DE60336812D1 - Npolymerisation - Google Patents
NpolymerisationInfo
- Publication number
- DE60336812D1 DE60336812D1 DE60336812T DE60336812T DE60336812D1 DE 60336812 D1 DE60336812 D1 DE 60336812D1 DE 60336812 T DE60336812 T DE 60336812T DE 60336812 T DE60336812 T DE 60336812T DE 60336812 D1 DE60336812 D1 DE 60336812D1
- Authority
- DE
- Germany
- Prior art keywords
- aluminoxane
- disclosed
- support material
- activators
- heterocyclic compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012190 activator Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Polyethers (AREA)
- Indole Compounds (AREA)
- Disintegrating Or Milling (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Tires In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/186,361 US6703338B2 (en) | 2002-06-28 | 2002-06-28 | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
| PCT/US2003/020199 WO2004003037A1 (en) | 2002-06-28 | 2003-06-26 | Halogen substituted catalyst system for olefin polymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60336812D1 true DE60336812D1 (en) | 2011-06-01 |
Family
ID=29999290
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60336812T Expired - Lifetime DE60336812D1 (en) | 2002-06-28 | 2003-06-26 | Npolymerisation |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US6703338B2 (https=) |
| EP (3) | EP1517930B1 (https=) |
| JP (3) | JP4361862B2 (https=) |
| KR (1) | KR100713748B1 (https=) |
| CN (4) | CN1659193B (https=) |
| AT (1) | ATE506381T1 (https=) |
| AU (3) | AU2003238849B2 (https=) |
| BR (3) | BR0305256A (https=) |
| CA (3) | CA2488052C (https=) |
| CZ (1) | CZ20041151A3 (https=) |
| DE (1) | DE60336812D1 (https=) |
| MX (1) | MXPA05000067A (https=) |
| MY (1) | MY137541A (https=) |
| NO (1) | NO20040872L (https=) |
| PL (1) | PL373380A1 (https=) |
| RU (1) | RU2293088C2 (https=) |
| SG (1) | SG173215A1 (https=) |
| TW (1) | TWI280252B (https=) |
| WO (3) | WO2004003031A2 (https=) |
| ZA (1) | ZA200409750B (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6274684B1 (en) | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
| US7741417B2 (en) * | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| US7220695B2 (en) * | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
| CN101903414A (zh) * | 2007-11-08 | 2010-12-01 | 埃克森美孚化学专利公司 | 金属茂的卤素取代的杂环型含杂原子的配体-铝氧烷活化 |
| US8022005B2 (en) * | 2007-11-08 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8524846B1 (en) | 2009-07-02 | 2013-09-03 | The University Of Toledo | Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts |
| US9045568B2 (en) | 2012-08-03 | 2015-06-02 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polyethylene with long chain branching |
| CA2877754C (en) * | 2012-08-03 | 2018-12-11 | Exxonmobil Chemical Patents Inc. | Catalysts comprising salan ligands |
| WO2014022010A2 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Non-symmetric catalysts comprising salan ligands |
| US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
| EP2880098B1 (en) | 2012-08-03 | 2018-01-10 | ExxonMobil Chemical Patents Inc. | Halogenated catalysts comprising salan ligands |
| US9365661B2 (en) | 2012-08-03 | 2016-06-14 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified salan catalyst compounds |
| US9120879B2 (en) | 2012-11-02 | 2015-09-01 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| SG11201506868UA (en) | 2013-03-13 | 2015-09-29 | Exxonmobil Chem Patents Inc | Diphenylamine salan catalyst |
| WO2014204625A1 (en) | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Salenol catalyst |
| WO2014204624A1 (en) * | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Thio-salalen catalyst |
| WO2014204681A1 (en) | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
| WO2015088819A1 (en) | 2013-12-13 | 2015-06-18 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| CN106132924B (zh) | 2014-03-31 | 2019-03-19 | 埃克森美孚化学专利公司 | 亚苯基桥连的salalen催化剂 |
| US10351647B2 (en) | 2015-05-29 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
| MX2018001111A (es) | 2015-07-31 | 2018-07-06 | Cargill Inc | Fibras citricas con caracteristicas de union al agua optimizadas. |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1302641B (https=) * | 1961-05-02 | 1970-12-10 | ||
| JPS5421391B1 (https=) * | 1969-07-10 | 1979-07-30 | ||
| US4224181A (en) * | 1979-03-07 | 1980-09-23 | Exxon Research & Engineering Co. | Ziegler type catalyst system |
| US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
| US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| IT1178466B (it) * | 1984-03-20 | 1987-09-09 | Montedison Spa | Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
| IT1251462B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5221761A (en) * | 1992-04-29 | 1993-06-22 | Instituto Guido Donegani | Melt transesterification process for the production of polycarbonates |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| EP0649992B1 (de) | 1993-10-23 | 1997-07-30 | WABCO GmbH | Betätigungseinrichtung für eine Scheibenbremse |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| EP0785955B1 (en) | 1994-10-13 | 1999-07-14 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| DE69502028T2 (de) * | 1994-10-31 | 1998-12-10 | Dsm N.V., Heerlen | Katalytische zusammensetzung und verfahren zur olefinpolymerisation |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| GB9522859D0 (en) * | 1995-11-08 | 1996-01-10 | Borealis As | Compounds |
| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
| US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| JP2000035973A (ja) * | 1996-06-11 | 2000-02-02 | Masanobu Kujirada | 遠隔匂い発生システム |
| JP3889881B2 (ja) * | 1997-07-10 | 2007-03-07 | 三井化学株式会社 | オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| WO1999032525A1 (en) | 1997-12-23 | 1999-07-01 | The Dow Chemical Company | Finishing design to increase the polymer content in an olefin solution polymerization process |
| AU749065B2 (en) * | 1998-02-20 | 2002-06-20 | Dow Chemical Company, The | Catalyst activators comprising expanded anions |
| JP2002517571A (ja) * | 1998-06-12 | 2002-06-18 | ユニベーション・テクノロジーズ・エルエルシー | 活性化されたルイス酸−塩基錯体を使用するオレフィン重合方法 |
| US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
| CN1192033C (zh) * | 1998-10-08 | 2005-03-09 | 陶氏化学公司 | 桥连的金属配合物 |
| US6500949B2 (en) * | 1998-10-08 | 2002-12-31 | Dow Global Technologies Inc. | Bridged metal complexes |
| US6147173A (en) * | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| ES2217859T3 (es) * | 1998-12-12 | 2004-11-01 | Basell Polyolefine Gmbh | Compuesto de metal de transicion zwitterionico, neutro. |
| BR0013051A (pt) * | 1999-07-29 | 2002-04-02 | Dow Chemical Co | Processo para preparar interpolìmeros de olefinas funcionalizados com silano melhorados, produtos obtidos, derivados destes e seu uso |
| WO2001023442A1 (en) * | 1999-09-27 | 2001-04-05 | The Dow Chemical Company | Supported catalyst comprising expanded anions |
| EP1235767A1 (en) * | 1999-11-26 | 2002-09-04 | Sasol Technology (Proprietary) Limited | Hydrocarbon conversion process |
| DE60103702T2 (de) | 2000-02-24 | 2005-06-23 | Basell Polyolefine Gmbh | Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist |
| WO2001083447A2 (en) * | 2000-05-04 | 2001-11-08 | Sasol Technology (Pty) Ltd | A halopyrrole ligand for use in a catalyst system |
| WO2002008303A1 (en) * | 2000-07-20 | 2002-01-31 | The Dow Chemical Company | Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom |
| DE60205597T2 (de) * | 2001-03-19 | 2006-05-18 | Dow Global Technologies, Inc., Midland | Metall-komplexverbindungen mit einem acetylen-liganden, polymerisations-katalysatoren und ein additions-polymerisations-prozess |
| US7417006B2 (en) * | 2001-05-21 | 2008-08-26 | Basell Polyolefine Gmbh | Catalyst system for the polymerization of olefins |
| US7193024B2 (en) * | 2001-06-15 | 2007-03-20 | Dow Global Technology Inc. | Alpha-Olefin based branched polymer |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
-
2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
-
2003
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en not_active Ceased
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/en not_active Expired - Lifetime
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active Expired - Fee Related
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-06-26 EP EP03742245A patent/EP1517931B1/en not_active Expired - Lifetime
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en not_active Ceased
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en not_active Ceased
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 EP EP03742270A patent/EP1517932A2/en not_active Withdrawn
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
-
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown
Also Published As
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