JP2004503455A5 - - Google Patents
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- Publication number
- JP2004503455A5 JP2004503455A5 JP2000533378A JP2000533378A JP2004503455A5 JP 2004503455 A5 JP2004503455 A5 JP 2004503455A5 JP 2000533378 A JP2000533378 A JP 2000533378A JP 2000533378 A JP2000533378 A JP 2000533378A JP 2004503455 A5 JP2004503455 A5 JP 2004503455A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- phase
- reaction
- phosphorus
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003054 catalyst Substances 0.000 claims description 212
- 229910052698 phosphorus Inorganic materials 0.000 claims description 174
- 239000011574 phosphorus Substances 0.000 claims description 168
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 152
- 238000006243 chemical reaction Methods 0.000 claims description 141
- 239000012071 phase Substances 0.000 claims description 126
- 229910052751 metal Inorganic materials 0.000 claims description 108
- 239000002184 metal Substances 0.000 claims description 108
- 239000007788 liquid Substances 0.000 claims description 103
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 87
- 239000008346 aqueous phase Substances 0.000 claims description 78
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 77
- 238000007254 oxidation reaction Methods 0.000 claims description 56
- 239000000203 mixture Substances 0.000 claims description 55
- 150000002739 metals Chemical class 0.000 claims description 52
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 44
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 claims description 44
- 230000003647 oxidation Effects 0.000 claims description 39
- 239000002253 acid Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 36
- 229910000510 noble metal Inorganic materials 0.000 claims description 35
- 239000007795 chemical reaction product Substances 0.000 claims description 34
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 29
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 22
- 241000894007 species Species 0.000 claims description 22
- 239000007791 liquid phase Substances 0.000 claims description 21
- -1 and oxides Chemical class 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 20
- 239000011780 sodium chloride Substances 0.000 claims description 20
- 239000010949 copper Substances 0.000 claims description 17
- 238000006555 catalytic reaction Methods 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000000047 product Substances 0.000 claims description 16
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 229910052763 palladium Inorganic materials 0.000 claims description 15
- 230000003197 catalytic Effects 0.000 claims description 13
- 239000011541 reaction mixture Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- FZTWZIMSKAGPSB-UHFFFAOYSA-N phosphide(3-) Chemical compound [P-3] FZTWZIMSKAGPSB-UHFFFAOYSA-N 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 229910052703 rhodium Inorganic materials 0.000 claims description 6
- 239000010948 rhodium Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 125000004437 phosphorous atoms Chemical group 0.000 claims description 5
- XTVVROIMIGLXTD-UHFFFAOYSA-N Copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
- 239000012072 active phase Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 229910052803 cobalt Inorganic materials 0.000 claims description 4
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 4
- 238000005755 formation reaction Methods 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000005751 Copper oxide Substances 0.000 claims description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L Copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 150000002902 organometallic compounds Chemical class 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- 230000005501 phase interface Effects 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 230000001590 oxidative Effects 0.000 claims 18
- GQZXNSPRSGFJLY-UHFFFAOYSA-N Hypophosphorous acid Chemical compound OP=O GQZXNSPRSGFJLY-UHFFFAOYSA-N 0.000 claims 16
- 239000000243 solution Substances 0.000 claims 16
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims 11
- 239000000463 material Substances 0.000 claims 9
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 5
- 230000001603 reducing Effects 0.000 claims 5
- 239000004471 Glycine Substances 0.000 claims 4
- 239000012530 fluid Substances 0.000 claims 4
- 235000021317 phosphate Nutrition 0.000 claims 4
- 239000007864 aqueous solution Substances 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- 150000002332 glycine derivatives Chemical class 0.000 claims 3
- 239000002638 heterogeneous catalyst Substances 0.000 claims 3
- 150000004678 hydrides Chemical class 0.000 claims 3
- 238000002156 mixing Methods 0.000 claims 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 3
- 238000010926 purge Methods 0.000 claims 3
- UHZZMRAGKVHANO-UHFFFAOYSA-M 2-chloroethyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N Glyphosate Chemical class OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims 2
- 239000003153 chemical reaction reagent Substances 0.000 claims 2
- 238000009826 distribution Methods 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 238000006366 phosphorylation reaction Methods 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 239000007790 solid phase Substances 0.000 claims 2
- 238000006467 substitution reaction Methods 0.000 claims 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N Hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 229910003481 amorphous carbon Inorganic materials 0.000 claims 1
- 238000010923 batch production Methods 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000012141 concentrate Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 239000011261 inert gas Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 238000005192 partition Methods 0.000 claims 1
- 239000008188 pellet Substances 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- ROFVEXUMMXZLPA-UHFFFAOYSA-N 2,2'-bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- GQDHEYWVLBJKBA-UHFFFAOYSA-H Copper(II) phosphate Chemical compound [Cu+2].[Cu+2].[Cu+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GQDHEYWVLBJKBA-UHFFFAOYSA-H 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J Pyrophosphate Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 239000005092 Ruthenium Substances 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- NHQSYENHCTXNIG-UHFFFAOYSA-N [Cu+3].[O-]P([O-])[O-] Chemical compound [Cu+3].[O-]P([O-])[O-] NHQSYENHCTXNIG-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7608998P | 1998-02-26 | 1998-02-26 | |
| US9904398P | 1998-09-03 | 1998-09-03 | |
| US25025499P | 1999-02-16 | 1999-02-16 | |
| PCT/US1999/003602 WO1999043612A1 (en) | 1998-02-26 | 1999-02-19 | Process and apparatus for preparation of phosphorus oxyacids from elemental phosphorus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004503455A JP2004503455A (ja) | 2004-02-05 |
| JP2004503455A5 true JP2004503455A5 (US06921834-20050726-C00004.png) | 2004-12-24 |
Family
ID=30003654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000533378A Pending JP2004503455A (ja) | 1998-02-26 | 1999-02-19 | 元素状燐から燐オキシ酸を製造する方法および装置 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2004503455A (US06921834-20050726-C00004.png) |
| AR (1) | AR017469A1 (US06921834-20050726-C00004.png) |
| ID (1) | ID27590A (US06921834-20050726-C00004.png) |
| MY (1) | MY133790A (US06921834-20050726-C00004.png) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1681294A1 (en) * | 2005-01-17 | 2006-07-19 | Solutia Europe N.V./S.A. | Process for the manufacture of aminopolyalkylene-phosphonic acid compounds |
| EP1681295A1 (en) * | 2005-01-17 | 2006-07-19 | Solutia Europe N.V./S.A. | Process for the manufacture of aminoakylenephosphonic acid compounds in the presence of a heterogeneous catalyst |
| CA2601510C (en) * | 2005-03-17 | 2013-05-07 | Sasol Technology (Proprietary) Limited | Method of operating a fluid bed reactor |
| WO2013149396A1 (en) * | 2012-04-06 | 2013-10-10 | Rhodia Operations | Process for production of hypophosphite salts |
| JP6402761B2 (ja) * | 2016-09-29 | 2018-10-10 | 住友金属鉱山株式会社 | 酸素吹込配管、及び金属材料の浸出処理方法 |
| CN114950502B (zh) * | 2022-06-21 | 2024-01-16 | 青岛大学 | 一种具有光催化析氢活性和稳定性的纳米棒状红磷光催化剂的制备方法 |
-
1999
- 1999-02-19 JP JP2000533378A patent/JP2004503455A/ja active Pending
- 1999-02-19 ID IDW20001652A patent/ID27590A/id unknown
- 1999-02-24 MY MYPI9900669 patent/MY133790A/en unknown
- 1999-02-26 AR ARP990100839 patent/AR017469A1/es unknown
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