JP6774575B2 - A phytotoxicity reducing agent containing a bactericidal compound as an active ingredient, and a herbicidal composition containing the phytotoxicity reducing agent and a herbicidal compound. - Google Patents
A phytotoxicity reducing agent containing a bactericidal compound as an active ingredient, and a herbicidal composition containing the phytotoxicity reducing agent and a herbicidal compound. Download PDFInfo
- Publication number
- JP6774575B2 JP6774575B2 JP2019555040A JP2019555040A JP6774575B2 JP 6774575 B2 JP6774575 B2 JP 6774575B2 JP 2019555040 A JP2019555040 A JP 2019555040A JP 2019555040 A JP2019555040 A JP 2019555040A JP 6774575 B2 JP6774575 B2 JP 6774575B2
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- Prior art keywords
- phytotoxicity
- reducing agent
- herbicidal
- compound
- herbicidal compound
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- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 description 1
- QFNFRZHOXWNWAQ-UHFFFAOYSA-N triclopyricarb Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NC(Cl)=C(Cl)C=C1Cl QFNFRZHOXWNWAQ-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- IMEVJVISCHQJRM-UHFFFAOYSA-N triflusulfuron-methyl Chemical group COC(=O)C1=CC=CC(C)=C1S(=O)(=O)NC(=O)NC1=NC(OCC(F)(F)F)=NC(N(C)C)=N1 IMEVJVISCHQJRM-UHFFFAOYSA-N 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- 239000000664 voltage gated sodium channel blocking agent Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229940048462 zinc phosphide Drugs 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/86—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Catching Or Destruction (AREA)
Description
本発明は、薬害軽減剤に関する。さらに詳しくは、本発明は、殺菌性化合物を有効成分とする薬害軽減剤、並びに該薬害軽減剤と除草性化合物とを含む薬害軽減された除草性組成物に関するものである。 The present invention relates to a phytotoxicity reducing agent. More specifically, the present invention relates to a phytotoxicity reducing agent containing a bactericidal compound as an active ingredient, and a herbicidal composition containing the phytotoxicity reducing agent and a herbicidal compound.
除草剤の使用は、作物栽培において、当該作物の適切な収量の確保、効率的な当該作物の栽培を実現するためには、欠かせないものとなっている。現在、使用されている除草剤は、当該作物への選択性が付与されており、防除対象となる植物を除いて、当該作物には、原則損害を与えないものとなっている。 The use of herbicides is indispensable in crop cultivation in order to secure an appropriate yield of the crop and to realize efficient cultivation of the crop. Currently, the herbicides used are endowed with selectivity for the crop, and in principle do not cause damage to the crop except for the plants to be controlled.
しかしながら、当該除草剤の作物選択性は必ずしも十分ではなく、当該除草剤の使用条件によっては、当該除草剤による当該作物への生育障害、生育抑制、成長抑制、褐点の出現、分げつ抑制、黄化、葉枯れ、枯死、萎凋、白化、捻転、褐変、根部生長阻害等といった既知または未知の望ましくない薬害が発生することがある。 However, the crop selectivity of the herbicide is not always sufficient, and depending on the conditions of use of the herbicide, the herbicide causes growth disorders, growth suppression, growth suppression, appearance of brown spots, and cracking suppression in the crop. , Yellowing, leaf withering, withering, wilting, whitening, twisting, browning, inhibition of root growth, etc. may cause known or unknown undesired phytotoxicity.
これまでに、それらの当該薬害を回避するために、作用の異なる除草剤の併用や、薬害軽減効果のある化合物(Safener)と、除草剤との併用などが行われている(特許文献1〜4、非特許文献1)。 So far, in order to avoid the phytotoxicity, herbicides having different actions have been used in combination, and a compound (Safener) having a phytotoxicity-reducing effect has been used in combination with a herbicide (Patent Documents 1 to 1). 4. Non-patent document 1).
ヒドロキシイソキサゾール、ピカルブトラゾクス、シアゾファミド、カスガマイシン、クロロタロニル、ベノミル、チオファネートメチル、イソプロチオラン及びアミスルブロムからなる群より選択される化合物は、公知の殺菌性化合物であり、それぞれの化合物は、下記の表1に示されるように、該当する特許文献において記載されている。 The compounds selected from the group consisting of hydroxyisoxazole, picalbutrazox, siazophamide, kasugamycin, chlorotalonil, benomyl, thiophanate methyl, isoprothiolane and amysulfrom are known bactericidal compounds, and each compound is described in Table 1 below. As shown in, it is described in the relevant patent document.
過去に殺菌性化合物である3−ヒドロキシ−5−イソキサゾール(以下、「ヒドロキシイソキサゾール」という。)がイネにおける除草剤薬害軽減効果を持つことが報告されている(非特許文献2)。 In the past, it has been reported that 3-hydroxy-5-isoxazole (hereinafter referred to as "hydroxyisoxazole"), which is a bactericidal compound, has an effect of reducing herbicide damage in rice (Non-Patent Document 2).
また、抵抗性誘導剤であるイソチアゾールカルボキサミド類を、種子処理および育苗箱施用することによって、除草剤薬害軽減効果を有することが知られている(特許文献16〜18)。 Further, it is known that isothiazole carboxamides, which are resistance inducers, have a herbicide phytotoxicity-reducing effect by treating seeds and applying them to a nursery box (Patent Documents 16 to 18).
また、殺菌活性かつ殺虫活性を有するイソプロチオランは、除草剤であるテフリルトリオンに対し、薬害軽減効果を有することが知られている(特許文献19)。 Further, isoprothiolan having bactericidal activity and insecticidal activity is known to have a phytotoxicity reducing effect on the herbicide tefryltrione (Patent Document 19).
しかしながら、これら従来の薬害軽減剤は、除草活性を有する化合物または単用では生物活性(除草活性、殺菌活性、殺虫活性等)を有さない化合物を有効成分とするもので、その対象を特定の栽培植物に限定することによって、特定の除草剤についてのみ、当該除草剤による薬害が軽減されるものであった。したがって、既存の薬害軽減剤では、種々の栽培作物に対して普遍的に使用できるものではなかった(特許文献1〜4、非特許文献1)。 However, these conventional phytotoxicity reducing agents contain a compound having herbicidal activity or a compound having no biological activity (herbicide activity, bactericidal activity, insecticidal activity, etc.) as an active ingredient, and the target is specific. By limiting to cultivated plants, the phytotoxicity caused by the herbicide was reduced only for a specific herbicide. Therefore, the existing phytotoxicity reducing agents have not been universally usable for various cultivated crops (Patent Documents 1 to 4 and Non-Patent Document 1).
具体的には、殺菌性化合物であるヒドロキシイソキサゾールについて、その薬害軽減効果が確認されている除草剤は、シメトリンやDCPA(propanil; Dimethyl 2,3,5,6−tetrachlorobenzene−1,4−dicarboxylate)、MCC(swep)・MCP(2−メチル−4−クロロフェノキシ酢酸エチル)などの主として光合成阻害型の除草剤である。したがって、近年開発された除草剤の薬害軽減効果に関しては知見が得られていない。 Specifically, regarding hydroxyisoxazole, which is a bactericidal compound, herbicides whose phytotoxicity-reducing effect has been confirmed are simethrin and DCPA (propanil; Dimethyl 2,3,5,6-terrachlorophenene-1,4-). It is a mainly photosynthesis-inhibiting herbicide such as dicarboxylate), MCC (swep) and MCP (2-methyl-4-chlorophenoxyacetate ethyl). Therefore, no knowledge has been obtained regarding the phytotoxicity-reducing effect of recently developed herbicides.
また、イソプロチオランについては、テフリルトリオンに対する除草剤薬害軽減は知られているものの、その他の除草剤に対する薬害軽減効果に関しては知見が得られていない。 Regarding isoprothiolane, although it is known to reduce the phytotoxicity of herbicides against tefryltrione, no knowledge has been obtained regarding the phytotoxicity-reducing effect of other herbicides.
さらには、ピカルブトラゾクス、シアゾファミド、カスガマイシン、クロロタロニル、ベノミル、チオファネートメチル、イソプロチオラン及びアミスルブロム等の殺菌活性を有する殺菌性化合物の除草剤薬害軽減効果については現在のところ明らかにされていない。 Furthermore, the herbicidal phytotoxicity-reducing effect of bactericidal compounds having bactericidal activity such as picarbutrazox, siazofamide, kasugamycin, chlorotalonil, benomyl, thiophanate-methyl, isoprothiolan and amysulfrom has not been clarified at present.
本発明の課題は、除草効果以外の生物活性を有し、異なる作用を示す様々な除草剤に対しても薬害軽減効果を示し、既存の薬害軽減剤よりも栽培植物に対する薬害軽減効果が優れ、かつ、栽培植物が限定されない使用範囲の広い新規な薬害軽減剤を見出すことである。 The subject of the present invention is that it has a biological activity other than the herbicidal effect, shows a phytotoxicity-reducing effect on various herbicides showing different actions, and has a phytotoxicity-reducing effect on cultivated plants superior to existing herbicides. At the same time, it is necessary to find a new phytotoxicity-reducing agent having a wide range of use, which is not limited to cultivated plants.
本発明者らは、上記課題を解決するべく、種々検討を行った結果、所定の殺菌性化合物が除草剤薬害軽減効果を示すことを見出した。即ち、所定の殺菌性化合物を有効成分とする薬害軽減剤、並びに該薬害軽減剤と除草性化合物とを含む除草性組成物が良好な薬害軽減効果を有することを見出し、本発明を完成した。 As a result of various studies to solve the above problems, the present inventors have found that a predetermined bactericidal compound exhibits a herbicide phytotoxicity reducing effect. That is, they have found that a phytotoxicity reducing agent containing a predetermined bactericidal compound as an active ingredient and a herbicidal composition containing the phytotoxicity reducing agent and a herbicidal compound have a good phytotoxicity reducing effect, and completed the present invention.
すなわち、本発明は、以下[1]−[18]の通りである。
[1] ピカルブトラゾクス又はその塩を有効成分として含有する、作物に対する下記(A1)乃至(A6)からなる群より選択される少なくとも1種類の除草性化合物又はそれらの塩による薬害の軽減剤。
(A1)ACCase阻害型除草性化合物
(A2)アセトラクテート合成酵素阻害型除草性化合物
(A3)白化型除草性化合物
(A4)VLCFA阻害型除草性化合物
(A5)プロトポリフィリノーゲンIXオキシダーゼ阻害型除草性化合物
(A6)合成オーキシン系除草性化合物
[2] 前記除草性化合物がオキサジクロメホンである、[1]に記載の薬害軽減剤。
[3] 前記作物がイネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッコリー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木(苗木)、西洋芝(ベントグラス、ライグラス、ブルーグラス)若しくは日本芝である、[1]または[2]に記載の薬害軽減剤。
[4] 前記作物がイネである、[1]乃至[3]のいずれかに記載の薬害軽減剤。
[5] 下記(A1)乃至(A6)からなる群より選択される、少なくとも1種類の除草性化合物又はそれらの塩と、ピカルブトラゾクス又はその塩を有効成分として含有する作物に対する薬害軽減剤と、を含有する、除草性組成物。
(A1)ACCase阻害型除草性化合物
(A2)アセトラクテート合成酵素阻害型除草性化合物
(A3)白化型除草性化合物
(A4)VLCFA阻害型除草性化合物
(A5)プロトポリフィリノーゲンIXオキシダーゼ阻害型除草性化合物
(A6)合成オーキシン系除草性化合物
[6] オキサジクロメホンと、ピカルブトラゾクス又はその塩を有効成分として含有する作物に対する薬害軽減剤と、を含有する、除草性組成物。
[7] 前記作物が、イネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッコリー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木(苗木)、西洋芝(ベントグラス、ライグラス、ブルーグラス)もしくは日本芝である、[5]又は[6]に記載の除草性組成物。
[8] 前記作物が、イネである、[5]乃至[7]のいずれかに記載の除草性組成物。
[9] 除草性化合物が下記(A2−1)及び(A3−1)からなる群より選択される、少なくとも1種類の除草性化合物又はそれらの塩である[7]に記載の除草性組成物。
(A2−1)スルホニルウレア系除草性化合物、ピリミジニル安息香酸系除草性化合物若しくはトリアゾロピリミジン系除草性化合物
(A3−1)ピラゾール系除草性化合物若しくはトリケトン系除草性化合物
[10] 下記(B1)ないし(B4)からなる群より選択される施用方法により、作物に対する薬害を軽減する方法。
(B1)[1]乃至[4]のいずれかに記載の薬害軽減剤aと、当該薬害軽減剤を含まない除草性組成物bとを混合して施用する方法、
(B2)[1]乃至[4]のいずれかに記載の薬害軽減剤aと、当該薬害軽減剤を含まない除草性組成物bとを、独立して同じ作物に施用する方法、
(B3)[1]乃至[4]のいずれかに記載の薬害軽減剤aと、[5]乃至[9]のいずれかに記載の除草性組成物cとを、独立して同じ作物に施用する方法、
(B4)[5]乃至[9]のいずれかに記載の除草性組成物cを施用する方法。
[11] 薬害軽減剤a、除草性組成物b又は除草性組成物cを、植物体及び/又は種子に処理するか、あるいは土壌への施用及び/又は植物体の根若しくは地下茎に処理する、[10]に記載の薬害を軽減する方法。
[12] 種子への前記処理が、当該種子への吹付、塗沫、浸漬、粉衣又は散布である[11]に記載の薬害を軽減する方法。
[13] 土壌への前記施用が、水田土壌への処理、土壌表面への処理、土壌への潅注又は土壌への混和である[11]に記載の薬害を軽減する方法。
[14] 前記作物がイネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木(苗木)、西洋芝(ベントグラス、ライグラス、ブルーグラス)又は日本芝である[10]に記載の薬害を軽減する方法。
[15] 前記作物がイネである、[10]又は[14]に記載の薬害を軽減する方法。
[16] 前記(B1)ないし(B4)からなる群より選択される施用方法を、移植前の植物体に1回若しくは2回行うか、あるいは土壌及び/又は植物体の根若しくは地下茎に1回若しくは2回行う、[10]に記載の薬害を軽減する方法。
[17] 前記(B2)の施用方法が、薬害軽減剤aを移植前の植物体に1回又は2回施用し、当該薬害軽減剤を含まない除草性組成物bを移植後の土壌及び/又は植物体に施用する方法であり、前記作物がイネである、[10]又は[16]に記載の薬害を軽減する方法。
[18] 薬害軽減剤aがピカルブトラゾクス若しくはその塩であり、除草性組成物bが上記(A2−1)及び(A3−1)からなる群より選択される、少なくとも1種類の除草性化合物又はそれらの塩である、[10]、[16]又は[17]に記載の薬害を軽減する方法。
That is, the present invention is as follows [1]-[ 18 ].
[1] At least one herbicide compound selected from the group consisting of the following (A1) to (A6) for crops containing picalbutrazox or a salt thereof as an active ingredient , or an agent for reducing phytotoxicity caused by salts thereof. ..
(A1) ACCase-inhibiting herbicidal compound
(A2) Acetolactate synthase inhibitory herbicidal compound
(A3) Whitening herbicidal compound
(A4) VLCFA inhibitory herbicidal compound
(A5) Protopolyphilinogen IX oxidase-inhibiting herbicidal compound
(A6) Synthetic auxin-based herbicidal compound [2] The phytotoxicity reducing agent according to [1], wherein the herbicidal compound is oxadichromephone.
[3] The crops are rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green pepper, pea, cauliflower, azuki, strawberry, cabbage, radish, mibuna, mizuna, turnip, nabana, Chinese cabbage, broccoli, cauliflower, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, capsicum, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honeybee, ginger, radish, tobacco, carnation, iris , Kiku, fig, cabbage, timber (sapling), western turf (ventgrass, ryegrass, bluegrass) or Japanese turf, according to [1] or [2] .
[4] The phytotoxicity reducing agent according to any one of [1] to [ 3 ], wherein the crop is rice.
[5] A phytotoxicity-reducing agent for crops containing at least one herbicide compound or a salt thereof selected from the group consisting of the following (A1) to (A6) and picalbutrazox or a salt thereof as an active ingredient. And, a herbicidal composition containing.
(A1) ACCase-inhibiting herbicidal compound (A2) Acetractate synthase-inhibiting herbicidal compound (A3) Whitening-type herbicidal compound (A4) VLCFA-inhibiting herbicidal compound (A5) Protopolyphilinogen IX oxidase-inhibiting herbicide Sex compound (A6) Synthetic auxin-based herbicide compound [6] A herbicidal composition containing oxadichromephone and a chemical damage reducing agent for crops containing picalbutrazox or a salt thereof as an active ingredient.
[7] The crops are rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green pepper, pea, cauliflower, azuki, strawberry, cabbage, radish, mibuna, mizuna, turnip, nabana. , Chinese cabbage, broccoli, cauliflower, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, capsicum, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okura, honeybee, ginger, radish, tobacco, carnation, The herbicidal composition according to [ 5 ] or [ 6 ], which is iris, kiku, fig, cabbage, timber (sapling), western turf (bentgrass, ryegrass, bluegrass) or Japanese turf.
[8] The herbicidal composition according to any one of [ 5 ] to [ 7 ], wherein the crop is rice.
[9] The herbicidal composition according to [ 7 ], wherein the herbicidal compound is at least one herbicidal compound selected from the group consisting of the following (A2-1) and (A3-1) or a salt thereof. ..
(A2-1) sulfonylurea herbicide compound, pyrimidinyl benzoic acid herbicide compound or triazolopyrimidine herbicide compound (A3-1) pyrazole herbicide compound or triketone herbicide compound [10] The following (B1) to A method for reducing chemical damage to crops by an application method selected from the group consisting of (B4).
(B1) A method of mixing and applying the phytotoxicity reducing agent a according to any one of [1] to [ 4 ] and the herbicidal composition b containing no phytotoxicity reducing agent.
(B2) A method of independently applying the phytotoxicity reducing agent a according to any one of [1] to [ 4 ] and the herbicidal composition b not containing the phytotoxicity reducing agent to the same crop.
(B3) The phytotoxicity reducing agent a according to any one of [1] to [ 4 ] and the herbicidal composition c according to any one of [ 5 ] to [ 9 ] are independently applied to the same crop. how to,
(B4) A method for applying the herbicidal composition c according to any one of [ 5 ] to [ 9 ].
[11] The phytotoxicity reducing agent a, herbicide composition b or herbicide composition c is treated on a plant and / or seed, or applied to soil and / or treated on a root or rhizome of a plant. The method for reducing phytotoxicity according to [ 10 ].
[12] The method for reducing phytotoxicity according to [ 11 ], wherein the treatment on the seed is spraying, smearing, dipping, coating or spraying the seed.
[13] The method for reducing phytotoxicity according to [ 11 ], wherein the application to the soil is treatment to paddy soil, treatment to the soil surface, irrigation to soil or mixing with soil.
[14] The crops are rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green pepper, pea, soramame, adzuki bean, strawberry, cabbage, radish, mibuna, mizuna, turnip, nabana, Chinese cabbage, block, cabbage, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, capsicum, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okura, honeybee, ginger, radish, tobacco, carnation, iris , Kiku, Azuki, Turnip, Timber (sapling), Western turf (Bentgrass, Ryegrass, Bluegrass) or Japanese turf [ 10 ].
[15] The method for reducing phytotoxicity according to [ 10 ] or [ 14 ], wherein the crop is rice.
[16] The application method selected from the group consisting of (B1) to (B4) is applied once or twice to the plant before transplantation, or once to the soil and / or the root or rhizome of the plant. Alternatively, the method for reducing the phytotoxicity described in [ 10 ], which is performed twice.
[17] In the application method of (B2) above, the phytotoxicity reducing agent a is applied to the plant before transplantation once or twice, and the herbicidal composition b containing no phytotoxicity reducing agent is applied to the soil after transplantation and /. Alternatively, the method for reducing phytotoxicity according to [ 10 ] or [ 16 ], which is a method of applying to a plant and the crop is rice.
[18] At least one kind of herbicidal agent in which the phytotoxicity reducing agent a is picarubutrazox or a salt thereof and the herbicidal composition b is selected from the group consisting of the above (A2-1) and (A3-1). The method for reducing phytotoxicity according to [ 10 ], [ 16 ] or [ 17 ], which is a compound or a salt thereof.
本発明は、殺菌性化合物が除草剤薬害軽減効果を示すことを見出したことに基づく。即ち、本発明により、除草剤処理前後または除草剤処理時に殺菌活性を有する薬害軽減剤を処理することによって、殺菌活性に由来する病害防除効果が期待でき、かつ、種々の栽培作物に対して普遍的に使用可能で良好な薬害軽減効果を得ることができる。 The present invention is based on the finding that a bactericidal compound exhibits a herbicide phytotoxicity reducing effect. That is, according to the present invention, by treating a phytotoxicity reducing agent having a bactericidal activity before and after the herbicide treatment or during the herbicide treatment, a disease control effect derived from the bactericidal activity can be expected, and it is universal for various cultivated crops. It can be used effectively and a good phytotoxicity reduction effect can be obtained.
次に、本明細書で使用する各種の用語について説明する。 Next, various terms used in the present specification will be described.
「薬害軽減剤」とは、雑草や病害虫の防除をするため農業用資材を栽培作物に使用する際に、該作物への生育障害、生育抑制、成長抑制、褐点の出現、分げつ抑制、黄化、葉枯れ、枯死、萎凋、白化、捻転、褐変、根部生長阻害等といった既知または未知の望ましくない薬害が想定される場合において、農業用資材と併用するか、もしくは農業用資材の使用前後に単用することで、その薬害を軽減する組成物である。 "Pharmaceutical damage reducing agent" means, when agricultural materials are used for cultivated crops to control weeds and pests, growth disorders, growth suppression, growth suppression, appearance of brown spots, and sprinkling suppression on the crops. , Yellowing, leaf withering, withering, wilting, bleaching, twisting, browning, inhibition of root growth, etc. When known or unknown undesired phytotoxicity is expected, use in combination with agricultural materials or use of agricultural materials It is a composition that reduces the phytotoxicity when used alone before and after.
「ヒドロキシイソキサゾール、ピカルブトラゾクス、シアゾファミド、カスガマイシン、クロロタロニル、ベノミル、チオファネートメチル、イソプロチオラン及びアミスルブロムからなる群より選択される化合物」の塩とは、当該化合物の金属塩、酸付加塩等を示し、例えば、リチウム、ナトリウム、カリウムといったアルカリ金属の塩、例えば、カルシウム、バリウム、マグネシウムといったアルカリ土類金属の塩、例えば、アルミニウムの塩又はマンガン、銅、亜鉛、鉄といった遷移金属の塩、例えば、フッ化水素酸、塩酸、臭化水素酸、沃化水素酸等のハロゲン化水素酸の塩、例えば、硝酸、硫酸、燐酸、塩素酸、過塩素酸等の無機酸の塩、例えば、メタンスルホン酸、エタンスルホン酸、トリフルオロメタンスルホン酸、ベンゼンスルホン酸、p−トルエンスルホン酸等のスルホン酸の塩、例えば、ギ酸、酢酸、プロピオン酸、トリフルオロ酢酸、フマール酸、酒石酸、蓚酸、マレイン酸、リンゴ酸、コハク酸、安息香酸、マンデル酸、アスコルビン酸、乳酸、グルコン酸、クエン酸等のカルボン酸の塩又は例えば、グルタミン酸、アスパラギン酸等のアミノ酸の塩などが挙げられる。 The salt of "a compound selected from the group consisting of hydroxyisoxazole, picarbutrazox, siazophamide, kasgamicin, chlorotalonyl, benomil, thiophanatemethyl, isoprothiolane and amysulfrom" indicates a metal salt, an acid addition salt or the like of the compound. , For example, alkali metal salts such as lithium, sodium, potassium, eg, alkaline earth metal salts such as calcium, barium, magnesium, eg aluminum salts or transition metal salts such as manganese, copper, zinc, iron, eg. Salts of hydrohalogen such as hydrofluoric acid, hydrochloric acid, hydrobromic acid, hydroiodic acid, eg salts of inorganic acids such as nitrate, sulfuric acid, phosphoric acid, chloric acid, perchloric acid, eg methanesulfone Salts of sulfonic acids such as acids, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid, for example, formic acid, acetic acid, propionic acid, trifluoroacetic acid, fumaric acid, tartaric acid, oxalic acid, maleic acid, Examples thereof include salts of carboxylic acids such as malic acid, succinic acid, benzoic acid, mandelic acid, ascorbic acid, lactic acid, gluconic acid and citric acid, or salts of amino acids such as glutamic acid and aspartic acid.
「ACCase阻害型除草性化合物」とは、例えば、アリロキシプロピオン酸系化合物、シクロヘキサジオンオキシム系化合物等を示し、例えば、プロパキザホップ、キザロホップ、ハロキシホップ、フルアジホップブチル、フルアジホップ−P−ブチル、シハロホップブチル、クロジナホッププロパルギル、ジクロホップメチル、フェノキサプロップ−P−エチル、ブトロキシジム、プロフォキシジム、クレトジム、テプラロキシジム、トラルコキシジム、セトキシジム、シクロキシジム、ピノキサデン等である。 The “ACCase-inhibiting herbicidal compound” refers to, for example, an allyloxypropionic acid compound, a cyclohexadionoxime compound, and the like, and for example, propaxahop, xarohop, haloxhop, fluazihopbutyl, fluazihop-P-butyl. , Sihalohop butyl, clozina hop propargyl, diclohop methyl, phenoxaprop-P-ethyl, butroxydim, profoxydim, cretodim, teplaroxydim, tralcoxydim, setoxydim, cycloxime, pinoxaden and the like.
「アセトラクテート合成酵素阻害型除草性化合物」とは、例えば、スルホニルウレア系化合物、スルホニルアミノカルボニルトリアゾリノン系化合物、ピリミジニル安息香酸系化合物、トリアゾロピリミジン系化合物、イミダゾリノン系化合物等を示し、中でも、例えば、アミドスルフロン、アジムスルフロン、トリフロキシスルフロン、ベンスルフロンメチル、シクロスルファムロン、フルピルスルフロンメチル、フォーラムスルフロン、クロリムロンエチル、エタメトスルフロンメチル、ハロスルフロンメチル、ニコスルフロン、クロルスルフロン、エトキシスルフロン、イマゾスルフロン、オキサスルフロン、ピラゾスルフロンエチル、トリトスルフロン、シノスルフロン、フラザスルフロン、ヨードスルフロンメチル、プリミスルフロンメチル、リムスルフロン、チフェンスルフロンメチル、メソスルフロンメチル、メトスルフロンメチル、プロスルフロン、トリアスルフロン、トリフルスルフロンメチル、スルホスルフロン、トリベヌロンメチル、トリフロキシスルフロン、フルセトスルフロン、メタゾスルフロン、プロピリスルフロン、フルカルバゾン、プロポキシカルバゾン、ビスピリバック、ピリベンゾキシム、ピリチオバック、ピリフタリド、ピリミノバックメチル、ピリミスルファン、トリアファモン、クロランスラムメチル、ジクロスラム、フロラスラム、フルメトスラム、メトスラム、ペノキススラム、イマザピック、イマザピル、イマザメタベンズメチル、イマザキン、イマザモックス、イマゼタピル等であり、好適には、アジムスルフロン、ベンスルフロンメチル、ハロスルフロンメチル、イマゾスルフロン、ピラゾスルフロンエチル、フルセトスルフロン、メタゾスルフロン、プロピリスルフロン、ビスピリバック、ピリフタリド、ピリミノバックメチル、ピリミスルファン、トリアファモン、ペノキススラム等であり、さらに好適にはイマゾスルフロン、ピリミスルファン等である。 The "acetolactate synthase-inhibiting herbicidal compound" refers to, for example, a sulfonylurea compound, a sulfonylaminocarbonyltriazolinone compound, a pyrimidinylbenzoic acid compound, a triazolopyrimidine compound, an imidazolinone compound, and the like. , For example, amide sulfuron, azim sulfuron, trifloxysulfuron, benzulfuron methyl, cyclosulfamron, flupyrsulfuron methyl, forum sulfuron, chlorimlon ethyl, etamethosulfuron methyl, halosulfuron methyl, nicosulfron Chlorsulfuron, ethoxysulfuron, imazosulfuron, oxasulfuron, pyrazosulfuron ethyl, tritosulfuron, synosulfuron, frazasulfuron, iodosulfuron methyl, primisulfuron methyl, limsulfuron, tifensulfon methyl, mesosulfuron methyl , Methosulfuron Methyl, Prosulfuron, Triasulfuron, Triflusulfuron Methyl, Sulfosulfuron, Tribenuron Methyl, Trifloxysulfuron, Flucetosulfone, Metazosulfuron, Propyrisulfuron, Flucarbazone, Propoxycarbazone, Bispyrivac, Pyribenzoxim , Pyrichiobac, Pyriftalide, Pyriminobacmethyl, Pyrimisurfan, Triafamon, Chloranthrum Methyl, Dicroslam, Floraslam, Fulmethoslam, Methoslam, Penokis Slam, Imazapic, Imazapill, Imazametabensmethyl, Imazakin, Imazamox, Imazetapill Preferably, with azimuthulfone, benzulfuron methyl, halosulfuronmethyl, imazosulfone, pyrazosulfone ethyl, flusetosulfone, metazosulfone, propyrsulfone, bispyribac, pyriphthalide, pyriminobacmethyl, pyrimisulfan, triafamon, penoxthrum, etc. Yes, more preferably imazosulfuron, pyrimisulfan and the like.
「白化型除草性化合物」とは、例えば、ピラゾール系化合物、トリケトン系化合物等を示し、例えば、ピラゾレート、ピラゾキシフェン、ベンゾフェナップ、ピラスルフォトール、トプラメゾン、トルピラレート、メソトリオン、スルコトリオン、ベンゾビシクロン、テフリルトリオン、テンボトリオン、ビシクロピロン、ランコトリオン、シクロピリモレート、フェンキノトリオン等であり、好適には、ピラゾレート、ピラゾキシフェン、ベンゾフェナップ、メソトリオン、スルコトリオン、ベンゾビシクロン、テフリルトリオン、ランコトリオン、シクロピリモレート、フェンキノトリオン等であり、さらに好適には、スルコトリオン、テフリルトリオン等である。 The "whitening type herbicidal compound" refers to, for example, a pyrazole-based compound, a triketone-based compound, and the like, for example, pyrazolate, pyrazoxifene, benzophenap, pyrazolephotol, topramison, tolpyralate, mesotrione, sulcotrione, benzobicyclo. Compounds, tefryltrione, tembotrione, bicyclopyrone, lancotrion, cyclopyrimolate, phenquinotrione, etc., preferably pyrazolate, pyrazoxifene, benzophenap, mesotrione, sulcotrione, benzobicyclone, tefryltrione. , Lancotrione, cyclopyrimolate, fenquinotrione and the like, and more preferably sulcotrione, tefryltrione and the like.
「VLCFA阻害型除草性化合物」とは、例えば、クロロアセトアミド系化合物等を示し、例えば、アセトクロール、ブタクロール、アラクロール、ジメタクロール、ジメテナミド、プロパクロール、テニルクロール、メタザクロール、メトラクロール、S-メトラクロール、プレチラクロール、ペトキサミド、メフェナセット、カフェンストロール、フェントラザミド、イプフェンカルバゾン、フェノキサスルホン等である。 The "VLCFA-inhibiting herbicidal compound" refers to, for example, a chloroacetamide-based compound, for example, acetochlor, butachlor, alachlor, dimethacrol, dimethenamide, propachlor, tenylchlor, metazachlor, metrachlor, S-methacrol. , Pretilachlor, petoxamide, mephenacet, cafentrol, fentrazamide, ipphencarbazone, fenoxasulfone and the like.
「プロトポリフィリノーゲンIXオキシダーゼ阻害型除草性化合物」とは、例えば、ジフェニルエーテル系化合物、トリアゾリノン系化合物等を示し、例えば、アシフルオフェン、ビフェノックス、ホメサフェン、ラクトフェン、オキシフルオルフェン、カルフェントラゾンエチル、スルフェントラゾン、ペントキサゾン、ピラクロニル、オキサジアゾン、オキサジアルギル等である。 The "protopolyphilinogen IX oxidase-inhibiting herbicidal compound" refers to, for example, a diphenyl ether compound, a triazolinone compound, etc., for example, asifluofen, bifenox, homesaphen, lactophene, oxyfluorphen, calfentrazone ethyl, Sulfentrazone, pentoxazone, pyracronyl, oxadiazone, oxadiargyl, etc.
「合成オーキシン系除草性化合物」とは、例えば、フェノキシカルボン酸系化合物等を示し、例えば、クロメプロップ、MCPA、MCPB、2,4−DB、フロルピラウキシフェンベンジル等である。 The "synthetic auxin-based herbicidal compound" refers to, for example, a phenoxycarboxylic acid-based compound or the like, and is, for example, clomeprop, MCPA, MCPB, 2,4-DB, fluoropyrauxifenebenzyl or the like.
本発明でいう「作物」とは、人が繁殖と生育を保護・管理する植物をいう。作物は、その栽培方法や商品価値、利用目的、利用部分、植物学的分類等を総合的に判断して分類されており、一般的には、作物は、農作物と園芸作物とに大別される。
農作物は利用目的により、食用作物、工芸作物、飼料作物、緑肥作物に分けられている。具体的には、例えば、イネ、コムギ、オオムギ、ジャガイモ、トウモロコシ、ブドウ、リンゴ、ナシ、モモ、ネクタリン、ウメ、アンズ、オウトウ、カキ、カリン、マルメロ、クリ、キューイフルーツ、ブルーベリー、ビワ、バナナ、カンキツ、イチジク、オリーブ、パパイヤ、アケビ、アブラヤシ、ダイズ、ラッカセイ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミズナ、ミブナ、カブ、コマツナ、ハクサイ、ブロッコリー、カリフラワー、ナバナ、レタス、非結球レタス、トマト、ナス、ピーマン、トウガラシ、トウガン、ネギ、タマネギ、ワケギ、キュウリ、ニガウリ、メロン、スイカ、カボチャ、ズッキーニ、ニンジン、ミョウガ、ショウガ、ゴボウ、ウド、タラノキ、ホウレンソウ、テンサイ、アスパラガス、オクラ、セリ、ベニバナ、ナタネ、ミツバ、サツマイモ、サトイモ、ヤマノイモ、コンニャク、サトウキビ、タバコ、チャ、コーヒー、ヒマワリ、チューリップ、カーネーション、バジル、アイリス、アスター、バラ、キク、ワタ、ポップ、リンドウ、ユリ、ボタン、シャクヤク、シクラメン、ラッキョウ、コショウ、ニンニク、フキ、シソ、シナモン、ワサビ、タラノキ、レンコン、ソルガム、西洋芝(ベントグラス、バミューダグラス、ブルーグラス、ライグラス)、日本芝、オーチャードグラス、イタリアンライグラス、アルファルファ、レッドクローバー、カノコソウ、クワ、ケイトウ、ホウズキ、キンセンカ、ベニバナ、ツツジ類、サクラ、カシ、ボケ、ポプラ、イヌツゲ、ジンチョウゲ、樹木類、材木(苗木)等が挙げられる。
中でもイネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッコリー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木(苗木)、西洋芝(ベントグラス、ライグラス、ブルーグラス)、日本芝等が好ましく、イネ、テンサイ、西洋芝、日本芝、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、エンドウ等がより好ましく、イネが特に好ましいが、これらに限定されるものではない。The "crop" as used in the present invention refers to a plant in which a person protects and manages reproduction and growth. Crop is classified by comprehensively judging its cultivation method, commercial value, purpose of use, part of use, botanical classification, etc. In general, crops are roughly classified into agricultural crops and horticultural crops. To.
Agricultural crops are divided into food crops, industrial crops, forage crops, and green manure crops according to the purpose of use. Specifically, for example, rice, wheat, radish, potato, corn, grape, apple, pear, peach, nectarin, horse, apricot, peach, oyster, curin, marmelo, chestnut, kiwi fruit, blueberry, biwa, banana, Aralia elata, fig, olive, papaya, akebi, abra palm, soybean, lacquer, green onion, pea, perilla, azuki, strawberry, cabbage, radish, mizuna, mibuna, turnip, komatsuna, hakusai, broccoli, cauliflower, navana, lettuce, non-heading Lettuce, tomatoes, eggplants, peppers, peppers, peppers, green onions, onions, sardines, cucumbers, sardines, melons, watermelons, pumpkins, zucchini, carrots, myoga, ginger, gobo, udo, taranoki, spinach, tensai, asparagus, okura , Seri, Benibana, Rapeseed, Mitsuba, Sweet potato, Satoimo, Yamanoimo, Konnaku, Satoukibi, Tobacco, Cha, Coffee, Sunflower, Tulip, Carnation, Basil, Iris, Aster, Rose, Kiku, Wata, Pop, Lindow, Yuri, Button , Shakuyaku, cyclamen, rakkyo, pepper, garlic, turnip, perilla, cinnamon, wasabi, taranoki, renkon, sorghum, western turf (bentgrass, Bermudagrass, bluegrass, ryegrass), Japanese turf, orchardgrass, Italian ryegrass, alfalfa, Examples include red clover, Japanese mustard spinach, mulberry, Japanese mustard spinach, Aralia elata, Japanese mustard spinach, green onion, radish, cherry, oak, bokeh, poplar, inutsuge, ginchoge, trees, timber (saplings) and the like.
Among them, rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green beans, pea, soramame, azuki, strawberry, cabbage, radish, mibuna, mizuna, cub, nabana, hakusai, broccoli, cauliflower , Lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, corn, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honeybee, ginger, corn, tobacco, carnation, iris, kiku, fig, Rice, sugar beet, western turf, Japanese turf, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, pea, etc. are preferable, such as citrus fruits, timber (saplings), western turf (bent glass, ryegrass, blue grass), Japanese turf, etc. Is more preferable, and rice is particularly preferable, but the present invention is not limited thereto.
本発明でいう「植物体」とは、前記「作物」を構成する全ての部位を総称するものであり、例えば、茎、葉、根、種子、花、果実等が挙げられる。
本発明でいう「種子」とは、幼植物が発芽するための栄養分を蓄え農業上繁殖に用いられるものをいう。具体的には、例えば、トウモロコシ、ダイズ、ワタ、イネ、テンサイ、コムギ、オオムギ、ヒマワリ、トマト、キュウリ、ナス、ホウレンソウ、サヤエンドウ、カボチャ、サトウキビ、タバコ、ピーマンおよびセイヨウアブラナ等の種子やサトイモ、ジャガイモ、サツマイモ、コンニャク等の種芋、食用ユリ、チューリップ等の球根やラッキョウ等の種球等;さらに遺伝子等を人工的に操作することにより生み出された植物であり、自然界に元来存在するものではない遺伝子組み換え作物;例えば、除草剤耐性を付与したダイズ、トウモロコシ、ワタ等、寒冷地適応した、例えば、イネ、タバコ等;または殺虫物質生産能を付与した、例えば、トウモロコシ、ワタ等の種子、ジャガイモの塊茎等が挙げられるがこれらに限定されるものではない。 The "plant body" as used in the present invention is a general term for all the parts constituting the "crop", and examples thereof include stems, leaves, roots, seeds, flowers, and fruits.
The term "seed" as used in the present invention refers to a seed that stores nutrients for germination of seedlings and is used for agricultural reproduction. Specifically, for example, seeds such as corn, soybean, cotton, rice, tensai, wheat, barley, sunflower, tomato, cucumber, eggplant, spinach, pod, pumpkin, sugar cane, tobacco, pepper and rapeseed, and potatoes and potatoes. , Potatoes such as potatoes and corn, edible lilies, bulbs such as tulips and seed balls such as corn; Furthermore, it is a plant produced by artificially manipulating genes, etc., and does not originally exist in the natural world. Genetically modified crops; for example, herbicide-tolerant soybeans, corn, cotton, etc., cold-adapted, such as rice, tobacco, etc .; or pesticide-producing ability, such as corn, cotton, etc. seeds, potatoes Examples include, but are not limited to, corn tubers.
次に、本発明の殺菌性化合物を有効成分とする薬害軽減剤、並びに該薬害軽減剤と除草性化合物とを含む薬害軽減された除草性組成物について説明する。 Next, a phytotoxicity reducing agent containing the bactericidal compound of the present invention as an active ingredient, and a herbicidal composition containing the phytotoxicity reducing agent and the herbicidal compound will be described.
第1に、本発明の殺菌性化合物を有効成分とする薬害軽減剤について説明する。
本発明の薬害軽減剤は、ヒドロキシイソキサゾール、ピカルブトラゾクス、シアゾファミド、カスガマイシン、クロロタロニル、ベノミル、チオファネートメチル、イソプロチオラン及びアミスルブロムからなる群より選択される少なくとも1種の化合物又はその塩を有効成分として含有する。
前記有効成分は。本発明の効果の観点から、ヒドロキシイソキサゾール、ピカルブトラゾクス又はアミスルブロム若しくはその塩であることが好ましい。First, a phytotoxicity reducing agent containing the bactericidal compound of the present invention as an active ingredient will be described.
The phytotoxicity reducing agent of the present invention contains at least one compound selected from the group consisting of hydroxyisoxazole, picarbutrazox, siazofamide, casugamycin, chlorotalonil, benomyl, thiophanate methyl, isoprothiolan and amysulfrom as an active ingredient. contains.
The active ingredient is. From the viewpoint of the effect of the present invention, hydroxyisoxazole, picarubutrazox, amisulbrom or a salt thereof is preferable.
本発明の薬害軽減剤は、そのまま使用してもかまわないが、通常、担体と混合して用いられ、必要に応じて、界面活性剤、結合剤、崩壊剤、安定剤、pH調整剤、抗菌防黴剤(防腐剤)、増粘剤、消泡剤、湿潤剤、固着剤、着色剤等の補助剤を添加して、常法に従って、適時、水和剤、フロアブル剤、顆粒水和剤、OD剤、粉剤、液剤、乳剤、粒剤、パック剤等の剤型に製剤化することができる。当該剤型は、効果が発揮される限りにおいて、それらの組成物に限定されるものではない。 The chemical damage reducing agent of the present invention may be used as it is, but is usually used in combination with a carrier, and if necessary, a surfactant, a binder, a disintegrant, a stabilizer, a pH adjuster, and an antibacterial agent. Add auxiliary agents such as fungicides (preservatives), thickeners, defoamers, wetting agents, fixing agents, and coloring agents, and timely wettable powders, flowable agents, and granular wettable powders according to the conventional method. , OD agents, powders, liquids, emulsions, granules, packs, etc. can be formulated. The dosage form is not limited to those compositions as long as the effect is exhibited.
本発明の薬害軽減剤に使用される担体とは、処理すべき部位への有効成分の到達を助け、また有効成分化合物の貯蔵、輸送、取扱いを容易にするために配合される、合成もしくは天然の無機または有機物質を意味し、通常農園芸用薬剤に使用されるものであるならば、固体または液体のいずれでも使用することができ、特定のものに限定されるものではない。 The carrier used in the phytotoxicity reducing agent of the present invention is a synthetic or natural compound formulated to help the active ingredient reach the site to be treated and to facilitate the storage, transportation and handling of the active ingredient compound. As long as it means an inorganic or organic substance of the above and is usually used for agricultural and horticultural chemicals, it can be used as either a solid or a liquid, and is not limited to a specific one.
本発明の薬害軽減剤に使用することができる固体担体としては、例えば、ベントナイト、モンモリロナイト、珪藻土、白土、タルク、クレー等の無機物質;木粉、鋸屑、等の植物性有機物質;または尿素等を挙げることができる。 Examples of the solid carrier that can be used for the chemical damage reducing agent of the present invention include inorganic substances such as bentonite, montmorillonite, diatomaceous earth, white clay, talc and clay; vegetable organic substances such as wood flour and sawdust; or urea and the like. Can be mentioned.
本発明の薬害軽減剤に使用することができる液体担体としては、例えば、トルエン等の芳香族炭化水素類;ナフテン類;n−パラフィン、流動パラフィン、ケロシン等のパラフィン系炭化水素類;アセトン、メチルエチルケトン等のケトン類;ジオキサン、ジエチレングリコールジメチルエーテル等のエーテル類;エタノール、エチレングリコール等のアルコール類;エチレンカーボネート等のカーボネート類;ジメチルホルムアミド等の非プロトン性溶媒;または水等を挙げることができる。 Examples of the liquid carrier that can be used for the chemical damage reducing agent of the present invention include aromatic hydrocarbons such as toluene; naphthenes; paraffinic hydrocarbons such as n-paraffin, liquid paraffin, and kerosine; acetone and methyl ethyl ketone. Ketones such as; ethers such as dioxane and diethylene glycol dimethyl ether; alcohols such as ethanol and ethylene glycol; carbonates such as ethylene carbonate; aprotonic solvents such as dimethylformamide; or water and the like.
さらに、本発明の薬害軽減剤の効力を増強するために、製剤の剤型、処理方法等を考慮して、目的に応じて、それぞれ、単独にまたは組み合わせて、補助剤を使用することもできる。補助剤としては、例えば、界面活性剤、結合剤、崩壊剤、安定剤、pH調整剤、防菌防黴剤、増粘剤、消泡剤、凍結防止剤等を挙げることができる。 Further, in order to enhance the efficacy of the phytotoxicity reducing agent of the present invention, an auxiliary agent may be used alone or in combination, depending on the purpose, in consideration of the dosage form, treatment method, etc. of the preparation. .. Examples of the auxiliary agent include surfactants, binders, disintegrants, stabilizers, pH adjusters, fungicides, thickeners, defoamers, antifreeze agents and the like.
本発明の薬害軽減剤に使用することができる界面活性剤としては、通常、農薬製剤を乳化、分散、拡展または/および湿潤する等の目的で使用される界面活性剤が使用できる。そのようなものとしては、例えば、ソルビタン脂肪酸エステル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンポリオキシプロピレンブロックポリマー、アルキルポリオキシエチレンポリオキシプロピレンブロックポリマーエーテル、ポリオキシエチレンアルキルアミン、ポリオキシエチレン脂肪酸アミド、ポリオキシエチレンビスフェニルエーテル、高級アルコールのポリオキシアルキレン付加物およびポリオキシエチレンエーテルおよびエステル型シリコーンおよびフッ素系界面活性剤等の非イオン性界面活性剤;
アルキルサルフェート、ポリオキシエチレンアルキルエーテルサルフェート、ポリオキシエチレンベンジルフェニルエーテルサルフェート、ポリオキシエチレンスチリルフェニルエーテルサルフェート、パラフィンスルホネート、アルカンスルホネート、AOS、ジアルキルスルホサクシネート、アルキルベンゼンスルホネート、リグニンスルホネート、ポリオキシエチレンアルキルフェニルエーテルスルホネート、脂肪酸塩、N−メチル−脂肪酸サルコシネート、ポリオキシエチレンアルキルエーテルホスフェート、ポリオキシエチレンフェニルエーテルホスフェート、ポリオキシエチレンポリオキシプロピレンブロックポリマーホスフェート、ホスファチジルコリン、ホスファチジルエタノールイミン、アルキルホスフェート、トリポリ燐酸ナトリウム等のアニオン性界面活性剤;
アクリル酸とアクリロニトリル、アクリルアミドメチルプロパンスルホン酸から導かれるポリアニオン型高分子界面活性剤;
アルキルトリメチルアンモニウムクロライド、アルキルジメチルベンザルコニウムクロライド、ベンゼトニウムクロライド等のカチオン性界面活性剤;
またはジアルキルジアミノエチルベンタイン、アルキルジメチルベンジルベンタイン等の両性界面活性剤が挙げられる。As the surfactant that can be used in the phytotoxicity reducing agent of the present invention, a surfactant that is usually used for the purpose of emulsifying, dispersing, spreading and / or wetting a pesticide preparation can be used. Such examples include, for example, sorbitan fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polyoxypropylene block polymer. Nonionic interfaces such as ethers, polyoxyethylene alkylamines, polyoxyethylene fatty acid amides, polyoxyethylene bisphenyl ethers, polyoxyalkylene adducts of higher alcohols and polyoxyethylene ethers and ester-type silicones and fluorosurfactants. Activator;
Alkyl sulphate, polyoxyethylene alkyl ether sulphate, polyoxyethylene benzyl phenyl ether sulphate, polyoxyethylene styrylphenyl ether sulphate, paraffin sulfonate, alkane sulfonate, AOS, dialkyl sulfosuccinate, alkylbenzene sulfonate, lignin sulfonate, polyoxyethylene alkyl phenyl Ether sulfonate, fatty acid salt, N-methyl-fatty acid sarcosinate, polyoxyethylene alkyl ether surfactant, polyoxyethylene phenyl ether phosphate, polyoxyethylene polyoxypropylene block polymer phosphate, phosphatidylcholine, phosphatidylethanolimine, alkylphosphate, sodium tripolyphosphate, etc. Anionic surfactants;
Polyanionic polymer surfactant derived from acrylic acid, acrylonitrile, and acrylamide methylpropane sulfonic acid;
Cationic surfactants such as alkyltrimethylammonium chloride, alkyldimethylbenzalkonium chloride, benzethonium chloride;
Alternatively, amphoteric surfactants such as dialkyldiaminoethylbenzine and alkyldimethylbenzylbenzine can be mentioned.
結合剤としては、例えば、アルギン酸ナトリウム、ポリビニルアルコール、アラビアゴム、カルボキシメチルセルロース(以下、「CMCナトリウム」という。)、ベントナイト等が挙げられる。 Examples of the binder include sodium alginate, polyvinyl alcohol, gum arabic, carboxymethyl cellulose (hereinafter referred to as “CMC sodium”), bentonite and the like.
崩壊剤としては、例えば、CMCナトリウム、クロスカルメロースナトリウム等が挙げられる。 Examples of the disintegrant include CMC sodium, croscarmellose sodium and the like.
安定剤としては、例えば、ヒンダードフェノール系の酸化防止剤;またはベンゾトリアゾール系、ヒンダードアミン系の紫外線吸収剤等が挙げられる。 Examples of the stabilizer include a hindered phenol-based antioxidant; or a benzotriazole-based or hindered amine-based ultraviolet absorber.
pH調整剤としては、例えば、リン酸、酢酸、水酸化ナトリウム等が挙げられる。 Examples of the pH adjuster include phosphoric acid, acetic acid, sodium hydroxide and the like.
防菌防黴剤としては、例えば、1,2−ベンゾイソチアゾリン−3−オン等の工業用殺菌剤、防菌防黴剤等が挙げられる。 Examples of the antibacterial and antifungal agent include industrial fungicides such as 1,2-benzoisothiazolin-3-one, antibacterial and antifungal agents, and the like.
増粘剤としては、例えば、キサンタンガム、グアーガム、CMCナトリウム、アラビアゴム、ポリビニルアルコール、モンモリロナイト等が挙げられる。 Examples of the thickener include xanthan gum, guar gum, CMC sodium, gum arabic, polyvinyl alcohol, montmorillonite and the like.
消泡剤としては、例えば、シリコーン系化合物等が挙げられる。 Examples of the defoaming agent include silicone compounds and the like.
凍結防止剤としては、例えば、プロピレングリコール、エチレングリコール等が挙げられる。 Examples of the antifreeze agent include propylene glycol, ethylene glycol and the like.
以上記載した補助剤は例であって、本発明の補助剤は以上のものに何ら限定されるものではない。 The auxiliary agents described above are examples, and the auxiliary agents of the present invention are not limited to the above.
本発明の薬害軽減剤における有効成分の含有量は、通常、重量比で、0.1〜100%の範囲であり、好ましくは、0.1〜90%の範囲であり、さらに好ましくは、1〜80%の範囲であり、特に好ましくは、5〜50%の範囲である。 The content of the active ingredient in the phytotoxicity reducing agent of the present invention is usually in the range of 0.1 to 100% by weight, preferably in the range of 0.1 to 90%, and more preferably 1 It is in the range of ~ 80%, particularly preferably in the range of 5-50%.
本発明の薬害軽減剤は、栽培作物に対する様々な薬害に効果を発揮することができ、例えば、除草性化合物に起因する作物に対する薬害、例えば、生育障害、生育抑制、成長抑制、褐点の出現、分げつ抑制、黄化、葉枯れ、枯死、萎凋、白化、捻転、褐変、根部生長阻害等の薬害を軽減することができる。
本発明の薬害軽減剤は、中でも、除草性化合物に起因する作物に対する薬害抑制効果に特に優れる。The phytotoxicity reducing agent of the present invention can exert an effect on various phytotoxicity on cultivated crops, for example, phytotoxicity on crops caused by herbicidal compounds, for example, growth disorder, growth inhibition, growth inhibition, appearance of brown spots. It can reduce phytotoxicity such as weed control, yellowing, leaf withering, withering, wilting, whitening, twisting, browning, and root growth inhibition.
The phytotoxicity reducing agent of the present invention is particularly excellent in the phytotoxicity-suppressing effect on crops caused by herbicidal compounds.
本発明の殺菌性化合物を有効成分とする薬害軽減剤は、除草性化合物に起因する作物に対する薬害、例えば、生育障害、生育抑制、成長抑制、褐点の出現、分げつ抑制、黄化、葉枯れ、枯死、萎凋、白化、捻転、褐変、根部生長阻害等を回避することが可能である。
対象作物として、例えば、イネ、コムギ、オオムギ、ジャガイモ、トウモロコシ、ブドウ、リンゴ、ナシ、モモ、ネクタリン、ウメ、アンズ、オウトウ、カキ、カリン、マルメロ、クリ、キューイフルーツ、ブルーベリー、ビワ、バナナ、カンキツ、イチジク、オリーブ、パパイヤ、アケビ、アブラヤシ、ダイズ、ラッカセイ、インゲン、エンドウ、サヤエンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミズナ、ミブナ、カブ、コマツナ、ハクサイ、ブロッコリー、カリフラワー、ナバナ、レタス、トマト、ナス、ピーマン、トウガラシ、トウガン、ネギ、タマネギ、ワケギ、キュウリ、ニガウリ、メロン、スイカ、カボチャ、ズッキーニ、ニンジン、ミョウガ、ショウガ、ゴボウ、ウド、タラノキ、ホウレンソウ、テンサイ、アスパラガス、オクラ、セリ、ベニバナ、ナタネ、ミツバ、サツマイモ、サトイモ、ヤマノイモ、コンニャク、サトウキビ、タバコ、チャ、コーヒー、ヒマワリ、チューリップ、カーネーション、バジル、アイリス、アスター、バラ、キク、ワタ、ポップ、リンドウ、ユリ、ボタン、シャクヤク、シクラメン、ラッキョウ、コショウ、ニンニク、フキ、シソ、シナモン、ワサビ、タラノキ、レンコン、ソルガム、西洋芝(ベントグラス、バミューダグラス、ブルーグラス、ライグラス)、日本芝、オーチャードグラス、イタリアンライグラス、アルファルファ、レッドクローバー、カノコソウ、クワ、ケイトウ、ホウズキ、キンセンカ、ベニバナ、ツツジ類、サクラ、カシ、ボケ、ポプラ、イヌツゲ、ジンチョウゲ、樹木類、材木(苗木)等が挙げられる。
中でもイネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッコリー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木(苗木)、西洋芝(ベントグラス、ライグラス、ブルーグラス)、日本芝が好ましく、イネ、テンサイ、西洋芝、日本芝、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、エンドウ等がより好ましく、イネが特に好ましいThe phytotoxicity-reducing agent containing the bactericidal compound of the present invention as an active ingredient may cause phytotoxicity to crops caused by the herbicidal compound, for example, growth disorder, growth inhibition, growth inhibition, appearance of brown spots, sprinkling inhibition, yellowing, It is possible to avoid leaf withering, withering, wilting, bleaching, twisting, browning, inhibition of root growth, and the like.
Target crops include, for example, rice, wheat, barley, potato, corn, grape, apple, pear, peach, nectarine, seaweed, apricot, peach, oyster, karin, marmelo, chestnut, kiwi fruit, blueberry, biwa, banana, citrus. , Fig, olive, papaya, akebi, abra palm, soybean, lacquer, green onion, pea, pea pea, perilla, azuki, strawberry, cabbage, radish, mizuna, mibuna, turnip, komatsuna, hakusai, broccoli, cauliflower, navana, lettuce, tomato , Eggplant, peppers, Japanese mustard spinach, Japanese mustard spinach, green onion, onion, sardine, cucumber, Japanese mustard spinach, melon, watermelon, pumpkin, zucchini, carrot, myoga, ginger, gobo, udo, taranoki, spinach, tensai, asparagus, okura, seri, Benibana, rapeseed, honeybee, sweet potato, sweet potato, yamanoimo, konjak, sugar cane, tobacco, cha, coffee, sunflower, tulip, carnation, basil, iris, aster, rose, kiku, cotton, pop, lindo, lily, button, shakuyaku, Cyclamen, rakkyo, pepper, garlic, fuki, perilla, cinnamon, wasabi, taranoki, renkon, sorghum, western turf (bentgrass, Bermudagrass, bluegrass, ryegrass), Japanese turf, orchardgrass, Italian ryegrass, alfalfa, red clover, Examples include Aralia cordata, Kuwa, Keito, Aralia cordata, Kinsenka, Benibana, Tsutsuji, Sakura, Kashi, Bokeh, Poplar, Inutsuge, Jinchoge, Trees, Timber (sapling) and the like.
Among them, rice, wheat, caterpillar, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green beans, peas, soramame, azuki, strawberry, cabbage, radish, mibuna, mizuna, cub, nabana, hakusai, broccoli, cauliflower , Lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, sugar cane, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honeybee, ginger, corn, tobacco, carnation, iris, kiku, fig, Rice, sugar beet, western turf, Japanese turf, wheat, corn, corn, rapeseed, cotton, sunflower, sugar cane, pea, etc. are preferable, such as citrus, timber (sapling), western turf (bentgrass, ryegrass, bluegrass), and Japanese turf. More preferred, especially rice
本発明において、イネとはイネ科イネ属(Oryza)の一年生植物を示し、2つの生態型であるジャポニカ種(O.sativa subsp.japonica)とインディカ種(O.sativa subsp. indica)に分類される。また、イネの食用部分の主成分であるでんぷんは、分子構造の違いからアミロースとアミロペクチンに分別され、20%程度のアミロースを含む品種がうるち(粳)、遺伝的欠損によりアミロース含量が0%である品種がもち(糯)に分類される。具体的なうるち品種として、例えば、コシヒカリ、日本晴、あきたこまち、きらら397、キヌヒカリ、ひとめぼれ、ななつぼし、ほしのゆめ、はえぬき、どまんなか、ササニシキおよびヒノヒカリ等が、もち品種として、例えば、羽二重糯、大正糯、こがねもち、みやこがねもち、旭糯、藤蔵糯、ヒヨクモチ、ヒメノモチ、もちひかり、ゆめのはたもち、はくちょうもち、トヨハタモチ、わたぼうし等が、低アミロース品種として、例えば、彩、ミルキークイーン、夢ごこち、イクヒカリ、ミルキーパール、ヒメノモチ等が、酒造好適米として、例えば、山田錦、五百万石、美山錦、雄町、八反、八反錦、吟風、ゆめさんさ、若水、夢の香、渡船等、飼料用として、例えば、ホシユタカ、ホシアオバ、クサノホシ、クサユタカ、ニシアオバおよびミナミユタカ等が挙げられる。この他、陸稲、黒米、赤米、緑米および耐病性、耐虫性を指標として育種された特殊な品種、古典的な育種法または遺伝子組換え技術により除草剤耐性、殺虫効果、病害虫に対する抵抗性を付与された品種も含まれる。 In the present invention, rice refers to an annual plant of the genus Oryza of the family Gramineae, and is classified into two ecological types, Japonica species (O. sativa subsp. Japanica) and Indica species (O. sativa subsp. Indica). To. In addition, starch, which is the main component of the edible portion of rice, is divided into amylose and amylopectin due to the difference in molecular structure, and varieties containing about 20% amylose are glutinous (rice cake), and the amylose content is 0% due to genetic deficiency. The varieties that are are classified as mochi (starch). Specific rice varieties include, for example, Koshihikari, Nihonharu, Akita Komachi, Kirara 397, Kinuhikari, Hitomebore, Nanatsuboshi, Hoshino Yume, Haenuki, Domannaka, Sasanishiki, and Hinohikari. Rice, Taisho rice, Kogane mochi, Miyako gane mochi, Asahi rice, Fujikura rice, Hiyokumochi, Himenomochi, Mochihikari, Yume no Hatamochi, Hakuchomochi, Toyohatamochi, Wataboshi, etc. are low amylose varieties, for example, Aya. , Milky Queen, Yumegokochi, Ikuhikari, Milky Pearl, Himenomochi, etc. are suitable rice for sake brewing, for example, Yamada Nishiki, Gohyakumangoku, Miyama Nishiki, Omachi, Hattan, Hattan Nishiki, Ginfu, Yumesansa, Wakamizu. For feed, for example, Hoshiyutaka, Hoshiaoba, Kusanohoshi, Kusayutaka, Nishiaoba, Minamiyutaka, etc. can be mentioned. In addition, upland rice, black rice, red rice, green rice and special varieties cultivated using disease resistance and insect resistance as indicators, herbicide resistance, insecticidal effect, resistance to pests by classical breeding methods or genetic recombination technology Breeds that have been given sex are also included.
本発明において、対象作物としては、イネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッコリー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木(苗木)、西洋芝(ベントグラス、ライグラス、ブルーグラス)もしくは日本芝であることが好ましい。本発明の薬害軽減剤は、これらの作物において除草性化合物に起因する薬害を軽減する効果に特に優れる。 In the present invention, the target crops include rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green pepper, pea, cauliflower, azuki, strawberry, cabbage, daikon, mibuna, mizuna, and turnip. , Navana, Chinese cabbage, broccoli, cauliflower, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, pepper, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honeybee, ginger, raccoon, tobacco, It is preferably carnation, iris, kiku, fig, cabbage, timber (sapling), western turf (bentgrass, ryegrass, bluegrass) or Japanese turf. The phytotoxicity reducing agent of the present invention is particularly excellent in the effect of reducing phytotoxicity caused by herbicidal compounds in these crops.
本発明の殺菌性化合物を有効成分とする薬害軽減剤は、本来の殺菌活性に起因する植物病害防除としても使用できる。防除できる病害としては、
例えば、イネのいもち病(Magnaporthe grisea)、紋枯病(Thanatephorus cucumeris)、褐色菌核病(Ceratobasidium setariae)、褐色小粒菌核病(Waitea circinata)、褐色紋枯病(Thanatephorus cucumeris)、球状菌核病(Sclerotium hydrophilum)、赤色菌核病(Wairea circinata)、黒しゅ病(Entyloma dactylidis)、小球菌核病(Magnaporthe salvinii)、灰色菌核病(Ceratobasidium cornigerum)、ごま葉枯病(Cochliobolus miyabeanus)、条葉枯病(Sphaerulina oryzina)、ばか苗病(Gibberella fujikuroi)、苗立枯病(Pythium spp.、Fusarium spp.、Trichoderma spp.、Rhizopus spp.、Rhizoctonia solani、Mucor sp.)、苗腐病(Pythium spp.、Achlya spp.、Dictyuchus spp.)、稲こうじ病(Claviceps virens)、墨黒穂病(Tilletia barclayana)、褐色米(Curvularia spp.、Alternaria spp.)、黄化萎縮病(Sclerophthora macrospora)、白葉枯病(Xanthomonas oryzae pv. oryzae)、褐条病(Acidovorax avenae subsp. avenae)、内頴褐変病(Erwinia ananas)、苗立枯細菌病(Burkholderia plantarii)、もみ枯細菌病(Burkholderia glumae)、葉鞘褐変病(Pseudomonas fuscovaginae)、かさ枯病(Pseudomonas syringae pv.oryzae)、株腐病(Erwinia chrysanthemi)、黄萎病(Phytoplasma oryzae)、縞葉枯病(Rice stripe tenuivirus)、萎縮病(Rice dwarf reovirus);The phytotoxicity reducing agent containing the bactericidal compound of the present invention as an active ingredient can also be used for controlling plant diseases caused by the original bactericidal activity. Diseases that can be controlled include
For example, rice blast disease (Magnaporthe grisea), sclerotium sulcus (Thanatephorus sclerotium), brown sclerotium (Ceratobasidium setaliae), brown small-grained fungus nuclei (Waitea cyrcinatus), brown sclerotium Disease (Sclerotium hydrophilum), Red sclerotium disease (Wairea cyclinata), Black scab (Entyloma dactylidis), Small bulbar sclerotium disease (Magnaporthe salvinii), Gray sclerotium disease (Ceratobi) Sclerotium oryzina, idiot seedling disease (Gibberella fujikuroi), seedling blight (Phythium spp., Sclerotium spp., Trichoderma spp., Rhizoctonia spp., Rhizoctonia spp., Rhizoctonia spp., Rhizoctonia spp. Pythium spp., Achlya spp., Dictyuchus spp.), Clavices virens, Tilletia barclayana, brown rice (Curvalaria spp., Alternaria spp., Alternaria sp.), Sclerotia spp. White leaf blight (Xanthomonas oryzae pv. Oryzae), brown streak disease (Acidovorax avenae subsp. Avenae), rhizoctonia chinensis (Erwinia ananas), seedling blight (Burkara) splerotium blight Leaf sheath browning disease (Pseudomonas fuscovaginae), capsular blight (Pseudomonas syringae pv. Oryzae), strain rot (Erwinia chrysanthemi), yellow wilt disease (Phytoplasma) reovirus);
ムギ類のうどんこ病(Blumeria graminis f.sp.hordei; f.sp.tritici)、さび病(Puccinia striiformis、 Puccinia graminis、Puccinia recondita、Puccinia hordei)、斑葉病(Pyrenophora graminea)、網斑病(Pyrenophora teres)、赤かび病(Gibberella zeae、Fusarium culmorum、Fusarium avenaceum、Monographella nivalis)、雪腐病(Typhula incarnata、Typhula ishikariensis、Monographella nivalis)、裸黒穂病(Ustilago nuda)、なまぐさ黒穂病(Tilletia caries、Tilletia controversa)、眼紋病(Pseudocercosporella herpotrichoides)、株腐病(Ceratobasidium gramineum)、雲形病(Rhynchosporium secalis)、葉枯病(Septoria tritici)、ふ枯病(Phaeosphaeria nodorum)、苗立枯病(Fusarium spp.、Pythium spp.、Rhizoctonia spp.、Septoria spp.、Pyrenophora spp.)、立枯病(Gaeumannomyces graminis)、炭疽病(Colletotrichum graminicola)、麦角病(Claviceps purpurea)、斑点病(Cochliobolus sativus)、黒節病(Pseudomonas syringae pv. syringae); Udonko disease of wheat (Blumeria graminis f.sp.hordei; f.sp.tritici), rust (Puccinia striiformis, Puccinia graminis, Puccinia praminis, Puccinia recondita, Puccinia recondita, Puccinia leaf blight, Fusarium head blight, Fusarium head blight, Fusarium head blight, Fusarium head blight. Pyrenophora teres), Fusarium head blight (Gibberella zeae, Fusarium culmorum, Fusarium avenaceum, Monographella nivalis), snow mold (Typhula incarnata, Typhula ishikariensis, Monographella nivalis), loose smut (Ustilago nuda), fishy smell smut (Tilletia caries, Tilletia controlrosa, Puccinia cosporella herpotorichoides, Ceratobasidium gramineum, Monographella nivalis, Fusarium funis, Fusarium head blight, Fusarium head blight, Fusarium head blight, Fusarium head blight , Puccinia spp., Rhizoctonia spp., Septoria spp., Pyrenophora spp.), Gaeumanomyces graminis, Colletotrichu vulgaris, Colletotrichum vulgaris, Fusarium head blight Disease (Pseudomonas syringae pv. Silingae);
トウモロコシの赤かび病(Gibberella zeae等)、苗立枯病(Fusarium avenaceum、 Penicillium spp、 Pythium spp.、Rhizoctonia spp.)、さび病(Puccinia sorghi)、ごま葉枯病(Cochliobolus heterostrophus)、黒穂病(Ustilago maydis)、炭疽病(Colletotrichum graminicola)、北方斑点病(Cochliobolus carbonum)、褐条病(Acidovorax avenae subsp. avenae)、条斑細菌病(Burkholderia andropogonis)、倒伏細菌病(Erwinia chrysanthemi pv. zeae)、萎ちょう細菌病(Erwinia stewartii);ブドウのべと病(Plasmopara viticola)、さび病(Physopella ampelopsidis)、うどんこ病(Uncinula necator)、黒とう病(Elsinoe ampelina)、晩腐病(Glomerella cingulata、 Colletotrichum acutatum)、黒腐病(Guignardia bidwellii)、つる割病(Phomopsis viticola)、すす点病(Zygophiala jamaicensis)、灰色かび病(Botrytis cinerea)、芽枯病(Diaporthe medusaea)、紫紋羽病(Helicobasidium mompa)、白紋羽病(Rosellinia necatrix)、根頭がんしゅ病(Agrobacterium vitis); Fusarium head blight (Gibberella zeae, etc.), Bacterial blight (Fusarium avenceum, Pencillum spp, Pythium spp., Rhizoctonia spp.), Panama disease (Puccinia cochliobolus), Black rot (Puncinia cochliobolus) Ustylago mayidis, Botrytis cinerea, Botrytis cinerea, Cochliobolus carbonum, Fusarium head blight, Fusarium head blight, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea. Bacterial wilt disease (Erwinia stewartii); Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea, Botrytis cinerea actatum), black rot (Guignardia bidwellii), Panama disease (Phomopsis viticola), soot spot disease (Zygophila jamacinsis), Botrytis cinerea, sprouting disease (Bottrytis cinerea), bud blight ), Botrytis cinerea, Fusarium head blight (Agrobacteria vitis);
リンゴのうどんこ病(Podosphaera leucotricha)、黒星病(Venturia inaequalis)、斑点落葉病(Alternaria mali)、赤星病(Gymnosporangium yamadae)、モニリア病(Monilinia mali)、腐らん病(Valsa ceratosperma)、輪紋病(Botryosphaeria berengeriana)、炭疽病(Colletotrichum acutatum、Glomerella cingulata)、すす点病(Zygophiala jamaicensis)、すす斑病(Gloeodes pomigena)、黒点病(Mycosphaerella pomi)、紫紋羽病(Helicobasidium mompa)、白紋羽病(Rosellinia necatrix)、胴枯病(Phomopsis mali、Diaporthe tanakae)、褐斑病(Diplocarpon mali)、リンゴの火傷病(Erwinia amylovora)、根頭がんしゅ病(Agrobacterium tumefaciens)、毛根病(Agrobacterium rhizogenes);ナシの黒斑病(Alternaria kikuchiana)、黒星病(Venturia nashicola)、赤星病(Gymnosporangium asiaticum)、輪紋病(Botryosphaeria berengeriana f.sp. piricola)、胴枯病(Phomopsis fukushii)、枝枯細菌病(Erwinia sp.)、根頭がんしゅ病(Agrobacterium tumefaciens)、さび色胴枯病(Erwinia chrysanthemi pv. chrysanthemi)、花腐細菌病(Pseudomonas syringae pv. syringae);セイヨウナシの疫病(Phytophthora cactorum、 Phytophthora syringae)、枝枯細菌病(Erwinia sp.);モモの黒星病(Cladosporium carpophilum)、ホモプシス腐敗病(Phomopsis sp.)、疫病(Phytophthora sp.)、炭疽病(Colletotrichum gloeosporioides)、縮葉病(Taphrina deformans)、穿孔細菌病(Xhanthomonas campestris pv. pruni)、根頭がんしゅ病(Agrobacterium tumefaciens);オウトウの炭疽病(Glomerella cingulata)、幼果菌核病(Monilinia kusanoi)、灰星病(Monilinia fructicola)、根頭がんしゅ病(Agrobacterium tumefaciens)、樹脂細菌病(Pseudomonas syringae pv. syringae);カキの炭疽病(Glomerella cingulata)、落葉病(Cercospora kaki; Mycosphaerella nawae)、うどんこ病(Phyllactinia kakikora)、根頭がんしゅ病(Agrobacterium tumefaciens);カンキツの黒点病(Diaporthe citri)、緑かび病(Penicillium digitatum)、青かび病(Penicillium italicum)、そうか病(Elsinoe fawcettii)、褐色腐敗病(Phytophthora citrophthora)、かいよう病(Xhanthomonas campestris pv. citri)、褐斑細菌病(Pseudomonas syringae pv. syringae)、グリーニング病(Liberibactor asiaticus)、根頭がんしゅ病(Agrobacterium tumefaciens); Apple's Udonko disease (Podosphaera leucotricha), scab (Venturia inaequualis), spotted foliage disease (Alternaria mari), gymnosporangium yamadae, gymnosporangium yamadae, Monilla disease (Minaria) Botryosphaeria berengeriana), Colletotricum actatum, Glomerella cingulata, Gymnosporangium gymaicensis, Gymnosporangium, Gymnosporangium, Gymnosporangium, Gymnosporangium, Gymnosporangium (Rosellina necatrix), Phomopsis mari, Diaporthe tanakae, Diplocarpon mari, apple burn disease (Erwinia amylovora), Gymnosporangium (Gymnosporangium), Gymnosporangium (Gymnosporangium), Gymnosporangium (Phomopsis mari, Diaporthe tanakae) Pear black spot disease (Alternaria kikuchiana), scab (Venturia nashicola), gymnosporangium asiaticum, ring-spot disease (Botryosphaeria sciatiaticum), bacillus phosparia bericia serrata. (Erwinia sp.), Gymnosporangium tumefaciens, Erwinia chrysanthemi pv. Chrysanthemi, Pseudomonas symptom (Pseudomonas symptom), Phomopsis syllabus, Gymnosporangium serrata, Gymnosporangium sp. Phytophora syringae, Bacterial blight (Erwinia sp.); Gymnosporangium peach (Cladosporium carpophilum), Phomopsis sp., Epidemic (P.) hytophora sp. ), Colletotricum gloeosporeoides, Taphrina deformans, Xanthomonas campestris pv. Pruni, Radical bacterium, Agrobacterium sickness, Xanthomonas campestris pv. Pruni, Xanthomonas campestris pv. Mycorinia kusanoi, ash (Monilinia fracticola), root cancer disease (Agrobacterium tumefaciens), resin bacterial disease (Pseudomonas syringae pv. Syringa) cartilage (Pseudomonas syringae pv. Cercospora kaki; Mycosphaerella nawae, Phyllactinia kakikora, Agrobacterium tumefaciens; Xanthomonas campis, Xanthomonas campis, Xanthomonas campis, Xanthomonas campis, Xanthomonas campis Elsinoe fawcettii, Phytophthora citropthora, Xanthomonas campestris pv. Citri, Pseudomonas radii sickness, Pseudomonas sylvestris, scabies, scabies, scabies, scabies, scabies, scabies, scabies, scabies. Agrobacterium tumefaciens;
トマト、キュウリ、豆類、イチゴ、ジャガイモ、キャベツ、ナス、レタス等の灰色かび病(Botrytis cinerea);トマト、キュウリ、豆類、イチゴ、ジャガイモ、ナタネ、キャベツ、ナス、レタス等の菌核病(Sclerotinia sclerotiorum);トマト、キュウリ、豆類、ダイコン、スイカ、ナス、ナタネ、ピーマン、ホウレンソウ、テンサイ等各種野菜の苗立枯病(Rhizoctonia spp.、Pythium spp.、Fusarium spp.、Phythophthora spp.、Sclerotinia sclerotiorum等);ナス科植物の青枯病(Ralstonia solanacearum);ウリ類のべと病(Pseudoperonospora cubensis)、うどんこ病(Sphaerotheca fuliginea)、炭疽病(Colletotrichum orbiculare)、つる枯病(Didymella bryoniae)、つる割病(Fusarium oxysporum)、疫病(Phytophthora parasitica、Phytophthora melonis、Phytophthora nicotianae、Phytophthora drechsleri、Phytophthora capsici等)、褐斑細菌病(Xhanthomonas campestris pv.cucurbitae)、軟腐病(Erwinia carotovora subsp. carotovora)、斑点細菌病(Pseudomonas syringae pv. lachrymans)、縁枯細菌病(Pseudomonas marginalis pv. marginalis)、がんしゅ病(Streptomyces sp.)、毛根病(Agrobacterium rhizogenes)、キュウリモザイクウィルス(Cucumber mosaic virus);トマトの輪紋病(Alternaria solani)、葉かび病(Fulvia fulva)、疫病(Phytophthora infestans)、萎凋病(Fusarium oxysporum)、根腐病(Pythium myriotylum、Pythium dissotocum)、炭疽病(Colletotrichum gloeosporioides)、かいよう病(Clavibacter michiganensis)、茎えそ細菌病(Pseudomonas corrugata)、黒斑細菌病(Pseudomonas viridiflava)、軟腐病(Erwinia carotovora subsp. carotovora)、葉こぶ病(Crynebacterium sp.)、萎黄病(Phytoplasma asteris)、黄化萎縮病(Tabaco leaf curl subgroup III geminivirus);ナスのうどんこ病(Sphaerotheca fuliginea等)、すすかび病(Mycovellosiella nattrassii)、疫病(Phytophthora infestans)、褐色腐敗病(Phytophthora capsici)、褐斑細菌病(Pseudomonas cichorii)、茎えそ細菌病(Pseudomonas corrugata)、茎腐細菌病(Erwinia chrysanthemi)、軟腐病(Erwinia carotovora subsp. carotovora)、斑点細菌病(Pseudomonas sp.); Gray mold (Botrytis cinerea) such as tomatoes, cucumbers, beans, strawberries, potatoes, cabbage, eggplants, lettuce; Phytophthora sclerotiorum such as tomatoes, cucumbers, beans, strawberries, potatoes, rapeseed, cabbage, eggplants, lettuce ); Seedling blight of various vegetables such as tomatoes, cucumbers, beans, daikon, watermelons, eggplants, rapeseed, peppers, phytophthora spp., Phytophthora spp., Phytophthora spp., Phytophthora spp. Ralstonia solanacerum; Phytophthora coubensis, Phytophthora phytophthora, Didymella brysophylla, Colletotric (Fusarium oxysporum), plague (Phytophthora parasitica, Phytophthora melonis, Phytophthora nicotianae, Phytophthora drechsleri, Phytophthora capsici, etc.), brown spot bacterial diseases (Xhanthomonas campestris pv.cucurbitae), soft rot (Erwinia carotovora subsp. carotovora), spot bacterial ( Pseudomonas syringae pv. Lachrymans, Didymella brystophylla (Pseudomonas marginalis pv. Marginalis), Cancer disease (Streptomyces sp.), Phytophthora cucumber cucumber cucumber cucumber cucumber cucumber cucumber cucumber cucumber cucumber (Alternaria solani), leaf mold (Fulvia fulva), plague (Phytophthora influences), wilt disease (Fusalyum oxysporum), root rot (Phytophthora thyliothylum, Pyth) ium disotocum, anthrax (Collettrichum gloeosporeoides), scab (Clavibacter michiganensis), stalk bacterial disease (Pseudomonas corrugata), black spot bacterial disease (Pseudomonas corrugata), black spot bacterial disease (Pseudomonas) carotovora), leaf hump disease (Crynebacteriaium sp.), Pseudomonas asteris, Pseudomonas japonicum (Tabaco leaf curl subgrop III geminivirus), Pseudomonas vulgaris, Pseudomonas vulgaris, Pseudomonas vulgaris. , Pseudomonas bacteria, Pseudomonas cithorii, Pseudomonas corrugata, Pseudomonas corrugata, Pseudomonas corrugata, Pseudomonas corrugata, Pseudomonas corrugata, Pseudomonas corrugata carotovora), Bacterial spot disease (Pseudomonas sp.);
ナタネの黒斑病(Alternaria brassicae)、黒腐病(Xhanthomonas campestris pv. campestris)、黒斑細菌病(Pseudomonas syringae pv. maculicola)、軟腐病(Erwinia carotovora);アブラナ科野菜の黒斑病(Alternaria brassicae等)、白斑病(Cercosporella brassicae)、根朽病(Phoma lingam)、根こぶ病(Plasmodiophora brassicae)、べと病(Peronospora parasitica)、黒腐病(Xhanthomonas campestris pv. campestris)、黒斑細菌病(Pseudomonas syringae pv. maculicola)、軟腐病(Erwinia carotovora subsp. carotovora);キャベツの株腐病(Thanatephorus cucumeris)、萎黄病(Fusarium oxysporum);ハクサイの尻腐病(Rhizoctonia solani)、黄化病(Verticillium dahliae);ネギのさび病(Puccinia allii)、黒斑病(Alternaria porri)、白絹病(Sclerotium rolfsii)、白色疫病(Phytophthora porri)、黒腐菌核病(Sclerotium cepivorum);タマネギのかいよう病(Curtobacterium flaccumfaciens)、軟腐病(Erwinia carotovora subsp. carotovora)、斑点細菌病(Pseudomonas syringae pv. syringae)、腐敗病(Erwinia rhapontici)、鱗片腐敗病(Burkholderia gladioli)、萎黄病(Phytoplasma asteris);ニンニクの軟腐病(Erwinia carotovora subsp. carotovora)、春腐病(Pseudomonas marginalis pv.marginalis);ダイズの紫斑病(Cercospora kikuchii)、黒とう病(Elsinoe glycines)、黒点病(Diaporthe phaseolorum)、リゾクトニア根腐病(Rhizoctonia solani)、茎疫病(Phytophthora sojae)、べと病(Peronospora manshurica)、さび病(Phakopsora pachyrhizi)、炭疽病(Colletotrichum truncatum等)、葉焼病(Xhanthomonas campestris pv. glycines)、斑点細菌病(Pseudomonas syringae pv. glycinea); Pectobacterium carotobacterium (Pseudomonas syringae pv. Maclicola), Pectobacterium carotobacterium (Pseudomonas syringae pv. Maculica), Pectobacterium carotobacterium (Pseudomonas syringae pv. Maculica), Pectobacterium carotobacterium (Pseudomonas syringae pv. Etc.), White spot disease (Cercosporella brassicae), Root rot disease (Phoma lingama), Root hump disease (Plasmodiophora brassicae), Penot disease (Peronospora parastica), Black rot (Xhanthoma) black rot (Xhanthoma) . Pseudomonas syringae pv maculicola), soft rot (Erwinia carotovora subsp carotovora);. cabbage of stock rot (Thanatephorus cucumeris), yellows disease (Fusarium oxysporum); Chinese cabbage ass rot (Rhizoctonia solani), Kikabyo (Verticillium dahliae ); Pseudomonas rust (Puccinia alli), black spot disease (Alternaria porri), white silk disease (Sclerotium lorfsii), white epidemic (Pytobacterium porri), black rotobacter carotobacterium (Sclerotium caroto .. flaccumfaciens), soft rot (Erwinia carotovora subsp carotovora), spot bacterial (Pseudomonas syringae pv syringae), rot (Erwinia rhapontici), scale rot (Burkholderia gladioli), yellows disease (Phytoplasma asteris); garlic soft rot (Erwinia carotovora subsp. Carotovora), Spring rot (Pseudomonas marginalis pv. Marginalis); Soybean purple spot disease (Cerc) ospora kikuchii, black scab (Elsinoe gycines), black spot disease (Diaporthe phaseolorum), Rhizoctonia root rot (Rhizoctonia solani), stalk epidemic (Phytophthora sako) Charcoal rot (Collettrichum truncatum, etc.), Downy mildew (Xhanthomonas campestris pv. glycines), Pseudomonas syringae pv. Glycinea;
インゲンの炭疽病(Colletotrichum lindemuthianum)、青枯病(Ralstonia solanacearum)、かさ枯病(Pseudomonas syringae pv. phaseolicola)、褐斑細菌病(Pseudomonas viridiflava)、葉焼病(Xhanthomonas campestris pv. phaseoli);ラッカセイの黒渋病(Mycosphaerella berkeleyi)、褐斑病(Mycosphaerella arachidis)、青枯病(Ralstonia solanacearum);エンドウのうどんこ病(Erysiphe pisi)、べと病(Peronospora pisi)、つる枯細菌病(Pseudomonas syringae pv.pisi)、つる腐細菌病(Xhanthomonas campestris pv. pisi);ソラマメのべと病(Peronospora viciae)、疫病(Phytophthora nicotianae);ジャガイモの夏疫病(Alternaria solani)、黒あざ病(Thanatephorus cucumeris)、疫病(Phytophthora infestans)、銀か病(Helminthosporium solani)、乾腐病(Fusarium oxysporum、Fusarium solani)、粉状そうか病(Spongospora subterranea)、青枯病(Ralstonia solanacearum)、黒あし病(Erwinia carotovora subsp. atroseptica)、そうか病(Streptomyces scabies、Streptomyces acidiscabies)、軟腐病(Erwinia carotovora subsp. carotovora)、粘性腐敗病(Crostridium spp.)、輪腐病(Clavibacter michiganensis subsp.sepedonicus);サツマイモの立枯病(Streptomyces ipomoeae);テンサイの褐斑病(Cercospora beticola)、べと病(Peronospora schachtii)、黒根病(Aphanomyces cochioides)、蛇の目病(Phoma betae)、根頭がんしゅ病(Agrobacterium tumefaciens)、そうか病(Streptomyces scabies)、斑点細菌病(Pseudomonas syringae pv. aptata); Ralstonia solanacearum, Ralstonia solanacearum, Pseudomonas syringae pv. Phaseolicola, Ralstonia solanacea, Ralstonia solanaceum, Ralstonia solanacearum, Ralstonia solanacearum, Pseudomonas syringae pv. Black rot of potato (Mycosphaerella berkeleii), brown rot of potato (Mycosphaerella arachidis), brown rot of potato (Ralstonia solanacearum); pea swelling disease (Erysipe pisi), beto disease (Peronisso) . Pisi), Ralstonia solanacearum (Xhanthomonas campestris pv. Pisi); Ralstonia solanaceae (Peronospora viciae), Epidemic (Phytophthora nicotianae); Ralstonia solanacea (Alter) black rot of potato (Alter) (Phytophthora infestans), silver rot (Helminthosporium solani), dry rot (Fusarium oxysporum, Fusarim solani), powdery scab (Spongospora bacterium erosia), brown rot of potato (Ralstonia solana) atroseptica), scab (Streptomyces bacteria, Streptomyces acidiscavies), soft rot (Erwinia carotovora subsp. Carotovora), viscous rot (Crossridia bacteria), rot of potatoes, rot of potatoes, rot of potatoes, rot of potatoes, rot of potatoes. Streptomyces ipomoea); brown rot of potato (Cercospora beticola), sticky disease (Pe) ronospora schatii), black root disease (Aphanomyces cochioides), serpentine disease (Phoma betae), root cancer swelling disease (Agrobacterium tumefaciens), scab (Streptomyces bacillus) scab (Streptomyces sca aptata);
ニンジンの黒葉枯病(Alternaria dauci)、こぶ病(Rhizobacter dauci)、根頭がんしゅ病(Agrobacterium tumefaciens)、ストレプトミセスそうか病(Streptomyces spp.)、軟腐病(Erwinia carotovora subsp. carotovora);イチゴのうどんこ病(Sphaerotheca aphanis var. aphanis)、疫病(Phytophthora nicotianae等)、炭疽病(Glomerella cingulata等)、果実腐敗病(Pythium ultimum)、青枯病(Ralstonia solanacearum)、角斑細菌病(Xhanthomonas campestris)、芽枯細菌病(Pseudomonas marginalis pv. marginalis);チャの網もち病(Exobasidium reticulatum)、白星病(Elsinoe leucospila)、炭疽病(Colletotrichum theae−sinensis)、輪斑病(Pestalotiopsis longiseta)、赤焼病(Pseudomonas syringae pv.theae)、かいよう病(Xhanthomonas campestris pv. theicola)、てんぐ巣病(Pseudomonas sp.);タバコの赤星病(Alternaria alternata)、うどんこ病(Erysiphe cichoracearum)、炭疽病(Colletotrichum gloeosporioides)、疫病(Phytophthora nicotianae)、野火病(Pseudomonas syringae pv.tabaci)、黄がさ細菌病(Pseudomonas syringae pv.mellea)、空洞病(Erwinia carotovora subsp. carotovora)、立枯病(Ralstonia solanacearum)、タバコモザイクウィルス(Tobaco mosaic virus);ワタの立枯病(Fusarium oxysporum);ヒマワリの菌核病(Sclerotinia sclerotiorum)、角点病(Xhanthomonas campestris pv.malvacearum)、空洞病Erwinia carotovora subsp. carotovora)、斑点細菌病(Pseudomonas syringae pv.helianthi);バラの黒星病(Diplocarpon rosae)、うどんこ病(Sphaerotheca pannosa等)、疫病(Phytophthora megasperma)、べと病(Peronospora sparsa)、根頭がんしゅ病(Agrobacterium tumefaciens);キクの褐斑病(Septoria obesa)、白さび病(Puccinia horiana)、疫病(Phytophthora cactorum)、斑点細菌病(Pseudomonas cichorii)、軟腐病(Erwinia carotovora subsp. carotovora)、根頭がんしゅ病(Agrobacterium tumefaciens)、毛根病(Agrobacterium rhizogenes)、緑化病(Phytoplasma aurantifolia);芝のブラウンパッチ病(Rhizoctonia solani)、ダラースポット病(Sclerotinia homoeocarpa)、カーブラリア葉枯病(Curvularia sp.)、さび病 (Puccinia zoysiae)、ヘルミントスポリウム葉枯病(Cochliobolus sp.)、雲形病(Rhynchosporium secalis)、立枯病(Gaeumannomyces graminis)、炭疽病(Colletotrichum sp.)、雪腐褐色小粒菌核病(Typhula incarnata)、雪腐黒色小粒菌核病(Typhula ishikariensis)、雪腐大粒菌核病(Myriosclerotinia borealis)、フェアリーリング病(Marasmius oreades等)、ピシウム病(Pythium aphanidermatum等)、いもち病(Pyricularia grisea)等が挙げられる。 Carrot black leaf blight (Alternaria dauci), hump disease (Rhizobacter dauci), root cancer scab (Agrobacterium tumefaciens), Streptomyces scab (Streptomyces spp.), Soft rot. Pseudomonas vulgaris (Sphaerotheca aphanis var. Aphanis), plague (Phytophthora nicotianae, etc.), charcoal scab (Glomerella chingulata, etc.), fruit rot (Pseudomonas antrum), fruit rot (Pseudomonas antrum) Campestris), Pseudomonas marginalis pv. Marginalis; Cha's net blast (Exobasidedium reticularatum), white scab (Elsinoe leucosti sliosti sulosa), charcoal scab (Xanthomonas campestris), charcoal scab (Xanthomonas campestris) Pseudomonas syringae pv. Theae, Xanthomonas campestris pv. Theicola, Pseudomonas sp., Pseudomonas sp., Pseudomonas sp., Tobacco red scab (Alternaria), tobacco red scab (Alternaria) gloeosporioides), late blight (Phytophthora nicotianae), wildfire disease (Pseudomonas syringae pv.tabaci), Huang and bacterial diseases (Pseudomonas syringae pv.mellea), cavity disease (Erwinia carotovora subsp. carotovora), damping off (Ralstonia solanacearum), Tobacco mosaic virus; Bacterial wilt of cotton (Fusarium oxysporum); Mycorrhizal disease of sunflower (Sclar) otinia sclerotiorum), Xhanthomonas campestris pv. malvacearum), cavities Erwinia carotovora subsp. carotovora), spot bacterial disease (Pseudomonas syringae pv. Helianthi); rose scab (Diplocarpon rosae), udonko disease (Sphaerotheca pannosasa, etc.), epidemic (Phera), epidemic (Phera) Agrobacterium tumefaciens; brown spot disease of Kiku (Septoria obesa), white rust disease (Puccinia horiana), epidemic (Phytophthora bactorum), spot bacterial disease (Pseudomonas clam) Head cancer disease (Agrobacterium tumefaciens), hair root disease (Agrobacterium rhizogenes), green disease (Pseudomonas aurantifolia); turf brown patch disease (Rhizoctonia saria leaf saturia) turf brown patch disease (Rhizoctonia solari) ), Pseudomonas zoysiae, Helmintsporium leaf blight (Cochliobolus sp.), Rhynchosporium secalis, Gaeumanomyces graminis, Charcoal rot, Colleto Nuclear disease (Typhula incarnata), snow rot black granule bacterium nuclear disease (Typula ishikariensis), snow rot large bacterium nuclear disease (Myriosclerotia borelialis), fairy ring disease (Marasmius oreadias, etc.) Pyricularia bacteria) and the like.
第2に、薬害軽減剤と除草性化合物とを含む薬害軽減された除草性組成物について説明する。 Secondly, the phytotoxicity-reduced herbicidal composition containing the phytotoxicity-reducing agent and the herbicidal compound will be described.
本発明の「薬害軽減剤と除草性化合物とを含む薬害軽減された除草性組成物(以下、除草性組成物と記載)」に含まれる薬害軽減剤は、上述の薬害軽減剤を用いることができる。 The above-mentioned phytotoxicity-reducing agent may be used as the phytotoxicity-reducing agent contained in the "herbicide-reducing composition containing a phytotoxicity-reducing agent and a herbicidal compound (hereinafter referred to as a herbicidal composition)" of the present invention. it can.
本発明の除草性組成物に含まれる除草性化合物としては、下記(A1)乃至(A6)からなる群から選択される除草性化合物又はそれらの塩以外に、例えば、ブロモブチド、シメトリン、ジメタメトリン、ベンタゾン、ダイムロン、クミルロン、オキサジクロメホン、エスプロカルブ、ピリブチカルブ、モリネート、シンメチリン等を挙げることができる。 The herbicidal compound contained in the herbicidal composition of the present invention includes, for example, bromobutide, simethrin, dimetamethrin, and bentazone, in addition to herbicidal compounds selected from the group consisting of the following (A1) to (A6) or salts thereof. , Dimuron, Kumilron, Oxadichromefon, Esprocarb, Pyribuchicarb, Molinate, Symmethyrin and the like.
本発明の除草性組成物は、本発明の効果の観点から、下記(A1)乃至(A6)からなる群より選択される、少なくとも1種類の除草性化合物又はそれらの塩であることが好ましく、下記(A2)及び(A3)からなる群より選択される、少なくとも1種類の除草性化合物又はそれらの塩であることがより好ましい。
(A1)ACCase阻害型除草性化合物
(A2)アセトラクテート合成酵素阻害型除草性化合物
(A3)白化型除草性化合物
(A4)VLCFA阻害型除草性化合物
(A5)プロトポリフィリノーゲンIXオキシダーゼ阻害型除草性化合物
(A6)合成オーキシン系除草性化合物From the viewpoint of the effect of the present invention, the herbicidal composition of the present invention is preferably at least one kind of herbicidal compound selected from the group consisting of the following (A1) to (A6) or a salt thereof. More preferably, it is at least one herbicidal compound selected from the group consisting of the following (A2) and (A3) or a salt thereof.
(A1) ACCase-inhibiting herbicidal compound (A2) Acetractate synthase-inhibiting herbicidal compound (A3) Whitening herbicidal compound (A4) VLCFA-inhibiting herbicidal compound (A5) Protopolyphilinogen IX oxidase-inhibiting herbicide Sex compound (A6) Synthetic auxin-based herbicidal compound
前記(A2)としては、(A2−1)スルホニルウレア系除草性化合物、ピリミジニルサリチル酸系除草性化合物若しくはトリアゾロピリミジン系除草性化合物が好ましく、前記(A3)としては、(A3−1)ピラゾール系除草性化合物若しくはトリケトン系除草性化合物が好ましい。 As the (A2), a (A2-1) sulfonylurea-based herbicidal compound, a pyrimidinyl salicylate-based herbicidal compound or a triazolopyrimidine-based herbicidal compound is preferable, and as the (A3), (A3-1) pyrazole-based herbicide is used. A sex compound or a triketone-based herbicidal compound is preferable.
本発明においては、前記(A2−1)及び(A3−1)からなる群より選択される、少なくとも1種類の除草性化合物又はそれらの塩であることがより好ましい。 In the present invention, at least one herbicidal compound selected from the group consisting of (A2-1) and (A3-1) or a salt thereof is more preferable.
本発明の除草性組成物は、これらの除草性化合物以外に、薬害軽減剤において例示された前記担体や前記補助剤を含むことができる。 In addition to these herbicidal compounds, the herbicidal composition of the present invention may contain the carrier and the auxiliary agent exemplified in the phytotoxicity reducing agent.
本発明の組成物における除草性化合物の含有量は、通常、重量比で、0.1〜90%の範囲であり、好ましくは、1〜80%の範囲であり、さらに好ましくは、5〜50%の範囲である。
本発明の組成物における、薬害軽減剤と除草性化合物の含有量の合計は、通常、重量比で0.1〜90%の範囲であり、好ましくは、1〜80%の範囲であり、さらに好ましくは、5〜50%の範囲である。The content of the herbicidal compound in the composition of the present invention is usually in the range of 0.1 to 90% by weight, preferably in the range of 1 to 80%, more preferably 5 to 50. It is in the range of%.
The total content of the phytotoxicity reducing agent and the herbicidal compound in the composition of the present invention is usually in the range of 0.1 to 90% by weight, preferably in the range of 1 to 80%, and further. It is preferably in the range of 5 to 50%.
本発明の組成物における、薬害軽減剤と除草性化合物の混合比は、通常、重量比で除草性化合物に対し薬害軽減剤が0.001〜1000の比率であり、好ましくは、0.01〜100の比率である。 In the composition of the present invention, the mixing ratio of the phytotoxicity reducing agent and the herbicidal compound is usually 0.001 to 1000 in terms of weight ratio of the phytotoxicity reducing agent to the herbicidal compound, preferably 0.01 to. It is a ratio of 100.
本発明の除草性組成物は、一般的な農薬の製造に関する常法に従って、製造することができる。薬害軽減剤の有効成分である殺菌性化合物および除草性化合物の少なくとも2種類の有効成分を混合し、これに必要に応じて前記の担体および前記の補助剤等を混合して、双方の有効成分を含有する組成物を製造することができる、または、薬害軽減剤の有効成分である殺菌性化合物および除草性化合物のどちらか一方を含有する組成物を先に製造した後、それにもう一方を加え、双方の有効成分を含有する薬害軽減された除草性組成物を製造してもかまわない。 The herbicidal composition of the present invention can be produced according to a general method for producing pesticides. At least two types of active ingredients, a bactericidal compound and a herbicidal compound, which are the active ingredients of the phytotoxicity reducing agent, are mixed, and if necessary, the carrier and the auxiliary agent are mixed, and both active ingredients are used. A composition containing either a bactericidal compound or a herbicidal compound, which is an active ingredient of a phytotoxicity reducing agent, can be produced first, and then the other is added to the composition. , A phytotoxicity-reduced herbicidal composition containing both active ingredients may be produced.
通常、好ましくは双方の有効成分を混合した混合物を調製して、当該薬害軽減された除草性組成物を製造する。
本発明の除草性組成物は、水和剤、フロアブル剤、顆粒水和剤、OD剤、粉剤、液剤、乳剤、粒剤、パック剤等の剤型に製剤化することができる。Usually, a mixture of both active ingredients is preferably prepared to produce the herbicidal composition with reduced phytotoxicity.
The herbicidal composition of the present invention can be formulated into dosage forms such as wettable powders, flowable agents, granule wettable powders, OD agents, powders, liquids, emulsions, granules and packs.
本発明の除草性組成物は、本発明の効果の観点から、薬害軽減剤に含まれる前記有効成分が、ヒドロキシイソキサゾール、ピカルブトラゾクス及びアミスルブロムからなる群より選択される少なくとも1種類の化合物又はその塩であり、かつ除草性化合物が、(A1)乃至(A6)からなる群より選択される、少なくとも1種類の化合物又はそれらの塩であることが好ましい。 In the herbicidal composition of the present invention, from the viewpoint of the effect of the present invention, at least one kind of active ingredient contained in the phytotoxicity reducing agent is selected from the group consisting of hydroxyisoxazole, picalbutrazox and amysulfrom. It is preferable that the compound or a salt thereof, and the herbicidal compound is at least one compound selected from the group consisting of (A1) to (A6) or a salt thereof.
本発明の除草性組成物は、殺菌活性を備えるとともに、本来の除草活性に起因する雑草防除としても使用できる。防除できる雑草として、例えば、メヒシバ、オヒシバ、エノコログサ、アキノエノコログサ、キンエノコログサ、イヌビエ、オオクサキビ、テキサスパニカム、メリケンニクキビ、セイバンモロコシ、シャッターケーン、ギョウギシバ、カラスムギ、ネズミムギ、ブラックグラス、ウマノチャヒキ、アレチノチャヒキ、ヒメカナリークサヨシ、セイヨウヌカボ、スズメノカタビラ、シバムギ、コゴメガヤツリ、ハマスゲ、キハマスゲ、スベリヒユ、アオゲイトウ、ホナガアオゲイトウ、イチビ、アメリカキンゴジカ、ソバカズラ、サナエタデ、アメリカサナエタデ、ハルタデ、ナガバギシギシ、エゾノギシギシ、イタドリ、シロザ、ホウキギ、イヌタデ、イヌホオズキ、シロバナチョウセンアサガオ、マルバアサガオ、アメリカアサガオ、マルバアメリカアサガオ、マメアサガオ、セイヨウヒルガオ、ヒメオドリコソウ、ホトケノザ、オナモミ、野生ヒマワリ、イヌカミツレ、カミツレ、コーンマリーゴールド、オロシャギク、ブタクサ、オオブタクサ、ヒメムカシヨモギ、ヨモギ、セイタカアワダチソウ、アメリカツノクサネム、エビスグサ、フロリダベガーウィード、シロツメクサ、クズ、カラスノエンドウ、ツユクサ、マルバツユクサ、ヤエムグラ、ハコベ、ワイルドラディッシュ、ノハラガラシ、ナズナ、オオイヌノフグリ、フラサバソウ、フィールドパンジー、ワイルドパンジー、ヒナゲシ、ワスレナグサ、オオトウワタ、トウダイグサ、オオニシキソウ、アメリカフウロ、オランダフウロ、スギナ等の畑地雑草、タイヌビエ、ヒメタイヌビエ、タマガヤツリ、コゴメガヤツリ、ヒデリコ、マツバイ、イヌホタルイ、タイワンヤマイ、ミズガヤツリ、クログワイ、コウキヤガラ、シズイ、コナギ、アゼナ、アブノメ、キカシグサ、ヒメミソハギ、ミゾハコベ、チョウジタデ、ウリカワ、ヘラオモダカ、オモダカ、ヒルムシロ、セリ、ミズハコベ、アゼトウガラシ、アメリカアゼナ、タカサブロウ、イボクサ、キシュウスズメノヒエ、エゾノサヤヌカグサ、タケトアゼナ、オオアブノメ、ホソバヒメミソハギ、タウコギ、アメリカセンダングサ、クサネム、アメリカツノクサネム、アゼガヤ、藻類等の水田雑草等が挙げられるが、これらに限定されるものではない。 The herbicidal composition of the present invention has bactericidal activity and can also be used as weed control due to the original herbicidal activity. Weeds that can be controlled include, for example, Japanese morning glory, Japanese morning glory, green foxtail, morning glory, green foxtail, Japanese morning glory, Japanese morning glory, Japanese morning glory, Texas panicum, melken nickname, Seiban morokoshi, shutter cane, Japanese morning glory, Japanese morning glory, Japanese morning glory, Japanese morning glory, Japanese morning glory, Japanese morning glory, Japanese morning glory. Setaria viridis, Setaria viridis, Setaria viridis, Cyperus iria, Cyperus iria, Hamasuge, Kihamasuge, Suberihiyu, Aogateto, Honagaaogeito, Ichibi, American King deer, Soba Kazura, Sanae Tade, American morning glory, Japanese morning glory, Japanese morning glory, Japanese morning glory, Japanese morning glory, Japanese morning glory , Inutade, Inuhozuki, Shirobanachosen Asagao, Maruba Asagao, American morning glory, Malva American morning glory, Mameasagao, Seiyouhirugao, Himeodorikosou, Hotokenoza, Onamomi, Wild sunflower, Inukamitsure, Chamomile, Cyperus iria, Cyperus iria, Cyperus iria Yomogi, Seitaka Awadachisou, American morning glory, Ebisugusa, Florida Begarweed, White foxtail, Kuzu, Karasuno pea, Tsuyukusa, Marubatsuyukusa, Yaemgra, Hakobe, Wild radish, Noharagarashi, Nazuna, Oinunofuguri, Hula , Wasurenagusa, Otowata, Todaigusa, Onishikisou, American Fuuro, Dutch Fuuro, Sugina and other field weeds, Tainubie, Himeta Inubie, Tamagayatsuri, Kogomegayatsuri, Hiderico, Matsubai, Inuhotarui, Taiwanyamai, Mizugaya Azena, Abnome, Kikashigusa, Himemisohagi, Mizohakobe, Choujitade, Urikawa, Heraomodaka, Omodaka, Hirumushiro, Seri, Mizuhakobe, Azetogarashi, American Azena, Takasaburo, Ibokusa, Kishuusuzumenohie , American foxtail, morning glory, paddy weeds such as algae, etc., but are not limited to these.
本発明の除草性組成物は、本発明の薬害軽減剤を含むため、除草性化合物に起因する作物に対する薬害、例えば、成長抑制、褐点の出現、黄化、枯死、萎凋等を回避することが可能である。
対象作物としては、薬害軽減剤において例示された作物を挙げることができる。Since the herbicidal composition of the present invention contains the phytotoxicity reducing agent of the present invention, it is necessary to avoid phytotoxicity to crops caused by the herbicidal compound, for example, growth inhibition, appearance of brown spots, yellowing, withering, wilting and the like. Is possible.
Examples of the target crops include the crops exemplified in the phytotoxicity reducing agent.
第3に、本発明の薬害軽減剤または本発明の除草性組成物を用いた、作物に対する薬害軽減方法について説明する。 Thirdly, a method for reducing phytotoxicity on crops using the phytotoxicity reducing agent of the present invention or the herbicidal composition of the present invention will be described.
本発明においては、下記(B1)乃至(B4)からなる群より選択される施用方法により、作物に対する薬害を軽減することができる。
(B1)本発明の薬害軽減剤(以下、薬害軽減剤aと記載)と、薬害軽減剤aを含まない除草性組成物(以下、除草性組成物bと記載)とを混合して施用する方法、
(B2)薬害軽減剤aと、除草性組成物bとを、独立して同じ作物に施用する方法、
(B3)薬害軽減剤aと、本発明の除草性組成物(以下、除草性組成物cと記載)とを、独立して同じ作物に施用する方法、
(B4)除草性組成物cを施用する方法。In the present invention, phytotoxicity to crops can be reduced by an application method selected from the group consisting of the following (B1) to (B4).
(B1) The phytotoxicity reducing agent of the present invention (hereinafter referred to as phytotoxicity reducing agent a) and the herbicidal composition containing no phytotoxicity reducing agent a (hereinafter referred to as herbicidal composition b) are mixed and applied. Method,
(B2) A method in which the phytotoxicity reducing agent a and the herbicidal composition b are independently applied to the same crop.
(B3) A method in which the phytotoxicity reducing agent a and the herbicidal composition of the present invention (hereinafter referred to as herbicidal composition c) are independently applied to the same crop.
(B4) A method of applying the herbicidal composition c.
除草性組成物bとしては、薬害軽減剤を含まない以外は本発明の除草性組成物と同一のものを用いることができる。
本発明においては、薬害軽減剤aがヒドロキシイソキサゾール、ピカルブトラゾクス又はアミスルブロム若しくはその塩であり、除草性組成物bが上記(A2−1)及び(A3−1)からなる群より選択される、少なくとも1種類の除草性化合物又はそれらの塩であることが好ましい。As the herbicidal composition b, the same herbicidal composition as that of the present invention can be used except that it does not contain a phytotoxicity reducing agent.
In the present invention, the phytotoxicity reducing agent a is hydroxyisoxazole, picalbutrazox or amisulfrom or a salt thereof, and the herbicidal composition b is selected from the group consisting of the above (A2-1) and (A3-1). It is preferably at least one kind of herbicidal compound or a salt thereof.
本発明においては、前記(B1)乃至(B4)からなる群より選択される施用方法を、移植前の植物体に1回若しくは2回行うか、あるいは土壌及び/又は植物体の根若しくは地下茎に1回若しくは2回行うことができる。
前記(B2)の施用方法は、薬害軽減剤aを移植前の植物体に1回又は2回施用し、当該薬害軽減剤を含まない除草性組成物bを移植後の土壌及び/又は植物体に施用する方法であり、前記作物がイネであることが好ましい。In the present invention, the application method selected from the group consisting of (B1) to (B4) is applied once or twice to the plant before transplantation, or to the soil and / or the root or rhizome of the plant. It can be done once or twice.
In the application method of (B2), the phytotoxicity reducing agent a is applied to the plant before transplantation once or twice, and the herbicidal composition b containing no phytotoxicity reducing agent is applied to the soil and / or the plant after transplantation. It is a method to be applied to rice, and it is preferable that the crop is rice.
これらの施用方法においては、薬害軽減剤a、除草性組成物b又は除草性組成物cを、植物体及び/又は種子に処理するか、あるいは土壌への施用及び/又は植物体の根若しくは地下茎への処理を行う。以下に、前記(B1)乃至(B4)の施用方法を詳細に説明する。 In these application methods, the phytotoxicity reducing agent a, the herbicidal composition b or the herbicidal composition c is treated on a plant and / or seed, or applied to soil and / or the root or rhizome of the plant. To process. The application methods of the above (B1) to (B4) will be described in detail below.
前記(B1)乃至(B4)における、薬害軽減剤a、除草性組成物b又は除草性組成物cの施用方法としては、例えば、植物個体への茎葉散布処理、苗箱処理、水田土壌への処理、土壌表面への散布処理、土壌表面への散布処理後の土壌混和、土壌中への注入処理、土壌中での注入処理後の土壌混和、土壌潅注処理、土壌潅注処理後の土壌混和、植物種子への吹き付け処理、植物種子への塗沫処理、植物種子への浸漬処理、植物種子への粉衣処理、植物種子への散布処理等があげられるが、通常、当業者が利用するどの様な施用方法においても十分な効力を発揮する。 Examples of the method of applying the chemical damage reducing agent a, the herbicidal composition b or the herbicidal composition c in (B1) to (B4) include foliar spraying treatment on individual plants, seedling box treatment, and paddy soil. Treatment, spraying treatment on soil surface, soil mixing after spraying treatment on soil surface, injection treatment into soil, soil mixing after injection treatment in soil, soil irrigation treatment, soil mixing after soil irrigation treatment, Examples include spraying on plant seeds, smearing on plant seeds, dipping in plant seeds, powdering on plant seeds, spraying on plant seeds, etc., which are usually used by those skilled in the art. It is fully effective even in such application methods.
前記(B1)乃至(B4)の施用方法において、薬害軽減剤a、除草性組成物b又は除草性組成物cの施用量および施用濃度は、対象作物、対象病害、病害の発生程度、化合物の剤型、施用方法、各種環境条件等によって変動するが、散布又は潅注する場合には、有効成分量として、ヘクタール当たり50〜1,000,000gが適当であり、望ましくは、ヘクタール当り100〜500,000gである。また、種子処理の場合の使用量は、種子1kg当たり0.001から50g、好ましくは0.01から10gである。薬害軽減剤a、除草性組成物b又は除草性組成物cを、植物個体への茎葉散布処理、土壌表面への散布処理、土壌中への注入処理、土壌潅注処理する場合は、適当な担体に適当な濃度に希釈した後、処理を行っても良い。植物種子に接触させる場合は、適当な濃度に希釈した後、植物種子に浸漬、粉衣、吹き付け、散布、塗沫処理して用いても良い。粉衣・吹き付け・散布・塗沫処理する場合の製剤使用量は、通常、乾燥植物種子重量の0.05〜50%程度、さらに望ましくは0.1〜30%が適当であるが、このような使用量は、これら範囲に限定されるものではなく、製剤の形態や処理対象となる植物種子の種類により変わりうる。 In the application methods of (B1) to (B4), the application dose and application concentration of the phytotoxicity reducing agent a, the herbicidal composition b or the herbicidal composition c are the target crop, the target disease, the degree of occurrence of the disease, and the compound. Although it varies depending on the dosage form, application method, various environmental conditions, etc., when spraying or irrigating, the amount of active ingredient is appropriately 50 to 1,000,000 g per hectare, and preferably 100 to 500 per hectare. It is 000 g. The amount used in the seed treatment is 0.001 to 50 g, preferably 0.01 to 10 g per 1 kg of seeds. When the phytotoxicity reducing agent a, the herbicidal composition b or the herbicidal composition c is sprayed on individual plants, sprayed on the soil surface, injected into the soil, or irrigated with soil, an appropriate carrier is used. After diluting to an appropriate concentration, the treatment may be carried out. When it comes into contact with plant seeds, it may be diluted to an appropriate concentration and then immersed, powdered, sprayed, sprayed or smeared on the plant seeds. The amount of the preparation used for powder coating, spraying, spraying, and smearing is usually about 0.05 to 50%, more preferably 0.1 to 30% of the weight of dried plant seeds. The amount used is not limited to these ranges, and may vary depending on the form of the preparation and the type of plant seed to be treated.
薬害軽減剤a、除草性組成物b又は除草性組成物cは、単独で処理されてもよく、殺菌剤、殺虫剤、殺ダニ剤、殺線虫剤又は植調剤と組合せて、同時に若しくは順次処理されてもよい。 The phytotoxicity reducing agent a, the herbicidal composition b or the herbicidal composition c may be treated alone or in combination with a fungicide, an insecticide, an acaricide, a nematode or a planting agent, simultaneously or sequentially. May be processed.
組合せて処理される殺菌剤としては、例えば、フェニルアミド系殺菌剤、有糸核分裂および細胞分裂阻害剤、コハク酸脱水素酵素阻害剤(SDHI剤)、キノン外部阻害剤(QoI剤)、キノン内部阻害剤(QiI殺剤)、酸化的リン酸化脱共役阻害剤、キノン外部スチグマテリン結合サブサイト阻害剤(QoSI剤)、アミノ酸生合成阻害剤、タンパク質生合成阻害剤、シグナル伝達阻害剤、脂質および細胞膜生合成阻害剤、脱メチル化阻害剤(DMI剤)、アミン系殺菌剤、ステロール生合成のC4位脱メチル化における3−ケト還元酵素阻害剤、ステルール生合成のスクアレンエポキシダーゼ阻害剤、細胞壁生合成阻害剤、メラニン生合成阻害剤、宿主植物抵抗性誘導剤、ジチオカーバメート系殺菌剤、フタルイミド系殺菌剤、グアニジン系殺菌剤、多作用点接触活性型殺菌剤、その他の殺菌剤等を挙げることができる。組合せて処理される、殺虫剤、殺ダニ剤、殺線虫剤としては、例えば、カーバメート系アセチルコリンエステラーゼ(AChE)阻害剤、有機リン系アセチルコリンエステラーゼ(AChE)阻害剤、GABA作動性塩素イオンチャネルブロッカー、ナトリウムチャネルモジュレーター、ニコチン性アセチルコリン受容体(nAChR)競合的モジュレーター、ニコチン性アセチルコリン受容体(nAChR)アロステリックモジュレーター、グルタミン酸作動性塩素イオンチャネル(GluCl) アロステリックモジュレーター、幼若ホルモン類似剤、非特異的(マルチサイト)阻害剤、ダニ類成長阻害剤、ミトコンドリアATP合成酵素阻害剤、プロトン勾配を撹乱する酸化的リン酸化脱共役剤、ニコチン性アセチルコリン受容体(nAChR)チャネルブロッカー、キチン生合成阻害剤タイプ0、キチン生合成阻害剤タイプ1、ハエ目昆虫脱皮阻害剤、脱皮ホルモン(エクダイソン)受容体アゴニスト、ミトコンドリア電子伝達系複合体III阻害剤、ミトコンドリア電子伝達系複合体I阻害剤(METI)、電位依存性ナトリウムチャネルブロッカー、アセチルCoAカルボキシラーゼ阻害剤、ミトコンドリア電子伝達系複合体IV阻害剤、ミトコンドリア電子伝達系複合体II阻害剤、リアノジン受容体モジュレーター、弦音器官モジュレーター 標的部位未特定、その他の剤などを挙げることができ、1種又はそれ以上を組合せて使用することができるが、これらに限定されるものではない。 Examples of the bactericides to be treated in combination include phenylamide bactericides, filamentous nuclear division and cell division inhibitors, succinate dehydrogenase inhibitors (SDHI agents), quinone external inhibitors (QoI agents), and quinone internals. Inhibitors (QiI killing agents), oxidative phosphorylation deconjugation inhibitors, quinone external stigmaterin binding subsite inhibitors (QoSI agents), amino acid biosynthesis inhibitors, protein biosynthesis inhibitors, signaling inhibitors, lipids and cell membranes Biosynthesis inhibitor, demethylation inhibitor (DMI agent), amine-based bactericide, 3-ketoreductase inhibitor in C4 demethylation of sterol biosynthesis, squalene epoxidase inhibitor of sterol biosynthesis, cell wall growth Synthesis inhibitors, melanin biosynthesis inhibitors, host plant resistance inducers, dithiocarbamate bactericides, phthalimide bactericides, guanidine bactericides, multi-action point contact active bactericides, other bactericides, etc. Can be done. Examples of insecticidal agents, acaricides, and nematode repellents that are treated in combination include carbamate acetylcholineresterase (AChE) inhibitors, organic phosphorus acetylcholineresterase (AChE) inhibitors, and GABAergic chlorine ion channel blockers. , Sodium channel modulator, nicotinic acetylcholine receptor (nAChR) competitive modulator, nicotinic acetylcholine receptor (nAChR) allosteric modulator, glutamate-operated chlorine ion channel (GluCl) allosteric modulator, immature hormone inhibitor, non-specific ( Multisite) inhibitor, tick growth inhibitor, mitochondrial ATP synthase inhibitor, oxidative phosphorylation deconjugate that disrupts proton gradient, nicotinic acetylcholine receptor (nAChR) channel blocker, chitin biosynthesis inhibitor type 0 , Chitin biosynthesis inhibitor type 1, flies insect dehullation inhibitor, dehulling hormone (Ekdyson) receptor agonist, mitochondrial electron transfer system complex III inhibitor, mitochondrial electron transfer system complex I inhibitor (METI), potential dependence Sexual sodium channel blocker, acetyl CoA carboxylase inhibitor, mitochondrial electron transfer system complex IV inhibitor, mitochondrial electron transfer system complex II inhibitor, lianodine receptor modulator, chord organ modulator Target site unspecified, other agents, etc. It can be used alone or in combination of one or more, but is not limited thereto.
殺菌剤としては、例えば、ベナラキシル(benalaxyl)、ベナラキシルM又はキララキシル(benalaxyl−Mまたはkiralaxyl)、フララキシル(furalaxyl)、メタラキシル(metalaxyl)、メタラキシルMまたはメフェノキサム(metalaxyl−Mまたはmefenoxam)、オキサジキシル(oxadixyl)、オフラセ(ofurace)等のフェニルアミド系殺菌剤;
カルベンダジム(carbendazim)、フベリダゾール(fuberidazole)、チアベンダゾール(thiabendazole)、チオファネート(thiophanate)、ジエトフェンカルブ(diethofencarb)、ゾキサミド(zoxamide)、エタボキサム(ethaboxam)、ペンシクロン(pencycuron)、フルオピコリド(fluopicolide)、フェナマクリル(phenamacril)等の有糸核分裂および細胞分裂阻害剤;
ベノダニル(benodanil)、ベンゾビンジフルピル(benzovindiflupyr)、ビキサフェン(bixafen)、ボスカリド(boscalid)、カルボキシン(carboxin)、フェンフラム(fenfuram)、フルオピラム(fluopyram)、フルトラニル(flutolanil)、フルキサピロキサド(fluxapyroxad)、フラメトピル(furametpyr)、イソフェタミド(isofetamid)、イソピラザム(isopyrazam)、メプロニル(mepronil)、オキシカルボキシン(oxycarboxin)、ペンチオピラド(penthiopyrad)、ペンフルフェン(penflufen)、ピジフルメトフェン(pydiflumetofen)、セダキサン(sedaxane)、チフルザミド(thifluzamide)、ピラジフルミド(pyraziflumid)、イソフルシプラム(isoflucypram)、フルインダピル(fluindapyr)、インピルフルキサム(inpyrfluxam)、ピラプロポイン(pyrapropoyne)等のコハク酸脱水素酵素阻害剤(SDHI剤);
アゾキシストロビン(azoxystrobin)、クモキシストロビン(coumoxystrobin)、ジモキシストロビン(dimoxystrobin)、エノキサストロビン(enoxastrobin)、ファモキサドン(famoxadone)、フェンアミドン(fenamidone)、フェナミンストロビン(fenaminstrobin)、フルフェノキシストロビン(flufenoxystrobin)、フルオキサストロビン(fluoxastrobin)、クレソキシムメチル(kresoxim−methyl)、マンデストロビン(mandestrobin)、メトミノストロビン(metominostrobin)、オリサストロビン(orysastrobin)、ピコキシストロビン(picoxystrobin)、ピラクロストロビン(pyraclostrobin)、ピラメトストロビン(pyrametostrobin)、ピラオキシストロビン(pyraoxystrobin)、ピリベンカルブ(pyribencarb)、トリクロピリカルブ(triclopyricarb)、トリフロキシストロビン(trifloxystrobin)、メチルテトラプロール(metyltetraprol)等のキノン外部阻害剤(QoI剤):
ビナパクリル(binapacryl)、メプチルジノカップ(meptyldinocap)、ジノカップ(dinocap)、フルアジナム(fluazinam)等の酸化的リン酸化脱共役阻害剤;
アメトクトラジン(ametoctradin)等のキノン外部スチグマテリン結合サブサイト阻害剤(QoSI剤);
シプロジニル(cyprodinil)、メパニピリム(mepanipyrim)、ピリメタニル(pyrimethanil)等のアミノ酸生合成阻害剤;
ストレプトマイシン(streptomycin)、ブラストサイジンS(blasticidin−S)、オキシテトラサイクリン(oxytetracycline)等のタンパク質生合成阻害剤;
フェンピクロニル(fenpiclonil)、フルジオキソニル(fludioxonil)、キノキシフェン(quinoxyfen)、プロキナジド(proquinazid)、クロゾリネート(chlozolinate)、ジメタクロン(dimethachlone)、イプロジオン(iprodione)、プロシミドン(procymidone)、ビンクロゾリン(vinclozolin)等のシグナル伝達阻害剤;
エジフェンホス(edifenphos)、イプロベンホス(iprobenfos)、ピラゾホス(pyrazophos)、ビフェニル(biphenyl)、
クロロネブ(chloroneb)、ジクロラン(dicloran)、キントゼン(quintozene)、テクナゼン(tecnazene)、トルクロホスメチル(tolclofos−methyl)、エトリジアゾール(echlomezol or etridiazole)、ヨードカルブ(iodocarb)、プロパモカルブ(propamocarb)、プロチオカルブ(prothiocarb)等の脂質および細胞膜生合成阻害剤;
アザコナゾール(azaconazole)、ビテルタノール(bitertanol)、ブロムコナゾール(bromuconazole)、シプロコナゾール(cyproconazole)、ジフェノコナゾール(difenoconazole)、ジニコナゾール(diniconazole)、ジニコナゾールM(diniconazole−M)、[b−12.8]エポキシコナゾール(epoxiconazole)、エタコナゾール(etaconazole)、フェナリモル(fenarimol)、フェンブコナゾール(fenbuconazole)、フルキンコナゾール(fluquinconazole)、キンコナゾール(quinconazole)、フルシラゾール(flusilazole)、フルトリアホール(flutriafol)、ヘキサコナゾール(hexaconazole)、イマザリル(imazalil)、イミベンコナゾール(imibenconazole)、イプコナゾール(ipconazole)、メトコナゾール(metconazole)、ミクロブタニル(myclobutanil)、ヌアリモール(nuarimol)、オキスポコナゾール(oxpoconazole)、オキスポコナゾールフマル酸塩(oxpoconazole fumarate)、ペフラゾエート(pefurazoate)、ペンコナゾール(penconazole)、プロクロラズ(prochloraz)、プロピコナゾール(propiconazole)、プロチオコナゾール(prothioconazole)、ピリフェノックス(pyrifenox)、ピリソキサゾール(pyrisoxazole)、シメコナゾール(simeconazole)、テブコナゾール(tebuconazole)、テトラコナゾール(tetraconazole)、トリアジメホン(triadimefon)、トリアジメノール(triadimenol)、トリフルミゾール(triflumizole)、トリホリン(triforine)、トリチコナゾール(triticonazole)、メフェントリフルコナゾール(mefentrifluconazole)、イプフェントリフルコナゾール(ipfentrifluconazole)等の脱メチル化阻害剤(DMI剤);
アルジモルフ(aldimorph)、ドデモルフ(dodemorph)、フェンプロピモルフ(fenpropimorph)、トリデモルフ(tridemorph)、フェンプロピジン(fenpropidin)、ピペラリン(piperalin)、スピロキサミン(spiroxamine)等のアミン系殺菌剤;
フェンヘキサミド(fenhexamid)、フェンピラザミン(fenpyrazamine)等のステロール生合成のC4位脱メチル化における3−ケト還元酵素阻害剤;
ピリブチカルブ(pyributicarb)、[b−15.2]ナフチフィン(naftifine)、[b−15.3]テルビナフィン(terbinafine)等のステルール生合成のスクアレンエポキシダーゼ阻害剤;
ポリオキシン類(polyoxins)、ジメトモルフ(dimethomorph)、フルモルフ(flumorph)、ピリモルフ(pyrimorph)、ベンチアバリカルブ(benthiavalicarb)、ベンチアバリカルブイソプロピル(benthivalicarb−isopropyl)、イプロバリカルブ(iprovalicarb)、マンジプロパミド(mandipropamid)、バリフェナレート(valifenalate)等の細胞壁生合成阻害剤;
フサライド(phthalide or fthalide)、ピロキロン(pyroquilone)、トリシクラゾール(tricyclazole)、カルプロパミド(carpropamid)、ジクロシメット(diclocymet)、フェノキサニル(fenoxanil)、トルプロカルブ(tolprocarb)等のメラニン生合成阻害剤;
アシベンゾラルSメチル(acibenzolar−S−methyl)、プロベナゾール(probenazole)、チアジニル(tiadinil)、イソチアニル(isotianil)、ラミナリン(laminarin)、ジクロベンチアゾクス(dichlobentiazox)等の宿主植物抵抗性誘導剤;
マンコゼブ、マンゼブ(mancozeb or manzeb)、マンネブ(maneb)、メチラム(metiram)、プロピネブ(propineb)、チウラム(thiram)、ジネブ(zineb)、ジラム(ziram)、フェルバム(ferbam)等のジチオカーバメート系殺菌剤;
キャプタン(captan)、キャプタホール(captafol)、ホルペット(folpet)、フルオロホルペット(fluorofolpet)等;
フタルイミド系殺菌剤:
グアザチン(guazatine)、イミノクタジン(iminoctadine)、イミノクタジンアルベシル酸塩(iminoctadine albesilate)、イミノクタジン三酢酸塩(iminoctadine triacetate)等のグアニジン系殺菌剤;
塩基性塩化銅(copper oxychloride)、水酸化第二銅(copper(II) hydroxide)、塩基性硫酸銅(copper hydroxide sulfate)、有機銅化合物(organocopper compound)、ドデシルベンゼンスルホン酸ビスエチレンジアミン銅錯塩[II](Dodecylbenzenesulphonic acid bisethylenediamine copper [II] salt、DBEDC)、硫黄(sulphur)、フルオルイミド(fluoroimide)、ジクロフルアニド(dichlofluanid)、トリルフルアニド(tolylfluanid)、アニラジン(anilazine)、ジチアノン(dithianon)、キノメチオナート(chinomethionat or quinomethionate)、ハウチワマメ苗木の子葉からの抽出物(BLAD)等の多作用点接触活性型殺菌剤;
ジクロベンチアゾクス(dichlobentiazox)、フェンピコキサミド(fenpicoxamid)、ジピメチトロン(dipymetitrone)、ブピリメート(bupirimate)、ジメチリモール(dimethirimol)、エチリモール(ethirimol)、酢酸トリフェニルスズ(fentin acetate)、塩化トリフェニルスズ(fentin chloride)、水酸化トリフェニルスズ(fentin hydroxide)、オキソリニック酸(oxolinic acid)、ヒメキサゾール(hymexazol)、オクチリノン(octhilinone)、ホセチル(fosetyl)、亜リン酸(phosphorous acid)、亜リン酸のナトリウム塩(sodium phosphite)、亜リン酸のアンモニウム塩(ammonium phosphite)、亜リン酸のカリウム塩(potassium phosphite)、テクロフタラム(tecloftalam)、トリアゾキシド(triazoxide)、フルスルファミド(flusulfamide)、ジクロメジン(diclomezine)、シルチオファム(silthiofam)、ジフルメトリム(diflumetorim)、メタスルホカルブ(methasulfocarb)、シフルフェナミド(cyflufenamid)、メトラフェノン(metrafenone)、ピリオフェノン(pyriofenone)、ドジン(dodine)、[フルチアニル(flutianil)、フェリムゾン(ferimzone)、オキサチアピプロリン(oxathiapiprolin)、テブフロキン(tebufloquin)、バリダマイシン類(validamycins)、シモキサニル(cymoxanil)、キノフメリン(Quinofumelin)、フェンピコキサミド(fenpicoxamid)、アミノピリフェン(aminopyrifen)、ピリダクロメチル(pyridachlometyl)、イプフルフェノキン(ipflufenoquin)、フルオピモミド(fluopimomide)、フロリルピコキサミド(florylpicoxamid)等のその他の殺菌剤が挙げられる。Examples of the bactericidal agent include benalaxyl, benalaxyl M or kiraluxyl (benalaxyl-M or kilaraxyl), furalaxyl, metalalaxyl, metalaxyl, metalaxyl M or mephenoxyl, metalaxyl M or mephenoxyl, and mephenoxyl. , Phenylamide bactericides such as ofrace;
Carbendazim (carbendazim), fuberidazole (fuberidazole), thiabendazole (thiabendazole), thiophanate (thiophanate), diethofencarb (diethofencarb), zoxamide (zoxamide), ethaboxam (ethaboxam), pencycuron (pencycuron), fluopicolide (fluopicolide), Fenamakuriru (phenamacril) Mitotic and cell division inhibitors such as;
Benodanil, benzobindiflupyr, bixafen, boscalid, carboxin, fenfluam, fluopylaflulux, fluopyram, fluopyram, fluopyram ), Flametpyr, isofetamide, isopyrazam, mepronil, oxycarboxin, penthiopyrado, penthiopyrado, penfludefeneflenefeneflenfeneflenfene ), Thifluzamide, pyraziflumid, isoflucyplam, fluindapyr, impylfluxam, impyrfluxam, pyrapropoin (pyrapropoin) dehydrogenase, pyrapropoin (pyrapropoin)
Azoxystrobin, spidermethylstrobin, dimoxystrobin, enoxastrobin, famoxadenone, phenamiden, phenamidenne, phenamidenne Phenoxystrobin, fluoxastrobin, cresoxim-methyl, mandestrobin, metominostrovin, metominostrovin, orysastrobin, orystrobin, orysastrobin Crostrobin, pyrametostrobin, pyraoxystrobin, pyribencarb, triclopyricarb, trichloropyricarb, trifluoropyricarb, trifloxystrobin, trifluorytricarb, trifloxystrobin, trifloxystrobin External inhibitor (QoI agent):
Oxidative phosphorylation uncoupling inhibitors such as binapacryl, meptyldinocap, dinocap, fluazinam;
Quinone external stigmaterin-binding subsite inhibitor (QoSI agent) such as amethoctradin;
Amino acid biosynthesis inhibitors such as cyprodinil, mepanipyrim, pyrimethanil;
Protein biosynthesis inhibitors such as streptomycin, blastidin-S, oxytetracycline;
Fenpiclonil, fludioxonil, quinoxyphen, proquinazid, chromozolinate, dimethaclone, dimethaclone, dimethaclone, dimethaclone, dimethaclone, iprodion, iprodion, iprodion ;
Edifenphos, iprobenphos, pyrazophos, biphenyl,
Chloroneb, dichloran, quintozene, technazene, tolclofos-methyl, etridiazol (echlomezol or eridiabolo) provocal Lipids and cell membrane biosynthesis inhibitors;
Azaconazole, bitertanol, bromuconazole, cyproconazole, diphenoconazole, diphenoconazole, diphenoconazol, diphonazole8, diniconazole, diniconazole, diniconazole Epoxyconazole, etaconazole, fenarimol, fenbuconazole, fluquinconazole, quinconazole, quinconazole, quinconazole, quinconazole, quinconazole, quinconazole, quinconazole, fluconazole, fluconazole, fluconazole, fluconazole, fluconazole, fluconazole, fluconazole Nazol (hexaconazole), imazalil, imibenconazole, ipconazole, metconazole, microbutanil, microbutanil, microbutanil, nuarimol Oxpoconazole fumarate, pefurazoate, penconazole, prochloraz, propiconazole, propiconazole, prothioconazole, prothioconazole (prothioconazole) simeconazole, tebuconazole, tetraconazole, triadimephon, triadimenol, triflumizole, triflumizole, trifolylconazole, trifolylconazole, trifolylconazole, trifolia Demethylation inhibitors (DMI agents) such as (mefentrifluconazole), ipfentrifluconazole (ipfentrifluconazole);
Aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, piperalin, spiroxamine, etc.
3-keto reductase inhibitor in C4 demethylation of sterol biosynthesis such as fenhexamide, fenpyrazamine;
Squalene biosynthetic squalene epoxidase inhibitors such as pyribticarb, [b-15.2] naftifine, [b-15.3] terbinafine;
Polyoxins, dimethomorph, flumorph, pyrimorph, benchavaricarb, benchavaricarb isopropyl (benthivalicab-isopropanol), isopropyl alcohol, propanol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol, isopropyl alcohol. Cell wall biosynthesis inhibitors such as valifenate;
Phthalide or phthalide, pyroquilone, tricyclazole, carpropamide, diclocymet, phenoxanil, phenoxanil, phenoxanil, tolprocanyl, etc.
Host plant resistance inducers such as acibenzolar S-methyl, probenazole, tiadinil, isotianil, laminarin, dichlobentiazox, etc.
Mancozeb, manzeb or manzeb, maneb, methilam, propineb, thiram, zineb, zineb, ziram, ferbam, ferbam ;
Captan, captafol, folpet, fluorofolpet, etc .;
Phthalimide fungicide:
Guanidine-based fungicides such as guazatin, iminoctazine, iminoctadine albesilate, iminoctadine triacetate;
Basic copper chloride (copper oxide), cupper (II) hydride, basic copper sulfate (copper hydride sulfate), organic copper compound (organocopper compound), dodecylbenzene sulfonate bisethylenediamine complex ] (Dodecylbene sulphonic acid bisethylene copper [II] salt, DBEDC), sulfur (sulfur), fluoroidide, dichlofluandi, dichlofluandi, dichlofluandi, trilfluanide Multi-acting point contact active bactericides such as copper), extracts from leaflets of Hachiwamame seedlings (BLAD);
Dichlobentiazox, fenpicoxamide, dipymetritrone, bupilimate, dimethilimol, dimethilimol, ethilimol, fentin acetate, triphenyltin acetate fentin chloride, triphenyltin hydroxide (fentin hydroxide), oxolinic acid, humexazol, octylinone, Josetyl, phosphorous acid, phosphorous acid, phosphorous acid, phosphorous acid, phosphorous acid. (Sodium phophite), ammonium salt of phosphorous acid (ammonium phophite), potassium salt of phosphorous acid (potassium phophite), tecloftalam, triazoxide (triazoxide), flusulfamide, flusulfamide, fentin ), Diflumetrim, metasulfocarb, cyflufenamide, metrafenone, pyriophenone, pyriophenone, dozin, dozine, phodine, fluorifene, fluorifene oxasiapipurolin, tebufloquin, validamycins, cymoxanil, quinofumulin, fenpicoxymid, fempicoxamide, aminopyridamine, aminopyridamine Other bactericidal agents such as (ipflufenoquin), fluopimomide, flolylpicoxamide and the like.
殺虫剤としては、ホスホカルブ(phosphocarb)、アラニカルブ(alanycarb)、ブトカルボキシム(butocarboxim)、ブトキシカルボキシム(butoxycarboxim)、チオジカルブ(thiodicarb)、チオファノックス(thiofanox)、アルジカルブ(aldicarb)、ベンジオカルブ(bendiocarb)、ベンフラカルブ(benfuracarb)、カルバリル(carbaryl)、カルボフラン(carbofuran)、カルボスルファン(carbosulfan)、エチオフェンカルブ(ethiofencarb)、フェノブカルブ(fenobucarb)、ホルメタネート(formetanate)、フラチオカルブ(furathiocarb)、イソプロカルブ(isoprocarb)、メチオカルブ(methiocarb)、メソミル(methomyl)、オキサミル(oxamyl)、ピリミカーブ(pirimicarb)、プロポキスル(propoxur)、トリメタカルブ(trimethacarb)、XMC(3,5−xylyl methylcarbamate)、アリキシカルブ(allyxycarb)、アルドキシカルブ(aldoxycarb)、ブフェンカルブ(bufencarb)、ブタカルブ(butacarb)、カーバノレート(carbanolate)、メトルカルブ(metolcarb)、キシルイルカルブ(xylylcarb)、フェノチオカルブ(fenothiocarb)、キシリルカルブ(xylylcarb)、ベンダイオカルブ(bendiocarb)等のカーバメート系アセチルコリンエステラーゼ(AChE)阻害剤;
アセフェート(acephate)、アザメチホス(azamethiphos)、アジンホス−メチル(azinphos−methyl)、アジンホス−エチル(azinphos−ethyl)、エセフォン(ethephon)、カズサホス(cadusafos)、クロルエトキシホス(chlorethoxyfos)、クロルフェンビンホス(chlorfenvinphos)、クロルメホス(chlormephos)、クロルピリホス(chlorpyrifos)、クロルピリホス−メチル(chlorpyrifos−methyl)、クマホス(coumaphos)、シアノホス(cyanophos)、デメトン−S−メチル(demeton−S−methyl)、ダイアジノン(diazinon)、ジクロフェンチオン(dichlofenthion)、ジクロルボス(dichlorvos)、ジクロトホス(dicrotophos)、ジメトエート(dimethoate)、ジメチルビンホス(dimethylvinphos)、ジスルホトン(disulfoton)、O−エチル O−4−ニトロフェニル フェニルホスホノチオアート(O−ethyl O−4−nitrophenyl phenylphosphonothioate)、エチオン(ethion)、エトプロホス(ethoprophos)、ファムフール(famphur)、フェナミホス(fenamiphos)、フェニトロチオン(fenitrothion)、フェンチオン(fenthion)、ホスチアゼート(fosthiazate)、ヘプテノホス(heptenophos)、イソフェンホス−メチル(isofenphos−methyl)、イソカルボホス(Isocarbophos)、イソキサチオン(isoxathion)、マラチオン(malathion)、メカルバム(mecarbam)、メタミドホス(methamidophos)、メチダチオン(methidathion)、メビンホス(mevinphos)、モノクロトホス(monocrotophos)、ナレッド(naled)、オメトエート(omethoate)、オキシデメトン−メチル(oxydemeton−methyl)、パラチオン(parathions)、パラチオン−メチル(parathion−methyl)、フェントエート(phenthoate)、ホレート(phorate)、ホサロン(phosalone)、ホスメット(phosmet)、ホスファミドン(phosphamidon)、ホキシム(phoxim)、ピリミホス−メチル(pirimiphos−methyl)、プロフェノホス(profenofos)、プロペタンホス(propetamphos)、プロチオホス(prothiofos)、ピラクロホス(pyraclofos)、ピリダフェンチオン(pyridaphenthion)、キナルホス(quinalphos)、スルホテップ(sulfotep)、テブピリムホス(tebupirimfos)、テメホス(temephos)、テルブホス(terbufos)、チオメトン(thiometon)、トリアゾホス(triazophos)、トリクロルホン(trichlorfon)、バミドチオン(vamidothion)、クロルチオン(chlorothion)、ブロムフェンビンホス(bromfenvinfos)、ブロモホス(bromophos)、ブロモホス−エチル(bromophos−ethyl)、ブタチオホス(butathiofos)、カルボフェノチオン(carbophenothion)、クロルホキシム(chlorphoxim)、スルプロホス(sulprofos)、ジアミダホス(diamidafos)、テトラクロルビンホス(tetrachlorvinphos)、プロパホス(propaphos)、メスルフェンホス(mesulfenfos)、ジオキサベンゾホス(dioxabenzofos)、エトリムホス(etrimfos)、オキシデプロホス(oxydeprofos)、ホルモチオン(formothion)、フェンスルホチオン(fensulfothion)、イサゾホス(isazofos)、イミシアホス(imicyafos)、イサミドホス(isamidofos)、チオナジン(thionazin)、ホスチエタン(fosthietan)等の有機リン系アセチルコリンエステラーゼ(AChE)阻害剤;
クロルデン(chlordane)、エンドスルファン(endosulfan)、リンデン(lindane)、ジエノクロル(dienochlor)、エチプロール(ethiprole)、フィプロニル(fipronil)、[アセトプロール(acetoprole)等のGABA作動性塩素イオンチャネルブロッカー;
アクリナトリン(acrinathrin)、アレスリン[(1R)−アイソマー](allethrin[(1R)−isomer])、ビフェントリン(bifenthrin)、ビオアレスリン(bioallethrin)、ビオアレスリン S−シクロペンテニル アイソマー(bioallethrin S−cyclopentenyl isomer)、ビオレスメトリン(bioresmethrin)、シクロプロトリン(cycloprothrin)、シフルトリン(cyfluthrin)、ベータ−シフルトリン(beta−cyfluthrin)、シハロトリン(cyhalothrin)、ガンマ−シハロトリン(gamma−cyhalothrin)、ラムダ−シハロトリン(lambda−cyhalothrin)、シペルメトリン(cypermethrin)、アルファ−シペルメトリン(alpha−cypermethrin)、ベータ−シペルメトリン(beta−cypermethrin)、セタ−シペルメトリン(theta−cypermethrin)、ゼダ−シペルメトリン(zeta−cypermethrin)、シフェノトリン[(1R)−トランス−アイソマー](cyphenothrin[(1R)−trans−isomer])、デルタメトリン(deltamethrin)、エンペントリン[(EZ)−(1R)−アイソマー](empenthrin[(EZ)−(1R)−isomer])、エスフェンバレレート(esfenvalerate)、エトフェンプロックス(ethofenprox)、フェンプロパトリン(fenpropathrin)、フェンバレレート(fenvalerate)、フルシトリネート(flucythrinate)、フルメトリン(flumethrin)、タウ−フルバリネート(tau−fluvalinate)、ハルフェンプロックス(halfenprox)、イミプロトリン(imiprothrin)、メトトリン(methothrin)、メトフルトリン(metofluthrin)、イプシロン−メトフルトリン(epsilon−metofluthrin)、モンフルオロトリン(momfluorothrin)、イプシロン−モンフルオロトリン(epsilon−momfluorothrin)、ペルメトリン(permethrin)、フェノトリン[(1R)−トランス−アイソマー](phenothrin[(1R)−trans−isomer])、プラレトリン(prallethrin)、レスメトリン(resmethrin)、カデトリン(kadethrin)、シラフルオフェン(silafluofen)、テフルトリン(tefluthrin)、テトラメトリン(tetramethrin)、テトラメトリン[(1R)−アイソマー](tetramethrin[(1R)−isomer])、トラロメトリン(tralomethrin)、トランスフルトリン(transfluthrin)、ZXI8901(3−(4−bromophenoxy)phenyl]−cyanomethyl 4−(difluoromethoxy)−α−(1−methylethyl)benzeneacetate)、バイオペルメトリン(biopermethrin)、フラメトリン(furamethrin)、プロフルトリン(profluthrin)、フルブロシトリネート(flubrocythrinate)、ジメフルトリン(dimefluthrin)、DDT(dichloro−diphenyl−trichloroethane)、メトキシクロル(methoxychlor)、フェノトリン(phenothrin)、フルバリネート(fluvalinate)等のナトリウムチャネルモジュレーター;
アセタミプリド(acetamiprid)、クロチアニジン(clothianidin)、ジノテフラン(dinotefuran)、イミダクロプリド(imidacloprid)、ニテンピラム(nitenpyram)、チアクロプリド(thiacloprid)、チアメトキサム(thiamethoxam)、ニコチン(nicotine)、硫酸ニコチン(nicotine sulfate)、スルホキサフロル(sulfoxaflor)、フルピラジフロン(flupyradifurone)、トリフルメゾピリム(triflumezopyrim)等のニコチン性アセチルコリン受容体(nAChR)競合的モジュレーター;
スピノサド(spinosad)、スピネトラム(spinetoram)等のニコチン性アセチルコリン受容体(nAChR)アロステリックモジュレーター;
アバメクチン(abamectin)、エマメクチン安息香酸塩(emamectin benzoate)、レピメクチン(lepimectin)、ミルベメクチン(milbemectin)等のグルタミン酸作動性塩素イオンチャネル(GluCl) アロステリックモジュレーター;
ヒドロプレン(hydroprene)、キノプレン(kinoprene)、メトプレン(methoprene)、フェノキシカルブ(fenoxycarb)、ピリプロキシフェン(pyriproxyfen)等の幼若ホルモン類似剤;
臭化メチル(methyl bromide)、クロルピクリン(chloropicrin)、クリオライト(cryolite)、フッ化スルフリル(sulfuryl fluoride)、ホウ砂(borax)、ホウ酸(boric acid)、オクタホウ酸ニナトリウム塩(disodium octaborate)、メタホウ酸ナトリウム塩(sodium metaborate)吐酒石(tartar emetic)、ダゾメット(dazomet)、メタム(metam)、カーバムナトリウム塩(metham sodium)等の非特異的(マルチサイト)阻害剤;
ピメトロジン(pymetrozine)、ピリフルキナゾン(pyrifluquinazon)等の弦音器官TRPVチャネルモジュレーター;
クロフェンテジン(clofentezine)、ジフロビダジン(diflovidazin)、ヘキシチアゾクス(hexythiazox)、エトキサゾール(etoxazole)等のダニ類成長阻害剤;
ジアフェンチウロン(diafenthiuron)、アゾシクロチン(azocyclotin)、シヘキサチン(cyhexatin)、フェンブタチンオキシド(fenbutatin oxide)、プロパルギット(propargite)、テトラジホン(tetradifon)等のミトコンドリアATP合成酵素阻害剤;
クロルフェナピル(chlorfenapyl)、DNOC(dinitro−ortho−cresol)、ビナパクリル(binapacryl)、スルフルラミド(sulfluramid)等のプロトン勾配を撹乱する酸化的リン酸化脱共役剤;
ベンスルタップ(bensultap)、カルタップ塩酸塩(cartap hydrochloride)、チオシクラム(thiocyclam)、モノスルタップ(monosultap)等のニコチン性アセチルコリン受容体(nAChR)チャネルブロッカー;
ビストリフルロン(bistrifluron)、クロルフルアズロン(chlorfluazuron)、ジフルベンズロン(diflubenzuron)、フルシクロクスロン(flucycloxuron)、フルフェノクスロン(flufenoxuron)、ヘキサフルムロン(hexaflumuron)、ルフェヌロン(lufenuron)、ノバルロン(novaluron)、ノビフルムロン(noviflumuron)、テフルベンズロン(teflubenzuron)、トリフルムロン(triflumuron)等のキチン生合成阻害剤タイプ0;
ブプロフェジン(buprofezin)等のキチン生合成阻害剤タイプ1;
シロマジン(cyromazine)等のハエ目昆虫脱皮阻害剤;
クロマフェノジド(chromafenozide)、ハロフェノジド(halofenozide)、メトキシフェノジド(methoxyfenozide)、テブフェノジド(tebufenozide)等の脱皮ホルモン(エクダイソン)受容体アゴニスト;
アミトラズ(amitraz)等のオクトパミン受容体アゴニスト;
ヒドラメチルノン(hydramethylnon)、アセキノシル(acequinocyl)、フルアクリピリム(fluacrypyrim)、ビフェナゼート(bifenazate)等のミトコンドリア電子伝達系複合体III阻害剤;
フェナザキン(fenazaquin)、フェンピロキシメート(fenpyroximate)、ピリダベン(pyridaben)、ピリミジフェン(pylimidifen)、テブフェンピラド(tebufenpyrad)、トルフェンピラド(tolfenpyrad)、ロテノン(rotenone)等のミトコンドリア電子伝達系複合体I阻害剤(METI);
インドキサカルブ(indoxacarb)、メタフルミゾン(metaflumizone)等の電位依存性ナトリウムチャネルブロッカー;
スピロジクロフェン(spirodiclofen)、スピロメシフェン(spiromesifen)、スピロテトラマト(spirotetramat)等のアセチルCoAカルボキシラーゼ阻害剤;
リン化アルミニウム(aluminum phosphide)、リン化カルシウム(calcium phosphide)、リン化水素(phosphine)、リン化亜鉛(zinc phosphide)、シアン化カルシウム(calcium cyanide)、シアン化ナトリウム(potassium cyanide)、シアン化カリウム(sodium cyanide)等のミトコンドリア電子伝達系複合体IV阻害剤;
シエノピラフェン(cyenopyrafen)、シフルメトフェン(cyflumetofen)、ピフルブミド(pyflubumide)等のミトコンドリア電子伝達系複合体II阻害剤;
クロラントラニリプロール(chlorantraniliprole)、[cシアントラニリプロール(cyantraniliprole)、フルベンジアミド(flubendiamide)等のリアノジン受容体モジュレーター;
フロニカミド(flonicamid)等の弦音器官モジュレーター 標的部位未特定;
アザジラクチン(azadirachtin)、ベンゾキシメート(benzoximate)、フェニソブロモレート(phenisobromolate)、キノメチオナート(chinomethionat)、ジコホル(dicofol)、ピリダリル(pyridalyl)、ブロモプロピレート(bromopropylate)、トリアザメート(triazamate)、ジシクラニル(dicyclanil)、ジノブトン(dinobuton)、ジノカップ(dinocap)、シアン化水素(hydrogen cyanide)、ヨウ化メチル(methyl iodide)、カランジン(karanjin)、]塩化水銀(mercury chloride)、メチルイソチオシアネート(methyl isothiocyanate)、ペンタクロロフェノール(pentachlorophenol)、ホスフィン(phosphine)、ピペロニル ブトキシド(piperonyl butoxide)、ポリナクチン複合体(polynactins)、サバディラ(sabadilla)、スルコフロン塩(スルコフロン−ナトリウム(sulcofuron−sodium))、トリブホス(tribufos)、アルドリン(aldrin)、アミジチオオン(amidithion)、アミドチオエート(amidothioate)、アミノカルブ(aminocarb)、アミトン(amiton)、アラマイト(aramite)、]アチダチオン(athidathion)、アゾトエート(azothoate)、ポリスルフィドバリウム(barium polysulphide)、ベンクロチアズ(benclothiaz)、5−(1,3−ベンゾジオキソール−5−イル)−3−ヘキシルシクロヘキサ−2−エノン(5−(1,3−benzodioxole−5−yl)−3−hexylcyclohexa−2−enone)、1,1−ビス(4−クロロフェニル)−2−エトキシエタノール(1,1−bis(4−chlorophenyl)−2−ethoxyethanol)、ブトネート(butonate)、ブトピロノキシル(butopyronoxyl)、2−(2−ブトキシエトキシ)エチル チオシアナート(2−(2−butoxyethoxy)ethyl thiocyanate)、カンフェクロル(camphechlor)、クロルベンシド(chlorbenside)、クロルデコン(chlordecone)、クロルジメホルム(chlordimeform)、クロルフェネトール(chlorfenethol)、クロルフェンソン(chlorfenson)、フルアズロン(fluazuron)、メタアルデヒド(metaldehyde)、ビアラホス(bialaphos)、塩酸レバミゾール(levamisol)、アミドフルメト(amidoflumet)、ピラフルプロール(pyrafluprole)、ピリプロール(pyriprole)、トラロピリル(tralopyril)、フルピラゾフォス(flupyrazofos)、ジオフェノラン(diofenolan)、クロルベンジレート(chlorobenzilate)、フルフェンジン(flufenzine)、ベンゾメート(benzomate)、フルフェネリム(flufenerim)、アルベンダゾール(albendazole)、オキシベンダゾール(oxibendazole)、フェンベンダゾール(fenbendazole)、メタム・ナトリウム(metam−sodium)、1,3−ジクロロプロペン(1,3−dichloropropene)、フロメトキン(flometoquin)、シクラニリプロール(cyclaniliprole)、テトラニリプロール(tetraniliprole)、ブロフラニリド(broflanilide)、ジクロロメゾチアズ(dicloromezotiaz)、エチレンジブロマイド(ethylene dibromide)、アクリロニトリル(acrylonitrile)、ビス(2−クロロエチル)エーテル(bis(2−chloroethyl)ether)、1−ブロモ−2−クロロエタン(1−bromo−2−chloroethane)、3−ブロモ−1−クロロプロパ−1−エン(3−bromo−1−chloroprop−1−ene)、ブロモシクレン(bromocyclen)、二硫化炭素(carbon disulfide)、四塩化炭素(tetrachloromethane)、ネマデクチン(nemadectin)、シミアゾール(cymiazole)カルシウム ポリスルフィド(calcium polysulfide)、サイトカイニン(cytokinin)、2−(オクチルチオ)エタノール、オレイン酸カリウム(potassium oleate)、オレイン酸ナトリウム(sodium oleate)、マシン油(machine oil)、]タール油(tar oil)、アナバシン(anabasine)、酒石酸モランテル(morantel tartrate)、除虫菊(ピレトリン(pyrethrum))、ナタネ油(rape seed oil)、ダイズレチシン(soybean lecithin)、デンプン(starch)、ヒドロキシプロピルデンプン(hydroxypropylstarch)、脂肪酸グリセリド(decanoyloctanoylglycerol)、プロピレングリコールモノ脂肪酸エステル(propylene glycol fatty acid ester)、ケイソウ土(diatomite)。アフォキソラネル(afoxolaner)、フルアザインドリジン(fluazaindolizine)、アフィドピロペン(afidopyropen)、シハロジアミド(cyhalodiamide)、チオキサザフェン(tioxazafen)、フルヘキサフォン(fluhexafon)、フルララネル(fluralaner)、フルキサメタミド(fluxametamide)、テトラクロラントラニリプロール(tetrachlorantraniliprole)、サロラネル(sarolaner)、ロチラネル(lotilaner)、シクロキサプリド(cycloxaprid)、フルエンスルホン(fluensulfone)、TPIC(tripropyl isocyanurate)、D−D(1,3−Dichloropropene)、ペルオキソカルボナート(peroxocarbonate)、MB−599(verbutin)、ビス(2,3,3,3−テトラクロロプロピル)エーテル(bis(2,3,3,3−tetrachloropropyl) ether)、DCIP(bis(2−chloro−1−methylethyl)ether)、ENT−8184(N−(2−Ethylhexyl)bicyclohept−5−ene−2,3−dicarboximide)、Bayer 22408(O,O−diethyl O−naphthalimido phosphorothioate)、Bayer 32394(tris(1−dodecyl−3−methyl−2−phenylbenzimidazolium)hexacyanoferrate)、ベンズピリモキサン(benzpyrimoxan)、アシノナピル(acynonapyr)、フルピリミン(flupyrimin)、チクロピラゾフロール(tyclopyrazoflor)、オキサゾスルフィル(oxazosulfyl)、スピロピジオン(spiropidion)等のその他の剤が挙げられる。Insecticides include phosphocarb, alanycarb, butocarboxim, butoxycarboxim, thiodiccarb, thiophanocarb, thiofanox (thiofanox). , Benfuracarb, carbaryl, carbofuran, carbosulfan, ethiophencarb, fenobucarb, fenobucarb, formetanate, formetanate, formetanate, fenobucarb, fenobucarb, carbaryl, carbofuran, carbosulfan metiocarb), mesomil, oxamyl, pyrimicarb, propoxur, trimetacarb, XMC (3,5-xylyl methylcarbalcarba), alicarbalb. Bufencarb, butacarb, carbanolate, metolcarb, xylylcarb, phenothiocarb, phenothiocarb, xylycarbylase, xylycarbylase, xylycarbylase, xylycarba, xylycarba, etc. AChE) Inhibitor;
Acephate, azamethiphos, azinphos-methyl, azinphos-ethyl, ethephon, cassaphos, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos Chlorpyrifos, chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumapos, cyanophos, cyanophos, cyanophos, demethon-dysome, demethon-sion Dichromenthion, dichlorvos, dichlortophos, dimethoate, dimethylvinphos, disulfoton, disulfoton, O-ethyl O-4-nitrophenyl -4-nitropheneyl phenylphosphonothioate, ethion, ethoplophos, famphur, fenamiphos, pheniphos, pheniphothion, pheniphothion, fenthion, fentiphos (Isofenphos-methyl), Isocarbophos, isoxathion, malathion, mecarbam, methamidophos, methamidofos, methamidophos, methionophos, methionphos, methionphos, methionphos, methionphos, methionphos, methionphos ), Omethoate, oxydemethon-methyl, parathions, parathion-methyl, phenth ooate, phorate, phosalone, phosmet, phosphamiden, phoxim, pyrimiphos-methyl, pirimiphos-methyl, profenophos, phophophos, phophophos, prophophos. ), Pyraclophos, pyridaphenthion, quinalphos, sulfotep, tebupirimphos, tebupirimphos, temefos, terbuphos, terbuphos, terbuphos, terbuphos. ), Vamidothion, chlorthion, bromfenvinphos, bromophos, bromophos-ethyl, butatiophos, phoxim, carbophophos, carbophophos, carbophos, phoxim, phoxim, phoxim, phoxim, phoxim. , Sulprophos, diamidaphos, tetrachlorvinphos, propaphos, mesulfenphos, mesulfenphos, dioxabenzophos (dioxabenzophos), dioxabenzophos (dioxabenzophos) (Formothion), fensulphothion, isazophos, imiciaphos, isamidofos, thionazine, phostietan (phostietan), etc.
GABAergic chlorine channels such as chlordane, endosulfan, lindane, dienochlor, ethiprole, fipronil, [acetoprole]
Acrinathrin, Aresulin [(1R) -isomer] (allethrin [(1R) -isomer]), bifenthrin, bioallethrin, bioatherethrin S-cyclopentenyl cystel-cypermethrin isomer (bio) Bioresmethrin, cycloprothrin, cypermethrin, beta-cypermethrin, cypermethrin, gamma-cypermethrin, gamma-cypermethrin, gamma-cypermethrin, gamma-cypermethrin, cypermethrin, cypermethrin, cypermethrin, cypermethrin, cypermethrin, cypermethrin Permethrin (cypermethrin), alpha-cypermethrin (alpha-cypermethrin), beta-cypermethrin (beta-cypermethrin), seta-cypermethrin (theta-cypermethrin), zeda-cypermethrin (zeta-cypermethrin) )-Trans-Isomer] (cypermethrin [(1R) -trans-isomer]), deltamethrin, empentrin [(EZ)-(1R) -isomer] (empenthrin [(EZ)-(1R) -isomer]) , Esfenvalate, etofenprox, fenpropathrin, fenvalate, flucythrinate, flumethrin, tau-flulate Halfenprox, imiprothrin, methothrin, methothrin, epsilon-methrin, epsilon-methrin, methrin, methrin, methrin, methrin, methrin, methrin, methrin, methrin (Permethrin), Fe Notrin [(1R) -trans-isomer] (phenothrin [(1R) -trans-isomer]), prallethrin, resmethrin, kadethrin, sirafluthrin, tetramethrin, tetramethrin, tetramethrin, tetramethrin, tetramethrin, tetramethrin, tetramethrin, tetramethrin, tetramethrin, phenothrin [(1R) -trans-isomer]. Tetramethrin, tetramethrin [(1R) -isomer] (tetramethrin [(1R) -isomer]), tramethrin, transfluthrin, ZXI8901 (3- (4-bromophenothrin) phenothrin), tetramethrin [(1R) -isomer]) difluoromethrin, -α- (1-methylthyl) phenothrin), biopermethrin, furamethrin, profluthrin, profluthrin, fluthrinthrin, fluthrin, fluthrin, fluthrin, fluthrin , Tetramethrin, phenothrin, transfluthrin and other sodium channel modulators;
Acetamiprid (acetamiprid), clothianidin (clothianidin), dinotefuran (dinotefuran), imidacloprid (imidacloprid), nitenpyram (nitenpyram), thiacloprid (thiacloprid), thiamethoxam (thiamethoxam), nicotine (nicotine), nicotine (nicotine sulfate) sulfate, Suruhokisafuroru (sulfoxaflor ), Flupyradifurone, nicotinic acetylcholine receptor (nAChR) competitive modulators such as triflumezopyrim;
Nicotinic acetylcholine receptor (nAChR) allosteric modulators such as spinosad and spinetoram;
Glutamic acid-operated chlorine ion channels (GluCl) allosteric modulators such as abamectin, emamectin benzoate, repimectin, milbemectin;
Juvenile hormone analogs such as hydroprene, quinoprene, methoprene, phenoxycarb, pyriproxyfen;
Methyl bromide, chloropicrin, cryolite, sulfuryl fluoride, borax, boric acid, disodium octaborate, disodium salt. Sodium sodium metaborate Non-specific (multisite) inhibitors such as tareretic, dasomet, metam, sodium carbam sodium;
String organ TRPV channel modulators such as pymetrosine and pyrifluquinazon;
Tick growth inhibitors such as clofentezine, diflovidazin, hexithiazox, etoxazole;
Mitochondrial ATP synthases such as diafenthiuron, azocyclotin, cyhexatin, fenbutatin oxide, propargite, tetradiphon;
Oxidative phosphorylation decoupling agents that disrupt proton gradients such as chlorfenapyr, DNOC (dinitro-ortho-cresol), binapacryl, sulfuramide;
Nicotinic acetylcholine receptor (nAChR) channel blockers such as bensultap, cultap hydrochloride, thiocyclam, monosultap;
Bistrifluron, chlorfluazuron, diflubenzuron, flubenzuron, flufenoxuron, flufenoxuron, hexafluuron, hexafluuron, hexulfuron ), Chitin biosynthesis inhibitor type 0 such as noviflumuron, teflubenzuron, triflumuron;
Chitin biosynthesis inhibitor type 1 such as buprofezin;
Flies insect molting inhibitors such as cyromazine;
Moulting hormone (ecdyson) receptor agonists such as chromaphenozide, halophenozide, methoxyphenozide, and tebufenozide;
Octopamine receptor agonists such as amitraz;
Mitochondrial electron transport chain complex III inhibitors such as hydramethylnon, acequinocyl, fluacrypyrim, biphenazate;
Fenazaquin, fenpyroximate, pyridaben, pyrimidifen, tebufenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, rotenone, etc.
Voltage-gated sodium channel blockers such as indoxacarb and metaflumizone;
Acetyl-CoA carboxylase inhibitors such as spirodiclofen, spiromesifen, spirotetramat;
Aluminum phosphide, calcium phosphide, calcium phosphide, phosphine, zinc phosphide, calcium cyanide, sodium cyanide, sodium cyanide, potassium cyanide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide, calcium phosphide Inhibitors of mitochondrial electron transfer system complex IV such as cyanide);
Mitochondrial electron transport chain complex II inhibitors such as cyenopyraphen, cyflumetofen, and pyflubumide;
Ryanodine receptor modulators such as chlorotranniliprole, cyantraniliprole, flubendiamide;
String organ modulators such as flonicamide Target site unspecified;
Azadilactin, benzoximate, phenisobromolate, quinomethionat, dicofol, pyridalyl, pyropropylate (bromate), bromopropylate (bromolate), and bromopropirate (bromite). ), Dinobuton, dinocap, hydrogen cyanide, methyl iodide, karanjin,] mercury chloride, pentachlorophenol, methylisothiocyanate. ), Dinobuton, dinocap, hydrogen cyanide, methyliodide, karanjin, mercury chloride, pentachlorophenol, methylisothiocyanate. (Pentachlorophenol), phosphine, piperonyl butoxide, polynactins, sabadilla, sulcofluone salt (sulcofluone-sodium, sulcofur). , Amidithion, amidothioate, aminocarb, amiton, aramite,] athidathion, isothiocyanate, azotoate, pentachlorophenol, polysulfide, hydrogen cyanide, hydrocyanate, hydrocyanate, and hydrocyanate. , 5- (1,3-benzodioxol-5-yl) -3-hexylcyclohexa-2-enone (5- (1,3-benzodioxole-5-yl) -3-hexylcyclohexa-2-enone) , 1,1-bis (4-chlorophenyl) -2-ethoxyethanol (1,1-bis (4-chlorophenyl) -2-ethoxyethanol), butonate, butopyronoxyl, 2- (2-butoxyethoxy) ) Ethyl thiocyanate (2- (2-butoxyethoxy) ethyl thiocyanate), camphoryl (ca) mphechlor, chlorbenside, chlordecone, chlordimeform, chlorphenethol, chlorfenbendazole, chlorphenesol, fluorphenson, fluorefasolve, fluorenesolve (Levamisol), amidoflumet, pyrafluple, pyriprole, tralopylil, flupyrazofos, flupyrazofos, diofenolan (diofenbendazole, diofenbendazole, diofenbendazole, diofenbendazole) benzomete, flufenerim, albendazole, oxybendazole, fenbendazole, metam-sodium, 1,3-dichloropropene 1,3-dichloropropene, 1,3-dichloropropene, fenbendazole, fenbendazole, metam-sodium, 1,3-dichloropropene , Frometoquin, carbonilyprole, tetraniliprole, brofranilide, dichloromesothiaz, dichloromethozotiaz, ethylene dibromide (eth), ethylene dibromide -Chloroethyl) ether (bis (2-chloroethyl) ether), 1-bromo-2-chloroethane (1-blomo-2-chloroethane), 3-bromo-1-chloropropa-1-ene (3-bromo-1-chlororop) -1-ene), bromocyclene, carbon disulfide (carbendazole), carbon tetrachloride (tetraculomethane), nemadetin, cymiazole, calcium polysulfide (calcium cyclinyl) n), 2- (octylthio) ethanol, potassium oleate, fatty acid sodium oleate, machine oil,] tar oil, anabasine, morantel tartrate. startrate, insecticide chrysanthemum (pyrethrum), rapeseed ole, soybean lecithin, starch, hydroxypropyl starch (hydroxypropylstarch), fatty acid glyceride (delicro) fatty acid glyceryl glycol fatty acid ester), ileic acid (diatomite). Afoxolaner, fluazaindolizine, affidopyropen, cyhalodiamide, tioxazaphen, tioxazaphen, fluhexaphen, fluhexaphen, fluhexaphen, fluhexaphene Roll (tetraculolantiliroll), sarolaner, rotilaner, cycloxaprid, fluensulfone, TPIC (tripropyl isopropyltorocyanurate), D-Done3, MB-599 (verbutin), bis (2,3,3,3-tetrachloropropyl) ether (bis (2,3,3,3-tetrachloropropyl) ether), DCIP (bis (2-chloro-1-methyl)) Ether), ENT-8184 (N- (2-Ethylhexyl) bicyclohept-5-ene-2,3-dicarboximide), Bayer 22408 (O, O-diethyl O-naphthalimide phosphorothiate), Body- 3-methyl-2-phenylbenzazolium (hexacyanopherate), benzpyrimoxan, asynonapyr, flupyrimin, fluoripylomi, tyclopyrazofluorol (tyclozylospira) Other agents of.
以下に、本発明の殺菌性化合物を有効成分とする薬害軽減剤、並びに該薬害軽減剤と除草性化合物とを含む薬害軽減された除草性組成物の製剤例、試験例、施用例を示し、本発明を具体的に説明するが、本発明はこれらに限られるものではない。 Hereinafter, preparation examples, test examples, and application examples of a phytotoxicity-reducing agent containing the bactericidal compound of the present invention as an active ingredient and a phytotoxicity-reduced herbicidal composition containing the phytotoxicity-reducing agent and a herbicidal compound are shown. The present invention will be specifically described, but the present invention is not limited thereto.
なお、以下の製剤例中に記載の各成分の配合部数は全て重量部数を意味する。 In addition, the number of parts of each component described in the following formulation examples means the number of parts by weight.
<参考例1(ピカルブトラゾクスの合成)>
特許文献6の製造例24に記載の方法に準じて、
(1−メチル−1H−5−テトラゾリル)−フェニル−メタノンオキシム 3.46gとt−ブチル ベンゾイル−(6−(ブロモメチル)ピリジン−2−イル)カルバメート[CAS No.1334119−10−6] 13.69gから合成中間体であるt−ブチル ベンゾイル−{6−((Z)−(1−メチル−1H−5−テトラゾリル)フェニルメチレン−アミノオキシメチル)−2−ピリジル}カルバメート 2.47gを得たのちに、メタノール溶媒中、20%NaOH水溶液にて反応し、ピカルブトラゾクス 1.68gを得た。
1H−NMR (CDCl3) δ: 7.86 (1H, d, J = 8.3 Hz),7.65(1H, t, J = 8.0 Hz), 7.51(2H, t, J = 4.3 Hz), 7.44(1H, dd, J = 8.4, 6.3 Hz), 7.38(2H, t, J = 7.5 Hz), 7.22(1H, s), 6.93(1H, d, J = 7.3 Hz), 5.25(2H, s), 3.98(3H, s), 1.52(9H, s).<Reference Example 1 (Synthesis of Picaru Butrazox)>
According to the method described in Production Example 24 of Patent Document 6,
(1-Methyl-1H-5-tetrazolyl) -phenyl-methanone oxime 3.46 g and t-butyl benzoyl- (6- (bromomethyl) pyridin-2-yl) carbamate [CAS No. 1334119-10-6] Synthetic intermediate from 13.69 g t-butyl benzoyl- {6-((Z)-(1-methyl-1H-5-tetrazolyl) phenylmethylene-aminooxymethyl) -2-pyridyl } After obtaining 2.47 g of carbamate, the reaction was carried out in a 20% aqueous NaOH solution in a methanol solvent to obtain 1.68 g of picarbutrazox.
1 H-NMR (CDCl 3 ) δ: 7.86 (1H, d, J = 8.3 Hz), 7.65 (1H, t, J = 8.0 Hz), 7.51 (2H, t, J = 4.3 Hz), 7.44 (1H, dd, J = 8.4, 6.3 Hz), 7.38 (2H, t, J = 7.5 Hz), 7.22 (1H, 1H, s), 6.93 (1H, d, J = 7.3 Hz), 5.25 (2H, s), 3.98 (3H, s), 1.52 (9H, s).
<製剤例1(ピカルブトラゾクス水和剤)>
ピカルブトラゾクス:10部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 1 (Picalbutrazox wettable powder)>
Picalbutrazox: 10 parts, Neogen Powder (registered trademark): 0.5 parts, Carplex (registered trademark): 0.5 parts, Gosenol (registered trademark): 0.2 parts, Radiolite (registered trademark) : 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例2(ヒドロキシイソキサゾール・ピリミスルファン水和剤)>
ヒドロキシイソキサゾール:30部、ピリミスルファン:2部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト:0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 2 (Hydroxyisoxazole / pyrimisulfan wettable powder)>
Hydroxyisoxazole: 30 parts, pyrimisulfan: 2 parts, neogen powder (registered trademark): 0.5 parts, carplex (registered trademark): 0.5 parts, gosenol (registered trademark): 0.2 parts , Radiolite: 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例3(アミスルブロム・イマゾスルフロン水和剤)>
アミスルブロム:20部、イマゾスルフロン:1部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 3 (Amisulbrom / Imazosulfuron wettable powder)>
Amisulbrom: 20 parts, Imazosulfuron: 1 part, Neogen powder (registered trademark): 0.5 parts, Carplex (registered trademark): 0.5 parts, Gosenol (registered trademark): 0.2 parts, Radiolite (registered) Trademark): 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例4(シアゾファミド・イマゾスルフロン水和剤)>
シアゾファミド:10部、イマゾスルフロン:0.5部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 4 (Ciazophamid / Imazosulfone wettable powder)>
Siazophamide: 10 parts, Imazosulflon: 0.5 parts, Neogen powder (registered trademark): 0.5 parts, Carplex (registered trademark): 0.5 parts, Gosenol (registered trademark): 0.2 parts, Radiolite (Registered trademark): 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例5(カスガマイシン・ピラゾレート水和剤)>
カスガマイシン:1部、ピラゾレート:50部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 5 (Kasugamycin / pyrazolate wettable powder)>
Kasugamycin: 1 part, pyrazolate: 50 parts, Neogen powder (registered trademark): 0.5 parts, Carplex (registered trademark): 0.5 parts, Gosenol (registered trademark): 0.2 parts, Radiolite (registered) Trademark): 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例6(クロロタロニル・スルコトリオン水和剤)>
クロロタロニル:30部、スルコトリオン:10部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 6 (Chlorothalonil sulcotrione wettable powder)>
Chlorotalonyl: 30 parts, sulcotrione: 10 parts, neogen powder (registered trademark): 0.5 parts, carplex (registered trademark): 0.5 parts, gosenol (registered trademark): 0.2 parts, radiolite ( Registered trademark): 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例7(ベノミル・テニルクロール水和剤)>
ベノミル:20部、テニルクロール:5部:50部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 7 (Benomil / Tenilchlor wettable powder)>
Benomil: 20 parts, Tenil chlor: 5 parts: 50 parts, Neogen powder (registered trademark): 0.5 parts, Carplex (registered trademark): 0.5 parts, Gosenol (registered trademark): 0.2 parts, Radio Light (registered trademark): 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例8(チオファネートメチル・ピリミスルファン水和剤)>
チオファネートメチル:40部、ピリミスルファン:3部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 8 (thiophanate methyl pyrimisulfan wettable powder)>
Thiophanate-methyl: 40 parts, pyrimisulfan: 3 parts, neogen powder (registered trademark): 0.5 parts, carplex (registered trademark): 0.5 parts, gosenol (registered trademark): 0.2 parts, radiolite (Registered trademark): 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例9(ピカルブトラゾクス・ピリミスルファン水和剤)>
ピカルブトラゾクス:10部、ピリミスルファン:1部、ネオゲンパウダー(登録商標):0.5部、カープレックス(登録商標):0.5部、ゴーセノール(登録商標):0.2部、ラヂオライト(登録商標):0.8部、H微粉:残部とし、合計100部を粉砕混合して水和剤を得た。<Formulation Example 9 (Picalbutrazox pyrimisulfan wettable powder)>
Picalbutrazox: 10 parts, pyrimisulfan: 1 part, Neogen powder (registered trademark): 0.5 parts, Carplex (registered trademark): 0.5 parts, Gosenol (registered trademark): 0.2 parts , Radiolite (registered trademark): 0.8 parts, H fine powder: balance, and a total of 100 parts were pulverized and mixed to obtain a wettable powder.
<製剤例10(ピカルブトラゾクス・ピリミスルファン粒剤)>
ピカルブトラゾクス:3部、ピリミスルファン:0.3部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー64.5部、タルク27.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 10 (Picalbutrazox pyrimisulfan granules)>
Picalbutrazox: 3 parts, pyrimisulfan: 0.3 parts, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 64.5 parts, talc 27.7 parts, etc. After uniformly pulverizing and mixing, water was added and kneaded, and granulated and dried to obtain granules.
<製剤例11(ヒドロキシイソキサゾール・ピリミスルファン粒剤)>
ヒドロキシイソキサゾール:5部、ピリミスルファン:0.2部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー62.6部、タルク27.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 11 (Hydroxyisoxazole / pyrimisulfan granules)>
Hydroxyisoxazole: 5 parts, pyrimisulfan: 0.2 parts, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 62.6 parts, talc 27.7 parts, etc. After uniformly pulverizing and mixing, water was added and kneaded, and granulated and dried to obtain granules.
<製剤例12(アミスルブロム・イマゾスルフロン粒剤)>
アミスルブロム:5部、イマゾスルフロン:0.4部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー56.4部、タルク33.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 12 (Amisulbrom / Imazosulfuron Granules)>
Amisulbrom: 5 parts, Imazosulfuron: 0.4 parts, Polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, Clay 56.4 parts, Talc 33.7 parts, after uniformly pulverizing and mixing. , Water was added and kneaded, and granulated and dried to obtain granules.
<製剤例13(シアゾファミド・イマゾスルフロン粒剤)>
シアゾファミド:2.5部、イマゾスルフロン:0.2部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー59.1部、タルク33.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 13 (Ciazophamid / Imazosulfone Granules)>
Siazofamide: 2.5 parts, Imazosulfuron: 0.2 parts, Polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, Clay 59.1 parts, Talc 33.7 parts, etc. are uniformly crushed. After mixing, water was added and kneaded, and granulated and dried to obtain granules.
<製剤例14(カスガマイシン・ピラゾレート粒剤)>
カスガマイシン:0.1部、ピラゾレート:20部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー53.7部、タルク21.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 14 (Kasugamycin / pyrazolate granules)>
Kasugamycin: 0.1 part, pyrazolate: 20 parts, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 53.7 parts, talc 21.7 parts, etc. , Water was added and kneaded, and granulated and dried to obtain granules.
<製剤例15(クロロタロニル・スルコトリオン粒剤)>
クロロタロニル:4部、スルコトリオン:1部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー65.8部、タルク33.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Preparation Example 15 (Chlorothalonil / Sulcotrione Granules)>
Chlorothalonil: 4 parts, sulcotrione: 1 part, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 65.8 parts, talc 33.7 parts, etc. Water was added and kneaded, and granulated and dried to obtain granules.
<製剤例16(ベノミル・テニルクロール粒剤)>
ベノミル:5部、テニルクロール:1部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー68.8部、タルク29.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 16 (Benomyl / Tenylchlor Granules)>
Benomyl: 5 parts, tenyl chlor: 1 part, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 68.8 parts, talc 29.7 parts, etc. Was added and kneaded, and granulated and dried to obtain granules.
<製剤例17(チオファネートメチル・ピリミスルファン粒剤)>
チオファネートメチル:5部、ピリミスルファン:0.4部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー62.4、タルク27.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 17 (thiophanate methyl pyrimisulfan granules)>
Thiophanate methyl: 5 parts, pyrimisulfan: 0.4 parts, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 62.4 parts, talc 27.7 parts, etc. After that, water was added and kneaded, and granulated and dried to obtain granules.
<製剤例18(イソプロチオラン・ピリミスルファン粒剤)>
イソプロチオラン:12部、ピリミスルファン:0.4部、ポリオキシエチレン・ポリオキシプロピレン縮合物1.5部、CMCナトリウム3部、クレー55.4、タルク27.7部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤を得た。<Formulation Example 18 (isoprothiolan / pyrimisulfan granules)>
Isoprothiolane: 12 parts, pyrimisulfan: 0.4 parts, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 55.4 parts, talc 27.7 parts, etc. After that, water was added and kneaded, and granulated and dried to obtain granules.
供試薬剤
(B1)ヒドロキシイソキサゾール液剤(商品名/タチガレン(登録商標)液剤、有効成分ヒドロキシイソキサゾール、30重量%、三井化学アグロ(株)製)
(B2)製剤例1で得られたピカルブトラゾクス水和剤
(B3)アミスルブロム顆粒水和剤(商品名/オラクル(登録商標)顆粒水和剤、有効成分アミスルブロム、50重量%、日産化学工業(株)製)
(B4)シアゾファミド水和剤(商品名/ランマン(登録商標)フロアブル、有効成分シアゾファミド、9.4重量%、石原バイオサイエンス(株)製)
(B5)カスガマイシン液剤(商品名/カスミン(登録商標)液剤、有効成分カスガマイシン、2重量%、北興化学工業(株)製)
(B6)クロロタロニル水和剤(商品名/ダコニール(登録商標)1000水和剤、有効成分クロロタロニル、40重量%、(株)エス・ディー・エス バイオテック製)
(B7)ベノミル水和剤(商品名/ベンレート(登録商標)水和剤、有効成分ベノミル、50重量%、住友化学工業(株)製)
(B8)チオファネートメチル水和剤(商品名/トップジン(登録商標)M水和剤、有効成分チオファネートメチル、70重量%、日本曹達(株)製)
(B9)イソプロチオラン粒剤(商品名/フジワン(登録商標)粒剤、有効成分イソプロチオラン、12重量%、日本農薬(株)製)
(B10)ヒドロキシイソキサゾール粉剤(商品名/タチガレン(登録商標)粉剤、有効成分ヒドロキシイソキサゾール、4重量%、三井化学アグロ(株)製)Dispensant (B1) Hydroxyisoxazole solution (trade name / Tachigaren (registered trademark) solution, active ingredient hydroxyisoxazole, 30% by weight, manufactured by Mitsui Kagaku Agro Co., Ltd.)
(B2) Picalbutrazox wettable powder (B3) Amisulbrom granule wettable powder obtained in Preparation Example 1 (trade name / Oracle (registered trademark) granule wettable powder, active ingredient Amisulbrom, 50% by weight, Nissan Chemical Industry Co., Ltd. Made by Co., Ltd.)
(B4) Siazofamide wettable powder (trade name / Lanman (registered trademark) flowable, active ingredient siazofamide, 9.4% by weight, manufactured by Ishihara Bioscience Co., Ltd.)
(B5) Kasugamycin solution (trade name / Kasmin (registered trademark) solution, active ingredient kasugamycin, 2% by weight, manufactured by Hokuko Chemical Industry Co., Ltd.)
(B6) Chlorothalonil wettable powder (trade name / Daconil (registered trademark) 1000 wettable powder, active ingredient chlorotalonil, 40% by weight, manufactured by SDS Biotech Co., Ltd.)
(B7) Benomyl wettable powder (trade name / Benlate (registered trademark) wettable powder, active ingredient benomyl, 50% by weight, manufactured by Sumitomo Chemical Co., Ltd.)
(B8) Thiophanate-methyl wettable powder (trade name / Topzin (registered trademark) M wettable powder, active ingredient thiophanate-methyl, 70% by weight, manufactured by Nippon Soda Corporation)
(B9) Isoprothiolan granules (trade name / Fujiwan (registered trademark) granules, active ingredient isoprothiolane, 12% by weight, manufactured by Nihon Nohyaku Co., Ltd.)
(B10) Hydroxyisoxazole powder (trade name / Tachigaren (registered trademark) powder, active ingredient hydroxyisoxazole, 4% by weight, manufactured by Mitsui Kagaku Agro Co., Ltd.)
<試験例1>
(B1)〜(B8)の薬液を、それぞれ600ppm、100ppm、250ppm、94ppm、5000ppm、800ppm、1000ppm及び1000ppmの濃度となるように希釈(それぞれ、500倍、1000倍、2000倍、1000倍、4倍、500倍、500倍及び700倍)、土壌に潅注(B1、B2、B3,B4、B6、B7、B8;500ml/育苗箱相当量、B5;50ml/育苗箱相当量)、または(B9)を50g/育苗箱、(B10)を6g/育苗箱で処理した後、供試作物(イネ品種:コシヒカリ)を播種した。17日間、26℃の温室で栽培した苗(約2.1葉期)に、再度、所定の濃度に希釈した、(B1)〜(B8)の薬液を土壌に潅注または(B9)を50g/育苗箱で処理した後、薬剤処理・移植苗とした。<Test Example 1>
The chemicals (B1) to (B8) are diluted to concentrations of 600 ppm, 100 ppm, 250 ppm, 94 ppm, 5000 ppm, 800 ppm, 1000 ppm and 1000 ppm, respectively (500 times, 1000 times, 2000 times, 1000 times and 4). Double, 500 times, 500 times and 700 times), irrigate the soil (B1, B2, B3, B4, B6, B7, B8; 500 ml / nursery box equivalent, B5; 50 ml / nursery box equivalent), or (B9) ) Was treated in a 50 g / nursery box, and (B10) was treated in a 6 g / nursery box, and then a prototype (rice variety: Koshihikari) was sown. Seedlings cultivated in a greenhouse at 26 ° C. for 17 days (about 2.1 leaf stage) were again diluted to a predetermined concentration, and the chemical solutions (B1) to (B8) were irrigated into the soil or 50 g / of (B9) was added. After treatment in a nursery box, the seedlings were treated with chemicals and transplanted.
代掻きをした水田土壌を含むコンテナ(30×30cm)に、薬剤処理・移植苗と薬剤処理をしていない移植苗を、移植深度1.5cmで、2本を1株とし、10株ずつ移植した。移植4日後、水深2cmに保った状態で、ピリミスルファン0.67%粒剤(商品名/ベストパートナー(登録商標)粒剤、クミアイ化学工業(株)製)を20kg/ha相当量を処理した。なお対照として水稲に対する雑草の影響を排除するために雑草のみを取り除いた完全除草区を設置した 。
薬剤処理21日後に、植物体の抜き取り調査を行った。
なお、乾燥重は、地上部と根部に切り分け100℃1時間、80℃2日間で乾燥した重量を測定した。
完全除草区に比べて、ピリミスルファン0.67%粒剤処理区では地上部乾物重、根部乾物重において薬害が確認された。薬害が確認された区に関して上記殺菌剤処理区では上記殺菌剤無処理区と比べて、地上部乾物重、根部乾物重が増加しており、薬害軽減効果を有することが確認された。In a container (30 x 30 cm) containing paddy soil that had been scraped, 10 strains of chemical-treated / transplanted seedlings and 10 strains of transplanted seedlings that had not been treated with chemicals were transplanted at a transplantation depth of 1.5 cm, with 2 plants as 1 plant. .. 4 days after transplantation, while keeping the water depth at 2 cm, treat 20 kg / ha of pyrimisulfan 0.67% granules (trade name / Best Partner (registered trademark) granules, manufactured by Kumiai Chemical Industry Co., Ltd.). did. As a control, a complete weed control area was set up in which only weeds were removed in order to eliminate the effects of weeds on paddy rice.
Twenty-one days after the chemical treatment, a sampling survey of plants was conducted.
The dry weight was measured by cutting the above-ground part and the root part and drying at 100 ° C. for 1 hour and 80 ° C. for 2 days.
Compared with the complete herbicide plot, in the pyrimisulfan 0.67% granule treatment plot, phytotoxicity was confirmed in the above-ground dry matter weight and the root dry matter weight. Regarding the plots where phytotoxicity was confirmed, the above-ground dry matter weight and root dry matter weight were increased in the above-mentioned fungicide-treated plot as compared with the above-mentioned fungicide-free plot, and it was confirmed that the plot had a phytotoxicity-reducing effect.
<試験例2>
ヒドロキシイソキサゾール液剤(B1)、ピカルブトラゾクス水和剤(B2)、アミスルブロム顆粒水和剤(B3)をそれぞれ600ppm、100ppm及び250ppmの濃度となるように希釈(500倍、1000倍及び2000倍)、土壌に潅注後(500ml/育苗箱相当量)、供試作物(イネ品種:コシヒカリ)を播種した。17日間、26℃の温室で栽培した苗(約2.1葉期)に、再度、所定の濃度に希釈した、(B1)〜(B3)の薬液を土壌に潅注し、薬剤処理・移植苗とした。<Test Example 2>
Hydroxyisoxazole solution (B1), picalbutrazox wettable powder (B2), and amisulbrom granule wettable powder (B3) were diluted to concentrations of 600 ppm, 100 ppm, and 250 ppm, respectively (500 times, 1000 times, and 2000). After irrigating the soil (500 ml / equivalent amount of the nursery box), the sample (rice variety: Koshihikari) was sown. Seedlings cultivated in a greenhouse at 26 ° C for 17 days (about 2.1 leaf stage) were again irrigated with the chemical solutions (B1) to (B3) diluted to a predetermined concentration, and treated with chemicals and transplanted seedlings. And said.
代掻きをした水田土壌を含むコンテナ(30×30cm)に、薬剤処理・移植苗と薬剤処理をしていない移植苗を、移植深度1.5cmで、2本を1株とし、10株ずつ移植した。移植4日後、水深2cmに保った状態で、オキサジクロメホン0.8%、テフリルトリオン3%粒剤(商品名/エーワン(登録商標)粒剤、北興化学工業(株)製)を20kg/ha相当量を処理した。また、別のコンテナに、ピリミスルファン0.67%粒剤を20kg/ha相当量を処理した。なお対照として水稲に対する雑草の影響を排除するために雑草のみを取り除いた完全除草区を設置した 。
薬剤処理26日後に、植物体の抜き取り調査を行った。
なお、乾燥重は、地上部と根部に切り分け100℃1時間、80℃2日間で乾燥した重量を測定した。In a container (30 x 30 cm) containing paddy soil that had been scraped, 10 strains of chemical-treated / transplanted seedlings and 10 strains of transplanted seedlings that had not been treated with chemicals were transplanted at a transplantation depth of 1.5 cm, with 2 plants as 1 plant. .. 4 days after transplantation, while keeping the water depth at 2 cm, oxadichromephon 0.8% and tefryltrione 3% granules (trade name / A-One (registered trademark) granules, manufactured by Hokuko Chemical Industry Co., Ltd.) are equivalent to 20 kg / ha. The amount was processed. In addition, another container was treated with pyrimisulfan 0.67% granules in an amount equivalent to 20 kg / ha. As a control, a complete herbicide plot was set up in which only weeds were removed in order to eliminate the effects of weeds on paddy rice.
Twenty-six days after the chemical treatment, a sampling survey of plants was conducted.
The dry weight was measured by cutting the above-ground part and the root part and drying at 100 ° C. for 1 hour and 80 ° C. for 2 days.
完全除草区に比べて、オキサジクロメホン0.8%、テフリルトリオン3%粒剤処理区、ピリミスルファン0.67%粒剤処理区では地上部乾物重、根部乾物重において薬害が確認された。薬害が確認された区に関して、ヒドロキシイソキサゾール液剤処理区では、ヒドロキシイソキサゾール液剤無処理区と比べて、地上部乾物重、根部乾物重が増加しており、薬害軽減効果を有することが確認された。 Compared with the complete herbicide group, phytotoxicity was confirmed in the above-ground dry matter weight and the root dry matter weight in the oxadichromefone 0.8%, tefryltrione 3% granule treatment group, and pyrimisulfan 0.67% granule treatment group. Regarding the plots where phytotoxicity was confirmed, the hydroisoxazole solution-treated plots had increased above-ground dry matter weight and root dry matter weight as compared with the hydroxyisoxazole liquid-non-treated plots, and could have the effect of reducing phytotoxicity. confirmed.
完全除草区に比べて、オキサジクロメホン0.8%、テフリルトリオン3%粒剤処理区、ピリミスルファン0.67%粒剤処理区では地上部乾物重、根部乾物重において薬害が確認された。薬害が確認された区に関して、ピカルブトラゾクス水和剤処理区では、ピカルブトラゾクス水和剤無処理区と比べて、地上部乾物重、根部乾物重が増加しており、薬害軽減効果を有することが確認された。 Compared with the complete herbicide group, phytotoxicity was confirmed in the above-ground dry matter weight and the root dry matter weight in the oxadichromefone 0.8%, tefryltrione 3% granule treatment group, and pyrimisulfan 0.67% granule treatment group. Regarding the plots where phytotoxicity was confirmed, the above-ground dry matter weight and root dry matter weight increased in the Picarubutrazox wettable powder-treated plot compared to the Picarubutrazox wettable powder-free plot, and the effect of reducing phytotoxicity. Was confirmed to have.
完全除草区に比べて、オキサジクロメホン0.8%、テフリルトリオン3%粒剤処理区、ピリミスルファン0.67%粒剤処理区では地上部乾物重、根部乾物重において薬害が確認された。薬害が確認された区に関して、アミスルブロム顆粒水和剤処理区では、アミスルブロム顆粒水和剤無処理区と比べて、地上部乾物重、根部乾物重が増加しており、薬害軽減効果を有することが確認された。 Compared with the complete herbicide group, phytotoxicity was confirmed in the above-ground dry matter weight and the root dry matter weight in the oxadichromefone 0.8%, tefryltrione 3% granule treatment group, and pyrimisulfan 0.67% granule treatment group. Regarding the plots where phytotoxicity was confirmed, the above-ground dry matter weight and root dry matter weight were increased in the amisulbrom granule wettable powder-treated plot as compared with the amisulfrom granule wettable powder-free plot, and it may have a phytotoxicity reduction effect. confirmed.
<試験例3>
ヒドロキシイソキサゾール液剤(B1)を、600ppmの濃度となるように希釈(500倍)後、で21日生育させた稚苗(イネ品種:さがびより)潅注した(500ml/育苗箱相当量)。<Test Example 3>
Hydroxyisoxazole solution (B1) was diluted (500 times) to a concentration of 600 ppm, and then irrigated with seedlings (rice varieties: from Sagabi) grown for 21 days (500 ml / equivalent amount of nursery box). ..
代掻きをした水田(滋賀県野洲市 三井化学アグロ(株)農業化学研究所内)に、薬剤処理・移植苗と薬剤処理をしていない移植苗を、3本を1株とし、移植した。移植5日後、水深5cmに保った状態で、オキサジクロメホン0.8%、テフリルトリオン3%粒剤を20kg/ha相当量を処理した。また、別のコンテナに、ピリミスルファン0.67%粒剤を20kg/ha相当量を処理した。なお対照として水稲に対する雑草の影響を排除するために雑草のみを取り除いた完全除草区を設置した 。
除草剤処理30日後に、草丈、茎数及び植物体の抜き取り調査を行った。
なお、乾燥重は、地上部と根部に切り分け100℃1時間、80℃2日間で乾燥した重量を測定した。Three seedlings treated with chemicals and transplanted seedlings without chemical treatment were transplanted into a paddy field (inside Agricultural Chemistry Research Institute, Mitsui Chemicals Agro Co., Ltd., Yasu City, Shiga Prefecture). Five days after the transplantation, 20 kg / ha of oxadichromephone 0.8% and tefryltrione 3% granules was treated while maintaining the water depth at 5 cm. In addition, another container was treated with pyrimisulfan 0.67% granules in an amount equivalent to 20 kg / ha. As a control, a complete herbicide plot was set up in which only weeds were removed in order to eliminate the effects of weeds on paddy rice.
Thirty days after the herbicide treatment, plant height, number of stems, and sampling of plants were investigated.
The dry weight was measured by cutting the above-ground part and the root part and drying at 100 ° C. for 1 hour and 80 ° C. for 2 days.
完全除草区に比べて、オキサジクロメホン0.8%、テフリルトリオン3%粒剤倍量処理区、ピリミスルファン0.67%粒剤倍量処理区では草丈、茎数、地上部乾物重、根部乾物重において薬害が確認された。薬害が確認された区に関して、ヒドロキシイソキサゾール液剤処理区では、ヒドロキシイソキサゾール液剤無処理区と比べて、茎数、地上部乾物重、根部乾物重が増加しており、薬害軽減効果を有することが確認された。 Compared to the complete herbicide plot, oxadichromefone 0.8%, tefryltrione 3% granule double treatment plot, pyrimisulfan 0.67% granule double treatment plot, plant height, number of stems, above-ground dry matter weight, root Chemical damage was confirmed in the dry matter weight. Regarding the groups where phytotoxicity was confirmed, the number of stems, the weight of dry matter above the ground, and the weight of dry matter at the roots increased in the hydroxyisoxazole solution-treated group compared to the hydroxyisoxazole solution-untreated group, and the effect of reducing phytotoxicity was achieved. It was confirmed to have.
本発明によれば、既存の薬害軽減剤と比較して、種々の栽培作物に対して普遍的に使用可能で良好な薬害軽減剤および該薬害軽減剤と除草性化合物とを含む薬害軽減された除草性組成物を得ることができる。 According to the present invention, as compared with existing phytotoxicity mitigating agents, phytotoxicity mitigating agents that are universally usable and good for various cultivated crops and phytotoxicity mitigating agents containing the phytotoxicity mitigating agents and herbicides are alleviated. A herbicidal composition can be obtained.
この出願は、2018年2月23日に出願された日本出願特願2018−030986号を基礎とする優先権を主張し、その開示の全てをここに取り込む。 This application claims priority on the basis of Japanese application Japanese Patent Application No. 2018-030986 filed on February 23, 2018 and incorporates all of its disclosures herein.
Claims (18)
(A1)ACCase阻害型除草性化合物
(A2)アセトラクテート合成酵素阻害型除草性化合物
(A3)白化型除草性化合物
(A4)VLCFA阻害型除草性化合物
(A5)プロトポリフィリノーゲンIXオキシダーゼ阻害型除草性化合物
(A6)合成オーキシン系除草性化合物 At least one herbicide compound selected from the group consisting of the following (A1) to (A6) for crops or a phytotoxicity-reducing agent due to the salt thereof, which contains picalbutrazox or a salt thereof as an active ingredient.
(A1) ACCase-inhibiting herbicidal compound
(A2) Acetolactate synthase inhibitory herbicidal compound
(A3) Whitening herbicidal compound
(A4) VLCFA inhibitory herbicidal compound
(A5) Protopolyphilinogen IX oxidase-inhibiting herbicidal compound
(A6) Synthetic auxin herbicidal compound
(A1)ACCase阻害型除草性化合物
(A2)アセトラクテート合成酵素阻害型除草性化合物
(A3)白化型除草性化合物
(A4)VLCFA阻害型除草性化合物
(A5)プロトポリフィリノーゲンIXオキシダーゼ阻害型除草性化合物
(A6)合成オーキシン系除草性化合物 At least one herbicide compound selected from the group consisting of the following (A1) to (A6) or a salt thereof, and a phytotoxicity reducing agent for crops containing Picalbutrazox or a salt thereof as an active ingredient. The herbicidal composition contained.
(A1) ACCase inhibitory herbicidal compound (A2) Acetractate synthase inhibitory herbicidal compound (A3) Whitening herbicidal compound (A4) VLCFA inhibitory herbicidal compound (A5) Protopolyphilinogen IX oxidase inhibitory herbicide Sex compound (A6) Synthetic auxin-based herbicidal compound
(A2−1)スルホニルウレア系除草性化合物、ピリミジニル安息香酸系除草性化合物若しくはトリアゾロピリミジン系除草性化合物
(A3−1)ピラゾール系除草性化合物若しくはトリケトン系除草性化合物 The herbicidal composition according to claim 7 , wherein the herbicidal compound is at least one kind of herbicidal compound or a salt thereof selected from the group consisting of the following (A2-1) and (A3-1).
(A2-1) Sulfonylurea-based herbicidal compound, pyrimidinylbenzoic acid-based herbicidal compound or triazolopyrimidine-based herbicidal compound (A3-1) Pyrazole-based herbicidal compound or triketone-based herbicidal compound
(B1)請求項1乃至4のいずれかに記載の薬害軽減剤aと、当該薬害軽減剤を含まない除草性組成物bとを混合して施用する方法、
(B2)請求項1乃至4のいずれかに記載の薬害軽減剤aと、当該薬害軽減剤を含まない除草性組成物bとを、独立して同じ作物に施用する方法、
(B3)請求項1乃至4のいずれかに記載の薬害軽減剤aと、請求項5乃至9のいずれかに記載の除草性組成物cとを、独立して同じ作物に施用する方法、
(B4)請求項5乃至9のいずれかに記載の除草性組成物cを施用する方法。 A method for reducing phytotoxicity on crops by an application method selected from the group consisting of the following (B1) to (B4).
(B1) A method of mixing and applying the phytotoxicity reducing agent a according to any one of claims 1 to 4 and the herbicidal composition b not containing the phytotoxicity reducing agent.
(B2) A method of independently applying the phytotoxicity reducing agent a according to any one of claims 1 to 4 and the herbicidal composition b not containing the phytotoxicity reducing agent to the same crop.
(B3) A method in which the phytotoxicity reducing agent a according to any one of claims 1 to 4 and the herbicidal composition c according to any one of claims 5 to 9 are independently applied to the same crop.
(B4) The method of applying the herbicidal composition c according to any one of claims 5 to 9 .
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