JP2005290339A - 接着剤組成物 - Google Patents
接着剤組成物 Download PDFInfo
- Publication number
- JP2005290339A JP2005290339A JP2004134886A JP2004134886A JP2005290339A JP 2005290339 A JP2005290339 A JP 2005290339A JP 2004134886 A JP2004134886 A JP 2004134886A JP 2004134886 A JP2004134886 A JP 2004134886A JP 2005290339 A JP2005290339 A JP 2005290339A
- Authority
- JP
- Japan
- Prior art keywords
- block copolymer
- styrene block
- double bond
- liquid rubber
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 25
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 229920001971 elastomer Polymers 0.000 claims abstract description 20
- 239000005060 rubber Substances 0.000 claims abstract description 20
- 229920006132 styrene block copolymer Polymers 0.000 claims abstract description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 14
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 9
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 9
- 239000003505 polymerization initiator Substances 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims description 2
- -1 polypropylene Polymers 0.000 abstract description 17
- 229920002635 polyurethane Polymers 0.000 abstract description 9
- 239000004743 Polypropylene Substances 0.000 abstract description 8
- 229920000098 polyolefin Polymers 0.000 abstract description 8
- 229920001155 polypropylene Polymers 0.000 abstract description 8
- 239000004814 polyurethane Substances 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 8
- 238000000465 moulding Methods 0.000 abstract description 6
- 239000004698 Polyethylene Substances 0.000 abstract description 4
- 229910052736 halogen Inorganic materials 0.000 abstract description 4
- 150000002367 halogens Chemical class 0.000 abstract description 4
- 229920000573 polyethylene Polymers 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000004342 Benzoyl peroxide Substances 0.000 description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- 229920005672 polyolefin resin Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229920005830 Polyurethane Foam Polymers 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 229920001084 poly(chloroprene) Polymers 0.000 description 3
- 239000011496 polyurethane foam Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 229920002397 thermoplastic olefin Polymers 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- LVMTVPFRTKXRPH-UHFFFAOYSA-N penta-1,2-diene Chemical compound CCC=C=C LVMTVPFRTKXRPH-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
【解決手段】
二重結合を有するスチレンブロック共重合体と、二重結合および一分子中に1.5個以上の水酸基を有する液状ゴムを重合開始剤と共に加熱撹拌し、得られた物質にポリイソシアネートと反応させたプレポリマーを主成分とし、且つスチレンブロック共重合体/液状ゴムの比率が20/80〜80/20であることを特徴とする接着剤組成物をプレポリマー化することを特徴とする接着剤の製造方法。
【選択図】なし
Description
開始剤の使用量は通常スチレンブロック共重合体と液状ゴムを足した100重量部に対し好ましくは0.01〜5重量部の範囲で添加すればよい。加熱温度および加熱時間は使用する開始剤等によって異なるが、例えば、70〜110℃で、1〜24時間、窒素置換下で、例えばトルエン等の有機溶剤の溶液中で反応すればよい。更にこの反応後にプレポリマーを行うことで所望の特性が得られる。
得られた接着剤をスプレーガンを使用し、ポリプロピレン成形品上に塗布(塗布量;150g/m2−wet)し、80℃に設定した乾燥炉により2分間乾燥した。20℃雰囲気中に5分間放置した該ポリプロピレン成形品と自動車内装表皮材(布地からなる表層材とポリウレタンを主成分とした発泡体2mm厚のラミネート品)とをプレス成形により接着した。
接着品を20℃・65%RH雰囲気中に1日養生し、20℃雰囲気中での引張試験機による180°はく離接着強度を測定した。
接着品を20℃・65%RH雰囲気中に1日養生し、80℃雰囲気中で表皮材の一端に垂直方向に200g/25mmの荷重をかけ24時間のクリープ試験を行い、はく離長さを測定した。試験結果を表1に示す。
Claims (3)
- 二重結合を有するスチレンブロック共重合体と、二重結合および一分子中に1.5個以上の水酸基を有する液状ゴムと重合開始剤を加熱撹拌し、得られた物質にポリイソシアネートを反応させたプレポリマーを主成分とする接着剤組成物。
- 請求項1記載のスチレンブロック共重合体/液状ゴムの比率が90/10〜30/70であることを特徴とする接着剤組成物。
- 二重結合を有するスチレンブロック共重合体と、二重結合および一分子中に1.5個以上の水酸基を有する液状ゴムと重合開始剤を加熱撹拌した後、プレポリマー化することを特徴とする接着剤の製造方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004134886A JP4685367B2 (ja) | 2004-04-01 | 2004-04-01 | 接着剤組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004134886A JP4685367B2 (ja) | 2004-04-01 | 2004-04-01 | 接着剤組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005290339A true JP2005290339A (ja) | 2005-10-20 |
JP4685367B2 JP4685367B2 (ja) | 2011-05-18 |
Family
ID=35323626
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004134886A Expired - Lifetime JP4685367B2 (ja) | 2004-04-01 | 2004-04-01 | 接着剤組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4685367B2 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017061061A1 (ja) | 2015-10-05 | 2017-04-13 | 日立化成株式会社 | 接着剤組成物 |
WO2020246063A1 (ja) | 2019-06-06 | 2020-12-10 | 昭和電工マテリアルズ株式会社 | ホットメルト接着剤組成物 |
US11390780B2 (en) | 2017-03-30 | 2022-07-19 | Showa Denko Materials Co., Ltd. | Adhesive composition |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57143376A (en) * | 1981-03-03 | 1982-09-04 | Hitachi Cable Ltd | Two-pack type adhesive composition |
JPH06329999A (ja) * | 1993-05-17 | 1994-11-29 | Daiabondo Kogyo Kk | 粘着材,粘着テープ及び粘着シート |
JPH08300577A (ja) * | 1995-05-12 | 1996-11-19 | Hitachi Kasei Polymer Co Ltd | 自動車内装用プレコート表皮材 |
JPH10292161A (ja) * | 1997-04-16 | 1998-11-04 | Hitachi Kasei Polymer Co Ltd | ポリオレフィン用接着テープ |
JP2001115124A (ja) * | 1998-12-08 | 2001-04-24 | Nitto Denko Corp | 粘着剤組成物およびその製造方法と粘着シ―ト類 |
JP2004010719A (ja) * | 2002-06-05 | 2004-01-15 | Kuraray Co Ltd | 粘・接着剤組成物 |
-
2004
- 2004-04-01 JP JP2004134886A patent/JP4685367B2/ja not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57143376A (en) * | 1981-03-03 | 1982-09-04 | Hitachi Cable Ltd | Two-pack type adhesive composition |
JPH06329999A (ja) * | 1993-05-17 | 1994-11-29 | Daiabondo Kogyo Kk | 粘着材,粘着テープ及び粘着シート |
JPH08300577A (ja) * | 1995-05-12 | 1996-11-19 | Hitachi Kasei Polymer Co Ltd | 自動車内装用プレコート表皮材 |
JPH10292161A (ja) * | 1997-04-16 | 1998-11-04 | Hitachi Kasei Polymer Co Ltd | ポリオレフィン用接着テープ |
JP2001115124A (ja) * | 1998-12-08 | 2001-04-24 | Nitto Denko Corp | 粘着剤組成物およびその製造方法と粘着シ―ト類 |
JP2004010719A (ja) * | 2002-06-05 | 2004-01-15 | Kuraray Co Ltd | 粘・接着剤組成物 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017061061A1 (ja) | 2015-10-05 | 2017-04-13 | 日立化成株式会社 | 接着剤組成物 |
KR20170057171A (ko) | 2015-10-05 | 2017-05-24 | 히타치가세이가부시끼가이샤 | 접착제 조성물 |
US10113090B2 (en) | 2015-10-05 | 2018-10-30 | Hitachi Chemical Company, Ltd. | Adhesive composition |
US11390780B2 (en) | 2017-03-30 | 2022-07-19 | Showa Denko Materials Co., Ltd. | Adhesive composition |
WO2020246063A1 (ja) | 2019-06-06 | 2020-12-10 | 昭和電工マテリアルズ株式会社 | ホットメルト接着剤組成物 |
KR20220019100A (ko) | 2019-06-06 | 2022-02-15 | 쇼와덴코머티리얼즈가부시끼가이샤 | 핫멜트 접착제 조성물 |
Also Published As
Publication number | Publication date |
---|---|
JP4685367B2 (ja) | 2011-05-18 |
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