JP2005527716A5 - - Google Patents
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- Publication number
- JP2005527716A5 JP2005527716A5 JP2004507595A JP2004507595A JP2005527716A5 JP 2005527716 A5 JP2005527716 A5 JP 2005527716A5 JP 2004507595 A JP2004507595 A JP 2004507595A JP 2004507595 A JP2004507595 A JP 2004507595A JP 2005527716 A5 JP2005527716 A5 JP 2005527716A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- perfluorinated
- groups
- polyether
- fluorinated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920000570 polyether Polymers 0.000 claims 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims 14
- 239000000203 mixture Substances 0.000 claims 13
- 150000001875 compounds Chemical class 0.000 claims 7
- 125000005647 linker group Chemical group 0.000 claims 7
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 125000005529 alkyleneoxy group Chemical group 0.000 claims 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 2
- 125000000524 functional group Chemical group 0.000 claims 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 2
- 229920001228 polyisocyanate Polymers 0.000 claims 2
- 239000005056 polyisocyanate Substances 0.000 claims 2
- 239000000376 reactant Substances 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 239000004606 Fillers/Extenders Substances 0.000 claims 1
- 230000002411 adverse Effects 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- -1 carbodiimide compound Chemical class 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 125000005515 organic divalent group Chemical group 0.000 claims 1
- 125000000962 organic group Chemical group 0.000 claims 1
Claims (11)
- 繊維質基材の外観および/または感触に実質的に悪影響を及ぼさずに前記繊維質基材を撥油性および/または撥水性にするために適するフルオロケミカル組成物であって、1個以上の過フッ素化ポリエーテル基を含むフッ素化ポリエーテル化合物と1個以上のブロックトイソシアネート基を含む非フッ素化有機化合物および/またはカルボジイミド化合物を含むエキステンダーと含むフルオロケミカル組成物。
- 前記1個以上の過フッ素化ポリエーテル基は少なくとも750g/モルの分子量を有する、請求項1に記載のフルオロケミカル組成物。
- 前記組成物は、750g/モル未満の分子量を有する過フッ素化ポリエーテル部分および/または過フッ素化ポリエーテル基の過フッ素化末端基以外の6個を上回る炭素原子のパーフルオロ脂肪族基を含まず、または前記組成物は、過フッ素化ポリエーテル部分の末端基以外のパーフルオロ脂肪族基の全重量を基準にして10重量%以下の量で6個を上回る炭素原子の前記パーフルオロ脂肪族基を含み、および/または前記フルオロケミカル組成物中の過フッ素化ポリエーテル部分の全重量を基準にして10重量%以下の量で750g/モル未満の分子量を有する前記過フッ素化ポリエーテル基を含む、請求項2に記載のフルオロケミカル組成物。
- 前記フッ素化ポリエーテル化合物は一般式
Rf−Q−Tk (II)
(式中、Rfは一価過フッ素化ポリエーテル基を表し、Qは化学結合あるいは二価有機連結基または三価有機連結基を表し、Tは1個以上のツェレウィチノフ水素原子を有する官能基を表し、kは1または2である)
に対応する、請求項1に記載のフルオロケミカル組成物。 - 前記過フッ素化ポリエーテル基は次式
R1 f−O−R2 f−(R3 f)q−
(式中、R1 fは過フッ素化アルキル基を表し、R2 fは1、2、3または4個の炭素原子を有する過フッ素化アルキレンオキシ基または前記過フッ素化アルキレンオキシ基の混合基からなる過フッ素化ポリアルキレンオキシ基を表し、R3 fは過フッ素化アルキレン基を表し、qは0または1である)
に対応する、請求項1に記載のフルオロケミカル組成物。 - R2 fは次式
−[CF(CF3)−CF2O]n−
(式中、nは3〜25の整数である)
に対応する、請求項4に記載のフルオロケミカル組成物。 - 請求項1〜6のいずれか1項に記載のフルオロケミカル組成物を前記繊維質基材に被着させる工程を含む、繊維質基材を処理する方法。
- 繊維質基材に撥油性および/または撥水性の特性を付与する請求項1〜6のいずれか1項に記載のフルオロケミカル組成物の使用。
- 一般式
R1 f−[CF(CF3)−CF2O]n−CF(CF3)−A−Q1−Tk
(式中、R1 fは過フッ素化アルキル基を表し、nは3〜25の整数であり、Aはカルボニル基またはCH2基であり、Q1は有機三価連結基であり、kは2であり、Tはイソシアネート反応性基を表し、各Tは同じかまたは異なってもよい)
に対応する化合物。 - a.次式
R1 f−O−[CF(CF3)−CF2O]n−CF(CF3)−A−Q1−Tk
(式中、R1 fは過フッ素化アルキル基を表し、nは3〜25の整数であり、Aはカルボニル基またはCH2基であり、Q1は化学結合あるいは有機二価連結基または有機三価連結基であり、Tはイソシアネートと反応できる官能基を表し、kは1または2である)
のフッ素化ポリエーテル、
b.ポリイソシアネート化合物またはポリイソシアネート化合物の混合物および
c.任意にイソシアネート基と反応できる1種以上の共反応物
を含む反応物の組み合わせを反応させることにより得ることができるフッ素化ポリエーテル化合物。 - 次式
(PFE)u−W−(PFA)w
(式中、PFEは過フッ素化ポリエーテル基を表し、Wは二価非フッ素化有機連結基または多価非フッ素化有機連結基を表し、PFAは炭素原子数3〜18の過フッ素化脂肪族基を表し、uおよびwはそれぞれ少なくとも1である)に対応するフッ素化ポリエーテル化合物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US38308502P | 2002-05-24 | 2002-05-24 | |
PCT/US2003/016343 WO2003100159A1 (en) | 2002-05-24 | 2003-05-23 | Fluorochemical composition comprising perfluoropolyether and an extender for the treatment of fibrous substrates |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005527716A JP2005527716A (ja) | 2005-09-15 |
JP2005527716A5 true JP2005527716A5 (ja) | 2006-07-06 |
Family
ID=29584504
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004507595A Withdrawn JP2005527716A (ja) | 2002-05-24 | 2003-05-23 | 繊維質基材を処理するためのパーフルオロポリエーテルおよびエキステンダーを含むフルオロケミカル組成物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20040077237A1 (ja) |
EP (1) | EP1507918A1 (ja) |
JP (1) | JP2005527716A (ja) |
KR (1) | KR20050014834A (ja) |
CN (1) | CN1656279A (ja) |
AU (1) | AU2003239607A1 (ja) |
BR (1) | BR0311260A (ja) |
CA (1) | CA2487068A1 (ja) |
MX (1) | MXPA04011628A (ja) |
WO (1) | WO2003100159A1 (ja) |
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US20050249956A1 (en) * | 2004-05-07 | 2005-11-10 | Naiyong Jing | Stain repellent optical hard coating |
US20050249940A1 (en) * | 2004-05-07 | 2005-11-10 | 3M Innovative Properties Company | Fluoropolyether poly(meth)acryl compounds |
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CN101528807B (zh) * | 2004-07-01 | 2012-08-08 | 3M创新有限公司 | 硬涂料组合物及其方法 |
US20060013983A1 (en) * | 2004-07-15 | 2006-01-19 | 3M Innovative Properties Company | Adhesive delivery of oil and water repellents |
US8440779B2 (en) | 2004-11-04 | 2013-05-14 | 3M Innovative Properties Company | Carbodiimide compound and compositions for rendering substrates oil and water repellent |
US7682771B2 (en) * | 2004-12-29 | 2010-03-23 | 3M Innovative Properties Company | Compositions containing photosensitive fluorochemical and uses thereof |
JP2008527090A (ja) | 2004-12-30 | 2008-07-24 | スリーエム イノベイティブ プロパティズ カンパニー | 耐汚染性フルオロケミカル組成物 |
CA2593694A1 (en) * | 2004-12-30 | 2006-07-13 | 3M Innovative Properties Company | Articles comprising a fluorochemical surface layer and related methods |
US7652112B2 (en) | 2005-07-06 | 2010-01-26 | E.I. Du Pont De Nemours And Company | Polymeric extenders for surface effects |
US7674500B2 (en) | 2005-08-05 | 2010-03-09 | 3M Innovative Properties Company | Process for preserving wood using fluoro-materials |
AU2006278511A1 (en) * | 2005-08-05 | 2007-02-15 | 3M Innovative Properties Company | Repellent materials |
US20070066785A1 (en) * | 2005-09-22 | 2007-03-22 | Acosta Erick J | Triazole-containing fluorinated urethanes and ureas |
US20070066762A1 (en) * | 2005-09-22 | 2007-03-22 | Acosta Erick J | Triazole-containing fluorinated polymers |
US7722955B2 (en) | 2006-04-13 | 2010-05-25 | 3M Innovative Properties Company | Flooring substrate having a coating of a curable composition |
US20070265412A1 (en) * | 2006-05-09 | 2007-11-15 | 3M Innovative Properties Company | Extenders for fluorochemical treatment of fibrous substrates |
US7470745B2 (en) * | 2006-11-13 | 2008-12-30 | E. I. Du Pont De Nemours And Company | Perfluoroether based polymers |
US20080116414A1 (en) * | 2006-11-22 | 2008-05-22 | 3M Innovative Properties Company | Fluorochemical composition for treatment of a fibrous substrate |
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US8828098B2 (en) * | 2006-12-18 | 2014-09-09 | 3M Innovative Properties Company | Extenders for fluorochemical treatment of fibrous substrates |
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WO2008154345A1 (en) * | 2007-06-06 | 2008-12-18 | 3M Innovative Properties Company | Fluorinated ether compositions and methods of using the same |
EP2158264B1 (en) | 2007-06-08 | 2019-04-10 | 3M Innovative Properties Company | Blends of fluoroalkyl-containing ester oligomers with polydicarbodiimide(s) |
CN102149674A (zh) * | 2008-07-18 | 2011-08-10 | 3M创新有限公司 | 氟化醚化合物及其使用方法 |
WO2010030042A1 (en) * | 2008-09-15 | 2010-03-18 | Daikin Industries, Ltd. | Fluorosilicone polymers and surface treatment agent |
US20110232530A1 (en) * | 2008-11-25 | 2011-09-29 | Dams Rudolf J | Fluorinated ether urethanes and methods of using the same |
CN102317403A (zh) | 2008-12-18 | 2012-01-11 | 3M创新有限公司 | 使含烃地层与氟化醚组合物接触的方法 |
GB0919014D0 (en) | 2009-10-30 | 2009-12-16 | 3M Innovative Properties Co | Soll and stain resistant coating composition for finished leather substrates |
CN102337677B (zh) * | 2010-07-14 | 2014-03-19 | 杜邦公司 | 表面涂覆过的聚酯纤维基质及其制备方法 |
US10619057B2 (en) * | 2015-08-19 | 2020-04-14 | Hrl Laboratories, Llc | Compositions and methods for fabricating durable, low-ice-adhesion coatings |
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CN108603975B (zh) * | 2015-12-16 | 2020-12-22 | 普睿司曼股份公司 | 具有提高的耐高温性的光纤 |
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-
2003
- 2003-05-23 EP EP20030734156 patent/EP1507918A1/en not_active Withdrawn
- 2003-05-23 BR BR0311260A patent/BR0311260A/pt not_active IP Right Cessation
- 2003-05-23 MX MXPA04011628A patent/MXPA04011628A/es active IP Right Grant
- 2003-05-23 WO PCT/US2003/016343 patent/WO2003100159A1/en active Application Filing
- 2003-05-23 JP JP2004507595A patent/JP2005527716A/ja not_active Withdrawn
- 2003-05-23 CA CA 2487068 patent/CA2487068A1/en not_active Abandoned
- 2003-05-23 CN CNA038119064A patent/CN1656279A/zh active Pending
- 2003-05-23 AU AU2003239607A patent/AU2003239607A1/en not_active Abandoned
- 2003-05-23 US US10/444,415 patent/US20040077237A1/en not_active Abandoned
- 2003-05-23 KR KR10-2004-7019021A patent/KR20050014834A/ko not_active Application Discontinuation
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