JP2005511874A5 - - Google Patents

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Publication number
JP2005511874A5
JP2005511874A5 JP2003552829A JP2003552829A JP2005511874A5 JP 2005511874 A5 JP2005511874 A5 JP 2005511874A5 JP 2003552829 A JP2003552829 A JP 2003552829A JP 2003552829 A JP2003552829 A JP 2003552829A JP 2005511874 A5 JP2005511874 A5 JP 2005511874A5
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group
compound
component
composition according
composition
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JP2003552829A
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JP2005511874A (ja
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Priority claimed from US10/022,118 external-priority patent/US6890360B2/en
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Publication of JP2005511874A publication Critical patent/JP2005511874A/ja
Publication of JP2005511874A5 publication Critical patent/JP2005511874A5/ja
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Claims (14)

  1. (a)(1)1種または複数種の多官能性イソシアネート化合物;
    (2)1種または複数種の親水性ポリオキシアルキレン化合物;
    (3)次式:
    X−R1−Si−(Y)3
    (式中、Xは、−NH2;−SH;−OH;−N=C=O;または−NRH(Rは、フェニル、直鎖および分枝鎖の脂肪族、脂環式、および脂肪族エステル基からなる群から選択される)であり;R1は、アルキレン、ヘテロアルキレン、アラルキレン、またはヘテロアラルキレン基であり;
    各Yはそれぞれ独立して、ヒドロキシル;アルコキシ、アシルオキシ、ヘテロアルコキシ、ヘテロアシルオキシ、ハロ、およびオキシムからなる群から選択される加水分解性部位;またはフェニル、脂環式、直鎖脂肪族、および分枝鎖脂肪族からなる群から選択される非加水分解性部位であり、少なくとも1つのYは加水分解性部位である)の1種または複数種のシラン化合物;および
    (4)次式:
    f −Z−R 2 −X
    {式中、R f は、パーフルオロアルキル基またはパーフルオロへテロアルキル基であり;
    Zは、共有結合、スルホンアミド基、カルボキサミド基、カルボキシル基、またはスルホニル基から選択される連結基であり;
    2 は、炭素原子1〜14個の、直鎖または分枝鎖の二価アルキレン、シクロアルキレン、またはヘテロアルキレン基であり;
    Xは、−NH 2 ;−SH;−OH;−N=C=O;または−NRH(Rは、フェニル、直鎖および分枝鎖の脂肪族、脂環式、および脂肪族エステル基からなる群から選択される)であり;R 1 は、アルキレン、ヘテロアルキレン、アラルキレン、またはヘテロアラルキレン基である。}
    1種または複数種のフルオロケミカル単官能性化合物;
    の反応生成物を含む1種または複数種のウレタンを含む第1成分と、
    (b)前記フルオロケミカルウレタン化合物で処理され繊維基材の撥油性および/または撥水性あるいはソイル/ステインリリース性をさらに改善することができる、1種または複数種の親水性補助化合物を含む第2成分と、
    を含有する化学組成物。
  2. fが、炭素2〜12個のパーフルオロアルキル基である、請求項に記載の化学組成物。
  3. 前記第2補助成分が、ポリイソシアネート、ブロック剤、ポリオキシアルキレン化合物の反応生成物である、請求項1に記載の組成物。
  4. 前記第2成分のポリイソシアネートの前記イソシアネート基が、ブロックイソシアネート基である、請求項に記載の組成物。
  5. 前記第1成分の前記親水性ポリオキシアルキレン化合物の量が、前記ウレタン化合物の利用可能なイソシアネート基の0.1〜30%と反応するのに十分な量であり、前記シラン化合物の量が、前記ウレタン化合物の利用可能なイソシアネート基の0.1〜25%と反応するのに十分な量であり、かつ前記フルオロケミカル単官能性化合物の量が、前記ウレタン化合物の利用可能なイソシアネート基の60〜90%と反応するのに十分な量である、請求項1に記載の組成物。
  6. 前記第2成分の前記ポリオキシアルキレン化合物の量が、前記補助化合物の利用可能なイソシアネート基の約25〜約75%が反応するような量である、請求項に記載の組成物。
  7. 前記第1成分のウレタン化合物と前記第2補助化合物との比が、12:1〜1:12である、請求項1に記載の組成物。
  8. 前記第1成分の前記ポリオキシアルキレン化合物が、1を超える官能価を有する、請求項1に記載の組成物。
  9. 前記第2成分の前記ポリオキシアルキレン化合物が、1の官能価を有する、請求項に記載の組成物。
  10. 請求項1〜9のいずれか一項に記載の化学組成物と溶媒との溶液を含む、処理用組成物。
  11. 化学組成物を約0.1〜約50%含有する、請求項10に記載の処理用組成物。
  12. 求項10に記載の処理用組成物から得られる硬化されたコーティングを有する繊維基材を含む物品。
  13. 請求項10に記載の処理用組成物を塗布する段階と、そのコーティング組成物を硬化させる段階と、を含む繊維基材にステインリリース特性を付与する方法。
  14. 前記コーティング組成物が、繊維上に固体0.05%〜5%を提供するのに十分な量で塗布される、請求項13に記載の方法。
JP2003552829A 2001-12-17 2002-10-22 繊維基材の処理に用いられるフルオロケミカルウレタン組成物 Pending JP2005511874A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/022,118 US6890360B2 (en) 2001-12-17 2001-12-17 Fluorochemical urethane composition for treatment of fibrous substrates
PCT/US2002/033781 WO2003051953A1 (en) 2001-12-17 2002-10-22 Fluorochemical urethane composition for treatment of fibrous substrates

Publications (2)

Publication Number Publication Date
JP2005511874A JP2005511874A (ja) 2005-04-28
JP2005511874A5 true JP2005511874A5 (ja) 2006-01-05

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JP2003552829A Pending JP2005511874A (ja) 2001-12-17 2002-10-22 繊維基材の処理に用いられるフルオロケミカルウレタン組成物

Country Status (9)

Country Link
US (1) US6890360B2 (ja)
EP (1) EP1458782B1 (ja)
JP (1) JP2005511874A (ja)
KR (1) KR20040068260A (ja)
CN (1) CN100406486C (ja)
AT (1) ATE493453T1 (ja)
AU (1) AU2002342090A1 (ja)
DE (1) DE60238787D1 (ja)
WO (1) WO2003051953A1 (ja)

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