JP2003518169A5 - - Google Patents
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- JP2003518169A5 JP2003518169A5 JP2001547180A JP2001547180A JP2003518169A5 JP 2003518169 A5 JP2003518169 A5 JP 2003518169A5 JP 2001547180 A JP2001547180 A JP 2001547180A JP 2001547180 A JP2001547180 A JP 2001547180A JP 2003518169 A5 JP2003518169 A5 JP 2003518169A5
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- Prior art keywords
- support
- catalyst
- compound
- resin
- metal
- Prior art date
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- 238000000034 method Methods 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Description
【特許請求の範囲】
【請求項１】 (ａ)(ｉ)少なくとも１つのカチオン及び
(ｉｉ)少なくとも非配位性であるか又は弱く配位するアニオンを含む、支持体に結合された触媒活性剤を提供し、支持体が支持体粒子又はポリマー鎖であり、２ミクロン以下であり、脂肪族溶媒に可溶性であるか又は分散可能であること、
(ｂ)触媒に支持体に結合した触媒活性剤を接触させることにより触媒を活性化すること、並びに
(ｃ)重合条件下で、オレフィンモノマーに活性化された触媒化合物を接触させること
を含む、ポリオレフィン樹脂を製造する方法。
【請求項２】 支持体が、熱分解法シリカ、アルミナ、アルミノ珪酸塩、又はシリカ含有第１４族化合物を含む、請求項１の方法。
【請求項３】 支持体が本質的にヒドロカルビルポリマー鎖を含む、請求項１の方法。
【請求項４】 重合条件が、本質的に溶液相又は超臨界相重合条件である、請求項１の方法。
【請求項５】 樹脂が、エチレンから誘導される単位を含有するエラストマー性ポリマーである、請求項１乃至４のいずれか１請求項の方法。
【請求項６】 オレフィンがプロピレンである、請求項５の方法。
【請求項７】 樹脂が、エチレンから誘導された単位を含む半結晶性又は結晶性のポリマーである、請求項１又は２の方法。
【請求項８】 請求項１乃至７のいずれか１請求項の方法により製造される樹脂を含む電気装置。
【請求項９】触媒化合物が少なくとも一つのシクロペンタジエニル基を含有する有機金属の３乃至６族金属化合物である、請求項１乃至８のいずれか１請求項の方法。
【請求項１０】 金属がチタンであり、金属化合物が１つの、π結合されたシクロペンタジエニル基を含む、請求項９の方法。
【請求項１１】 金属がジルコニウム又はハフニウムを含有し、金属化合物が少なくとも２つのシクロペンタジエニル基を含有する、請求項９の方法。
【請求項１】 (ａ)(ｉ)少なくとも１つのカチオン及び
(ｉｉ)少なくとも非配位性であるか又は弱く配位するアニオンを含む、支持体に結合された触媒活性剤を提供し、支持体が支持体粒子又はポリマー鎖であり、２ミクロン以下であり、脂肪族溶媒に可溶性であるか又は分散可能であること、
(ｂ)触媒に支持体に結合した触媒活性剤を接触させることにより触媒を活性化すること、並びに
(ｃ)重合条件下で、オレフィンモノマーに活性化された触媒化合物を接触させること
を含む、ポリオレフィン樹脂を製造する方法。
【請求項２】 支持体が、熱分解法シリカ、アルミナ、アルミノ珪酸塩、又はシリカ含有第１４族化合物を含む、請求項１の方法。
【請求項３】 支持体が本質的にヒドロカルビルポリマー鎖を含む、請求項１の方法。
【請求項４】 重合条件が、本質的に溶液相又は超臨界相重合条件である、請求項１の方法。
【請求項５】 樹脂が、エチレンから誘導される単位を含有するエラストマー性ポリマーである、請求項１乃至４のいずれか１請求項の方法。
【請求項６】 オレフィンがプロピレンである、請求項５の方法。
【請求項７】 樹脂が、エチレンから誘導された単位を含む半結晶性又は結晶性のポリマーである、請求項１又は２の方法。
【請求項８】 請求項１乃至７のいずれか１請求項の方法により製造される樹脂を含む電気装置。
【請求項９】触媒化合物が少なくとも一つのシクロペンタジエニル基を含有する有機金属の３乃至６族金属化合物である、請求項１乃至８のいずれか１請求項の方法。
【請求項１０】 金属がチタンであり、金属化合物が１つの、π結合されたシクロペンタジエニル基を含む、請求項９の方法。
【請求項１１】 金属がジルコニウム又はハフニウムを含有し、金属化合物が少なくとも２つのシクロペンタジエニル基を含有する、請求項９の方法。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17273799P | 1999-12-20 | 1999-12-20 | |
| US60/172,737 | 1999-12-20 | ||
| PCT/US2000/034706 WO2001046273A1 (en) | 1999-12-20 | 2000-12-20 | Processes for the preparation polyolefin resins using supported ionic catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003518169A JP2003518169A (ja) | 2003-06-03 |
| JP2003518169A5 true JP2003518169A5 (ja) | 2008-03-06 |
Family
ID=22629002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001547180A Withdrawn JP2003518169A (ja) | 1999-12-20 | 2000-12-20 | 担持イオン性触媒を使用するポリオレフィン樹脂の製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US6562920B2 (ja) |
| EP (1) | EP1250362B1 (ja) |
| JP (1) | JP2003518169A (ja) |
| KR (1) | KR20020063242A (ja) |
| CN (2) | CN1227272C (ja) |
| AT (1) | ATE395368T1 (ja) |
| BR (1) | BR0016495A (ja) |
| CA (1) | CA2393327A1 (ja) |
| DE (1) | DE60038900D1 (ja) |
| MX (1) | MXPA02006197A (ja) |
| WO (1) | WO2001046273A1 (ja) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6562920B2 (en) | 1999-12-20 | 2003-05-13 | Exxonmobil Chemical Patents Inc. | Processes for the preparation polyolefin resins using supported ionic catalysts |
| US6818013B2 (en) * | 2001-06-14 | 2004-11-16 | Cordis Corporation | Intravascular stent device |
| WO2003000740A2 (en) | 2001-06-20 | 2003-01-03 | Exxonmobil Chemical Patents Inc. | Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them |
| DE10163154A1 (de) * | 2001-12-20 | 2003-07-03 | Basell Polyolefine Gmbh | Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation |
| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| US8058371B2 (en) * | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
| US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
| US8008412B2 (en) * | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| CN101041701B (zh) | 2002-09-20 | 2013-02-27 | 埃克森美孚化学专利公司 | 包括丙烯的聚合物及其应用 |
| AU2003277350A1 (en) | 2002-10-24 | 2004-05-13 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US7144934B2 (en) * | 2002-10-24 | 2006-12-05 | Dow Global Technologies Inc. | Charge dissipation modifiers for olefinic interpolymer compositions |
| WO2004052950A1 (en) * | 2002-12-05 | 2004-06-24 | Exxonmobil Chemical Patents Inc. | High temperature bulk polymerization of branched crystalline polypropylene |
| WO2004052952A1 (en) | 2002-12-05 | 2004-06-24 | Exxonmobil Chemical Patents Inc. | Branched diene-modified crystalline polypropylene terpolymers |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| WO2006019494A1 (en) | 2004-07-14 | 2006-02-23 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
| US7662895B2 (en) * | 2005-11-22 | 2010-02-16 | Exxonmobil Chemical Patents Inc. | Syndiotactic propylene elastomers |
| US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
| EP2201042B1 (en) * | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line blending of plasticizers with a base polymer |
| CN101855249B (zh) | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
| US7910679B2 (en) * | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
| EP2450403A1 (en) | 2007-12-20 | 2012-05-09 | ExxonMobil Research and Engineering Company | Polypropylene ethylene-propylene copolymer blends and in-line process to produce them |
| US7994237B2 (en) * | 2007-12-20 | 2011-08-09 | Exxonmobil Research And Engineering Company | In-line process to produce pellet-stable polyolefins |
| US8318875B2 (en) * | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US7939610B2 (en) | 2008-05-22 | 2011-05-10 | Exxonmobil Research And Engineering Company | Polymerization processes for broadened molecular weight distribution |
| US8399586B2 (en) | 2008-09-05 | 2013-03-19 | Exxonmobil Research And Engineering Company | Process for feeding ethylene to polymerization reactors |
| US20100113692A1 (en) * | 2008-11-04 | 2010-05-06 | Mcguire Jr James E | Apparatus for Continuous Production of Partially Polymerized Compositions |
| US8765217B2 (en) * | 2008-11-04 | 2014-07-01 | Entrotech, Inc. | Method for continuous production of (meth)acrylate syrup and adhesives therefrom |
| US8329079B2 (en) * | 2009-04-20 | 2012-12-11 | Entrochem, Inc. | Method and apparatus for continuous production of partially polymerized compositions and polymers therefrom |
| US8372924B2 (en) | 2010-01-14 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
| US8425847B2 (en) | 2010-01-14 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
| US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| WO2021086468A1 (en) * | 2019-10-28 | 2021-05-06 | Exxonmobil Chemical Patents Inc. | Supported non-coordinating anion activators, use thereof, and production thereof |
| US20240018283A1 (en) * | 2020-11-24 | 2024-01-18 | Lg Chem, Ltd. | Organic-inorganic hybrid polyolefin composite and preparation method thereof |
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2000
- 2000-12-20 US US09/742,762 patent/US6562920B2/en not_active Expired - Fee Related
- 2000-12-20 KR KR1020027007884A patent/KR20020063242A/ko not_active Application Discontinuation
- 2000-12-20 CN CNB008174067A patent/CN1227272C/zh not_active Expired - Fee Related
- 2000-12-20 EP EP00986633A patent/EP1250362B1/en not_active Expired - Lifetime
- 2000-12-20 US US09/745,232 patent/US6590055B2/en not_active Expired - Fee Related
- 2000-12-20 BR BR0016495-0A patent/BR0016495A/pt not_active IP Right Cessation
- 2000-12-20 CA CA002393327A patent/CA2393327A1/en not_active Abandoned
- 2000-12-20 CN CNA2004100973341A patent/CN1631910A/zh active Pending
- 2000-12-20 AT AT00986633T patent/ATE395368T1/de not_active IP Right Cessation
- 2000-12-20 DE DE60038900T patent/DE60038900D1/de not_active Expired - Lifetime
- 2000-12-20 JP JP2001547180A patent/JP2003518169A/ja not_active Withdrawn
- 2000-12-20 WO PCT/US2000/034706 patent/WO2001046273A1/en active Application Filing
- 2000-12-20 MX MXPA02006197A patent/MXPA02006197A/es not_active Application Discontinuation
-
2003
- 2003-05-28 US US10/446,320 patent/US7163993B2/en not_active Expired - Fee Related
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