JP2004530020A5 - - Google Patents
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- JP2004530020A5 JP2004530020A5 JP2002589551A JP2002589551A JP2004530020A5 JP 2004530020 A5 JP2004530020 A5 JP 2004530020A5 JP 2002589551 A JP2002589551 A JP 2002589551A JP 2002589551 A JP2002589551 A JP 2002589551A JP 2004530020 A5 JP2004530020 A5 JP 2004530020A5
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- JP
- Japan
- Prior art keywords
- polymer
- stretching
- film
- membrane
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920000642 polymer Polymers 0.000 claims description 89
- 239000012528 membrane Substances 0.000 claims description 50
- 229910052615 phyllosilicate Inorganic materials 0.000 claims description 44
- -1 polyethylene Polymers 0.000 claims description 44
- 238000000034 method Methods 0.000 claims description 35
- 239000011888 foil Substances 0.000 claims description 28
- 229910052645 tectosilicate Inorganic materials 0.000 claims description 27
- 125000000524 functional group Chemical group 0.000 claims description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
- 238000005341 cation exchange Methods 0.000 claims description 18
- 150000001768 cations Chemical class 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000002243 precursor Substances 0.000 claims description 17
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 14
- 239000004743 Polypropylene Substances 0.000 claims description 12
- 238000004132 cross linking Methods 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 10
- 239000000446 fuel Substances 0.000 claims description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 9
- 238000005349 anion exchange Methods 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 125000000623 heterocyclic group Chemical group 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 5
- 239000004693 Polybenzimidazole Substances 0.000 claims description 5
- 238000000909 electrodialysis Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 229920002492 poly(sulfone) Polymers 0.000 claims description 5
- 229920002530 polyetherether ketone Polymers 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 238000005868 electrolysis reaction Methods 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 229920000554 ionomer Polymers 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 claims description 4
- 229920001643 poly(ether ketone) Polymers 0.000 claims description 4
- 229920006393 polyether sulfone Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920001195 polyisoprene Polymers 0.000 claims description 4
- 238000001223 reverse osmosis Methods 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- DPZYLEIWHTWHCU-UHFFFAOYSA-N 3-ethenylpyridine Chemical compound C=CC1=CC=CN=C1 DPZYLEIWHTWHCU-UHFFFAOYSA-N 0.000 claims description 3
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229920008285 Poly(ether ketone) PEK Polymers 0.000 claims description 3
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 claims description 3
- 229920002873 Polyethylenimine Polymers 0.000 claims description 3
- 229920000491 Polyphenylsulfone Polymers 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910001431 copper ion Inorganic materials 0.000 claims description 3
- 238000000502 dialysis Methods 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000005373 pervaporation Methods 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229920000885 poly(2-vinylpyridine) Polymers 0.000 claims description 3
- 229920000075 poly(4-vinylpyridine) Polymers 0.000 claims description 3
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 claims description 3
- 229920001657 poly(etheretherketoneketone) Polymers 0.000 claims description 3
- 229920000636 poly(norbornene) polymer Polymers 0.000 claims description 3
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 claims description 3
- 229920005649 polyetherethersulfone Polymers 0.000 claims description 3
- 229920000306 polymethylpentene Polymers 0.000 claims description 3
- 239000011116 polymethylpentene Substances 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 229920001955 polyphenylene ether Polymers 0.000 claims description 3
- 238000012805 post-processing Methods 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 239000004695 Polyether sulfone Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 claims description 2
- 125000001072 heteroaryl group Chemical group 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000010954 inorganic particle Substances 0.000 claims 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 1
- 241000047703 Nonion Species 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 1
- 229920001660 poly(etherketone-etherketoneketone) Polymers 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 125000000626 sulfinic acid group Chemical group 0.000 claims 1
- 239000002904 solvent Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 238000011282 treatment Methods 0.000 description 17
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 16
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- 229910052901 montmorillonite Inorganic materials 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- 239000002131 composite material Substances 0.000 description 12
- 239000000975 dye Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 238000001125 extrusion Methods 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 150000001336 alkenes Chemical class 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 7
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- 239000000010 aprotic solvent Substances 0.000 description 6
- 239000000440 bentonite Substances 0.000 description 6
- 229910000278 bentonite Inorganic materials 0.000 description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 229920004695 VICTREX™ PEEK Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 239000012982 microporous membrane Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920002480 polybenzimidazole Polymers 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 239000012266 salt solution Substances 0.000 description 5
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 229920000557 Nafion® Polymers 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 230000029936 alkylation Effects 0.000 description 4
- 238000005804 alkylation reaction Methods 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 4
- 125000000542 sulfonic acid group Chemical group 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- 239000004734 Polyphenylene sulfide Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 125000002883 imidazolyl group Chemical group 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000012798 spherical particle Substances 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 229920004878 Ultrapek® Polymers 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000012707 chemical precursor Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- DOUHZFSGSXMPIE-UHFFFAOYSA-N hydroxidooxidosulfur(.) Chemical group [O]SO DOUHZFSGSXMPIE-UHFFFAOYSA-N 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 239000005267 main chain polymer Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 2
- 239000013557 residual solvent Substances 0.000 description 2
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 2
- 0 *c1c(*)c(*)c(C(c(c(*)c2*)c(*)c(*)c2N(*)*)=C(C(*)=C2*)C(*)=C(*)C2=[N+](*)*)c(*)c1* Chemical compound *c1c(*)c(*)c(C(c(c(*)c2*)c(*)c(*)c2N(*)*)=C(C(*)=C2*)C(*)=C(*)C2=[N+](*)*)c(*)c1* 0.000 description 1
- LVJZCPNIJXVIAT-UHFFFAOYSA-N 1-ethenyl-2,3,4,5,6-pentafluorobenzene Chemical compound FC1=C(F)C(F)=C(C=C)C(F)=C1F LVJZCPNIJXVIAT-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- NJLHHACGWKAWKL-UHFFFAOYSA-N ClP(Cl)=O Chemical compound ClP(Cl)=O NJLHHACGWKAWKL-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 229920003295 Radel® Polymers 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000002009 alkene group Chemical group 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 229910001588 amesite Inorganic materials 0.000 description 1
- 239000003011 anion exchange membrane Substances 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N cyclobenzothiazole Natural products C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 230000009615 deamination Effects 0.000 description 1
- 238000006481 deamination reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 229940083094 guanine derivative acting on arteriolar smooth muscle Drugs 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 125000003106 haloaryl group Chemical group 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
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- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
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| KR100407793B1 (ko) * | 2001-09-04 | 2003-12-01 | 한국과학기술연구원 | 분리능이 있는 수소 이온 교환 복합막, 복합 용액, 그제조방법 및 이를 포함하는 연료전지 |
| FI122368B (fi) * | 2003-11-06 | 2011-12-30 | Valtion Teknillinen | Menetelmä huokoisen muovikalvon valmistamiseksi ja muovikalvo |
| FR2869032B1 (fr) * | 2004-04-15 | 2006-06-02 | Commissariat Energie Atomique | Procede de preparation de particules d'argile conductrices de protons et materiau comprenant de telles particules |
| FR2883292B1 (fr) * | 2005-03-16 | 2008-01-04 | Inst Nat Polytech Grenoble | Extrusion de polymeres ioniques a groupements ioniques acides |
| FR2883293B1 (fr) * | 2005-03-16 | 2007-05-25 | Inst Nat Polytech Grenoble | Extrusion de polymeres ioniques a groupements ioniques alcalins |
| JP4550920B2 (ja) * | 2008-06-05 | 2010-09-22 | 株式会社東芝 | 燃料電池 |
| KR100928898B1 (ko) * | 2009-04-17 | 2009-11-30 | (주)씨에스텍 | 미세다공성 고분자 분리막의 제조방법 및 상기 방법으로 제조된 미세다공성 고분자 분리막 |
| KR101156439B1 (ko) * | 2010-02-11 | 2012-06-18 | 삼성모바일디스플레이주식회사 | 복합체막, 이를 포함하는 플렉시블 기판 및 이를 채용한 유기 발광장치 |
| US9192625B1 (en) * | 2011-07-01 | 2015-11-24 | Mangala Joshi | Antimicrobial nanocomposite compositions, fibers and films |
| CN103509364B (zh) * | 2012-06-29 | 2016-08-03 | 罗门哈斯公司 | 含银组合物 |
| WO2014025735A1 (en) * | 2012-08-07 | 2014-02-13 | Promerus, Llc | Cycloalkylnorbornene monomers, polymers derived therefrom and their use in pervaporation |
| JP6251174B2 (ja) * | 2012-08-31 | 2017-12-20 | 日本碍子株式会社 | オレフィンの回収方法 |
| ES2992476T3 (es) | 2012-10-12 | 2024-12-12 | Univ California | Membranas de polianilina, usos y métodos para ello |
| US10456755B2 (en) | 2013-05-15 | 2019-10-29 | The Regents Of The University Of California | Polyaniline membranes formed by phase inversion for forward osmosis applications |
| RU2717512C2 (ru) | 2014-04-08 | 2020-03-23 | Дзе Риджентс Оф Дзе Юниверсити Оф Калифорния | Устойчивые к хлору гидрофильные фильтрационные мембраны на основе полианилина |
| US11021584B2 (en) | 2014-08-21 | 2021-06-01 | William Winchin Yen | Microporous sheet product and methods for making and using the same |
| WO2016073580A1 (en) | 2014-11-05 | 2016-05-12 | William Winchin Yen | Microporous sheet product and methods for making and using the same |
| KR20170077221A (ko) | 2014-11-05 | 2017-07-05 | 윌리암 윈친 옌 | 미세다공성 시트 제품 및 그의 제조 및 사용 방법 |
| KR20170079234A (ko) * | 2015-12-30 | 2017-07-10 | 상명대학교산학협력단 | 질산염을 포함하는 ｓｆ６ 분리용 고분자 전해질 분리막 |
| IT201700115604A1 (it) * | 2017-10-14 | 2019-04-14 | Spin Pet Srl | Processo per una membrana anionica nanostrutturata innovativa basata su un copolimero a catena laterale epossidica ed argilla stratificata modificata per elettrolisi e celle a combustibile. |
| CN111902203B (zh) * | 2018-03-30 | 2022-07-15 | 日本碍子株式会社 | 沸石膜复合体、沸石膜复合体的制造方法以及分离方法 |
| WO2022243976A1 (en) * | 2021-05-20 | 2022-11-24 | King Abdullah University Of Science And Technology | Metal-polymer coordination membranes for molecular sieving |
| CN113601879B (zh) * | 2021-08-03 | 2023-03-24 | 上海康宁医疗用品有限公司 | 一种三维立体的膨体聚四氟乙烯面部植入体的生产工艺 |
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| DE1992482U (de) * | 1968-05-17 | 1968-08-22 | Melter & Kühn, 7530 Pforzheim | Tischuhr |
| US4297935A (en) | 1978-02-24 | 1981-11-03 | Marmon Company | Divider keyer circuit for synthesis organ |
| DE3214447C2 (de) | 1982-04-20 | 1994-05-11 | Eilentropp Hew Kabel | Ungesintertes Wickelband des Polytetrafluorethylen |
| JPS63108041A (ja) * | 1986-06-12 | 1988-05-12 | Tokuyama Soda Co Ltd | 微多孔性フィルム及びその製法 |
| US5229465A (en) | 1990-06-30 | 1993-07-20 | Praxair Technology, Inc. | Oxygen-permeable polymeric membranes |
| US4909971A (en) * | 1988-03-25 | 1990-03-20 | Du Pont Canada Inc. | Process for making a heterogeneous membrane film |
| US4842741A (en) | 1988-03-25 | 1989-06-27 | Du Pont Canada Inc. | Heterogeneous membranes from highly filled thermoplastic orientable polymers |
| JPH0657307B2 (ja) * | 1990-06-30 | 1994-08-03 | ユニオン・カーバイド・インダストリアル・ガセズ・テクノロジー・コーポレーション | 酸素透過高分子膜 |
| US5690949A (en) * | 1991-10-18 | 1997-11-25 | Minnesota Mining And Manufacturing Company | Microporous membrane material for preventing transmission of viral pathogens |
| NL9301245A (nl) * | 1993-07-15 | 1995-02-01 | Tno | Werkwijze en inrichting voor het afscheiden van een component uit een fluidummengsel. |
| US5744183A (en) * | 1995-08-17 | 1998-04-28 | Ellsworth; Robert M. | Removal of sulfides from alcoholic beverages |
| WO1997044121A1 (en) * | 1996-05-17 | 1997-11-27 | Colorado School Of Mines | Membrane separation of components in a fluid mixture |
| US5670051A (en) | 1996-05-23 | 1997-09-23 | Membrane Technology And Research, Inc. | Olefin separation membrane and process |
| CN1100595C (zh) * | 1997-08-06 | 2003-02-05 | 天津纺织工学院 | 无机粒子填充的聚合物分离膜及制造方法 |
| DE19836514A1 (de) | 1998-08-12 | 2000-02-17 | Univ Stuttgart | Modifikation von Engineeringpolymeren mit N-basischen Gruppe und mit Ionenaustauschergruppen in der Seitenkette |
| US6953510B1 (en) * | 1998-10-16 | 2005-10-11 | Tredegar Film Products Corporation | Method of making microporous breathable film |
| JP2000256492A (ja) * | 1999-03-04 | 2000-09-19 | Toyota Central Res & Dev Lab Inc | 多孔材料及びその製造方法 |
| DE19929482A1 (de) * | 1999-06-28 | 2001-03-01 | Univ Stuttgart | Polymermembran zur Anreicherung von Olefinen aus Olefin/Paraffin-Mischungen |
| KR100315894B1 (ko) * | 1999-12-30 | 2001-12-24 | 박호군 | 고분자 전해질을 이용한 알켄 분리용 고체상 촉진 수송분리막 |
| DE10024575A1 (de) | 2000-11-02 | 2001-11-22 | Univ Stuttgart | Kovalent vernetzte Polymere und Polymermembranen via Sulfinatalkylierung |
| DE10024576A1 (de) | 2000-05-19 | 2001-11-22 | Univ Stuttgart | Kovalent und ionisch vernetzte Polymere und Polymermembranen |
-
2002
- 2002-05-13 JP JP2002589551A patent/JP4154244B2/ja not_active Expired - Fee Related
- 2002-05-13 WO PCT/EP2002/005256 patent/WO2002092673A1/de not_active Ceased
- 2002-05-13 ES ES02743003T patent/ES2292774T3/es not_active Expired - Lifetime
- 2002-05-13 EP EP20070013532 patent/EP1884534A3/de not_active Withdrawn
- 2002-05-13 US US10/477,174 patent/US8079480B2/en not_active Expired - Fee Related
- 2002-05-13 DE DE10292065T patent/DE10292065D2/de not_active Expired - Lifetime
- 2002-05-13 CA CA2446881A patent/CA2446881C/en not_active Expired - Fee Related
- 2002-05-13 KR KR10-2003-7014681A patent/KR20040008173A/ko not_active Ceased
- 2002-05-13 DE DE50210461T patent/DE50210461D1/de not_active Expired - Lifetime
- 2002-05-13 CN CNA02814015XA patent/CN1527859A/zh active Pending
- 2002-05-13 AU AU2002342310A patent/AU2002342310B2/en not_active Ceased
- 2002-05-13 KR KR1020097020575A patent/KR101005674B1/ko not_active Expired - Fee Related
- 2002-05-13 EP EP02743003A patent/EP1392765B1/de not_active Expired - Lifetime
- 2002-05-13 AT AT02743003T patent/ATE366771T1/de active
-
2004
- 2004-01-12 ZA ZA2004/00186A patent/ZA200400186B/en unknown
-
2007
- 2007-05-21 JP JP2007134592A patent/JP2007262419A/ja active Pending
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2008
- 2008-09-28 AU AU2008229666A patent/AU2008229666A1/en not_active Abandoned
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2009
- 2009-01-09 AU AU2009200145A patent/AU2009200145A1/en not_active Abandoned
- 2009-04-30 AU AU2009201729A patent/AU2009201729A1/en not_active Abandoned
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2011
- 2011-12-16 US US13/329,112 patent/US9126147B2/en not_active Expired - Fee Related
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2015
- 2015-09-07 US US14/846,902 patent/US20150376360A1/en not_active Abandoned
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