JP2002523647A - コポリエステルバインダー繊維 - Google Patents
コポリエステルバインダー繊維Info
- Publication number
- JP2002523647A JP2002523647A JP2000567770A JP2000567770A JP2002523647A JP 2002523647 A JP2002523647 A JP 2002523647A JP 2000567770 A JP2000567770 A JP 2000567770A JP 2000567770 A JP2000567770 A JP 2000567770A JP 2002523647 A JP2002523647 A JP 2002523647A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- copolyester
- binder fiber
- component
- dicarboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 272
- 229920001634 Copolyester Polymers 0.000 title claims abstract description 219
- 239000011230 binding agent Substances 0.000 title claims abstract description 144
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 190
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 89
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 56
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims abstract description 39
- -1 amine compound Chemical class 0.000 claims description 79
- 239000003054 catalyst Substances 0.000 claims description 78
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 60
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 57
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 57
- 239000000203 mixture Substances 0.000 claims description 56
- 239000000463 material Substances 0.000 claims description 48
- 229920000728 polyester Polymers 0.000 claims description 44
- 150000002148 esters Chemical class 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 32
- 239000002253 acid Substances 0.000 claims description 30
- 229920000642 polymer Polymers 0.000 claims description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 150000008064 anhydrides Chemical class 0.000 claims description 21
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 20
- 229910052787 antimony Inorganic materials 0.000 claims description 19
- 239000000155 melt Substances 0.000 claims description 18
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 16
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims description 13
- 239000003060 catalysis inhibitor Substances 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 11
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- 229920000098 polyolefin Polymers 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 150000001805 chlorine compounds Chemical class 0.000 claims description 8
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims description 8
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 claims description 7
- 150000001414 amino alcohols Chemical class 0.000 claims description 7
- 150000004985 diamines Chemical class 0.000 claims description 7
- 150000003951 lactams Chemical class 0.000 claims description 7
- 125000002723 alicyclic group Chemical group 0.000 claims description 5
- 150000001413 amino acids Chemical class 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 5
- 229920001123 polycyclohexylenedimethylene terephthalate Polymers 0.000 claims description 5
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- LNYYKKTXWBNIOO-UHFFFAOYSA-N 3-oxabicyclo[3.3.1]nona-1(9),5,7-triene-2,4-dione Chemical compound C1=CC(C(=O)OC2=O)=CC2=C1 LNYYKKTXWBNIOO-UHFFFAOYSA-N 0.000 claims description 3
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 claims description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 2
- 239000004626 polylactic acid Substances 0.000 claims description 2
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 claims 2
- 239000002861 polymer material Substances 0.000 claims 2
- 239000004745 nonwoven fabric Substances 0.000 abstract description 21
- 239000002131 composite material Substances 0.000 abstract description 7
- 239000004753 textile Substances 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 26
- 238000005809 transesterification reaction Methods 0.000 description 26
- 239000000047 product Substances 0.000 description 21
- 239000003086 colorant Substances 0.000 description 20
- 238000006068 polycondensation reaction Methods 0.000 description 20
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 18
- 239000010936 titanium Substances 0.000 description 18
- 239000010941 cobalt Substances 0.000 description 17
- 229910017052 cobalt Inorganic materials 0.000 description 17
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 17
- 239000011162 core material Substances 0.000 description 17
- 239000011572 manganese Substances 0.000 description 16
- 239000008188 pellet Substances 0.000 description 16
- 239000004744 fabric Substances 0.000 description 12
- 238000002844 melting Methods 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 11
- 239000000975 dye Substances 0.000 description 10
- 238000005886 esterification reaction Methods 0.000 description 10
- 229910052719 titanium Inorganic materials 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- 229910052725 zinc Inorganic materials 0.000 description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 238000004043 dyeing Methods 0.000 description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 8
- 229910052748 manganese Inorganic materials 0.000 description 8
- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 description 7
- VXUYXOFXAQZZMF-UHFFFAOYSA-N tetraisopropyl titanate Substances CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 238000001994 activation Methods 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 229940071125 manganese acetate Drugs 0.000 description 6
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 230000004913 activation Effects 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 239000006085 branching agent Substances 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 229910052733 gallium Inorganic materials 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000002074 melt spinning Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 241000288673 Chiroptera Species 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- 229940011182 cobalt acetate Drugs 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 229910052732 germanium Inorganic materials 0.000 description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WYOFTXWVYIGTCT-UHFFFAOYSA-K [OH-].[Sb+3].OCC([O-])=O.OCC([O-])=O Chemical compound [OH-].[Sb+3].OCC([O-])=O.OCC([O-])=O WYOFTXWVYIGTCT-UHFFFAOYSA-K 0.000 description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 2
- 238000007718 adhesive strength test Methods 0.000 description 2
- 229920006125 amorphous polymer Polymers 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000009960 carding Methods 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 238000011437 continuous method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- HYZQBNDRDQEWAN-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;manganese(3+) Chemical compound [Mn+3].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O HYZQBNDRDQEWAN-LNTINUHCSA-N 0.000 description 1
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
- GZZLQUBMUXEOBE-UHFFFAOYSA-N 2,2,4-trimethylhexane-1,6-diol Chemical compound OCCC(C)CC(C)(C)CO GZZLQUBMUXEOBE-UHFFFAOYSA-N 0.000 description 1
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 1
- FOUQLSBYBRTDKN-UHFFFAOYSA-L 2-carboxyphenolate;cobalt(2+) Chemical compound [Co+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O FOUQLSBYBRTDKN-UHFFFAOYSA-L 0.000 description 1
- BUYHVRZQBLVJOO-UHFFFAOYSA-N 2-ethyl-2,4-dimethylhexane-1,3-diol Chemical compound CCC(C)C(O)C(C)(CC)CO BUYHVRZQBLVJOO-UHFFFAOYSA-N 0.000 description 1
- QNKRHLZUPSSIPN-UHFFFAOYSA-N 2-ethyl-2-(2-methylpropyl)propane-1,3-diol Chemical compound CCC(CO)(CO)CC(C)C QNKRHLZUPSSIPN-UHFFFAOYSA-N 0.000 description 1
- QUVMSYUGOKEMPX-UHFFFAOYSA-N 2-methylpropan-1-olate;titanium(4+) Chemical compound [Ti+4].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] QUVMSYUGOKEMPX-UHFFFAOYSA-N 0.000 description 1
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 1
- 229920008790 Amorphous Polyethylene terephthalate Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102100032566 Carbonic anhydrase-related protein 10 Human genes 0.000 description 1
- 229920008651 Crystalline Polyethylene terephthalate Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- 101000867836 Homo sapiens Carbonic anhydrase-related protein 10 Proteins 0.000 description 1
- RFAXLXKIAKIUDT-UHFFFAOYSA-N IPA-3 Chemical compound C1=CC=C2C(SSC3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 RFAXLXKIAKIUDT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- XDODWINGEHBYRT-UHFFFAOYSA-N [2-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCCC1CO XDODWINGEHBYRT-UHFFFAOYSA-N 0.000 description 1
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 description 1
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- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
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- VQNBUJAEBQLLKU-UHFFFAOYSA-H tricalcium;diphosphate;hydrate Chemical compound O.[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VQNBUJAEBQLLKU-UHFFFAOYSA-H 0.000 description 1
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- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- HYPTXUAFIRUIRD-UHFFFAOYSA-N tripropan-2-yl stiborite Chemical compound [Sb+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] HYPTXUAFIRUIRD-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Artificial Filaments (AREA)
- Multicomponent Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/143,437 US6197856B1 (en) | 1997-08-28 | 1998-08-28 | Copolymer binder fibers |
| US09/143,437 | 1998-08-28 | ||
| US09/187,004 | 1998-11-06 | ||
| US09/187,004 US6132868A (en) | 1997-11-06 | 1998-11-06 | Copolyester binder fibers |
| PCT/US1999/017830 WO2000012792A1 (en) | 1998-08-28 | 1999-08-06 | Copolyester binder fibers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002523647A true JP2002523647A (ja) | 2002-07-30 |
| JP2002523647A5 JP2002523647A5 (enExample) | 2006-10-05 |
Family
ID=26841030
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000567769A Pending JP2002523646A (ja) | 1998-08-28 | 1999-08-06 | ネオペンチルグリコールを含むポリエステル及びそれから形成された繊維 |
| JP2000567770A Pending JP2002523647A (ja) | 1998-08-28 | 1999-08-06 | コポリエステルバインダー繊維 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000567769A Pending JP2002523646A (ja) | 1998-08-28 | 1999-08-06 | ネオペンチルグリコールを含むポリエステル及びそれから形成された繊維 |
Country Status (7)
| Country | Link |
|---|---|
| EP (2) | EP1115925B1 (enExample) |
| JP (2) | JP2002523646A (enExample) |
| CN (2) | CN1324415A (enExample) |
| BR (2) | BR9913205A (enExample) |
| DE (2) | DE69921487T2 (enExample) |
| MX (2) | MXPA01001886A (enExample) |
| WO (2) | WO2000012792A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012111860A1 (ja) | 2011-02-18 | 2012-08-23 | ミドリ安全株式会社 | 自然環境条件下及びこれより厳しい自然環境条件下又はこれと同様又はこれ以上に厳しい使用条件下に安定であり、耐薬品性と耐久性に優れた透明樹脂組成物及びそれを用いる製品 |
| KR101212885B1 (ko) * | 2003-12-30 | 2012-12-14 | 킴벌리-클라크 월드와이드, 인크. | 감소된 린트 및 슬러프를 갖는 부직 웹 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6495656B1 (en) * | 1990-11-30 | 2002-12-17 | Eastman Chemical Company | Copolyesters and fibrous materials formed therefrom |
| EP1200505B1 (en) | 1999-08-06 | 2004-07-07 | Eastman Chemical Company | Polyesters having a controlled melting point and fibers formed therefrom |
| US7994078B2 (en) | 2002-12-23 | 2011-08-09 | Kimberly-Clark Worldwide, Inc. | High strength nonwoven web from a biodegradable aliphatic polyester |
| US7892993B2 (en) * | 2003-06-19 | 2011-02-22 | Eastman Chemical Company | Water-dispersible and multicomponent fibers from sulfopolyesters |
| KR100519164B1 (ko) * | 2003-09-16 | 2005-10-05 | 주식회사 효성 | 심색성 폴리에스터 해도형 복합사 및 이의 제조방법 |
| CN100432118C (zh) * | 2006-03-22 | 2008-11-12 | 南昌大学 | 原位酯交换低聚乳酸合成可降解性芳香/脂肪共聚酯的方法 |
| CN102177190A (zh) * | 2008-08-07 | 2011-09-07 | 英威达技术有限公司 | 制备聚酯的方法 |
| WO2010026361A1 (en) * | 2008-08-07 | 2010-03-11 | Invista Technologies S.A.R.L. | Process for production of polyesters with low acetaldehyde content and regeneration rate |
| JP5735844B2 (ja) * | 2011-04-07 | 2015-06-17 | 株式会社クラレ | 染色性に優れたカチオン可染ポリエステル繊維および繊維集合体 |
| CN104499084B (zh) * | 2014-12-31 | 2016-11-30 | 江苏恒力化纤股份有限公司 | 一种高上染率聚酯纤维fdy丝及其制备方法 |
| KR102471008B1 (ko) * | 2016-03-04 | 2022-11-24 | 도레이첨단소재 주식회사 | 안티몬 비용출 심초형 복합섬유 및 이를 포함하는 안티몬 비용출 트리코트 여과직물 |
| FR3063080B1 (fr) * | 2017-02-23 | 2021-04-30 | Bostik Sa | Composition comprenant un polyester et film adhesif activable a basse temperature |
| EP3466389B1 (en) * | 2017-10-06 | 2020-05-20 | The Procter & Gamble Company | Absorbent article comprising a carded resin-bonded nonwoven web with fibers comprising antimony-free polyethylene terephthalate |
| EP3466385B1 (en) | 2017-10-06 | 2020-05-27 | The Procter & Gamble Company | Absorbent article or wipe comprising a nonwoven material with bicomponent fibers comprising antimony-free polyethylene terephthalate |
| CN109111587B (zh) * | 2018-08-20 | 2023-05-26 | 浙江汇锋智造科技有限公司 | 阻燃抗腐蚀环境工程用高分子膜材的制备方法及其装置 |
| TWI682945B (zh) * | 2018-09-20 | 2020-01-21 | 遠東新世紀股份有限公司 | 用於製備低熔點共聚酯纖維的樹脂、低熔點共聚酯纖維及其製備方法 |
| CN113767197A (zh) * | 2019-07-15 | 2021-12-07 | 普莱玛有限公司 | 回收聚酯粘合剂纤维 |
| CN114901882B (zh) * | 2019-12-27 | 2023-09-08 | 韩国商东丽先端素材股份有限公司 | 汽车内饰材料用纤维集合体及包括其的汽车内饰材料 |
| WO2022065191A1 (ja) * | 2020-09-28 | 2022-03-31 | 東洋紡株式会社 | 長繊維不織布、及び、長繊維不織布の製造方法 |
| TWI803790B (zh) * | 2020-11-24 | 2023-06-01 | 遠東新世紀股份有限公司 | 鞘芯型熱黏合纖維及不織布 |
| CN116695272A (zh) * | 2023-08-08 | 2023-09-05 | 江苏恒科新材料有限公司 | 一种透气阳离子易染聚酯纤维及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE592181A (enExample) * | 1955-12-22 | |||
| GB977104A (en) * | 1960-02-17 | 1964-12-02 | Hoechst Ag | Process for the manufacture of linear, aromatic fibre-forming polyesters |
| NL284670A (enExample) * | 1961-10-24 | |||
| GB1528601A (en) * | 1975-09-24 | 1978-10-18 | Ici Ltd | Preparation of linear polyesteramides |
| JPS6036565A (ja) * | 1983-08-09 | 1985-02-25 | Asahi Glass Co Ltd | 被覆用硬化性樹脂組成物 |
| JPS63203818A (ja) * | 1987-02-12 | 1988-08-23 | Nippon Ester Co Ltd | ホツトメルト型バインダ−繊維 |
| JPH055212A (ja) * | 1991-06-24 | 1993-01-14 | Toray Ind Inc | ポリエステル繊維の製法 |
| TW381104B (en) * | 1996-02-20 | 2000-02-01 | Eastman Chem Co | Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol |
| EP1015674B1 (en) * | 1997-08-28 | 2006-10-18 | Eastman Chemical Company | Improved copolymer binder fibers |
| EP1029120B1 (en) * | 1997-11-06 | 2003-08-13 | Eastman Chemical Company | Copolyester binder fibers |
-
1999
- 1999-08-06 JP JP2000567769A patent/JP2002523646A/ja active Pending
- 1999-08-06 WO PCT/US1999/017830 patent/WO2000012792A1/en not_active Ceased
- 1999-08-06 JP JP2000567770A patent/JP2002523647A/ja active Pending
- 1999-08-06 CN CN99812603A patent/CN1324415A/zh active Pending
- 1999-08-06 WO PCT/US1999/017828 patent/WO2000012791A1/en not_active Ceased
- 1999-08-06 DE DE69921487T patent/DE69921487T2/de not_active Expired - Fee Related
- 1999-08-06 DE DE69926518T patent/DE69926518T2/de not_active Expired - Fee Related
- 1999-08-06 EP EP99940922A patent/EP1115925B1/en not_active Expired - Lifetime
- 1999-08-06 BR BR9913205-2A patent/BR9913205A/pt not_active IP Right Cessation
- 1999-08-06 EP EP19990939047 patent/EP1108075B1/en not_active Expired - Lifetime
- 1999-08-06 CN CNB998126012A patent/CN1167836C/zh not_active Expired - Fee Related
- 1999-08-06 MX MXPA01001886A patent/MXPA01001886A/es unknown
- 1999-08-06 BR BR9913206-0A patent/BR9913206A/pt not_active Application Discontinuation
- 1999-08-06 MX MXPA01002107A patent/MXPA01002107A/es unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101212885B1 (ko) * | 2003-12-30 | 2012-12-14 | 킴벌리-클라크 월드와이드, 인크. | 감소된 린트 및 슬러프를 갖는 부직 웹 |
| WO2012111860A1 (ja) | 2011-02-18 | 2012-08-23 | ミドリ安全株式会社 | 自然環境条件下及びこれより厳しい自然環境条件下又はこれと同様又はこれ以上に厳しい使用条件下に安定であり、耐薬品性と耐久性に優れた透明樹脂組成物及びそれを用いる製品 |
| KR20130117852A (ko) | 2011-02-18 | 2013-10-28 | 미도리안젠 가부시키가이샤 | 자연 환경 조건 하 및 이보다 가혹한 자연 환경 조건 하 또는 이와 유사 또는 그 이상으로 가혹한 사용 조건 하에 안정되고 내약품성과 내구성이 뛰어난 투명 수지 조성물 및 이를 이용하는 제품 |
| US9550885B2 (en) | 2011-02-18 | 2017-01-24 | Midori Anzen Co., Ltd. | Transparent resin composition having good chemical resistance, durability and stability under natural environmental conditions, harsher natural environmental conditions, and similar or harsher usage conditions, and product using same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1324415A (zh) | 2001-11-28 |
| EP1108075B1 (en) | 2004-10-27 |
| CN1167836C (zh) | 2004-09-22 |
| JP2002523646A (ja) | 2002-07-30 |
| EP1115925B1 (en) | 2005-08-03 |
| BR9913206A (pt) | 2001-05-22 |
| MXPA01002107A (es) | 2002-08-20 |
| DE69921487T2 (de) | 2005-02-24 |
| EP1115925A1 (en) | 2001-07-18 |
| CN1330735A (zh) | 2002-01-09 |
| EP1108075A1 (en) | 2001-06-20 |
| BR9913205A (pt) | 2001-05-22 |
| WO2000012791A1 (en) | 2000-03-09 |
| DE69921487D1 (de) | 2004-12-02 |
| WO2000012792A1 (en) | 2000-03-09 |
| DE69926518D1 (de) | 2005-09-08 |
| MXPA01001886A (es) | 2002-04-24 |
| DE69926518T2 (de) | 2006-01-05 |
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