JP2004506769A - フェノール系塩を基礎とする老化防止剤 - Google Patents
フェノール系塩を基礎とする老化防止剤 Download PDFInfo
- Publication number
- JP2004506769A JP2004506769A JP2002519552A JP2002519552A JP2004506769A JP 2004506769 A JP2004506769 A JP 2004506769A JP 2002519552 A JP2002519552 A JP 2002519552A JP 2002519552 A JP2002519552 A JP 2002519552A JP 2004506769 A JP2004506769 A JP 2004506769A
- Authority
- JP
- Japan
- Prior art keywords
- phenolic
- salt
- aging
- groups
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 21
- 150000002989 phenols Chemical class 0.000 claims abstract description 29
- 150000003839 salts Chemical class 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 10
- 229920000620 organic polymer Polymers 0.000 claims abstract description 10
- -1 basic metal salt Chemical class 0.000 claims description 17
- 229910052728 basic metal Inorganic materials 0.000 claims description 9
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001447 alkali salts Chemical class 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 150000004678 hydrides Chemical class 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 230000032683 aging Effects 0.000 description 14
- 229920001971 elastomer Polymers 0.000 description 11
- 230000003647 oxidation Effects 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 239000005060 rubber Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- AKNMPWVTPUHKCG-UHFFFAOYSA-N 2-cyclohexyl-6-[(3-cyclohexyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound OC=1C(C2CCCCC2)=CC(C)=CC=1CC(C=1O)=CC(C)=CC=1C1CCCCC1 AKNMPWVTPUHKCG-UHFFFAOYSA-N 0.000 description 2
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920013648 Perbunan Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920006170 Therban® Polymers 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000000899 pressurised-fluid extraction Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- HNSDLXPSAYFUHK-UHFFFAOYSA-N 1,4-bis(2-ethylhexyl) sulfosuccinate Chemical compound CCCCC(CC)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(CC)CCCC HNSDLXPSAYFUHK-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical class NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- GWZOBVONNOSKQI-UHFFFAOYSA-N CC(NC[IH]OC(C)=O)=O Chemical compound CC(NC[IH]OC(C)=O)=O GWZOBVONNOSKQI-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Chemical group 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 150000001342 alkaline earth metals Chemical group 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 150000003819 basic metal compounds Chemical class 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- OBIFJJIDQJXRTR-UHFFFAOYSA-N hexa-1,3,5-triene;styrene Chemical compound C=CC=CC=C.C=CC1=CC=CC=C1 OBIFJJIDQJXRTR-UHFFFAOYSA-N 0.000 description 1
- 229920006168 hydrated nitrile rubber Polymers 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- CSJDCSCTVDEHRN-UHFFFAOYSA-N methane;molecular oxygen Chemical compound C.O=O CSJDCSCTVDEHRN-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 150000003336 secondary aromatic amines Chemical class 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/138—Phenolates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
- Cereal-Derived Products (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10039754 | 2000-08-16 | ||
| PCT/EP2001/008996 WO2002014419A1 (de) | 2000-08-16 | 2001-08-03 | Alterungsschutzmittel auf basis von phenolischen salzen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004506769A true JP2004506769A (ja) | 2004-03-04 |
| JP2004506769A5 JP2004506769A5 (OSRAM) | 2008-07-17 |
Family
ID=7652425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002519552A Pending JP2004506769A (ja) | 2000-08-16 | 2001-08-03 | フェノール系塩を基礎とする老化防止剤 |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US20020072557A1 (OSRAM) |
| EP (1) | EP1311604B1 (OSRAM) |
| JP (1) | JP2004506769A (OSRAM) |
| KR (1) | KR100727512B1 (OSRAM) |
| CN (1) | CN1214063C (OSRAM) |
| AT (1) | ATE308584T1 (OSRAM) |
| AU (1) | AU2002213847A1 (OSRAM) |
| BR (1) | BR0113217B1 (OSRAM) |
| CA (1) | CA2419375A1 (OSRAM) |
| DE (1) | DE50107928D1 (OSRAM) |
| ES (1) | ES2248400T3 (OSRAM) |
| MX (1) | MXPA03001351A (OSRAM) |
| TW (1) | TW538085B (OSRAM) |
| WO (1) | WO2002014419A1 (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016084734A1 (ja) * | 2014-11-27 | 2016-06-02 | 日本ゼオン株式会社 | ニトリルゴム組成物、高飽和ニトリルゴムのラテックス組成物、ゴム架橋物 |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006025423A1 (de) * | 2006-05-31 | 2007-12-06 | Siemens Ag | Röntgenanlage mit dual energy Betrieb und Auswertungsverfahren für im dual energy Betrieb erfasste Projektionsbilder |
| EP2065437A1 (en) | 2007-11-30 | 2009-06-03 | Lanxess Deutschland GmbH | Improved polymer vulcanizate and process for the production thereof |
| EP2145920A1 (en) | 2008-07-15 | 2010-01-20 | Lanxess Deutschland GmbH | Vulcanizable polymer compositions |
| KR101409075B1 (ko) | 2008-09-12 | 2014-06-23 | 란세스 인크. | 향상된 내열성, 압축영구변형률, 및 가공성을 가지는 신규 엘라스토머 조성물 |
| EP2199326B1 (en) * | 2008-12-19 | 2014-10-29 | LANXESS Deutschland GmbH | Vulcanizable polymer compositions |
| KR102365309B1 (ko) | 2014-02-03 | 2022-02-22 | 아란세오 도이치란드 게엠베하 | 안정화된 고무 |
| EP3102632B1 (en) | 2014-02-03 | 2022-12-07 | Aquaspersions Ltd. | Antioxidant stabiliser for polymers |
| CN105985832A (zh) * | 2015-01-29 | 2016-10-05 | 中国石油天然气股份有限公司 | 一种具有抗氧化性能的液压油添加剂组合物 |
| CN105985833A (zh) * | 2015-01-29 | 2016-10-05 | 中国石油天然气股份有限公司 | 一种无锌液压油添加剂组合物 |
| CA2991197A1 (en) | 2015-07-07 | 2017-01-12 | 3M Innovative Properties Company | Electret webs with charge-enhancing additives |
| WO2017007677A1 (en) | 2015-07-07 | 2017-01-12 | 3M Innovative Properties Company | Substituted benzotriazole phenolate salts and antioxidant compositions formed therefrom |
| KR102636758B1 (ko) | 2015-07-07 | 2024-02-15 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 치환된 벤조트라이아졸 페놀 |
| EP3320038A1 (en) | 2015-07-07 | 2018-05-16 | 3M Innovative Properties Company | Polymeric matrices with ionic additives |
| CN107556563A (zh) * | 2017-09-11 | 2018-01-09 | 常州市五洲化工有限公司 | 一种用于热塑性弹性体的新型抗氧剂的制备方法 |
| KR102833236B1 (ko) | 2025-03-04 | 2025-07-14 | 주식회사 대성티엠씨 | Its 기반 터널 소방 설비 연계 비상 상황 대응 장치 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS587436A (ja) * | 1981-07-01 | 1983-01-17 | ユニオン、カ−バイド、コ−ポレ−シヨン | ハロゲン化物残留物を含有する還移金属触媒添加オレフイン重合体におけるゲル化防止成分としての障害されたフエノ−ル性酸化防止剤の金属塩 |
| JPS62260842A (ja) * | 1986-04-25 | 1987-11-13 | チバ−ガイギ− アクチエンゲゼルシヤフト | 光の作用に対して安定化された熱可塑性ポリマ− |
| JPH01211588A (ja) * | 1987-12-19 | 1989-08-24 | Basf Ag | 複素環族ビシクロ〔３．３．１〕ノナン誘導体及びその用途 |
| JPH0360444A (ja) * | 1989-07-28 | 1991-03-15 | Sekisui Chem Co Ltd | 塩化ビニル系合わせガラス用中間膜組成物及びその組成物を用いた合わせガラス用中間膜 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2581909A (en) * | 1949-03-30 | 1952-01-08 | Firestone Tire & Rubber Co | Stabilization of acrylonitrile-butadiene-1, 3 copolymers |
| US2560029A (en) * | 1949-10-28 | 1951-07-10 | Firestone Tire & Rubber Co | Butadiene-styrene rubbery copolymer stabilized with antimonyl-4,6 dimethyl catecholate |
| BE517864A (OSRAM) * | 1952-02-23 | |||
| BE518313A (OSRAM) * | 1952-03-11 | |||
| CH445110A (de) * | 1954-03-13 | 1967-10-15 | Bayer Ag | Verfahren zum Wärmestabilisieren von Polyamiden |
| BE625285A (OSRAM) * | 1961-11-30 | |||
| US3723489A (en) * | 1971-02-25 | 1973-03-27 | Ciba Geigy Corp | Metal derivatives of 3,5-di-t-butyl-4-hydroxyphenyl propionic acid |
| US3906055A (en) * | 1973-09-10 | 1975-09-16 | Stanford Research Inst | Epoxy resin with metal salt of bisphenol or novolac as fire resistant composition |
| US4211663A (en) * | 1978-05-01 | 1980-07-08 | Mobil Oil Corporation | Alkali metal containing transition metal complexes of thiobis (alkylphenols) as stabilizers for various organic media |
| US4444929A (en) * | 1982-11-24 | 1984-04-24 | The B. F. Goodrich Company | Unsymmetrical phosphite-phenolic isocyanurate stabilizer combinations |
| IT1190366B (it) * | 1985-06-19 | 1988-02-16 | Bozetto Ind Chim | Composizioni polimeriche stabilizzate e sistemi stabilizzanti adatti allo scopo |
| TW254955B (OSRAM) * | 1992-09-25 | 1995-08-21 | Ciba Geigy | |
| DE69413981T2 (de) * | 1993-07-15 | 1999-04-01 | Ciba Specialty Chemicals Holding Inc., Basel | Verfahren zur stabilisierung von styrolhaltigem recyklisiertem plastikmaterial und stabilisatormischungen hierfür |
-
2001
- 2001-08-03 AU AU2002213847A patent/AU2002213847A1/en not_active Abandoned
- 2001-08-03 ES ES01982201T patent/ES2248400T3/es not_active Expired - Lifetime
- 2001-08-03 CN CNB018174000A patent/CN1214063C/zh not_active Expired - Fee Related
- 2001-08-03 WO PCT/EP2001/008996 patent/WO2002014419A1/de not_active Ceased
- 2001-08-03 CA CA002419375A patent/CA2419375A1/en not_active Abandoned
- 2001-08-03 JP JP2002519552A patent/JP2004506769A/ja active Pending
- 2001-08-03 DE DE50107928T patent/DE50107928D1/de not_active Expired - Lifetime
- 2001-08-03 MX MXPA03001351A patent/MXPA03001351A/es active IP Right Grant
- 2001-08-03 EP EP01982201A patent/EP1311604B1/de not_active Expired - Lifetime
- 2001-08-03 KR KR1020037002246A patent/KR100727512B1/ko not_active Expired - Fee Related
- 2001-08-03 BR BRPI0113217-2A patent/BR0113217B1/pt not_active IP Right Cessation
- 2001-08-03 AT AT01982201T patent/ATE308584T1/de not_active IP Right Cessation
- 2001-08-14 TW TW090119824A patent/TW538085B/zh not_active IP Right Cessation
- 2001-08-14 US US09/929,190 patent/US20020072557A1/en not_active Abandoned
-
2003
- 2003-11-06 US US10/702,868 patent/US20040092634A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS587436A (ja) * | 1981-07-01 | 1983-01-17 | ユニオン、カ−バイド、コ−ポレ−シヨン | ハロゲン化物残留物を含有する還移金属触媒添加オレフイン重合体におけるゲル化防止成分としての障害されたフエノ−ル性酸化防止剤の金属塩 |
| JPS62260842A (ja) * | 1986-04-25 | 1987-11-13 | チバ−ガイギ− アクチエンゲゼルシヤフト | 光の作用に対して安定化された熱可塑性ポリマ− |
| JPH01211588A (ja) * | 1987-12-19 | 1989-08-24 | Basf Ag | 複素環族ビシクロ〔３．３．１〕ノナン誘導体及びその用途 |
| JPH0360444A (ja) * | 1989-07-28 | 1991-03-15 | Sekisui Chem Co Ltd | 塩化ビニル系合わせガラス用中間膜組成物及びその組成物を用いた合わせガラス用中間膜 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016084734A1 (ja) * | 2014-11-27 | 2016-06-02 | 日本ゼオン株式会社 | ニトリルゴム組成物、高飽和ニトリルゴムのラテックス組成物、ゴム架橋物 |
| KR20170089874A (ko) * | 2014-11-27 | 2017-08-04 | 니폰 제온 가부시키가이샤 | 니트릴 고무 조성물, 고포화 니트릴 고무의 라텍스 조성물, 고무 가교물 |
| JPWO2016084734A1 (ja) * | 2014-11-27 | 2017-09-07 | 日本ゼオン株式会社 | ニトリルゴム組成物、高飽和ニトリルゴムのラテックス組成物、ゴム架橋物 |
| RU2664145C1 (ru) * | 2014-11-27 | 2018-08-15 | Зэон Корпорейшн | Композиция на основе нитрильного каучука, латексная композиция высоконасыщенного нитрильного каучука и сшитый каучук |
| US10308793B2 (en) | 2014-11-27 | 2019-06-04 | Zeon Corporation | Nitrile rubber composition, latex composition of highly saturated nitrile rubber, and cross-linked rubber |
| KR102401457B1 (ko) | 2014-11-27 | 2022-05-23 | 니폰 제온 가부시키가이샤 | 니트릴 고무 조성물, 고포화 니트릴 고무의 라텍스 조성물, 고무 가교물 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE50107928D1 (de) | 2005-12-08 |
| EP1311604A1 (de) | 2003-05-21 |
| EP1311604B1 (de) | 2005-11-02 |
| MXPA03001351A (es) | 2004-04-05 |
| BR0113217A (pt) | 2003-06-24 |
| WO2002014419A1 (de) | 2002-02-21 |
| KR100727512B1 (ko) | 2007-06-14 |
| AU2002213847A1 (en) | 2002-02-25 |
| KR20030028810A (ko) | 2003-04-10 |
| CN1469896A (zh) | 2004-01-21 |
| US20040092634A1 (en) | 2004-05-13 |
| CN1214063C (zh) | 2005-08-10 |
| BR0113217B1 (pt) | 2010-12-14 |
| ATE308584T1 (de) | 2005-11-15 |
| ES2248400T3 (es) | 2006-03-16 |
| TW538085B (en) | 2003-06-21 |
| CA2419375A1 (en) | 2002-02-21 |
| US20020072557A1 (en) | 2002-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2004506769A (ja) | フェノール系塩を基礎とする老化防止剤 | |
| CA1166271A (en) | Discoloration prevention of phenolic antioxidants | |
| US4138389A (en) | Polymeric antioxidants | |
| CN104292141B (zh) | 含硫醚和氨基甲酸酯基团的大分子受阻酚抗氧剂及其制备方法与应用 | |
| AU737822B2 (en) | Phenol/diene novolac resins, process of preparation and rubber-based compositions containing the said resins | |
| JP3424513B2 (ja) | アクリルゴム用酸化防止剤 | |
| US3903049A (en) | Oxidation resistant sulfur curable rubbery polymers | |
| US6946526B2 (en) | Nitrile polymer vulcanizate and process for the production thereof | |
| US4116785A (en) | Phosphonitrilic polymers with curability by sulfur accelerated cures or radiation cures | |
| CA1042888A (en) | Vulcanizable rubber compositions | |
| EP3066088B1 (en) | Cyclic carbonate azide | |
| US4417017A (en) | Polymeric antioxidants prepared from diphenyalmine and dialkylalkenylbenzene or dihydroxyalkylbenzene | |
| CN116284494B (zh) | 一种带烯基壳聚糖基多功能大分子橡胶防老剂及其制备方法和应用 | |
| GB1596594A (en) | Substituted diphenylamines | |
| Avirah et al. | Studies on natural rubber bound para‐phenylenediamine antioxidants in NBR | |
| US5218025A (en) | Method for improving properties of vulcanized rubber containing inorganic whity filler | |
| HK1062308A (en) | Antioxidant agent based on phenolic salts | |
| JPH0499762A (ja) | 芳香族ジチオカルボン酸のスルフアイド誘導体、その製法及びこれより成る天然−及び合成ゴム用の架橋剤 | |
| US4093786A (en) | 1,1-Bis(tert-butylperoxy)cyclododecane | |
| SU836035A1 (ru) | Резинова смесь на основе хлоропреновогоКАучуКА | |
| JPS63275655A (ja) | １，３，４−チアジアゾールのフェノール誘導体を含有するゴム組成物 | |
| JPH07247314A (ja) | メルカプト基含有ポリマーの製法 | |
| EP0335815A2 (en) | Gel prevention in polymers | |
| JPS58120648A (ja) | クロロプレン系合成ゴム用加硫促進剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20070704 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080529 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080529 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20101227 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20101228 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110428 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110511 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110607 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110614 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20120419 |