JP2005531670A5 - - Google Patents
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- JP2005531670A5 JP2005531670A5 JP2004517963A JP2004517963A JP2005531670A5 JP 2005531670 A5 JP2005531670 A5 JP 2005531670A5 JP 2004517963 A JP2004517963 A JP 2004517963A JP 2004517963 A JP2004517963 A JP 2004517963A JP 2005531670 A5 JP2005531670 A5 JP 2005531670A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- catalyst system
- atom
- formula
- heterocyclic nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000003054 catalyst Substances 0.000 claims 10
- 125000004429 atom Chemical group 0.000 claims 6
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 claims 4
- -1 heterocyclic nitrogen-containing compound Chemical class 0.000 claims 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims 3
- 239000012190 activator Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 3
- 239000003446 ligand Substances 0.000 claims 3
- 239000002685 polymerization catalyst Substances 0.000 claims 3
- PAPNRQCYSFBWDI-UHFFFAOYSA-N 2,5-Dimethyl-1H-pyrrole Chemical compound CC1=CC=C(C)N1 PAPNRQCYSFBWDI-UHFFFAOYSA-N 0.000 claims 2
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-O 1H-indol-1-ium Chemical compound C1=CC=C2[NH2+]C=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-O 0.000 claims 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 claims 1
- RSEBUVRVKCANEP-UHFFFAOYSA-N 2-pyrroline Chemical compound C1CC=CN1 RSEBUVRVKCANEP-UHFFFAOYSA-N 0.000 claims 1
- BMJOPWQYDZAFDZ-UHFFFAOYSA-N 3,4-difluoro-1h-pyrrole Chemical compound FC1=CNC=C1F BMJOPWQYDZAFDZ-UHFFFAOYSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 229910013504 M-O-M Inorganic materials 0.000 claims 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 150000002391 heterocyclic compounds Chemical group 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims 1
- 125000001041 indolyl group Chemical group 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- ZVJHJDDKYZXRJI-UHFFFAOYSA-N pyrroline Natural products C1CC=NC1 ZVJHJDDKYZXRJI-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/186,361 US6703338B2 (en) | 2002-06-28 | 2002-06-28 | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
| PCT/US2003/020320 WO2004003032A2 (en) | 2002-06-28 | 2003-06-26 | Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005531670A JP2005531670A (ja) | 2005-10-20 |
| JP2005531670A5 true JP2005531670A5 (https=) | 2008-07-24 |
Family
ID=29999290
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517607A Expired - Fee Related JP4361862B2 (ja) | 2002-06-28 | 2003-05-29 | 重合用触媒の活性剤、その製造方法及び重合プロセスにおけるその使用 |
| JP2004517963A Withdrawn JP2005531670A (ja) | 2002-06-28 | 2003-06-26 | 複素環窒素含有活性化剤及びオレフィン重合用触媒系 |
| JP2004517894A Withdrawn JP2005530907A (ja) | 2002-06-28 | 2003-06-26 | オレフィン重合用のハロゲン置換触媒系 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517607A Expired - Fee Related JP4361862B2 (ja) | 2002-06-28 | 2003-05-29 | 重合用触媒の活性剤、その製造方法及び重合プロセスにおけるその使用 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517894A Withdrawn JP2005530907A (ja) | 2002-06-28 | 2003-06-26 | オレフィン重合用のハロゲン置換触媒系 |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US6703338B2 (https=) |
| EP (3) | EP1517930B1 (https=) |
| JP (3) | JP4361862B2 (https=) |
| KR (1) | KR100713748B1 (https=) |
| CN (4) | CN1659193B (https=) |
| AT (1) | ATE506381T1 (https=) |
| AU (3) | AU2003238849B2 (https=) |
| BR (3) | BR0305256A (https=) |
| CA (3) | CA2488052C (https=) |
| CZ (1) | CZ20041151A3 (https=) |
| DE (1) | DE60336812D1 (https=) |
| MX (1) | MXPA05000067A (https=) |
| MY (1) | MY137541A (https=) |
| NO (1) | NO20040872L (https=) |
| PL (1) | PL373380A1 (https=) |
| RU (1) | RU2293088C2 (https=) |
| SG (1) | SG173215A1 (https=) |
| TW (1) | TWI280252B (https=) |
| WO (3) | WO2004003031A2 (https=) |
| ZA (1) | ZA200409750B (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6274684B1 (en) | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
| US7741417B2 (en) * | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| US7220695B2 (en) * | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
| CN101903414A (zh) * | 2007-11-08 | 2010-12-01 | 埃克森美孚化学专利公司 | 金属茂的卤素取代的杂环型含杂原子的配体-铝氧烷活化 |
| US8022005B2 (en) * | 2007-11-08 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8524846B1 (en) | 2009-07-02 | 2013-09-03 | The University Of Toledo | Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts |
| US9045568B2 (en) | 2012-08-03 | 2015-06-02 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polyethylene with long chain branching |
| CA2877754C (en) * | 2012-08-03 | 2018-12-11 | Exxonmobil Chemical Patents Inc. | Catalysts comprising salan ligands |
| WO2014022010A2 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Non-symmetric catalysts comprising salan ligands |
| US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
| EP2880098B1 (en) | 2012-08-03 | 2018-01-10 | ExxonMobil Chemical Patents Inc. | Halogenated catalysts comprising salan ligands |
| US9365661B2 (en) | 2012-08-03 | 2016-06-14 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified salan catalyst compounds |
| US9120879B2 (en) | 2012-11-02 | 2015-09-01 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| SG11201506868UA (en) | 2013-03-13 | 2015-09-29 | Exxonmobil Chem Patents Inc | Diphenylamine salan catalyst |
| WO2014204625A1 (en) | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Salenol catalyst |
| WO2014204624A1 (en) * | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Thio-salalen catalyst |
| WO2014204681A1 (en) | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
| WO2015088819A1 (en) | 2013-12-13 | 2015-06-18 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| CN106132924B (zh) | 2014-03-31 | 2019-03-19 | 埃克森美孚化学专利公司 | 亚苯基桥连的salalen催化剂 |
| US10351647B2 (en) | 2015-05-29 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
| MX2018001111A (es) | 2015-07-31 | 2018-07-06 | Cargill Inc | Fibras citricas con caracteristicas de union al agua optimizadas. |
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| DE1302641B (https=) * | 1961-05-02 | 1970-12-10 | ||
| JPS5421391B1 (https=) * | 1969-07-10 | 1979-07-30 | ||
| US4224181A (en) * | 1979-03-07 | 1980-09-23 | Exxon Research & Engineering Co. | Ziegler type catalyst system |
| US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
| US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| IT1178466B (it) * | 1984-03-20 | 1987-09-09 | Montedison Spa | Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
| IT1251462B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5221761A (en) * | 1992-04-29 | 1993-06-22 | Instituto Guido Donegani | Melt transesterification process for the production of polycarbonates |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| EP0649992B1 (de) | 1993-10-23 | 1997-07-30 | WABCO GmbH | Betätigungseinrichtung für eine Scheibenbremse |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| EP0785955B1 (en) | 1994-10-13 | 1999-07-14 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| DE69502028T2 (de) * | 1994-10-31 | 1998-12-10 | Dsm N.V., Heerlen | Katalytische zusammensetzung und verfahren zur olefinpolymerisation |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
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| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
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| US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| JP2000035973A (ja) * | 1996-06-11 | 2000-02-02 | Masanobu Kujirada | 遠隔匂い発生システム |
| JP3889881B2 (ja) * | 1997-07-10 | 2007-03-07 | 三井化学株式会社 | オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| WO1999032525A1 (en) | 1997-12-23 | 1999-07-01 | The Dow Chemical Company | Finishing design to increase the polymer content in an olefin solution polymerization process |
| AU749065B2 (en) * | 1998-02-20 | 2002-06-20 | Dow Chemical Company, The | Catalyst activators comprising expanded anions |
| JP2002517571A (ja) * | 1998-06-12 | 2002-06-18 | ユニベーション・テクノロジーズ・エルエルシー | 活性化されたルイス酸−塩基錯体を使用するオレフィン重合方法 |
| US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
| CN1192033C (zh) * | 1998-10-08 | 2005-03-09 | 陶氏化学公司 | 桥连的金属配合物 |
| US6500949B2 (en) * | 1998-10-08 | 2002-12-31 | Dow Global Technologies Inc. | Bridged metal complexes |
| US6147173A (en) * | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| ES2217859T3 (es) * | 1998-12-12 | 2004-11-01 | Basell Polyolefine Gmbh | Compuesto de metal de transicion zwitterionico, neutro. |
| BR0013051A (pt) * | 1999-07-29 | 2002-04-02 | Dow Chemical Co | Processo para preparar interpolìmeros de olefinas funcionalizados com silano melhorados, produtos obtidos, derivados destes e seu uso |
| WO2001023442A1 (en) * | 1999-09-27 | 2001-04-05 | The Dow Chemical Company | Supported catalyst comprising expanded anions |
| EP1235767A1 (en) * | 1999-11-26 | 2002-09-04 | Sasol Technology (Proprietary) Limited | Hydrocarbon conversion process |
| DE60103702T2 (de) | 2000-02-24 | 2005-06-23 | Basell Polyolefine Gmbh | Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist |
| WO2001083447A2 (en) * | 2000-05-04 | 2001-11-08 | Sasol Technology (Pty) Ltd | A halopyrrole ligand for use in a catalyst system |
| WO2002008303A1 (en) * | 2000-07-20 | 2002-01-31 | The Dow Chemical Company | Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom |
| DE60205597T2 (de) * | 2001-03-19 | 2006-05-18 | Dow Global Technologies, Inc., Midland | Metall-komplexverbindungen mit einem acetylen-liganden, polymerisations-katalysatoren und ein additions-polymerisations-prozess |
| US7417006B2 (en) * | 2001-05-21 | 2008-08-26 | Basell Polyolefine Gmbh | Catalyst system for the polymerization of olefins |
| US7193024B2 (en) * | 2001-06-15 | 2007-03-20 | Dow Global Technology Inc. | Alpha-Olefin based branched polymer |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
-
2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
-
2003
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en not_active Ceased
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/en not_active Expired - Lifetime
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active Expired - Fee Related
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-06-26 EP EP03742245A patent/EP1517931B1/en not_active Expired - Lifetime
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en not_active Ceased
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en not_active Ceased
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 EP EP03742270A patent/EP1517932A2/en not_active Withdrawn
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
-
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown
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