JP2002512283A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2002512283A5 JP2002512283A5 JP2000544721A JP2000544721A JP2002512283A5 JP 2002512283 A5 JP2002512283 A5 JP 2002512283A5 JP 2000544721 A JP2000544721 A JP 2000544721A JP 2000544721 A JP2000544721 A JP 2000544721A JP 2002512283 A5 JP2002512283 A5 JP 2002512283A5
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- long
- molecular weight
- alkoxylation
- periodic table
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007858 starting material Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 15
- 229920005862 polyol Polymers 0.000 description 15
- 239000004721 Polyphenylene oxide Substances 0.000 description 13
- 229920000570 polyether Polymers 0.000 description 13
- 150000003077 polyols Chemical class 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000000737 periodic effect Effects 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000006555 catalytic reaction Methods 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- -1 perfluoroalkyl sulfonates Chemical class 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 238000010626 work up procedure Methods 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- NRMNRSCGHRWJAK-UHFFFAOYSA-K lutetium(3+);trifluoromethanesulfonate Chemical compound [Lu+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F NRMNRSCGHRWJAK-UHFFFAOYSA-K 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19817676A DE19817676A1 (de) | 1998-04-21 | 1998-04-21 | Verfahren zur aufarbeitungsfreien Herstellung langkettiger Polyetherpolyole |
| DE19817676.7 | 1998-04-21 | ||
| PCT/EP1999/002397 WO1999054383A1 (de) | 1998-04-21 | 1999-04-08 | Verfahren zur aufarbeitungsfreien herstellung langkettiger polyetherpolyole |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002512283A JP2002512283A (ja) | 2002-04-23 |
| JP2002512283A5 true JP2002512283A5 (enExample) | 2006-06-01 |
| JP4361688B2 JP4361688B2 (ja) | 2009-11-11 |
Family
ID=7865246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000544721A Expired - Fee Related JP4361688B2 (ja) | 1998-04-21 | 1999-04-08 | 後処理しない長鎖ポリエーテルポリオールの製造方法 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6482993B1 (enExample) |
| EP (1) | EP1073689B1 (enExample) |
| JP (1) | JP4361688B2 (enExample) |
| KR (1) | KR100567719B1 (enExample) |
| CN (1) | CN1117112C (enExample) |
| AU (1) | AU3813999A (enExample) |
| BR (1) | BR9909752A (enExample) |
| CA (1) | CA2328453C (enExample) |
| DE (2) | DE19817676A1 (enExample) |
| ES (1) | ES2193702T3 (enExample) |
| HU (1) | HUP0101515A3 (enExample) |
| ID (1) | ID27091A (enExample) |
| PT (1) | PT1073689E (enExample) |
| TW (1) | TW446723B (enExample) |
| WO (1) | WO1999054383A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19928156A1 (de) | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
| AU2003288142A1 (en) * | 2002-11-22 | 2004-06-18 | Basf Aktiengesellschaft | Enzymatic synthesis of polyol acrylates |
| WO2011063156A2 (en) * | 2009-11-18 | 2011-05-26 | Nektar Therapeutics | Acid salt forms of polymer-drug conjugates and alkoxylation methods |
| CA2822005A1 (en) | 2010-12-20 | 2012-06-28 | Bayer Intellectual Property Gmbh | Method for producing polyether polyols |
| KR101404702B1 (ko) | 2011-03-08 | 2014-06-17 | 에스케이이노베이션 주식회사 | 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법 |
| EP2691440B1 (en) | 2011-03-31 | 2015-05-27 | Dow Global Technologies LLC | Method for producing short-chain polyfunctional polyether polyols utilizing superacid and double-metal cyanide catalysis |
| JP6227549B2 (ja) | 2011-12-20 | 2017-11-08 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ | ヒドロキシ−アミノポリマーおよびその製造方法 |
| WO2016064698A1 (en) | 2014-10-22 | 2016-04-28 | Dow Global Technologies Llc | Dual catalyst system for high primary hydroxyl polyols |
| CN107200837B (zh) * | 2016-03-18 | 2019-10-18 | 淮安巴德聚氨酯科技有限公司 | 一种利用dmc催化剂循环制备聚醚多元醇的方法 |
| JP7372636B2 (ja) | 2017-09-14 | 2023-11-01 | ノースウェスタン ユニバーシティ | ポリオールの製造プロセス |
| CN111094390B (zh) | 2017-09-14 | 2023-06-20 | 陶氏环球技术有限责任公司 | 制造多元醇的方法 |
| WO2019055740A1 (en) | 2017-09-14 | 2019-03-21 | Dow Global Technologies Llc | LEWIS ACID CATALYST FOR POLYMERIZATION |
| US11572440B2 (en) | 2020-02-18 | 2023-02-07 | Covestro Llc | Methods for purifying polyols containing oxyalkylene units to reduce 2-methyl-2-pentenal content |
| FR3111901B1 (fr) * | 2020-06-30 | 2023-02-17 | Arkema France | PROCÉdÉ D’ALCOXYLATION AMÉLIORÉ |
| CN113754877B (zh) * | 2021-09-10 | 2023-09-22 | 山东一诺威新材料有限公司 | 低导热系数聚醚多元醇的制备方法 |
| CN118878813B (zh) * | 2024-07-23 | 2025-04-25 | 上海优铖工逸技术有限公司 | 一种聚醚多元醇的合成方法 |
| CN119019670B (zh) * | 2024-10-30 | 2025-01-24 | 中化东大(淄博)有限公司 | 低粘度、高分子量聚醚多元醇及其制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3715402A (en) | 1969-08-08 | 1973-02-06 | Basf Wyandotte Corp | Removal of catalysts from polyols |
| US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| US4137398A (en) | 1978-06-09 | 1979-01-30 | Basf Wyandotte Corporation | Process for the removal of catalyst from polyether polyol |
| DE3229216A1 (de) | 1982-08-05 | 1984-02-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur reinigung von rohen polyether-polyolen |
| US4430490A (en) | 1982-08-10 | 1984-02-07 | Ppg Industries, Inc. | Polyether polyols and their method of preparation |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| JPH09500161A (ja) * | 1993-07-16 | 1997-01-07 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | 不均一系触媒を使用する環状エーテルの重合、及び解重合 |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| DE69528190T2 (de) * | 1994-10-28 | 2003-07-31 | Du Pont | Polymerisation von cyclischen ethern und unter anwendung der katalysatoren aus gewählten metallverbindungen |
| US5545601A (en) | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
| US5627120A (en) | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| DE19702787A1 (de) * | 1997-01-27 | 1998-07-30 | Bayer Ag | Verfahren zur Herstellung von Polyetherpolyolen |
| DE19757574A1 (de) | 1997-12-23 | 1999-06-24 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19745120A1 (de) | 1997-10-13 | 1999-04-15 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19810269A1 (de) | 1998-03-10 | 2000-05-11 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
-
1998
- 1998-04-21 DE DE19817676A patent/DE19817676A1/de not_active Withdrawn
-
1999
- 1999-04-06 TW TW088105400A patent/TW446723B/zh not_active IP Right Cessation
- 1999-04-08 EP EP99920615A patent/EP1073689B1/de not_active Expired - Lifetime
- 1999-04-08 AU AU38139/99A patent/AU3813999A/en not_active Abandoned
- 1999-04-08 CN CN99807670A patent/CN1117112C/zh not_active Expired - Lifetime
- 1999-04-08 WO PCT/EP1999/002397 patent/WO1999054383A1/de not_active Ceased
- 1999-04-08 PT PT99920615T patent/PT1073689E/pt unknown
- 1999-04-08 DE DE59904736T patent/DE59904736D1/de not_active Expired - Lifetime
- 1999-04-08 JP JP2000544721A patent/JP4361688B2/ja not_active Expired - Fee Related
- 1999-04-08 ID IDW20002156A patent/ID27091A/id unknown
- 1999-04-08 BR BR9909752-4A patent/BR9909752A/pt not_active Application Discontinuation
- 1999-04-08 ES ES99920615T patent/ES2193702T3/es not_active Expired - Lifetime
- 1999-04-08 KR KR1020007011635A patent/KR100567719B1/ko not_active Expired - Fee Related
- 1999-04-08 HU HU0101515A patent/HUP0101515A3/hu unknown
- 1999-04-08 CA CA002328453A patent/CA2328453C/en not_active Expired - Fee Related
- 1999-04-08 US US09/673,583 patent/US6482993B1/en not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2002512283A5 (enExample) | ||
| RU2002106401A (ru) | Способ получения полиэфирполиолов | |
| JP6598855B2 (ja) | 高い一級ヒドロキシルポリオールのための二重触媒系 | |
| KR101156415B1 (ko) | Ｄｍｃ-촉매화 공정에서의 출발물질 공급 스트림의산성화법 | |
| US20080167502A1 (en) | Method For Producing an Dmc Catalyst | |
| KR100610285B1 (ko) | 고함량의 1차 ｏｈ기를 갖는 장쇄 폴리에테르 폴리올 | |
| JP4361688B2 (ja) | 後処理しない長鎖ポリエーテルポリオールの製造方法 | |
| EP2837648A1 (en) | Process for preparing polyether carbonate polyols | |
| KR20140047109A (ko) | 폴리올의 연속 합성 방법 | |
| CA2443117A1 (en) | Processes for preparing ethylene oxide-capped polyols | |
| JPH10212348A (ja) | ポリエーテルポリオールの製造方法 | |
| US8119825B2 (en) | Method for the production of multimetal cyanide compounds | |
| JP2004051996A5 (enExample) | ||
| EP0638058B1 (en) | Alkoxylation process | |
| US5110991A (en) | Heterogeneous catalyst for alkoxylation of alcohols | |
| KR102241144B1 (ko) | 이중 금속 시안화물 촉매를 이용한 초분지 폴리글리시돌 제조 방법 및 이에 의해 제조된 초분지 폴리글리시돌 | |
| CN113906081A (zh) | 制备聚醚碳酸酯多元醇的方法 | |
| JPH03195728A (ja) | ポリオキシアルキレンポリオールの精製法 | |
| EP4083107B1 (en) | Method for purifying branched polyethylene glycol | |
| CN100554311C (zh) | 有机化合物的烷氧基化方法 | |
| KR102833474B1 (ko) | 폴리우레탄 경질폼용 폴리에테르 카보네이트 폴리올의 제조방법 및 이로부터 제조된 폴리에테르 카보네이트 폴리올 | |
| CN117986560A (zh) | 一种钙钛复合催化剂及其制备方法与应用 | |
| CN114144451A (zh) | 制备聚醚碳酸酯多元醇的方法 | |
| CN119119399A (zh) | 一种支化聚合型席夫碱金属化合物及其制备方法和应用 | |
| RU2002117017A (ru) | Способ получения простых полиэфиров полиолов |