JP2005520023A - ビニルシランモノマーを含む架橋可能なアクリロシランポリマーの調製と使用 - Google Patents
ビニルシランモノマーを含む架橋可能なアクリロシランポリマーの調製と使用 Download PDFInfo
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- JP2005520023A JP2005520023A JP2003576484A JP2003576484A JP2005520023A JP 2005520023 A JP2005520023 A JP 2005520023A JP 2003576484 A JP2003576484 A JP 2003576484A JP 2003576484 A JP2003576484 A JP 2003576484A JP 2005520023 A JP2005520023 A JP 2005520023A
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- acrylosilane
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- monomers
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- 229920000642 polymer Polymers 0.000 title claims abstract description 159
- 239000000178 monomer Substances 0.000 title claims abstract description 94
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 title abstract description 9
- 238000002360 preparation method Methods 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims abstract description 59
- 239000008199 coating composition Substances 0.000 claims abstract description 43
- 239000002253 acid Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims description 31
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 24
- 239000011230 binding agent Substances 0.000 claims description 22
- 229910000077 silane Inorganic materials 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000000524 functional group Chemical group 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 11
- 239000012948 isocyanate Substances 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 239000004815 dispersion polymer Substances 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 150000002513 isocyanates Chemical class 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- 150000002118 epoxides Chemical class 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 14
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- 238000005260 corrosion Methods 0.000 abstract description 14
- 239000002904 solvent Substances 0.000 abstract description 13
- -1 vinyl alkoxy silanes Chemical class 0.000 description 26
- 238000006243 chemical reaction Methods 0.000 description 19
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
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- 150000003077 polyols Chemical group 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
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- 239000000126 substance Substances 0.000 description 8
- 239000004971 Cross linker Substances 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 7
- 125000005250 alkyl acrylate group Chemical group 0.000 description 7
- 239000003505 polymerization initiator Substances 0.000 description 7
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000004070 electrodeposition Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000005056 polyisocyanate Substances 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 125000004386 diacrylate group Chemical group 0.000 description 4
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 3
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 3
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920003270 Cymel® Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 2
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
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- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000013036 UV Light Stabilizer Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004873 anchoring Methods 0.000 description 2
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- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
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- 235000014113 dietary fatty acids Nutrition 0.000 description 2
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- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
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- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 2
- LKEDKQWWISEKSW-UHFFFAOYSA-N nonyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCOC(=O)C(C)=C LKEDKQWWISEKSW-UHFFFAOYSA-N 0.000 description 2
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
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- MOVRCMBPGBESLI-UHFFFAOYSA-N prop-2-enoyloxysilicon Chemical compound [Si]OC(=O)C=C MOVRCMBPGBESLI-UHFFFAOYSA-N 0.000 description 2
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- PYOKUURKVVELLB-UHFFFAOYSA-N trimethyl orthoformate Chemical compound COC(OC)OC PYOKUURKVVELLB-UHFFFAOYSA-N 0.000 description 2
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- CLHPBURJMZXHFZ-UHFFFAOYSA-N (1,2,2-trimethylcyclohexyl) prop-2-enoate Chemical compound CC1(C)CCCCC1(C)OC(=O)C=C CLHPBURJMZXHFZ-UHFFFAOYSA-N 0.000 description 1
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- PCLLJCFJFOBGDE-UHFFFAOYSA-N (5-bromo-2-chlorophenyl)methanamine Chemical compound NCC1=CC(Br)=CC=C1Cl PCLLJCFJFOBGDE-UHFFFAOYSA-N 0.000 description 1
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- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- VHMICKWLTGFITH-UHFFFAOYSA-N 2H-isoindole Chemical compound C1=CC=CC2=CNC=C21 VHMICKWLTGFITH-UHFFFAOYSA-N 0.000 description 1
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- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
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- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
- C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/095,951 US6767642B2 (en) | 2002-03-11 | 2002-03-11 | Preparation and use of crosslinkable acrylosilane polymers containing vinyl silane monomers |
| PCT/US2003/007355 WO2003078486A1 (en) | 2002-03-11 | 2003-03-11 | Preparation and use of crosslinkable acrylosilane polymers containing vinyl silane monomers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005520023A true JP2005520023A (ja) | 2005-07-07 |
| JP2005520023A5 JP2005520023A5 (enExample) | 2006-04-27 |
Family
ID=27788275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003576484A Withdrawn JP2005520023A (ja) | 2002-03-11 | 2003-03-11 | ビニルシランモノマーを含む架橋可能なアクリロシランポリマーの調製と使用 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6767642B2 (enExample) |
| EP (1) | EP1483305A1 (enExample) |
| JP (1) | JP2005520023A (enExample) |
| KR (1) | KR20040098662A (enExample) |
| CN (1) | CN1643009A (enExample) |
| AU (1) | AU2003223241A1 (enExample) |
| BR (1) | BR0311215A (enExample) |
| CA (1) | CA2477777A1 (enExample) |
| MX (1) | MXPA04008718A (enExample) |
| TW (1) | TW200307605A (enExample) |
| WO (1) | WO2003078486A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009067957A (ja) * | 2007-09-17 | 2009-04-02 | Kansai Paint Co Ltd | 塗料組成物及び塗膜形成方法 |
| JP2018505237A (ja) * | 2014-12-02 | 2018-02-22 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | コポリマーおよび当該コポリマーを含有する顔料入りコーティング剤 |
| JP2023525072A (ja) * | 2020-05-07 | 2023-06-14 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 二重反応性コーティング組成物、その製造及びその使用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050074617A1 (en) * | 2003-10-02 | 2005-04-07 | Jun Lin | Clearcoat composition having both windshield sealant and recoat adhesion |
| JP2005347636A (ja) * | 2004-06-04 | 2005-12-15 | Az Electronic Materials Kk | トレンチ・アイソレーション構造の形成方法 |
| US7838078B2 (en) * | 2004-08-30 | 2010-11-23 | E. I. Du Pont De Nemours And Company | Clearcoat composition compatible with both waterborne and solventborne basecoats |
| US7871669B2 (en) * | 2004-08-30 | 2011-01-18 | E.I. Du Pont De Nemours And Company | Method for achieving a durable two-tone finish on a vehicle |
| CN1312185C (zh) * | 2005-03-11 | 2007-04-25 | 华南理工大学 | 硅酸盐/多官能有机烷氧基硅烷交联聚丙烯酸盐吸水树脂的制备方法 |
| WO2007016234A2 (en) * | 2005-07-29 | 2007-02-08 | E. I. Du Pont De Nemours And Company | Method for producing damage resistant multi-layer coatings on an automotive body or part thereof |
| GB0623110D0 (en) * | 2006-11-21 | 2006-12-27 | Ciba Sc Holding Ag | Microcapules, their use and processes for their manufacture |
| KR100981613B1 (ko) * | 2007-12-31 | 2010-09-10 | 주식회사 노루홀딩스 | 고내후성 실리콘-아크릴레이트 수지의 제조방법 및 2액형자연 경화 도료의 제조방법 |
| JP5306669B2 (ja) * | 2008-02-29 | 2013-10-02 | ＡｚエレクトロニックマテリアルズＩｐ株式会社 | シリカ質膜の形成方法およびそれにより形成されたシリカ質膜 |
| US20090239043A1 (en) * | 2008-03-24 | 2009-09-24 | Ppg Industries Ohio, Inc. | Oleophilic compositions, coatings employing the same, and devices formed therefrom |
| CN101555385B (zh) * | 2009-05-07 | 2012-10-24 | 中国科学院广州化学研究所 | 一种水稀释型有机硅涂料及其制备方法 |
| CN103124752B (zh) | 2010-08-03 | 2015-04-01 | 巴斯夫欧洲公司 | 基于多乙烯基硅氧烷低聚物的聚合物分散体及其制备方法和用途 |
| CN102180975B (zh) * | 2011-04-07 | 2013-01-02 | 泸州北方化学工业有限公司 | 醋酸纤维素酯的制备工艺 |
| US20150210587A1 (en) * | 2014-01-27 | 2015-07-30 | Ppg Industries Ohio, Inc. | Method of forming a coated glass substrate |
| CN105017462B (zh) * | 2014-04-23 | 2017-10-24 | 南京工业大学 | 一类耐日晒荧光涂料乳液及其制备方法 |
| EP3227350B1 (de) * | 2014-12-02 | 2019-08-21 | BASF Coatings GmbH | Pigmentiertes beschichtungsmittel und daraus hergestellte beschichtungen |
| US10544250B2 (en) | 2014-12-02 | 2020-01-28 | Basf Coatings Gmbh | Pigmented coating agent and coatings produced therefrom |
| CN105601796B (zh) * | 2015-12-22 | 2018-10-02 | 上海金力泰化工股份有限公司 | 含多环基团的硅烷改性丙烯酸树脂及包含其的清漆组合物 |
| WO2017162811A1 (de) | 2016-03-23 | 2017-09-28 | Covestro Deutschland Ag | Härtbare zusammensetzungen auf basis von alkoxysilangruppen-haltigen prepolymeren |
| WO2017184814A1 (en) | 2016-04-21 | 2017-10-26 | Bridgestone Corporation | Terminal-functionalized polymer, rubber composition containing same and related processes |
| PL3363827T3 (pl) * | 2017-02-21 | 2020-06-15 | Hexion Research Belgium Sa | Wytwarzanie utwardzalnych w warunkach otoczenia sieciowalnych kopolimerów rozgałęzionego estru winylowego i winylosilanu oraz ich zastosowanie |
| US10947407B2 (en) | 2017-12-01 | 2021-03-16 | Essential Industries, Inc. | Coating compositions |
| KR20210001513A (ko) | 2019-06-28 | 2021-01-06 | 호서대학교 산학협력단 | 가교 아크릴 페인트 조성물 및 이의 제조 방법 |
| EP3771726A1 (en) * | 2019-07-30 | 2021-02-03 | Hexion Research Belgium SA | One pack ambient cure crosslinkable copolymers of vinyl branched ester and vinyl silane compositions and use thereof |
| CN116368164B (zh) * | 2020-10-28 | 2026-06-12 | 美国陶氏有机硅公司 | 有机硅-(甲基)丙烯酸酯共聚物及其制备和在个人护理组合物中使用的方法 |
| EP4056652A1 (de) | 2021-03-11 | 2022-09-14 | Covestro Deutschland AG | Alterungsbeständige feuchtigkeitshärtende zusammensetzungen |
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| FR2218351B1 (enExample) * | 1973-02-16 | 1976-05-14 | Protex Manuf Prod Chimiq | |
| US4603064A (en) | 1985-08-05 | 1986-07-29 | Ppg Industries, Inc. | Color plus clear coating method utilizing addition interpolymers from isobornyl (meth)acrylate which contain alkoxysilane and/or acyloxysilane groups |
| US4614777A (en) | 1985-08-05 | 1986-09-30 | Ppg Industries, Inc. | Addition interpolymers from isobornyl (meth)acrylate which contain alkoxysilane and/or acyloxysilane groups |
| US5276108A (en) | 1985-09-09 | 1994-01-04 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Curable resin and process for preparing the same |
| US5288771A (en) * | 1988-06-15 | 1994-02-22 | Kansai Paint Company, Limited | Water-dispersible core-shell resin which exhibits excellent sagging resistance in coatings |
| CA2014109C (en) | 1989-04-06 | 1999-08-31 | Toshiro Nambu | Coated material |
| US5252660A (en) * | 1990-12-17 | 1993-10-12 | E. I. Du Pont De Nemours And Company | Coating comprising solution organosilane polymer and silane functional dispersed polymer |
| US5162426A (en) | 1990-12-17 | 1992-11-10 | E. I. Du Pont De Nemours And Company | Coatings comprising dispersed polymers with silane crosslinking |
| US5244959A (en) * | 1990-12-17 | 1993-09-14 | E. I. Du Pont De Nemours And Company | Coatings comprising an organosilane solution polymer and a crosslink functional dispersed polymer |
| EP0598294A3 (en) | 1992-11-12 | 1994-06-22 | Kanegafuchi Chemical Ind | Room temperature cross-linkable aqueous composition and process for preparing the same. |
| KR100336216B1 (ko) * | 1993-12-22 | 2002-10-18 | 트렘코, 리미티드 | 수분-경화성변성아크릴중합체밀봉제조성물 |
| US6362301B1 (en) * | 1994-06-13 | 2002-03-26 | Rohm And Haas Company | Curable composition |
| US5886125A (en) | 1997-02-25 | 1999-03-23 | E. I. Du Pont De Nemours And Company | Crosslinkable copolymers comprising vinyl silane and vinyl esters of branched fatty acid |
| US6261642B1 (en) * | 1997-07-08 | 2001-07-17 | Kansai Paint Co., Ltd. | High-solids coating composition and method for forming topcoat using the same |
| WO1999019411A1 (en) | 1997-10-15 | 1999-04-22 | E.I. Du Pont De Nemours And Company | Coating compositions containing non-aqueous dispersed polymer, a silane functional acrylic polymer and a triazine |
| US6080816A (en) * | 1997-11-10 | 2000-06-27 | E. I. Du Pont De Nemours And Company | Coatings that contain reactive silicon oligomers |
-
2002
- 2002-03-11 US US10/095,951 patent/US6767642B2/en not_active Expired - Fee Related
-
2003
- 2003-02-19 TW TW92103411A patent/TW200307605A/zh unknown
- 2003-03-11 EP EP20030719371 patent/EP1483305A1/en not_active Withdrawn
- 2003-03-11 MX MXPA04008718A patent/MXPA04008718A/es unknown
- 2003-03-11 AU AU2003223241A patent/AU2003223241A1/en not_active Abandoned
- 2003-03-11 JP JP2003576484A patent/JP2005520023A/ja not_active Withdrawn
- 2003-03-11 KR KR10-2004-7014190A patent/KR20040098662A/ko not_active Withdrawn
- 2003-03-11 CA CA 2477777 patent/CA2477777A1/en not_active Abandoned
- 2003-03-11 CN CNA038058456A patent/CN1643009A/zh active Pending
- 2003-03-11 WO PCT/US2003/007355 patent/WO2003078486A1/en not_active Ceased
- 2003-03-11 BR BR0311215A patent/BR0311215A/pt not_active IP Right Cessation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009067957A (ja) * | 2007-09-17 | 2009-04-02 | Kansai Paint Co Ltd | 塗料組成物及び塗膜形成方法 |
| JP2018505237A (ja) * | 2014-12-02 | 2018-02-22 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | コポリマーおよび当該コポリマーを含有する顔料入りコーティング剤 |
| JP2023525072A (ja) * | 2020-05-07 | 2023-06-14 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 二重反応性コーティング組成物、その製造及びその使用 |
| JP7771086B2 (ja) | 2020-05-07 | 2025-11-17 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 二重反応性コーティング組成物、その製造及びその使用 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20040098662A (ko) | 2004-11-20 |
| BR0311215A (pt) | 2005-02-22 |
| AU2003223241A1 (en) | 2003-09-29 |
| WO2003078486A1 (en) | 2003-09-25 |
| CA2477777A1 (en) | 2003-09-25 |
| US20030170468A1 (en) | 2003-09-11 |
| MXPA04008718A (es) | 2004-12-06 |
| EP1483305A1 (en) | 2004-12-08 |
| US6767642B2 (en) | 2004-07-27 |
| CN1643009A (zh) | 2005-07-20 |
| TW200307605A (en) | 2003-12-16 |
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