JPWO2018074525A1 - Slow-release granular fertilizer formulation with pesticides - Google Patents

Abstract

Provided is a slow-acting granular fertilizer formulation containing an agrochemical, in which precipitation of an agrochemical component or a fertilizer component, decomposition / separation of each component is suppressed, excellent long-term stability, and risks such as flammability are reduced. A slow-acting granular fertilizer formulation containing a pesticide, containing a non-petroleum solvent and a pesticide.

Description

  The present invention relates to a slow-acting granular fertilizer preparation containing agricultural chemicals and a method for using the same.

There are many types of fertilizers, and there are various methods for their classification. There are mixed fertilizers in which both are mixed, but both components differ greatly, but they are common in that the water-soluble components of inorganic compounds are absorbed by plants, and various improvements have been made to provide for plant nutrition. Yes.
Among existing chemical fertilizers, a typical example of slow-acting granular fertilizer is a composition (Patent Document 1) in which magnesium potassium phosphate and magnesium ammonium phosphate are mixed in a predetermined proportion.

  Japanese Patent Application Laid-Open No. 2008-133267 (Patent Document 2) discloses a method for suppressing paddy rice damage caused by paddy rice sucking pests, and a paddy rice planted with a neonicotinoid insecticide and siliceous fertilizer. Describes the application to the water surface. The siliceous fertilizer is defined as a fertilizer in which the amount of soluble silicic acid in a fertilizer composition such as calcium silicate, potassium silicate, and liquid potassium silicate is 10% by weight or more, but from the viewpoint of workability when applied. It is used as an agrochemical fertilizer mixture mixed with an agrochemical formulation.

  WO2014 / 098203 (Patent Document 3) contains one or more agricultural chemical components impregnated in granular fertilizer or attached to the surface of granular fertilizer, and has an agricultural chemical content in the range of 15 to 80 grains per gram A method for applying a pesticide-containing granular fertilizer comprising applying a granular fertilizer composition to soil using a fertilizer application is described (see claim 1). The pesticide-containing granular fertilizer composition used in the application method is obtained by adding a predetermined amount of a pesticide component containing a predetermined amount of neonicotinoid insecticide to an organic solvent such as coating oil to a raw material of a commercially available chemical fertilizer. It is a feature that the obtained mixed liquid is mixed with the chemical fertilizer, specifically, coating oil (Example 1 to Example 3, Example 5) or C10-11 alkylbenzene (Example 4). The solvent is mixed with clothianidin (Examples 1 to 3), fenitrothion (Example 4) or furametopyr (Example 5), which are agrochemical components, to obtain a mixed solution, and the obtained mixed solution is used as the chemical fertilizer. It is manufactured by mixing.

Japanese Patent Publication No. 44-18891 JP 2008-133267 A WO2014 / 098203

  However, the siliceous fertilizer used in Patent Document 2 and the chemical fertilizer used in Patent Document 3 are ordinary soluble chemical fertilizers.

Ordinary chemical fertilizers have a problem that the fertilization work including the additional fertilization work becomes excessive because the fertilization effect does not last. On the other hand, since slow-acting fertilizers have long-lasting fertilization effects, they are not only effective in reducing fertilization labor and efficient use of fertilizer components, but also have little impact on the environment. It is growing.
However, no slow-acting granular fertilizer containing a pesticide obtained by treating a slow-acting fertilizer with a pesticide is currently unknown at all.
An object of the present invention is to produce a slow-acting granular fertilizer containing an agrochemical that can apply a slow-acting granular fertilizer and an agrochemical component to a plant at the same time, and that does not give adverse effects such as phytotoxicity to the plant.

  As a result of intensive studies to solve the above problems, the present inventors have used a non-petroleum solvent to dissolve the agrochemical component, and contain the agrochemical and the fertilizer. When the preparation was prepared, the slow-release granular fertilizer preparation was found to have no adverse effects such as phytotoxicity on plants, and the present invention was completed.

That is, the present invention includes the following aspects.
(1) A slow-acting granular fertilizer preparation containing a pesticide containing a non-petroleum solvent and a pesticide active ingredient.

(2) The preparation according to (1), wherein the water solubility of the non-petroleum solvent is 100 ppm or more.

(3) Non-petroleum solvents are ether solvents, nitrile solvents, alcohol solvents, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, amine solvents. The preparation according to (1) or (2), which is a solvent, an aldehyde solvent, a fatty acid ester solvent, a nitrogen-containing carrier solvent or a glycol ether solvent.

(4) The preparation according to any one of (1) to (3), wherein the non-petroleum solvent is a glycol ether solvent.

(5) The preparation according to any one of (1) to (4), further comprising water and / or liquid or liquid fertilizer.

(6) Pesticides are carbamate acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, cyclic diene organochlorine GABA agonist chloride channel antagonists, phenylpyrazole (fiprole) GABA agonists Chloride channel antagonist, pyrethroid and pyrethrin sodium channel modulator, sodium channel modulator, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonist, nicotinic acetylcholine receptor (nAChR) agonist, butenolide nicotinic acetylcholine receptor ( nAChR) agonist, spinosyn nicotinic acetylcholine receptor (nAChR) allosteric modulator -Avermectin and milbemycin chloride channel activators, juvenile hormone analogs, non-specific (multi-site) inhibitors, chordal organ modulators, mite growth inhibitors, microorganism-derived insect midgut membrane disruptors, mitochondria ATP synthase inhibitor, oxidative phosphorylation uncoupler, nereistoxin analog nicotinic acetylcholine receptor (nAChR) channel blocker, benzoylurea chitin biosynthesis inhibitor (type 0), chitin biosynthesis inhibitor (type 1), fly insect insect molting inhibitor, diacyl-hydrazine molting hormone (ecdysone) receptor agonist, octopamine receptor agonist, mitochondrial electron transport system complex III inhibitor, mitochondrial electron transport system complex I inhibitor (METI) , Voltage-gated sodium channel Locker, Tetronic acid and Tetramic acid derivative Acetyl CoA carboxylase inhibitor, Phosphine mitochondrial electron transport complex IV inhibitor, Cyanide mitochondrial electron transport complex IV inhibitor, β-Ketonitrile derivative Mitochondrial electron transport complex II inhibitor Agents, diamide-based ryanodine receptor modulators, natural enemy insects, mites, nematode biological pesticides, microbial biological pesticides, air gate-blocking pesticides, pheromones, azadirachtin, benzomate (benzoximate), bifenazate, phenisobromolate ( Bromopropylate), quinoxaline (quinomethionate), sodium aluminum fluoride, kelsen (eg, dicophor), pyridalyl, pyrifluquinazone, sulfur, ferric phosphate, metaldehyde and 1,3-dichloropro An insecticide selected from the group consisting of pens;
Acylalanine PA fungicides (phenylamides), oxazolidinone PA fungicides (phenylamides), butyrolactone PA fungicides (phenylamides), hydroxy (2-amino-) pyrimidines, isoxazole aromatic hetero Rings, isothialone aromatic heterocycles, carboxylic acids, benzimidazole MBC fungicide (methylbenzimidazole carbamate), thiophanate MBC fungicide (methylbenzimidazole carbamate), N-phenyl carbamates, toluamide benzamides, Ethylaminothiazole carboxamide type thiazole carboxamides, phenylureas, pyridinylmethylbenzoamide type benzamides, pyrimidineamines, pyrazole carboxamides, phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furan carboxamide SDHI ( Succinate dehydrogenase inhibitor), oxathiin carboxamide SDHI (succinate dehydrogenase inhibitor), thiazole carboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase) Enzyme inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxyacetamide QoI fungicide (Qo inhibitor), methoxycarbamate QoI fungicide ( Qo inhibitor), oxyimi Acetic acid-based QoI fungicide (Qo inhibitor), Oximinoacetamide-based QoI fungicide (Qo inhibitor), Oxazolidinedione-based QoI fungicide (Qo inhibitor), Dihydrodioxazine-based QoI fungicide (Qo inhibitor), Imidazo Linone-based QoI fungicide (Qo inhibitor), benzyl carbamate-based QoI fungicide (Qo inhibitor), cyanoimidazole-based QiI fungicide (Qi inhibitor), sulfamoyl triazole-based QiI fungicide (Qi inhibitor), dinitro Phenylcrotonic acids, 2,6-dinitroanilines, triphenyltin compounds, organotin compounds, thiophenecarboxamides, triazolopyrimidylamine-based QoSI fungicides (Qo inhibitors, stigmaterin-binding type), anilinopyrimidine-based AP sterilization Agent (anilinopyrimidines), enopyranuron Acid antibiotics, hexopyranosyl antibiotics, glucopyranosyl antibiotics, tetracycline antibiotics, allyloxyquinoline aza-naphthalenes, quinazolinone aza-naphthalenes, phenylpyrrole PP fungicides (phenylpyrroles), dicarboximides, phospho Rothiolates, dithiolanes, aromatic hydrocarbon-based AH fungicides (including aromatic hydrocarbons, chlorophenyls, nitroanilines), 1,2,4-thiadiazole-based heteroaromatics, carbamates, Bacillus genus and Produced bactericidal lipopeptide microorganisms (genus Bacillus), terpene hydrocarbons and terpene alcohol plant extracts, piperazine DMI fungicides (demethylation inhibitors, SBI: class I), pyridine DMI fungicides ( Demethylation inhibitor, BI: class I), pyrimidine DMI fungicide (demethylation inhibitor, SBI: class I), imidazole DMI fungicide (demethylation inhibitor, SBI: class I), triazole DMI fungicide (demethylation) Inhibitor, SBI: class I), triazoline thione DMI fungicide (demethylation inhibitor, SBI: class I), morpholine amines (morpholine, SBI: class II), piperidine amines (Morpholines, SBI: Class II), Spiroketal amine amines (Morpholines, SBI: Class II), Hydroxyanilides (SBI: Class III), Aminopyrazolinone compounds (SBI: Class III) Thiocarbamates (SBI: class IV), allylamines (SBI: class IV), glucopyranosyl antibiotics, pep Dilpyrimidine nucleoside polyoxins, cinnamic amide CAA fungicides (carboxylic amides), valinamide carbamate CAA fungicides (carboxylic amides), mandelic acid amide CAA fungicides (carboxylic amides), iso Benzofuranone MBI-R (melanin biosynthesis inhibitor-reductase), pyrroloquinolinone MBI-R (melanin biosynthesis inhibitor-reductase), triazolobenzothiazole MBI-R (melanin biosynthesis inhibitor-reductase) ), Cyclopropanecarboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase), carboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase), propionamide MBI-D (melanin biosynthesis inhibitor-dehydration) Enzyme), benzothiadiazoles, benzoisothiazoles, Asianazole carboxamides, natural polysaccharides, plant extracts, cyanoacetamide oximes, ethylphosphonate phosphonates, phosphonates, phthalamic acids, benzotriazines, benzenesulfonamides, pyridazinones, thiocarbamate compounds, phenylacetamide Compound, benzophenone allyl phenyl ketone compound, benzoylpyridine allyl phenyl ketone compound, guanidine, cyanomethylene thiazolidine thiazolidine compound, pyrimidinone hydrazone, piperidinyl thiazole isoxazoline, acetic acid 4-quinoline compound, inorganic compound, Dithiocarbamates and their analogs, phthalimides, chloronitriles (phthalonitriles), sulfamides, guanidines, triazines, quino Bactericides selected from the group consisting of thiones (anthraquinones), quinoxalines, maleimides, physical inhibitors, bicarbonates, silvers, organocoppers and soil disinfectants;
Or allyloxypropionate acetyl CoA carboxylase (ACCase) inhibitor, cyclohexanedione acetyl CoA carboxylase (ACCase) inhibitor, phenylpyrazoline acetyl CoA carboxylase (ACCase) inhibitor, sulfonylurea acetolactate synthase (ALS) Inhibitors (acetohydroxyacid synthase (AHAS) inhibitors), imidazolinone acetolactate synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors), triazolopyrimidine acetolactate synthase (ALS) ) Inhibitors (acetohydroxyacid synthase (AHAS) inhibitors), pyrimidinyl (thio) benzoate acetolactate synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors , Sulfonylaminocarbonyltriazolinone acetolactate synthase (ALS) inhibitor (acetohydroxy acid synthase (AHAS) inhibitor), triazine photosynthesis (photochemical II) inhibitor, triazinone photosynthesis (photochemical II) inhibition Agents, triazolinone photosynthesis (photochemical II) inhibitors, uracil photosynthesis (photochemical II) inhibitors, pyridazinone photosynthesis (photochemical II) inhibitors, phenyl carbamate photosynthesis (photochemical II) inhibitors, urea photosynthesis (Photochemical II) inhibitors, amide photosynthesis (photochemical II) inhibitors, nitrile photosynthesis (photochemical II) inhibitors, benzothiadiadinone photosynthesis (photochemical II) inhibitors, phenylpyridazine photosynthesis (photochemistry) II) inhibitors, bipyridylium photosystem I electron conversion agents, diphenyl ether protoporphyrin Genoxidase (PPO) inhibitors, phenylpyrazole protoporphyrinogen oxidase (PPO) inhibitors, N-phenylphthalimide protoporphyrinogen oxidase (PPO) inhibitors, thiadiazole protoporphyrinogen oxidase ( PPO) inhibitor, oxadiazole protoporphyrinogen oxidase (PPO) inhibitor, triazolinone protoporphyrinogen oxidase (PPO) inhibitor, oxazolidinedione protoporphyrinogen oxidase (PPO) inhibitor, Pyrimidinedione protoporphyrinogen oxidase (PPO) inhibitor, protoporphyrinogen oxidase (PPO) inhibitor, carotenoid biosynthesis inhibitor in pyridazinone phytoene desaturase system (PDS), pyridinecarboxamide Carotenoid biosynthesis inhibitor in phytoene desaturase system (PDS), carotenoid biosynthesis inhibitor in phytoene desaturase system (PDS), triketone 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor , Isoxazole 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor, pyrazole 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor, 4-hydroxyphenylpyruvate dioxygenase enzyme ( 4-HPPD) inhibitor, triazole carotenoid biosynthesis (target site unknown) inhibitor, isoxazolidinone carotenoid biosynthesis (target site unknown) inhibitor, urea carotenoid biosynthesis (target site unknown) inhibitor, diphenyl ether carotenoid Noid biosynthesis (target site unknown) inhibitor, glycine-based EPSP synthase inhibitor, phosphinic acid-based glutamine synthetase inhibitor, carbamate-based DHP (dihydropteroic acid) synthase inhibitor, dinitroaniline-based microtubule polymerization inhibitor , Phosphoramidate microtubule polymerization inhibitor, pyridine microtubule polymerization inhibitor, benzamide microtubule polymerization inhibitor, benzoic acid microtubule polymerization inhibitor, carbamate mitosis / microtubule formation inhibitor, chloro Inhibitor of acetamide VLCFA (cell division inhibitor), Inhibitor of acetamide VLCFA (cell division inhibitor), Inhibitor of oxyacetamide VLCFA (cell division inhibitor), Inhibitor of tetrazolinone VLCFA (Inhibition of cell division) Agent), VLCFA inhibitor (cell division inhibitor), nitrile cell wall (cellulose) Inhibitors, benzamide cell wall (cellulose) synthesis inhibitors, triazolocarboxamide cell wall (cellulose) synthesis inhibitors, quinolinecarboxylic acid cell wall (cellulose) synthesis inhibitors, dinitrophenol uncoupling (membrane disruption) agents, thio Carbamate lipid synthesis inhibitor (non-ACCase inhibitor), phosphorodithioate lipid synthesis inhibitor (non-ACCase inhibitor), benzofuran lipid synthesis inhibitor (non-ACCase inhibitor), chlorocarbonic acid lipid synthesis inhibitor (non-ACCase inhibitor) Agent, phenoxycarboxylic acid-based indoleacetic acid-like activity (synthetic auxin) agent, benzoic acid-based indoleacetic acid-like activity (synthetic auxin) agent, pyridinecarboxylic acid-based indoleacetic acid-like activity (synthetic auxin) agent, quinolinecarboxylic acid-based indoleacetic acid-like agent Activity (synthetic oxy ) Agent, indole acetic acid-like activity (synthetic auxin) agent, phthalamate auxin transfer inhibitor, semicarbazone auxin transfer inhibitor, arylaminopropionic acid compound, pyrazolium compound, organic arsenic compound, microorganism, bromobutide, (chlor) -Selected from the group consisting of flulenol, cinmethylin, cumyluron, dazomet, diimron, methyldaimlone, etozanide, fosamine, indanophan, carbam / carbam sodium salt, oxadichromemephone, oleic acid, pelargonic acid, pyributycarb, chlorate and cyanate The preparation according to any one of (1) to (5), which is a herbicide.

(6-1) Pesticides are carbamate acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, phenylpyrazole (fiprol) GABAergic chloride channel antagonists, pyrethroids and pyrethrin sodium Channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, spinosyn nicotinic acetylcholine receptor (nAChR) allosteric modulators, avermectin and milbemycin chloride channel activators, string sound organ modulators, oxidative phosphorylation Conjugating agent, Mitochondrial electron transport system complex III inhibitor, Mitochondrial electron transport system complex I inhibitor (METI), Voltage dependence Pesticides selected from the group consisting of soluble sodium channel blockers, tetronic and tetramic acid derivative acetyl CoA carboxylase inhibitors, diamide ryanodine receptor modulators, quinoxaline (quinomethionate), pyridalyl and metaaldehyde;
Or acylalanine PA fungicides (phenylamides), oxazolidinone PA fungicides (phenylamides), butyrolactone PA fungicides (phenylamides), isoxazole aromatic heterocycles, benzimidazole MBC fungicides (Methylbenzimidazole carbamate), N-phenyl carbamates, phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furan carboxamide SDHI (succinate dehydrogenase inhibitor), oxathiin carboxamide SDHI (succinate dehydrogenase inhibitor), thiazole carboxamide SDHI (succinate dehydrogenase inhibitor) Enzyme inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxy Acetamide QoI fungicide (Qo inhibitor), Methoxycarbamate QoI fungicide (Qo inhibitor), Oximinoacetic acid QoI fungicide (Qo inhibitor), Oximinoacetamide QoI fungicide (Qo inhibitor), Oxazolidinedione QoI fungicide (Qo inhibitor), dihydrodioxazine QoI fungicide (Qo inhibitor), imidazolinone QoI fungicide (Qo inhibitor), benzyl carbamate QoI fungicide (Qo inhibitor), cyanoimidazole QiI fungicide (Qi inhibitor), sulfamoyl triazol QiI fungicides (Qi inhibitors), 2,6-dinitroanilines, anilinopyrimidine AP fungicides (anilinopyrimidines), phenylpyrrole PP fungicides (phenylpyrroles), dicarboximides, piperazine Type DMI fungicide (demethylation inhibitor, SBI: class I), pyridine type DMI fungicide (demethylation inhibitor, SBI: class I), pyrimidine type DMI fungicide (demethylation inhibitor, SBI: class) I), imidazole-based DMI fungicide (demethylation inhibitor, SBI: class I), triazole-based DMI fungicide (demethylation inhibitor, SBI: class I), triazolinethione-based DMI fungicide (demethylation) Inhibitor, SBI: class I), isobenzofuranone MBI-R (melanin biosynthesis inhibitor-reductase), pyrroloquinolinone MBI-R (melanin biosynthesis inhibitor-reductase), triazolobenzothiazole MBI-R (melanin biosynthesis inhibitor-reductase), cyclopropanecarboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase) ), Carboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase), propionamide MBI-D (melanin biosynthesis inhibitor-dehydrase), benzothiadiazoles, benzoisothiazoles, thiadiazole carboxamides, cyanoacetamide The preparation according to any one of (1) to (6), which is a fungicide selected from the group consisting of oximes, benzenesulfonamides, pyridazinones, guanidines and quinoxalines.

(6-2) Pesticides are carbamate acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, phenylpyrazole (fiprol) GABAergic chloride channel antagonists, pyrethroids and pyrethrin sodium From the group consisting of channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, oxidative phosphorylation uncouplers, avermectin and milbemycin chloride channel activators, string sound organ modulators and diamide ryanodine receptor modulators Selected pesticides;
Or isoxazole aromatic heterocycles, benzimidazole MBC fungicide (methylbenzimidazole carbamate), phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase) Inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furan carboxamide SDHI (succinate dehydrogenase inhibitor), oxathiin carboxamide SDHI (succinate dehydrogenase inhibitor), Thiazolecarboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate Qo Bactericides (Qo inhibitors), methoxyacetamide QoI bactericides (Qo inhibitors), methoxycarbamate QoI bactericides (Qo inhibitors), oximinoacetic acid QoI bactericides (Qo inhibitors), oximinoacetamide QoI bactericides Agent (Qo inhibitor), oxazolidinedione QoI fungicide (Qo inhibitor), dihydrodioxazine Qo fungicide (Qo inhibitor), imidazolinone QoI fungicide (Qo inhibitor), benzyl carbamate QoI fungicide (Qo inhibitor), piperazine DMI fungicide (demethylation inhibitor, SBI: class I), pyridine DMI fungicide (demethylation inhibitor, SBI: class I), pyrimidine DMI fungicide (demethylation) Inhibitor, SBI: class I), imidazole DMI fungicide (demethylation inhibitor, SBI: Kura A fungicide selected from the group consisting of I), a triazole DMI fungicide (demethylation inhibitor, SBI: class I) and a triazolinethione DMI fungicide (demethylation inhibitor, SBI: class I) The preparation according to any one of (1) to (6-1).

(6-3) Pesticides are aldicarb, bendiocarb, butcarboxyme, butoxycarboxyme, NAC (carbaryl), carbofuran, etiophencarb, BPMC (fenobcarb), formethanate, MIPC (isoprocarb), mesomil, MTMC (metholcarb), Oxamyl, pyrimicarb, PHC (propoxyl), thiophanox, triazamate, XMC, MPMC (xylylcarb), acephate, azamethiphos, kazusafos, CVP (chlorfenvinphos), dimethone-S-methyl, DDVP (dichlorochlors), dicrotofos, dimethoate , Dimethylvinphos, etoprophos, phenamifos, phostiazete, heptenofos, marathon (malathion), mecarbam, methamidophos, DMTP (methidachi) ON), mevinphos, monocrotophos, ometoate, oxydimetone methyl, phosphamidone, propetamphos, thiomethone, DEP (trichlorfone), bamidthione, flumetrin, fipronil, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thianicotine, thianicotine sulfate , Sulfoxafurol, Flupiradifuron, Pyriproxyfen, Methyl bromide, Chlorpicrin, sulfuryl fluoride, borax, Tartar, Pymetrozine, Flonicamid, BPPS (propargite), DNOC, cartap, thiocyclam, thiosultap sodium salt , Cyromazine, hydrogen phosphide, hydrocyanic acid, azadirachtin, sodium aluminum fluoride, 1,3-dichloro Propene, dicyclanil, ethylene dibromide, insecticide selected from the group consisting of Sabajira and co CFC sodium;
Or flaxyl, metalaxyl, metalaxyl M, oxadixyl, ofrase, dimethylirimol, hydroxyisoxazole (hymexazole), octylinone, fenflam, carboxin, oxycarboxyl, framethopyl, metminostrobin, cyazofamid, pyrimethanil, kasugamycin, streptomycin, IBP (iprobenphos ), Echromezol (etridiazole), propamocarb, prothiocarb, pyrifenox, imazalyl, pefazoate, triflumizole, flutriahole, microbutanyl, propiconazole, tetraconazole, phenpropidine, spiroxamine, validamycin, polyoxin, iprovalicarb, pyroxylone , Simoxanyl, fosetyl, phosphorous acid and salt, full Rufamide, metasulfocarb, guanidine (dodine), ferimzone, potassium hydrogen carbonate, farbum, guazatine, iminotadine acetate / iminoctadine arbesylate (iminoctadine), copper sulfate, formaldehyde, 8-hydroxyquinoline sulfate, iodomethane, chloride (1) to (6-2), which is a fungicide selected from the group consisting of 2mercury, metham, methyl bromide, methylisothiocyanate, myrdiomycin, nabum, phenylmercury acetate, 2-phenylphenol and poroxin. It is a formulation as described in any one of these.

(6-4) Any one of (1) to (6-3), wherein the pesticide is at least one selected from the group consisting of acephate, fipronil, acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam, nitenpyram, and flonicamid. It is a formulation as described in any one.

(6-5) Any one of (1) to (6-4), wherein the pesticide is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram. It is a formulation as described in one.

(6-6) The agrochemical is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran and thiamethoxam, according to any one of (1) to (6-5) The formulation.

(6-7) The preparation according to any one of (1) to (6-6), wherein the agricultural chemical is dinotefuran.

(7) It is a formulation as described in any one of (1)-(6) whose content rate of an agrochemical is 0.01 to 10 weight%.

(8) The slow-release granular fertilizer is a slow-release mixed granular fertilizer, chemically synthesized slow-release granular fertilizer, slow-release coated granular fertilizer, slow-release pressure-molded granular fertilizer, or slow-release nitrification inhibitor-containing fertilizer The preparation according to any one of (1) to (7).

(9) Slow-acting granular fertilizer is a plant essential element such as Chisso (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), The preparation according to any one of (1) to (8), which contains any one or more fertilizer components selected from the group consisting of calcium (Ca) and sulfur (S).

(9-1) The slow-acting granular fertilizer contains at least two kinds of fertilizer components selected from the group consisting of nitrogen (N), phosphorus (P) and potassium (K) as plant essential elements. ) Or (9).

(9-2) Any of (8) to (9-1), wherein the slow-acting granular fertilizer contains fertilizer components of nitrogen (P) and potassium (K) as plant essential elements It is a formulation as described in one.

(9-3) The group in which the slow-acting granular fertilizer further comprises iron (Fe), copper (Cu), zinc (Zn), molybdenum (Mo), cobalt (Co) and chlorine (Cl) as plant essential elements. It is a formulation as described in any one of (8)-(9-2) containing any 1 or more types of the fertilizer component selected from these.

(10) The slow-release granular fertilizer contains chisso (N), phosphorus (P), and potassium (K) as a plant essential element in a ratio of guaranteed component amount 3: 20: 3, according to (9) It is a formulation.

(11) The slow-acting granular fertilizer contains chisso (N), phosphorus (P), and potassium (K) as a plant essential element in a ratio of guaranteed components of 2: 5: 2 as described in (9) It is a formulation.

(12) The preparation according to any one of (8) to (11), wherein the content of the slow-release granular fertilizer is 0.1 wt% to 99.9 wt%.

(13) The preparation according to any one of (1) to (7), wherein the content ratio of the non-petroleum solvent is 0.1 wt% to 10 wt%.

(14) Pesticide content is 0.01 wt% to 10 wt%, non-petroleum solvent content is 0.1 wt% to 10 wt%, slow-release granular fertilizer content is 0.1 wt% The preparation according to any one of (1) to (13), which is ˜99.9% by weight.

(15) Pesticide content is 0.03% to 5% by weight, non-petroleum solvent content is 0.1% to 10% by weight, slow-release granular fertilizer content is 50.0% by weight The preparation according to (14), which is ˜99.8% by weight.

(16) Use of the preparation according to any one of (1) to (15) for agricultural horticulture or household horticulture.

The slow-acting granular fertilizer preparation containing an agrochemical of the present invention is essentially different from ordinary soluble chemical fertilizers used in Patent Documents 2 and 3 in terms of elution of fertilizer components.
Moreover, the slow-release granular fertilizer preparation containing an agrochemical of the present invention belongs to the class of inorganic fertilizers mainly composed of inorganic compounds, and can be produced using, in particular, chemically synthesized chemical fertilizers as raw materials.

  According to the present invention, a slow-release granule fertilizer pesticide that does not cause phytotoxicity to plants, that is, a slow-release granular fertilizer formulation containing a pesticide, in which precipitation of the pesticide component or fertilizer component, decomposition / separation of each component is suppressed, Can be provided.

Various terms used in this specification will be described.
In the present specification, a numerical range indicated by using “to” indicates a range including the numerical values described before and after “to” as the minimum value and the maximum value, respectively. Further, the content of each component in the composition means the total amount of the plurality of substances present in the composition unless there is a specific notice when there are a plurality of substances corresponding to each component in the composition.

“Agricultural chemicals” refers to fungi, nematodes, worms, insects, mice and other animals and plants or viruses (hereinafter referred to as “pests and pests”) that damage crops (including trees and agricultural and forestry products; hereinafter referred to as “agricultural crops”). Plant growth regulation used for the promotion or suppression of physiological functions such as fungicides, insecticides and other chemicals used for control (including those used as raw materials or materials used for control) and crops A chemical, a germination inhibitor and other chemicals, but the agricultural chemical is not particularly limited as long as it is a chemical used for agriculture, and any chemical can be used. Any of insecticide, fungicide and herbicide It may be. Specific examples of agricultural chemicals include, for example, alanic carb, aldicarb, bendiocarb, benfuracarb, butcarboxyme, butoxycarboxyme, NAC (carbaryl), carbofuran, carbosulfan, etiophencarb, BPMC (fenobucarb), formethanate, furatiocarb, MIPC ( Carbamate acetylcholinesterase (AChE) inhibitors such as isoprocarb), methiocarb, mesomil, MTMC (metholcarb), oxamyl, pyrimicarb, PHC (propoxyl), thiodicarb, thiophanox, triazamate, trimetacarb, XMC, MPMC (xylylcarb), acephate , Azamethiphos, azine phosethyl, azine phosmethyl, kazusafos, chloretoxyphos, CVP (chlorfen Nyphos), Chlormefos, Chlorpyrifos, Chlorpyrifosmethyl, Coumafos, CYAP (Cyanophos), Dimeton-S-methyl, Diazinon DDVP (Dichlorvos), Dicrotophos, Dimethoate, Dimethylvinphos, Ethylthiomethone (disulfoton), EPN, Ethion, Etoprophos, Fanful , Fenamiphos, MEP (fenitrothion), MPP (fenthion), phosthiazeate, heptenophos, imisiaphos, isofenphos, isopropyl-o- (methoxyaminothiophosphoryl) salicylate, isoxathion, marathon (malathion), mecarbam, methamidophos, DMTP (methidathion), mevinphos , Monocrotophos, BRP (Nared), Ometoate, Oxydimethone methyl, Parathion, Methyl Lathion (parathion methyl), PAP (fentoate), folate, hosalon, PMP (phosmet), phosphamidone, oxime, pyrimifosmethyl, propenofos, propetamphos, prothiophos, pyraclophos, pyridafenthione, quinalphos, sulfotep, tebupyrimphos, temufos, terbufos, CVMP Vinphos), thiometone, triazophos, DEP (trichlorphone), organophosphorus acetylcholinesterase (AChE) inhibitors such as bamidthione, cyclic diene organochlorine GABAergic chloride channel antagonists such as chlorden, benzoepin (endosulfan), acrinathrin, Allethrin (allethrin, d-cis-trans-, d-trans-isomer), bifenthrin, Bioareslin (bioareslin, S-cyclopentenyl-isomer), bioresmethrin, cycloproton, cyfluthrin (cyfluthrin, β-isomer), cyhalothrin (cyhalothrin, λ-, γ-isomer), cypermethrin (cypermethrin, α-, β-, θ-, ζ-isomers), cyphenothrin [(1R) -trans isomer], deltamethrin, empentrin [(EZ)-(1R) -isomer], esfenvalerate, etofenprox , Fenpropatoline, fenvalerate, flucitrinate, flumethrin, fulvalinate (τ-fulvalinate), halfenprox, imiprotorin, cadreslin, permethrin, phenothrin [(1R) -trans isomer], praretrin, pyrethrin, resmethrin, Silafluofe , Tefluthrin, phthalthrin (tetramethrin), tetramethrin [(1R) -isomer], pyrethroids such as tralomethrin and transfluthrin and sodium channel modulators such as pyrethrins, sodium channels modulators such as DDT and methoxychlor, acetamiprid, clothianidin, dinotefuran, Neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists such as imidacloprid, nitenpyram, thiacloprid and thiamethoxam, nicotinic acetylcholine receptor (nAChR) agonists such as nicotine sulfate (nicotine) and sulfoxafur, butenolide nicotinic acetylcholine such as flupiradiflon Receptor (nAChR) agonist, spinetoram, spinosad, etc. Spinosyn nicotinic acetylcholine receptor (nAChR) allosteric modulator, abamectin, emamectin benzoate, apimectin and milbemectin and other avermectin and milbemycin chloride channel activators, hydroprene, quinoprene, methoprene, phenoxycarb, pyriproxyfen, etc. Juvenile hormone analogs, methyl bromide, alkyl halides other than methyl bromide, nonspecific (multisite) inhibitors such as chloropicrin, sulfuryl fluoride, borax, and tartar, pymetrozine, Chordal organ modulators such as flonicamid, mite growth inhibitors such as clofentezin, hexythiazox, difluvidazine, etoxazole; t. subsp. israelensis, B.I. t. subsp. aizawai, B.I. t. subsp. Kurstaki, B.I. t. subsp. tenebrionis and B.E. t. Proteins contained in crops (Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry34Ab1 / Cry35Ab1), microorganism-derived insect mesenteric intestinal membrane disruptors, azofentin, Mitochondrial ATP synthase inhibitors such as tricyclohexyltin hydroxide (cyhexatin), phenbutadium oxide, BPPS (propargite), tetradiphone, oxidative phosphorylation uncouplers such as chlorfenapyr, DNOC, sulfuramide, bensultap, cartap, thiocyclam, thiosulfur Nereistoxin analog nicotinic acetylcholine receptor (nAChR) channel blockers such as tap sodium salt , Bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novallon, nobiflumuron, teflubenzuron, triflumuron and other benzoylurea chitin biosynthesis inhibitors (type 0), buprofezin Chitin biosynthesis inhibitors (type 1), fly insect insect molting inhibitors such as cyromazine, diacyl-hydrazine molting hormone (ecdysone) receptor agonists such as chromafenozide, halofenozide, methoxyphenozide, tebufenozide, octopamine receptors such as amitraz Agonists, hydramethylnon, acequinosyl, fluacrylpyrim and other mitochondrial electron transport system complex III inhibitors, phenazaquin, fenpyroximate, pyrimidifen Mitochondrial electron transport complex I inhibitors (METI) such as pyridaben, tebufenpyrad, tolfenpyrad, deris (rotenon), voltage-gated sodium channel blockers such as indoxacarb, metaflumizone, spirodiclofen, spiromesifen, spirotetramat Tetronic acid and tetramic acid derivatives such as acetyl CoA carboxylase inhibitors, aluminum phosphide mitochondrial electron transport complex IV inhibitors such as calcium phosphide, hydrogen phosphide, zinc phosphide, cyanide mitochondrial electrons such as cyanide Transmission system complex IV inhibitor, β-ketonitrile derivatives such as sienopyraphene and cyflumethofen Mitochondrial electron transport system complex II inhibitor, chlorantraniliprole, cyantraniliprole, full Diamide-type ryanodine receptor modulators such as benzamide, Steinerne capocapsae, Chili dust mite, Kukumeri Scarid mite, Shogama flies, Namihime Hanakamemushi, Tarimikumekamemushi, Onsutsutachibachi, Isaea Himekobachi, Koreman Amabatachi Natural enemies such as the mosquito, tick and nematode biological pesticides, Pasteuria penetrans, Bacillus thuringiensis (BT), Monacrosporium fimatopagum, Pekir Myces tenuipes, Boberia bronniati, Boberia vassiana Pesticides, starches, reduced starch saccharified products, machine oils, air-sealed pesticides such as sodium oleate, Konagakon-Plus, Confuser G, Confuser Pheromone such as N, Confuser V, Scashibacon, Nitorure (Ameshiro), Hamakikon-N, Peodin SL, Yotokon-H, Yotokon-S, Azadirachtin, Benzomate (Benzoximate), Bifenazate, Phenisobromolate (Bromopropylate) ), Quinoxaline (quinomethionate), sodium aluminum fluoride, kelsen (dicophol), pyridalyl, pyrifluquinazone, sulfur, ferric phosphate, metaldehyde and 1,3-dichloropropene;
Acylalanine PA fungicides (phenylamides) such as benalaxyl, benalaxyl M, furaxyl, metalaxyl, metalaxyl M, oxazolidinone PA fungicides (phenylamides) such as oxadixil, butyrolactone PA fungicides (phenylamide) such as ofulase Hydroxyl (2-amino-) pyrimidines such as bupyrimate, dimethylylmol, and ethylimole, isoxazole aromatic heterocycles such as hydroxyisoxazole (hymexazole), isothiazolone aromatic heterocycles such as octyninone, oxolinic Carboxylic acids such as acids, Benomyl, carbendazole (carbendazim), benzimidazole MBC fungicides such as fuberidazole, thiabendazole (methylbenzimidazole carba Thiophenate MBC fungicides (methyl benzimidazole carbamate) such as thiophanate, thiophanate methyl, N-phenyl carbamates such as dietofencarb, toluamide benzamides such as zoxamide, ethylaminothiazole carboxamide thiazole carboxamides such as ethaboxam, Phenylureas such as pencyclone, pyridinylmethylbenzoamide benzamides such as flupicolide, pyrimidineamines such as diflumetrim, pyrazole carboxamides such as tolfenpyrad, phenylbenzamides SDHI (succinic acid dehydration such as benodanyl, flutolanil, mepronil) Enzyme inhibitors), phenyloxoethylthiophenamide series SDHI (isofetamide, etc.) Succinate dehydrogenase inhibitors), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitors) such as fluopyram, franc carboxamide SDHI (succinate dehydrogenase inhibitors) such as fenfram, carboxin, oxy Oxatiin carboxamide SDHI (succinic acid dehydrogenase inhibitor) such as carboxin, thiazole carboxamide SDHI (succinic acid dehydrogenase inhibitor) such as tifluzamide, benzobindiflupyr, bixafen, floxapyroxad, flametopil, Pyrazole-4-carboxamide series SDHI (succinate dehydrogenase inhibitor) such as isopyrazam, penflufen, penthiopyrad, sedaxane, pyridinecarboxamide series SDHI (succinate dehydrogenase inhibitor) such as boscalid, azoxys Methoxyacrylate-based QoI bactericides (Qo inhibitors) such as thrombin, cumoxystrobin, enoxastrobin, fluphenoxystrobin, picoxystrobin, pyroxystrobin, and methoxyacetamide-based QoI bactericides such as mandestrobin Agents (Qo inhibitors), methoxycarbamate-based QoI fungicides (Qo inhibitors) such as pyraclostrobin, pyramethostrobin, triclopyricarb, oximinoacetic acid-based QoI fungicides (Qo inhibitors) such as cresoxime methyl and trifloxystrobin ), Oximinoacetamide-based QoI fungicides (Qo inhibitors) such as dimoxystrobin, phenaminestrobin, metminostrobin, orisatrobin, oxazolidinedione-based QoI fungicides (Qo inhibitors) such as famoxadone, full Dihydrodioxazine-based QoI fungicides (Qo inhibitors) such as xastrobin, imidazolinone-based QoI fungicides (Qo inhibitors) such as phenamidon, benzylcarbamate-based QoI fungicides (Qo inhibitors) such as pyribencarb, and ciazofamid Cyanoimidazole-based QiI fungicides (Qi inhibitors), sulfamoyltriazole-based QiI fungicides (Qi inhibitors) such as amisulbrom, dinitrophenylcrotonic acids such as BINAPACRIL (binapacryl), meptyldinocup, DPC (dinocup), 2,6-Dinitroanilines such as fluazinam, triphenyltin compounds such as triphenyltin acetate, triphenyltin chloride, and triphenyltin hydroxide, organic tin compounds such as sylthiofam, and thiophenecarboxamides , Triazolopyrimidylamine-based QoSi fungicides (Qo inhibitor, stigmaterine-binding type) such as amethoctrazine, anilinopyrimidine-based AP fungicides (anilinopyrimidines) such as cyprodinil, mepanipyrim, pyrimethanil, blasticidin S, etc. Enopyruronic acid antibiotics, hexopyranosyl antibiotics such as kasugamycin, glucopyranosyl antibiotics such as streptomycin, tetracycline antibiotics such as oxytetracycline, allyloxyquinoline aza-naphthalenes such as quinoxyphene, quinazolinone aza-naphthalenes such as proquinazide, fenpiclonil , Phenylpyrrole PP fungicides (phenylpyrroles) such as fludioxonil, clozolinate, iprodione, procymidone, bink Dicarboximides such as lozoline, EDDP (edifenphos), IBP (iprobenphos), phosphorothiolates such as pyrazophos, dithiolanes such as isoprothiolane, biphenyl, chloroneb, CNA (dichlorane), PCNB (quintozen), technazen, tolcrophos Aromatic hydrocarbon AH fungicides such as methyl (aromatic hydrocarbons, chlorophenyls, nitroanilines), 1,2,4-thiadiazole heteroaromatics such as echromezol (etridiazole), iodocarb, propamocarb, prothiocarb, etc. Carbamates, Bacillus subtilis QST713 strain, Bacillus subtilis FZB24 strain, Bacillus subtilis MBI600 strain, Bacillus subtilis D747 strain and the like Terpene hydrocarbons such as extracted bactericidal lipopeptide microorganisms (genus Bacillus), extracts of Goseika Yupte (tea tree) and terpene alcohol-based plant extracts, piperazine-based DMI fungicides (demethylation inhibitors such as triphorin) , SBI: class I), pyridine-based DMI fungicides (demethylation inhibitors, SBI: class I) such as pyriphenox, pyrisoxazole, and pyrimidine-based DMI fungicides (demethylation inhibitors, SBI, such as phenalimol, nuarimol) : Class I), imidazole DMI fungicides (demethylation inhibitors, SBI: class I) such as imazalyl, oxpoconazole, pefazoate, prochloraz, triflumizole, azaconazole, viteltanol, bromconazole, cyproconazole , Gifenoconazo , Diniconazole, epoxiconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, flutriazole, hexaconazole, imibenconazole, ipconazole, metconazole, microbutanyl, penconazole, propiconazole, cimeconazole, tebuconazole, tetraconazole , Triazoline DMI fungicides (demethylation inhibitors, SBI: class I) such as triazimephone, triazimenol, and triticonazole, and triazolinethione DMI fungicides (demethylation inhibitor, SBI) such as prothioconazole : Morpholine amines such as class I), aldimorph, dodemorph, fenpropimorph, tridemorph (morpholines, SBI: class II), phenpropidin, piperari Piperidine amines such as morpholine (SBI: class II), Spiroketal amine amines such as spiroxamine (morpholine, SBI: class II), and hydroxyanilides such as phenhexamide (SBI: class) III), aminopyrazolinone compounds such as fenpyrazamine (SBI: class III), thiocarbamates such as pyributycarb (SBI: class IV), allylamines such as naphthifine and terbinafine (SBI: class IV), and glucopyranosyl such as validamycin Antibiotics, peptidylpyrimidine nucleoside polyoxins such as polyoxins, cinnamic acid amide CAA fungicides (carboxylic amides) such as dimethomorph, fullmorph, pyrimorph, etc., Bench Avaricarb, Iprovaricarb, Balifu Valinamide carbamate-based CAA fungicides (carboxylic amides) such as narate, mandelic acid-based CAA fungicides (carboxylic acid amides) such as mandipropamide, isobenzofuranone-based MBI-R (melanin biosynthesis inhibitors such as fusalides) -Reductase), pyrroloquinolinone-based MBI-R (melanin biosynthesis inhibitor-reductase) such as pyrokilone, triazolobenzothiazole-based MBI-R (melanin biosynthesis inhibitor-reductase) such as tricyclazole, and cyclopropamide such as carpropamide. Propanonamide MBI-D (melanin biosynthesis inhibition) such as propanecarboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase), carboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase) such as diclocimet, and phenoxanil Agent-dehydration fermentation ), Benzothiadiazoles such as acibenzoral S methyl, benzoisothiazoles such as probenazole, thiadiazole carboxamides such as thiazinyl and isothianyl, natural polysaccharides such as laminarin, plant extracts such as giant red lily extract, cyano such as simoxanil Acetamide oximes, ethylphosphonate phosphonates such as fosetyl, phosphonates such as phosphorous acid and its salts, phthalamic acids such as teclophthalam, benzotriazines such as triazoxide, benzenesulfonamides such as fursulfamide, pyridazinones such as dichromedin Thiocarbamate compounds such as metasulfocarb, phenylacetamide compounds such as cyflufenamide, benzophenone-based allyl such as metolaphenone Phenyl ketone compounds, benzoylpyridine allyl phenyl ketone compounds such as pyriophenone, guanidines such as guanidine (dodin), cyanomethylene thiazolidine thiazolidine compounds such as fluthianyl, pyrimidinone hydrazones such as ferrimzone, and oxathiapiproline 4-quinoline acetate compounds such as peridinylthiazole isoxazolines, tebufloquine, inorganic compounds such as copper (various salts), sulfur, dithiocarbamates such as farbum, manzeb, mannebu, methylam, propineb, thiuram, dineb, ziram and Its analogs, captan, difortan (captahol), phthalimides such as holpet, chloronitriles (phthalonitrile) such as TPN (chlorotalonyl), sulfenic acid type Diclofluanid), sulfamides such as tolylfluanid, guanidines such as guazatine and iminotadine acetate / iminotazine albecylate (iminotazine), triazines such as triazine (aniladazine), and quinones such as dithianone (anthraquinones) Quinoxalines such as quinoxaline (quinomethionate), maleimides such as fluorimide, physical inhibitors such as machine oil and organic oil, bicarbonates such as potassium bicarbonate, silver, 8-hydroxyquinoline copper, dodecylbenzene Organic copper agents such as bisethylenediamine copper complex salt of sulfonic acid (II) and nonylphenol sulfonic acid copper salt, as well as dazomet, chloropicrin, methyl isothiocyanate, carbam sodium salt, ammonium N-methyldithiocarbamate Fungicides selected from the group consisting of soil disinfectants such as
Or allyloxypropionate-based acetyl CoA carboxylase (ACCase) inhibition such as clodinahop propargyl, cyhalohop butyl, diclohop methyl, phenoxaprop P ethyl, fluazihop P, haloxy hop R methyl, propaxa hop, quizalofop P ethyl Agent, cyclooxydione-based acetyl-CoA carboxylase (ACCase) inhibitors such as aroxidim, butroxidim, cretodim, cycloxydim, profoxydim, cetoxydim, tepraloxydim, and tralcoxydim, phenylpyrazoline-based acetyl-CoA carboxylase (ACCase) inhibitors such as pinoxaden, amides Sulfuron, Azimusulfuron, Bensulfuron methyl, Chlorimuron ethyl, Chlorsulfuro , Cinosulfuron, cycloalkyl sulfates Pham Ron, Etame Tosuru Freon methyl, ethoxysulfuron, flazasulfuron, flupyrsulfuron, foramsulfuron, halosulfuron-methyl,
Imazosulfuron, iodosulfuron, mesosulfuron, metsulfuron methyl, nicosulfuron, oxasulfuron, primisulflon, prosulfuron, pyrazosulfuron ethyl, rimsulfuron, sulfomethuron methyl, sulfosulfuron, thifensulfuron methyl, triasulfuron Sulfonylurea acetolactate synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors) such as tribenuronmethyl, trifloxysulfuron, triflusulfuronmethyl, tritosulfuron, imazapic, imaza Imidazolinone-based acetolactate synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors) such as metabenzmethyl, imazamox, imazapill, imazaquin, and imazetapill, chlorane Triazolopyrimidine-based acetolactate synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors) such as rammethyl, diclosram, flurosum ram, methotram, penoxsulam, bispyribac-sodium salt, pyribenzoxim, pyriftalide, pyrithiobac- Pyrimidinyl (thio) benzoate acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors) such as sodium salts, pyriminobac-methyl, etc., full carbazone-sodium salt, propoxycarbazone-sodium salt Sulfonylaminocarbonyltriazolinone-based acetolactate synthase (ALS) inhibitor (acetohydroxy acid synthase (AHAS) inhibitor), amethrin, atrazine, cyanazine, des Triazines such as trizine photosynthesis II (photochemical II) inhibitors such as trithin, dimethamethrin, promethone, promethrin, propazine (propazine), CAT (simazine), cimetrine, terbumethone, terbutyrazine, terbutrin, triethazine, hexazinone, metamitron, metribidine Photosynthesis (photochemical II) inhibitors, triazolinone photosynthesis (photochemical II) inhibitors such as amicarbazone, uracil photosynthesis (photochemical II) inhibitors such as bromacil, lenacyl and terbacil, pyridazinone photosynthesis such as PAC (chloridazone) (Photochemical II) Inhibitors, Phenylcarbamate photosynthesis (photochemical II) inhibitors such as desmedifam and phenmedifam, chlorbromulone, chlorotoluron, chloroxuron, dimeflon, DCM Urea photosynthesis (photochemical II) inhibitors such as U (diuron), ethidimuron, phenuron, fluometuron, isoproturon, isouron, linuron, metabenzthiazuron, metblomuron, methoxuron, monolinuron, nebulon, ciduron, tebuthiuron, DCPA (propanil) ), Amide photosynthesis (photochemical II) inhibitors such as CMMP (pentanochlor), nitrile photosynthesis (photochemical II) inhibitors such as bromophenoxime, bromoxynil, and ioxonyl, and benzothiadiazinone photosynthesis such as bentazone (Photochemical II) inhibitors, phenylpyridazine photosynthesis (photochemical II) inhibitors such as pyridate and pyridafor, bipyridylium photochemical I electron conversion agents such as diquat and paraquat, acifluorfen, bif Diphenyl ether protoporphyrinogen oxidase (PPO) inhibitors such as enox, clomethoxynyl (clomethoxyphene), fluoroglycofenethyl, fomesafen, halosafene, lactofen, oxyflowphene, phenylpyrazoles such as fluazolate, pyraflufenethyl Protoporphyrinogen oxidase (PPO) inhibitors, N-phenylphthalimide protoporphyrinogen oxidase (PPO) inhibitors such as sinidone ethyl, flumioxazin and full microlac pentyl, thiadiazole protos such as fluthiaset methyl and thiadimine Porphyrinogen oxidase (PPO) inhibitors, oxadiazole-based protoporphyrinogen oxidase (P O) Inhibitors, triazolinone-based protoporphyrinogen oxidase (PPO) inhibitors such as azaphenidine, carfentrazone ethyl, sulfentrazone, and oxazolidinedione-based protoporphyrinogen oxidase (PPO) inhibitors such as pentoxazone , Pyrimidinedione protoporphyrinogen oxidase (PPO) inhibitors such as benzphendizone and butaphenacyl, protoporphyrinogen oxidase (PPO) inhibitors such as pyraclonyl, profluazole and flufenpyrethyl, norflurazon, etc. Carotenoid biosynthesis in pyridinecarboxamide-based phytoene desaturase (PDS) such as diflufenican and picolinaphene, inhibitors of carotenoid biosynthesis in pyridazinone-based phytoene desaturase (PDS) Carotenoid biosynthesis inhibitors in phytoene desaturase systems (PDS) such as pesticides, beflubutamide, fluridone, flurochloridone, and flurtamone, triketone series 4-hydroxyphenylpyruvic acid dioxygenase enzymes such as mesotrione and sulcotrione (4- HPPD) inhibitors, isoxazole-based 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors such as isoxachlortol and isoxaflutol, pyrazoles such as benzophenap, pyrazolate (pyrazolinate) and pyrazoxifene 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors, 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors such as benzobicyclone, ATA (amito) Roll) and other triazole carotenoid biosynthesis (target site unknown) inhibitors, isomazolidinone carotenoid biosynthesis (target site unknown) inhibitors such as clomazone, urea carotenoid biosynthesis (target site unknown) inhibitors such as fluometuron, Diphenyl ether carotenoid biosynthesis (target site unknown) inhibitors such as acronifene, glycine EPSP synthase inhibitors such as glyphosate and glyphosate trimesium salt (sulfosato), phosphinic acid glutamine synthetase inhibitors such as glufosinate and bialaphos (villanaphos) Agents, carbamate DHP (dihydropteroic acid) synthase inhibitors such as ashram, bethrosin (benfluralin), butorarin, dinitramine, ethalfluralin, oryzalin, pendimethalin, Dinitroaniline microtubule polymerization inhibitors such as rifluralin, phosphoramidate microtubule polymerization inhibitors such as amiprophosmethyl and butamifos, pyridine microtubule polymerization inhibitors such as dithiopyr and thiazopyr, and benzamides such as propyzamide and tebutam -Based microtubule polymerization inhibitors, benzoic acid-based microtubule polymerization inhibitors such as TCTP (chlortar dimethyl), carbamate-based mitosis / microtubule formation inhibitors such as IPC (chlorprofam), profam, and carbetaamide, acetochlor , Inhibitors of chloroacetamide VLCFA (cell division inhibitors) such as alachlor, butachlor, dimetachlor, dimethenamide, metazachlor, metolachlor, petoxamide, pretilachlor, propachlor, propisochlor, tenyl chlor, Inhibitors of acetamide VLCFA (cell division inhibitor) such as namid, napropamide, naproanilide, inhibitors of oxyacetamide VLCFA (cell division inhibitor) such as flufenacet and mefenacet, inhibitors of tetrazolinone VLCFA such as fentolazamide (Cell division inhibitor), inhibitors of VLCFA (cell division inhibitor) such as anilophos, caffentrol, piperophos, nitrile cell wall (cellulose) synthesis inhibitors such as DBN (diclobenil), DCBN (chlorthiamid), and benzamides such as isoxaben Cell wall (cellulose) synthesis inhibitors, triazolocarboxamide cell wall (cellulose) synthesis inhibitors such as flupoxam, quinolinecarboxylic acid cell wall (cellulose) synthesis inhibitors such as quinchlorac, DN Dinitrophenol-based uncoupling (membrane breaking) agents such as OC, DNBP (dinoseb) and dinoterb, butyrate, hexylthiocarbam (cycloate), dimethylpiperate, EPTC, eprocarb, molinate, olvencarb, pebrate, prosulfocarb, bencho curve ( Thiobencarb), thiocarbazyl, trialate, vernarate and other thiocarbamate lipid synthesis inhibitors (non-ACCase inhibitors), phosphorodithioate-based lipid synthesis inhibitors (non-ACCase inhibitors) such as SAP (benthlide), benfrecetate, etofumesate, etc. Inhibition of benzofuran lipid synthesis (non-ACCase inhibitor), TCA, DPA (Dalapon), tetrapion (flupropanate) and other chlorocarbonic lipid synthesis inhibition (non-ACCase inhibition) Agents, chromeprop, 2,4-PA (2,4-D), 2,4-DB, dichloroprop, MCPA, MCPB, MCPP (mecoprop), etc. Benzoic acid-based indole acetic acid-like active (synthetic auxin) agents such as chloramben, MDBA (dicamba), TCBA (2,3,6-TBA), pyridinecarboxylic acid-based indole acetic acid-like activity such as clopyralide, fluroxypyr, picloram, triclopyr (Synthetic auxin) agents, quinoline carboxylic acid-based indole acetic acid-like active (synthetic auxin) agents such as quinclolac and quinmelac, indole acetic acid-like active (synthetic auxin) agents such as benazoline ethyl, and phthalate auxin transfer such as NPA (naptalam) Inhibitor, di Semicarbazone auxin transfer inhibitors such as rufenzopyr-sodium salt, arylaminopropionic acid compounds such as Framprop M methyl / isopropyl, pyrazolium compounds such as difenzocoat, organic arsenic compounds such as DSMA and MSMA, Zantomonas campestris Microorganisms such as, bromobutide, (chloro) -flurenol, cinmethyline, cumylron, dazomet, dimrone, methyldaimlone, ettobenzamide, fosamine, indanophan, carbam / carbam sodium salt, oxadichrome mehon, oleic acid, pelargonic acid, pyributycarb, chlorate and Mention may be made of herbicides selected from the group consisting of cyanates.

Among them, pesticides include carbamate acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, phenylpyrazole (fiprol) GABAergic chloride channel antagonists, pyrethroid and pyrethrin sodium channel modulators, Neonicotinoid nicotinic acetylcholine receptor (nAChR) agonist, spinosyn nicotinic acetylcholine receptor (nAChR) allosteric modulator, avermectin and milbemycin chloride channel activators, string sound organ modulators, oxidative phosphorylation uncouplers, Mitochondrial electron transport complex III inhibitor, mitochondrial electron transport complex I inhibitor (METI), voltage dependence Thorium channel blockers, tetronic acid and tetramic acid derivatives acetyl CoA carboxylase inhibitor, diamide ryanodine receptor modulators, quinoxaline (Kinomechionato) and insecticide selected from the group consisting of pyridalyl and metaldehyde;
Or acylalanine PA fungicides (phenylamides), oxazolidinone PA fungicides (phenylamides), butyrolactone PA fungicides (phenylamides), isoxazole aromatic heterocycles, benzimidazole MBC fungicides (Methylbenzimidazole carbamate), N-phenyl carbamates, phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furan carboxamide SDHI (succinate dehydrogenase inhibitor), oxathiin carboxamide SDHI (succinate dehydrogenase inhibitor), thiazole carboxamide SDHI (succinate dehydrogenase inhibitor) Enzyme inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxy Acetamide QoI fungicide (Qo inhibitor), Methoxycarbamate QoI fungicide (Qo inhibitor), Oximinoacetic acid QoI fungicide (Qo inhibitor), Oximinoacetamide QoI fungicide (Qo inhibitor), Oxazolidinedione QoI fungicide (Qo inhibitor), dihydrodioxazine QoI fungicide (Qo inhibitor), imidazolinone QoI fungicide (Qo inhibitor), benzyl carbamate QoI fungicide (Qo inhibitor), cyanoimidazole QiI fungicide (Qi inhibitor), sulfamoyl triazol QiI fungicides (Qi inhibitors), 2,6-dinitroanilines, anilinopyrimidine AP fungicides (anilinopyrimidines), phenylpyrrole PP fungicides (phenylpyrroles), dicarboximides, piperazine Type DMI fungicide (demethylation inhibitor, SBI: class I), pyridine type DMI fungicide (demethylation inhibitor, SBI: class I), pyrimidine type DMI fungicide (demethylation inhibitor, SBI: class) I), imidazole DMI fungicide (demethylation inhibitor, SBI: class I), triazole DMI fungicide (demethylation inhibitor, SBI: class I), triazolinethione DMI fungicide (demethylation) Inhibitor, SBI: class I), isobenzofuranone MBI-R (melanin biosynthesis inhibitor-reductase), pyrroloquinolinone MBI-R (melanin biosynthesis inhibitor-reductase), triazolobenzothiazole MBI-R (melanin biosynthesis inhibitor-reductase), cyclopropanecarboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase) , Carboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase), propionamide MBI-D (melanin biosynthesis inhibitor-dehydrase), benzothiadiazoles, benzoisothiazoles, thiadiazole carboxamides, cyanoacetamidooxime And bactericides selected from the group consisting of benzenesulfonamides, pyridazinones, guanidines and quinoxalines.

Pesticides include carbamate acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, phenylpyrazole (fiprol) GABAergic chloride channel antagonists, pyrethroid and pyrethrin sodium channel modulators, neo Insecticides selected from the group consisting of nicotinoid nicotinic acetylcholine receptor (nAChR) agonists, oxidative phosphorylation uncouplers, avermectin and milbemycin chloride channel activators, string sound organ modulators and diamide ryanodine receptor modulators Agent;
Or isoxazole aromatic heterocycles, benzimidazole MBC fungicide (methylbenzimidazole carbamate), phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase) Inhibitors), pyridinylethylbenzamides SDHI (succinate dehydrogenase inhibitors), furan carboxamide SDHI (succinate dehydrogenase inhibitors), oxathiin carboxamide SDHI (succinate dehydrogenase inhibitors) , Thiazolecarboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate Q I fungicides (Qo inhibitors), methoxyacetamide-based QoI fungicides (Qo inhibitors), methoxycarbamate-based QoI fungicides (Qo inhibitors), oxyiminoacetic acid-based QoI fungicides (Qo inhibitors), oxyiminoacetamide-based QoI Bactericides (Qo inhibitors), oxazolidinedione QoI bactericides (Qo inhibitors), dihydrodioxazine QoI bactericides (Qo inhibitors), imidazolinone QoI bactericides (Qo inhibitors), benzyl carbamate QoI bactericides Agent (Qo inhibitor), piperazine DMI fungicide (demethylation inhibitor, SBI: class I), pyridine DMI fungicide (demethylation inhibitor, SBI: class I), pyrimidine DMI fungicide (demethylation inhibitor) Methylation inhibitor, SBI: Class I), Imidazole-based DMI fungicide (Demethylation inhibitor, SBI: Qu Sterilization selected from the group consisting of triazole DMI fungicides (demethylation inhibitors, SBI: class I) and triazolinethiones DMI fungicides (demethylation inhibitors, SBI: class I) An agent or the like is preferable.

Specific examples of pesticides include, for example, aldicarb, bendiocarb, butcarboxyme, butoxycarboxyme, NAC (carbaryl), carbofuran, etiophencarb, BPMC (fenobcarb), formethanate, MIPC (isoprocarb), mesomil, MTMC (metholcarb) ), Oxamyl, Pirimicurve, PHC (propoxyl), Thiophanox, Triazamate, XMC, MPMC (Xylylcarb), Acephate, Azamethifos, Kazusafos, CVP (Chlorfenvinphos), Dimethon-S-methyl, DDVP (Dichlorvos), Dicrotophos , Dimethoate, dimethylvinphos, etoprophos, phenamifos, phostiazete, heptenofos, marathon (malathion), mecarbam, methamidophos, DM P (methidathion), mevinphos, monocrotophos, ometoate, oxydimethone methyl, phosphamidone, propetamphos, thiomethone, DEP (trichlorfone), bamidthione, flumethrin, fipronil, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyrithiamethyprithine, thianthisulfate Nicotine), sulfoxafurol, flupiradiflon, pyriproxyfen, methyl bromide, chlorpicrin, sulfuryl fluoride, borax, tartar, pymetrozine, flonicamid, BPPS (propargite), DNOC, cartap, thiocyclam, thiosultap Sodium salt, cyromazine, hydrogen phosphide, hydrocyanic acid, azadirachtin, sodium aluminum fluoride, , 3-dichloropropene, dicyclanil, ethylene dibromide, insecticide selected from the group consisting of Sabajira and co CFC sodium;
And flaraxil, metalaxyl, metalaxyl M, oxadixyl, ofrase, dimethylirimol, hydroxyisoxazole (hymexazole), octylinone, fenflam, carboxin, oxycarboxyl, framethopyl, metminostrobin, cyazofamid, pyrimethanil, kasugamycin, streptomycin, IBP (iprobenphos ), Echromezol (etridiazole), propamocarb, prothiocarb, pyrifenox, imazalyl, pefazoate, triflumizole, flutriahole, microbutanyl, propiconazole, tetraconazole, phenpropidine, spiroxamine, validamycin, polyoxin, iprovalicarb, pyroxylone , Simoxanyl, fosetyl, phosphorous acid and salt, full Rufamide, metasulfocarb, guanidine (dodine), ferimzone, potassium hydrogen carbonate, farbum, guazatine, iminotadine acetate / iminoctadine arbesylate (iminoctadine), copper sulfate, formaldehyde, 8-hydroxyquinoline sulfate, iodomethane, chloride 2 Contains at least one selected from the group consisting of fungicides selected from the group consisting of mercury, metham, methyl bromide, methyl isothiocyanate, myrdiomycin, nabum, phenylmercury acetate, 2-phenylphenol and poroxin. It is desirable.
Among them, the pesticide preferably contains at least one selected from the group consisting of acephate, fipronil, acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam, nitenpyram and flonicamid, and more preferably, for example, acetamiprid, Containing at least one selected from the group consisting of imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, more preferably at least one selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran and thiamethoxam It is to contain seeds, and particularly preferably to contain dinotefuran.

  “Fertilizer” is defined in the “Fertilizer Control Law of Japan” and is intended to provide chemical changes to the soil for the purpose of providing nutrition for plants or contributing to plant cultivation. It refers to "a product applied to plants for the purpose of providing them with plant nutrition".

  According to the official standards established based on the Fertilizer Control Law, nitrogenous fertilizer, phosphate fertilizer, calcareous fertilizer, organic fertilizer, compound fertilizer, calcareous fertilizer, silicic fertilizer, bitter fertilizer, manganese fertilizer, boron fertilizer It is classified as a fertilizer mixed with pesticides and others, such as trace element compound fertilizer and sludge fertilizer. The fertilizer effect can be classified into fast-acting fertilizer or slow-acting fertilizer.

As used herein, “granular” means that the solid material has a certain size.
The “slow-acting fertilizer” in the present specification is a general term for fertilizers in which the fertilization effect appears slowly, and has the feature that after fertilization, the fertilizer components are gradually eluted and the fertilization effect lasts for a long time. Specifically, for example,
(1) Nitrogenous fertilizer, phosphate fertilizer, calcareous fertilizer, organic fertilizer, compound fertilizer, calcareous fertilizer, silicic acid fertilizer (limited to silica gel fertilizer), clay soil fertilizer, manganese fertilizer, boron fertilizer, trace amount A slow-acting fertilizer (hereinafter referred to as “slow-acting compounded fertilizer”) that is granulated or shaped by blending any two or more of fertilizers mixed with pesticides and others, such as elemental compound fertilizer and sludge fertilizer.
(2) Slow-acting fertilizers manufactured by adding chemical operations to fertilizers or fertilizer raw materials in complex fertilizers. For example, based on formaldehyde-processed urea fertilizer, isobutyraldehyde condensed urea fertilizer, ammonium clay phosphate, etc. (hereinafter referred to as “chemically synthesized slow-release fertilizer”);
(3) Slow-acting coated fertilizers such as coated nitrogen fertilizer, coated phosphate fertilizer, coated potassium fertilizer, coated composite fertilizer, coated bitter manure, etc .;
(4) Slow-acting press-molding fertilizers such as tablet fertilizers whose elution of components is adjusted by press-molding; and (5) Slow-acting nitrification inhibitor-containing fertilizers containing nitrification inhibitors Among them, chemical synthetic slow-release fertilizer is preferable.

  Therefore, “slow-release granular fertilizer” means the above-mentioned slow-release fertilizer that is granular, and the quality and quantity of the fertilizer are uniform and the fertilizer effect varies in any part. Means no solid fertilizer. Specifically, it means a slow-release mixed granular fertilizer, a chemically synthesized slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressure-molded granular fertilizer, or a slow-release nitrification inhibitor-containing fertilizer. The term “slow-release granular fertilizer preparation containing pesticide” means a preparation of the above-mentioned “slow-release granular fertilizer” containing an agrochemical component, and the quality and quantity of any part of the preparation is uniform. It means a solid fertilizer formulation that has the same fertilizer and pesticide effects. As this slow-acting granular fertilizer preparation containing pesticides, for example, those granulated by chemical operation, those granulated by a granulator, pellets, tablets, coated with resin, etc. Can be mentioned.

  The particle diameter of the slow-acting granular fertilizer preparation containing an agrochemical of the present invention may be, for example, 0.1 mm to 50.0 mm, preferably less than 10 mm, more preferably less than 2 mm. The particle size can be measured using a particle size distribution measuring device or the like.

  The weight ratio of nitrogen (N), phosphorus (P) and potassium (K), which are guaranteed ingredients for a slow-release granular fertilizer formulation containing pesticides, may be any weight ratio as long as it functions as a slow-release fertilizer. Although there is no particular limitation, the weight ratio of N: P: K is, for example, 1: 1: 1 (for example, 5: 5: 5, 6: 6: 6, 7: 7: 7, 8: 8: 8, 10: 10:10) and the like, and the weight ratio of N: P: K is, for example, 1: 2: 1 (for example, 5: 10: 5), 1.2: 2: 1 (for example, 6:10: 5), 1: 3: 2 (eg, 3: 9: 6, etc.), 2: 3: 1 (eg, 4: 6: 2, etc.), etc. The weight ratio of the components, N: P: K is, for example, 2: 1: 2 (eg, 4: 2: 4), 2: 1: 3 (eg, 4: 2: 6, etc.), 3: 1: 2 (eg, : 2: 4, etc.), such as a valley-type guaranteeing component having a low weight ratio of P to N and K, and a weight ratio of N: P: K is, for example, 2: 1: 1 (for example, 6: 3: 3) A downstream guarantee component having a high weight ratio of N to P and K, such as 3: 2: 1 (for example, 9: 6: 3), and a weight ratio of N: P: K is, for example, 1: 1: 2. Specific examples of upstream guarantee components having a high weight ratio of K to N and P, such as 1: 3: 6 (for example, 3: 3: 6) and 1: 2: 3 (for example, 3: 6: 9, etc.) it can.

  Furthermore, the weight ratio of each N, P and K is as follows: nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), calcium A preparation containing any one or more fertilizer components selected from the group consisting of (Ca) and sulfur (S), or a group consisting of Chisso (N), phosphorus (P) and potassium (K) As long as it is in the range of a preparation containing at least two fertilizer components, either one may be zero.

Particularly preferred are solid or granular fertilizer pesticide formulations wherein the weight ratio of N: P: K is 6: 40: 6 (3: 20: 3) or 8: 20: 8 (2: 5: 2).
The weight ratio of the guarantee component is a numerical value indicating the minimum ratio of nitrogen (N), phosphorus (P) and potassium (K) contained in a predetermined fertilizer, and is limited to the numerical value. Is not to be done. Therefore, a fertilizer whose weight ratio is equal to or higher than the numerical value is qualified as a fertilizer, and the fertilizer is also included in the slow-acting granular fertilizer preparation containing an agricultural chemical of the present invention.

“Liquid or liquid fertilizer” indicates that the fertilizer is liquid or the fertilizer is in a liquid state. Although there is essentially no difference between the two, examples of liquid fertilizer include liquid silicate fertilizer, liquid trace element compound fertilizer, liquid by-product nitrogen fertilizer, liquid phosphate fertilizer, etc. Examples thereof include liquid nitrogen fertilizer and liquid composite fertilizer.
As a fertilizer used as a main component of the slow-release granular fertilizer containing an agricultural chemical of the present invention, a commercially available slow-release granular fertilizer can be used, and a fertilizer manufactured according to the method described in Patent Document 1 can be used. it can.

  The “non-petroleum solvent” of the present invention is a solvent having a functional group in its structure, for example, a solvent containing a hydroxyl group, a carboxyl group, an aldehyde group, etc. Among them, from the viewpoint of workability or safety, A non-petroleum solvent having a flash point of 40 ° C. or higher is preferred. For example, ether solvents, nitrile solvents, alcohol solvents such as alcohol and polyhydric alcohol, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, amines And solvent, aldehyde solvent, fatty acid ester solvent, nitrogen-containing carrier solvent, glycol ether solvent and the like.

  The specific non-petroleum solvent is not particularly limited as long as it is a solvent miscible with water to some extent, for example, a solvent having a water solubility of 100 ppm or more. For example, ether solvents such as tetrahydrofuran and 1,4-dioxane; acetonitrile, Nitrile solvents such as propionitrile, butyronitrile, isobutyronitrile, malononitrile; methanol, ethanol, propanol, isopropanol, 1-butanol, 2-butanol, isobutanol, t-butanol, allyl alcohol, ethylene glycol, 1,2 -Alcohol solvents such as propanediol (propylene glycol), 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, glycerin; acetone, methyl ethyl ketone, die Ketone solvents such as tilketone; carbonate solvents such as dimethyl carbonate, diethyl carbonate, ethylene carbonate, and propylene carbonate; ester solvents such as methyl formate, ethyl formate, methyl acetate, ethyl acetate, γ-butyrolactone, methyl lactate, and ethyl lactate Solvent: Amides such as formamide, N, N-dimethylformamide, N, N-diethylformamide, N, N-dimethylacetamide, N, N-diethylacetamide, N, N-dimethylpropionamide, N, N-dimethyllactamide Solvents such as tetramethylurea and 1,3-dimethyl-2-imidazolidinone Carbamide solvents; Sulfoxide solvents such as dimethyl sulfoxide; Sulfone solvents such as dimethylsulfone and sulfolane; Ammonia and methyl Amines such as amine, dimethylamine, diethylamine, triethylamine, isopropylamine, diisopropylamine, ethyldiisopropylamine, pyrrolidine, N-methylpyrrolidine, piperidine, N-methylpiperidine, morpholine, N-methylmorpholine, pyridine, ethanolamine Solvents; Aldehyde solvents such as formaldehyde, acetaldehyde, propionaldehyde, butanal, pentanal; Fatty acid esters such as coconut oil fatty acid methyl ester, succinic acid dimethyl ester, glutamic acid dimethyl ester, adipic acid dimethyl ester; N-methylpyrrolidone, N -Nitrogen-containing carrier solvents such as ethyl pyrrolidone.

  “Glycol ether” means a compound in which one or both of the hydroxyl groups of a diol or its condensate are etherified, such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monoisopropyl ether. , Ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol mono t-butyl ether, ethylene glycol mono 2-methylpentyl ether, ethylene glycol monohexyl ether, ethylene glycol mono 2-ethyl-hexyl ether, ethylene glycol monovinyl ether, ethylene Glycol monoallyl ether, ethylene glycol monobenzyl ether Ter, ethylene glycol monophenyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monohexyl ether, Diethylene glycol mono 2-ethylhexyl ether, diethylene glycol monoallyl ether, diethylene glycol monobenzyl ether, diethylene glycol monophenyl ether, diethylene glycol mono (methylphenyl) ether, diethyl Lenglycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, diethylene glycol divinyl ether, diethylene glycol ethyl vinyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, triethylene glycol monovinyl ether, Triethylene glycol dimethyl ether, tetraethylene glycol monophenyl ether, tetraethylene glycol diethyl ether, polyethylene glycol monomethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether , Propylene glycol monopropyl ether, propylene glycol monoisopropyl ether, propylene glycol monobutyl ether, propylene glycol phenyl ether, propylene glycol mono (methylphenyl) ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol dipropyl ether, propylene glycol diisopropyl Ether, propylene glycol dibutyl ether, propylene glycol diisobutyl ether, propylene glycol diallyl ether, propylene glycol diphenyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol Propyl ether, dipropylene glycol monobutyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol dibutyl ether, dipropylene glycol diisobutyl ether, dipropylene glycol allyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether , Tripropylene glycol monobutyl ether, butylene glycol monomethyl ether, butylene glycol dimethyl ether, isopropyl glycol, diisopropyl glycol, dimethyl diglycol, methyl ethyl diglycol, 3-methoxy-3-methyl-1-butanol, etc. Slow-acting granular with pesticide The fertilizer preparation preferably contains at least one glycol ether selected from the group consisting of these.

  Among them, suitable glycol ethers include, for example, ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol monoallyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monobenzyl ether, propylene glycol monopropyl ether, isopropyl glycol, Examples include isopropyl diglycol, dimethyl diglycol, methyl ethyl diglycol or 3-methoxy-3-methyl-1-butanol, and the slow-acting granular fertilizer preparation containing agricultural chemicals of the present invention is selected from the group consisting of these It is preferable to contain at least one kind. The most preferable slow-release granular fertilizer preparation containing an agricultural chemical of the present invention contains 3-methoxy-3-methyl-1-butanol as a glycol ether.

  “Water” means, for example, purified water, distilled water, ion-exchanged water, pure water, ultrapure water, sterilized water, filtered water, etc., and is not particularly limited, and any water can be used. In addition to the above-mentioned water, it can be used as long as it does not hinder the function and performance of the agricultural chemical, industrial water, well water, tap water, etc.

Next, the manufacturing method of the slow-acting granular fertilizer formulation containing an agrochemical of this invention is demonstrated.
A slow-acting granular fertilizer formulation containing an agrochemical, for example, contains an agrochemical (hereinafter sometimes referred to as “agrochemical component”) in a mixed solution of one or more non-petroleum solvents or one or more non-petroleum solvents and water. It can be produced by dissolving by a known method and impregnating the solution into a slow-release granular fertilizer. And if necessary, it can also be produced by mixing and impregnating the solution with a fertilizer (hereinafter sometimes referred to as “fertilizer component”), a surfactant or other compounding components.

  The order in which the pesticide is dissolved in one or more non-petroleum solvents is not particularly limited, and can be appropriately selected according to the properties of each component. There is no restriction | limiting in particular in the form of the agrochemical component used as a raw material, A solid state or a liquid state may be sufficient.

  The agrochemical component added to one or more non-petroleum solvents dissolves each component under appropriate heating or heating, with appropriate stirring, and when insoluble matter is present, for example, if necessary, a microfiltration membrane It is possible to produce a slow-release granular fertilizer formulation containing a desired agricultural chemical by impregnating the slow-release fertilizer with the filtered solution by performing filtration using an ultrafiltration membrane, reverse osmosis membrane, etc. it can. Although any filtration method can be used, it is usually advantageous to use a filter of about 1 μm. Although the temperature which prepares a slow-release granular fertilizer formulation containing an agrochemical is not specifically limited, It can carry out under room temperature, heating, or heating. The temperature of the mixed solution at the time of preparation is 0 ° C. to the boiling point of the solvent, preferably 25 ° C. to 80 ° C., particularly preferably 40 ° C. to 75 ° C.

In order to stably produce the slow-acting granular fertilizer preparation containing agricultural chemicals of the present invention, it contains one or more non-petroleum solvents or a mixture of one or more non-petroleum solvents and water prepared in advance, and an agricultural chemical. It is desirable to use a method for impregnating a slow release fertilizer with an aqueous composition.
Accordingly, an aqueous composition containing one or more non-petroleum solvents or a mixture of one or more non-petroleum solvents and water and an agrochemical (hereinafter, this aqueous composition may be referred to as “premix”). Is useful as a raw material for producing the slow-acting granular fertilizer preparation containing agricultural chemicals of the present invention.

The premix containing the agrochemical component can be produced by dissolving the agrochemicals described in paragraphs [0038] to [0041] in a non-petroleum solvent.
Suitable premixes containing agrochemical ingredients are glycol ethers as non-petroleum solvents, preferably ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol monoallyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, At least one selected from the group consisting of diethylene glycol monobenzyl ether, propylene glycol monopropyl ether, isopropyl glycol, diisopropyl glycol, dimethyl diglycol, methyl ethyl diglycol and 3-methoxy-3-methyl-1-butanol, more preferred The glycol ether contains 3-methoxy-3-methyl-1-butanol as an agrochemical, A premix containing at least one neonicotinoid selected from the group consisting of pride, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, more preferably dinotefuran. In addition, the premix containing an agrochemical component can be impregnated in a slow release fertilizer by adding water and / or liquid or liquid fertilizer as appropriate.

Examples of premixes containing glycol ether, agricultural chemicals and water include dinotefuran-ethylene glycol monoisopropyl ether-water solution, dinotefuran-ethylene glycol monobutyl ether-water solution, dinotefuran-ethylene glycol monoisobutyl ether-water solution, dinotefuran-ethylene glycol mono Allyl ether-water solution, dinotefuran-diethylene glycol monomethyl ether-water solution, dinotefuran-diethylene glycol monoisopropyl ether-water solution, dinotefuran-diethylene glycol monobutyl ether-water solution, dinotefuran-diethylene glycol monoisobutyl ether-water solution, dinotefuran-diethylene glycol monobenzyl ether-water solution, dinotefuran- Diechi N-glycol dimethyl ether-water solution, dinotefuran-diethylene glycol diethyl ether-water solution, dinotefuran-diethylene glycol methyl ethyl ether-water solution, dinotefuran-triethylene glycol monomethyl ether-water solution, dinotefuran-triethylene glycol monobutyl ether-water solution, dinotefuran-triethylene glycol dimethyl ether- Aqueous solution, dinotefuran-polyethylene glycol monomethyl ether-aqueous solution, dinotefuran-propylene glycol monomethyl ether-aqueous solution, dinotefuran-propylene glycol monopropyl ether-aqueous solution, dinotefuran-dipropylene glycol monomethyl ether-aqueous solution, dinotefuran-tripropylene glycol monomethyl ether Ter-water solution, dinotefuran-3-methoxy-3-methyl-1-butanol-water solution, imidacloprid-ethylene glycol monoisopropyl ether-water solution, imidacloprid-ethylene glycol monobutyl ether-water solution, imidacloprid-ethylene glycol monoisobutyl ether-water solution, imidacloprid -Ethylene glycol monoallyl ether-aqueous solution, imidacloprid-diethylene glycol monomethyl ether-aqueous solution, imidacloprid-diethylene glycol monoisopropyl ether-aqueous solution, imidacloprid-diethylene glycol monobutyl ether-aqueous solution, imidacloprid-diethylene glycol monoisobutyl ether-aqueous solution, imidacloprid-diethylene glycol mono Benzyl ether-water solution, imidacloprid-diethylene glycol dimethyl ether-water solution, imidacloprid-diethylene glycol diethyl ether-water solution, imidacloprid-diethylene glycol methyl ethyl ether-water solution, imidacloprid-triethylene glycol monomethyl ether-water solution, imidacloprid-triethylene glycol monobutyl ether-water solution, imidacloprid -Triethylene glycol dimethyl ether-aqueous solution, imidacloprid-polyethylene glycol monomethyl ether-aqueous solution, imidacloprid-propylene glycol monomethyl ether-aqueous solution, imidacloprid-propylene glycol monopropyl ether-aqueous solution, imidacloprid-dipropylene glycol Lumpur monomethyl ether - aqueous, imidacloprid - tripropylene glycol monomethyl ether - aqueous, imidacloprid-3-methoxy-3-methyl-1-butanol - water solution,
Clothianidin-ethylene glycol monoisopropyl ether-water solution, clothianidin-ethylene glycol monobutyl ether-water solution, clothianidin-ethylene glycol monoisobutyl ether-water solution, clothianidin-ethylene glycol monoallyl ether-water solution, clothianidin-diethylene glycol monomethyl ether-water solution, clothianidin-diethylene glycol Monoisopropyl ether-water solution, clothianidin-diethylene glycol monobutyl ether-water solution, clothianidin-diethylene glycol monoisobutyl ether-water solution, clothianidin-diethylene glycol monobenzyl ether-water solution, clothianidin-diethylene glycol dimethyl ether-water solution, clothia Nidin-diethylene glycol diethyl ether-water solution, clothianidin-diethylene glycol methyl ethyl ether-water solution, clothianidin-triethylene glycol monomethyl ether-water solution, clothianidin-triethylene glycol monobutyl ether-water solution, clothianidin-triethylene glycol dimethyl ether-water solution, clothianidin-polyethylene glycol Monomethyl ether-water solution, clothianidin-propylene glycol monomethyl ether-water solution, clothianidin-propylene glycol monopropyl ether-water solution, clothianidin-dipropylene glycol monomethyl ether-water solution, clothianidin-tripropylene glycol monomethyl ether-water solution, clothianidin -3-methoxy-3-methyl-1-butanol-water solution,
Thiamethoxam-ethylene glycol monoisopropyl ether-water solution, thiamethoxam-ethylene glycol monobutyl ether-water solution, thiamethoxam-ethylene glycol monoisobutyl ether-water solution, thiamethoxam-ethylene glycol monoallyl ether-water solution, thiamethoxam-diethylene glycol monomethyl ether-water solution, thiamethoxam-diethylene glycol Monoisopropyl ether-water solution, thiamethoxam-diethylene glycol monobutyl ether-water solution, thiamethoxam-diethylene glycol monoisobutyl ether-water solution, thiamethoxam-diethylene glycol monobenzyl ether-water solution, thiamethoxam-diethylene glycol dimethyl ether-water solution, thiameth Xam-diethylene glycol diethyl ether-water solution, thiamethoxam-diethylene glycol methyl ethyl ether-water solution, thiamethoxam-triethylene glycol monomethyl ether-water solution, thiamethoxam-triethylene glycol monobutyl ether-water solution, thiamethoxam-triethylene glycol dimethyl ether-water solution, thiamethoxam-polyethylene glycol Monomethyl ether-water solution, thiamethoxam-propylene glycol monomethyl ether-water solution, thiamethoxam-propylene glycol monopropyl ether-water solution, thiamethoxam-dipropylene glycol monomethyl ether-water solution, thiamethoxam-tripropylene glycol monomethyl ether-water solution, thiamethoxam -3-methoxy-3-methyl-1-butanol-water solution,
Acetamiprid-ethylene glycol monoisopropyl ether-water solution, acetamiprid-ethylene glycol monobutyl ether-water solution, acetamiprid-ethylene glycol monoisobutyl ether-water solution, acetamiprid-ethylene glycol monoallyl ether-water solution, acetamiprid-diethylene glycol monomethyl ether-water solution, acetamiprid-diethylene glycol Monoisopropyl ether-water solution, acetamiprid-diethylene glycol monobutyl ether-water solution, acetamiprid-diethylene glycol monoisobutyl ether-water solution, acetamiprid-diethylene glycol monobenzyl ether-water solution, acetamiprid-diethylene glycol dimethyl ether-water solution, acetami Prido-diethylene glycol diethyl ether-water solution, acetamiprid-diethylene glycol methyl ethyl ether-water solution, acetamiprid-triethylene glycol monomethyl ether-water solution, acetamiprid-triethylene glycol monobutyl ether-water solution, acetamiprid-triethylene glycol dimethyl ether-water solution, acetamiprid-polyethylene glycol Monomethyl ether-water solution, acetamiprid-propylene glycol monomethyl ether-water solution, acetamiprid-propylene glycol monopropyl ether-water solution, acetamiprid-dipropylene glycol monomethyl ether-water solution, acetamiprid-tripropylene glycol monomethyl ether-water solution, acetamiprid -3-methoxy-3-methyl-1-butanol-water solution,
Thiacloprid-ethylene glycol monoisopropyl ether-water solution, thiacloprid-ethylene glycol monobutyl ether-water solution, thiacloprid-ethylene glycol monoisobutyl ether-water solution, thiacloprid-ethylene glycol monoallyl ether-water solution, thiacloprid-diethylene glycol monomethyl ether-water solution, thiacloprid-diethylene glycol Monoisopropyl ether-water solution, thiacloprid-diethylene glycol monobutyl ether-water solution, thiacloprid-diethylene glycol monoisobutyl ether-water solution, thiacloprid-diethylene glycol monobenzyl ether-water solution, thiacloprid-diethylene glycol dimethyl ether-water solution, thiaclo Pride-diethylene glycol diethyl ether-water solution, thiacloprid-diethylene glycol methyl ethyl ether-water solution, thiacloprid-triethylene glycol monomethyl ether-water solution, thiacloprid-triethylene glycol monobutyl ether-water solution, thiacloprid-triethylene glycol dimethyl ether-water solution, thiacloprid-polyethylene glycol Monomethyl ether-water solution, thiacloprid-propylene glycol monomethyl ether-water solution, thiacloprid-propylene glycol monopropyl ether-water solution, thiacloprid-dipropylene glycol monomethyl ether-water solution, thiacloprid-tripropylene glycol monomethyl ether-water solution, thiacloprid -3-methoxy-3-methyl-1-butanol-water solution,
Nitenpyram-ethylene glycol monoisopropyl ether-water solution, nitenpyram-ethylene glycol monobutyl ether-water solution, nitenpyram-ethylene glycol monoisobutyl ether-water solution, nitenpyram-ethylene glycol monoallyl ether-water solution, nitenpyram-diethylene glycol monomethyl ether-water solution, nitenpyram-diethylene glycol Monoisopropyl ether-water solution, nitenpyram-diethylene glycol monobutyl ether-water solution, nitenpyram-diethylene glycol monoisobutyl ether-water solution, nitenpyram-diethylene glycol monobenzyl ether-water solution, nitenpyram-diethylene glycol dimethyl ether-water solution, nitenpyram-diethyleneglycol Cole diethyl ether-water solution, nitenpyram-diethylene glycol methyl ethyl ether-water solution, nitenpyram-triethylene glycol monomethyl ether-water solution, nitenpyram-triethylene glycol monobutyl ether-water solution, nitenpyram-triethylene glycol dimethyl ether-water solution, nitenpyram-polyethylene glycol monomethyl ether -Aqueous solution, nitenpyram-propylene glycol monomethyl ether-aqueous solution, nitenpyram-propylene glycol monopropyl ether-aqueous solution, nitenpyram-dipropylene glycol monomethyl ether-aqueous solution, nitenpyram-tripropylene glycol monomethyl ether-aqueous solution, nitenpyram-3-methoxy-3- Methyl-1-butanol -Aqueous solutions, etc.
Preferably, dinotefuran-ethylene glycol monobutyl ether-water solution, dinotefuran-ethylene glycol monoisobutyl ether-water solution, dinotefuran-ethylene glycol monoallyl ether-water solution, dinotefuran-diethylene glycol monobutyl ether-water solution, dinotefuran-diethylene glycol monoisobutyl ether-water solution, Dinotefuran-diethylene glycol monobenzyl ether-water solution, dinotefuran-propylene glycol monopropyl ether-water solution, dinotefuran-3-methoxy-3-methyl-1-butanol-water solution,
Imidacloprid-ethylene glycol monobutyl ether-water solution, imidacloprid-ethylene glycol monoisobutyl ether-water solution, imidacloprid-ethylene glycol monoallyl ether-water solution, imidacloprid-diethylene glycol monobutyl ether-water solution, imidacloprid-diethylene glycol monoisobutyl ether-water solution, imidacloprid-diethylene glycol monohydrate Benzyl ether-water solution, imidacloprid-propylene glycol monopropyl ether-water solution, imidacloprid-3-methoxy-3-methyl-1-butanol-water solution,
Clothianidin-ethylene glycol monobutyl ether-water solution, clothianidin-ethylene glycol monoisobutyl ether-water solution, clothianidin-ethylene glycol monoallyl ether-water solution, clothianidin-diethylene glycol monobutyl ether-water solution, clothianidin-diethylene glycol monoisobutyl ether-water solution, clothianidin-diethylene glycol mono Benzyl ether-water solution, clothianidin-propylene glycol monopropyl ether-water solution, clothianidin-3-methoxy-3-methyl-1-butanol-water solution,
Thiamethoxam-ethylene glycol monobutyl ether-water solution, thiamethoxam-ethylene glycol monoisobutyl ether-water solution, thiamethoxam-ethylene glycol monoallyl ether-water solution, thiamethoxam-diethylene glycol monobutyl ether-water solution, thiamethoxam-diethylene glycol monoisobutyl ether-water solution, thiamethoxam-diethylene glycol mono Benzyl ether-water solution, thiamethoxam-propylene glycol monopropyl ether-water solution, thiamethoxam-3-methoxy-3-methyl-1-butanol-water solution,
Acetamiprid-ethylene glycol monobutyl ether-water solution, Acetamiprid-ethylene glycol monoisobutyl ether-water solution, Acetamiprid-ethylene glycol monoallyl ether-water solution, Acetamiprid-diethylene glycol monobutyl ether-water solution, Acetamiprid-diethylene glycol monoisobutyl ether-water solution, Acetamiprid-diethylene glycol mono Benzyl ether-water solution, acetamiprid-propylene glycol monopropyl ether-water solution, acetamiprid-3-methoxy-3-methyl-1-butanol-water solution, etc.
More preferably, dinotefuran-3-methoxy-3-methyl-1-butanol-water solution, imidacloprid-3-methoxy-3-methyl-1-butanol-water solution, clothianidin-3-methoxy-3-methyl-1-butanol -Aqueous solution, thiamethoxam-3-methoxy-3-methyl-1-butanol-water solution, acetamiprid-3-methoxy-3-methyl-1-butanol-water solution, etc.
Most preferred is dinotefuran-3-methoxy-3-methyl-1-butanol-water solution.

In the slow-acting granular fertilizer preparation containing the agricultural chemical of the present invention, any agricultural chemical component such as an insecticide, a bactericidal agent, a herbicide, or a plant regulator can be blended as the agricultural chemical component.
Examples of the plant regulator component include maleic hydrazide and salts thereof, abscisic acid, rice benfide, paclobutrazol, uniconazole, tripentenol, or psychocell.
As an agrochemical component, any solid, semi-solid, or liquid at room temperature can be used. It is possible to combine two or more different types of subjects, such as insecticides, fungicides or herbicides.

  The agrochemical component and the non-petroleum solvent to be used are not particularly limited as long as these two components are contained, but suitable ranges thereof include 0.01% to 10% of the agrochemical component and a non-petroleum solvent. 0.1% to 10%, fertilizer component total weight 0.1% to 99.9%, more preferably 0.01% to 10% agricultural chemical component, 0.1% non-petroleum solvent -10%, total fertilizer component weight 0.1% -99.8%, more preferably 0.03% -5% agricultural chemical component, 0.1% -10% non-petroleum solvent, fertilizer component The total weight is 50.0% to 99.9%.

  In addition to the above-described blending components, a surfactant can be blended in the slow-acting granular fertilizer preparation containing agrochemicals as necessary. The surfactant is not particularly limited as long as it is usually used in an agrochemical formulation. For example, a nonionic surfactant, an anionic surfactant, or a cationic surfactant can be used, and preferably a nonionic interface. One type or two or more types of activators and anionic surfactants, more preferably one type or two or more types of nonionic surfactants can be mixed and used.

Specific examples of the surfactant include, for example, polyoxyethylene alkyl aryl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene polystyryl phenyl ether, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene oleyl ester, polyoxyethylene Nonionic surfactants such as ethylene fatty acid esters and sorbitan fatty acid esters;
Fatty acid salt, alkyl sulfate ester salt, alkyl benzene sulfonate, α-olefin sulfonate, alkyl sulfosuccinate, polyoxyethylene alkylaryl ether sulfate and phosphate, polyoxyethylene styrylphenyl ether sulfate and phosphate and alkylamine salt Anionic surfactants such as;
Examples include cationic surfactants such as primary to tertiary fatty amine salts, alkylammonium chloride salts, tetraalkylammonium salts, trialkylbenzylammonium salts, alkylpyridinium salts, alkylhydroxyethylimidazolinium salts, and more An anionic surfactant and a cationic surfactant compound type surfactant are also included. These surfactants may be used alone or in combination of two or more. The compounding quantity is 0.1-70 weight part normally in an agrochemical liquid mixture, Preferably it is 0.1-30 weight part, More preferably, it is 0.1-10 weight part.

  In addition to the above-described blending components, additives can be blended in the slow-acting granular fertilizer preparation containing agricultural chemicals as necessary. Examples of additives include pH adjusters for improving the stability of agricultural chemical ingredients, such as lactic acid, hydrochloric acid, phosphoric acid, sodium citrate, citric acid, disodium hydrogen phosphate, sodium dihydrogen phosphate, hydrogen phosphate. Slow release with pesticides such as dipotassium, potassium dihydrogen phosphate, phthalic acid, potassium hydrogen phthalate, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, succinic acid, sodium borate, N-ethylmorpholine The blending ratio is 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight, based on the total amount of the granular fertilizer preparation. As antioxidant, dibutylhydroxytoluene etc. can be mix | blended by the mixture ratio 0.001-1 weight part, Preferably 0.005-0.5 weight part. As the ultraviolet absorber, 2-hydroxy-4-n-octoxybenzophenone or the like can be blended at a blending ratio of 0.001 to 1 part by weight, preferably 0.005 to 0.5 part by weight. As an antifoaming agent, an acetylene glycol type antifoaming agent, a silicone type antifoaming agent, a fluorine type antifoaming agent, a fatty acid type antifoaming agent, etc. are blended in an amount of 0.001 to 5 parts by weight, preferably 0.01 to 2. It can mix | blend by a weight part. As the antibacterial agent, benzothiazole derivatives, sorbic acid, potassium sorbate, butyl p-oxybenzoate, glutaraldehyde, thiazolone, BNPK (2-bromo-2-nitropropane-1,3-diol), etc. The blending ratio can be 0.01 to 5 parts by weight, preferably 0.01 to 2 parts by weight.

  In addition, auxiliary agents described later such as colorants, crystal precipitation inhibitors, thickeners, dispersants, chelating agents, effect expression accelerators, composition homogenizers, and nitrification inhibitors are added as necessary. However, these adjuvants are not limited to those exemplified here.

  Examples of the colorant include azoic dyes, azo dyes, acridines, aniline dyes, aniline black, indanthrene, eosin, congo red, dihydroindole, methylene blue, phenazine derivative dyes, neutral red, phenolphthalein, fuchsin, fluorescein, para red. , Mauve, carotene; carotenoids such as xanthophyll, cryptoxanthine, zeaxanthin, fucoxanthin, lycopene, lutein; flavonoids such as flavones, flavanone, anthrochlor, anthocyan, catechin; quinones such as melanin; chlorophyll, chlorophyllide, bacteriochlorophyll , Cytochrome, pheophorbide, pheoporphyrin, hemerythrin, hemoglobin, hemovanadine, hemocyanin, porfu Porphyrin pigments such as phosphorus, porphine, myoglobin; phycobilin pigments such as phycocyanin, phycobilin, phycoerythrin, phytochrome, biliverdin, bilirubin; alizarin, anthocyan, anthraquinone, indigo, urobilin, erythrocruolin, cartamine, xanthone, Curcumin, crocetin, chlorin, chlorocruoline, genistein, cochineal, gossypol, conmelinin, shikonin, stercopyrine, tannin, tulasin, bixin, hypericin, pinnaglobin, brazirin, purpurin, betacyanin, berberine, horbilin, mangosteen (mangostin) Leghemoglobin, litmus, rhodopsin, rhodoxanthin, rhodomatine In addition, for example, carbon black, bengara, solvent red 23, C.I. Acid Blue 1 (C.I. Acid Blue 1), C.I. Acid Yellow 23 (C.I. Acid Yellow 23), etc. Can be mentioned.

  Examples of the crystal precipitation inhibitor include ethylene glycol, propylene glycol, glycerin, cyclodextrins, and alkylene oxide adducts of glycerin.

Examples of the thickener include products available from Sanki Co., Ltd., for example, roast bean gum such as MEYPROLBG FULL ^™ M-200, guar gum such as SUPERGEL ^™ 200, JAGUAR ^™ C-13S, etc. guar gum derivatives, carrageenan, such as WG-108, pectins such as ^{YM-150-LJ TM,} xanthan gum, such as KELZAN ^TM, gellan gum such as KELCOGEL ^TM AFT, diutan gums such as ^{KELCO-CRETE TM DG, SB gUM} -R TM starches such as, dextrins such as MALTRIN ^(R) M040, cellulose derivatives such as Finnfix ^TM (carboxymethylcellulose derivatives), can be cited tara gum such Supinogamu .

Examples of the dispersant include products available from Kao, etc., for example, β-naphthalenesulfonic acid formalin condensate sodium salt such as Demol ^TM N, and special aromatic sulfonic acid formalin such as Demol ^TM SN-B. Sodium salt of condensate, special polycarboxylic acid type polymer surfactant such as demole ^TM P, polycarboxylic acid sodium salt such as Nop Cospers ^TM 44-C, polycarboxylic acid ammonium salt such as Nop Cospers ^TM 5600, SN Dispersant ^TM Examples include special polycarboxylic acid ammonium salts such as 5023, neutralized polyphosphate amino alcohols such as SN Dispersant ^TM 2060, and condensed naphthalene sulfonic acid ammonium salts such as Roma PWA-40 ^TM .

Examples of the chelating agent include products available from Cylest Co., Ltd., but include EDTA (Ethylene Diamine Tetraacetic Acid), NTA (Nitrilo Triacetic Acid), DTPA (Diethylene Triminee Pentaetic Acid), and EDTA. Acid), TTHA (Triethylene Tetramine Hexaacid Acid), PDTA (1,3-Propaneamine Tetraacetic Acid), DPTA-OH (1,3-Diamino-2-hydroxypropanetic Acid) , HIDA (Hydroxyethyl Imino Diacetic Acid), DHEG (Dihydroxyethyl Glycine), GEDTA (Glycol Ether Diamine Tetraacetic Acid), CMGA (Dicarboxymethyl Glutamic Acid), EDDS ((S, S) -Ethylene Diamine Disuccinic Acid), HEDP (Hydroxyethylidene Diphosphonic Acid ), NTMP (Nitrilotis (Methylene Phosphonic Acid)), PBTC (Phosphobutane Tricarboxylic Acid), EDTMP (Ethylene Diamine T) etra (Methylene Phosphonic Acid)), EDTA metal salts such as EDTA · Fe · Na · H ₂ O, DTPA metal salts such as DTPA · Fe · Na · H, PDTA metals such as PDTA · Fe · NH ₄ · H ₂ O Salt, HOCH ₂ (CHOH) ₄ COONa, and the like.

  Examples of the effect expression accelerator include ferrous sulfate, copper sulfate, zinc sulfate, and ammonium molybdate.

  Examples of the composition homogenization accelerator include gypsum, paraffin and mineral oil, corn starch, zeolite, and the like.

When water and / or liquid or liquid fertilizer is used, examples of nitrification inhibition include 2-amino-4-chloro-6-methylpyrimidine (AM) and N-2,5-dichlorophenylsuccinamic acid. (DCS), dicyandiamide, 1-amidino-2-thiourea (ASU) and the like.
Moreover, the water to be used is not specifically limited, for example, purified water, distilled water, ion exchange water, pure water, ultrapure water, sterilized water, filtered water, and any water can be used.

  A slow-acting granular fertilizer preparation containing an agrochemical can be usually used as planting treatment, stock treatment, or soil mixing. When applying the prepared slow-release granular fertilizer preparation containing agricultural chemicals to plants, it can be used as it is. Although the usage-amount with respect to a plant is determined by the content of the slow-release granular fertilizer formulation containing an agricultural chemical, it can use 1g-20g per strain.

  The plant that can be applied is not particularly limited as long as it can be applied to the slow-release granular fertilizer preparation containing the agricultural chemical of the present invention, in the agricultural field, for example, in the horticultural field, such as crops, craft crops, feed crops, For example, vegetables, fruit trees, flower buds and the like can be mentioned.

  Specifically, flowers; potted flowers; vegetables including fruit vegetables, leaf vegetables, root vegetables; flower trees; fruit trees including deciduous fruit trees and evergreen fruit trees; lawns; garden trees; wildflowers; bulbs; foliage plants; Can be mentioned.

  When used for planting treatment, plant stock treatment, and soil mixing, generally depending on the type and content of active ingredient, a slow-release granular fertilizer preparation containing pesticides is directly measured and processed. Moreover, the application amount and application time of the slow-acting granular fertilizer preparation containing the agricultural chemical can be appropriately determined according to the active ingredient of the agricultural chemical to be blended.

  Furthermore, as described above, the slow-release granular fertilizer preparation containing the agricultural chemical of the present invention can be applied to plants alone, but the following liquid fertilizer is used together with the slow-release granular fertilizer preparation containing the agricultural chemical of the present invention. Can be used in combination.

As a specific example of the combined use method, after applying the slow-release granular fertilizer formulation containing the agricultural chemical of the present invention, for example, a liquid fertilizer, a fertilizer applied by solubilizing a powder fertilizer in water, a liquid fertilizer such as a liquid fertilizer containing agricultural chemical Can be applied. The concentration and application rate of the liquid fertilizer to be applied can be appropriately selected in consideration of the target plant and the state of the plant. For example, a suitable application rate of the liquid fertilizer diluted 250 to 2000 times is ² to 3 L / m ² .

  Specific examples of liquid fertilizers used in combination include liquid fertilizers such as Hyponex undiluted solution, flower factory undiluted solution, vegeful liquid fertilizer, liquid fertilizer of Myrose rose; fine powder Hyponex that is a powder fertilizer, and water-soluble high purity powder containing various trace elements Fertilizer Peters, water-soluble horticultural fertilizers OK-F-1, OK-F-3, OK-F-9, OK-F-12, OK-F-17, OK Ace, OK Special Fertilizers solubilized and applied; Examples of liquid fertilizers containing pesticides include Hyponex undiluted pesticides.

  EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples.

Example 1 (slow-acting granular fertilizer formulation with agricultural chemicals)
0.2 parts of dinotefuran raw material, 0.2 parts of 3-methoxy-3-methyl-1-butanol (manufactured by Kuraray Co., Ltd., trade name Solfit) and 3.6 parts of water were mixed to obtain a premix. This premix was added to and mixed with a slow-acting granular fertilizer Magnamp K (manufactured by Hyponex Japan Co., Ltd.) to obtain a slow-acting granular fertilizer containing dinotefuran.

Example 2
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to isopropyl glycol (product name: iPG, manufactured by Nippon Emulsifier Co., Ltd.) in Example 1 above. Sexual fertilizer was obtained.

Example 3
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to isopropyl diglycol (product name: iPDG, manufactured by Nippon Emulsifier Co., Ltd.) in Example 1 above. An effective granular fertilizer was obtained.

Example 4
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to dimethyl diglycol (trade name DMDG, manufactured by Nippon Emulsifier Co., Ltd.) in Example 1 above. An effective granular fertilizer was obtained.

Example 5
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to methyl ethyl diglycol (trade name MEDG, manufactured by Nippon Emulsifier Co., Ltd.), and dinotefuran was added. A slow-acting granular fertilizer was obtained.

Example 6
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to diethylene glycol monobutyl ether (manufactured by Dow Chemical Japan Co., Ltd., trade name BUTYLCARBITOL) in Example 1, and dinotefuran. A slow-release granular fertilizer was obtained.

Example 7
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to methyl lactate (trade name: PURASOLV ML, manufactured by Covion Japan Co., Ltd.), and dinotefuran was added. A slow-acting granular fertilizer was obtained.

Example 8
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to N-ethylpyrrolidone (made by MYI Chemical Co, Ltd., trade name NEP) in Example 1 above, A slow-acting granular fertilizer containing dinotefuran was obtained.

Example 9
The same treatment as in Example 1 except that 3-methoxy-3-methyl-1-butanol was changed to N, N-dimethyl lactamide (product name: N, N-dimethyllactamide, manufactured by Corbion Purac) in Example 1 above. To obtain a slow-acting granular fertilizer containing dinotefuran.

Example 10
The same treatment as in Example 1 was performed except that the dinotefuran raw material was changed to a himexazole raw material in Example 1 to obtain a slow-acting granular fertilizer containing himexazole.

Example 11
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was increased to 2.0 parts and water was reduced to 1.8 parts in Example 1 above. An effective granular fertilizer was obtained.

Comparative Example 1
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to solvent naphtha (trade name Solvesso 100, manufactured by ExxonMobil Co., Ltd.) in Example 1 above. An effective granular fertilizer was obtained.

Comparative Example 2
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to solvent naphtha (product name: Naphthezol 220, manufactured by Gordo Solvent Co., Ltd.) in Example 1, and dinotefuran-containing An effective granular fertilizer was obtained.

Comparative Example 3
The same treatment as in Example 1 was carried out except that 3-methoxy-3-methyl-1-butanol was changed to liquid paraffin (made by Idemitsu Kosan Co., Ltd., trade name Daphne Oil SY-15) in Example 1 above, A slow-acting granular fertilizer containing dinotefuran was obtained.

Comparative Example 4
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to isodecyl phthalate (manufactured by Shin Nippon Rika Co., Ltd., trade name Sunsizer DIDP). A slow-acting granular fertilizer containing dinotefuran was obtained.

  In order to show the usefulness of the slow-release granular fertilizer preparation containing an agricultural chemical of the present invention, the following Test Example 1 (manufacturability of premix), Test Example 2 (whether or not impregnation into slow-release granular fertilizer), Test Example 3 (Formulation stability) and Test Example 4 (germination inhibition test) were performed.

Test Example 1 (Premix productivity)
In the preparation of the premix, the solubility of dinotefuran was visually evaluated. The results are shown in Table 1. Evaluation criteria are: ○: completely dissolved, x: agrochemical active ingredient is suspended.

Test Example 2 (Possibility of impregnation of premix into slow-release granular fertilizer containing pesticides)
Whether the prepared premix was impregnated into a slow-release granular fertilizer containing pesticides was evaluated. The results are shown in Table 1. Judgment criteria indicate that ◯: uniform processing is possible without problems, Δ: processing is possible but non-uniform, and X: processing is not possible.

Test Example 3 (Formulation stability)
The prepared sample was put in an aluminum bag and subjected to aging for 2 weeks at 54 ° C., and the state of the sample after aging was confirmed. The results are shown in Table 1. Judgment criteria are: ○: no change, x: deterioration such as solidification and crystal precipitation.

Test Example 4 (germination inhibition test)
The germination inhibition test of the slow-acting granular fertilizer preparation containing agricultural chemicals according to the present invention is carried out by a method of a cultivation test on damage to plants according to the notice of No. 1943, No. 1943 dated April 18, 1984 in Japan. The test was conducted in accordance with (Extract).
A pot having a diameter of 11.3 centimeters and a height of 6.5 centimeters (Neubauer pot) was used. As the test fertilizer, 5 g and 10 g of a slow-release granular fertilizer preparation containing agricultural chemicals were used per liter of the test soil. As a control fertilizer, Magamp K, a slow-acting granular fertilizer having the same fertilizer components as the test fertilizer, was used.
The test soil used was a mixture of peat moss, akadama earth, and pearlite in a 4: 3: 3 ratio.
Komatsuna was used as the prototype.
The test soil was filled into a test container so as to be about 500 ml.
(I) The test area provided a standard amount application area and a double amount application area using the test fertilizer and the control fertilizer.
(B) Test plot for the test fertilizer According to the amount of ingredients in the prototype of the slow-release granular fertilizer preparation containing pesticides, the standard application area was 5 g per liter of soil, and the double application quantity was 10 g. .
(C) Test plots for the control fertilizer The test plots using the control fertilizer were provided according to those using the test fertilizer.
(D) Method of fertilization The fertilizer was applied by mixing well with the soil in the entire test container.
(E) Seeds and seed methods of crops The seed amount was 20 per test container.
The seeds were formed using tweezers or the like so that the seeds were equally spaced, and after seeding, the seeds were covered with air-dried soil so that the seeds were hidden.
The soil moisture during the test period was replenished with water to maintain the moisture state at the start of the test for about 10 days after the start of the test, and then water was appropriately supplied according to the growth of the crop. The cultivation temperature during the test period was kept in the range of 15 to 25 degrees Celsius. The cultivation period was 25 days after seeding.
Regarding the preparations of Example 1, Example 2, Example 3, Example 7, Example 8, and Example 9 of the present invention, the germination rate and presence / absence of abnormal symptoms were investigated. The results are shown in Table 2.

  ADVANTAGE OF THE INVENTION According to this invention, the phytotoxicity with respect to a plant does not generate | occur | produce but a safe slow-release granular fertilizer formulation containing an agricultural chemical can be provided.

Claims (16)

  A slow-release granular fertilizer formulation containing a pesticide containing a non-petroleum solvent and a pesticide active ingredient.   The formulation according to claim 1, wherein the water solubility of the non-petroleum solvent is 100 ppm or more.   Non-petroleum solvents are ether solvents, nitrile solvents, alcohol solvents, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, amine solvents, aldehydes The preparation according to claim 1 or 2, which is a system solvent, a fatty acid ester solvent, a nitrogen-containing carrier solvent or a glycol ether solvent.   The preparation according to any one of claims 1 to 3, wherein the non-petroleum solvent is a glycol ether solvent.   The preparation according to any one of claims 1 to 4, further comprising water and / or liquid or liquid fertilizer. Pesticides are carbamate acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, cyclic diene organochlorine GABA agonist chloride channel antagonists, phenylpyrazole (fiprole) GABA agonist chloride channels Antagonist, pyrethroid and pyrethrin sodium channel modulator, sodium channel modulator, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonist, nicotinic acetylcholine receptor (nAChR) agonist, butenolide nicotinic acetylcholine receptor (nAChR) agonist Spinosynic nicotinic acetylcholine receptor (nAChR) allosteric modulators, Lumectin and milbemycin chloride channel activators, juvenile hormone analogs, non-specific (multi-site) inhibitors, stringed organ modulators, mites growth inhibitors, microbial-derived insect midgut membrane disruptors, mitochondrial ATP synthesis Enzyme inhibitor, oxidative phosphorylation uncoupler, nereistoxin analog nicotinic acetylcholine receptor (nAChR) channel blocker, benzoylurea chitin biosynthesis inhibitor (type 0), chitin biosynthesis inhibitor (type 1) , Fly insect insect molting inhibitor, diacyl-hydrazine molting hormone (ecdysone) receptor agonist, octopamine receptor agonist, mitochondrial electron transport system complex III inhibitor, mitochondrial electron transport system complex I inhibitor (METI), potential Dependent sodium channel block -Tetronic acid and tetramic acid derivative acetyl CoA carboxylase inhibitor, phosphine mitochondrial electron transport complex IV inhibitor, cyanide mitochondrial electron transport complex IV inhibitor, β-ketonitrile derivative mitochondrial electron transport complex II inhibition Agents, diamide-based ryanodine receptor modulators, natural enemy insects, mites, nematode biological pesticides, microbial biological pesticides, air gate-blocking pesticides, pheromones, azadirachtin, benzomate (benzoximate), bifenazate, phenisobromolate ( Bromopropyrate), quinoxaline (quinomethionate), sodium aluminum fluoride, kelsen (dicofol), pyridalyl, pyrifluquinazone, sulfur, ferric phosphate, metaldehyde and 1,3-dichloropropene Insecticide selected;
Acylalanine PA fungicides (phenylamides), oxazolidinone PA fungicides (phenylamides), butyrolactone PA fungicides (phenylamides), hydroxy (2-amino-) pyrimidines, isoxazole aromatic hetero Rings, isothiazolone aromatic heterocycles, carboxylic acids, benzimidazole MBC fungicide (methylbenzimidazole carbamate), thiophanate MBC fungicide (methylbenzimidazole carbamate), N-phenyl carbamates, toluamide benzamides, Ethylaminothiazole carboxamide type thiazole carboxamides, phenylureas, pyridinylmethylbenzoamide type benzamides, pyrimidineamines, pyrazole carboxamides, phenylbenzamido SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furan carboxamide SDHI (Succinic acid dehydrogenase inhibitor), oxathiin carboxamide SDHI (succinic acid dehydrogenase inhibitor), thiazole carboxamide SDHI (succinic acid dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinic acid dehydration) Elementary enzyme inhibitors), pyridinecarboxamide SDHI (succinic dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxyacetamide QoI fungicide (Qo inhibitor), methoxycarbamate QoI fungicide (Qo inhibitor), oxyi Nonacetic acid-based QoI fungicide (Qo inhibitor), Oximinoacetamide-based QoI fungicide (Qo inhibitor), Oxazolidinedione-based QoI fungicide (Qo inhibitor), Dihydrodioxazine-based QoI fungicide (Qo inhibitor), Imidazolinone-based QoI fungicide (Qo inhibitor), benzyl carbamate-based QoI fungicide (Qo inhibitor), cyanoimidazole-based QiI fungicide (Qi inhibitor), sulfamoyltriazole-based QiI fungicide (Qi inhibitor), Dinitrophenylcrotonic acids, 2,6-dinitroanilines, triphenyltin compounds, organotin compounds, thiophenecarboxamides, triazolopyrimidylamine-based QoSI fungicides (Qo inhibitors, stigmaterin-binding type), anilinopyrimidine AP Bactericides (anilinopyrimidines), enopyranuro Acid antibiotics, hexopyranosyl antibiotics, glucopyranosyl antibiotics, tetracycline antibiotics, allyloxyquinoline aza-naphthalenes, quinazolinone aza-naphthalenes, phenylpyrrole PP fungicides (phenylpyrroles), dicarboximides, Phosphorothiolates, dithiolanes, aromatic hydrocarbon AH fungicides (including aromatic hydrocarbons, chlorophenyls, nitroanilines), 1,2,4-thiadiazole heteroaromatics, carbamates, Bacillus genus And produced bactericidal lipopeptide microorganism (Bacillus genus), terpene hydrocarbons and terpene alcohol plant extract, piperazine DMI fungicide (demethylation inhibitor, SBI: class I), pyridine DMI bactericidal Agent (demethylation inhibition SBI: class I), pyrimidine DMI fungicide (demethylation inhibitor, SBI: class I), imidazole DMI fungicide (demethylation inhibitor, SBI: class I), triazole DMI fungicide (demethylation) Methylation inhibitor, SBI: class I), triazoline thione DMI fungicide (demethylation inhibitor, SBI: class I), morpholine amines (morpholine, SBI: class II), piperidine amine (Morpholines, SBI: class II), spiroketal amine amines (morpholine, SBI: class II), hydroxyanilides (SBI: class III), aminopyrazolinone compounds (SBI: class III) ), Thiocarbamates (SBI: class IV), allylamines (SBI: class IV), glucopyranosyl antibiotics, Putidyl pyrimidine nucleoside polyoxins, cinnamic amide CAA fungicides (carboxylic amides), valinamide carbamate CAA fungicides (carboxylic amides), mandelic acid amide CAA fungicides (carboxylic amides), Isobenzofuranone MBI-R (melanin biosynthesis inhibitor-reductase), pyrroloquinolinone MBI-R (melanin biosynthesis inhibitor-reductase), triazolobenzothiazole MBI-R (melanin biosynthesis inhibitor-reduction) Enzyme), cyclopropanecarboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase), carboxamide MBI-D (melanin biosynthesis inhibitor-dehydrase), propionamide MBID-D (melanin biosynthesis inhibitor- Dehydrase), benzothiadiazoles, benzoisothiazole , Thiadiazole carboxamides, natural polysaccharides, plant extracts, cyanoacetamide oximes, ethylphosphonate phosphonates, phosphonates, phthalamic acids, benzotriazines, benzenesulfonamides, pyridazinones, thiocarbamate compounds, phenylacetamide Compound, benzophenone allyl phenyl ketone compound, benzoylpyridine allyl phenyl ketone compound, guanidine, cyanomethylene thiazolidine thiazolidine compound, pyrimidinone hydrazone, piperidinyl thiazole isoxazoline, acetic acid 4-quinoline compound, inorganic compound, Dithiocarbamates and their analogs, phthalimides, chloronitriles (phthalonitriles), sulfamides, guanidines, triazines, Bactericides selected from the group consisting of quinones (anthraquinones), quinoxalines, maleimides, physical inhibitors, bicarbonates, silvers, organic coppers and soil disinfectants;
Or allyloxypropionate acetyl CoA carboxylase (ACCase) inhibitor, cyclohexanedione acetyl CoA carboxylase (ACCase) inhibitor, phenylpyrazoline acetyl CoA carboxylase (ACCase) inhibitor, sulfonylurea acetolactate synthase (ALS) Inhibitors (acetohydroxyacid synthase (AHAS) inhibitors), imidazolinone acetolactate synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors), triazolopyrimidine acetolactate synthase (ALS) ) Inhibitors (acetohydroxyacid synthase (AHAS) inhibitors), pyrimidinyl (thio) benzoate acetolactate synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors , Sulfonylaminocarbonyltriazolinone acetolactate synthase (ALS) inhibitor (acetohydroxy acid synthase (AHAS) inhibitor), triazine photosynthesis (photochemical II) inhibitor, triazinone photosynthesis (photochemical II) inhibition Agents, triazolinone photosynthesis (photochemical II) inhibitors, uracil photosynthesis (photochemical II) inhibitors, pyridazinone photosynthesis (photochemical II) inhibitors, phenyl carbamate photosynthesis (photochemical II) inhibitors, urea photosynthesis (Photochemical II) inhibitors, amide photosynthesis (photochemical II) inhibitors, nitrile photosynthesis (photochemical II) inhibitors, benzothiadiadinone photosynthesis (photochemical II) inhibitors, phenylpyridazine photosynthesis (photochemistry) II) inhibitors, bipyridylium photosystem I electron conversion agents, diphenyl ether protoporphyrin Genoxidase (PPO) inhibitors, phenylpyrazole protoporphyrinogen oxidase (PPO) inhibitors, N-phenylphthalimide protoporphyrinogen oxidase (PPO) inhibitors, thiadiazole protoporphyrinogen oxidase ( PPO) inhibitor, oxadiazole protoporphyrinogen oxidase (PPO) inhibitor, triazolinone protoporphyrinogen oxidase (PPO) inhibitor, oxazolidinedione protoporphyrinogen oxidase (PPO) inhibitor, Pyrimidinedione protoporphyrinogen oxidase (PPO) inhibitor, protoporphyrinogen oxidase (PPO) inhibitor, carotenoid biosynthesis inhibitor in pyridazinone phytoene desaturase system (PDS), pyridinecarboxamide Carotenoid biosynthesis inhibitor in phytoene desaturase system (PDS), carotenoid biosynthesis inhibitor in phytoene desaturase system (PDS), triketone 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor , Isoxazole 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor, pyrazole 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitor, 4-hydroxyphenylpyruvate dioxygenase enzyme ( 4-HPPD) inhibitor, triazole carotenoid biosynthesis (target site unknown) inhibitor, isoxazolidinone carotenoid biosynthesis (target site unknown) inhibitor, urea carotenoid biosynthesis (target site unknown) inhibitor, diphenyl ether carotenoid Inhibitor of bioid synthesis (target site unknown), glycine EPSP synthase inhibitor, phosphinic acid glutamine synthetase inhibitor, carbamate DHP (dihydropteroic acid) synthase inhibitor, dinitroaniline microtubule polymerization inhibitor , Phosphoramidate microtubule polymerization inhibitor, pyridine microtubule polymerization inhibitor, benzamide microtubule polymerization inhibitor, benzoic acid microtubule polymerization inhibitor, carbamate mitosis / microtubule formation inhibitor, chloro Inhibitor of acetamide VLCFA (cell division inhibitor), Inhibitor of acetamide VLCFA (cell division inhibitor), Inhibitor of oxyacetamide VLCFA (cell division inhibitor), Inhibitor of tetrazolinone VLCFA (Inhibition of cell division) Agent), VLCFA inhibitor (cell division inhibitor), nitrile cell wall (cellulose) Growth inhibitor, benzamide cell wall (cellulose) synthesis inhibitor, triazolocarboxamide cell wall (cellulose) synthesis inhibitor, quinolinecarboxylic acid cell wall (cellulose) synthesis inhibitor, dinitrophenol uncoupling (membrane disruption) agent, Thiocarbamate lipid synthesis inhibitor (non-ACCase inhibitor), phosphorodithioate lipid synthesis inhibitor (non-ACCase inhibitor), benzofuran lipid synthesis inhibitor (non-ACCase inhibitor), chlorocarbonic lipid synthesis inhibitor (non-ACCase inhibitor) ), Phenoxycarboxylic acid-based indole acetic acid-like active (synthetic auxin) agent, benzoic acid-based indole acetic acid-like active (synthetic auxin) agent, pyridinecarboxylic acid-based indole acetic acid-like active (synthetic auxin) agent, quinolinecarboxylic acid-based indole acetic acid Like activity (synthetic oxy ) Agent, indole acetic acid-like activity (synthetic auxin) agent, phthalamate auxin transfer inhibitor, semicarbazone auxin transfer inhibitor, arylaminopropionic acid compound, pyrazolium compound, organic arsenic compound, microorganism, bromobutide, (chlor) -Selected from the group consisting of flulenol, cinmethylin, cumyluron, dazomet, dimuron, methyl dimemron, etozanide, fosamine, indanophan, carbam / carbam sodium salt, oxadichromemephone, oleic acid, pelargonic acid, pyributycarb, chlorate and cyanate The preparation according to any one of claims 1 to 5, which is a herbicide.   The formulation of any one of Claims 1-6 whose content rate of an agrochemical is 0.01 to 10 weight%.   The slow-release granular fertilizer is a slow-release mixed granular fertilizer, a chemically synthesized slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressure-molded granular fertilizer or a slow-release nitrification inhibitor-containing fertilizer The preparation according to any one of claims 1 to 7.   Slow-acting granular fertilizer has plant essential elements such as nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), calcium (Ca ) And any one or more fertilizer components selected from the group consisting of sulfur (S), and the preparation according to any one of claims 1 to 8.   The preparation according to claim 9, wherein the slow-acting granular fertilizer contains chisso (N), phosphorus (P) and potassium (K) as plant essential elements in a ratio of a guaranteed component amount of 3: 20: 3.   The preparation according to claim 9, wherein the slow-acting granular fertilizer contains chisso (N), phosphorus (P) and potassium (K) as plant essential elements in a ratio of the guaranteed component amount of 2: 5: 2.   The preparation according to any one of claims 8 to 11, wherein the content of the slow-acting granular fertilizer is 0.1 wt% to 99.9 wt%.   The preparation according to any one of claims 1 to 7, wherein the content ratio of the non-petroleum solvent is 0.1 wt% to 10 wt%.   The content ratio of the pesticide is 0.01 wt% to 10 wt%, the content ratio of the non-petroleum solvent is 0.1 wt% to 10 wt%, and the content ratio of the slow-release granular fertilizer is 0.1 wt% to 99.99%. The formulation according to any one of claims 1 to 13, which is 9% by weight.   The content ratio of the agricultural chemical is 0.03% to 5% by weight, the content ratio of the non-petroleum solvent is 0.1% to 10% by weight, and the content ratio of the slow-release granular fertilizer is 50.0% to 99%. The formulation according to claim 14, which is 9% by weight.   Use of the preparation according to any one of claims 1 to 15 for agriculture, horticulture or household horticulture.