JP2005068424A - 触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用 - Google Patents

触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用 Download PDF

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Publication number
JP2005068424A
JP2005068424A JP2004240323A JP2004240323A JP2005068424A JP 2005068424 A JP2005068424 A JP 2005068424A JP 2004240323 A JP2004240323 A JP 2004240323A JP 2004240323 A JP2004240323 A JP 2004240323A JP 2005068424 A JP2005068424 A JP 2005068424A
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pair
metal
metal atom
complex
norbornene
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JP2005068424A5 (https=
Inventor
Brian Leslie Goodall
ブライアン・レスリー・グッダル
Jennifer Lynn Petoff
ジェニファー・リン・ペトフ
Han Shen
ハン・シェン
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Rohm and Haas Co
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Rohm and Haas Co
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Publication of JP2005068424A publication Critical patent/JP2005068424A/ja
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Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04Nickel compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/12Esters of monohydric alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03Multinuclear procatalyst, i.e. containing two or more metals, being different or not

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
JP2004240323A 2003-08-21 2004-08-20 触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用 Pending JP2005068424A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US49687303P 2003-08-21 2003-08-21
US55924304P 2004-04-02 2004-04-02
US10/857,330 US7087687B2 (en) 2003-08-21 2004-05-28 Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Publications (2)

Publication Number Publication Date
JP2005068424A true JP2005068424A (ja) 2005-03-17
JP2005068424A5 JP2005068424A5 (https=) 2008-03-13

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JP2004240323A Pending JP2005068424A (ja) 2003-08-21 2004-08-20 触媒組成物およびその調製およびエチレン性不飽和モノマーからポリマーを調製するための使用

Country Status (6)

Country Link
US (1) US7087687B2 (https=)
EP (1) EP1508577A1 (https=)
JP (1) JP2005068424A (https=)
KR (1) KR100560061B1 (https=)
CN (1) CN1267460C (https=)
TW (1) TWI262196B (https=)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006009003A (ja) * 2004-06-14 2006-01-12 Rohm & Haas Co 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP2006233214A (ja) * 2005-02-22 2006-09-07 Rohm & Haas Co 保護された触媒組成物およびその製造およびエチレン性不飽和モノマーからポリマーを製造するための使用
JP2007063470A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニル系モノマー重合用触媒組成物およびそのビニル系モノマーの重合への使用
JP2007063469A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニルエステル系モノマー重合用触媒組成物およびそのビニルエステル系モノマーの重合への使用
JP2009096970A (ja) * 2007-01-31 2009-05-07 Sumitomo Bakelite Co Ltd 環状オレフィン系ポリマーの製造方法
JP2009203479A (ja) * 2005-05-27 2009-09-10 Rohm & Haas Co 触媒組成物およびその製造ならびにエチレン性不飽和モノマーからポリマーを製造するための使用
JP2009535444A (ja) * 2006-04-28 2009-10-01 エルジー・ケム・リミテッド アルケン−アクリレート−ノルボルネン3元共重合体及びその製造方法
JP2010509484A (ja) * 2006-11-14 2010-03-25 ユニベーション・テクノロジーズ・エルエルシー 触媒系及び重合方法
JP2011179012A (ja) * 2011-05-20 2011-09-15 Kuraray Co Ltd ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用
JP2012077284A (ja) * 2010-09-10 2012-04-19 Showa Denko Kk ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
WO2012057135A1 (ja) * 2010-10-26 2012-05-03 昭和電工株式会社 ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
JP2012121956A (ja) * 2010-12-07 2012-06-28 Sumitomo Bakelite Co Ltd 付加型ノルボルネン系樹脂、その製造方法、該樹脂を含む樹脂組成物、ならびに該樹脂を含む成形体および該成形体を含む複合部材

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
US7199074B2 (en) 2004-06-14 2007-04-03 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7595369B2 (en) * 2004-11-10 2009-09-29 Lg Chem, Ltd. Method of polymerizing cyclic olefins and vinyl olefins, copolymer produced by the method and optical anisotropic film comprising the same
US7635739B2 (en) 2005-08-31 2009-12-22 Rohm And Haas Company Substantially linear polymers and methods of making and using same
US20080118570A1 (en) * 2006-11-20 2008-05-22 Zhi Liu Polymer coated drug-ion exchange resins and methods
CA2620852A1 (en) 2007-02-28 2008-08-28 Rohm And Haas Company A porous linear polymer composition and method of making same
JP5016512B2 (ja) 2007-02-28 2012-09-05 ローム アンド ハース カンパニー 実質的に線状のコポリマーおよびその製造方法
JP5111145B2 (ja) 2007-02-28 2012-12-26 ローム アンド ハース カンパニー 非環式脂肪族オレフィンの重合
JP5047832B2 (ja) * 2007-02-28 2012-10-10 ローム アンド ハース カンパニー フリーラジカル開始ポリマーを実質的に含まない、極性および非極性オレフィンのコポリマーを製造するための組成物および方法
FR2937643B1 (fr) * 2008-10-27 2011-10-14 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires
EP2707399B1 (en) 2011-05-09 2015-08-19 Reliance Industries Limited Nitrogen containing external donor system for propylene polymerization
US20160046842A1 (en) 2013-03-27 2016-02-18 Japan Polyethylene Corporation Polar-group-containing olefin copolymer, polar-group-containing multinary olefin copolymer, olefin-based resin composition, and adhesive and layered product each using the same
CN103360544B (zh) * 2013-07-26 2015-07-01 宁波工程学院 降冰片烯类、丙烯酸酯类和戊烯类共聚用催化剂及共聚方法
SG11202003755XA (en) * 2017-10-31 2020-05-28 Dow Global Technologies Llc Catalyst systems comprising carborane cocatalysts
CN113877551B (zh) * 2021-10-25 2023-12-29 湖北科技学院 重金属和放射性金属离子吸附材料及其制备方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) * 1970-07-13 1974-12-15 Способ получения линейных полимеров
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
DE69325757T2 (de) 1992-09-21 1999-12-30 Montell Technology Co. B.V., Hoofddorp Polymerisationsverfahren
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) * 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US5929181A (en) * 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
US6265506B1 (en) * 1997-06-09 2001-07-24 The B. F. Goodrich Company Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US6593440B2 (en) * 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US7087691B2 (en) * 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
US6111041A (en) * 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
KR20010024020A (ko) * 1997-09-15 2001-03-26 그래햄 이. 테일러 2-금속 착체 및 이로부터 제조된 중합 촉매
US6417303B1 (en) * 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
US6037297A (en) * 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
WO2000001747A1 (en) * 1998-07-01 2000-01-13 The B.F. Goodrich Company Polycyclic copolymer compositions
SG72966A1 (en) * 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
JP2002521534A (ja) 1998-07-27 2002-07-16 バセル テクノロジー カンパニー ビー.ブイ. 重合方法
ATE286923T1 (de) * 1998-10-05 2005-01-15 Promerus Llc Katalysator und verfahren zur polymerisation von cycloolefinen
ID30159A (id) * 1998-12-09 2001-11-08 Goodrich Co B F Polimerisasi adisi dalam cetakan dari monomer-monomer tipe-norbene menggunakan kompleksi logam golongan-10
US6544919B1 (en) * 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
MXPA02011836A (es) * 2000-05-31 2003-05-14 Du Pont Catalizadores para la polimerizacion de olefinas.
US6506861B2 (en) * 2000-05-31 2003-01-14 E. I. Du Pont De Nmeours And Company Polymerization of olefins
US20030144441A1 (en) * 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) * 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
AU2003241078A1 (en) 2002-06-04 2003-12-19 Thales Technologies, Ag Polymerization catalysts
KR100576971B1 (ko) * 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) * 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006009003A (ja) * 2004-06-14 2006-01-12 Rohm & Haas Co 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP2009108332A (ja) * 2004-06-14 2009-05-21 Rohm & Haas Co 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用
JP2006233214A (ja) * 2005-02-22 2006-09-07 Rohm & Haas Co 保護された触媒組成物およびその製造およびエチレン性不飽和モノマーからポリマーを製造するための使用
JP2009203479A (ja) * 2005-05-27 2009-09-10 Rohm & Haas Co 触媒組成物およびその製造ならびにエチレン性不飽和モノマーからポリマーを製造するための使用
JP2007063470A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニル系モノマー重合用触媒組成物およびそのビニル系モノマーの重合への使用
JP2007063469A (ja) * 2005-09-01 2007-03-15 Kuraray Co Ltd 金属化合物、金属化合物を含むビニルエステル系モノマー重合用触媒組成物およびそのビニルエステル系モノマーの重合への使用
JP2012237006A (ja) * 2006-04-28 2012-12-06 Lg Chem Ltd アルケン−アクリレート−ノルボルネン3元共重合体及びその製造方法
JP2009535444A (ja) * 2006-04-28 2009-10-01 エルジー・ケム・リミテッド アルケン−アクリレート−ノルボルネン3元共重合体及びその製造方法
JP2010509484A (ja) * 2006-11-14 2010-03-25 ユニベーション・テクノロジーズ・エルエルシー 触媒系及び重合方法
JP2009096970A (ja) * 2007-01-31 2009-05-07 Sumitomo Bakelite Co Ltd 環状オレフィン系ポリマーの製造方法
JP2012077284A (ja) * 2010-09-10 2012-04-19 Showa Denko Kk ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
WO2012057135A1 (ja) * 2010-10-26 2012-05-03 昭和電工株式会社 ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
US8835580B2 (en) 2010-10-26 2014-09-16 Showa Denko K.K. Catalyst for norbornene monomer polymerization and method for producing norbornene polymer
JP5834017B2 (ja) * 2010-10-26 2015-12-16 昭和電工株式会社 ノルボルネン系モノマー重合用触媒及びノルボルネン系重合体の製造方法
JP2012121956A (ja) * 2010-12-07 2012-06-28 Sumitomo Bakelite Co Ltd 付加型ノルボルネン系樹脂、その製造方法、該樹脂を含む樹脂組成物、ならびに該樹脂を含む成形体および該成形体を含む複合部材
JP2011179012A (ja) * 2011-05-20 2011-09-15 Kuraray Co Ltd ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用

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Publication number Publication date
US7087687B2 (en) 2006-08-08
KR20050020725A (ko) 2005-03-04
CN1597709A (zh) 2005-03-23
CN1267460C (zh) 2006-08-02
US20050043494A1 (en) 2005-02-24
EP1508577A1 (en) 2005-02-23
TW200514795A (en) 2005-05-01
TWI262196B (en) 2006-09-21
KR100560061B1 (ko) 2006-03-13

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