JP2004224690A - 新規な部分酸化反応器 - Google Patents
新規な部分酸化反応器 Download PDFInfo
- Publication number
- JP2004224690A JP2004224690A JP2004015029A JP2004015029A JP2004224690A JP 2004224690 A JP2004224690 A JP 2004224690A JP 2004015029 A JP2004015029 A JP 2004015029A JP 2004015029 A JP2004015029 A JP 2004015029A JP 2004224690 A JP2004224690 A JP 2004224690A
- Authority
- JP
- Japan
- Prior art keywords
- chamber
- reactor
- gas
- reaction
- supply means
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
- B01J8/0221—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/006—Baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/244—Concentric tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00548—Flow
- B01J2208/00557—Flow controlling the residence time inside the reactor vessel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00085—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/0015—Controlling the temperature by thermal insulation means
- B01J2219/00155—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- B01J2219/00768—Baffles attached to the reactor wall vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/187—Details relating to the spatial orientation of the reactor inclined at an angle to the horizontal or to the vertical plane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0883—Methods of cooling by indirect heat exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1276—Mixing of different feed components
- C01B2203/1282—Mixing of different feed components using static mixers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
Abstract
【解決手段】反応器は、任意の方向の軸に沿って伸びた密閉容器、酸素を含む予熱ガス供給手段12、炭化水素供給原料供給手段9、及び水素リッチ流出物の排出手段11を含む部分酸化反応器である。これは、炭化水素供給手段9、及び予熱ガス供給手段12に接続される、ほぼ等温の部分酸化反応が内部で行われる、第1内部チャンバ5を含み、チャンバ5内でガスを乱流状態にする手段、ピストン流れを作る第2チャンバ7への第1チャンバ5の連通手段8を含む。連通手段8は、オリフィスを含み第2チャンバ7は予熱されたガスの供給手段12によって間接的に熱を交換し、第2チャンバ7は、水素リッチ流出物の前記排出手段11に接続する。
【選択図】図1
Description
‐内部中空容器(5)の内面に沿って位置し、かつ流れ中に供給原料損失を発生させる多孔質装置(8)によって終わる断熱材(6)の十分な厚さによって熱絶縁された内部中空容積(5)により構成される流れの方向の第1反応チャンバ。この供給原料損失が、例えば邪魔板(13)のような、ガス反応体を乱流状態にする手段によって第1チャンバ内にもたらされる大きな再循環と組み合わせて、完全に撹拌されるタイプの反応チャンバ(5)を生み出すことに寄与する。
‐ほぼ円環形状の内部中空容積から構成され、かつ燃焼ガスの大きな再循環を発生させ、かつ前記第1チャンバ(305)に完全に撹拌される流れに近い性質を与えるために、円環形インサート(308)を含む第1反応チャンバ(305)。
下記の比較実施例により、典型的な部分酸化供給原料に対する従来の、すなわち高度でない熱集積により比較的低温で機能する、POX反応器の性能を本発明の反応器‐熱交換器の性能と比較することが可能になる。
本発明の図6による反応器‐熱交換器は、一方で同一量のブタンが供給され、かつ他方で空気及び水蒸気の混合物が供給される。ブタンは、前出の実施例と同じ外部熱交換器内で450℃に予熱される。
7 第2チャンバ
8 連通手段
9 炭化水素供給原料供給手段
11 流出物の排出手段
12 予熱ガス供給手段
Claims (13)
- ‐任意の方向の軸に沿って伸びた密閉容器、
‐酸素及び場合により水蒸気を含む予熱ガス供給手段(12)、
‐炭化水素供給原料供給手段(9)、
‐水素リッチ流出物の排出手段(11)、
‐炭化水素供給原料供給手段(9)、及び予熱ガス供給手段(12)に接続される、ほぼ等温の部分酸化反応が内部で行われる、第1内部チャンバ(5)、
‐完全に撹拌されるタイプの流れを生み出すことに適合したガスを乱流状態にする手段、
‐ピストン流れを作るために適した容積の第2チャンバ(7)への第1チャンバ(5)の連通手段(8)を含む部分酸化反応器であって、連通手段(8)は、少なくとも1つのオリフィスを含み、かつ第2チャンバ(7)は、このように予熱された前記ガスの供給手段(12)によって、長さの少なくとも一部に対して間接的に熱を交換し、第2チャンバは、水素リッチ流出物の前記排出手段(11)に接続し、
かつ予熱ガス供給手段(12)は、反応器の密閉容器とほぼ同軸の環状容器を含み、かつ第2チャンバ(7)は、前記密閉容器とほぼ同軸である反応器。 - 第2チャンバ(7)は、連通手段(8)と連通するほぼ断熱の第1領域、及び酸素を含むガスの供給手段(12)により熱を交換する第2領域を含む請求項1に記載の反応器。
- 第2チャンバ(7)の第1領域は、水蒸気改質触媒を含む請求項2に記載の反応器。
- 第2チャンバは、セラミックタイプの材料中に作られるか、又は多孔質又は非多孔質のセラミック材料によって熱流体の側に場合により被覆される金属材料中に作られる請求項1から3のいずれかに記載の反応器。
- 第1チャンバ(5)内部でガスを乱流状態にする手段は、ガスの内部再循環円環壁、邪魔板、及び一方で供給原料をかつ他方で酸素を含むガスを別個にかつほぼ向流で噴射する装置からなる群から選択される請求項1から4のいずれかに記載の反応器。
- 第1チャンバ(5)及び第2チャンバ(7)は、反応器の密閉容器とほぼ同軸であり、かつガス供給手段の環状容器は、第1チャンバ(5)及び第2チャンバ(7)を取り囲む請求項2から5のいずれかに記載の反応器。
- 炭化水素、アルコール又は生物量からの油を含み供給原料からの、かつ請求項1から6のいずれかに記載の反応器を使用する、水素リッチ流出物の生成方法。
- 酸素を含むガスは、理論酸素量に対する質量比0.1〜0.6にあり、かつ第1チャンバ内の再利用率は、25%以上であり、かつ好ましくは50%を超える請求項7に記載の方法。
- 前記ガスは、第2チャンバ内を循環する流出物との間接的熱交換によって800℃〜1400℃の温度で予熱される請求項7又は8のいずれかに記載の方法。
- 第1チャンバの温度、及び場合により第2チャンバの第1領域の温度は、1100℃〜1800℃、かつ好ましくは1400℃〜1650℃である請求項7から9のいずれかに記載の方法。
- モル比H2O/C(式中、Cは、炭化水素供給原料中に含まれる炭素の量を示す)は、0〜2、かつ好ましくは0.2〜0.8である請求項7から10のいずれかに記載の方法。
- 酸素を含むガス供給においてガス状炭化水素を噴射し、かつ第1チャンバの上流で得られる混合物の発火を行って低温点火を行う請求項7から11のいずれかに記載の方法。
- 第1及び第2チャンバ内の滞留時間は、50m秒〜1秒である請求項7から12のいずれかに記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0300751A FR2850372B1 (fr) | 2003-01-23 | 2003-01-23 | Nouveau reacteur d'oxydation partielle |
FR0300751 | 2003-01-23 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2004224690A true JP2004224690A (ja) | 2004-08-12 |
JP2004224690A5 JP2004224690A5 (ja) | 2007-03-08 |
JP5099959B2 JP5099959B2 (ja) | 2012-12-19 |
Family
ID=32669176
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004015029A Expired - Fee Related JP5099959B2 (ja) | 2003-01-23 | 2004-01-23 | 新規な部分酸化反応器 |
Country Status (4)
Country | Link |
---|---|
US (2) | US7422728B2 (ja) |
JP (1) | JP5099959B2 (ja) |
DE (1) | DE102004003468B4 (ja) |
FR (1) | FR2850372B1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010534182A (ja) * | 2007-07-23 | 2010-11-04 | エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツング | アンドルソフ法によりシアン化水素を製造するための反応器 |
JP2011526873A (ja) * | 2008-07-02 | 2011-10-20 | パワーセル スウェーデン アーベー | 炭化水素燃料を水素リッチガスに転化するための改質反応器及び方法 |
KR20160019450A (ko) * | 2013-06-17 | 2016-02-19 | 프랙스에어 테크놀로지, 인코포레이티드 | 산화 반응에서의 그을음 제어 |
JP2016525060A (ja) * | 2013-07-18 | 2016-08-22 | ワット フュエル セル コーポレーション | 改質可能燃料と酸素含有ガス及び/又は蒸気とを混合するための装置及び方法 |
KR20200095071A (ko) * | 2019-01-31 | 2020-08-10 | 한국화학연구원 | 메탄의 비산화 직접전환 반응기 및 이를 이용한 에틸렌 및 방향족 화합물의 제조방법 |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2883861B1 (fr) * | 2005-04-05 | 2007-06-29 | N Ghy Sa | Enceinte de reaction et d'echanges thermiques pour la production d'hydrogene a partir d'hydrocarbure, d'eau et d'oxygene et dispositif generateur d'hydrogene |
DE102005018981A1 (de) * | 2005-04-23 | 2006-10-26 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von Acetylen und Synthesegas durch schnelle Mischung der Reaktanden |
DE102006039933A1 (de) * | 2006-08-25 | 2008-02-28 | Enerday Gmbh | Reformer zum Umsetzen von gasförmigem Brennstoff und Oxidationsmittel zu Reformat |
US7744664B2 (en) * | 2006-11-15 | 2010-06-29 | Delphi Technologies, Inc. | Compact counterflow fuel reformer |
US20120164547A1 (en) * | 2007-07-26 | 2012-06-28 | Bloom Energy Corporation | CPOX Reactor Design for Liquid Fuel and Liquid Water |
PL2198133T3 (pl) * | 2007-08-30 | 2011-08-31 | Energy Conversion Tech As | Zespół filtra cząstek stałych i sposób czyszczenia filtra cząstek stałych |
CN105293435A (zh) * | 2008-07-02 | 2016-02-03 | 瑞典电池公司 | 将烃类燃料转化为富氢气体的方法 |
EP2526268A4 (en) * | 2009-12-31 | 2015-08-12 | Westport Power Inc | ENGINE SYSTEM WITH EXHAUST COOLED FUEL PROCESSOR |
WO2012005644A1 (en) * | 2010-07-09 | 2012-01-12 | Reformtech Sweden Ab | Method for providing a homogeneous mixture of liquid fuels and oxidants for use in a catalytic reactor |
EP2598741A4 (en) * | 2010-07-26 | 2014-06-25 | Westport Power Inc | FUEL PROCESSOR WITH MOUNTED COLLECTION |
DE102011100417A1 (de) * | 2011-05-04 | 2012-11-08 | Vaillant Gmbh | Reformer |
US9627701B2 (en) | 2013-11-06 | 2017-04-18 | Watt Fuel Cell Corp. | Integrated gaseous fuel CPOX reformer and fuel cell systems, and methods of producing electricity |
CA2929816C (en) | 2013-11-06 | 2018-03-13 | Watt Fuel Cell Corp. | Chemical reactor with manifold for management of a flow of gaseous reaction medium thereto |
JP6549600B2 (ja) | 2013-11-06 | 2019-07-24 | ワット・フューエル・セル・コーポレイションWatt Fuel Cell Corp. | 液体燃料cpox改質器と燃料セルの統合システム、及び電気を生成する方法 |
CA2929546C (en) | 2013-11-06 | 2019-03-05 | Watt Fuel Cell Corp. | Gaseous fuel cpox reformers and methods of cpox reforming |
JP6285563B2 (ja) | 2013-11-06 | 2018-02-28 | ワット・フューエル・セル・コーポレイションWatt Fuel Cell Corp. | 構造成分としてペロブスカイトを有する改質器 |
KR101796509B1 (ko) | 2013-11-06 | 2017-12-01 | 와트 퓨얼 셀 코퍼레이션 | 액체 연료 촉매 부분산화 개질 장치 및 촉매 부분산화 개질 방법 |
US9595726B2 (en) | 2014-01-07 | 2017-03-14 | Advanced Cooling Technologies, Inc. | Fuel reforming system and process |
KR101771303B1 (ko) * | 2015-02-16 | 2017-08-24 | 한국가스공사 | 연료처리장치 |
US10557391B1 (en) * | 2017-05-18 | 2020-02-11 | Advanced Cooling Technologies, Inc. | Incineration system and process |
CN112654421B (zh) * | 2018-09-05 | 2023-05-09 | 巴斯夫欧洲公司 | 用于进行两种不同密度的不混溶流体之间的反应的反应器 |
EP3747537A1 (en) * | 2019-06-06 | 2020-12-09 | CMI UVK GmbH | Reactor for treating a metal containing acid solution, in particular a pickling sludge, and/or for regenerating an acid component from a metal containing acid solution, preheater device, method |
US20220234887A1 (en) * | 2021-01-25 | 2022-07-28 | Bradley D. Damstedt | Methods of operational flexibility in partial oxidation |
CN114160051A (zh) * | 2021-12-31 | 2022-03-11 | 华东理工大学 | 反应装置 |
CN114873561A (zh) * | 2022-05-12 | 2022-08-09 | 哈尔滨工业大学 | 一种变催化剂粒径的填充床式重整制氢反应器及反应方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3516807A (en) * | 1966-04-06 | 1970-06-23 | Texas Instruments Inc | Apparatus for producing hydrogen gas by the partial oxidation of a carbonaceous fuel containing hydrogen |
US4650651A (en) * | 1983-06-09 | 1987-03-17 | Union Carbide Corporation | Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons |
JPH04154602A (ja) * | 1990-10-18 | 1992-05-27 | Mitsubishi Gas Chem Co Inc | 断熱リホーマー装置 |
JP2002003204A (ja) * | 2000-06-15 | 2002-01-09 | Toshiba Corp | 燃料改質器 |
WO2002045838A1 (en) * | 2000-12-05 | 2002-06-13 | Texaco Development Corporation | Compact fuel processor for producing a hydrogen rich gas |
JP2003306305A (ja) * | 2002-04-09 | 2003-10-28 | Nippon Oil Corp | オートサーマルリフォーミング方法および装置 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2592320B1 (fr) * | 1985-12-30 | 1988-04-08 | Inst Francais Du Petrole | Nouveau procede d'oxydation d'une charge oxydable en phase gazeuse et reacteur pour la mise en oeuvre de ce procede. |
US5441546A (en) * | 1993-11-08 | 1995-08-15 | Moard; David | Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources |
US6126908A (en) * | 1996-08-26 | 2000-10-03 | Arthur D. Little, Inc. | Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
DE19955892C2 (de) * | 1999-11-20 | 2002-04-25 | Daimler Chrysler Ag | Vorrichtung zur Reformierung eines Kohlenwasserstoffs mit langkettigen Kohlenwasserstoffanteilen |
US6650651B1 (en) * | 1999-12-13 | 2003-11-18 | Nortel Networks Limited | System and method to implement a packet switch output buffer |
US7367996B2 (en) * | 2001-05-30 | 2008-05-06 | Nuvera Fuel Cells, Inc. | Heat transfer optimization in multi shelled reformers |
US6936238B2 (en) * | 2002-09-06 | 2005-08-30 | General Motors Corporation | Compact partial oxidation/steam reactor with integrated air preheater, fuel and water vaporizer |
-
2003
- 2003-01-23 FR FR0300751A patent/FR2850372B1/fr not_active Expired - Fee Related
-
2004
- 2004-01-22 DE DE102004003468A patent/DE102004003468B4/de not_active Expired - Fee Related
- 2004-01-23 US US10/762,238 patent/US7422728B2/en not_active Expired - Fee Related
- 2004-01-23 JP JP2004015029A patent/JP5099959B2/ja not_active Expired - Fee Related
-
2008
- 2008-05-22 US US12/125,411 patent/US7625414B2/en not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3516807A (en) * | 1966-04-06 | 1970-06-23 | Texas Instruments Inc | Apparatus for producing hydrogen gas by the partial oxidation of a carbonaceous fuel containing hydrogen |
US4650651A (en) * | 1983-06-09 | 1987-03-17 | Union Carbide Corporation | Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons |
JPH04154602A (ja) * | 1990-10-18 | 1992-05-27 | Mitsubishi Gas Chem Co Inc | 断熱リホーマー装置 |
JP2002003204A (ja) * | 2000-06-15 | 2002-01-09 | Toshiba Corp | 燃料改質器 |
WO2002045838A1 (en) * | 2000-12-05 | 2002-06-13 | Texaco Development Corporation | Compact fuel processor for producing a hydrogen rich gas |
JP2004515432A (ja) * | 2000-12-05 | 2004-05-27 | テキサコ ディベラップメント コーポレイション | 水素リッチのガスを生成させるためのコンパクトな燃料処理装置 |
JP2003306305A (ja) * | 2002-04-09 | 2003-10-28 | Nippon Oil Corp | オートサーマルリフォーミング方法および装置 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010534182A (ja) * | 2007-07-23 | 2010-11-04 | エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツング | アンドルソフ法によりシアン化水素を製造するための反応器 |
US8802020B2 (en) | 2007-07-23 | 2014-08-12 | Evonik Röhm Gmbh | Reactor for preparing hydrogen cyanide by the Andrussow process |
JP2011526873A (ja) * | 2008-07-02 | 2011-10-20 | パワーセル スウェーデン アーベー | 炭化水素燃料を水素リッチガスに転化するための改質反応器及び方法 |
KR20160019450A (ko) * | 2013-06-17 | 2016-02-19 | 프랙스에어 테크놀로지, 인코포레이티드 | 산화 반응에서의 그을음 제어 |
JP2016528137A (ja) * | 2013-06-17 | 2016-09-15 | プラクスエア・テクノロジー・インコーポレイテッド | 酸化反応における煤の制御 |
KR102244458B1 (ko) | 2013-06-17 | 2021-04-23 | 프랙스에어 테크놀로지, 인코포레이티드 | 산화 반응에서의 그을음 제어 |
JP2016525060A (ja) * | 2013-07-18 | 2016-08-22 | ワット フュエル セル コーポレーション | 改質可能燃料と酸素含有ガス及び/又は蒸気とを混合するための装置及び方法 |
KR20200095071A (ko) * | 2019-01-31 | 2020-08-10 | 한국화학연구원 | 메탄의 비산화 직접전환 반응기 및 이를 이용한 에틸렌 및 방향족 화합물의 제조방법 |
KR102190110B1 (ko) | 2019-01-31 | 2020-12-11 | 한국화학연구원 | 메탄의 비산화 직접전환 반응기 및 이를 이용한 에틸렌 및 방향족 화합물의 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
US20040151663A1 (en) | 2004-08-05 |
US20080307707A1 (en) | 2008-12-18 |
JP5099959B2 (ja) | 2012-12-19 |
DE102004003468A1 (de) | 2004-08-05 |
FR2850372A1 (fr) | 2004-07-30 |
FR2850372B1 (fr) | 2006-06-09 |
US7625414B2 (en) | 2009-12-01 |
DE102004003468B4 (de) | 2012-10-25 |
US7422728B2 (en) | 2008-09-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5099959B2 (ja) | 新規な部分酸化反応器 | |
US5110563A (en) | Catalytic combustion | |
US5229102A (en) | Catalytic ceramic membrane steam-hydrocarbon reformer | |
US6506359B1 (en) | Auto-oxidation and internal heating type reforming method and apparatus for hydrogen production | |
US9561958B2 (en) | Isothermal reactor for partial oxidation of methane | |
KR100858834B1 (ko) | 컴팩트형 증기 개질기 | |
US11701632B2 (en) | Method and reactor for producing one or more products | |
US6835482B2 (en) | Fuel reforming apparatus for polymer electrolyte membrane fuel cell | |
RU2411075C2 (ru) | Компактный риформинг-реактор | |
US20080127553A1 (en) | Mehtod and system for vaporization of liquid fuels | |
JP2004537487A (ja) | イオン輸送膜装置及び方法 | |
EA003626B1 (ru) | Эндотермический реактор | |
JP2002187705A (ja) | 単管円筒式改質器 | |
JP2004224690A5 (ja) | ||
EP0199878B1 (en) | Apparatus for hydrocarbon fuel processing | |
US4938685A (en) | Catalytic combustion | |
ZA200509014B (en) | Device for converting gaseous streams | |
RU2374173C1 (ru) | Способ получения синтез-газа | |
US20020132147A1 (en) | Chambered reactor for fuel processing | |
GB2384726A (en) | Heating of autothermal hydrocarbon reformation reactor | |
JPH06305702A (ja) | ガス改質装置の起動方法 | |
JPH06206702A (ja) | 炭化水素反応器 | |
CA1299088C (en) | Catalytic combustion |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070119 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070119 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100720 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101018 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101021 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101118 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101124 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101216 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101221 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110120 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111206 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120227 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120828 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120925 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20151005 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5099959 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |