JP2005509685A - アシルホスフィン及びその誘導体のマルチマー形態 - Google Patents

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Publication number

JP2005509685A

JP2005509685A JP2003545667A JP2003545667A JP2005509685A JP 2005509685 A JP2005509685 A JP 2005509685A JP 2003545667 A JP2003545667 A JP 2003545667A JP 2003545667 A JP2003545667 A JP 2003545667A JP 2005509685 A JP2005509685 A JP 2005509685A

Authority

JP

Japan

Prior art keywords

alkyl

substituted

phenyl

unsubstituted

lithium

Prior art date

2001-11-20

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

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• 125000000217 alkyl group Chemical group 0.000 claims abstract description 185
• -1 1- Cyclopentyl Chemical group 0.000 claims abstract description 157
• 150000001875 compounds Chemical class 0.000 claims abstract description 94
• 229910052717 sulfur Inorganic materials 0.000 claims abstract description 58
• 229910052760 oxygen Inorganic materials 0.000 claims abstract description 57
• 229910052736 halogen Inorganic materials 0.000 claims abstract description 41
• 150000002367 halogens Chemical class 0.000 claims abstract description 41
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract description 20
• 125000003118 aryl group Chemical group 0.000 claims abstract description 19
• 125000005647 linker group Chemical group 0.000 claims abstract description 19
• 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 18
• 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 18
• 125000000392 cycloalkenyl group Chemical group 0.000 claims abstract description 12
• 125000001624 naphthyl group Chemical group 0.000 claims abstract description 12
• 125000003342 alkenyl group Chemical group 0.000 claims abstract description 10
• 125000000623 heterocyclic group Chemical group 0.000 claims abstract description 10
• 125000004350 aryl cycloalkyl group Chemical group 0.000 claims abstract description 8
• 239000000203 mixture Substances 0.000 claims description 100
• 238000000576 coating method Methods 0.000 claims description 79
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 79
• 229910052739 hydrogen Inorganic materials 0.000 claims description 66
• 239000001257 hydrogen Substances 0.000 claims description 64
• 150000002431 hydrogen Chemical class 0.000 claims description 54
• 239000011248 coating agent Substances 0.000 claims description 52
• PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 claims description 34
• 238000004519 manufacturing process Methods 0.000 claims description 31
• 239000000463 material Substances 0.000 claims description 30
• 125000002947 alkylene group Chemical group 0.000 claims description 27
• 238000000034 method Methods 0.000 claims description 27
• 239000000178 monomer Substances 0.000 claims description 25
• 239000000654 additive Substances 0.000 claims description 23
• 125000003545 alkoxy group Chemical group 0.000 claims description 23
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 22
• 229920000642 polymer Polymers 0.000 claims description 20
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 18
• 238000007639 printing Methods 0.000 claims description 18
• 239000000758 substrate Substances 0.000 claims description 18
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 17
• 239000000843 powder Substances 0.000 claims description 17
• 239000013307 optical fiber Substances 0.000 claims description 15
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 14
• 229910052799 carbon Inorganic materials 0.000 claims description 13
• 125000004432 carbon atom Chemical group C* 0.000 claims description 13
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 12
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 12
• 239000004305 biphenyl Substances 0.000 claims description 10
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
• 230000003287 optical effect Effects 0.000 claims description 10
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
• 235000010290 biphenyl Nutrition 0.000 claims description 9
• 239000003365 glass fiber Substances 0.000 claims description 9
• 238000007645 offset printing Methods 0.000 claims description 9
• 230000000996 additive effect Effects 0.000 claims description 7
• 125000004450 alkenylene group Chemical group 0.000 claims description 7
• 239000002131 composite material Substances 0.000 claims description 7
• 229910052731 fluorine Inorganic materials 0.000 claims description 7
• 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 7
• 238000007650 screen-printing Methods 0.000 claims description 7
• 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 6
• 125000004956 cyclohexylene group Chemical group 0.000 claims description 5
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 5
• 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 4
• 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims description 4
• PCPQWYHRMVULIX-UHFFFAOYSA-P [1-[2,3-dihydroxy-4-[4-(oxoazaniumylmethylidene)pyridin-1-yl]butyl]pyridin-4-ylidene]methyl-oxoazanium;dinitrate Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.C1=CC(=C[NH+]=O)C=CN1CC(O)C(O)CN1C=CC(=C[NH+]=O)C=C1 PCPQWYHRMVULIX-UHFFFAOYSA-P 0.000 claims description 4
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
• 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 4
• 239000000853 adhesive Substances 0.000 claims description 3
• 230000001070 adhesive effect Effects 0.000 claims description 3
• 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 claims description 3
• NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 3
• 239000003094 microcapsule Substances 0.000 claims description 3
• 125000001422 pyrrolinyl group Chemical group 0.000 claims description 3
• 238000012360 testing method Methods 0.000 claims description 3
• 125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 2
• 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 2
• 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 2
• 125000004419 alkynylene group Chemical group 0.000 claims description 2
• 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 2
• 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 2
• 238000005538 encapsulation Methods 0.000 claims description 2
• ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 2
• 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 claims description 2
• 125000001153 fluoro group Chemical group F* 0.000 claims description 2
• 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 2
• 230000001678 irradiating effect Effects 0.000 claims description 2
• 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 claims description 2
• 125000001064 morpholinomethyl group Chemical group [H]C([H])(*)N1C([H])([H])C([H])([H])OC([H])([H])C1([H])[H] 0.000 claims description 2
• 125000001424 substituent group Chemical group 0.000 claims description 2
• 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
• 125000000319 biphenyl-4-yl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 claims 1
• 238000004061 bleaching Methods 0.000 claims 1
• 239000005548 dental material Substances 0.000 claims 1
• 125000003710 aryl alkyl group Chemical group 0.000 abstract description 7
• 229910052744 lithium Inorganic materials 0.000 description 45
• 239000000049 pigment Substances 0.000 description 37
• WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 32
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 28
• 238000006243 chemical reaction Methods 0.000 description 22
• 239000000460 chlorine Substances 0.000 description 19
• 238000001723 curing Methods 0.000 description 18
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 17
• 239000000976 ink Substances 0.000 description 17
• 230000005855 radiation Effects 0.000 description 17
• 239000010410 layer Substances 0.000 description 16
• 238000002360 preparation method Methods 0.000 description 16
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
• 229920001577 copolymer Polymers 0.000 description 15
• 239000000243 solution Substances 0.000 description 15
• 239000002904 solvent Substances 0.000 description 15
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 14
• 238000009472 formulation Methods 0.000 description 14
• YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 14
• XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
• XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 12
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
• 150000001266 acyl halides Chemical class 0.000 description 12
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
• 150000001412 amines Chemical class 0.000 description 11
• 239000000835 fiber Substances 0.000 description 11
• 239000003973 paint Substances 0.000 description 11
• 229920005862 polyol Polymers 0.000 description 11
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 10
• 239000003795 chemical substances by application Substances 0.000 description 10
• 229910052751 metal Inorganic materials 0.000 description 10
• 239000002184 metal Substances 0.000 description 10
• 229920005989 resin Polymers 0.000 description 10
• 239000011347 resin Substances 0.000 description 10
• TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 9
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 9
• 239000000975 dye Substances 0.000 description 9
• 239000010408 film Substances 0.000 description 9
• 229920000728 polyester Polymers 0.000 description 9
• XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 8
• UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 8
• 229910052801 chlorine Inorganic materials 0.000 description 8
• 239000003085 diluting agent Substances 0.000 description 8
• 239000003999 initiator Substances 0.000 description 8
• 239000007788 liquid Substances 0.000 description 8
• 229920002120 photoresistant polymer Polymers 0.000 description 8
• 229920001296 polysiloxane Polymers 0.000 description 8
• 239000007787 solid Substances 0.000 description 8
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 7
• FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 7
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
• 125000001931 aliphatic group Chemical group 0.000 description 7
• 239000008199 coating composition Substances 0.000 description 7
• 125000002993 cycloalkylene group Chemical group 0.000 description 7
• 239000006185 dispersion Substances 0.000 description 7
• 229910000073 phosphorus hydride Inorganic materials 0.000 description 7
• 150000003077 polyols Chemical class 0.000 description 7
• 239000000600 sorbitol Substances 0.000 description 7
• 238000003756 stirring Methods 0.000 description 7
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
• 125000003860 C1-C20 alkoxy group Chemical group 0.000 description 6
• 0 CCc1c(C)c([*-])c(C)c(C)c1C Chemical compound CCc1c(C)c([*-])c(C)c(C)c1C 0.000 description 6
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
• LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 6
• 238000005481 NMR spectroscopy Methods 0.000 description 6
• 239000006096 absorbing agent Substances 0.000 description 6
• 229910052786 argon Inorganic materials 0.000 description 6
• 125000000732 arylene group Chemical group 0.000 description 6
• 229910052794 bromium Inorganic materials 0.000 description 6
• 125000005724 cycloalkenylene group Chemical group 0.000 description 6
• 150000002009 diols Chemical class 0.000 description 6
• 150000002148 esters Chemical class 0.000 description 6
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
• 238000002844 melting Methods 0.000 description 6
• 230000008018 melting Effects 0.000 description 6
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
• 229910052753 mercury Inorganic materials 0.000 description 6
• 239000003960 organic solvent Substances 0.000 description 6
• 238000007254 oxidation reaction Methods 0.000 description 6
• 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 6
• 229920000647 polyepoxide Polymers 0.000 description 6
• 229920000570 polyether Polymers 0.000 description 6
• 239000004814 polyurethane Substances 0.000 description 6
• 229920002635 polyurethane Polymers 0.000 description 6
• 230000008569 process Effects 0.000 description 6
• 239000000047 product Substances 0.000 description 6
• 150000003254 radicals Chemical class 0.000 description 6
• 239000000126 substance Substances 0.000 description 6
• RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 5
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
• 239000005977 Ethylene Substances 0.000 description 5
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
• YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
• 229910003849 O-Si Inorganic materials 0.000 description 5
• 229910003872 O—Si Inorganic materials 0.000 description 5
• 239000004721 Polyphenylene oxide Substances 0.000 description 5
• NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 5
• PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 5
• 150000004056 anthraquinones Chemical class 0.000 description 5
• 239000012298 atmosphere Substances 0.000 description 5
• 239000012965 benzophenone Substances 0.000 description 5
• 239000011230 binding agent Substances 0.000 description 5
• 150000001735 carboxylic acids Chemical class 0.000 description 5
• 239000007859 condensation product Substances 0.000 description 5
• DVIDIZXCFDHODG-UHFFFAOYSA-N cyclopentylphosphane Chemical compound PC1CCCC1 DVIDIZXCFDHODG-UHFFFAOYSA-N 0.000 description 5
• 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 5
• JLHMVTORNNQCRM-UHFFFAOYSA-N ethylphosphine Chemical compound CCP JLHMVTORNNQCRM-UHFFFAOYSA-N 0.000 description 5
• 239000011737 fluorine Substances 0.000 description 5
• PWFZLKWEXYJYQO-UHFFFAOYSA-N lithium;phenylphosphanyl-(2,4,6-trimethylphenyl)methanone Chemical compound [Li].CC1=CC(C)=CC(C)=C1C(=O)PC1=CC=CC=C1 PWFZLKWEXYJYQO-UHFFFAOYSA-N 0.000 description 5
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
• 239000002609 medium Substances 0.000 description 5
• 150000002734 metacrylic acid derivatives Chemical class 0.000 description 5
• 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 5
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• 230000003647 oxidation Effects 0.000 description 5
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• 239000007858 starting material Substances 0.000 description 5
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
• KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
• GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 4
• VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 4
• KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
• QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
• 239000004952 Polyamide Substances 0.000 description 4
• 239000002202 Polyethylene glycol Substances 0.000 description 4
• OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
• RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 4
• 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 4
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
• 239000006227 byproduct Substances 0.000 description 4
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• 229910052802 copper Inorganic materials 0.000 description 4
• 239000010949 copper Substances 0.000 description 4
• JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
• QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 4
• SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 4
• 238000001035 drying Methods 0.000 description 4
• 238000010894 electron beam technology Methods 0.000 description 4
• 239000003995 emulsifying agent Substances 0.000 description 4
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• 239000007789 gas Substances 0.000 description 4
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• 235000011187 glycerol Nutrition 0.000 description 4
• 238000010438 heat treatment Methods 0.000 description 4
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• 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 4
• CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 4
• 238000000016 photochemical curing Methods 0.000 description 4
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• 229920006395 saturated elastomer Polymers 0.000 description 4
• 150000003568 thioethers Chemical class 0.000 description 4
• YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 4
• 239000004408 titanium dioxide Substances 0.000 description 4
• 229920006337 unsaturated polyester resin Polymers 0.000 description 4
• 239000000080 wetting agent Substances 0.000 description 4
• 239000002023 wood Substances 0.000 description 4
• 235000014692 zinc oxide Nutrition 0.000 description 4
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