JP2023027251A - Agrochemical-containing slow-releasing granular fertilizer formulation - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an agrochemical-containing slow-releasing granular fertilizer formulation in which crystallization of an agrochemical component or a fertilizing component and decomposition/separation of the respective components are suppressed, long-term stability is high, and a risk such as flammability is reduced.

SOLUTION: An agrochemical-containing slow-releasing granular fertilizer formulation is produced by a production method of the agrochemical-containing slow-releasing granular fertilizer formulation containing a non-petroleum-based solvent and an agrochemical active component. The production method includes impregnating or mixing a previously prepared aqueous composition containing a mix of one or more non-petroleum-based solvents and water into a slow-releasing granular fertilizer. In the agrochemical-containing slow-releasing granular fertilizer formulation, a content ratio of the agrochemical component is 0.01-10%, a content ratio of the non-petroleum-based solvents is 0.1-10%, and a content ratio of the slow-releasing granular fertilizer is 50.0-99.9%.

SELECTED DRAWING: None

COPYRIGHT: (C)2023,JPO&INPIT

Description

TECHNICAL FIELD The present invention relates to a slow-release granular fertilizer formulation containing an agricultural chemical and a method for using the same.

There are many types of fertilizers, and there are many ways to classify them. Fertilizers can be roughly classified into organic fertilizers and inorganic fertilizers. There are compounded fertilizers that are a mixture of both, but although the ingredients of the two differ greatly, they have in common that the water-soluble components of inorganic compounds are absorbed by plants, and various improvements have been made to provide nutrients for plants. there is
Among existing chemical fertilizers, a representative example of a slow-release granular fertilizer is a composition in which magnesium potassium phosphate and magnesium ammonium phosphate are uniformly mixed at a predetermined ratio (Patent Document 1).

Japanese Patent Application Laid-Open No. 2008-133267 (Patent Document 2) discloses a method for suppressing damage to paddy rice by sucking pests of paddy rice. It is described that it is applied to the water surface. The siliceous fertilizer is defined as a fertilizer such as calcium silicate, potassium silicate, liquid potassium silicate, etc., in which the amount of soluble silicic acid in the fertilizer composition is 10% by weight or more. , as a pesticide-fertilizer mixture mixed with pesticide formulations.

WO2014/098203 (Patent Document 3) discloses that one or more agricultural chemical components are impregnated in granular fertilizer or attached to the surface of granular fertilizer, and the number of grains per gram is in the range of 15 to 80. A method for applying a pesticide-containing granular fertilizer comprising applying a granular fertilizer composition to soil using a fertilizer applicator is described (see claim 1). The pesticide-containing granular fertilizer composition used in the application method is obtained by adding a predetermined amount of pesticide ingredients containing a neonicotinoid insecticide to an organic solvent such as coating oil to a raw material of a commercially available general chemical fertilizer. It is characterized by obtaining a mixed solution obtained by mixing it with the chemical fertilizer, specifically, coating oil (Examples 1 to 3, Example 5) or C10-11 alkylbenzene (Example 4) Clothianidin (Examples 1 to 3), fenitrothion (Example 4) or furametpyr (Example 5), which are agricultural chemical components, are mixed with a solvent to obtain a mixture, and the obtained mixture is used as the chemical fertilizer. It is manufactured by mixing to

Japanese Patent Publication No. 44-18891 JP 2008-133267 A WO2014/098203

However, the siliceous fertilizer used in Patent Document 2 and the chemical fertilizer used in Patent Document 3 are ordinary soluble chemical fertilizers.

Ordinary chemical fertilizers do not maintain their fertilizing effect, so there is a problem that fertilization labor including top-dressing work becomes excessive. On the other hand, the demand for slow-release fertilizers has been growing steadily in recent years because of their long-lasting fertilizing effect, which not only saves manpower for applying fertilizers and makes efficient use of fertilizer components, but also has little impact on the environment. growing.
However, no pesticide-containing slow-release granular fertilizers obtained by treating slow-release fertilizers with pesticides are known at present.
An object of the present invention is to produce an agricultural chemical-containing slow-release granular fertilizer that can be applied to plants at the same time as a slow-release granular fertilizer and an agricultural chemical component and that does not adversely affect plants such as phytotoxicity.

As a result of intensive studies to solve the above problems, the present inventors have found a pesticide-containing slow-release granular fertilizer containing pesticides and fertilizers using a non-petroleum solvent to dissolve the pesticide components. When the formulation was prepared, the present inventors found that the slow-release granular fertilizer formulation does not exert adverse effects such as phytotoxicity on plants, and completed the present invention.

That is, the present invention includes the following aspects.
(1) A slow-release granular fertilizer formulation containing a non-petroleum solvent and an active ingredient of an agricultural chemical.

(2) The formulation according to (1), wherein the non-petroleum solvent has a water solubility of 100 ppm or more.

(3) Non-petroleum solvents include ether solvents, nitrile solvents, alcohol solvents, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, and amine solvents. The formulation according to (1) or (2), which is a solvent, an aldehyde solvent, a fatty acid ester solvent, a nitrogen-containing carrier solvent, or a glycol ether solvent.

(4) The formulation according to any one of (1) to (3), wherein the non-petroleum solvent is a glycol ether solvent.

(5) The formulation according to any one of (1) to (4), further containing water and/or liquid or liquid fertilizer.

(6) The pesticide is a carbamate acetylcholinesterase (AChE) inhibitor, an organophosphorus acetylcholinesterase (AChE) inhibitor, a cyclic diene organochlorine GABAergic chloride ion channel antagonist, a phenylpyrazole (fiprole) GABAergic chloride channel antagonists, pyrethroid and pyrethrin sodium channel modulators, sodium channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, nicotinic acetylcholine receptor (nAChR) agonists, butenolide nicotinic acetylcholine receptors ( nAChR) agonists, spinosynnic nicotinic acetylcholine receptor (nAChR) allosteric modulators, avermectin- and milbemycin-based chloride channel activators, juvenile hormone analogues, non-specific (multi-site) inhibitors, chordotonal modulators, mites Growth inhibitor, microbial-derived insect midgut lining disrupter, mitochondrial ATP synthase inhibitor, oxidative phosphorylation uncoupler, nereistoxin analog nicotinic acetylcholine receptor (nAChR) channel blocker, benzoyl urea chitin biosynthesis Synthesis inhibitor (type 0), chitin biosynthesis inhibitor (type 1), Diacyl insect molting inhibitor, diacyl-hydrazine molting hormone (ecdysone) receptor agonist, octopamine receptor agonist, mitochondrial electron transport system complex III inhibitors, mitochondrial electron transport chain complex I inhibitors (METI), voltage-dependent sodium channel blockers, tetronic acid and tetramic acid derivative acetyl-CoA carboxylase inhibitors, phosphine-based mitochondrial electron transport chain complex IV inhibitors, cyanide-based mitochondria Electron transport complex IV inhibitor, β-ketonitrile derivative mitochondrial electron transport complex II inhibitor, diamide-based ryanodine receptor modulator, natural enemy insect/mite/nematode biopesticide, microbial biopesticide, stigma blocker Pesticides, pheromones, azadirachtin, benzomates (benzoximates), bifenazates, phenisobromorates (bromopropylates), quinoxalines (quinomethionates), sodium aluminum fluoride, quercene (such as dicofol), pyridalyl, pyrifruquinazone, sulfur, ferric phosphate, metaldehyde and 1,3 - an insecticide selected from the group consisting of dichloropropene;
Acylalanine PA fungicides (phenylamides), oxazolidinone PA fungicides (phenylamides), butyrolactone PA fungicides (phenylamides), hydroxy(2-amino-)pyrimidines, isoxazole aromatic hetero rings, isothialone-based aromatic heterocycles, carboxylic acids, benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), thiophanate-based MBC fungicides (methylbenzimidazole carbamate), N-phenyl carbamates, toluamide-based benzamides, Ethylaminothiazolecarboxamide-based thiazolecarboxamides, phenylureas, pyridinylmethylbenzamide-based benzamides, pyrimidineamines, pyrazolecarboxamides, phenylbenzamide-based SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furancarboxamide SDHI (succinate dehydrogenase inhibitor), oxathiincarboxamide SDHI (succinate dehydrogenase inhibitor) acid dehydrogenase inhibitor), thiazolecarboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor) agent), methoxyacrylate-based QoI fungicide (Qo inhibitor), methoxyacetamide-based QoI fungicide (Qo inhibitor), methoxycarbamate-based QoI fungicide (Qo inhibitor), oximinoacetic acid-based QoI fungicide (Qo inhibitor) , oximinoacetamide-based QoI fungicides (Qo inhibitors), oxazolidinedione-based QoI fungicides (Qo inhibitors), dihydrodioxazine-based QoI fungicides (Qo inhibitors), imidazolinone-based QoI fungicides (Qo inhibitors) , benzylcarbamate QoI fungicide (Qo inhibitor), cyanoimidazole QiI fungicide (Qi inhibitor), sulfamoyltriazole QiI fungicide (Qi inhibitor), dinitrophenylcrotonic acids, 2,6-dinitroaniline triphenyltin compound-based organotin compounds, thiophenecarboxamides, triazolopyrimidylamine-based QoSI fungicides (Qo inhibitors, stigmaterin-binding type), anilinopyrimidine-based AP fungicides (anilinopyrimidines), enopyranurone acid antibiotics, hexopyranosyl antibiotics, glucopyranosyl antibiotics, tetracycline antibiotics, allyloxyquinoline aza-naphthalenes, quinazolinone aza-naphthalenes, phenylpyrrole PP fungicides (phenylpyrroles), dicarboximides, phospho Lothiolates, dithiolanes, aromatic hydrocarbon AH fungicides (including aromatic hydrocarbons, chlorophenyls, nitroanilines), 1,2,4-thiadiazole heteroaromatics, carbamates, Bacillus and Produced fungicidal lipopeptide-based microorganisms (Bacillus genus), terpene hydrocarbons and terpene alcohol-based plant extracts, piperazine-based DMI fungicides (demethylation inhibitors, SBI: Class I), pyridine-based DMI fungicides ( demethylation inhibitor, SBI: class I), pyrimidine-based DMI fungicide (demethylation inhibitor, SBI: class I), imidazole-based DMI fungicide (demethylation inhibitor, SBI: class I), triazole DMI fungicide (demethylation inhibitor, SBI: class I), triazolinethione-based DMI fungicide (demethylation inhibitor, SBI: class I), morpholine amines (morpholines, SBI: class II ), piperidine-based amines (morpholines, SBI: class II), spiroketalamine-based amines (morpholines, SBI: class II), hydroxyanilides (SBI: class III), aminopyrazolinone-based compounds (SBI: Class III), thiocarbamates (SBI: Class IV), allylamines (SBI: Class IV), glucopyranosyl antibiotics, peptidylpyrimidine nucleoside polyoxins, cinnamic acid amide CAA fungicides (carboxylic acid amides) , valinamide carbamate-based CAA fungicides (carboxylic acid amides), mandelic acid amide-based CAA fungicides (carboxylic acid amides), isobenzofuranone-based MBI-R (melanin biosynthesis inhibitor-reductase), pyrroloquinolinone-based MBI -R (melanin biosynthesis inhibitor-reductase), triazolobenzothiazole-based MBI-R (melanin biosynthesis inhibitor-reductase), cyclopropanecarboxamide-based MBI-D (melanin biosynthesis inhibitor-dehydratase), Carboxamide-based MBI-D (melanin biosynthesis inhibitor - dehydratase), propionamide-based MBI-D (melanin biosynthesis inhibitor - dehydratase), benzothiadiazoles, Ben Zoisothiazoles, thiadiazolecarboxamides, polysaccharide natural products, plant extracts, cyanoacetamide oximes, ethylphosphonate-based phosphonates, phosphonates, phthalamic acids, benzotriazines, benzenesulfonamides, pyridazinones, thiocarbamates compounds, phenylacetamide compounds, benzophenone-based allyl phenyl ketone compounds, benzoylpyridine-based allyl phenyl ketone compounds, guanidines, cyanomethylenethiazolidine-based thiazolidine compounds, pyrimidinone hydrazones, piperidinylthiazole isoxazolines, acetic acid 4-quinoline compounds , inorganic compounds, dithiocarbamates and their analogs, phthalimides, chloronitriles (phthalonitriles), sulfamides, guanidines, triazines, quinones (anthraquinones), quinoxalines, maleimides, physical inhibitors , bicarbonate agents, silver agents, organic copper agents and soil disinfectants;
or allyloxypropionate-based acetyl-CoA carboxylase (ACCase) inhibitor, cyclohexanedione-based acetyl-CoA carboxylase (ACCase) inhibitor, phenylpyrazoline-based acetyl-CoA carboxylase (ACCase) inhibitor, sulfonylurea-based acetolactate synthase (ALS) inhibitor (acetohydroxy acid synthase (AHAS) inhibitor), imidazolinone-based acetolactate synthase (ALS) inhibitor (acetohydroxy acid synthase (AHAS) inhibitor), triazolopyrimidine-based acetolactate synthase (ALS) ) inhibitor (acetohydroxyacid synthase (AHAS) inhibitor), pyrimidinyl (thio)benzoate-based acetolactate synthase (ALS) inhibitor (acetohydroxyacid synthase (AHAS) inhibitor), sulfonylaminocarbonyltriazolinone acetolactate synthase (ALS) inhibitor (acetohydroxy acid synthase (AHAS) inhibitor), triazine photosynthesis (photosystem II) inhibitor, triazinone photosynthesis (photosystem II) inhibitor, triazolinone photosynthesis (photochemical system II) inhibitors, uracil photosynthesis (photosystem II) inhibitors, pyridazinone photosynthesis (photosystem II) inhibitors, phenylcarbamate photosynthesis (photosystem II) inhibitors, urea photosynthesis (photosystem II) inhibitors , amide-based photosynthesis (photosystem II) inhibitor, nitrile-based photosynthesis (photosystem II) inhibitor, benzothiadiazinon-based photosynthesis (photosystem II) inhibitor, phenylpyridazine-based photosynthesis (photosystem II) inhibitor, bipyridylium photochemical system I electron conversion agent, diphenyl ether protoporphyrinogen oxidase (PPO) inhibitor, phenylpyrazole protoporphyrinogen oxidase (PPO) inhibitor, N-phenylphthalimide protoporphyrinogen oxidase ( PPO) inhibitors, thiadiazole-based protoporphyrinogen oxidase (PPO) inhibitors, oxadiazole-based protoporphyrinogen oxidase (PPO) inhibitors, triazolinone-based protoporphyrinogen oxidase (PPO) inhibitors, oxazolidines dione-based protoporphyrinogen oxidase (PPO) inhibitor, pyrimidinedione-based protoporphyrinogen oxidase (PPO) inhibitor, protoporphyrinogen oxidase (PPO) inhibitor, pyridazinone-based phytoene desaturase system (PDS) ) inhibits carotenoid biosynthesis Toxins, pyridinecarboxamide-based carotenoid biosynthesis inhibitors at the phytoene desaturase system (PDS), carotenoid biosynthesis inhibitors at the phytoene desaturase system (PDS), triketone-based 4-hydroxyphenylpyruvate dioxygenase enzymes ( 4-HPPD) inhibitors, isoxazole-based 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors, pyrazole-based 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors, 4-hydroxyphenyl pyruvate dioxygenase enzyme (4-HPPD) inhibitor, triazole carotenoid biosynthesis (target site unknown) inhibitor, isoxazolidinone carotenoid biosynthesis (target site unknown) inhibitor, urea carotenoid biosynthesis (target site unknown) inhibitors, diphenyl ether-based carotenoid biosynthesis inhibitors (target site unknown), glycine-based EPSP synthase inhibitors, phosphinic acid-based glutamine synthetase inhibitors, carbamate-based DHP (dihydropteroic acid) synthase inhibitors, dinitroaniline microtubule polymerization inhibitor, phosphoramidate microtubule polymerization inhibitor, pyridine microtubule polymerization inhibitor, benzamide microtubule polymerization inhibitor, benzoic acid microtubule polymerization inhibitor, carbamate mitosis/microtubule formation inhibitor, chloroacetamide-based VLCFA inhibitor (cytostatic agent), acetamide-based VLCFA inhibitor (cytostatic agent), oxyacetamide-based VLCFA inhibitor (cytostatic agent), tetrazolinone-based VLCFA inhibitor agent (cytostatic agent), inhibitor of VLCFA (cytostatic agent), nitrile-based cell wall (cellulose) synthesis inhibitor, benzamide-based cell wall (cellulose) synthesis inhibitor, triazolocarboxamide-based cell wall (cellulose) synthesis inhibitor , quinoline carboxylic acid-based cell wall (cellulose) synthesis inhibitor, dinitrophenol-based uncoupling (membrane disruption) agent, thiocarbamate-based lipid synthesis inhibitor (non-ACCase inhibitor), phosphorodithioate-based lipid synthesis inhibitor (non-ACCase inhibitor ) agent, benzofuran-based lipid synthesis inhibitor (non-ACCase inhibitor) agent, chlorocarbonate-based lipid synthesis inhibitor (non-ACCase inhibitor) agent, phenoxycarboxylic acid-based indoleacetic acid-like activity (synthetic auxin) agent, benzoic acid-based indoleacetic acid-like activity ( synthetic auxin) agent, pyridinecarboxylic acid-based indoleacetic acid-like active (synthetic auxin) agent, quinolinecarboxylic acid-based India Indoleacetic acid-like active (synthetic auxin) agents, indoleacetic acid-like active (synthetic auxin) agents, phthalamate-type auxin transfer inhibitors, semicarbazone-type auxin transfer inhibitors, arylaminopropionic acid compounds, pyrazolium compounds, organic arsenic compounds , Microorganisms, Bromobutide, (Chlor)-Furrenol, Cymmethylin, Cumyluron, Dazomet, Daimuron, Methyldaimuron, Etobenzanide, Fosamine, Indanophan, Carbam/Carbam Sodium Salt, Oxadichromefone, Oleic Acid, Pelargonic Acid, Pirbuticarb, Chlorate and Cyanide The formulation according to any one of (1) to (5), which is a herbicide selected from the group consisting of acid salts.

(6-1) The pesticide is a carbamate acetylcholinesterase (AChE) inhibitor, an organophosphorus acetylcholinesterase (AChE) inhibitor, a phenylpyrazole (fiprole) GABAergic chloride ion channel antagonist, a pyrethroid or a pyrethrin sodium channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, spinosynnic nicotinic acetylcholine receptor (nAChR) allosteric modulators, avermectin and milbemycin class chloride channel activators, chordotonal modulators, oxidative phosphorylation desensitizers Coupling agents, mitochondrial electron transport chain complex III inhibitors, mitochondrial electron transport chain complex I inhibitors (METI), voltage-dependent sodium channel blockers, tetronic acid and tetramic acid derivative acetyl-CoA carboxylase inhibitors, diamide-based ryanodine receptors pesticides selected from the group consisting of modulators, quinoxalines (quinomethionates), pyridalyl and metaldehyde;
Or acylalanine-based PA fungicides (phenylamides), oxazolidinone-based PA fungicides (phenylamides), butyrolactone-based PA fungicides (phenylamides), isoxazole-based aromatic heterocycles, benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), N-phenyl carbamates, phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furancarboxamide-based SDHI (succinate dehydrogenase inhibitor), oxathiincarboxamide-based SDHI (succinate dehydrogenase inhibitor), thiazolecarboxamide-based SDHI (succinate dehydrogenase inhibitor) inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxyacetamide QoI fungicide (Qo inhibitor), methoxycarbamate QoI fungicide (Qo inhibitor), oximinoacetic acid QoI fungicide (Qo inhibitor), oximinoacetamide QoI fungicide (Qo inhibitor), oxazolidinedione QoI Fungicide (Qo inhibitor), dihydrodioxazine QoI fungicide (Qo inhibitor), imidazolinone QoI fungicide (Qo inhibitor), benzylcarbamate QoI fungicide (Qo inhibitor), cyanoimidazole QiI fungicide agent (Qi inhibitor), sulfamoyltriazole-based QiI fungicide (Qi inhibitor), 2,6-dinitroanilines, anilinopyrimidine-based AP fungicide (anilinopyrimidines), phenylpyrrole-based PP fungicide ( phenylpyrroles), dicarboximides, piperazine-based DMI fungicides (demethylation inhibitors, SBI: class I), pyridine-based DMI fungicides (demethylation inhibitors, SBI: class I), pyrimidine-based DMI fungicides agent (demethylation inhibitor, SBI: class I), imidazole-based DMI fungicide (demethylation inhibitor, SBI: class I), triazole-based DMI fungicide (demethylation inhibitor, SBI: class I) , triazolinethione-based DMI fungicide (demethylation inhibitor, SBI: Class I), isobenzofuranone-based MBI-R (melanin biosynthesis inhibitor-reductase), pyrroloquinolinone system MBI-R (melanin biosynthesis inhibitor-reductase), triazolobenzothiazole system MBI-R (melanin biosynthesis inhibitor-reductase), cyclopropanecarboxamide system MBI-D (melanin biosynthesis inhibitor-dehydratase ), carboxamide-based MBI-D (melanin biosynthesis inhibitor - dehydratase), propionamide-based MBI-D (melanin biosynthesis inhibitor - dehydratase), benzothiadiazoles, benzoisothiazoles, thiadiazolecarboxamides, cyanoacetamide The formulation according to any one of (1) to (6)), which is a fungicide selected from the group consisting of oximes, benzenesulfonamides, pyridazinones, guanidines and quinoxalines.

(6-2) The pesticide is a carbamate acetylcholinesterase (AChE) inhibitor, an organophosphorus acetylcholinesterase (AChE) inhibitor, a phenylpyrazole (fiprole) GABAergic chloride ion channel antagonist, a pyrethroid or a pyrethrin sodium from the group consisting of channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, oxidative phosphorylation uncouplers, avermectin and milbemycin class chloride channel activators, chordotonal modulators and diamide ryanodine receptor modulators. selected pesticides;
Or isoxazole aromatic heterocycles, benzimidazole MBC fungicide (methylbenzimidazole carbamate), phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide-based SDHI (succinate dehydrogenase inhibitor), furancarboxamide-based SDHI (succinate dehydrogenase inhibitor), oxathiincarboxamide-based SDHI (succinate dehydrogenase inhibitor), Thiazole carboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxyacetamide-based QoI fungicide (Qo inhibitor), methoxycarbamate-based QoI fungicide (Qo inhibitor), oximinoacetic acid-based QoI fungicide (Qo inhibitor), oximinoacetamide-based QoI fungicide ( Qo inhibitor), oxazolidinedione-based QoI fungicide (Qo inhibitor), dihydrodioxazine-based QoI fungicide (Qo inhibitor), imidazolinone-based QoI fungicide (Qo inhibitor), benzyl carbamate-based QoI fungicide (Qo inhibitor), piperazine-based DMI fungicide (demethylation inhibitor, SBI: class I), pyridine-based DMI fungicide (demethylation inhibitor, SBI: class I), pyrimidine-based DMI fungicide (demethylation inhibitor agent, SBI: Class I), imidazole-based DMI fungicides (demethylation inhibitors, SBI: Class I), triazole-based DMI fungicides (demethylation inhibitors, SBI: Class I) and triazolinethione-based DMI fungicides agent (demethylation inhibitor, SBI: Class I), the formulation according to any one of (1) to (6-1).

(6-3) pesticides include aldicarb, bendiocarb, butocaboxim, butoxycarboxim, NAC (carbaryl), carbofuran, ethiophenecarb, BPMC (phenocarb), formethanate, MIPC (isoprocarb), methomyl, MTMC (metolcarb), Oxamyl, pirimicarb, PHC (propoxur), thiophanox, triazamate, XMC, MPMC (xylylcarb), acephate, azamethifos, cassaphos, CVP (chlorfenbinphos), dimetone-S-methyl, DDVP (dichlorvos), dicrotophos, dimethoate , dimethylvinphos, etoprophos, fenamiphos, fosthiazate, heptenophos, marathon (malathion), mecarbam, methamidophos, DMTP (methidathion), mevinphos, monocrotophos, omethoate, oxydimethone methyl, phosphamidone, propetamphos, thiomethone, DEP (trichlorfon), bamidothion , flumethrin, fipronil, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, nicotine sulfate (nicotine), sulfoxaflor, flupyradifuron, pyriproxyfen, methyl bromide (methyl bromide), chloropicrin, sulfuryl fluoride, borax, Tartar emetic, pymetrozine, flonicamid, BPPS (propargite), DNOC, cartap, thiocyclam, thiosultap sodium salt, cyromazine, hydrogen phosphide, hydrocyanic acid, azadirachtin, sodium aluminum fluoride, 1,3-dichloropropene, dicyclanil, ethylene an insecticide selected from the group consisting of dibromide, sabadilla and sulcofuron sodium;
or furalaxyl, metalaxyl, metalaxyl M, oxadixyl, ofrace, dimethymol, hydroxyisoxazole (hymexazole), octhilinone, fenfram, carboxin, oxycarboxin, furametpyr, metminostrobin, cyazofamide, pyrimethanil, kasugamycin, streptomycin, IBP (iprobenfos) ), eclomezole (ethridiazole), propamocarb, prothiocarb, pyrifenox, imazalil, pefurazoate, triflumizole, flutriafol, microbutanil, propiconazole, tetraconazole, fenpropidine, spiroxamine, validamycin, polyoxin, iprovalicarb, pyroquilone , cymoxanil, fosetyl, phosphorous acid and salts, fursulfamide, metasulfocarb, guanidine (dodine), ferimzone, potassium bicarbonate, furbum, guazatin, iminoctadine acetate/iminoctadine albesilate (iminoctadine), copper sulfate, formaldehyde, A fungicide selected from the group consisting of 8-hydroxyquinoline sulfate, iodomethane, mercuric chloride, metam, methyl bromide, methyl isothiocyanate, mildiomycin, navum, phenylmercuric acetate, 2-phenylphenol and poloxine. A formulation according to any one of (1) to (6-2).

(6-4) Any of (1) to (6-3), wherein the pesticide is at least one selected from the group consisting of acephate, fipronil, acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam, nitenpyram and flonicamid. or one formulation.

(6-5) Any one of (1) to (6-4), wherein the pesticide is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram 1. A formulation according to one.

(6-6) Any one of (1) to (6-5), wherein the pesticide is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran and thiamethoxam is a formulation of

(6-7) The formulation according to any one of (1) to (6-6), wherein the pesticide is dinotefuran.

(7) The formulation according to any one of (1) to (6), wherein the pesticide content is 0.01% by weight to 10% by weight.

(8) The slow-release granular fertilizer is a slow-release mixed granular fertilizer, a chemically synthesized slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressurized granular fertilizer, or a slow-release nitration inhibitor compounded fertilizer. The formulation according to any one of (1) to (7).

(9) The slow-release granular fertilizer contains essential plant elements such as nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), The formulation according to any one of (1) to (8), containing any one or more fertilizer components selected from the group consisting of calcium (Ca) and sulfur (S).

(9-1) The slow-release granular fertilizer contains, as essential plant elements, at least two fertilizer components selected from the group consisting of nitrogen (N), phosphorus (P) and potassium (K), (8 ) or (9).

(9-2) Any one of (8) to (9-1), wherein the slow-release granular fertilizer contains nitrogen (N), phosphorus (P) and potassium (K) as essential plant elements. 1. A formulation according to one.

(9-3) A group of slow-release granular fertilizers further comprising iron (Fe), copper (Cu), zinc (Zn), molybdenum (Mo), cobalt (Co) and chlorine (Cl) as essential plant elements The formulation according to any one of (8) to (9-2), containing any one or more fertilizer components selected from

(10) The slow-release granular fertilizer according to (9), which contains nitrogen (N), phosphorus (P) and potassium (K) as essential plant elements in a ratio of guaranteed component amounts of 3:20:3. It is a formulation.

(11) The slow-release granular fertilizer according to (9), which contains nitrogen (N), phosphorus (P) and potassium (K) as essential plant elements in a guaranteed component amount ratio of 2:5:2. It is a formulation.

(12) The formulation according to any one of (8) to (11), wherein the slow-release granular fertilizer content is 0.1% to 99.9% by weight.

(13) The formulation according to any one of (1) to (7), wherein the content of the non-petroleum solvent is 0.1% by weight to 10% by weight.

(14) The content of agricultural chemicals is 0.01% to 10% by weight, the content of non-petroleum solvent is 0.1% to 10% by weight, and the content of slow-release granular fertilizer is 0.1% by weight. The formulation according to any one of (1) to (13), which is ~99.9% by weight.

(15) The content of pesticides is 0.03% to 5% by weight, the content of non-petroleum solvent is 0.1% to 10% by weight, and the content of slow-release granular fertilizer is 50.0% by weight. The formulation according to (14), which is ~99.8% by weight.

(16) Use of the formulation according to any one of (1) to (15) for agricultural gardening or home gardening.

The pesticide-containing slow-release granular fertilizer formulation of the present invention is essentially different from the usual soluble chemical fertilizers used in Patent Documents 2 and 3 in terms of elution of fertilizer components.
In addition, the slow-release granular fertilizer formulation containing agrochemicals of the present invention belongs to the classification of inorganic fertilizers containing inorganic compounds as the main component, and can be produced using, in particular, chemically synthesized chemical fertilizers as raw materials.

According to the present invention, a slow-release granular fertilizer pesticide that does not cause phytotoxicity to plants, that is, a slow-release granular fertilizer formulation containing an agrochemical in which deposition of agricultural chemical components or fertilizer components and decomposition/separation of the above components are suppressed are provided. can provide.

Various terms used in this specification are explained.
In this specification, the numerical range indicated using "to" indicates the range including the numerical values before and after "to" as the minimum and maximum values, respectively. Furthermore, the content of each component in the composition means the total amount of the multiple substances present in the composition unless otherwise specified when there are multiple substances corresponding to each component in the composition.

“Agricultural chemicals” are fungi, nematodes, mites, insects, mice and other animals, plants, or viruses (hereinafter referred to as “pests”) that damage agricultural crops (including trees and agricultural and forestry products; hereinafter referred to as “crops, etc.”). Fungicides, insecticides, and other agents used for control (including materials using such agents as raw materials or materials for such control), and plant growth regulators used to enhance or suppress the physiological functions of crops, etc. However, agricultural chemicals are not particularly limited as long as they are used for agriculture, and any chemical can be used, including insecticides, fungicides and herbicides. may be Specific examples of pesticides include alanicarb, aldicarb, bendiocarb, benfuracarb, butocaboxim, butoxycarboxim, NAC (carbaryl), carbofuran, carbosulphan, ethiofencarb, BPMC (fenobcarb), formethanate, furatiocarb, MIPC ( carbamate acetylcholinesterase (AChE) inhibitors such as isoprocarb), methiocarb, methomyl, MTMC (metolcarb), oxamyl, pirimicarb, PHC (propoxur), thiodicarb, thiophanox, triazamate, trimetacarb, XMC, MPMC (xylylcarb), acephate , Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Cadusaphos, Chlorethoxyphos, CVP (Chlorfenvinphos), Chlormephos, Chlorpyrifos, Chlorpyrifos-methyl, Coumaphos, CYAP (Cyanophos), Dimethone-S-methyl, Diazinon DDVP (Dichlorvos), Dicrotophos, Dimethoate, Dimethyl Vinphos, ethylthiomethone (disulfotone), EPN, ethione, ethprophos, fanfur, fenamiphos, MEP (fenitrothion), MPP (fenthion), fosthiazate, heptenophos, imishiaphos, isofenphos, isopropyl-o-(methoxyaminothiophosphoryl) salicylate, isoxathion , marathon (malathion), mecarbam, methamidophos, DMTP (methidathion), mevinphos, monocrotophos, BRP (naled), omethoate, oxydimethone-methyl, parathion, methylparathion (parathion-methyl), PAP (phenthoate), folate, fosarone, PMP ( phosmet), phosphamidone, phoxime, pyrimiphos-methyl, propenophos, propetamphos, prothiophos, pyraclophos, pyridafenthion, quinalphos, sulfotep, tebupyrimphos, temefos, terbufos, CVMP (tetrachlorbinphos), thiometone, triazophos, DEP (trichlorfon), vamidothion, and other organic compounds Phosphorus-based acetylcholinesterase (AChE) inhibitors, chlordane, cyclic diene organochlorine GABAergic chloride channel antagonists such as benzoepine (endosulfan), acrinathrin, allethrin (allethrin, d-cis-trans-, d-trans-isomer ), bifenthrin, bioallethrin (biorethrin, S-cyclopentenyl-isomer), bioresmethrin, cycloprothrin, cyfluthrin (cyfluthrin, β-isomer), cyhalothrin (cyhalothrin, λ-, γ-isomer), cypermethrin (cypermethrin, α-, β-, θ-, ζ-isomers), cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [(EZ)-(1R)-isomer], esfenvalerate, etofenprox , fenpropathrin, fenvalerate, flucythrinate, flumethrin, fluvalinate (τ-fluvalinate), halfenprox, imiprothrin, cadethrin, permethrin, phenothrin [(1R)-trans isomer], prallethrin, pyrethrin, resmethrin, Pyrethroid and pyrethrin sodium channel modulators such as silafluofen, tefluthrin, phthalthrin (tetramethrin), tetramethrin [(1R)-isomer], tralomethrin, transfluthrin, sodium channel modulators such as DDT, methoxychlor, acetamiprid, clothianidin, dinotefuran, Neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists such as imidacloprid, nitenpyram, thiacloprid and thiamethoxam; nicotinic acetylcholine receptor (nAChR) agonists such as nicotine sulfate (nicotine) and sulfoxaflor; butenolide nicotinic acetylcholines such as flupyradifuron receptor (nAChR) agonists, spinosyn-type nicotinic acetylcholine receptor (nAChR) allosteric modulators such as spinetoram, spinosad, avermectin- and milbemycin-type chloride channel activators such as abamectin, emamectin benzoate, lepimectin, milbemectin, hydroprene, Juvenile hormone analogues such as quinoprene, methoprene, fenoxycarb, pyriproxyfen, methyl bromide (methyl bromide), alkyl halides other than methyl bromide, chloropicrin, sulfuryl fluoride, borax, tartar emetic, etc. non-specific (multi-site) inhibitors, chordotonal modulators such as pymetrozine and flonicamid, mite growth inhibitors such as clofentezine, hexythiazox, diflovidazine, etoxazole;B. t. subsp. israelensis, B. t. subsp. aizawai, B. t. subsp. kurstaki, B.; t. subsp. tenebrionis and B. t. Proteins contained in crops (Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry34Ab1/Cry35Ab1), microorganism-derived insect midgut membrane disruptors such as Bacillus sphaericus, diafenthiuron, azocyclotin, Mitochondrial ATP synthase inhibitors such as tricyclohexyltin hydroxide (cyhexatin), fenbutatin oxide, BPPS (propargite), tetradifon, oxidative phosphorylation uncouplers such as chlorfenapyr, DNOC, sulfluramide, bensultap, cartap, thiocyclam, thiosulphate. Nicotinic acetylcholine receptor (nAChR) channel blockers, bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaruron, noviflumuron , teflubenzuron, triflumuron and other benzoyl urea-based chitin biosynthesis inhibitors (type 0), buprofezin and other chitin biosynthesis inhibitors (type 1), cyromazine and other fly insect moulting inhibitors, chromafenozide, halofenozide, methoxyfenozide, tebufenozide, etc. diacyl-hydrazine molting hormone (ecdysone) receptor agonists, octopamine receptor agonists such as amitraz, mitochondrial electron transport complex III inhibitors such as hydramethylnone, acequinosyl, fluacrypyrim, fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad , tolfenpyrad, mitochondrial electron transport chain complex I inhibitors (METI) such as delis (rotenone), voltage-gated sodium channel blockers such as indoxacarb and metaflumizone, tetorones such as spirodiclofen, spiromesifen, and spirotetramat Acid and tetramic acid derivatives Acetyl-CoA carboxylase inhibitors, phosphine-based mitochondrial electron transport complex IV inhibitors such as aluminum phosphide, calcium phosphide, hydrogen phosphide and zinc phosphide, cyanide-based mitochondrial electron transport complexes such as hydrocyanic acid beta-ketonitrile derivatives such as cyenopyrafen, cyflumetofen, etc. Mitochondrial electron transport chain complex II inhibitors, chlorantraniliprole, cyantranili Prole, diamide-based ryanodine receptor modulators such as flubendiamide, Steinernema capocapsae, Amblyseius californica, Amblyseius cucumeris, Dermatophyllum spp. Natural enemy insects, mites, and nematode-based biological pesticides such as leafhopper wasps and leafhoppers, Pasteuria penetrans, Bacillus thuringiensis (BT), Monaclosporium fimatopagum, Pechyromyces tenuipes, Beauveria brongniati, Beauveria bassiana, etc. Microbial biopesticides, starch, reduced starch saccharification products, machine oil, stigma blockage type pesticides such as sodium oleate, Konagakon-Plus, Confuser G, Confuser N, Confuser V, Sukarashibakon, Nitrure (Ameshiro), Hamakikon-N, Pheromones such as Pheodin SL, Spodoptera-H, Spodoptera-S, azadirachtin, benzomates (benzoximate), bifenazate, phenisobromorate (bromopropylate), quinoxaline (quinomethionate), sodium aluminum fluoride, quercene (dicofol ), pyridalyl, pyrifluquinazone, sulfur, ferric phosphate, metaldehyde and 1,3-dichloropropene;
Acylalanine-based PA fungicides (phenylamides) such as benalaxyl, benalaxyl M, furalaxyl, metalaxyl, and metalaxyl M; oxazolidinone-based PA fungicides (phenylamides) such as oxadixyl; ), hydroxy(2-amino-)pyrimidines such as bupirimate, dimethylmol, ethylimol, isoxazole aromatic heterocycles such as hydroxyisoxazole (hymexazole), isothiazolone aromatic heterocycles such as octylinone, oxolinic carboxylic acids such as acids, benomyl, carbendazole (carbendazim), fuberidazole, thiabendazole and other benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), thiophanate, thiophanate-methyl and other thiophanate-based MBC fungicides (methylbenzimidazole carbamate), N-phenyl carbamates such as diethofencarb, toluamide benzamides such as zoxamide, ethylaminothiazole carboxamide thiazole carboxamides such as ethaboxam, phenyl ureas such as pencicron, pyridinylmethylbenzamide benzamides such as fluopicolide, diflumetrim pyrimidine amines such as tolfenpyrad, pyrazole carboxamides such as tolfenpyrad, phenylbenzamide SDHIs (succinate dehydrogenase inhibitors) such as benodanil, flutolanil, and mepronil, phenyloxoethylthiophenamide SDHIs such as isofetamide (succinate dehydrogenation enzyme inhibitors), pyridinylethylbenzamide-based SDHIs (succinate dehydrogenase inhibitors) such as fluopyram, furancarboxamide-based SDHIs (succinate dehydrogenase inhibitors) such as fenfram, carboxin, oxycarboxin, etc. oxathiincarboxamide-based SDHIs (succinate dehydrogenase inhibitors), thiazole carboxamide-based SDHIs (succinate dehydrogenase inhibitors) such as thifluzamide, benzovindiflupyr, bixafen, fluxapyroxad, furametpyr, isopyrazam, penflufen, Pyrazole-4-carboxamide SDHIs (succinate dehydrogenase inhibitors) such as penthiopyrad and sedaxane, pyridinecarboxamide SDHIs (succinate dehydrogenase inhibitors) such as Boscalid, Azoxys Methoxyacrylate QoI fungicides (Qo inhibitors) such as thrombin, comoxistrobin, enoxastrobin, fluphenoxystrobin, picoxystrobin, pyraoxystrobin, methoxyacetamide QoI fungicides such as mandestrobin (Qo inhibitors), methoxycarbamate QoI fungicides (Qo inhibitors) such as pyraclostrobin, pyrametostrobin, and triclopiricarb, oximinoacetic acid QoI fungicides (Qo inhibitors) such as kresoxime methyl and trifloxystrobin ), oximinoacetamide QoI fungicides (Qo inhibitors) such as dimoxystrobin, phenaminestrobin, metminostrobin, orysastrobin, oxazolidinedione QoI fungicides (Qo inhibitors) such as famoxadone, fluoxastrobin Dihydrodioxazine-based QoI fungicides (Qo inhibitors) such as, imidazolinone-based QoI fungicides (Qo inhibitors) such as Fenamidone, benzylcarbamate-based QoI fungicides (Qo inhibitors) such as pyribencarb, cyano such as Cyazofamide Imidazole-based QiI fungicides (Qi inhibitors), sulfamoyltriazole-based QiI fungicides (Qi inhibitors) such as amisulbrom, BINAPACRIL (binapacryl), meptyldinocap, DPC (dinocap) and other dinitrophenyl crotonic acids, fluazinam 2,6-dinitroanilines such as triphenyltin acetate, triphenyltin chloride, triphenyltin hydroxide and other organic tin compounds, thiophenecarboxamides such as silthiopham, triazolopyrimidinium such as amethoctrazine luamine-based QoSI fungicides (Qo inhibitors, stigmatelin-binding type), anilinopyrimidine-based AP fungicides (anilinopyrimidines) such as cyprodinil, mepanipyrim, pyrimethanil, enopyranuronic acid antibiotics such as blasticidin S, kasugamycin, etc. hexopyranosyl antibiotics, glucopyranosyl antibiotics such as streptomycin, tetracycline antibiotics such as oxytetracycline, allyloxyquinoline aza-naphthalenes such as quinoxyphene, quinazolinone aza-naphthalenes such as proquinazid, phenylpyrrole PPs such as fenpicronil and fludioxonil Fungicides (phenylpyrroles), clozolinate, iprodione, procymidone, vink Dicarboximides such as rosolin, EDDP (edifenphos), IBP (iprobenfos), phosphorothiolates such as pyrazophos, dithiolanes such as isoprothiolane, biphenyl, chloroneb, CNA (dichlorane), PCNB (quintozene), technazene, tolclofos Aromatic hydrocarbon-based AH fungicides such as methyl (aromatic hydrocarbons, chlorophenyls, nitroanilines), 1,2,4-thiadiazole-based heteroaromatics such as eclomezol (ethridiazole), iodocarb, propamocarb, prothiocarb, etc. Carbamates, Bacillus subtilis QST713 strain, Bacillus subtilis FZB24 strain, Bacillus subtilis MBI600 strain, Bacillus subtilis D747 strain and other Bacillus genus and produced bactericidal lipopeptide-based microorganisms (Bacillus genus), Gosseikajupte (tea tree) extract Terpene hydrocarbons and terpene alcohol plant extracts such as, piperazine DMI fungicides such as trifoline (demethylation inhibitor, SBI: Class I), pyrifenox, pyridine DMI fungicides such as pyrisoxazole (demethylation Pyrimidine-based DMI fungicides (demethylation inhibitors, SBI: Class I) such as fenarimol and nuarimol (demethylation inhibitors, SBI: Class I), imazalil, oxpoconazole, pefurazoate, prochloraz, imidazoles such as triflumizole DMI fungicides (demethylation inhibitors, SBI: Class I), azaconazole, bitertanol, bromconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, flu Triazole-based DMI fungicides (demethylated (demethylation inhibitor, SBI: Class I), triazolinethione-based DMI fungicides such as prothioconazole (demethylation inhibitor, SBI: Class I), morpholine-based amines such as aldimorph, dodemorph, fenpropimorph, tridemorph (morpholines, SBI: Class II), fenpropidi piperidine-based amines (morpholines, SBI: class II) such as piperaline, spiroketalamine-based amines (morpholines, SBI: class II) such as spiroxamine, hydroxyanilides (SBI) such as phenhexamide : Class III), aminopyrazolinone compounds such as fenpyrazamine (SBI: Class III), thiocarbamates such as piributicarb (SBI: Class IV), allylamines such as naftifine and terbinafine (SBI: Class IV), validamycin, etc. glucopyranosyl antibiotics, peptidylpyrimidine nucleoside polyoxins such as polyoxins, cinnamic acid amide CAA fungicides (carboxylic acid amides) such as dimethomorph, flumorph, and pyrimorph, and valinamides such as bentiavaricarb, iprovalicarb, and valifenalate Carbamate-based CAA fungicides (carboxylic acid amides), mandelic acid amide-based CAA fungicides (carboxylic acid amides) such as mandipropamide, isobenzofuranone-based MBI-R (melanin biosynthesis inhibitor-reductase) such as phthalide, Pyrroloquinolinone-based MBI-R (melanin biosynthesis inhibitor-reductase) such as pyroquilone, triazolobenzothiazole-based MBI-R (melanin biosynthesis inhibitor-reductase) such as tricyclazole, cyclopropanecarboxamide-based MBI-R such as carpropamide- D (melanin biosynthesis inhibitor-dehydratase), carboxamide-based MBI-D (melanin biosynthesis inhibitor-hydrase) such as diclosimet, propionamide-based MBI-D (melanin biosynthesis inhibitor-dehydratase) such as fenoxanyl Benzothiadiazoles such as acibenzolar-S-methyl, benzoisothiazoles such as probenazole, thiadiazole carboxamides such as thiazinyl and isotianil, polysaccharides natural products such as laminarin, plant extracts such as Olepis purpurea extract, cyanoacetamide oximes such as cymoxanil , ethylphosphonate-based phosphonates such as fosetyl, phosphonates such as phosphorous acid and its salts, phthalamic acids such as teclophthalam, benzotriazines such as triazoxide, benzenesulfonamides such as fursulfamide, pyridazinones such as diclomedine, thiocarbamate compounds such as metasulfocarb; phenylacetamide compounds such as cyflufenamide; benzophenone-based allyl phenyl ketone compounds such as non, benzoylpyridine-based allyl phenyl ketone compounds such as pyriophenone, guanidines such as guanidine (Dodine), cyanomethylenethiazolidine-based thiazolidine compounds such as flutianil, pyrimidinone hydrazones such as ferimzone, oxa Piperidinyl thiazole isoxazolines such as thiapiproline, 4-quinoline acetate compounds such as tebufloquine, copper (various salts), inorganic compounds such as sulfur, farbum, mancozeb, maneb, metiram, propineb, thiuram, zineb, ziram dithiocarbamates and their analogues such as captan, difortan (captafol), phthalimides such as folpet, chloronitriles (phthalonitriles) such as TPN (chlorothalonyl), sulfenic acids (diclofluanides), tolylfluanides sulfamides such as, guanidines such as guazatine, iminoctadine acetate/iminoctadine albesilate (iminoctazine), triazines such as triazine (aniladin), quinones such as dithianone (anthraquinones), quinoxalines (quinomethionate), etc. Quinoxalines, maleimides such as fluorimide, physical inhibitors such as machine oils and organic oils, bicarbonate agents such as potassium bicarbonate, silver agents, 8-hydroxyquinoline copper, dodecylbenzenesulfonic acid bisethylenediamine copper complex salt (II ), organic copper agents such as nonylphenol sulfonic acid copper salts, and soil disinfectants such as dazomet, chloropicrin, methyl isothiocyanate, carbam sodium salt, ammonium N-methyldithiocarbamate;
or allyloxypropionate-based acetyl-CoA carboxylase (ACCase) inhibitors such as clodinafop-propargyl, cyhalofop-butyl, diclofop-methyl, fenoxaprop-P-ethyl, fluazifop-P, haloxyfop-R-methyl, propaxafop, quizalofop-P-ethyl cyclohexanedione-based acetyl-CoA carboxylase (ACCase) inhibitors such as alloxydim, butroxydim, clethodim, cyclooxydim, profoxydim, sethoxydim, tepraloxydim, and tralkoxydim; phenylpyrazoline-based acetyl-CoA carboxylase (ACCase) inhibitors such as pinoxaden; Sulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfuron, etamethsulfuron-methyl, ethoxysulfuron, flazasulfuron, flupyrsulfuron, foramsulfuron, halosulfuron-methyl ,
imazosulfuron, iodosulfuron, mesosulfuron, metsulfuron-methyl, nicosulfuron, oxasulfuron, primisulfuron, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron , tribenuron-methyl, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron and other sulfonylurea-based acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), imazapic, imaza imidazolinone-type acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors) such as metabenzmethyl, imazamox, imazapyr, imazaquin, imazethapyr, cloransulam methyl, diclosulam, florasulam, flumetsulam, metosulam , triazolopyrimidine-based acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors) such as penoxuram, bispyribac-sodium salt, pyribenzoxime, pyriftalide, pyrithiobac-sodium salt, pyriminobac-methyl, etc. Sulfonylaminocarbonyltriazolinone acetolactates such as pyrimidinyl (thio)benzoate-based acetolactate synthase (ALS) inhibitors (acetohydroxy acid synthase (AHAS) inhibitors), flucarbazone-sodium salt, propoxycarbazone-sodium salt synthase (ALS) inhibitors (acetohydroxyacid synthase (AHAS) inhibitors), ametrine, atrazine, cyanazine, desmethrin, dimethamethrin, promethrin, promethrin, propazine series (propazine), CAT (simazine), simetryn, terbumetone, terbuthylazine triazine photosynthesis (photosystem II) inhibitors such as , terbutrin, and trietadine; triazinones photosynthesis (photosystem II) inhibitors such as hexazinone, metamitron, and metribuzine; triazolinone photosynthesis (photosystem II) inhibitors such as amicarbazone; , renacil, terbasil and other uracil photosynthesis (photosystem II) inhibitors, PAC (chloridazone) and other pyridazinone photosynthesis (photosystem II) inhibitors, desmedifam, phenmedifam and other phenylcarbamate photosynthesis (photosystem II) inhibitors II) inhibitors, chlorbromuron, chlorotoluron, chloroxuron, di Urea photosynthesis (photosystem II) inhibitors such as meflon, DCMU (diuron), ethidimuron, fenuron, fluometuron, isoproturon, isouron, linuron, metabenzthiazuron, metbromuron, metoxuron, monolinuron, nebulon, siduron, tebuthiuron, DCPA amide photosynthesis (photosystem II) inhibitors such as (propanyl) and CMMP (pentanochlor); nitrile photosynthesis (photosystem II) inhibitors such as bromophenoxime, bromoxynil and ioxynil; and benzothiadiazinones such as bentazone. photosynthesis (photosystem II) inhibitors, phenylpyridazine photosynthesis (photosystem II) inhibitors such as pyridate and pyridafol, bipyridylium photosystem I electron conversion agents such as diquat and paraquat, acifluorfen, biphenox, clomethoxynil ( diphenyl ether-type protoporphyrinogen oxidase (PPO) inhibitors such as chloromethoxyphene), fluoroglycofen-ethyl, fomesafen, halosafen, lactofen, and oxyflufen, and phenylpyrazole-type protoporphyrinogens such as fluazolate and pyraflufen-ethyl oxidase (PPO) inhibitors, N-phenylphthalimide-based protoporphyrinogen oxidase (PPO) inhibitors such as sinidone-ethyl, flumioxazin, and flumicrolacpentyl, and thiadiazole-based protoporphyrinogen oxidation such as fluthiacet-methyl and thidiazimine Enzyme (PPO) inhibitors, oxadiazole-based protoporphyrinogen oxidase (PPO) inhibitors such as oxadiazone and oxadiargyl, triazolinone-based protoporphyrinogen oxidases such as azaphenidine, carfentrazone-ethyl and sulfentrazone (PPO) inhibitors, oxazolidinedione protoporphyrinogen oxidase (PPO) inhibitors such as pentoxazone, pyrimidinedione protoporphyrinogen oxidase (PPO) inhibitors such as benzfenzizone, butaphenacyl, pyraclonil, protoporphyrinogen oxidase (PPO) inhibitors such as Protoporphyrinogen oxidase (PPO) inhibitors such as fluazole and flufenpyrethyl; pyridazinone carotenoid biosynthesis inhibitors in the phytoene desaturase system (PDS) such as norflurazon; pyridinecarboxamides such as diflufenican and picolinafen; Phytoene desaturase system (P carotenoid biosynthesis inhibitors in the DS), carotenoid biosynthesis inhibitors in the phytoene desaturase system (PDS) such as beflubutamide, fluridone, flurochloridone, flurutamone, triketones such as mesotrione and sulcotrione 4-hydroxyphenylpyruvate acid dioxygenase enzyme (4-HPPD) inhibitors, isoxazole-based 4-hydroxyphenylpyruvate dioxygenase enzyme (4-HPPD) inhibitors such as isoxachlortole, isoxaflutole, benzofenap, pyrazolate (pyrazolinate ), pyrazole-based 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitors such as pyrazoxifene, 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitors such as benzobicirone, ATA (amitrol) triazole-based carotenoid biosynthesis (target site unknown) inhibitors such as clomazone, isoxazolidinone-based carotenoid biosynthesis (target site unknown) inhibitors such as clomazone, urea-based carotenoid biosynthesis (target site unknown) inhibitors such as fluometuron, acronifene, etc. diphenyl ether-based carotenoid biosynthesis (target site unknown) inhibitors, glycine-based EPSP synthase inhibitors such as glyphosate, glyphosate trimesium salt (sulfosate), glufosinate, phosphinic acid-based glutamine synthase inhibitors such as bialaphos (vilanaphos), Carbamate DHP (dihydropteroic acid) synthase inhibitors such as Ashram, dinitroaniline microtubule polymerization inhibitors such as bethlogin (benfluralin), butruarin, dinitramine, ethalfluralin, oryzaline, pendimethalin, and trifluralin, amipro phosphoramidate-based microtubule polymerization inhibitors such as phosmethyl and butamiphos; pyridine-based microtubule polymerization inhibitors such as dithiopyr and thiazopyr; benzamide-based microtubule polymerization inhibitors such as propyzamide and tebutam; benzoic acid microtubule polymerization inhibitors, carbamate mitosis/microtubule formation inhibitors such as IPC (chlorpropham), propham, carbetamid, acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, metazachlor, metra Inhibitors of chloroacetamide-based VLCFAs such as chlor, petoxamide, pretilachlor, propachlor, propisochlor, and thenylchlor harmful agents (cytostatics), inhibitors of acetamide VLCFAs (cytostatics) such as difenamide, napropamide and naproanilide, inhibitors of oxyacetamide VLCFAs (cytostatics) such as flufenacet and mefenacet, Tetrazolinone-based VLCFA inhibitors (cytostatics) such as fentrazamide, VLCFA inhibitors (cytostatics) such as anilophos, caffenstrol, and piperophos, nitrile-based cell walls (cellulose ) synthesis inhibitors, benzamide-based cell wall (cellulose) synthesis inhibitors such as isoxaben, triazolocarboxamide-based cell wall (cellulose) synthesis inhibitors such as flupoxam, quinoline carboxylic acid-based cell wall (cellulose) synthesis inhibitors such as quinclorac, DNOC , DNBP (dinoseb), dinoterb and other dinitrophenol-based uncoupling (membrane disrupting) agents, butyrate, hexylthiocarbam (cycloate), dimepiperate, EPTC, esprocarb, molinate, orbencarb, pevrate, prosulfocarb, benchocarb (thiobencarb) ), thiocarbamate-based lipid synthesis inhibitors (non-ACCase inhibitors) such as thiocarbadil, trialate, and vernalate, phosphorodithioate-based lipid synthesis inhibitors (non-ACCase inhibitors) such as SAP (benzuride), benfuresate, ethofumesate, etc. benzofuran-based lipid synthesis inhibitors (non-ACCase inhibitors), TCA, DPA (dalapon), chlorocarbonate-based lipid synthesis inhibitors (non-ACCase inhibitors) such as tetrapion (flupropanate), clomeprop, 2,4-PA (2, 4-D), 2,4-DB, dichlorprop, MCPA, MCPB, MCPP (mecoprop) and other phenoxycarboxylic acid-based indoleacetic acid-like active (synthetic auxin) agents, chloramben, MDBA (dicamba), TCBA (2, benzoic acid-based indoleacetic acid-like active (synthetic auxin) agents such as 3,6-TBA), pyridinecarboxylic acid-based indoleacetic acid-like active (synthetic auxin) agents such as clopyralid, fluroxypyr, picloram, and triclopyr, quinclolac, quinmerac, etc. quinoline carboxylic acid-based indole acetic acid-like active (synthetic auxin) agents, indole acetic acid-like active (synthetic auxin) agents such as benazoline ethyl, phthalamenes such as NPA (naptalam) auxin migration inhibitors, semicarbazone auxin migration inhibitors such as diflufenzopyr sodium salt, arylaminopropionic acid compounds such as furanprop M methyl/isopropyl, pyrazolium compounds such as difenzocort, DSMA, MSMA, and the like. Organic arsenic compounds, microorganisms such as Xanthomonas campestris, bromobutide, (chlor)-flurenol, cymmethylin, cumyluron, dazomet, daimuron, methyldaimuron, etobenzanide, fosamine, indanophan, carbam/carbam sodium salt, oxadichromefone, oleic acid , pelargonic acid, piributicarb, chlorates and cyanates.

Among the pesticides are carbamate-based acetylcholinesterase (AChE) inhibitors, organophosphorus-based acetylcholinesterase (AChE) inhibitors, phenylpyrazole-based (fiprole-based) GABAergic chloride ion channel antagonists, pyrethroid- and pyrethrin-based sodium channel modulators, neonicotinoid nicotinic acetylcholine receptor (nAChR) agonists, spinosynnic nicotinic acetylcholine receptor (nAChR) allosteric modulators, avermectin and milbemycin chloride channel activators, chordotonal modulators, oxidative phosphorylation uncouplers, Mitochondrial electron transport chain complex III inhibitor, mitochondrial electron transport chain complex I inhibitor (METI), voltage-gated sodium channel blocker, tetronic acid and tetramic acid derivative acetyl-CoA carboxylase inhibitor, diamide-based ryanodine receptor modulator, quinoxaline (quinomethionates) and insecticides selected from the group consisting of pyridalyl and metaldehyde;
Or acylalanine-based PA fungicides (phenylamides), oxazolidinone-based PA fungicides (phenylamides), butyrolactone-based PA fungicides (phenylamides), isoxazole-based aromatic heterocycles, benzimidazole-based MBC fungicides (methylbenzimidazole carbamate), N-phenyl carbamates, phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furancarboxamide-based SDHI (succinate dehydrogenase inhibitor), oxathiincarboxamide-based SDHI (succinate dehydrogenase inhibitor), thiazolecarboxamide-based SDHI (succinate dehydrogenase inhibitor) inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI fungicide (Qo inhibitor), methoxyacetamide QoI fungicide (Qo inhibitor), methoxycarbamate QoI fungicide (Qo inhibitor), oximinoacetic acid QoI fungicide (Qo inhibitor), oximinoacetamide QoI fungicide (Qo inhibitor), oxazolidinedione QoI Fungicide (Qo inhibitor), dihydrodioxazine QoI fungicide (Qo inhibitor), imidazolinone QoI fungicide (Qo inhibitor), benzylcarbamate QoI fungicide (Qo inhibitor), cyanoimidazole QiI fungicide agent (Qi inhibitor), sulfamoyltriazole-based QiI fungicide (Qi inhibitor), 2,6-dinitroanilines, anilinopyrimidine-based AP fungicide (anilinopyrimidines), phenylpyrrole-based PP fungicide ( phenylpyrroles), dicarboximides, piperazine-based DMI fungicides (demethylation inhibitors, SBI: class I), pyridine-based DMI fungicides (demethylation inhibitors, SBI: class I), pyrimidine-based DMI fungicides agent (demethylation inhibitor, SBI: class I), imidazole-based DMI fungicide (demethylation inhibitor, SBI: class I), triazole-based DMI fungicide (demethylation inhibitor, SBI: class I), Triazolinethione-based DMI fungicide (demethylation inhibitor, SBI: Class I), isobenzofuranone-based MBI-R (melanin biosynthesis inhibitor-reductase), pyrroloquinolinone-based MBI-R (melanin biosynthesis inhibitor-reductase), triazolobenzothiazole-based MBI-R (melanin biosynthesis inhibitor-reductase), cyclopropanecarboxamide-based MBI-D (melanin biosynthesis inhibitor-dehydratase) , carboxamide-based MBI-D (melanin biosynthesis inhibitor - dehydratase), propionamide-based MBI-D (melanin biosynthesis inhibitor - dehydratase), benzothiadiazoles, benzoisothiazoles, thiadiazole carboxamides, cyanoacetamide oxime , benzenesulfonamides, pyridazinones, guanidines and quinoxalines.

Pesticides are particularly carbamate-based acetylcholinesterase (AChE) inhibitors, organophosphorus-based acetylcholinesterase (AChE) inhibitors, phenylpyrazole-based (fiprole-based) GABAergic chloride ion channel antagonists, pyrethroid- and pyrethrin-based sodium channel modulators, neo An insecticide selected from the group consisting of nicotinoid nicotinic acetylcholine receptor (nAChR) agonists, oxidative phosphorylation uncouplers, avermectin and milbemycin chloride channel activators, chordotonal modulators and diamide ryanodine receptor modulators. agent;
Or isoxazole aromatic heterocycles, benzimidazole MBC fungicide (methylbenzimidazole carbamate), phenylbenzamide SDHI (succinate dehydrogenase inhibitor), phenyloxoethylthiophenamide SDHI (succinate dehydrogenase inhibitor), pyridinylethylbenzamide SDHI (succinate dehydrogenase inhibitor), furancarboxamide SDHI (succinate dehydrogenase inhibitor), oxathiincarboxamide SDHI (succinate dehydrogenase inhibitor) , thiazole carboxamide SDHI (succinate dehydrogenase inhibitor), pyrazole-4-carboxamide SDHI (succinate dehydrogenase inhibitor), pyridinecarboxamide SDHI (succinate dehydrogenase inhibitor), methoxyacrylate QoI disinfection agent (Qo inhibitor), methoxyacetamide-based QoI fungicide (Qo inhibitor), methoxycarbamate-based QoI fungicide (Qo inhibitor), oximinoacetic acid-based QoI fungicide (Qo inhibitor), oximinoacetamide-based QoI fungicide (Qo inhibitor), oxazolidinedione-based QoI fungicide (Qo inhibitor), dihydrodioxazine-based QoI fungicide (Qo inhibitor), imidazolinone-based QoI fungicide (Qo inhibitor), benzyl carbamate-based QoI fungicide ( Qo inhibitor), piperazine-based DMI fungicide (demethylation inhibitor, SBI: class I), pyridine-based DMI fungicide (demethylation inhibitor, SBI: class I), pyrimidine-based DMI fungicide (demethylation inhibitors, SBI: Class I), imidazole-based DMI fungicides (demethylation inhibitors, SBI: Class I), triazole-based DMI fungicides (demethylation inhibitors, SBI: Class I) and triazolinethiones Fungicides selected from the group consisting of DMI fungicides (demethylation inhibitors, SBI: Class I) are preferred.

Examples of specific pesticides include aldicarb, bendiocarb, butocaboxim, butoxycarboxim, NAC (carbaryl), carbofuran, ethiophenecarb, BPMC (phenocarb), formethanate, MIPC (isoprocarb), methomyl, MTMC (metolcarb ), oxamyl, pirimicarb, PHC (propoxur), thiophanox, triazamate, XMC, MPMC (xylylcarb), acephate, azamethifos, cassaphos, CVP (chlorfenbinphos), dimetone-S-methyl, DDVP (dichlorvos), dicrotophos , dimethoate, dimethylvinphos, etoprophos, fenamiphos, fosthiazate, heptenophos, marathon (malathion), mecarbam, methamidophos, DMTP (methidathion), mevinphos, monocrotophos, omethoate, oxydimethone methyl, phosphamidone, propetamphos, thiometone, DEP (trichlorfon) , vamidothion, flumethrin, fipronil, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, nicotine sulfate (nicotine), sulfoxaflor, flupyradifuron, pyriproxyfen, methyl bromide (methyl bromide), chloropicrin, sulfuryl fluoride, boron Sand, tartar emetic, pymetrozine, flonicamid, BPPS (propargite), DNOC, cartap, thiocyclam, thiosultap sodium salt, cyromazine, hydrogen phosphide, hydrocyanic acid, azadirachtin, sodium aluminum fluoride, 1,3-dichloropropene, dicyclanil , ethylene dibromide, sabadilla and sulcofuron sodium;
and furalaxyl, metalaxyl, metalaxyl M, oxadixyl, ofrace, dimethylmol, hydroxyisoxazole (hymexazole), octhilinone, fenfram, carboxin, oxycarboxin, furametpyr, metominostrobin, cyazofamide, pyrimethanil, kasugamycin, streptomycin, IBP (iprobenfos ), eclomezole (ethridiazole), propamocarb, prothiocarb, pyrifenox, imazalil, pefurazoate, triflumizole, flutriafol, microbutanil, propiconazole, tetraconazole, fenpropidine, spiroxamine, validamycin, polyoxin, iprovalicarb, pyroquilone , cymoxanil, fosetyl, phosphite and salts, fursulfamide, metasulfocarb, guanidine (dodine), ferimzone, potassium bicarbonate, farbum, guazatin, iminoctadine acetate/iminoctadine albesilate (iminoctadine), copper sulfate, formaldehyde, from bactericidal agents selected from the group consisting of 8-hydroxyquinoline sulfate, iodomethane, mercuric chloride, metam, methyl bromide, methyl isothiocyanate, mildiomycin, navum, phenylmercuric acetate, 2-phenylphenol and poloxine It is desirable to contain at least one selected from the group consisting of:
Among them, the agricultural chemical preferably contains at least one selected from the group consisting of acephate, fipronil, acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam, nitenpyram and flonicamid, more preferably, for example, acetamiprid, It contains at least one selected from the group consisting of imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, more preferably at least one selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran and thiamethoxam. It is to contain seeds, and particularly preferably to contain dinotefuran or the like.

"Fertilizer" is defined in the Fertilizer Regulation Law of Japan as "substances applied to the land for the purpose of providing nutrients to plants or bringing about chemical changes in the soil in order to contribute to the cultivation of plants. A substance that is applied to plants for the purpose of providing them with nutrients.

The official standards established based on the Fertilizer Control Law include nitrogenous fertilizers, phosphate fertilizers, potassium fertilizers, organic fertilizers, compound fertilizers, lime fertilizers, silicic fertilizers, magnesium fertilizers, manganese fertilizers, and boron fertilizers. , trace element complex fertilizers, sludge fertilizers, and fertilizers mixed with agricultural chemicals and other substances. In terms of fertilizer effect, it can be classified into fast-release fertilizer and slow-release fertilizer.

By "particulate" herein is meant that the solid material has a certain size.
The term "slow-release fertilizer" as used herein is a general term for fertilizers that exhibit a fertilizing effect slowly, and has the feature that the fertilizing component is gradually eluted after fertilization and the fertilizing effect lasts for a long period of time. Specifically, for example,
(1) Nitrogenous fertilizers, phosphate fertilizers, potassium fertilizers, organic fertilizers, compound fertilizers, lime fertilizers, silicic fertilizers (limited to silica gel fertilizers), magnesium fertilizers, manganese fertilizers, boron fertilizers, trace amounts Slow-release fertilizer (hereinafter referred to as "slow-release compound fertilizer") that is granulated or molded by blending two or more of fertilizers mixed with agricultural chemicals and other substances such as element compound fertilizers, sludge fertilizers, etc.;
(2) A slow-release fertilizer produced by chemically manipulating a fertilizer or a fertilizer raw material among compound fertilizers. For example, based on formaldehyde-processed urea fertilizer, isobutyraldehyde-condensed urea fertilizer, magnesium ammonium phosphate, etc. (hereinafter referred to as "synthetic slow-release fertilizer");
(3) Slow-release coated fertilizers such as coated nitrogen fertilizers, coated phosphate fertilizers, coated potassium fertilizers, coated compound fertilizers, and coated magnesium fertilizers;
(4) slow-release pressurized fertilizers such as tablet fertilizers whose component elution is adjusted by pressurization; and (5) slow-release nitration inhibitor compounded fertilizers, etc. Among them, chemically synthesized slow-release fertilizers are preferred.

Therefore, "slow-release granular fertilizer" means the above-mentioned slow-release fertilizer that is in the form of granules. means no solid fertilizers. Specifically, it means a slow-release compounded granular fertilizer, a synthetic slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressurized granular fertilizer, or a slow-release nitration inhibitor compounded fertilizer. "Agrochemical-containing slow-release granular fertilizer formulation" means a formulation of the above-mentioned "slow-release granular fertilizer" containing agricultural chemical ingredients, and the quality and quantity of any part of the formulation are uniform. It means a formulation of solid fertilizer that has a uniformity and does not vary in the effectiveness of fertilizers and pesticides. Examples of slow-release granular fertilizer formulations containing this agricultural chemical include those granulated by chemical manipulation, those granulated by a granulator, those in pellet form, those formed into tablets, those coated with resin, etc. and so on.

The particle size of the agricultural chemical-containing slow-release granular fertilizer formulation of the present invention may be, for example, 0.1 mm to 50.0 mm, preferably less than 10 mm, more preferably less than 2 mm. The particle size can be measured using a particle size distribution analyzer or the like.

The weight ratio of nitrogen (N), phosphorus (P), and potassium (K), which are guaranteed ingredients for a slow-release granular fertilizer formulation containing agrochemicals, may be any weight ratio as long as it functions as a slow-release fertilizer. Although not particularly limited, the weight ratio of N:P:K is, for example, 1:1:1 (e.g., 5:5:5, 6:6:6, 7:7:7, 8:8:8, 10:1:1). 10:10), a weight ratio of N:P:K such as 1:2:1 (e.g. 5:10:5), 1.2:2:1 (e.g. 6:10: 5, etc.), 1:3:2 (e.g., 3:9:6, etc.), 2:3:1 (e.g., 4:6:2, etc.), etc. The weight ratio of the components, N:P:K, is for example 2:1:2 (such as 4:2:4), 2:1:3 (such as 4:2:6), 3:1:2 (such as valley type guarantee components with a low weight ratio of P to N and K, such as 6:2:4, etc.; ), a high weight ratio of N to P and K such as 3:2:1 (such as 9:6:3), a weight ratio of N:P:K such as 1:1:1: 2 (e.g., 3:3:6, etc.), 1:2:3 (e.g., 3:6:9, etc.), etc. can be done.

Furthermore, the weight ratio of each N, P and K is nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), calcium (Ca) and sulfur (S) formulation containing any one or more fertilizer components selected from the group consisting of nitrogen (N), phosphorus (P) and potassium (K) selected from the group Either may be 0 as long as it is within the range of the formulation containing at least two of the fertilizer components.

Particularly preferred are solid or granular fertiliser-pesticide formulations in which the weight ratio of N:P:K is 6:40:6 (3:20:3) or 8:20:8 (2:5:2).
In addition, the weight ratio of the guaranteed ingredients is a numerical value indicating the minimum ratio of nitrogen (N), phosphorus (P) and potassium (K) contained in a predetermined fertilizer, and is limited to that numerical value. not to be Therefore, a fertilizer whose weight ratio is equal to or higher than the numerical value is qualified as a fertilizer, and the fertilizer is also included in the agricultural chemical-containing slow-release granular fertilizer formulation of the present invention.

"Liquid or liquid fertilizer" indicates that the fertilizer is liquid or that the fertilizer is in a liquid state. Although there is essentially no difference between the two, examples of liquid fertilizers include liquid potassium silicate fertilizers, liquid trace element compound fertilizers, liquid by-product nitrogen fertilizers, and liquid phosphate fertilizers. Examples include liquid nitrogen fertilizers and liquid compound fertilizers.
As the fertilizer used as the main component of the pesticide-containing slow-release granular fertilizer of the present invention, commercially available slow-release granular fertilizers can be used, and those produced according to the method described in Patent Document 1 can also be used. can.

The "non-petroleum solvent" of the present invention is a solvent having a functional group in its structure, for example, a solvent containing a hydroxyl group, a carboxyl group, an aldehyde group, etc. Among them, from the viewpoint of workability or safety, A non-petroleum solvent having a flash point of 40° C. or higher is preferred. For example, ether-based solvents, nitrile-based solvents, alcohols, alcohol-based solvents such as polyhydric alcohols, ketone-based solvents, carbonate-based solvents, ester-based solvents, amide-based solvents, carbamide-based solvents, sulfoxide-based solvents, sulfone-based solvents, amines system solvents, aldehyde-based solvents, fatty acid ester-based solvents, nitrogen-containing carrier-based solvents, glycol ether-based solvents, and the like.

Specific non-petroleum solvents include solvents that are miscible with water to some extent, such as solvents having a water solubility of 100 ppm or more, and are not particularly limited. Examples include ether solvents such as tetrahydrofuran and 1,4-dioxane; Nitrile solvents such as propionitrile, butyronitrile, isobutyronitrile, malononitrile; methanol, ethanol, propanol, isopropanol, 1-butanol, 2-butanol, isobutanol, t-butanol, allyl alcohol, ethylene glycol, 1,2 -Alcoholic solvents such as propanediol (propylene glycol), 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, glycerin; acetone, methyl ethyl ketone, diethyl ketone, etc. ketone solvents such as dimethyl carbonate, diethyl carbonate, ethylene carbonate and propylene carbonate; ester solvents such as methyl formate, ethyl formate, methyl acetate, ethyl acetate, γ-butyrolactone, methyl lactate and ethyl lactate; Amide solvents such as formamide, N,N-dimethylformamide, N,N-diethylformamide, N,N-dimethylacetamide, N,N-diethylacetamide, N,N-dimethylpropionamide, N,N-dimethyllactamide carbamide solvents such as tetramethylurea and 1,3-dimethyl-2-imidazolidinone; sulfoxide solvents such as dimethylsulfoxide; sulfone solvents such as dimethylsulfone and sulfolane; ammonia, methylamine, dimethylamine, diethylamine, Amine solvents such as triethylamine, isopropylamine, diisopropylamine, ethyldiisopropylamine, pyrrolidine, N-methylpyrrolidine, piperidine, N-methylpiperidine, morpholine, N-methylmorpholine, pyridine, ethanolamine; formaldehyde, acetaldehyde, propion Aldehyde-based solvents such as aldehyde, butanal and pentanal; Fatty acid ester-based solvents such as coconut oil fatty acid methyl ester, succinic acid dimethyl ester, glutamic acid dimethyl ester and adipate dimethyl ester; Nitrogen-containing solvents such as N-methylpyrrolidone and N-ethylpyrrolidone Carrier-based solvents are included.

"Glycol ether" means a compound in which one or both of the hydroxyl groups of a diol or its condensate is etherified, such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monoisopropyl ether. , ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol mono-t-butyl ether, ethylene glycol mono-2-methylpentyl ether, ethylene glycol monohexyl ether, ethylene glycol mono-2-ethyl-hexyl ether, ethylene glycol monovinyl ether, ethylene Glycol monoallyl ether, ethylene glycol monobenzyl ether, ethylene glycol monophenyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monohexyl ether, diethylene glycol mono 2-ethylhexyl ether, diethylene glycol monoallyl ether, diethylene glycol monobenzyl ether, diethylene glycol monophenyl ether, diethylene glycol mono(methylphenyl) ether, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether , diethylene glycol dibutyl ether, diethylene glycol divinyl ether, diethylene glycol ethyl vinyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, triethylene glycol monovinyl ether, triethylene glycol dimethyl ether, tetraethylene glycol monophenyl ether, Tetraethylene glycol Diethyl ether, polyethylene glycol Recall monomethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monoisopropyl ether, propylene glycol monobutyl ether, propylene glycol phenyl ether, propylene glycol mono(methylphenyl) ether, propylene glycol dimethyl ether, Propylene glycol diethyl ether, propylene glycol dipropyl ether, propylene glycol diisopropyl ether, propylene glycol dibutyl ether, propylene glycol diisobutyl ether, propylene glycol diallyl ether, propylene glycol diphenyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene Glycol monopropyl ether, dipropylene glycol mono butyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol dibutyl ether, dipropylene glycol diisobutyl ether, dipropylene glycol allyl ether, tripropylene glycol monomethyl ether, tripropylene glycol mono Ethyl ether, tripropylene glycol monobutyl ether, butylene glycol monomethyl ether, butylene glycol dimethyl ether, isopropyl glycol, diisopropyl glycol, dimethyl diglycol, methyl ethyl diglycol, 3-methoxy-3-methyl-1-butanol and the like. The slow-release granular fertilizer formulation containing an agricultural chemical of the invention preferably contains at least one glycol ether selected from the group consisting of these.

Among them, suitable glycol ethers include, for example, ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol monoallyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monobenzyl ether, propylene glycol monopropyl ether, isopropyl glycol, Isopropyldiglycol, dimethyldiglycol, methylethyldiglycol, 3-methoxy-3-methyl-1-butanol, etc., and the slow-release granular fertilizer formulation containing agrochemicals of the present invention is selected from the group consisting of these It is preferable to contain at least one. The most preferred pesticide-containing slow-release granular fertilizer formulation of the present invention contains 3-methoxy-3-methyl-1-butanol as the glycol ether.

"Water" means, for example, purified water, distilled water, ion-exchanged water, pure water, ultrapure water, sterilized water, filtered water, etc., and is not particularly limited, and any water can be used. In addition to the above water, agricultural water, industrial water, well water, tap water, etc. can be used as long as the functions and performance of the slow-release granular fertilizer formulation containing the pesticide are not impaired.

Next, the method for producing the agricultural chemical-containing slow-release granular fertilizer preparation of the present invention will be described.
Slow-release granular fertilizer formulations containing pesticides are, for example, pesticides (hereinafter sometimes referred to as "pesticide ingredients") in one or more non-petroleum solvents or a mixed solution of one or more non-petroleum solvents and water It can be produced by dissolving by a known method and impregnating slow-release granular fertilizer with the solution. Fertilizers (hereinafter also referred to as "fertilizer components"), surfactants and other compounding components may be mixed with the solution and impregnated, as required.

The order in which the agricultural chemicals are dissolved in one or more non-petroleum solvents is not particularly limited, and can be appropriately selected according to the properties of each component. There is no particular limitation on the form of the pesticide component as a raw material, and it may be in a solid state or a liquid state.

The agricultural chemical components added to one or more non-petroleum solvents are appropriately heated or heated and stirred as appropriate to dissolve each component. , an ultrafiltration membrane, a reverse osmosis membrane, or the like, and impregnating the filtered solution into the slow-release fertilizer to produce a desired pesticide-containing slow-release granular fertilizer formulation. can. Although any filtering method can be used, it is usually advantageous to use a filter of about 1 μm. The temperature for preparing the slow-release granular fertilizer formulation containing an agricultural chemical is not particularly limited, but it can be carried out at room temperature, under heating, or under heating. The temperature of the mixed solution during preparation is 0°C to the boiling point of the solvent, preferably 25°C to 80°C, particularly preferably 40°C to 75°C.

In order to stably produce the pesticide-containing slow-release granular fertilizer formulation of the present invention, one or more non-petroleum solvents or a mixture of one or more non-petroleum solvents and water, which are prepared in advance, contain pesticides. A manufacturing method of impregnating a slow-release fertilizer with an aqueous composition to be used is desirable.
Therefore, an aqueous composition containing one or more non-petroleum solvents or a mixture of one or more non-petroleum solvents and water, and an agricultural chemical (hereinafter, this aqueous composition is sometimes referred to as a "premix"). is useful as a raw material for producing the pesticide-containing slow-release granular fertilizer formulation of the present invention.

A premix containing agricultural chemical components can be produced by dissolving the agricultural chemicals described in paragraphs [0038] to [0041] in a non-petroleum solvent.
Preferred premixes containing pesticide ingredients are glycol ethers as non-petroleum solvents, preferably ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol monoallyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, At least one selected from the group consisting of diethylene glycol monobenzyl ether, propylene glycol monopropyl ether, isopropyl glycol, diisopropyl glycol, dimethyldiglycol, methylethyldiglycol and 3-methoxy-3-methyl-1-butanol, more preferably wherein the glycol ether is 3-methoxy-3-methyl-1-butanol and, as an agricultural chemical, at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram and more preferably a premix containing dinotefuran. The premix containing agricultural chemical components can be impregnated with slow-release fertilizer by adding water and/or liquid or liquid fertilizer as appropriate.

Examples of premixes containing glycol ethers, pesticides and water include dinotefuran - ethylene glycol monoisopropyl ether - aqueous solution, dinotefuran - ethylene glycol monobutyl ether - aqueous solution, dinotefuran - ethylene glycol monoisobutyl ether - aqueous solution, dinotefuran - ethylene glycol mono allyl ether - aqueous solution, dinotefuran - diethylene glycol monomethyl ether - aqueous solution, dinotefuran - diethylene glycol monoisopropyl ether - aqueous solution, dinotefuran - diethylene glycol monobutyl ether - aqueous solution, dinotefuran - diethylene glycol monoisobutyl ether - aqueous solution, dinotefuran - diethylene glycol monobenzyl ether - aqueous solution, dinotefuran - Diethylene glycol dimethyl ether - aqueous solution, dinotefuran - diethylene glycol diethyl ether - aqueous solution, dinotefuran - diethylene glycol methyl ethyl ether - aqueous solution, dinotefuran - triethylene glycol monomethyl ether - aqueous solution, dinotefuran - triethylene glycol monobutyl ether - aqueous solution, dinotefuran - triethylene glycol dimethyl ether - aqueous solution , dinotefuran - polyethylene glycol monomethyl ether - aqueous solution, dinotefuran - propylene glycol monomethyl ether - aqueous solution, dinotefuran - propylene glycol monopropyl ether - aqueous solution, dinotefuran - dipropylene glycol monomethyl ether - aqueous solution, dinotefuran - tripropylene glycol monomethyl ether - aqueous solution, dinotefuran -3-methoxy-3-methyl-1-butanol - aqueous solution, imidacloprid - ethylene glycol monoisopropyl ether - aqueous solution, imidacloprid - ethylene glycol monobutyl ether - aqueous solution, imidacloprid - ethylene glycol monoisobutyl ether - aqueous solution, imidacloprid - ethylene glycol monoallyl Ether - aqueous solution, imidacloprid - diethylene glycol monomethyl ether - aqueous solution, imidacloprid - diethylene glycol monoisopropyl ether - aqueous solution, imidacloprid - diethylene glycol monobutyl ether - aqueous solution, imidacloprid - diethylene glycol monoisobutyl ether - aqueous solution, imida Cloprid-diethylene glycol monobenzyl ether-water solution, imidacloprid-diethylene glycol dimethyl ether-water solution, imidacloprid-diethylene glycol diethyl ether-water solution, imidacloprid-diethylene glycol methyl ethyl ether-water solution, imidacloprid-triethylene glycol monomethyl ether-water solution, imidacloprid-triethylene glycol monobutyl ether - aqueous solution, imidacloprid - triethylene glycol dimethyl ether - aqueous solution, imidacloprid - polyethylene glycol monomethyl ether - aqueous solution, imidacloprid - propylene glycol monomethyl ether - aqueous solution, imidacloprid - propylene glycol monopropyl ether - aqueous solution, imidacloprid - dipropylene glycol monomethyl ether - aqueous solution, imidacloprid-tripropylene glycol monomethyl ether-aqueous solution, imidacloprid-3-methoxy-3-methyl-1-butanol-aqueous solution,
Clothianidin-ethylene glycol monoisopropyl ether-water solution, clothianidin-ethylene glycol monobutyl ether-water solution, clothianidin-ethylene glycol monoisobutyl ether-water solution, clothianidin-ethylene glycol monoallyl ether-water solution, clothianidin-diethylene glycol monomethyl ether-water solution, clothianidin-diethylene glycol Monoisopropyl ether - aqueous solution, clothianidin - diethylene glycol monobutyl ether - aqueous solution, clothianidin - diethylene glycol monoisobutyl ether - aqueous solution, clothianidin - diethylene glycol monobenzyl ether - aqueous solution, clothianidin - diethylene glycol dimethyl ether - aqueous solution, clothianidin - diethylene glycol diethyl ether - aqueous solution, clothianidin - diethylene glycol Methyl ethyl ether - aqueous solution, clothianidin - triethylene glycol monomethyl ether - aqueous solution, clothianidin - triethylene glycol monobutyl ether - aqueous solution, clothianidin - triethylene glycol dimethyl ether - aqueous solution, clothianidin - polyethylene glycol monomethyl ether - aqueous solution, clothianidin - propylene glycol monomethyl ether - aqueous solution -aqueous solution, clothianidin-propylene glycol monopropyl ether-aqueous solution, clothianidin-dipropylene glycol monomethyl ether-aqueous solution, clothianidin-tripropylene glycol monomethyl ether-aqueous solution, clothianidin-3-methoxy-3-methyl-1-butanol-aqueous solution,
Thiamethoxam - ethylene glycol monoisopropyl ether - aqueous solution, Thiamethoxam - ethylene glycol monobutyl ether - aqueous solution, Thiamethoxam - ethylene glycol monoisobutyl ether - aqueous solution, Thiamethoxam - ethylene glycol monoallyl ether - aqueous solution, Thiamethoxam - diethylene glycol monomethyl ether - aqueous solution, Thiamethoxam - diethylene glycol Monoisopropyl ether - aqueous solution, thiamethoxam - diethylene glycol monobutyl ether - aqueous solution, thiamethoxam - diethylene glycol monoisobutyl ether - aqueous solution, thiamethoxam - diethylene glycol monobenzyl ether - aqueous solution, thiamethoxam - diethylene glycol dimethyl ether - aqueous solution, thiamethoxam - diethylene glycol diethyl ether - aqueous solution, thiamethoxam - diethylene glycol Methyl ethyl ether - aqueous solution, thiamethoxam - triethylene glycol monomethyl ether - aqueous solution, thiamethoxam - triethylene glycol monobutyl ether - aqueous solution, thiamethoxam - triethylene glycol dimethyl ether - aqueous solution, thiamethoxam - polyethylene glycol monomethyl ether - aqueous solution, thiamethoxam - propylene glycol monomethyl ether - aqueous solution - aqueous solution, thiamethoxam-propylene glycol monopropyl ether-aqueous solution, thiamethoxam-dipropylene glycol monomethyl ether-aqueous solution, thiamethoxam-tripropylene glycol monomethyl ether-aqueous solution, thiamethoxam-3-methoxy-3-methyl-1-butanol-aqueous solution,
Acetamiprid-ethylene glycol monoisopropyl ether-water solution, Acetamiprid-ethylene glycol monobutyl ether-water solution, Acetamiprid-ethylene glycol monoisobutyl ether-water solution, Acetamiprid-ethylene glycol monoallyl ether-water solution, Acetamiprid-diethylene glycol monomethyl ether-water solution, Acetamiprid-diethylene glycol Acetamiprid-diethylene glycol monobutyl ether-water solution, Acetamiprid-diethylene glycol monobenzyl ether-water solution, Acetamiprid-diethylene glycol dimethyl ether-water solution, Acetamiprid-diethylene glycol diethyl ether-water solution, Acetamiprid-diethylene glycol-water solution Methyl ethyl ether - aqueous solution, acetamiprid - triethylene glycol monomethyl ether - aqueous solution, acetamiprid - triethylene glycol monobutyl ether - aqueous solution, acetamiprid - triethylene glycol dimethyl ether - aqueous solution, acetamiprid - polyethylene glycol monomethyl ether - aqueous solution, acetamiprid - propylene glycol monomethyl ether - aqueous solution -aqueous solution, acetamiprid-propylene glycol monopropyl ether-aqueous solution, acetamiprid-dipropylene glycol monomethyl ether-aqueous solution, acetamiprid-tripropylene glycol monomethyl ether-aqueous solution, acetamiprid-3-methoxy-3-methyl-1-butanol-aqueous solution,
Thiaclopride-ethylene glycol monoisopropyl ether-water solution, thiaclopride-ethylene glycol monobutyl ether-water solution, thiaclopride-ethylene glycol monoisobutyl ether-water solution, thiaclopride-ethylene glycol monoallyl ether-water solution, thiaclopride-diethylene glycol monomethyl ether-water solution, thiacloprid-diethylene glycol Monoisopropyl ether - aqueous solution, thiacloprid - diethylene glycol monobutyl ether - aqueous solution, thiacloprid - diethylene glycol monoisobutyl ether - aqueous solution, thiacloprid - diethylene glycol monobenzyl ether - aqueous solution, thiacloprid - diethylene glycol dimethyl ether - aqueous solution, thiacloprid - diethylene glycol diethyl ether - aqueous solution, thiacloprid - diethylene glycol Methyl ethyl ether - aqueous solution, thiacloprid - triethylene glycol monomethyl ether - aqueous solution, thiacloprid - triethylene glycol monobutyl ether - aqueous solution, thiacloprid - triethylene glycol dimethyl ether - aqueous solution, thiacloprid - polyethylene glycol monomethyl ether - aqueous solution, thiacloprid - propylene glycol monomethyl ether - aqueous solution - aqueous solution, thiacloprid-propylene glycol monopropyl ether-aqueous solution, thiacloprid-dipropylene glycol monomethyl ether-aqueous solution, thiacloprid-tripropylene glycol monomethyl ether-aqueous solution, thiacloprid-3-methoxy-3-methyl-1-butanol-aqueous solution,
Nitenpyram - ethylene glycol monoisopropyl ether - aqueous solution, nitenpyram - ethylene glycol monobutyl ether - aqueous solution, nitenpyram - ethylene glycol monoisobutyl ether - aqueous solution, nitenpyram - ethylene glycol monoallyl ether - aqueous solution, nitenpyram - diethylene glycol monomethyl ether - aqueous solution, nitenpyram - diethylene glycol Monoisopropyl ether - aqueous solution, Nitenpyram - diethylene glycol monobutyl ether - aqueous solution, Nitenpyram - diethylene glycol monoisobutyl ether - aqueous solution, Nitenpyram - diethylene glycol monobenzyl ether - aqueous solution, Nitenpyram - diethylene glycol dimethyl ether - aqueous solution, Nitenpyram - diethylene glycol diethyl ether - aqueous solution, Nitenpyram - diethylene glycol Methyl ethyl ether - aqueous solution, nitenpyram - triethylene glycol monomethyl ether - aqueous solution, nitenpyram - triethylene glycol monobutyl ether - aqueous solution, nitenpyram - triethylene glycol dimethyl ether - aqueous solution, nitenpyram - polyethylene glycol monomethyl ether - aqueous solution, nitenpyram - propylene glycol monomethyl ether - aqueous solution -Aqueous solution, Nitenpyram-propylene glycol monopropyl ether-aqueous solution, Nitenpyram-dipropylene glycol monomethyl ether-aqueous solution, Nitenpyram-tripropylene glycol monomethyl ether-aqueous solution, Nitenpyram-3-methoxy-3-methyl-1-butanol-aqueous solution, etc. mentioned,
Preferably, dinotefuran-ethylene glycol monobutyl ether-aqueous solution, dinotefuran-ethylene glycol monoisobutyl ether-aqueous solution, dinotefuran-ethylene glycol monoallyl ether-aqueous solution, dinotefuran-diethylene glycol monobutyl ether-aqueous solution, dinotefuran-diethylene glycol monoisobutyl ether-aqueous solution, dinotefuran-diethylene glycol monobenzyl ether-water solution, dinotefuran-propylene glycol monopropyl ether-water solution, dinotefuran-3-methoxy-3-methyl-1-butanol-water solution,
imidacloprid-ethylene glycol monobutyl ether-water solution, imidacloprid-ethylene glycol monoisobutyl ether-water solution, imidacloprid-ethylene glycol monoallyl ether-water solution, imidacloprid-diethylene glycol monobutyl ether-water solution, imidacloprid-diethylene glycol monoisobutyl ether-water solution, imidacloprid-diethylene glycol mono-water benzyl ether-aqueous solution, imidacloprid-propylene glycol monopropyl ether-aqueous solution, imidacloprid-3-methoxy-3-methyl-1-butanol-aqueous solution,
Clothianidin-Ethylene Glycol Monobutyl Ether-Water Solution, Clothianidin-Ethylene Glycol Monoisobutyl Ether-Water Solution, Clothianidin-Ethylene Glycol Monoallyl Ether-Water Solution, Clothianidin-Diethylene Glycol Monobutyl Ether-Water Solution, Clothianidin-Diethylene Glycol Monoisobutyl Ether-Water Solution, Clothianidin-Diethylene Glycol Mono benzyl ether-water solution, clothianidin-propylene glycol monopropyl ether-water solution, clothianidin-3-methoxy-3-methyl-1-butanol-water solution,
Thiamethoxam Ethylene Glycol Monobutyl Ether - Water, Thiamethoxam Ethylene Glycol Monoisobutyl Ether - Water, Thiamethoxam Ethylene Glycol Monoallyl Ether - Water, Thiamethoxam Diethylene Glycol Monobutyl Ether - Water, Thiamethoxam Diethylene Glycol Monoisobutyl Ether - Water, Thiamethoxam Diethylene Glycol Mono benzyl ether-aqueous solution, thiamethoxam-propylene glycol monopropyl ether-aqueous solution, thiamethoxam-3-methoxy-3-methyl-1-butanol-aqueous solution,
Acetamiprid-ethylene glycol monobutyl ether-water solution, Acetamiprid-ethylene glycol monoisobutyl ether-water solution, Acetamiprid-ethylene glycol monoallyl ether-water solution, Acetamiprid-diethylene glycol monobutyl ether-water solution, Acetamiprid-diethylene glycol monoisobutyl ether-water solution, Acetamiprid-diethylene glycol mono-water solution benzyl ether-aqueous solution, acetamiprid-propylene glycol monopropyl ether-aqueous solution, acetamiprid-3-methoxy-3-methyl-1-butanol-aqueous solution, etc.
More preferably, dinotefuran-3-methoxy-3-methyl-1-butanol-water solution, imidacloprid-3-methoxy-3-methyl-1-butanol-water solution, clothianidin-3-methoxy-3-methyl-1-butanol -aqueous solution, thiamethoxam-3-methoxy-3-methyl-1-butanol-aqueous solution, acetamiprid-3-methoxy-3-methyl-1-butanol-aqueous solution, etc.
Most preferred is dinotefuran-3-methoxy-3-methyl-1-butanol-water solution.

The slow-release granular fertilizer formulation containing an agricultural chemical of the present invention can contain any agricultural chemical ingredient such as an insecticide, a fungicide, a herbicide or a plant regulator as an agricultural chemical ingredient.
Plant regulator ingredients include, for example, maleic hydrazide and its salts, abscisic acid, inebenfide, paclobutrazole, uniconazole, tripentenol or psychocel.
The agricultural chemical component may be solid, semi-solid or liquid at room temperature. Combinations of two or more of completely different targets are also possible, for example insecticides, fungicides or herbicides.

The agricultural chemical component and the non-petroleum solvent to be used are not particularly limited as long as they contain these two components, but their preferred range is 0.01% to 10% of the agricultural chemical component and the non-petroleum solvent is 0.1% to 10%, the total weight of fertilizer components is 0.1% to 99.9%, and more preferably, the agricultural chemical component is 0.01% to 10%, and the non-petroleum solvent is 0.1%. 0.1% to 99.8% of the total weight of fertilizer ingredients, more preferably 0.03% to 5% of pesticide ingredients, 0.1% to 10% of non-petroleum solvents, fertilizer ingredients 50.0% to 99.9% by total weight.

A slow-release granular fertilizer formulation containing an agricultural chemical may optionally contain a surfactant in addition to the above ingredients. The surfactant is not particularly limited as long as it is usually used in agricultural chemical formulations. For example, nonionic surfactants, anionic surfactants, and cationic surfactants can be used, preferably nonionic surfactants. One or more of active agents and anionic surfactants, more preferably one or more of nonionic surfactants can be mixed and used.

Specific examples of surfactants include polyoxyethylene alkylaryl ethers, polyoxyethylene alkylphenyl ethers, polyoxyethylene polystyrylphenyl ethers, polyoxyethylene polyoxypropylene block copolymers, polyoxyethylene oleyl esters, polyoxyethylene nonionic surfactants such as ethylene fatty acid esters and sorbitan fatty acid esters;
Fatty acid salts, alkyl sulfate ester salts, alkyl benzene sulfonates, α-olefin sulfonates, alkyl sulfosuccinates, polyoxyethylene alkyl aryl ether sulfates and phosphates, polyoxyethylene styrylphenyl ether sulfates and phosphates, and alkylamine salts anionic surfactants such as;
cationic surfactants such as primary to tertiary fatty amine salts, alkylammonium chlorides, tetraalkylammonium salts, trialkylbenzylammonium salts, alkylpyridinium salts, alkylhydroxyethylimidazolinium salts; Compound surfactants of anionic surfactants and cationic surfactants are also included. These surfactants may be used alone or in combination of two or more. The blending amount thereof is usually, for example, 0.1 to 70 parts by weight, preferably 0.1 to 30 parts by weight, more preferably 0.1 to 10 parts by weight, in the pesticide mixed solution.

In addition to the above ingredients, additives may be added to the pesticide-containing slow-release granular fertilizer formulation, if necessary. Additives include, for example, pH adjusters for improving the stability of pesticide ingredients such as lactic acid, hydrochloric acid, phosphoric acid, sodium citrate, citric acid, disodium hydrogen phosphate, sodium dihydrogen phosphate, and hydrogen phosphate. Dipotassium, potassium dihydrogen phosphate, phthalic acid, potassium hydrogen phthalate, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, succinic acid, sodium borate, N-ethylmorpholine, etc. 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight, based on the total amount of the granular fertilizer formulation. As an antioxidant, dibutylhydroxytoluene or the like can be blended at a blending ratio of 0.001 to 1 part by weight, preferably 0.005 to 0.5 part by weight. As the ultraviolet absorber, 2-hydroxy-4-n-octoxybenzophenone or the like can be blended at a blending ratio of 0.001 to 1 part by weight, preferably 0.005 to 0.5 part by weight. As antifoaming agents, acetylene glycol antifoaming agents, silicone antifoaming agents, fluorine antifoaming agents, fatty acid antifoaming agents, etc. are mixed at a mixing ratio of 0.001 to 5 parts by weight, preferably 0.01 to 2 parts. It can be blended in parts by weight. Antibacterial agents include benzothiazole derivatives, sorbic acid, potassium sorbate, butyl p-hydroxybenzoate, glutaraldehyde, thiazolone, BNPK (2-bromo-2-nitropropane-1,3-diol), etc. It can be blended at a blending ratio of 0.01 to 5 parts by weight, preferably 0.01 to 2 parts by weight.

In addition, auxiliary agents such as coloring agents, crystal precipitation inhibitors, thickeners, dispersants, chelating agents, effect expression promoters, composition homogenization promoters, nitration inhibitors, etc., which will be described later, are added as necessary. However, these adjuvants are not limited to those exemplified here.

Examples of coloring agents include azoic dyes, azo dyes, acridine, aniline dyes, aniline black, indanthrene, eosin, congo red, dihydrointole, methylene blue, phenazine derivative dyes, neutral red, phenolphthalein, fuchsine, fluorescein, para red. , mauve, carotene; carotenoids such as xanthophyll, cryptoxanthin, zeaxanthin, fucoxanthin, lycopene, lutein; flavonoids such as flavones, flavanones, antoclores, anthocyans and catechins; quinones such as melanin; chlorophyll, chlorophyllide, bacteriochlorophyll , cytochrome, pheophorbide, pheoporphyrin, hemerythrin, hemoglobin, hemovanadin, hemocyanin, porphyrin, porphine, myoglobin and other porphyrin pigments; anthraquinone, indigo, urobilin, erythrochlorin, carthamine, xanthone machin, curcumin, crocetin, chlorin, chlorocruorin, genistein, cochinyl, gossypol, commelinin, shikonin, stercopyrin, tannin, turacin, bixin, hypericin, pinnaglobin, brazilin, In addition to purpurin, betacyanin, berberine, horbilin, mangostin, moringin, laminaran, leghemoglobin, litmus, rhodopsin, rhodoxanthin, rhodomatin, etc., such as carbon black, red iron oxide, solvent red 23, sea eye acid blue 1 (C.I. Acid Blue 1), C.I. Acid Yellow 23 (C.I. Acid Yellow 23), and the like.

Examples of crystal precipitation inhibitors include ethylene glycol, propylene glycol, glycerin, cyclodextrins, and alkylene oxide adducts of glycerin.

Examples of thickeners include products available from Sansho Co., Ltd., and examples thereof include roasted bean gum such as MEYPROLBG FLEUR ^™ M-200, guar gum such as SUPERGEL ^™ 200, and JAGUAR ^™ C-13S. , carrageenan such as WG-108, pectin such as YM-150-LJ ^TM , xanthan gum such as KELZAN ^TM , gellan gum such as KELCOGEL ^TM AFT, diutan gum such as KELCO-CRETE ^TM DG, SB GUM-R ^TM dextrins such as MALTRIN ^(R) M040; cellulose derivatives (carboxymethylcellulose derivatives) such as FINNFIX( ^TM) ; tara gums such as spinogum.

Examples of the dispersant include products available from Kao Corporation, etc. Examples include β-naphthalenesulfonic acid formalin condensate sodium salt such as Demol ^TM N, and special aromatic sulfonic acid formalin such as Demol ^TM SN-B. Sodium salts of condensates, special polycarboxylic acid-type polymer surfactants such as Demol ^TM P, sodium polycarboxylic acids such as Nopcosperse ^TM 44-C, ammonium polycarboxylic acids such as Nopcosperse ^TM 5600, SN Dispersant ^TM Special polycarboxylic acid ammonium salts such as 5023, polyphosphate aminoalcohol neutralized products such as SN Dispersant ^TM 2060, and condensed naphthalenesulfonic acid ammonium salts such as Roma PWA-40 ^TM can be mentioned.

Examples of the chelating agent include products available from Cherest Co., Ltd., including EDTA (Ethylene Diamine Tetraacetic Acid), NTA (Nitrilo Triacetic Acid), DTPA (Diethylene Triamine Pentaacetic Acid), HEDTA (Hydroxyethylene Ethylene Ａｃｉｄ）、ＴＴＨＡ（Ｔｒｉｅｔｈｙｌｅｎｅ Ｔｅｔｒａｍｉｎｅ Ｈｅｘａａｃｅｔｉｃ Ａｃｉｄ）、ＰＤＴＡ（１，３－Ｐｒｏｐａｎｅｄｉａｍｉｎｅ Ｔｅｔｒａａｃｅｔｉｃ Ａｃｉｄ）、ＤＰＴＡ－ＯＨ（１，３－Ｄｉａｍｉｎｏ－２－ｈｙｄｒｏｘｙｐｒｏｐａｎｅ Ｔｅｔｒａａｃｅｔｉｃ Ａｃｉｄ）、ＨＩＤＡ（Ｈｙｄｒｏｘｙｅｔｈｙｌ Ｉｍｉｎｏ Ｄｉａｃｅｔｉｃ Ａｃｉｄ）、ＤＨＥＧ（Ｄｉｈｙｄｒｏｘｙｅｔｈｙｌ Ｇｌｙｃｉｎｅ）、ＧＥＤＴＡ（Ｇｌｙｃｏｌ Ｅｔｈｅｒ Ｄｉａｍｉｎｅ Ｔｅｔｒａａｃｅｔｉｃ Ａｃｉｄ）、ＣＭＧＡ（Ｄｉｃａｒｂｏｘｙｍｅｔｈｙｌ Ｇｌｕｔａｍｉｃ Ａｃｉｄ）、ＥＤＤＳ（（Ｓ，Ｓ）‐Ｅｔｈｙｌｅｎｅ Ｄｉａｍｉｎｅ Ｄｉｓｕｃｃｉｎｉｃ Ａｃｉｄ）、ＨＥＤＰ（Ｈｙｄｒｏｘｙｅｔｈｙｌｉｄｅｎｅ Ｄｉｐｈｏｓｐｈｏｎｉｃ Ａｃｉｄ）、ＮＴＭＰ（Ｎｉｔｒｉｌｏｔｒｉｓ （Ｍｅｔｈｙｌｅｎｅ Ｐｈｏｓｐｈｏｎｉｃ Ａｃｉｄ））、 PBTC (Phosphonobutane Tricarboxylic Acid), EDTMP (Ethylene Diamine Tetra (Methylene Phosphonic Acid)), EDTA metal salts such as EDTA-Fe-Na- _H2O , DTPA metal salts such as DTPA-Fe-Na-H, PDTA-Fe PDTA metal salts such as NH ₄ .H ₂ O, HOCH ₂ (CHOH) ₄ COONa and the like can be mentioned.

Examples of effect expression accelerators include ferrous sulfate, copper sulfate, zinc sulfate, and ammonium molybdate.

Examples of composition uniformity promoters include gypsum, paraffin and mineral oil, cornstarch, zeolite, and the like.

When water and/or liquid or liquid fertilizers are used, nitration inhibitors include, for example, 2-amino-4-chloro-6-methylpyrimidine (AM), N-2,5-dichlorophenylsuccinamic acid (DCS), dicyandiamide, 1-amidino-2-thiourea (ASU) and the like.
Water to be used is not particularly limited, such as purified water, distilled water, ion-exchanged water, pure water, ultrapure water, sterilized water, and filtered water, and any water can be used.

Slow-release granular fertilizer formulations containing pesticides can usually be used for planting, planting, and soil mixing. When applying the prepared pesticide-containing slow-release granular fertilizer formulation to plants, it can be used as it is. The amount to be used for a plant is determined depending on the content of the slow-release granular fertilizer formulation containing agricultural chemicals, but 1 g to 20 g can be used per plant.

Plants that can be applied are not particularly limited as long as the pesticide-containing slow-release granular fertilizer formulation of the present invention can be applied. Examples include vegetables, fruit trees, and ornamental plants.

Specifically, flowering plants; potted flowers; vegetables including fruit vegetables, leafy vegetables and root vegetables; flowering trees; fruit trees including deciduous fruit trees and evergreen fruit trees; lawns; can be mentioned.

When used for planting holes, stock root treatment, and soil mixing, the slow-release granular fertilizer preparation containing agricultural chemicals is generally weighed directly and treated, depending on the type and content of the active ingredient. In addition, the application amount and application time of the slow-release granular fertilizer formulation containing the agricultural chemical can be appropriately determined according to the active ingredient of the agricultural chemical to be blended.

Furthermore, the agrochemical-containing slow-release granular fertilizer formulation of the present invention can be applied alone to plants as described above. can be used together.

Specific examples of the combination method include, after applying the slow-release granular fertilizer formulation containing agricultural chemicals of the present invention, for example, liquid fertilizers, fertilizers in which powder fertilizers are solubilized in water, and liquid fertilizers such as liquid fertilizers containing agricultural chemicals. can be applied. The concentration and application amount of the liquid fertilizer to be applied can be appropriately selected in consideration of the target plant and the state of the plant. 2-3 L/m ² .

Specific examples of liquid fertilizers used in combination include liquid fertilizers such as Hyponex undiluted solution, flower plant undiluted solution, Vegeful liquid fertilizer, Myrose rose liquid fertilizer; Fertilizer Peters, water-soluble horticultural fertilizers OK-F-1, OK-F-3, OK-F-9, OK-F-12, OK-F-17, OK Ace, OK Special Fertilizers that are applied after being solubilized in water; Examples of liquid fertilizers containing agricultural chemicals include Hyponex undiluted solution containing insecticides.

EXAMPLES The present invention will be specifically described below by way of examples, but the present invention is not limited to these examples.

Example 1 (Slow release granular fertilizer formulation containing pesticide)
0.2 parts of dinotefuran raw material, 0.2 parts of 3-methoxy-3-methyl-1-butanol (manufactured by Kuraray Co., Ltd., trade name Solfit) and 3.6 parts of water were mixed to obtain a premix. This premix was added to slow-release granular fertilizer Magump K (manufactured by Hyponex Japan Co., Ltd.) and mixed to obtain a slow-release granular fertilizer containing dinotefuran.

Example 2
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to isopropyl glycol (manufactured by Nippon Nyukazai Co., Ltd., trade name iPG) in Example 1 above, and a slow-acting product containing dinotefuran was performed. and obtained a soluble granular fertilizer.

Example 3
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to isopropyl diglycol (manufactured by Nippon Nyukazai Co., Ltd., trade name iPDG) in Example 1 above, and a dinotefuran-containing loosening agent was prepared. An effective granular fertilizer was obtained.

Example 4
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to dimethyldiglycol (manufactured by Nippon Nyukazai Co., Ltd., trade name DMDG) in Example 1 above, and a dinotefuran-containing loose An effective granular fertilizer was obtained.

Example 5
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to methyl ethyl diglycol (manufactured by Nippon Nyukazai Co., Ltd., trade name MEDG) in Example 1 above, and dinotefuran was added. A slow-release granular fertilizer was obtained.

Example 6
Dinotefuran A slow-release granular fertilizer was obtained.

Example 7
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to methyl lactate (manufactured by Corbion Japan Co., Ltd., trade name PURASOLV ML), and dinotefuran was added. A slow-release granular fertilizer was obtained.

Example 8
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to N-ethylpyrrolidone (manufactured by MYI Chemical Co, Ltd., trade name NEP), A slow-release granular fertilizer containing dinotefuran was obtained.

Example 9
The same treatment as in Example 1 except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to N,N-dimethyllactamide (manufactured by Corbion Purac, trade name N,N-dimethyllactamide). A slow-release granular fertilizer containing dinotefuran was obtained.

Example 10
A slow-release granular fertilizer containing hymexazole was obtained in the same manner as in Example 1, except that the active ingredient of dinotefuran was changed to the active ingredient of hymexazole.

Example 11
The procedure of Example 1 was repeated except that the amount of 3-methoxy-3-methyl-1-butanol was increased to 2.0 parts and the amount of water was decreased to 1.8 parts. An effective granular fertilizer was obtained.

Comparative example 1
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to Solvent Naphtha (manufactured by Exxon Mobil Co., Ltd., trade name Solvesso 100) in Example 1 above, and a dinotefuran-containing buffer was prepared. An effective granular fertilizer was obtained.

Comparative example 2
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol was changed to Solvent Naphtha (trade name Naphthesol 220, manufactured by Godo Solvent Co., Ltd.). An effective granular fertilizer was obtained.

Comparative example 3
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to liquid paraffin (manufactured by Idemitsu Kosan Co., Ltd., trade name Daphne Oil SY-15), A slow-release granular fertilizer containing dinotefuran was obtained.

Comparative example 4
The same treatment as in Example 1 was performed except that 3-methoxy-3-methyl-1-butanol in Example 1 was changed to isodecyl phthalate (manufactured by Shin Nippon Rika Co., Ltd., trade name Sanso Cizer DIDP), A slow-release granular fertilizer containing dinotefuran was obtained.

In order to demonstrate the usefulness of the pesticide-containing slow-release granular fertilizer formulation of the present invention, the following Test Example 1 (manufacturability of premix), Test Example 2 (whether or not slow-release granular fertilizer can be impregnated), and Test Example 3 (formulation stability) and Test Example 4 (germination inhibition test) were performed.

Test Example 1 (premix manufacturability)
In preparing the premix, the solubility of dinotefuran was visually evaluated. Table 1 shows the results. Evaluation criteria are as follows: ◯: completely dissolved, ×: active ingredient of pesticide suspended.

Test Example 2 (Possibility of Impregnation of Premix into Slow-Release Granular Fertilizer Containing Pesticide)
Whether or not the prepared premix could be impregnated into a slow-release granular fertilizer containing agricultural chemicals was evaluated. Table 1 shows the results. Criteria for judgment are as follows: ◯: uniform treatment possible, Δ: treatment possible but uneven, ×: treatment not possible.

Test Example 3 (formulation stability)
The prepared sample was placed in an aluminum bag and subjected to abuse for 2 weeks at 54° C., and the state of the sample after the lapse of time was confirmed. Table 1 shows the results. Judgment criteria are ○: No change, ×: Deterioration such as solidification and crystal precipitation.

Test Example 4 (germination inhibition test)
A germination inhibition test of the slow-release granular fertilizer formulation containing pesticides of the present invention is a method of cultivation test regarding damage to plants according to the notification of the Director of Agriculture, Forestry and Fisheries Ministry of Agriculture, Forestry and Fisheries Agricultural and Sericulture Bureau No. 59 Nosan No. 1943 dated April 18, 1984 in Japan ( Excerpt), the test was performed.
A pot (Neubauer pot) having an inner diameter of 11.3 cm and a height of 6.5 cm was used, and as the test fertilizer, 5 g and 10 g of a pesticide-containing slow-release granular fertilizer formulation were used per 1 liter of test soil. Magump K, a slow-release granular fertilizer with the same fertilizer components as the test fertilizer, was used as a control fertilizer.
A 4:3:3 mixture of peat moss, akadama soil and perlite was used as the test soil.
Komatsuna was used as the test sample.
The test soil was filled into the test container to a volume of approximately 500 milliliters.
(b) Test plots were set up with a standard dose application plot and a double dose application plot using the test fertilizer and the control fertilizer.
(B) Test area for test fertilizer According to the amount of ingredients in the prototype of the slow-release granular fertilizer formulation containing pesticides, the standard amount application area was 5 g per liter of soil, and the double amount application area was 10 g per liter. .
(c) Test plots using control fertilizer The test plots using the control fertilizer were established according to those using the test fertilizer.
(d) Fertilization method Fertilizer was applied by mixing well so that it would be uniform with the soil of the entire test container.
(e) Crop seed and seed method The amount of seed was set to 20 grains per test container.
The seeding was performed using tweezers or the like so that the seeds were evenly spaced. After seeding, the seeds were covered with air-dried soil to such an extent that the seeds were hidden.
For about 10 days after the start of the test, the moisture content of the soil during the test period was replenished with reduced water so as to maintain the moisture state at the start of the test. Cultivation temperature during the test period was kept within the range of 15 to 25 degrees Celsius. The cultivation period was 25 days after seeding.
The preparations of Examples 1, 2, 3, 7, 8 and 9 of the present invention were examined for their germination rate and the presence or absence of abnormal symptoms. Table 2 shows the results.

INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide a safe slow-release granular fertilizer formulation containing an agricultural chemical that does not cause chemical damage to plants.

Claims (10)

An agricultural chemical-containing slow-release granular fertilizer formulation manufactured by a method for producing an agricultural chemical-containing slow-release granular fertilizer formulation containing a non-petroleum solvent and an active ingredient of an agricultural chemical,
The manufacturing method comprises impregnating or mixing a slow-release granular fertilizer with a previously prepared aqueous composition containing a mixture of one or more non-petroleum solvents and water and an agricultural chemical,
Non-petroleum solvents include ether solvents, nitrile solvents, alcohol solvents, ketone solvents, carbonate solvents, ester solvents, amide solvents, carbamide solvents, sulfoxide solvents, sulfone solvents, amine solvents, Aldehyde-based solvent, fatty acid ester-based solvent, nitrogen-containing carrier-based solvent, or glycol ether-based solvent, where the fatty acid ester-based solvent is coconut oil fatty acid methyl ester, succinic acid dimethyl ester, glutamic acid dimethyl ester, or adipate dimethyl ester and
The pesticide is at least one neonicotinoid selected from the group consisting of acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, or hydroxyisoxazole (hymexazole),
In the slow-release granular fertilizer formulation containing agricultural chemicals, the content of the agricultural chemical component is 0.01% to 10%, and the content of the non-petroleum solvent is 0.1% to 10%. A slow-release granular fertilizer formulation containing an agricultural chemical having a content of 50.0% to 99.9%. 2. The formulation according to claim 1, wherein the non-petroleum solvent has a water solubility of 100 ppm or more. the ether solvent is tetrahydrofuran or 1,4-dioxane,
the nitrile solvent is acetonitrile, propionitrile, butyronitrile, isobutyronitrile or malononitrile,
Alcohol solvents include methanol, ethanol, propanol, isopropanol, 1-butanol, 2-butanol, isobutanol, t-butanol, allyl alcohol, ethylene glycol, 1,2-propanediol (propylene glycol), 1,3-propane diol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol or glycerin;
the ketone-based solvent is acetone, methyl ethyl ketone or diethyl ketone,
the carbonate-based solvent is dimethyl carbonate, diethyl carbonate, ethylene carbonate or propylene carbonate;
the ester solvent is methyl formate, ethyl formate, methyl acetate, ethyl acetate, γ-butyrolactone, methyl lactate or ethyl lactate;
Amide solvent is formamide, N,N-dimethylformamide, N,N-diethylformamide, N,N-dimethylacetamide, N,N-diethylacetamide, N,N-dimethylpropionamide or N,N-dimethyllactamide and
the carbamide-based solvent is tetramethylurea or 1,3-dimethyl-2-imidazolidinone,
the sulfoxide solvent is dimethyl sulfoxide,
the sulfone-based solvent is dimethylsulfone or sulfolane,
Amine solvents include ammonia, methylamine, dimethylamine, diethylamine, triethylamine, isopropylamine, diisopropylamine, ethyldiisopropylamine, pyrrolidine, N-methylpyrrolidine, piperidine, N-methylpiperidine, morpholine, N-methylmorpholine, pyridine or ethanolamine,
the aldehyde solvent is formaldehyde, acetaldehyde, propionaldehyde, butanal or pentanal,
the nitrogen-containing carrier solvent is N-methylpyrrolidone or N-ethylpyrrolidone,
Glycol ether solvents include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monoisobutyl ether, ethylene glycol mono-t-butyl ether, ethylene glycol mono 2-methylpentyl ether, ethylene glycol monohexyl ether, ethylene glycol mono 2-ethyl-hexyl ether, ethylene glycol monovinyl ether, ethylene glycol monoallyl ether, ethylene glycol monobenzyl ether, ethylene glycol monophenyl ether, ethylene glycol dimethyl ether, ethylene Glycol diethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monoisopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monoisobutyl ether, diethylene glycol monohexyl ether, diethylene glycol mono-2-ethylhexyl ether, diethylene glycol monoallyl ether, diethylene glycol Monobenzyl ether, diethylene glycol monophenyl ether, diethylene glycol mono(methylphenyl) ether, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, diethylene glycol divinyl ether, diethylene glycol ethyl vinyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, triethylene glycol monovinyl ether, triethylene glycol dimethyl ether, tetraethylene glycol monophenyl ether, tetraethylene glycol diethyl ether, polyethylene glycol monomethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, Propylene Glycol Monopropyl Ether, Propylene Glycol Recall monoisopropyl ether, propylene glycol monobutyl ether, propylene glycol phenyl ether, propylene glycol mono(methylphenyl) ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol dipropyl ether, propylene glycol diisopropyl ether, propylene glycol dibutyl ether, propylene Glycol diisobutyl ether, propylene glycol diallyl ether, propylene glycol diphenyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, Dipropylene glycol dibutyl ether, dipropylene glycol diisobutyl ether, dipropylene glycol allyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether, tripropylene glycol monobutyl ether, butylene glycol monomethyl ether, butylene glycol dimethyl ether, isopropyl glycol, diisopropyl A formulation according to claim 1 or 2, which is glycol, dimethyldiglycol, methylethyldiglycol or 3-methoxy-3-methyl-1-butanol. 4. The formulation according to any one of claims 1 to 3, wherein the non-petroleum solvent is a glycol ether solvent. 5. A formulation according to any one of claims 1 to 4, wherein the aqueous composition further contains a liquid or liquid fertilizer. The slow-release granular fertilizer is a slow-release compound granular fertilizer, a synthetic slow-release granular fertilizer, a slow-release coated granular fertilizer, a slow-release pressurized granular fertilizer, or a slow-release nitration inhibitor compounded fertilizer, A formulation according to any one of claims 1-5. The slow-release granular fertilizer contains essential plant elements such as nitrogen (N), phosphorus (P), potassium (K), silicon (Si), magnesium (Mg), manganese (Mn), boron (B), calcium (Ca ) and sulfur (S). 8. The formulation according to claim 7, wherein the slow-release granular fertilizer contains nitrogen (N), phosphorus (P) and potassium (K) as essential plant elements in a ratio of guaranteed ingredients of 3:20:3. 8. The formulation according to claim 7, wherein the slow-release granular fertilizer contains nitrogen (N), phosphorus (P) and potassium (K) as essential plant elements in a ratio of guaranteed ingredients of 2:5:2. Use of the pesticide-containing slow-release granular fertilizer formulation according to any one of claims 1 to 9 for agriculture, horticulture or home horticulture.