, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, nicotine sulfate (nicotine), sulfoxaflor, flupyradifuron, pyriproxyfen, methyl bromide, chlorpicrin, sulfuryl fluoride, borax, Tartarite, pymetrozine, flonicamid, BPPS (propargite), DNOC, cartap, thiocyclam, thiosultap sodium salt, cyromazine, hydrogen phosphide, hydrocyanic acid, azadirachtin, sodium aluminum fluoride, 1,3-dichloropropene, dicyclanil, ethylene an insecticide selected from the group consisting of dibromide, savazilla and sulcofuron sodium;
or furalaxyl, metalaxyl, metalaxyl M, oxadixyl, ofrase, dimethylimole, hydroxyisoxazole (hymexazole), octylinone, fenflam, carboxin, oxycarboxin, furametopyr, metominostrobin, cyazofamid, pyrimethanil, kasugamycin, streptomycin, IBP (iprobenfoss) ), eclomezole (etridiazole), propamocarb, prothiocarb, pyrifenox, imazalil, pefrazoate, triflumizole, flutriafol, myclobutanil, propiconazole, tetraconazole, fenpropidine, spiroxamine, validamycin, polyoxin, iprovaricarb, pyroquilone , cymoxanil, fosetyl, phosphorous acid and salts, fursulfamide, metasulfocarb, guanidine (dodine), felimzone, potassium bicarbonate, farbam, guazatine, iminoctadine acetate/iminoctadine albesylate (iminoctadine), copper sulfate, formaldehyde, A fungicide selected from the group consisting of 8-hydroxyquinoline sulfate, iodomethane, mercuric chloride, metam, methyl bromide, methyl isothiocyanate, mildiomycin, nabam, phenylmercuric acetate, 2-phenylphenol and poloxin. The formulation according to any one of (1) to (6-2).

(6-4) Any of (1) to (6-3), wherein the pesticide is at least one selected from the group consisting of acephate, fipronil, acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam, nitenpyram, and flonicamid. The preparation according to one of the above.

(6-5) Any one of (1) to (6-4), wherein the pesticide is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam, and nitenpyram. The formulation described in one of the above.

(6-6) The pesticide is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, and thiamethoxam, according to any one of (1) to (6-5). It is a formulation of

(6-7) The formulation according to any one of (1) to (6-6), wherein the pesticide is dinotefuran.

(7) The formulation according to any one of (1) to (6), wherein the content of the pesticide is 0.01% to 10% by weight.

(8) The slow-release granular fertilizer is a slow-release combination granular fertilizer, a chemically synthesized slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressure-molded granular fertilizer, or a slow-release nitrification inhibitor compound fertilizer. The formulation according to any one of (1) to (7).

(9) Slow-release granular fertilizer contains nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), The formulation according to any one of (1) to (8), containing any one or more fertilizer components selected from the group consisting of calcium (Ca) and sulfur (S).

(9-1) The slow-release granular fertilizer contains at least two fertilizer components selected from the group consisting of nitrogen (N), phosphorus (P), and potassium (K) as essential plant elements. ) or the formulation described in (9).

(9-2) Any one of (8) to (9-1), wherein the slow-release granular fertilizer contains fertilizer components of nitrogen (N), phosphorus (P), and potassium (K) as essential plant elements. The formulation described in one of the above.

(9-3) The slow-release granular fertilizer further contains iron (Fe), copper (Cu), zinc (Zn), molybdenum (Mo), cobalt (Co), and chlorine (Cl) as essential plant elements. The formulation according to any one of (8) to (9-2), containing any one or more of fertilizer components selected from the following.

(10) The slow-release granular fertilizer described in (9) contains nitrogen (N), phosphorus (P) and potassium (K) as essential plant elements in a guaranteed ingredient ratio of 3:20:3. It is a formulation.

(11) The slow-release granular fertilizer described in (9) contains nitrogen (N), phosphorus (P) and potassium (K) as essential plant elements in a guaranteed ingredient ratio of 2:5:2. It is a formulation.

(12) The formulation according to any one of (8) to (11), wherein the content of slow-release granular fertilizer is 0.1% to 99.9% by weight.

(13) The formulation according to any one of (1) to (7), wherein the content of the non-petroleum solvent is 0.1% to 10% by weight.

(14) The content of pesticides is 0.01% to 10% by weight, the content of non-petroleum solvents is 0.1% to 10% by weight, and the content of slow-release granular fertilizer is 0.1% by weight. ~99.9% by weight, the formulation according to any one of (1) to (13).

(15) The content of pesticides is 0.03% to 5% by weight, the content of non-petroleum solvents is 0.1% to 10% by weight, and the content of slow-release granular fertilizer is 50.0% by weight. The formulation according to (14) is 99.8% by weight.

(16) Use of the formulation according to any one of (1) to (15) for agricultural horticulture or home horticulture.

The pesticide-containing slow-release granular fertilizer formulation of the present invention is essentially different from the usual soluble chemical fertilizers used in Patent Documents 2 and 3 in terms of elution of fertilizer components.
Further, the slow-release granular fertilizer formulation containing pesticides of the present invention belongs to the category of inorganic fertilizers whose main components are inorganic compounds, and in particular can be produced using chemically synthesized chemical fertilizers as raw materials.

According to the present invention, there is provided a slow-release granular fertilizer pesticide that does not cause phytotoxicity to plants, that is, a slow-release granular fertilizer formulation containing pesticides that suppresses the precipitation of pesticide components or fertilizer components, and the decomposition and separation of each of the components. can be provided.

Various terms used in this specification will be explained.
In this specification, a numerical range indicated using "~" indicates a range that includes the numerical values written before and after "~" as the minimum and maximum values, respectively. Furthermore, if there are multiple substances corresponding to each component in the composition, the content of each component in the composition means the total amount of the multiple substances present in the composition, unless otherwise specified.

"Pesticides" refers to bacteria, nematodes, mites, insects, rats, and other animals, plants, or viruses (hereinafter referred to as "pests") that harm agricultural crops (including trees and agricultural and forestry products; hereinafter referred to as "crops, etc."). Fungicides, insecticides, and other drugs used for pest control (including materials using such drugs as raw materials or materials used for pest control) and plant growth regulators used to promote or suppress the physiological functions of agricultural crops, etc. There are no particular restrictions on pesticides as long as they are used for agricultural purposes, and any drug can be used, including insecticides, fungicides, and herbicides. It may be. Specific examples of pesticides include aranicarb, aldicarb, bendiocarb, benfuracarb, butocarboxime, butoxycarboxime, NAC (carbaryl), carbofuran, carbosulfan, ethiofencarb, BPMC (fenobucarb), formenate, furathiocarb, MIPC ( Carbamate acetylcholinesterase (AChE) inhibitors such as isoprocarb, methiocarb, methomyl, MTMC (metholcarb), oxamyl, pirimicarb, PHC (propoxur), thiodicarb, thiophanox, triazamate, trimetacarb, XMC, MPMC (xylylcarb), acephate , azamethyphos, azinphos ethyl, azinphos methyl, cassafos, chlorethoxyfos, CVP (chlorfenvinfos), chlormefos, chlorpyrifos, chlorpyrifos methyl, coumafos, CYAP (cyanophos), dimeton-S-methyl, diazinon DDVP (dichlorvos), dicrotofos, dimethoate, dimethyl Vinphos, ethylthiometone (disulfoton), EPN, ethion, ethoprofos, funflu, fenamiphos, MEP (fenitrothion), MPP (fenthion), fosthiazate, heptenophos, imisyafos, isofenphos, isopropyl-o-(methoxyaminothiophosphoryl) salicylate, isoxathion , Marathion (malathion), mecarbam, methamidophos, DMTP (methidathion), mevinphos, monocrotophos, BRP (nared), omethoate, oxydimethone methyl, parathion, methyl parathion (parathion methyl), PAP (phentoate), phorate, phosalone, PMP ( Phosmet), phosphamidone, phoxim, pirimiphos-methyl, profenofos, propetamfos, prothiofos, pyraclofos, pyridafenthion, quinalfos, sulfotep, tebupyrimphos, temefos, terbufos, CVMP (tetrachlorvinphos), thiometone, triazophos, DEP (trichlorfon), bamidothion, and other organic Phosphorous acetylcholinesterase (AChE) inhibitors, chlordane, cyclic diene organochlorine GABAergic chloride channel antagonists such as benzoepine (endosulfan), acrinathrine, allethrin (allethrin, d-cis-trans-, d-trans-isomers) ), bifenthrin, bioallethrin (bioallethrin, S-cyclopentenyl-isomer), bioresmethrin, cycloprothrin, cyfluthrin (cyfluthrin, β-isomer), cyhalothrin (cyhalothrin, λ-, γ-isomer), cypermethrin (cypermethrin, α-, β-, θ-, ζ-isomer), cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [(EZ)-(1R)-isomer], esfenvalerate , etofenprox, fenpropathrin, fenvalerate, flucitrinate, flumethrin, fluvalinate (τ-fluvalinate), halfenprox, imiprothrin, cadethrin, permethrin, phenothrin [(1R)-trans isomer], pralethrin, Pyrethroid and pyrethrin sodium channel modulators such as pyrethrin, resmethrin, cilafluofen, tefluthrin, phtarthrin (tetramethrin), tetramethrin [(1R)-isomer], tralomethrin, transfluthrin, sodium channel modulators such as DDT, methoxychlor, acetamiprid, Neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists such as clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam; nicotinic acetylcholine receptor (nAChR) agonists such as nicotine sulfate (nicotine) and sulfoxaflor; and butenolides such as flupyradifurone. nicotinic acetylcholine receptor (nAChR) agonists, spinosinic nicotinic acetylcholine receptor (nAChR) allosteric modulators such as spinetoram and spinosad, avermectin and milbemycin chloride channel activators such as abamectin, emamectin benzoate, lepimectin, and milbemectin. Juvenile hormone analogs such as beta, hydroprene, quinoprene, methoprene, phenoxycarb, and pyriproxyfen, methyl bromide, alkyl halides other than methyl bromide, chloropicrin, sulfuryl fluoride, borax, and vomit. Non-specific (multisite) inhibitors such as tartar, chordotonal organ modulators such as pymetrozine, flonicamid, mite growth inhibitors such as clofentezine, hexythiazox, diflobidazine, etoxazole, B. t. subsp. israelensis, B. t. subsp. aizawai, B. t. subsp. Kurstaki, B. t. subsp. tenebrionis and B. tenebrionis. t. Proteins contained in crops (Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry34Ab1/Cry35Ab1), insect midgut membrane disrupting agents derived from microorganisms such as Bacillus sphaericus, diafenthiuron, azocyclo Chin, Mitochondrial ATP synthase inhibitors such as tricyclohexyltin hydroxide (cyhexatin), fenbutastin oxide, BPPS (propargite), tetradifon, oxidative phosphorylation uncouplers such as chlorfenapyr, DNOC, sulfuramide, bensultap, cartap, thiocyclam, thiosul nicotinic acetylcholine receptor (nAChR) channel blockers such as TAP sodium salt, bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron , benzoylurea-based chitin biosynthesis inhibitors (type 0) such as teflubenzuron and triflumuron, chitin biosynthesis inhibitors (type 1) such as buprofezin, fly insect molting inhibitors such as cyromazine, chromafenozide, halofenozide, methoxyfenozide, tebufenozide, etc. diacyl-hydrazine ecdysone receptor agonists, octopamine receptor agonists such as amitraz, mitochondrial electron transport chain complex III inhibitors such as hydramethylnon, acequinocyl, fluacrypyrim, fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad , mitochondrial electron transport chain complex I inhibitors (METI) such as tolfenpyrad, Delis (rotenone), voltage-gated sodium channel blockers such as indoxacarb, metaflumizone, and tetrons such as spirodiclofen, spiromesifen, spirotetramat. Acids and tetramic acid derivatives Acetyl-CoA carboxylase inhibitors, phosphine-based mitochondrial electron transport system complex IV inhibitors such as aluminum phosphide, calcium phosphide, hydrogen phosphide, zinc phosphide, cyanide-based mitochondrial electron transport system complexes such as hydrocyanic acid β-ketonitrile derivatives such as cyenopyrafen and cyflumetofen, mitochondrial electron transport chain complex II inhibitors, diamide ryanodine receptor modulators such as chlorantraniliprole, cyantraniliprole, and flubendiamide, Steinernema carpocapsae, Natural enemy insects, mites, and nematode-based organisms such as Chirida mites, Kukumeris kavidrida, Shokugatama fly, Two-spotted stink bug, Black-spotted stink bug, Japanese wasp, Isaea wasp, Coleman oil wasp, Leafminer leafminer wasp, Leafminer leafminer wasp, etc. Pesticides, microbial biopesticides such as Pasteuria penetrans, Bacillus thuringiensis (BT), Monacrosporium phymatopagam, Pecilomyces tenuipes, Beauveria bronniati, Beauveria bassiana, starch, reduced starch saccharide, machine oil, oleic acid spiracle-blocking pesticides such as sodium, pheromone agents such as Konagacon-Plus, Confuser G, Confuser N, Confuser V, Kashibacon, Nitrure (Ameshiro), Hamakicon-N, Feodin SL, Yotokon-H, Yotokon-S, azadirachtin, Benzomate (benzoximate), bifenazate, fenisobromolate (bromopropylate), quinoxalines (quinomethionate), sodium aluminum fluoride, quersene (dicofol), pyridalyl, pyrifluquinazone, sulfur, ferric phosphate, metaldehyde, and an insecticide selected from the group consisting of 1,3-dichloropropene;
Acylalanine-based PA fungicides (phenylamides) such as benalaxyl, benalaxyl M, furaraxyl, metalaxyl, metalaxyl M, oxazolidinone-based PA fungicides (phenylamides) such as oxadixyl, and butyrolactone-based PA fungicides (phenylamides) such as Ofrace. ), hydroxy(2-amino-)pyrimidines such as bupirimate, dimethylimole, ethyrimole, isoxazole aromatic heterocycles such as hydroxyisoxazole (hymexazole), isothiazolone aromatic heterocycles such as octyrinone, oxolinics Carboxylic acids such as acids; benzimidazole-based MBC fungicides (methylbenzimidazole carbamate) such as benomyl, carbendazole (carbendazim), fuberidazole, thiabendazole; thiophanate-based MBC fungicides (methylbenzimidazole carbamate) such as thiophanate and thiophanate-methyl; N-phenyl carbamates such as diethencarb, toluamide benzamides such as zoxamide, ethylaminothiazole carboxamides such as ethaboxam, phenylureas such as pencyclone, pyridinylmethylbenzamide benzamides such as fluopicolide, diflumetrim pyrimidine amines such as tolfenpyrad, phenylbenzamide-based SDHIs (succinate dehydrogenase inhibitors) such as benodanil, flutolanil, and mepronil, phenyloxoethylthiophenamide-based SDHIs (succinate dehydrogenase inhibitors) such as isofetamide, etc. enzyme inhibitors), pyridinylethylbenzamide SDHIs (succinate dehydrogenase inhibitors) such as fluopyram, furancarboxamide SDHIs (succinate dehydrogenase inhibitors) such as fenflam, carboxin, oxycarboxin, etc. Oxathiin carboxamide SDHIs (succinate dehydrogenase inhibitors), thiazole carboxamide SDHIs (succinate dehydrogenase inhibitors) such as thifluzamide, benzobine diflupyr, bixafen, fluxapiroxad, furametopyr, isopyrazam, penflufen, Pyrazole-4-carboxamide SDHIs (succinate dehydrogenase inhibitors) such as penthiopyrad and sedaxane, pyridine carboxamide SDHIs (succinate dehydrogenase inhibitors) such as boscalid, azoxystrobin, coumoxystrobin, and enoki Methoxyacrylate QoI fungicides (Qo inhibitors) such as sustrobin, flufenoxystrobin, picoxystrobin, and pyraoxystrobin; methoxyacetamide QoI fungicides (Qo inhibitors) such as mandestrobin; Methoxycarbamate QoI fungicides (Qo inhibitors) such as clostrobin, pyrametostrobin, and triclopiricarb, oximinoacetic acid QoI fungicides (Qo inhibitors) such as cresoxime methyl and trifloxystrobin, dimoxystrobin, and fena. Oxyiminoacetamide QoI fungicides (Qo inhibitors) such as minstrobin, metominostrobin, orisastrobin, oxazolidinedione QoI fungicides (Qo inhibitors) such as famoxadone, dihydrodioxazine QoI fungicides such as fluoxastrobin (Qo inhibitors), imidazolinone QoI fungicides (Qo inhibitors) such as phenamidon, benzyl carbamate QoI fungicides (Qo inhibitors) such as pyribencarb, cyanoimidazole QiI fungicides (Qi inhibitors) such as cyazofamid. sulfamoyltriazole-based QiI fungicides (Qi inhibitors) such as amisulbrome, dinitrophenylcrotonic acids such as BINAPACRIL, meptyldinocap, and DPC (dinocap), and 2,6-dinitroanilines such as fluazinam. triphenyltin compound-based organotin compounds such as triphenyltin acetate, triphenyltin chloride, and triphenyltin hydroxide; thiophene carboxamides such as silthiopham; triazolopyrimidylamine-based QoSI fungicides (Qo inhibitors) such as ametoctrazine; anilinopyrimidine-based AP fungicides (anilinopyrimidines) such as cyprodinil, mepanipyrim, and pyrimethanil, enopyranuronic acid antibiotics such as blasticidin S, hexopyranosyl antibiotics such as kasugamycin, and glucopyranosyls such as streptomycin. Antibiotics, tetracycline antibiotics such as oxytetracycline, allyloxyquinoline aza-naphthalenes such as quinoxyphene, quinazolinone aza-naphthalenes such as proquinazide, phenylpyrrole-based PP fungicides (phenylpyrroles) such as fenpiclonil and fludioxonil, Dicarboximides such as clozolinate, iprodione, procymidone, vinclozolin, phosphorothiolates such as EDDP (edifenphos), IBP (iprobenfos), and pyrazophos, dithiolanes such as isoprothiolane, biphenyl, chloroneb, CNA (dichlorane), PCNB ( Aromatic hydrocarbon-based AH fungicides (aromatic hydrocarbons, chlorophenyls, nitroanilines) such as quintozene), technazene, tolclofos-methyl, 1,2,4-thiadiazole-based heteroaromatics such as eclomezole (etridiazole), iodocarb , carbamates such as propamocarb and prothiocarb, Bacillus species such as Bacillus subtilis QST713 strain, Bacillus subtilis FZB24 strain, Bacillus subtilis MBI600 strain, and Bacillus subtilis D747 strain, and bactericidal lipopeptide microorganisms produced (Bacillus genus), Gosei Kayupte ( Terpene hydrocarbons and terpene alcohol plant extracts such as tea tree extract, piperazine-based DMI fungicides (demethylation inhibitors, SBI: Class I) such as triforine, pyridine-based fungicides such as pyrifenox and pyrisoxazole. DMI fungicides (demethylation inhibitors, SBI: class I), pyrimidine DMI fungicides (demethylation inhibitors, SBI: class I) such as fenarimol, nuarimol, imazalil, oxpoconazole, pefrazoate, prochloraz, Imidazole DMI fungicides (demethylation inhibitors, SBI: Class I) such as triflumizole, azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fenbuconazole, flu Triazoles such as quinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole DMI fungicides (demethylation inhibitors, SBI: Class I), triazolithione DMI fungicides (demethylation inhibitors, SBI: Class I) such as prothioconazole, aldimorph, dodemorph, fenpropimorph, tridemorph Morpholine amines (morpholines, SBI: Class II) such as morpholines, piperidine amines (morpholines, SBI: Class II) such as fenpropidine and piperaline, spiroketal amines such as spiroxamine ( Morpholines, SBI: Class II), hydroxyanilides such as fenhexamide (SBI: Class III), aminopyrazolinone compounds such as fenpyrazamine (SBI: Class III), thiocarbamates such as pyributicarb (SBI: class IV), allylamines (SBI: class IV) such as naftifine and terbinafine, glucopyranosyl antibiotics such as validamycin, peptidylpyrimidine nucleoside polyoxins such as polyoxine, cinnamic acid amide type CAA fungicides such as dimethomorph, flumorph, and pyrimorph ( valinamide carbamate-based CAA fungicides (carboxylic acid amides) such as bentiavaricarb, iprovaricarb, and variphenarate, mandelic acid amide-based CAA fungicides (carboxylic acid amides) such as mandipropamide, fusaride isobenzofuranone-based MBI-R (melanin biosynthesis inhibitor-reductase) such as, pyrroloquinolinone-based MBI-R (melanin biosynthesis inhibitor-reductase) such as pyroquilone, triazolobenzothiazole-based MBI-R such as tricyclazole. (melanin biosynthesis inhibitor - reductase), cyclopropane carboxamide MBI-D such as carpropamide (melanin biosynthesis inhibitor - dehydratase), carboxamide MBI-D such as diclocimet (melanin biosynthesis inhibitor - dehydratase) , propionamide MBI-D (melanin biosynthesis inhibitor - dehydratase) such as phenoxanil, benzothiadiazoles such as acibenzolar S methyl, benzisothiazoles such as probenazole, thiadiazole carboxamides such as tiazinyl and isotianil, laminarin, etc. Polysaccharide natural products, plant extracts such as Japanese knotweed extract, cyanoacetamidoximes such as cymoxanil, ethylphosphonate phosphonates such as fosetyl, phosphonates such as phosphorous acid and its salts, phthalamic acids such as tecroftalam, triazoxide benzotriazines such as, benzenesulfonamides such as fursulfamide, pyridazinones such as diclomedine, thiocarbamate compounds such as methasulfocarb, phenylacetamide compounds such as cyflufenamide, benzophenone-based allyl phenyl ketone compounds such as metraphenone, benzoyls such as pyriophenone. Pyridine-based allyl phenyl ketone compounds, guanidines such as guanidine (dodine), cyanomethylenethiazolidine-based thiazolidine compounds such as fluthianil, pyrimidinone hydrazones such as felimzone, piperidinylthiazole isoxazolines such as oxathiapiproline, tebufloquine. 4-quinoline acetate compounds such as copper (various salts), inorganic compounds such as sulfur, dithiocarbamates and their analogs such as furbam, mancozeb, maneb, methiram, propineb, thiuram, zineb, ziram, captan, difortan ( phthalimides such as captafol), folpet, chloronitrites (phthalonitriles) such as TPN (chlorothalonil), sulfamides such as sulfenic acids (diclofluanid) and tolylfluanid, guazatine, iminoctadine acetate/iminoctadine albesil Guanidines such as acid salts (iminoctadine), triazines such as triazine (anilazine), quinones (anthraquinones) such as dithianone, quinoxalines such as quinoxalines (quinomethionate), maleimides such as fluorimide, machine oil, organic oil physical inhibitors such as, bicarbonate agents such as potassium bicarbonate, silver agents, 8-hydroxyquinoline copper, organic copper agents such as dodecylbenzenesulfonic acid bisethylenediamine copper complex salt (II), nonylphenolsulfonic acid copper salt, and dazomet. , a fungicide selected from the group consisting of soil disinfectants such as chloropicrin, methylisothiocyanate, carbam sodium salt, ammonium N-methyldithiocarbamate;
Or allyloxypropionate-based acetyl-CoA carboxylase (ACCase) inhibition such as clodinafop propargyl, cyhalofop butyl, diclofop methyl, fenoxaprop P ethyl, fluazifop P, haloxyfop R methyl, propaquizaf, quizalofop P ethyl Cyclohexanedione-based acetyl-CoA carboxylase (ACCase) inhibitors such as alloxydim, butroxydim, clethodim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim, phenylpyrazoline-based acetyl-CoA carboxylase (ACCase) inhibitors such as pinoxaden, amides Sulfuron, azimsulfuron, bensulfuron methyl, chlorimuron ethyl, chlorsulfuron, sinosulfuron, cyclosulfamuron, etamethsulfuron methyl, ethoxysulfuron, frazasulfuron, flupyrsulfuron, foramsulfuron, halosulfuron methyl ,
Imazosulfuron, iodosulfuron, methosulfuron, metsulfuron methyl, nicosulfuron, oxasulfuron, primisulfuron, prosulfuron, pyrazosulfuron ethyl, rimsulfuron, sulfometuron methyl, sulfosulfuron, thifensulfuron methyl, trisulfuron , tribenuron methyl, trifloxysulfuron, triflusulfuron methyl, tritosulfuron, and other sulfonylurea acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), imazapic, imaza Imidazolinone acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors) such as metabenzmethyl, imazamox, imazapyr, imazaquin, imazethapyr (acetohydroxy acid synthase (AHAS) inhibitors), chloransulam methyl, diclosulam, florasulam, flumetulam, metosulam , triazolopyrimidine-based acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors) such as penoxsulam, bispyribac-sodium salt, pyribenzoxime, pyrifthalide, pyrithiobac-sodium salt, pyriminobac-methyl, etc. Sulfonylaminocarbonyltriazolinone acetolactate such as pyrimidinyl (thio)benzoate acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), flucarbazone sodium salt, propoxycarbazone sodium salt, etc. synthetic enzyme (ALS) inhibitor (acetohydroxy acid synthase (AHAS) inhibitor), ametrine, atrazine, cyanazine, desmetrin, dimethamethrin, promethrin, promethrin, propazine series (propazine), CAT (simazine), cymetrine, terbumetone, terbuthylazine , triazine photosynthesis (photosystem II) inhibitors such as terbutryn and trietadine, triazinone photosynthesis (photosystem II) inhibitors such as hexazinone, metamitrone, and metribuzin, triazolinones photosynthesis (photosystem II) inhibitors such as amicarbazone, bromacil , uracil-based photosynthesis (photosystem II) inhibitors such as Renacil and Terbacil, pyridazinone-based photosynthesis (photosystem II) inhibitors such as PAC (chloridazone), and phenylcarbamate-based photosynthesis (photosystem II) inhibitors such as desmedipham and phenmedipham. II) Inhibitors, chlorbromulon, chlorotoluron, chloroxuron, dimefuron, DCMU (diuron), ethidimuron, fenuron, fluometuron, isoproturon, isouron, linuron, metabenzthiazuron, metobromuron, methoxuron, monolinuron, nebulon, ciduron, tebutiuron, etc. urea photosynthesis (photosystem II) inhibitors, amide photosynthesis (photosystem II) inhibitors such as DCPA (propanil) and CMMP (pentanochlor), and nitrile photosynthesis (photosystem II) inhibitors such as bromophenoxime, bromoxynil, and ioxinil. System II) inhibitors, benzothiadiazinone-based photosynthesis (photosystem II) inhibitors such as bentazone, phenylpyridazine-based photosynthesis (photosystem II) inhibitors such as pyridate and pyridafol, bipyridylium-based photosystem I such as diquat and paraquat. Electron conversion agents, diphenyl ether type protoporphyrinogen oxidase (PPO) inhibitors such as acifluorfen, bifenox, chromethoxynil (clomethoxyfene), fluoroglycofenethyl, fomesafen, halosafen, lactofen, oxiflofen, fluazolate, Phenylpyrazole-based protoporphyrinogen oxidase (PPO) inhibitors such as pyraflufenethyl, N-phenylphthalimide-based protoporphyrinogen oxidase (PPO) inhibitors such as cinidon ethyl, flumioxazine, flumicorac pentyl, fluti Thiadiazole protoporphyrinogen oxidase (PPO) inhibitors such as acetomethyl, thidiazimine, oxadiazole protoporphyrinogen oxidase (PPO) inhibitors such as oxadiazone and oxadiargyl, azafenidine, carfentrazone ethyl, sulfur Triazolinone-based protoporphyrinogen oxidase (PPO) inhibitors such as fentrazone, oxazolidinedione-based protoporphyrinogen oxidase (PPO) inhibitors such as pentoxazone, pyrimidinedione-based protoporphyrinogens such as benzfendizone, butafenacil, etc. Rinogen oxidase (PPO) inhibitors, protoporphyrinogen oxidase (PPO) inhibitors such as pyraclonil, profluazole, flufenpylethyl, and carotenoids in the pyridazinone phytoene desaturase system (PDS) such as norflurazone. Carotenoid biosynthesis inhibitors, phytoene desaturase system (PDS) such as beflubutamide, fluridone, flurochloridone, flurutamone, etc. Carotenoid biosynthesis inhibitors, triketone-based 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) enzyme (4-HPPD) inhibitors such as mesotrione and sulcotrione, and isoxazole-based 4-hydroxyphenylpyruvin such as isoxachlortole and isoxaflutole. Acid dioxygenase enzyme (4-HPPD) inhibitors, pyrazole-based 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors such as benzofenap, pyrazolinate (pyrazolinate), pyrazoxifene, 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors such as benzobiciclones, etc. Hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors, triazole carotenoid biosynthesis (target site unknown) inhibitors such as ATA (amitrole), isoxazolidinone carotenoid biosynthesis (target site unknown) inhibitors such as clomazone , urea-based carotenoid biosynthesis (target site unknown) inhibitors such as fluometuron, diphenyl ether-based carotenoid biosynthesis (target site unknown) inhibitors such as aclonifen, glycine-based EPSP synthase inhibitors such as glyphosate, glyphosate trimesium salt (sulfosate), etc. glufosinate, phosphinic acid-based glutamine synthetase inhibitors such as Bialafos (Vilanafos), carbamate-based DHP (dihydropteroic acid) synthase inhibitors such as Ashram, beslozin (benfluralin), butrualine, dinitramine, etalfluralin, oryzalin , dinitroaniline microtubule polymerization inhibitors such as pendimethalin and trifluralin, phosphoramidate microtubule polymerization inhibitors such as amiprophos-methyl and butamiphos, pyridine microtubule polymerization inhibitors such as dithiopyr and thiazopyr, propyzamide , benzamide-based microtubule polymerization inhibitors such as Tebutam, benzoic acid-based microtubule polymerization inhibitors such as TCTP (chlortal dimethyl), carbamate-based mitosis/microtubule formation such as IPC (chlorpropham), profam, and carbetamide. Inhibitors, chloroacetamide VLCFA inhibitors (cell division inhibitors) such as acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, metazachlor, metolachlor, petoxamide, pretilachlor, propachlor, propisochlor, tenylchlor, etc., diphenamide , acetamide VLCFA inhibitors (cell division inhibitors) such as napropamide and naproanilide, oxyacetamide VLCFA inhibitors (cell division inhibitors) such as flufenacet and mefenacet, and tetrazolinone VLCFA inhibitors such as fentrazamide ( cell division inhibitors), VLCFA inhibitors (cell division inhibitors) such as anilofos, cafenstrol, and piperofos, nitrile cell wall (cellulose) synthesis inhibitors such as DBN (diclobenil), and DCBN (chlorthiamide), benzamides such as isoxaben Cell wall (cellulose) synthesis inhibitors, triazolocarboxamide cell wall (cellulose) synthesis inhibitors such as flupoxam, quinolinecarboxylic acid cell wall (cellulose) synthesis inhibitors such as quinclorac, dinitrates such as DNOC, DNBP (dinoseb), and dinoterb. Phenolic uncoupling (membrane breaking) agents, butyrate, hexylthiocarbam (cycloate), dimepiperate, EPTC, esprocarb, molinate, olbencarb, pebrate, prosulfocarb, bentiocarb (thiobencarb), thiocarbasil, trialate, vernalate, etc. thiocarbamate-based lipid synthesis inhibitors (non-ACCase inhibitors), phosphorodithioate-based lipid synthesis inhibitors (non-ACCase inhibitors) such as SAP (bensuride), benzofuran-based lipid synthesis inhibitors (non-ACCase inhibitors) such as benfuresate and etofumesate agents, chlorocarbonate-based lipid synthesis inhibitors (non-ACCase inhibitors) such as TCA, DPA (Darapon), and tetrapion (flupropanate), clomeprop, 2,4-PA (2,4-D), 2,4-DB , phenoxycarboxylic acid-based indoleacetic acid-like active (synthetic auxin) agents such as dichlorprop, MCPA, MCPB, and MCPP (mecoprop), benzoic acids such as chloramben, MDBA (dicamba), and TCBA (2,3,6-TBA) Pyridine carboxylic acid-based indole acetic acid-like active (synthetic auxin) agents such as clopyralid, fluoroxypyr, picloram, and triclopyr, quinoline carboxylic acid-based indole acetic acid-like active (synthetic auxin) agents such as quinclorac and quinmerac Synthetic auxin) agents, indole acetic acid-like active (synthetic auxin) agents such as benazoline ethyl, phthalate auxin transfer inhibitors such as NPA (naptalam), semicarbazone auxin transfer inhibitors such as diflufenzopyr-sodium salt, Furanprop M Arylaminopropionic acid compounds such as methyl/isopropyl, pyrazolium compounds such as dipenzocort, organic arsenic compounds such as DSMA and MSMA, microorganisms such as Xanthomonas campestris, bromobutide, (chlor)-flurenol, synmethylin, cumyluron, Mention may be made of herbicides selected from the group consisting of dazomet, dimeron, methyldimeron, etobenzanide, fosamine, indanophane, carbam/carbam sodium salt, oxadiclomefon, oleic acid, pelargonic acid, pyributicarb, chlorates as well as cyanates. can.

Among them, the pesticides include carbamate-based acetylcholinesterase (AChE) inhibitors, organophosphorus-based acetylcholinesterase (AChE) inhibitors, phenylpyrazole-based (fiprole-based) GABAergic chloride channel antagonists, pyrethroid and pyrethrin-based sodium channel modulators, Neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, spinosyn nicotinic acetylcholine receptor (nAChR) allosteric modulators, avermectin and milbemycin chloride channel activators, chordotonal organ modulators, oxidative phosphorylation uncouplers, Mitochondrial electron transport chain complex III inhibitor, mitochondrial electron transport chain complex I inhibitor (METI), voltage-dependent sodium channel blocker, tetronic acid and tetramic acid derivative acetyl-CoA carboxylase inhibitor, diamide-based ryanodine receptor modulator, quinoxaline insecticides selected from the group consisting of (chinomethionates) and pyridalyl and metaldehydes;
Or acylalanine-based PA fungicides (phenylamides), oxazolidinone-based PA fungicides (phenylamides), butyrolactone-based PA fungicides (phenylamides), isoxazole-based aromatic heterocycles, benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), N-phenyl carbamates, phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furancarboxamide-based SDHI (succinate dehydrogenase inhibitor), oxathiin carboxamide-based SDHI (succinate dehydrogenase inhibitor), thiazole carboxamide-based SDHI (succinate dehydrogenase inhibitor) (inhibitor), pyrazole-4-carboxamide-based SDHI (succinate dehydrogenase inhibitor), pyridine carboxamide-based SDHI (succinate dehydrogenase inhibitor), methoxyacrylate-based QoI fungicide (Qo inhibitor), methoxyacetamide-based SDHI QoI fungicides (Qo inhibitors), methoxycarbamate-based QoI fungicides (Qo inhibitors), oximinoacetic acid-based QoI fungicides (Qo inhibitors), oxyiminoacetamide-based QoI fungicides (Qo inhibitors), oxazolidinedione-based QoI Fungicides (Qo inhibitors), dihydrodioxazine QoI fungicides (Qo inhibitors), imidazolinone QoI fungicides (Qo inhibitors), benzyl carbamate QoI fungicides (Qo inhibitors), cyanoimidazole QiI fungicides (Qi inhibitors), sulfamoyltriazole-based QiI fungicides (Qi inhibitors), 2,6-dinitroanilines, anilinopyrimidine-based AP fungicides (anilinopyrimidines), phenylpyrrole-based PP fungicides ( phenylpyrroles), dicarboximides, piperazine-based DMI fungicides (demethylation inhibitors, SBI: Class I), pyridine-based DMI fungicides (demethylation inhibitors, SBI: Class I), pyrimidine-based DMI fungicides (demethylation inhibitor, SBI: Class I), imidazole DMI fungicide (demethylation inhibitor, SBI: Class I), triazole DMI fungicide (demethylation inhibitor, SBI: Class I), Triazolinthione DMI fungicide (demethylation inhibitor, SBI: Class I), isobenzofuranone MBI-R (melanin biosynthesis inhibitor - reductase), pyrroloquinolinone MBI-R (melanin biosynthesis inhibitor - reductase), triazolobenzothiazole MBI-R (melanin biosynthesis inhibitor - reductase), cyclopropane carboxamide MBI-D (melanin biosynthesis inhibitor - dehydratase), carboxamide MBI-D (melanin biosynthesis inhibitor) inhibitor - dehydratase), propionamide MBI-D (melanin biosynthesis inhibitor - dehydratase), benzothiadiazoles, benzisothiazoles, thiadiazole carboxamides, cyanoacetamide oximes, benzenesulfonamides, pyridazinones, Bactericidal agents selected from the group consisting of guanidines and quinoxalines are preferred.

Pesticides include carbamate acetylcholinesterase (AChE) inhibitors, organophosphate acetylcholinesterase (AChE) inhibitors, phenylpyrazole (fiprole) GABAergic chloride channel antagonists, pyrethroid and pyrethrin sodium channel modulators, Insecticides selected from the group consisting of nicotinoid nicotinic acetylcholine receptor (nAChR) agonists, oxidative phosphorylation uncouplers, avermectin and milbemycin chloride channel activators, chordophonic organ modulators, and diamide ryanodine receptor modulators. agent;
or isoxazole-based aromatic heterocycles, benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), phenylbenzamide-based SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide-based SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide-based SDHI (succinate dehydrogenase inhibitor), furancarboxamide-based SDHI (succinate dehydrogenase inhibitor), oxathiincarboxamide-based SDHI (succinate dehydrogenase inhibitor) , thiazole carboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridine carboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI disinfection (Qo inhibitor), methoxyacetamide-based QoI fungicide (Qo inhibitor), methoxycarbamate-based QoI fungicide (Qo inhibitor), oximinoacetic acid-based QoI fungicide (Qo inhibitor), oxyiminoacetamide-based QoI fungicide (Qo inhibitor), oxazolidinedione QoI fungicide (Qo inhibitor), dihydrodioxazine QoI fungicide (Qo inhibitor), imidazolinone QoI fungicide (Qo inhibitor), benzyl carbamate QoI fungicide ( Qo inhibitor), piperazine-based DMI fungicide (demethylation inhibitor, SBI: Class I), pyridine-based DMI fungicide (demethylation inhibitor, SBI: Class I), pyrimidine-based DMI fungicide (demethylation inhibitor, SBI: Class I), inhibitor, SBI: Class I), imidazole-based DMI fungicide (demethylation inhibitor, SBI: Class I), triazole-based DMI fungicide (demethylation inhibitor, SBI: Class I), and triazolithiones A fungicide selected from the group consisting of DMI fungicides (demethylation inhibitors, SBI: class I) and the like are preferred.

Examples of specific pesticides include aldicarb, bendiocarb, butocarboxime, butoxycarboxime, NAC (carbaryl), carbofuran, ethiofencarb, BPMC (fenobucarb), formenate, MIPC (isoprocarb), methomyl, MTMC (metolcarb). ), oxamyl, pirimicarb, PHC (propoxur), thiophanox, triazamate, XMC, MPMC (xylylcarb), acephate, azamethyphos, casusafos, CVP (chlorfenvinphos), dimethone-S-methyl, DDVP (dichlorvos), dicrotofos , dimethoate, dimethylvinphos, ethoprofos, fenamiphos, fosthiazate, heptenophos, marathon (malathion), mecarbam, methamidophos, DMTP (methidathion), mevinphos, monocrotophos, omethoate, oxydimethone methyl, phosphamidone, propetamphos, thiometone, DEP (trichlorfon) , vamidothione, flumethrin, fipronil, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, nicotine sulfate (nicotine), sulfoxaflor, flupyradifurone, pyriproxyfen, methyl bromide, chlorpicrin, sulfuryl fluoride, boron Sand, tartarite, pymetrozine, flonicamid, BPPS (propargite), DNOC, cartap, thiocyclam, thiosultap sodium salt, cyromazine, hydrogen phosphide, hydrocyanic acid, azadirachtin, sodium aluminum fluoride, 1,3-dichloropropene, dicyclanil , ethylene dibromide, Sabadilla and Surcofuron sodium;
and furaraxyl, metalaxyl, metalaxyl M, oxadixyl, ofrace, dimethylimole, hydroxyisoxazole (hymexazole), octylinone, fenflam, carboxin, oxycarboxin, furametopyr, metominostrobin, cyazofamid, pyrimethanil, kasugamycin, streptomycin, IBP (iprobenfoss). ), eclomezole (etridiazole), propamocarb, prothiocarb, pyrifenox, imazalil, pefrazoate, triflumizole, flutriafol, myclobutanil, propiconazole, tetraconazole, fenpropidine, spiroxamine, validamycin, polyoxin, iprovaricarb, pyroquilone , cymoxanil, fosetyl, phosphorous acid and salts, fursulfamide, metasulfocarb, guanidine (dodine), felimzone, potassium bicarbonate, furbam, guazatine, iminoctadine acetate/iminoctadine albesilate (iminoctadine), copper sulfate, formaldehyde, A fungicide selected from the group consisting of 8-hydroxyquinoline sulfate, iodomethane, mercuric chloride, metham, methyl bromide, methyl isothiocyanate, mildiomycin, nabam, phenylmercuric acetate, 2-phenylphenol and poloxin. It is desirable to contain at least one selected from the group consisting of:
Among these, the pesticide preferably contains at least one selected from the group consisting of, for example, acephate, fipronil, acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam, nitenpyram, and flonicamid, and more preferably, for example, acetamiprid, It contains at least one member selected from the group consisting of imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, more preferably at least one member selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran and thiamethoxam. It is particularly preferable to contain seeds such as dinotefuran.

"Fertilizer" is defined in Japan's Fertilizer Control Law as "a substance applied to land for the purpose of providing plant nutrition or bringing about a chemical change in the soil to contribute to plant cultivation." "Things applied to plants for the purpose of providing nutrients to them."

The official standards established based on the Fertilizer Control Law include nitrogen fertilizers, phosphate fertilizers, potassium fertilizers, organic fertilizers, compound fertilizers, calcareous fertilizers, silicic acid fertilizers, magnesium fertilizers, manganese fertilizers, and boron fertilizers. , trace element compound fertilizers, sludge fertilizers, etc. are classified as fertilizers in which pesticides and other substances are mixed. In terms of fertilizer effects, fertilizers can be classified into fast-release fertilizers and slow-release fertilizers.

"Particulate" as used herein means that the solid substance has a certain size.
The term "slow-release fertilizer" as used herein is a general term for fertilizers whose fertilizing effect appears slowly, and has the feature that the fertilizer components gradually dissolve after fertilization and the fertilizing effect lasts for a long period of time. Specifically, for example,
(1) Nitrogen fertilizer, phosphate fertilizer, potassium fertilizer, organic fertilizer, compound fertilizer, calcareous fertilizer, silicic acid fertilizer (limited to silica gel fertilizer), magnesium fertilizer, manganese fertilizer, boron fertilizer, trace amount A slow-release fertilizer that is granulated or molded by blending two or more of fertilizers mixed with pesticides or other substances, such as elemental compound fertilizers, sludge fertilizers, etc. (hereinafter referred to as "slow-release compound fertilizers");
(2) A slow-release fertilizer that is manufactured by chemically manipulating fertilizer or fertilizer raw materials among compound fertilizers. For example, those based on formaldehyde-processed urea fertilizer, isobutyraldehyde condensed urea fertilizer, magnesium ammonium phosphate, etc. (hereinafter referred to as "chemically synthesized slow-release fertilizer");
(3) Slow-release coated fertilizers such as coated nitrogen fertilizers, coated phosphate fertilizers, coated potassium fertilizers, coated compound fertilizers, coated magnesia fertilizers;
(4) Slow-release pressure-molded fertilizers such as tablet fertilizers in which the elution of ingredients is controlled by pressure-molding; and (5) Slow-release nitrification inhibitor-containing fertilizers containing nitrification inhibitors. Of these, chemically synthesized slow-release fertilizers are preferred.

Therefore, "slow-release granular fertilizer" means the above-mentioned slow-release fertilizer that is in the form of granules, and the quality and quantity of the fertilizer is uniform no matter where it is taken, and there is no variation in the effect of the fertilizer. Not meant solid fertilizer. Specifically, it means a slow-release blended granular fertilizer, a chemically synthesized slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressure-molded granular fertilizer, a slow-release nitrification inhibitor-blended fertilizer, and the like. "Pesticide-containing slow-release granular fertilizer formulation" means a formulation of the above-mentioned "slow-release granular fertilizer" that contains pesticide ingredients, and the quality and quantity of all parts of the formulation are uniform. It means a solid fertilizer formulation that has the same effect as fertilizers and pesticides. This slow-release granular fertilizer formulation containing pesticides may be granulated by chemical operations, granulated by a granulator, pellets, tablets, or coated with resin, etc. I can list things like that.

The particle size of the pesticide-containing slow-release granular fertilizer formulation of the present invention may be, for example, from 0.1 mm to 50.0 mm, preferably less than 10 mm, and more preferably less than 2 mm. Note that the particle size can be measured using a particle size distribution measuring device or the like.

The weight ratio of nitrogen (N), phosphorus (P), and potassium (K), which are guaranteed ingredients for a slow-release granular fertilizer formulation containing pesticides, may be any weight ratio as long as it functions as a slow-release fertilizer. Although there is no particular restriction, the weight ratio of N:P:K may be, for example, 1:1:1 (for example, 5:5:5, 6:6:6, 7:7:7, 8:8:8, 10: 10:10, etc.), the weight ratio of N:P:K is, for example, 1:2:1 (for example, 5:10:5), 1.2:2:1 (for example, 6:10: 5, etc.), 1:3:2 (e.g. 3:9:6, etc.), 2:3:1 (e.g. 4:6:2, etc.), which has a high weight ratio of P to N and K. The weight ratio of the components N:P:K is, for example, 2:1:2 (for example, 4:2:4, etc.), 2:1:3 (for example, 4:2:6, etc.), 3:1:2 (for example, A valley-shaped guaranteed component with a low weight ratio of P to N and K such as 6:2:4, etc., and a valley-shaped guaranteed component with a low weight ratio of P to N and K such as ), a descending guaranteed component in which the weight ratio of N is high with respect to P and K, such as 3:2:1 (for example, 9:6:3), and the weight ratio of N:P:K is, for example, 1:1: 2 (for example, 3:3:6, etc.), 1:2:3 (for example, 3:6:9, etc.), etc. to specifically exemplify an upward type guaranteed component in which the weight ratio of K is high with respect to N and P. I can do it.

Furthermore, the weight ratios of each N, P, and K are nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), and calcium. (Ca) and sulfur (S), or a formulation containing one or more fertilizer components selected from the group consisting of nitrogen (N), phosphorus (P), and potassium (K). As long as the formulation contains at least two types of fertilizer components, either one may be zero.

Particular preference is given to solid or granular fertilizer-pesticide formulations in which the N:P:K weight ratio is 6:40:6 (3:20:3) or 8:20:8 (2:5:2).
The weight ratio of the guaranteed ingredients is a value indicating the minimum proportion of nitrogen (N), phosphorus (P), and potassium (K) contained in a given fertilizer, and is limited to that value. It is not something that will be done. Therefore, a fertilizer whose weight ratio is equal to or higher than the above value is qualified as a fertilizer, and the fertilizer is also included in the pesticide-containing slow-release granular fertilizer formulation of the present invention.

"Liquid or liquid fertilizer" indicates that the fertilizer is liquid or that the fertilizer is in a liquid state. Although there is essentially no difference between the two, liquid fertilizers include, for example, liquid potassium silicate fertilizer, liquid trace element compound fertilizer, liquid by-product nitrogen fertilizer, liquid phosphate fertilizer, etc. Examples include liquid nitrogen fertilizer and liquid compound fertilizer.
As the fertilizer used as the main component of the pesticide-containing slow-release granular fertilizer of the present invention, a commercially available slow-release granular fertilizer can be used, or a fertilizer manufactured according to the method described in Patent Document 1 can be used. can.

The "non-petroleum solvent" of the present invention is a solvent having a functional group in its structure, for example, a solvent containing a hydroxyl group, a carboxyl group, an aldehyde group, etc. Among them, from the viewpoint of workability or safety, A non-petroleum solvent with a flash point of 40° C. or higher is preferred. For example, ether solvents, nitrile solvents, alcohols, alcohol solvents such as polyhydric alcohols, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, and amines. Examples include solvents based on solvents, aldehyde solvents, fatty acid ester solvents, nitrogen-containing carrier solvents, and glycol ether solvents.

Specific non-petroleum solvents are not particularly limited as long as they are miscible with water to some extent, for example, solvents with water solubility of 100 ppm or more; examples include ether solvents such as tetrahydrofuran and 1,4-dioxane; acetonitrile; Nitrile solvents such as propionitrile, butyronitrile, isobutyronitrile, malononitrile; methanol, ethanol, propanol, isopropanol, 1-butanol, 2-butanol, isobutanol, t-butanol, allyl alcohol, ethylene glycol, 1,2 - Alcohol solvents such as propanediol (propylene glycol), 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, glycerin; acetone, methyl ethyl ketone, diethyl ketone, etc. Ketone solvents; carbonate solvents such as dimethyl carbonate, diethyl carbonate, ethylene carbonate, propylene carbonate; ester solvents such as methyl formate, ethyl formate, methyl acetate, ethyl acetate, γ-butyrolactone, methyl lactate, ethyl lactate; Amide solvents such as formamide, N,N-dimethylformamide, N,N-diethylformamide, N,N-dimethylacetamide, N,N-diethylacetamide, N,N-dimethylpropionamide, N,N-dimethyllactamide, etc. ; Carbamide solvents such as tetramethylurea and 1,3-dimethyl-2-imidazolidinone; Sulfoxide solvents such as dimethyl sulfoxide; Sulfone solvents such as dimethylsulfone and sulfolane; Ammonia, methylamine, dimethylamine, diethylamine, Amine solvents such as triethylamine, isopropylamine, diisopropylamine, ethyldiisopropylamine, pyrrolidine, N-methylpyrrolidine, piperidine, N-methylpiperidine, morpholine, N-methylmorpholine, pyridine, ethanolamine; formaldehyde, acetaldehyde, propion Aldehyde solvents such as aldehyde, butanal, and pentanal; Fatty acid ester solvents such as coconut oil fatty acid methyl ester, dimethyl succinate, dimethyl glutamate, and dimethyl adipate; Nitrogen-containing solvents such as N-methylpyrrolidone and N-ethylpyrrolidone. Examples include carrier-based solvents.

"Glycol ether" means a compound in which one or both of the hydroxyl groups of a diol or its condensate is etherified, such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, and ethylene glycol monoisopropyl ether. , ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol mono t-butyl ether, ethylene glycol mono 2-methylpentyl ether, ethylene glycol monohexyl ether, ethylene glycol mono 2-ethyl-hexyl ether, ethylene glycol monovinyl ether, ethylene Glycol monoallyl ether, ethylene glycol monobenzyl ether, ethylene glycol monophenyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monobutyl ether, diethylene glycol Monoisobutyl ether, diethylene glycol monohexyl ether, diethylene glycol mono2-ethylhexyl ether, diethylene glycol monoallyl ether, diethylene glycol monobenzyl ether, diethylene glycol monophenyl ether, diethylene glycol mono(methylphenyl) ether, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether , diethylene glycol dibutyl ether, diethylene glycol divinyl ether, diethylene glycol ethyl vinyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, triethylene glycol monovinyl ether, triethylene glycol dimethyl ether, tetraethylene glycol monophenyl ether, Tetraethylene glycol diethyl ether, polyethylene glycol monomethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monoisopropyl ether, propylene glycol monobutyl ether, propylene glycol phenyl ether, propylene glycol mono(methylphenyl) ) ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol dipropyl ether, propylene glycol diisopropyl ether, propylene glycol dibutyl ether, propylene glycol diisobutyl ether, propylene glycol diallyl ether, propylene glycol diphenyl ether, dipropylene glycol monomethyl ether, dipropylene Glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol dibutyl ether, dipropylene glycol diisobutyl ether, dipropylene glycol allyl ether, tripropylene glycol Monomethyl ether, tripropylene glycol monoethyl ether, tripropylene glycol monobutyl ether, butylene glycol monomethyl ether, butylene glycol dimethyl ether, isopropyl glycol, diisopropyl glycol, dimethyl diglycol, methyl ethyl diglycol, 3-methoxy-3-methyl-1- Examples include butanol, and the pesticide-containing slow-release granular fertilizer formulation of the present invention preferably contains at least one glycol ether selected from the group consisting of these.

Among them, suitable glycol ethers include, for example, ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol monoallyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monobenzyl ether, propylene glycol monopropyl ether, isopropyl glycol, Examples include isopropyl diglycol, dimethyl diglycol, methyl ethyl diglycol, or 3-methoxy-3-methyl-1-butanol, and the pesticide-containing slow-release granular fertilizer formulation of the present invention is selected from the group consisting of these. It is preferable to contain at least one kind. The most preferred slow-release granular fertilizer formulation containing pesticides of the present invention contains 3-methoxy-3-methyl-1-butanol as the glycol ether.

"Water" means, for example, purified water, distilled water, ion-exchanged water, pure water, ultrapure water, sterilized water, filtered water, etc., and is not particularly limited, and any water can be used. In addition to the above-mentioned water, agricultural water, industrial water, well water, tap water, etc. can be used as long as they do not impede the function and performance of the pesticide-containing slow-release granular fertilizer formulation.

Next, a method for producing the pesticide-containing slow-release granular fertilizer formulation of the present invention will be explained.
Slow-release granular fertilizer formulations containing pesticides, for example, include pesticides (hereinafter also referred to as "pesticides ingredients") in one or more non-petroleum solvents or a mixed solution of one or more non-petroleum solvents and water. It can be produced by dissolving it using a known method and impregnating slow-release granular fertilizer with the solution. If necessary, fertilizer (hereinafter also referred to as "fertilizer component"), surfactant, and other compounded components may be mixed into the solution and then manufactured by impregnating the solution.

The order in which agricultural chemicals are dissolved in one or more non-petroleum solvents is not particularly limited, and can be appropriately selected depending on the properties of each component. There is no particular restriction on the form of the agricultural chemical component used as a raw material, and it may be in a solid state or a liquid state.

Pesticide components added to one or more non-petroleum solvents are heated or heated as appropriate, and stirred as appropriate to dissolve each component, and if insoluble matter is present, as necessary, for example, through a microfiltration membrane. By performing filtration treatment using ultrafiltration membranes, reverse osmosis membranes, etc., and impregnating the filtered solution with slow-release fertilizer, it is possible to produce the desired pesticide-containing slow-release granular fertilizer formulation. can. Although any filtration method can be used, it is usually advantageous to use a filter of about 1 μm. The temperature at which the pesticide-containing slow-release granular fertilizer preparation is prepared is not particularly limited, but it can be prepared at room temperature, under heating, or under heating. The temperature of the mixed solution during preparation is 0°C to the boiling point of the solvent, preferably 25°C to 80°C, particularly preferably 40°C to 75°C.

In order to stably produce the pesticide-containing slow-release granular fertilizer formulation of the present invention, it is necessary to contain one or more non-petroleum solvents or a mixture of one or more non-petroleum solvents and water prepared in advance, and the pesticide. A manufacturing method in which a slow-release fertilizer is impregnated with an aqueous composition is desirable.
Therefore, an aqueous composition containing one or more non-petroleum solvents, a mixture of one or more non-petroleum solvents and water, and a pesticide (hereinafter, this aqueous composition may be referred to as a "premix"). is useful as a raw material for producing the pesticide-containing slow-release granular fertilizer formulation of the present invention.

A premix containing a pesticide component can be produced by dissolving the pesticide described in paragraph numbers [0038] to [0041] in a non-petroleum solvent.
Preferable premixes containing pesticide components include glycol ether as a non-petroleum solvent, preferably ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol monoallyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, At least one member selected from the group consisting of diethylene glycol monobenzyl ether, propylene glycol monopropyl ether, isopropyl glycol, diisopropyl glycol, dimethyl diglycol, methyl ethyl diglycol, and 3-methoxy-3-methyl-1-butanol, more preferably The glycol ether contains 3-methoxy-3-methyl-1-butanol, and at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram as a pesticide. , more preferably a premix containing dinotefuran. Note that the premix containing the pesticide component can be impregnated into a slow-release fertilizer by adding water and/or liquid or liquid fertilizer as appropriate.

Examples of premixes containing glycol ether, pesticide, and water include dinotefuran-ethylene glycol monoisopropyl ether-aqueous solution, dinotefuran-ethylene glycol monobutyl ether-aqueous solution, dinotefuran-ethylene glycol monoisobutyl ether-aqueous solution, dinotefuran-ethylene glycol monoisobutyl ether-aqueous solution, Allyl ether - aqueous solution, dinotefuran - diethylene glycol monomethyl ether - aqueous solution, dinotefuran - diethylene glycol monoisopropyl ether - aqueous solution, dinotefuran - diethylene glycol monobutyl ether - aqueous solution, dinotefuran - diethylene glycol monoisobutyl ether - aqueous solution, dinotefuran - diethylene glycol monobenzyl ether - aqueous solution, dinotefuran - Diethylene glycol dimethyl ether - aqueous solution, dinotefuran - diethylene glycol diethyl ether - aqueous solution, dinotefuran - diethylene glycol methyl ethyl ether - aqueous solution, dinotefuran - triethylene glycol monomethyl ether - aqueous solution, dinotefuran - triethylene glycol monobutyl ether - aqueous solution, dinotefuran - triethylene glycol dimethyl ether - aqueous solution , dinotefuran - polyethylene glycol monomethyl ether - aqueous solution, dinotefuran - propylene glycol monomethyl ether - aqueous solution, dinotefuran - propylene glycol monomethyl ether - aqueous solution, dinotefuran - dipropylene glycol monomethyl ether - aqueous solution, dinotefuran - tripropylene glycol monomethyl ether - aqueous solution, dinotefuran - polyethylene glycol monomethyl ether - aqueous solution -3-methoxy-3-methyl-1-butanol - aqueous solution, imidacloprid - ethylene glycol monoisopropyl ether - aqueous solution, imidacloprid - ethylene glycol monobutyl ether - aqueous solution, imidacloprid - ethylene glycol monoisobutyl ether - aqueous solution, imidacloprid - ethylene glycol monoallyl Ether -aqueous solution, imidacropride, dysleny -rengolicol monomethyl ether -aqueous solution, imidacropride -dyethylene glycol monoisopyl ether -aqueous solution, imidaclopride -died rangicolicol monobutyl ether -aqueous solution Dietholen Glycol Monoisobutyl ether -aqueous solution, imidacropride, eeticular ring recall monobenzyl ether -aqueous solution, imidaclopride dyethralenralicol dimethyl ether - aqueous solution, imidacloprid - diethylene glycol diethyl ether - aqueous solution, imidacloprid - diethylene glycol methyl ethyl ether - aqueous solution, imidacloprid - triethylene glycol monomethyl ether - aqueous solution, imidacloprid - triethylene glycol monobutyl ether - aqueous solution, imidacloprid - triethylene glycol dimethyl ether - aqueous solution, Imidacloprid - polyethylene glycol monomethyl ether - aqueous solution, imidacloprid - propylene glycol monomethyl ether - aqueous solution, imidacloprid - propylene glycol monopropyl ether - aqueous solution, imidacloprid - dipropylene glycol monomethyl ether - aqueous solution, imidacloprid - tripropylene glycol monomethyl ether - aqueous solution, imidacloprid - 3-methoxy-3-methyl-1-butanol-aqueous solution,
Clothianidin - ethylene glycol monoisopropyl ether - aqueous solution, clothianidin - ethylene glycol monobutyl ether - aqueous solution, clothianidin - ethylene glycol monoisobutyl ether - aqueous solution, clothianidin - ethylene glycol monoallyl ether - aqueous solution, clothianidin - diethylene glycol monomethyl ether - aqueous solution, clothianidin - diethylene glycol - aqueous solution Monoisopropyl ether - aqueous solution, clothianidin - diethylene glycol monobutyl ether - aqueous solution, clothianidin - diethylene glycol monoisobutyl ether - aqueous solution, clothianidin - diethylene glycol monobenzyl ether - aqueous solution, clothianidin - diethylene glycol dimethyl ether - aqueous solution, clothianidin - diethylene glycol diethyl ether - aqueous solution, clothianidin - diethylene glycol Methyl ethyl ether - aqueous solution, clothianidin - triethylene glycol monomethyl ether - aqueous solution, clothianidin - triethylene glycol monobutyl ether - aqueous solution, clothianidin - triethylene glycol dimethyl ether - aqueous solution, clothianidin - polyethylene glycol monomethyl ether - aqueous solution, clothianidin - propylene glycol monomethyl ether - aqueous solution -Aqueous solution, clothianidin-propylene glycol monopropyl ether-aqueous solution, clothianidin-dipropylene glycol monomethyl ether-aqueous solution, clothianidin-tripropylene glycol monomethyl ether-aqueous solution, clothianidin-3-methoxy-3-methyl-1-butanol-aqueous solution,
Thiamethoxam - ethylene glycol monoisopropyl ether - aqueous solution, thiamethoxam - ethylene glycol monobutyl ether - aqueous solution, thiamethoxam - ethylene glycol monoisobutyl ether - aqueous solution, thiamethoxam - ethylene glycol monoallyl ether - aqueous solution, thiamethoxam - diethylene glycol monomethyl ether - aqueous solution, thiamethoxam - diethylene glycol Monoisopropyl ether - aqueous solution, thiamethoxam - diethylene glycol monobutyl ether - aqueous solution, thiamethoxam - diethylene glycol monoisobutyl ether - aqueous solution, thiamethoxam - diethylene glycol monobenzyl ether - aqueous solution, thiamethoxam - diethylene glycol dimethyl ether - aqueous solution, thiamethoxam - diethylene glycol diethyl ether - aqueous solution, thiamethoxam - diethylene glycol Methyl ethyl ether - aqueous solution, thiamethoxam - triethylene glycol monomethyl ether - aqueous solution, thiamethoxam - triethylene glycol monobutyl ether - aqueous solution, thiamethoxam - triethylene glycol dimethyl ether - aqueous solution, thiamethoxam - polyethylene glycol monomethyl ether - aqueous solution, thiamethoxam - propylene glycol monomethyl ether - aqueous solution - aqueous solution, thiamethoxam - propylene glycol monopropyl ether - aqueous solution, thiamethoxam - dipropylene glycol monomethyl ether - aqueous solution, thiamethoxam - tripropylene glycol monomethyl ether - aqueous solution, thiamethoxam - 3-methoxy-3-methyl-1-butanol - aqueous solution,
Acetamiprid - ethylene glycol monoisopropyl ether - aqueous solution, acetamiprid - ethylene glycol monobutyl ether - aqueous solution, acetamiprid - ethylene glycol monoisobutyl ether - aqueous solution, acetamiprid - ethylene glycol monoallyl ether - aqueous solution, acetamiprid - diethylene glycol monomethyl ether - aqueous solution, acetamiprid - diethylene glycol Monoisopropyl ether - aqueous solution, acetamiprid - diethylene glycol monobutyl ether - aqueous solution, acetamiprid - diethylene glycol monoisobutyl ether - aqueous solution, acetamiprid - diethylene glycol monobenzyl ether - aqueous solution, acetamiprid - diethylene glycol dimethyl ether - aqueous solution, acetamiprid - diethylene glycol diethyl ether - aqueous solution, acetamiprid - diethylene glycol Methyl ethyl ether - aqueous solution, acetamiprid - triethylene glycol monomethyl ether - aqueous solution, acetamiprid - triethylene glycol monobutyl ether - aqueous solution, acetamiprid - triethylene glycol dimethyl ether - aqueous solution, acetamiprid - polyethylene glycol monomethyl ether - aqueous solution, acetamiprid - propylene glycol monomethyl ether - aqueous solution - aqueous solution, acetamiprid - propylene glycol monopropyl ether - aqueous solution, acetamiprid - dipropylene glycol monomethyl ether - aqueous solution, acetamiprid - tripropylene glycol monomethyl ether - aqueous solution, acetamiprid - 3-methoxy-3-methyl-1-butanol - aqueous solution,
Thiacloprid - ethylene glycol monoisopropyl ether - aqueous solution, thiacloprid - ethylene glycol monobutyl ether - aqueous solution, thiacloprid - ethylene glycol monoisobutyl ether - aqueous solution, thiacloprid - ethylene glycol monoallyl ether - aqueous solution, thiacloprid - diethylene glycol monomethyl ether - aqueous solution, thiacloprid - diethylene glycol Monoisopropyl ether - aqueous solution, thiacloprid - diethylene glycol monobutyl ether - aqueous solution, thiacloprid - diethylene glycol monoisobutyl ether - aqueous solution, thiacloprid - diethylene glycol monobenzyl ether - aqueous solution, thiacloprid - diethylene glycol dimethyl ether - aqueous solution, thiacloprid - diethylene glycol diethyl ether - aqueous solution, thiacloprid - diethylene glycol Methyl ethyl ether - aqueous solution, thiacloprid - triethylene glycol monomethyl ether - aqueous solution, thiacloprid - triethylene glycol monobutyl ether - aqueous solution, thiacloprid - triethylene glycol dimethyl ether - aqueous solution, thiacloprid - polyethylene glycol monomethyl ether - aqueous solution, thiacloprid - propylene glycol monomethyl ether - aqueous solution - aqueous solution, thiacloprid - propylene glycol monopropyl ether - aqueous solution, thiacloprid - dipropylene glycol monomethyl ether - aqueous solution, thiacloprid - tripropylene glycol monomethyl ether - aqueous solution, thiacloprid - 3-methoxy-3-methyl-1-butanol - aqueous solution,
Nitenpyram - ethylene glycol monoisopropyl ether - aqueous solution, nitenpyram - ethylene glycol monobutyl ether - aqueous solution, nitenpyram - ethylene glycol monoisobutyl ether - aqueous solution, nitenpyram - ethylene glycol monoallyl ether - aqueous solution, nitenpyram - diethylene glycol monomethyl ether - aqueous solution, nitenpyram - diethylene glycol Monoisopropyl ether - aqueous solution, nitenpyram - diethylene glycol monobutyl ether - aqueous solution, nitenpyram - diethylene glycol monoisobutyl ether - aqueous solution, nitenpyram - diethylene glycol monobenzyl ether - aqueous solution, nitenpyram - diethylene glycol dimethyl ether - aqueous solution, nitenpyram - diethylene glycol diethyl ether - aqueous solution, nitenpyram - diethylene glycol Methyl ethyl ether - aqueous solution, nitenpyram - triethylene glycol monomethyl ether - aqueous solution, nitenpyram - triethylene glycol monobutyl ether - aqueous solution, nitenpyram - triethylene glycol dimethyl ether - aqueous solution, nitenpyram - polyethylene glycol monomethyl ether - aqueous solution, nitenpyram - propylene glycol monomethyl ether - aqueous solution -Aqueous solution, nitenpyram-propylene glycol monopropyl ether-aqueous solution, nitenpyram-dipropylene glycol monomethyl ether-aqueous solution, nitenpyram-tripropylene glycol monomethyl ether-aqueous solution, nitenpyram-3-methoxy-3-methyl-1-butanol-aqueous solution, etc. mentioned,
Preferably, dinotefuran-ethylene glycol monobutyl ether-aqueous solution, dinotefuran-ethylene glycol monoisobutyl ether-aqueous solution, dinotefuran-ethylene glycol monoallyl ether-aqueous solution, dinotefuran-diethylene glycol monobutyl ether-aqueous solution, dinotefuran-diethylene glycol monoisobutyl ether-aqueous solution, dinotefuran-diethylene glycol monobenzyl ether-aqueous solution, dinotefuran-propylene glycol monopropyl ether-aqueous solution, dinotefuran-3-methoxy-3-methyl-1-butanol-aqueous solution,
Imidacloprid-ethylene glycol monobutyl ether-aqueous solution, Imidacloprid-ethylene glycol monoisobutyl ether-aqueous solution, Imidacloprid-ethylene glycol monoallyl ether-aqueous solution, Imidacloprid-diethylene glycol monobutyl ether-aqueous solution, Imidacloprid-diethylene glycol monoisobutyl ether-aqueous solution, Imidacloprid-diethylene glycol mono-aqueous solution Benzyl ether-aqueous solution, imidacloprid-propylene glycol monopropyl ether-aqueous solution, imidacloprid-3-methoxy-3-methyl-1-butanol-aqueous solution,
Clothianidin-ethylene glycol monobutyl ether-aqueous solution, clothianidin-ethylene glycol monoisobutyl ether-aqueous solution, clothianidin-ethylene glycol monoallyl ether-aqueous solution, clothianidin-diethylene glycol monobutyl ether-aqueous solution, clothianidin-diethylene glycol monoisobutyl ether-aqueous solution, clothianidin-diethylene glycol mono-aqueous solution benzyl ether-aqueous solution, clothianidin-propylene glycol monopropyl ether-aqueous solution, clothianidin-3-methoxy-3-methyl-1-butanol-aqueous solution,
Thiamethoxam - ethylene glycol monobutyl ether - aqueous solution, thiamethoxam - ethylene glycol monoisobutyl ether - aqueous solution, thiamethoxam - ethylene glycol monoallyl ether - aqueous solution, thiamethoxam - diethylene glycol monobutyl ether - aqueous solution, thiamethoxam - diethylene glycol monoisobutyl ether - aqueous solution, thiamethoxam - diethylene glycol mono - aqueous solution Benzyl ether-aqueous solution, thiamethoxam-propylene glycol monopropyl ether-aqueous solution, thiamethoxam-3-methoxy-3-methyl-1-butanol-aqueous solution,
Acetamiprid-ethylene glycol monobutyl ether-aqueous solution, acetamiprid-ethylene glycol monoisobutyl ether-aqueous solution, acetamiprid-ethylene glycol monoallyl ether-aqueous solution, acetamiprid-diethylene glycol monobutyl ether-aqueous solution, acetamiprid-diethylene glycol monoisobutyl ether-aqueous solution, acetamiprid-diethylene glycol mono-aqueous solution Examples include benzyl ether-aqueous solution, acetamiprid-propylene glycol monopropyl ether-aqueous solution, acetamiprid-3-methoxy-3-methyl-1-butanol-aqueous solution, etc.
More preferably, dinotefuran-3-methoxy-3-methyl-1-butanol-aqueous solution, imidacloprid-3-methoxy-3-methyl-1-butanol-aqueous solution, clothianidin-3-methoxy-3-methyl-1-butanol -aqueous solution, thiamethoxam-3-methoxy-3-methyl-1-butanol-aqueous solution, acetamiprid-3-methoxy-3-methyl-1-butanol-aqueous solution, etc.
Most preferred is dinotefuran-3-methoxy-3-methyl-1-butanol-aqueous solution.

The pesticide-containing slow-release granular fertilizer formulation of the present invention may contain any pesticide components such as insecticides, fungicides, herbicides, or plant regulators.
Examples of the plant regulator component include maleic hydrazide and its salts, abscisic acid, rice benfide, paclobutrazol, uniconazole, triapentenol, or sauccel.
As the agricultural chemical component, any one that is solid, semi-solid, or liquid at room temperature can be used. For example, it is also possible to combine two or more types of agents with completely different targets, such as insecticides, fungicides, or herbicides.

There is no particular restriction on the agricultural chemical component and non-petroleum solvent to be used as long as these two components are included, but the preferred range is 0.01% to 10% of the agricultural chemical component and a non-petroleum solvent. is 0.1% to 10%, the total weight of fertilizer components is 0.1% to 99.9%, and more preferably, the pesticide component is 0.01% to 10%, and the non-petroleum solvent is 0.1%. ~10%, the total weight of fertilizer components is 0.1% to 99.8%, more preferably pesticide components are 0.03% to 5%, non-petroleum solvents are 0.1% to 10%, fertilizer components are The total weight is 50.0% to 99.9%.

In addition to the above-mentioned ingredients, a surfactant can be added to the pesticide-containing slow-release granular fertilizer formulation, if necessary. The surfactant is not particularly limited as long as it is normally used in pesticide formulations, and for example, nonionic surfactants, anionic surfactants, and cationic surfactants can be used, and nonionic surfactants are preferably used. One or more kinds of active agents and anionic surfactants, more preferably one or more kinds of nonionic surfactants, can be used in combination.

Specific examples of surfactants include polyoxyethylene alkylaryl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene polystyrylphenyl ether, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene oleyl ester, polyoxy Nonionic surfactants such as ethylene fatty acid esters and sorbitan fatty acid esters;
Fatty acid salts, alkyl sulfate ester salts, alkylbenzene sulfonates, α-olefin sulfonates, alkyl sulfosuccinates, polyoxyethylene alkylaryl ether sulfates and phosphates, polyoxyethylene styrylphenyl ether sulfates and phosphates and alkylamine salts Anionic surfactants such as;
Examples include cationic surfactants such as primary to tertiary fatty amine salts, alkylammonium chloride salts, tetraalkylammonium salts, trialkylbenzylammonium salts, alkylpyridinium salts, and alkylhydroxyethylimidazolinium salts; Compound surfactants of anionic surfactants and cationic surfactants are also included. These surfactants may be used alone or in combination of two or more. The amount incorporated in the agrochemical mixture liquid is usually, for example, 0.1 to 70 parts by weight, preferably 0.1 to 30 parts by weight, and more preferably 0.1 to 10 parts by weight.

In addition to the above-mentioned ingredients, additives can be added to the slow-release granular fertilizer formulation containing pesticides as needed. Examples of additives include lactic acid, hydrochloric acid, phosphoric acid, sodium citrate, citric acid, disodium hydrogen phosphate, sodium dihydrogen phosphate, and hydrogen phosphate as pH adjusters to improve the stability of agricultural chemical components. Contains slow-acting pesticides such as dipotassium, potassium dihydrogen phosphate, phthalic acid, potassium hydrogen phthalate, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, succinic acid, sodium borate, and N-ethylmorpholine. It can be blended in an amount of 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight, based on the entire granular fertilizer preparation. As the antioxidant, dibutylhydroxytoluene or the like can be blended in a blending ratio of 0.001 to 1 part by weight, preferably 0.005 to 0.5 part by weight. As the ultraviolet absorber, 2-hydroxy-4-n-octoxybenzophenone or the like can be blended in a blending ratio of 0.001 to 1 part by weight, preferably 0.005 to 0.5 part by weight. As the antifoaming agent, an acetylene glycol antifoaming agent, a silicone antifoaming agent, a fluorine antifoaming agent, a fatty acid antifoaming agent, etc. are used in a blending ratio of 0.001 to 5 parts by weight, preferably 0.01 to 2 parts by weight. It can be blended in parts by weight. In addition, as antibacterial agents, benzothiazole derivatives, sorbic acid, potassium sorbate, butyl p-oxybenzoate, glutaraldehyde, thiazolone, BNPK (2-bromo-2-nitropropane-1,3-diol), etc. It can be blended in a blending ratio of 0.01 to 5 parts by weight, preferably 0.01 to 2 parts by weight.

Furthermore, the following auxiliary agents such as colorants, crystal precipitation inhibitors, thickeners, dispersants, chelating agents, effect promoters, composition uniformity promoters, and nitrification inhibitors may be added as necessary. However, these adjuvants are not limited to those exemplified here.

Examples of colorants include azoic dyes, azo dyes, acridine, aniline dyes, aniline black, indanthrene, eosin, Congo red, dihydrointole, methylene blue, phenazine derivative dyes, neutral red, phenolphthalein, fuchsin, fluorescein, and para red. , mauve, carotene; carotenoids such as xanthophyll, cryptoxanthin, zeaxanthin, fucoxanthin, lycopene, lutein; flavonoids, flavanones, anthoclors, anthocyans, catechins; quinones such as melanin; chlorophyll, chlorophyllide, bacteriochlorophyll , cytochrome, pheophorbide, pheoporphyrin, hemeerythrin, hemoglobin, hemovanadin, hemocyanin, porphyrin, porphyrin pigments such as myoglobin; phycobilin pigments such as phycocyanin, phycobilin, phycoerythrin, phytochrome, biliverdin, bilirubin; alizarin, anthocyan, Anthraquinone, indigo, urobilin, erythrocruorin, carthamine, xanthonmatin, curcumin, crocetin, chlorin, chlorocruorin, genistein, cochineal, gossypol, commelinin, shikonin, stercopyrine, tannin, thuracin, bixin, hypericin, pinnaglobin, brasilin, In addition to purpurin, betacyanin, berberine, holbirin, mangostin, moringin, laminaran, leghemoglobin, litmus, rhodopsin, rhodoxanthin, rhodomatin, etc., such as carbon black, red pepper, Solvent Red 23, C.I. Acid Blue 1 (C.I. Acid Blue 1), C.I. Acid Yellow 23 (C.I. Acid Yellow 23), and the like.

Examples of crystal precipitation inhibitors include ethylene glycol, propylene glycol, glycerin, cyclodextrins, and alkylene oxide adducts of glycerin.

Examples of thickeners include products available from Sansho Co., Ltd., such as roasted bean gum such as MEYPROLBG FLEUR ^TM M-200, guar gum such as SUPERGEL ^TM 200, JAGUAR ^TM C-13S, etc. guar gum derivatives, carrageenan such as WG-108, pectin such as YM-150-LJ ^TM , xanthan gum such as KELZAN ^TM , gellan gum such as KELCOGEL ^TM AFT, diutan gum such as KELCO-CRETE ^TM DG, SB GUM-R ^TM Examples thereof include starch such as, dextrin such as MALTRIN ^(R) M040, cellulose derivative (carboxymethyl cellulose derivative) such as FINNFIX ^TM , and cod gum such as spino gum.

Examples of dispersants include products available from Kao and others, such as β-naphthalenesulfonic acid formalin condensate sodium salt such as Demol ^TM N, and special aromatic sulfonic acid formalin such as Demol ^TM SN-B. Sodium salts of condensates, special polycarboxylic acid type polymeric surfactants such as Demol ^TM P, polycarboxylic acid sodium salts such as Nopcosperse ^TM 44-C, polycarboxylic acid ammonium salts such as Nopcosperse ^TM 5600, SN Dispersant ^TM Special polycarboxylic acid ammonium salts such as 5023, polyphosphoric acid amino alcohol neutralized products such as SN Dispersant ^™ 2060, and condensed naphthalenesulfonic acid ammonium salts such as Roma PWA-40 ^™ can be mentioned.

Examples of the chelating agent include products available from Cherest Co., Ltd., such as EDTA (Ethylene Diamine Tetraacetic Acid), NTA (Nitrilo Triacetic Acid), and DTPA (Diethylene Triamine Pentaacet). ic Acid), HEDTA (Hydroxyethyl Ethylene Diamine Triacetic Acid), TTHA (Triethylene Tetramine Hexaacetic Acid), PDTA (1,3-Propanediamine Tetraacetic Acid), DPTA-OH (1,3-Diamino-2-hydroxypr opene Tetraacetic Acid), HIDA (Hydroxyethyl Imino Diacetic Acid), DHEG (Dihydroxyethyl Glycine), GEDTA (Glycol Ether Diamine Tetraacetic Acid), CMGA (Dicarboxymethyl Glutamic Acid), EDDS ((S,S)-Ethylene Diamine Disuc cinic acid), HEDP (Hydroxyethylidene Diphosphonic Acid), NTMP (Nitrilotris (Methylene Phosphonic Acid)), EDTA metal salts such as PBTC (Phosphonobutane Tricarboxylic Acid), EDTMP (Ethylene Diamine Tetra (Methylene Phosphonic Acid)), EDTA, Fe, Na, H ₂ O, DTPA metal salts such as DTPA/Fe/Na/H, PDTA/Fe・PDTA metal salts such as NH ₄ .H ₂ O, HOCH ₂ (CHOH) ₄ COONa, etc. can be mentioned.

Examples of the effect promoter include ferrous sulfate, copper sulfate, zinc sulfate, and ammonium molybdate.

Examples of the composition homogenization promoter include gypsum, paraffin, mineral oil, corn starch, and zeolite.

When using water and/or liquid fertilizer, examples of nitrification suppression include 2-amino-4-chloro-6-methylpyrimidine (AM), N-2,5-dichlorophenylsuccinamic acid, (DCS), dicyandiamide, 1-amidino-2-thiourea (ASU), and the like.
Further, the water used is not particularly limited, and any water can be used, such as purified water, distilled water, ion-exchanged water, pure water, ultrapure water, sterilized water, and filtered water.

Slow-release granular fertilizer formulations containing pesticides can usually be used for planting hole treatment, plant base treatment, and soil mixing. When applying the prepared pesticide-containing slow-release granular fertilizer formulation to plants, it can be used as is. The amount used for plants is determined by the contents of the slow-release granular fertilizer formulation containing pesticides, but it can be used from 1 g to 20 g per plant.

The plants to which the pesticide-containing slow-release granular fertilizer formulation of the present invention can be applied are not particularly limited, and include plants in the agricultural field, such as crops, craft crops, feed crops, etc., in the horticultural field, Examples include vegetables, fruit trees, and flowers.

Specifically, flowers; potted flowers; vegetables including fruit vegetables, leafy vegetables, and root vegetables; flowering trees; fruit trees including deciduous fruit trees and evergreen fruit trees; lawns; garden trees; wildflowers; bulbs; ornamental plants; orchids; ground covers, etc. can be mentioned.

When used for planting hole treatment, plant base treatment, and soil mixing, the slow-release granular fertilizer formulation containing pesticides is generally directly measured and treated, although it depends on the type and content of the active ingredient. Further, the amount and timing of application of the pesticide-containing slow-release granular fertilizer formulation can be appropriately determined depending on the pesticide active ingredient to be blended.

Furthermore, the pesticide-containing slow-release granular fertilizer formulation of the present invention can be applied alone to plants as described above, but the following liquid fertilizer can be applied together with the pesticide-containing slow-release granular fertilizer formulation of the present invention. Can be used together.

As specific examples of the combination method, after applying the slow-release granular fertilizer formulation containing pesticides of the present invention, liquid fertilizers such as liquid fertilizers, fertilizers applied after solubilizing powdered fertilizers in water, liquid fertilizers containing pesticides, etc. can be applied. The concentration of the liquid fertilizer to be applied and its application amount can be appropriately selected in consideration of the target plant and the condition of the plant, but for example, a suitable application amount of a liquid fertilizer diluted 250 to 2000 times is: It is 2 to 3 L/ ^m2 .

Specific examples of liquid fertilizers that can be used in combination include liquid fertilizers such as Hyponex stock solution, Flower Plant stock solution, Vegeful liquid fertilizer, and Myrose rose liquid fertilizer; Hyponex powder fertilizer, and water-soluble high-purity powder containing various trace elements. Peters fertilizer, water-soluble gardening fertilizers OK-F-1, OK-F-3, OK-F-9, OK-F-12, OK-F-17, OK Ace, and OK Special in water. Fertilizer that is applied after being solubilized; Examples of liquid fertilizers containing pesticides include Hyponex undiluted solution containing pesticides.

EXAMPLES Hereinafter, the present invention will be specifically explained with reference to Examples, but the present invention is not limited to these Examples.

Example 1 (Slow-release granular fertilizer formulation containing pesticide)
A premix was obtained by mixing 0.2 parts of dinotefuran, 0.2 parts of 3-methoxy-3-methyl-1-butanol (manufactured by Kuraray Co., Ltd., trade name Solfit), and 3.6 parts of water. This premix was added to the slow-release granular fertilizer Magamp K (manufactured by Hyponex Japan Co., Ltd.) and mixed to obtain a slow-release granular fertilizer containing dinotefuran.

Example 2
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to isopropyl glycol (manufactured by Nippon Nyukazai Co., Ltd., trade name: iPG). granular fertilizer was obtained.

Example 3
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to isopropyl diglycol (manufactured by Nippon Nyukazai Co., Ltd., trade name: iPDG). An effective granular fertilizer was obtained.

Example 4
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to dimethyl diglycol (manufactured by Nippon Nyukazai Co., Ltd., trade name DMDG). An effective granular fertilizer was obtained.

Example 5
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to methyl ethyl diglycol (manufactured by Nippon Nyukazai Co., Ltd., trade name: MEDG), and dinotefuran was added. A slow-release granular fertilizer was obtained.

Example 6
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to diethylene glycol monobutyl ether (manufactured by Dow Chemical Japan Co., Ltd., trade name BUTYLCARBITOL), and dinotefuran was A slow-release granular fertilizer was obtained.

Example 7
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to methyl lactate (manufactured by Corbion Japan Co., Ltd., trade name PURASOL V ML), and dinotefuran-containing A slow-release granular fertilizer was obtained.

Example 8
The same treatment as in Example 1 was carried out, except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to N-ethylpyrrolidone (manufactured by MYI Chemical Co, Ltd., trade name NEP). A slow-release granular fertilizer containing dinotefuran was obtained.

Example 9
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to N,N-dimethyllactamide (manufactured by Corbion Purac, trade name: N,N-dimethyllactamide). A slow-release granular fertilizer containing dinotefuran was obtained.

Example 10
A slow-release granular fertilizer containing hymexazole was obtained by carrying out the same treatment as in Example 1, except that the dinotefuran drug substance in Example 1 was changed to hymexazole drug substance.

Example 11
The same treatment as in Example 1 was carried out except that the amount of 3-methoxy-3-methyl-1-butanol was increased to 2.0 parts and the amount of water was reduced to 1.8 parts. An effective granular fertilizer was obtained.

Comparative example 1
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to solvent naphtha (manufactured by ExxonMobil Corporation, trade name: Solvesso 100). An effective granular fertilizer was obtained.

Comparative example 2
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to solvent naphtha (manufactured by Gordo Solvent Co., Ltd., trade name Naftezol 220). An effective granular fertilizer was obtained.

Comparative example 3
The same treatment as in Example 1 was carried out, except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to liquid paraffin (manufactured by Idemitsu Kosan Co., Ltd., trade name Daphne Oil SY-15). A slow-release granular fertilizer containing dinotefuran was obtained.

Comparative example 4
The same treatment as in Example 1 was carried out, except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to isodecyl phthalate (manufactured by Shin Nippon Chemical Co., Ltd., trade name Sansocizer DIDP). A slow-release granular fertilizer containing dinotefuran was obtained.

In order to demonstrate the usefulness of the pesticide-containing slow-release granular fertilizer formulation of the present invention, the following Test Example 1 (manufacturability of premix), Test Example 2 (possibility of impregnation into slow-release granular fertilizer), Test Example 3 (Formulation stability) and Test Example 4 (germination inhibition test) were conducted.

Test example 1 (premix manufacturability)
In preparing the premix, the solubility of dinotefuran was visually evaluated. The results are shown in Table 1. The evaluation criteria are: ○: Completely dissolved; ×: The pesticide active ingredient is suspended.

Test Example 2 (Possibility of impregnation of premix into slow-release granular fertilizer containing pesticides)
The impregnation of the prepared premix into slow-release granular fertilizer containing pesticides was evaluated. The results are shown in Table 1. The criteria are: ◯: uniform processing possible without any problems; △: processing possible but uneven; ×: processing not possible.

Test example 3 (formulation stability)
The prepared sample was placed in an aluminum bag and subjected to aging at 54°C for two weeks, and the condition of the sample after aging was confirmed. The results are shown in Table 1. The criteria are: ○: no change; ×: deterioration such as caking and crystal precipitation.

Test example 4 (germination inhibition test)
The germination inhibition test for the slow-release granular fertilizer formulation containing pesticides of the present invention was carried out according to the method of cultivation test for damage to plants according to the Notification No. 59 No. 1943 of the Director-General of the Agriculture, Forestry and Fisheries Bureau of Agriculture, Forestry and Fisheries, dated April 18, 1981. The test was conducted according to the following.
A pot (Neubauer pot) with an inner diameter of 11.3 cm and a height of 6.5 cm was used, and 5 g and 10 g of a slow-release granular fertilizer formulation containing pesticides were used per 1 liter of test soil as the test fertilizer. As a control fertilizer, Magump K, a slow-release granular fertilizer with the same fertilizer components as the test fertilizer, was used.
The test soil used was a mixture of peat moss, Akadama soil, and perlite in a ratio of 4:3:3.
Komatsuna was used as the test crop.
Approximately 500 ml of the test soil was filled into a test container.
(B) The test plots were divided into a standard amount application region and a double amount application region using the test fertilizer and the control fertilizer.
(b) Test area for test fertilizer In accordance with the amount of ingredients in the prototype of the slow-release granular fertilizer formulation containing pesticides, the standard amount application area was set at 5 g per liter of soil, and the double amount application area was set at 10 g per liter of soil. .
(c) Test plot using control fertilizer Test plots using the control fertilizer were set up in the same manner as those using the test fertilizer.
(d) Fertilizer application method The fertilizer was applied after being thoroughly mixed with the soil in the entire test container.
(E) Crop seeds and seed method The amount of seeds was 20 seeds per test container.
The seeds were sown using tweezers etc. in a grid pattern so that the seeds were evenly spaced, and after sowing, the seeds were covered with air-dried soil to the extent that the seeds were covered.
During the test period, soil moisture was replenished for about 10 days after the start of the test to maintain the moisture level at the start of the test, and thereafter, water was added as appropriate according to the growth of the crops. The cultivation temperature during the test period was maintained within the range of 15 to 25 degrees Celsius. The cultivation period was 25 days after seeding.
The formulations of Example 1, Example 2, Example 3, Example 7, Example 8, and Example 9 of the present invention were investigated for their germination rates and the presence or absence of abnormal symptoms. The results are shown in Table 2.

According to the present invention, it is possible to provide a safe slow-release granular fertilizer formulation containing pesticides that does not cause phytotoxicity to plants.

Claims (10)

A pesticide-containing slow-release granular fertilizer formulation manufactured by a method for producing a pesticide-containing slow-release granular fertilizer formulation containing a non-petroleum solvent and a pesticide active ingredient,
The manufacturing method includes impregnating or mixing a slow-release granular fertilizer with a previously prepared aqueous composition containing a mixture of one or more non-petroleum solvents and water and a pesticide,
Non-petroleum solvents include ether solvents, nitrile solvents, alcohol solvents, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, amine solvents, An aldehyde solvent, a fatty acid ester solvent, a nitrogen-containing carrier solvent, or a glycol ether solvent, where the fatty acid ester solvent is coconut oil fatty acid methyl ester, succinic acid dimethyl ester, glutamic acid dimethyl ester, or adipic acid dimethyl ester. and
The pesticide is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, or hydroxyisoxazole (hymexazole),
In slow-release granular fertilizer formulations containing pesticides, the content rate of pesticide components is 0.01% to 10%, the content rate of non-petroleum solvents is 0.1% to 10%, and the content rate of slow-release granular fertilizers is A slow-release granular fertilizer formulation containing pesticides with a content ratio of 50.0% to 99.9%. The formulation according to claim 1, wherein the non-petroleum solvent has a water solubility of 100 ppm or more. the ether solvent is tetrahydrofuran or 1,4-dioxane,
The nitrile solvent is acetonitrile, propionitrile, butyronitrile, isobutyronitrile or malononitrile,
Alcohol solvents include methanol, ethanol, propanol, isopropanol, 1-butanol, 2-butanol, isobutanol, t-butanol, allyl alcohol, ethylene glycol, 1,2-propanediol (propylene glycol), 1,3-propane diol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol or glycerin,
The ketone solvent is acetone, methyl ethyl ketone or diethyl ketone,
The carbonate solvent is dimethyl carbonate, diethyl carbonate, ethylene carbonate or propylene carbonate,
The ester solvent is methyl formate, ethyl formate, methyl acetate, ethyl acetate, γ-butyrolactone, methyl lactate or ethyl lactate,
The amide solvent is formamide, N,N-dimethylformamide, N,N-diethylformamide, N,N-dimethylacetamide, N,N-diethylacetamide, N,N-dimethylpropionamide or N,N-dimethyllactamide. and
The carbamide solvent is tetramethylurea or 1,3-dimethyl-2-imidazolidinone,
The sulfoxide solvent is dimethyl sulfoxide,
The sulfonic solvent is dimethylsulfone or sulfolane,
The amine solvent is ammonia, methylamine, dimethylamine, diethylamine, triethylamine, isopropylamine, diisopropylamine, ethyldiisopropylamine, pyrrolidine, N-methylpyrrolidine, piperidine, N-methylpiperidine, morpholine, N-methylmorpholine, pyridine or ethanolamine,
The aldehyde solvent is formaldehyde, acetaldehyde, propionaldehyde, butanal or pentanal,
the nitrogen-containing carrier-based solvent is N-methylpyrrolidone or N-ethylpyrrolidone,
Glycol ether solvents include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol mono t-butyl ether, and ethylene glycol mono 2-methylpentyl ether, ethylene glycol monohexyl ether, ethylene glycol mono-2-ethyl-hexyl ether, ethylene glycol monovinyl ether, ethylene glycol monoallyl ether, ethylene glycol monobenzyl ether, ethylene glycol monophenyl ether, ethylene glycol dimethyl ether, ethylene Glycol diethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monohexyl ether, diethylene glycol mono 2-ethylhexyl ether, diethylene glycol monoallyl ether, diethylene glycol Monobenzyl ether, diethylene glycol monophenyl ether, diethylene glycol mono(methylphenyl) ether, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, diethylene glycol divinyl ether, diethylene glycol ethyl vinyl ether, triethylene glycol monomethyl ether, triethylene glycol Monoethyl ether, triethylene glycol monobutyl ether, triethylene glycol monovinyl ether, triethylene glycol dimethyl ether, tetraethylene glycol monophenyl ether, tetraethylene glycol diethyl ether, polyethylene glycol monomethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, Propylene glycol monopropyl ether, propylene glycol monoisopropyl ether, propylene glycol monobutyl ether, propylene glycol phenyl ether, propylene glycol mono(methylphenyl) ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol dipropyl ether, propylene glycol diisopropyl ether , propylene glycol dibutyl ether, propylene glycol diisobutyl ether, propylene glycol diallyl ether, propylene glycol diphenyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, dipropylene glycol dimethyl ether , dipropylene glycol diethyl ether, dipropylene glycol dibutyl ether, dipropylene glycol diisobutyl ether, dipropylene glycol allyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether, tripropylene glycol monobutyl ether, butylene glycol monomethyl ether, butylene The formulation according to claim 1 or 2, wherein the glycol is dimethyl ether, isopropyl glycol, diisopropyl glycol, dimethyl diglycol, methyl ethyl diglycol or 3-methoxy-3-methyl-1-butanol. The formulation according to any one of claims 1 to 3, wherein the non-petroleum solvent is a glycol ether solvent. 5. A formulation according to any one of claims 1 to 4, wherein the aqueous composition further comprises a liquid or liquid fertilizer. The slow-release granular fertilizer is a slow-release compound granular fertilizer, a chemically synthesized slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressure-molded granular fertilizer, or a slow-release nitrification inhibitor-containing fertilizer, The formulation according to any one of claims 1 to 5. Slow-release granular fertilizer contains nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), and calcium (Ca) as essential plant elements. ) and sulfur (S). 8. The formulation according to claim 7, wherein the slow-release granular fertilizer contains nitrogen (N), phosphorus (P), and potassium (K) as essential plant elements in a guaranteed ingredient ratio of 3:20:3. 8. The formulation according to claim 7, wherein the slow-release granular fertilizer contains nitrogen (N), phosphorus (P), and potassium (K) as essential plant elements in a guaranteed ingredient ratio of 2:5:2. Use of the pesticide-containing slow-release granular fertilizer formulation according to any one of claims 1 to 9 for agricultural, horticultural, or home horticultural purposes.