JP2005525316A - アルキルグリコールアルコキシレートまたはアルキルジグリコールアルコキシレート、該アルコキシレートと界面活性剤との混合物および該アルコキシレートの使用 - Google Patents
アルキルグリコールアルコキシレートまたはアルキルジグリコールアルコキシレート、該アルコキシレートと界面活性剤との混合物および該アルコキシレートの使用 Download PDFInfo
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- -1 Alkyl glycol Chemical compound 0.000 title claims abstract description 68
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title claims abstract description 56
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title claims abstract description 55
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- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
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- 150000007513 acids Chemical class 0.000 description 1
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- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
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- 230000033228 biological regulation Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
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- 125000004432 carbon atom Chemical group C* 0.000 description 1
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- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
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- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
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- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000013583 drug formulation Substances 0.000 description 1
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- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
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- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
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- 229920003023 plastic Polymers 0.000 description 1
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- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
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- 239000000758 substrate Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
- C09K23/018—Mixtures of two or more different organic oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/42—Ethers, e.g. polyglycol ethers of alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
− 金属加工を含めて個人的範囲、工業的範囲および研究所の範囲内で清浄化するための多目的清浄剤、織物用洗剤、噴霧用清浄剤、食器洗い用洗剤、
− 印刷工業における湿分保持剤、版胴清浄剤および印刷板清浄剤、
− 化粧用配合物、製薬学的調製物および植物保護配合物、
− ラッカー工業およびシート工業における例えば紙、接着剤のための塗料、染料配合物、被覆剤、
− 例えば、インキジェット印刷、塗料、医薬品または化粧品における噴霧に使用するための配合物、
− 皮革処理、例えば皮革の脱脂および皮革の可脂、
− 金属処理、例えば耐蝕性配合物、切削剤、研磨剤または穿孔助剤および潤滑剤、
− 織物工業における配合物、例えば均等剤または糸清浄化のための配合物、
− 浮選助剤および発泡助剤。
7の平均エトキシル化度を有するC13〜C15−オキソアルコールエトキシレート2g/l(BASF AGのLutensol(登録商標)AO 7)の水溶液を、気泡圧力張力計(Lauda社の型式MPT 2)を用いて試験する。42mN/mの界面張力は、平衡であることが見出され、この場合この界面張力は、0.7秒後に達成される。
ジヒドロキシアルキン(Air Products社のSurfynol(登録商標)104 H)を印刷工業の典型的な湿潤剤配合物中で試験した。湿潤剤配合物は、グリセリン150g/l、水770g/l、燐酸二水素ナトリウム20g/l、コハク酸40g/l、Surfynol 104H 10g/lを含有していた。混濁溶液を澄明するために、クメンスルホネート40g/l(配合物A)または4のエトキシル化度を有するヘキシルグリコールエトキシレート20g/l(配合物B)を添加した。その次に、配合物を1:50の比で希釈し、したがって最終的には、ジヒドロキシアルキン0.2g/lの含量が存在していた。動力学的界面張力を気泡圧力張力計で測定した。
紙を前記方法により第1表中に記載された分散液で被覆した。被覆の際の小液滴の寸法をフラウンホーファー回折によって測定した。
Claims (14)
- C4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールに対して1〜8の平均アルコキシル化度になるまでC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールをC2〜C5−アルコキシドでアルコキシル化することによって得ることができる、アルキルグリコールアルコキシレートまたはアルキルジグリコールアルコキシレート。
- 平均で1〜8のアルコキシル化度を有する、請求項1記載のC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールのC2〜C5−アルコキシレートと、5g/l 水の量で溶解され20℃で45mN/m未満の界面張力を示す界面活性剤および/またはジヒドロキシアルキンまたはその誘導体とからなる混合物。
- 界面活性剤が非イオン界面活性剤であり、平均で3〜30のアルコキシル化度を有するC9〜C20−アルカノールのC2〜C5−アルコキシレートおよびその混合物から選択されている、請求項2記載の混合物。
- 界面活性剤が気泡貧有の界面活性剤または抑泡界面活性剤である、請求項2記載の混合物。
- 請求項2から4までのいずれか1項に記載の混合物または請求項1記載のアルキルグリコールアルコキシレートまたはアルキルジグリコールアルコキシレートを含有する、洗剤、清浄剤もしくは湿潤剤または化粧用配合物、製薬学的調製物もしくは植物保護配合物。
- 請求項2から4までのいずれか1項に記載の混合物または請求項1記載のアルキルグリコールアルコキシレートまたはアルキルジグリコールアルコキシレートを含有する、塗料、着色剤配合物、噴霧に使用するための配合物、被覆剤、接着剤、皮革処理剤、浮選助剤、金属処理剤、発泡助剤、湿分保持剤または織物処理剤。
- 混合物または薬剤の全質量に対してC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールのC2〜C5−アルコキシレート0.1〜20質量%を含有する、請求項2から4までのいずれか1項に記載の混合物または請求項5または6記載の薬剤。
- 水性界面活性剤配合物または水性分散液中での界面張力の減少および界面張力の調節の促進のための平均で1〜8のアルコキシル化度を有する請求項1記載のC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールのC2〜C5−アルコキシレートの使用。
- 可溶化剤としておよび非イオン界面活性剤を含有する、水性配合物中での湿潤助剤の可溶性を上昇させるための平均で1〜8のアルコキシル化度を有する請求項1記載のC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールのC2〜C5−アルコキシレートの使用。
- 界面活性剤含有の配合物の粘度を減少させるための平均で1〜8のアルコキシル化度を有する請求項1記載のC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールのC2〜C5−アルコキシレートの使用。
- 水性湿潤剤中で湿潤速度を上昇させるための平均で1〜8のアルコキシル化度を有する請求項1記載のC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールのC2〜C5−アルコキシレートの使用。
- 水、顔料、結合剤、および顔料に対して0.05〜5質量%の請求項2から4までのいずれか1項に記載の混合物または請求項1記載のアルキルグリコールアルコキシレートを含有する水性配合物が重要である、請求項6記載の被覆剤。
- 噴霧に使用するための配合物が重要である、請求項12記載の被覆剤。
- 噴霧に使用するための配合物中の小液滴の寸法を縮小するための平均で1〜8のアルコキシル化度を有する請求項1記載のC4〜C8−アルキルグリコールまたはC4〜C8−アルキルジグリコールのC2〜C5−アルコキシレートの使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2002102007 DE10202007A1 (de) | 2002-01-21 | 2002-01-21 | Alkylglykolalkoxylate, ihre Mischungen mit Tensiden und ihre Verwendung |
DE2002145886 DE10245886A1 (de) | 2002-09-30 | 2002-09-30 | Alkylglykolalkoxylate, oder -diglykolalkoxylate, ihre Mischungen mit Tensiden und ihre Verwendung |
PCT/EP2003/000551 WO2003060049A2 (de) | 2002-01-21 | 2003-01-21 | Alkylglykolalkoxylate oder -diglykolalkoxylate, ihre mischungen mit tensiden und ihre verwendung |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005525316A true JP2005525316A (ja) | 2005-08-25 |
JP2005525316A5 JP2005525316A5 (ja) | 2008-07-31 |
Family
ID=26010943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003560136A Pending JP2005525316A (ja) | 2002-01-21 | 2003-01-21 | アルキルグリコールアルコキシレートまたはアルキルジグリコールアルコキシレート、該アルコキシレートと界面活性剤との混合物および該アルコキシレートの使用 |
Country Status (15)
Country | Link |
---|---|
US (1) | US20050049167A1 (ja) |
EP (1) | EP1470208B1 (ja) |
JP (1) | JP2005525316A (ja) |
KR (1) | KR100967369B1 (ja) |
CN (1) | CN100529038C (ja) |
AT (1) | ATE340235T1 (ja) |
AU (1) | AU2003205637B8 (ja) |
BR (1) | BR0306796B1 (ja) |
CA (1) | CA2472966A1 (ja) |
DE (1) | DE50305115D1 (ja) |
DK (1) | DK1470208T3 (ja) |
ES (1) | ES2271528T3 (ja) |
MX (1) | MXPA04006222A (ja) |
MY (1) | MY137154A (ja) |
WO (1) | WO2003060049A2 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006320882A (ja) * | 2005-05-17 | 2006-11-30 | Aguro Gijutsu Kk | 選択湿式比重選別機 |
JP2010228988A (ja) * | 2009-03-27 | 2010-10-14 | Taiheiyo Cement Corp | 石灰岩の不純物除去方法およびシステム |
JP2012519073A (ja) * | 2009-03-04 | 2012-08-23 | ビーエーエスエフ ソシエタス・ヨーロピア | 磁性の疎水性凝集塊 |
JPWO2018124120A1 (ja) * | 2016-12-28 | 2019-10-31 | 花王株式会社 | 水系インク用の洗浄液 |
Families Citing this family (8)
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---|---|---|---|---|
DE10341724A1 (de) * | 2003-09-10 | 2005-04-21 | Basf Ag | In Alkalien stabile Alkoxylate |
DE10341725A1 (de) * | 2003-09-10 | 2005-04-21 | Basf Ag | Festes wasserfreies Kompositmaterial |
DE102004034646A1 (de) * | 2004-07-16 | 2006-02-16 | Basf Ag | Methode zur Beschleunigung der Netzung in Lacken |
HUE039798T2 (hu) | 2011-04-05 | 2019-02-28 | R J Roberts Consulting Pty Ltd | Nedvesítõ készítmény |
JP6849278B2 (ja) * | 2016-12-28 | 2021-03-24 | 花王株式会社 | 水系インク用の洗浄液 |
BR112021017180A2 (pt) * | 2019-04-03 | 2021-11-09 | Chemetall Gmbh | Método para purgar circuitos de pintura revestidos com uma tinta não curada, solução de limpeza de purga de base aquosa, e, concentrado para produzir a solução de limpeza de purga de base aquosa |
DE102019213539A1 (de) * | 2019-09-05 | 2021-03-11 | Henkel Ag & Co. Kgaa | Reinigungsroboter umfassend ein Reinigungstuch und ein Reinigungsmittel |
BR112022007924A2 (pt) * | 2019-11-06 | 2022-07-12 | Advanced Wetting Tech Pty Ltd | Composição umectante melhorada |
Family Cites Families (9)
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US3882038A (en) * | 1968-06-07 | 1975-05-06 | Union Carbide Corp | Cleaner compositions |
US4153545A (en) * | 1977-08-18 | 1979-05-08 | Ppg Industries, Inc. | Method for cleaning membrane filter |
US5259993A (en) * | 1992-01-21 | 1993-11-09 | Cook Composites And Polymers Co. | Aqueous cleaner |
EP0616026A1 (en) * | 1993-03-19 | 1994-09-21 | The Procter & Gamble Company | Concentrated cleaning compositions |
NZ260144A (en) * | 1993-04-12 | 1995-10-26 | Colgate Palmolive Co | Cleaning composition; contains three liquid phases which merge at a tricritical point; use for removing tar or grease from articles |
US5340495A (en) * | 1993-04-30 | 1994-08-23 | Siebert, Inc. | Compositions for cleaning ink from a printing press and methods thereof |
JPH1017803A (ja) * | 1996-07-08 | 1998-01-20 | Fuji Xerox Co Ltd | インクジェット記録用インク及びインクジェット記録方法 |
US6017872A (en) * | 1998-06-08 | 2000-01-25 | Ecolab Inc. | Compositions and process for cleaning and finishing hard surfaces |
DE10017197A1 (de) * | 2000-04-07 | 2001-10-11 | Basf Ag | Alkoholalkoxylate als schaumarme oder schaumdämpfende Tenside |
-
2003
- 2003-01-20 MY MYPI20030191A patent/MY137154A/en unknown
- 2003-01-21 ES ES03702481T patent/ES2271528T3/es not_active Expired - Lifetime
- 2003-01-21 CN CNB038025205A patent/CN100529038C/zh not_active Expired - Fee Related
- 2003-01-21 US US10/500,889 patent/US20050049167A1/en not_active Abandoned
- 2003-01-21 BR BRPI0306796-3B1A patent/BR0306796B1/pt not_active IP Right Cessation
- 2003-01-21 DK DK03702481T patent/DK1470208T3/da active
- 2003-01-21 AT AT03702481T patent/ATE340235T1/de not_active IP Right Cessation
- 2003-01-21 CA CA002472966A patent/CA2472966A1/en not_active Abandoned
- 2003-01-21 AU AU2003205637A patent/AU2003205637B8/en not_active Ceased
- 2003-01-21 DE DE50305115T patent/DE50305115D1/de not_active Expired - Lifetime
- 2003-01-21 JP JP2003560136A patent/JP2005525316A/ja active Pending
- 2003-01-21 EP EP03702481A patent/EP1470208B1/de not_active Expired - Lifetime
- 2003-01-21 WO PCT/EP2003/000551 patent/WO2003060049A2/de active IP Right Grant
- 2003-01-21 KR KR1020047011177A patent/KR100967369B1/ko active IP Right Grant
-
2004
- 2004-06-23 MX MXPA04006222A patent/MXPA04006222A/es active IP Right Grant
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006320882A (ja) * | 2005-05-17 | 2006-11-30 | Aguro Gijutsu Kk | 選択湿式比重選別機 |
JP2012519073A (ja) * | 2009-03-04 | 2012-08-23 | ビーエーエスエフ ソシエタス・ヨーロピア | 磁性の疎水性凝集塊 |
JP2010228988A (ja) * | 2009-03-27 | 2010-10-14 | Taiheiyo Cement Corp | 石灰岩の不純物除去方法およびシステム |
JPWO2018124120A1 (ja) * | 2016-12-28 | 2019-10-31 | 花王株式会社 | 水系インク用の洗浄液 |
Also Published As
Publication number | Publication date |
---|---|
AU2003205637B8 (en) | 2008-04-17 |
MY137154A (en) | 2008-12-31 |
EP1470208A2 (de) | 2004-10-27 |
KR20040073574A (ko) | 2004-08-19 |
MXPA04006222A (es) | 2004-11-01 |
AU2003205637B2 (en) | 2008-04-03 |
CN1620495A (zh) | 2005-05-25 |
AU2003205637A1 (en) | 2003-07-30 |
WO2003060049A3 (de) | 2004-03-25 |
DK1470208T3 (da) | 2006-11-27 |
DE50305115D1 (de) | 2006-11-02 |
US20050049167A1 (en) | 2005-03-03 |
ES2271528T3 (es) | 2007-04-16 |
CN100529038C (zh) | 2009-08-19 |
CA2472966A1 (en) | 2003-07-24 |
BR0306796B1 (pt) | 2013-12-31 |
WO2003060049A2 (de) | 2003-07-24 |
BR0306796A (pt) | 2006-04-11 |
KR100967369B1 (ko) | 2010-07-05 |
ATE340235T1 (de) | 2006-10-15 |
EP1470208B1 (de) | 2006-09-20 |
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