JP2004534637A5 - - Google Patents
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- Publication number
- JP2004534637A5 JP2004534637A5 JP2002591144A JP2002591144A JP2004534637A5 JP 2004534637 A5 JP2004534637 A5 JP 2004534637A5 JP 2002591144 A JP2002591144 A JP 2002591144A JP 2002591144 A JP2002591144 A JP 2002591144A JP 2004534637 A5 JP2004534637 A5 JP 2004534637A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- nickel
- hydrogenation
- tio
- aromatic amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 10
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- 229910052759 nickel Inorganic materials 0.000 claims 5
- 238000004519 manufacturing process Methods 0.000 claims 4
- 230000000875 corresponding Effects 0.000 claims 3
- 238000005984 hydrogenation reaction Methods 0.000 claims 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 238000006722 reduction reaction Methods 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 1
- -1 aromatic amino compound Chemical class 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 239000000969 carrier Substances 0.000 claims 1
- 238000000975 co-precipitation Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- RNVCVTLRINQCPJ-UHFFFAOYSA-N o-toluidine Chemical compound CC1=CC=CC=C1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 claims 1
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 230000000737 periodic Effects 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
Claims (9)
- ニッケルおよび
アルカリ土類金属、Ｙ、ＬａおよびＣｅから選択された少なくとも１つの他の金属および
場合によっては元素の周期律表の第５族〜第１１族から選択される少なくとも１つのドープ金属を
相応する金属塩を含有する溶液から微粒状のＴｉＯ２−担体上で共沈させ、引続き乾燥、か焼および還元および場合によっては不動態化させ、ニッケル含有触媒に変えることによって得ることができる、ＴｉＯ２−担体上にニッケルを含有する触媒。 - 触媒中のニッケルの含量が全部の触媒に対して２０〜８０質量％である、請求項１記載の触媒。
- 他の１つの金属または複数の金属の酸化物とＴｉＯ２−担体との質量比が（０．２〜４）：１である、請求項１または２記載の触媒。
- ニッケルクリスタリットの寸法が４〜２０ｎｍである、請求項１から３までのいずれか１項に記載の触媒。
- 触媒の平均粒度（ｄ５０）が３〜８０μｍである、請求項１から４までのいずれか１項に記載の触媒。
- 触媒が還元後に不動態化されている、請求項１から５までのいずれか１項に記載の触媒。
- 請求項１から６までのいずれか１項に記載の触媒の製造法において、記載された処理工程を実施することを特徴とする、請求項１から６までのいずれか１項に記載の触媒の製造法。
- 芳香族アミノ化合物を相応するニトロ芳香族化合物の水素化によって製造する方法において、水素化を請求項１から６までのいずれか１項に記載の触媒の存在で実施することを特徴とする、芳香族アミノ化合物を相応するニトロ芳香族化合物の水素化によって製造する方法。
- 芳香族アミノ化合物をアニリン、ｏ−トルイジン、ｐ−トルイジンおよびトルイレンジアミンから選択する、請求項８記載の方法。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10124600A DE10124600A1 (de) | 2001-05-21 | 2001-05-21 | Ni/Ti02-Hydrierkatalysator |
| PCT/EP2002/005423 WO2002094434A1 (de) | 2001-05-21 | 2002-05-16 | Ni/tio2-hydrierkatalysator |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004534637A JP2004534637A (ja) | 2004-11-18 |
| JP2004534637A5 true JP2004534637A5 (ja) | 2006-01-05 |
| JP4338400B2 JP4338400B2 (ja) | 2009-10-07 |
Family
ID=7685503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002591144A Expired - Fee Related JP4338400B2 (ja) | 2001-05-21 | 2002-05-16 | Ｎｉ／ＴｉＯ２−水素化触媒 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7408086B2 (ja) |
| EP (1) | EP1397208B1 (ja) |
| JP (1) | JP4338400B2 (ja) |
| KR (1) | KR100874678B1 (ja) |
| CN (1) | CN1261209C (ja) |
| AT (1) | ATE320849T1 (ja) |
| DE (2) | DE10124600A1 (ja) |
| HU (1) | HU229646B1 (ja) |
| MX (1) | MXPA03010591A (ja) |
| WO (1) | WO2002094434A1 (ja) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060025301A1 (en) * | 2004-07-30 | 2006-02-02 | Reddy Benjaram M | Process for preparing nanosized, thermally stable, and high surface area multi-component metal oxides |
| CN100441293C (zh) * | 2005-09-26 | 2008-12-10 | 天津大学 | 氯代硝基苯加氢合成氯代苯胺负载型镍催化剂及制备方法 |
| JP4724860B2 (ja) * | 2005-10-19 | 2011-07-13 | 国立大学法人 大分大学 | 水素製造用触媒の製造方法 |
| US8067332B2 (en) * | 2006-05-03 | 2011-11-29 | Samsung Sdi Co., Ltd. | Methanation catalyst, and carbon monoxide removing system, fuel processor, and fuel cell including the same |
| KR101000684B1 (ko) * | 2007-10-11 | 2010-12-10 | 세종대학교산학협력단 | 이산화티타늄 나노튜브분말 및 이를 이용한 고압수소저장탱크 삽입용 판형 필름의 제조방법 |
| EP2203250B1 (en) * | 2007-10-19 | 2015-04-08 | Shell Internationale Research Maatschappij B.V. | Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation |
| WO2010130604A2 (de) * | 2009-05-14 | 2010-11-18 | Basf Se | Verfahren zur herstellung von aromatischen aminen |
| CN102718666A (zh) * | 2012-05-29 | 2012-10-10 | 吴江市屯村颜料厂 | 一种对甲苯胺的制备方法 |
| CN103480380B (zh) * | 2013-09-03 | 2015-04-22 | 万华化学集团股份有限公司 | 一种用于固定床苯胺精馏残渣资源化利用的催化剂及其制备方法 |
| CN104130194B (zh) * | 2014-08-12 | 2016-08-31 | 南通醋酸化工股份有限公司 | 一种5-氨基苯并咪唑酮的合成方法 |
| JP6824168B2 (ja) * | 2014-12-19 | 2021-02-03 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイＳｈｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌｅ Ｒｅｓｅａｒｃｈ Ｍａａｔｓｃｈａｐｐｉｊ Ｂｅｓｌｏｔｅｎ Ｖｅｎｎｏｏｔｓｈａｐ | 触媒の調製方法 |
| HUE053603T2 (hu) * | 2016-10-10 | 2021-07-28 | Basf Se | Katalizátor módosítása alkálifém, alkáliföldfém vagy ritkaföldfém ionokkal nitrovegyületek folytonos folyadék fázisú hidrogénezése során |
| CN106902835B (zh) * | 2017-02-27 | 2019-07-09 | 浙江林江化工股份有限公司 | 一种铈改性负载型镍基催化剂及其制备方法和应用 |
| JP7088690B2 (ja) * | 2017-02-28 | 2022-06-21 | 東ソー株式会社 | 芳香族化合物の製造方法 |
| CN111960948B (zh) * | 2020-09-16 | 2022-07-26 | 肯特催化材料股份有限公司 | 一种四丁基溴化铵的合成工艺 |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE152065C (ja) | ||||
| DE284371C (ja) | ||||
| US2889286A (en) * | 1955-05-13 | 1959-06-02 | Drew & Co Inc E F | Nickel-titanium catalysts |
| US2866752A (en) * | 1956-03-29 | 1958-12-30 | Standard Oil Co | Method of desulfurizing hydrocarbon oil using a nickel titanate catalyst |
| FR91928E (fr) * | 1966-10-20 | 1968-08-30 | Azote & Prod Chim | Compositions catalytiques de reformage à la vapeur et leurs procédés de préparation |
| US4113658A (en) * | 1967-04-14 | 1978-09-12 | Stamicarbon, N.V. | Process for homogeneous deposition precipitation of metal compounds on support or carrier materials |
| US3868332A (en) | 1970-10-26 | 1975-02-25 | Exxon Research Engineering Co | Massive nickel catalysts |
| US3794588A (en) * | 1971-09-23 | 1974-02-26 | Du Pont | Highly-active supported catalysts |
| US3972829A (en) * | 1974-11-07 | 1976-08-03 | Universal Oil Products Company | Method of depositing a catalytically active metallic component on a carrier material |
| US4042615A (en) * | 1976-04-05 | 1977-08-16 | Exxon Research And Engineering Co. | Hydrocarbon synthesis from CO and H2 using Ni supported on a titanium oxide |
| DE2712909A1 (de) * | 1976-04-05 | 1977-10-13 | Exxon Research Engineering Co | Verfahren zur synthese von kohlenwasserstoffen |
| US4073750A (en) * | 1976-05-20 | 1978-02-14 | Exxon Research & Engineering Co. | Method for preparing a highly dispersed supported nickel catalyst |
| LU76591A1 (ja) * | 1977-01-18 | 1978-09-13 | ||
| US4160745A (en) * | 1977-12-01 | 1979-07-10 | Exxon Research & Engineering Co. | Method of preparing highly active nickel catalysts and catalysts prepared by said method |
| US4273724A (en) * | 1979-07-09 | 1981-06-16 | Exxon Research & Engineering Co. | Hydrocarbon synthesis from CO and H2 using titanium promoted bulk nickel catalysts |
| CA1213875A (en) * | 1982-11-29 | 1986-11-12 | Shigeo Uno | Catalyst for catalytic combustion |
| EP0172280B1 (en) * | 1983-03-14 | 1988-03-09 | E.I. Du Pont De Nemours And Company | Catalyst composition |
| US4977126A (en) * | 1987-05-07 | 1990-12-11 | Exxon Research And Engineering Company | Process for the preparation of surface impregnated dispersed cobalt metal catalysts |
| FR2633605B1 (fr) * | 1988-07-01 | 1991-07-12 | Rhone Poulenc Chimie | Procede de preparation d'oxyde de titane et d'articles a base d'oxyde de titane |
| US5095160A (en) * | 1991-06-24 | 1992-03-10 | Phillips Petroleum Company | Conversion of benzene to toluene |
| US5204309A (en) * | 1991-12-30 | 1993-04-20 | Tpct Chemicals, Inc. | Catalysts for neutralizing air and gaseous exhausts |
| DE4339713A1 (de) | 1993-11-22 | 1995-05-24 | Basf Ag | Verfahren zur Oligomerisierung von Olefinen zu hochlinearen Oligomeren und Katalysatoren dafür |
| US5565092A (en) * | 1994-03-16 | 1996-10-15 | Exxon Chemical Patents Inc. | Halogen resistant hydrogenation process and catalyst |
| ES2155941T5 (es) * | 1995-09-15 | 2012-04-30 | Rhodia Chimie | Sustrato con revestimiento fotocatalítico a base de dióxido de titanio y dispersiones orgánicas a base de dióxido de titanio |
| US5977013A (en) * | 1996-12-19 | 1999-11-02 | Battelle Memorial Institute | Catalyst and method for aqueous phase reactions |
| US6086844A (en) * | 1996-12-26 | 2000-07-11 | Sumitomo Chemical Company, Ltd. | Titania fiber, method for producing the fiber and method for using the fiber |
| GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
| US6235677B1 (en) * | 1998-08-20 | 2001-05-22 | Conoco Inc. | Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids |
| US6319872B1 (en) * | 1998-08-20 | 2001-11-20 | Conoco Inc | Fischer-Tropsch processes using catalysts on mesoporous supports |
| EP0985448A1 (en) * | 1998-08-28 | 2000-03-15 | Engelhard Corporation | Nickel catalyst |
| DE19909177A1 (de) * | 1999-03-03 | 2000-09-07 | Kataleuna Gmbh Catalysts | Katalysator zur Hydrierung funktioneller Gruppen und Verfahren zu seiner Herstellung |
| DE19909168A1 (de) | 1999-03-03 | 2000-09-07 | Basf Ag | Verfahren zur Herstellung von Aminen |
| DE19909176A1 (de) | 1999-03-03 | 2000-09-07 | Kataleuna Gmbh Catalysts | Hydrierkatalysator und Verfahren zu seiner Herstellung |
| DE19915357A1 (de) * | 1999-04-06 | 2000-10-12 | Basf Ag | Verfahren zur Oligomerisierung von C¶2¶- bis C¶8¶-Olefinen |
| US6841512B1 (en) * | 1999-04-12 | 2005-01-11 | Ovonic Battery Company, Inc. | Finely divided metal catalyst and method for making same |
| US6964826B2 (en) * | 1999-04-12 | 2005-11-15 | Ovonic Battery Company, Inc. | Coated catalytic material with a metal phase in contact with a grain boundary oxide |
| US6309758B1 (en) * | 1999-05-06 | 2001-10-30 | W. R. Grace & Co.-Conn. | Promoted porous catalyst |
| DE19922038A1 (de) * | 1999-05-12 | 2000-11-16 | Basf Ag | Verfahren zur Oligomerisierung von C2- bis C8-Olefinen |
| US6399540B1 (en) * | 1999-08-12 | 2002-06-04 | Sumitomo Chemical Co., Ltd. | Porous titania, catalyst comprising the porous titania |
| US6528029B1 (en) * | 1999-10-13 | 2003-03-04 | Engelhard Corporation | Catalyst compositions employing sol gel particles and methods of using the same |
| DK1163955T3 (da) | 2000-06-14 | 2004-07-19 | Kataleuna Gmbh Catalysts | Hydrogeneringskatalysator til reducering af funktionelle grupper og fremgangsmåde til dennes fremstilling |
| US6842512B2 (en) * | 2000-11-14 | 2005-01-11 | Fuji Xerox Co., Ltd. | Systems and methods for managing electronic communications |
-
2001
- 2001-05-21 DE DE10124600A patent/DE10124600A1/de not_active Withdrawn
-
2002
- 2002-05-16 CN CNB028102762A patent/CN1261209C/zh not_active Expired - Fee Related
- 2002-05-16 US US10/478,475 patent/US7408086B2/en not_active Expired - Fee Related
- 2002-05-16 MX MXPA03010591A patent/MXPA03010591A/es active IP Right Grant
- 2002-05-16 JP JP2002591144A patent/JP4338400B2/ja not_active Expired - Fee Related
- 2002-05-16 WO PCT/EP2002/005423 patent/WO2002094434A1/de active IP Right Grant
- 2002-05-16 DE DE50206151T patent/DE50206151D1/de not_active Expired - Lifetime
- 2002-05-16 AT AT02750940T patent/ATE320849T1/de not_active IP Right Cessation
- 2002-05-16 HU HU0400780A patent/HU229646B1/hu not_active IP Right Cessation
- 2002-05-16 EP EP02750940A patent/EP1397208B1/de not_active Expired - Lifetime
- 2002-05-16 KR KR1020037015078A patent/KR100874678B1/ko not_active IP Right Cessation
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