ES2193702T3 - Procedimiento para la fabricacion de polioleteres de cadena larga. - Google Patents
Procedimiento para la fabricacion de polioleteres de cadena larga.Info
- Publication number
- ES2193702T3 ES2193702T3 ES99920615T ES99920615T ES2193702T3 ES 2193702 T3 ES2193702 T3 ES 2193702T3 ES 99920615 T ES99920615 T ES 99920615T ES 99920615 T ES99920615 T ES 99920615T ES 2193702 T3 ES2193702 T3 ES 2193702T3
- Authority
- ES
- Spain
- Prior art keywords
- long chain
- mol
- procedure
- manufacture
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
- B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/48—Ring-opening reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyethers (AREA)
Abstract
Procedimiento para la fabricación de polioléteres de cadena larga, caracterizado porque por medio de la catálisis con perfluoroalquilsulfonatos de los metales del grupo III A del sistema periódico de los elementos (de acuerdo con la convención de la IUPAC de 1970) y a partir de iniciadores con pesos moleculares de 18 a 400 g/mol se obtienen primero, por transformación con óxidos de alquileno a temperaturas de reacción de 80 a 200º C y concentraciones de catalizador de 5 a 200 ppm, compuestos iniciadores alcoxilados oligoméricos con pesos moleculares de 200 a 1.000 g/mol que a continuación se transforman, sin procesamiento ni separación del catalizador, por reacción con óxidos de alquileno en polioléteres de cadena larga con pesos moleculares de 1.000 a 100.000 g/mol mediante catalizadores de DMC a una concentración de catalizador de 0,1 a 30 ppm, respecto a la cantidad de polioléter que se va a fabricar.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19817676A DE19817676A1 (de) | 1998-04-21 | 1998-04-21 | Verfahren zur aufarbeitungsfreien Herstellung langkettiger Polyetherpolyole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2193702T3 true ES2193702T3 (es) | 2003-11-01 |
Family
ID=7865246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99920615T Expired - Lifetime ES2193702T3 (es) | 1998-04-21 | 1999-04-08 | Procedimiento para la fabricacion de polioleteres de cadena larga. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6482993B1 (es) |
| EP (1) | EP1073689B1 (es) |
| JP (1) | JP4361688B2 (es) |
| KR (1) | KR100567719B1 (es) |
| CN (1) | CN1117112C (es) |
| AU (1) | AU3813999A (es) |
| BR (1) | BR9909752A (es) |
| CA (1) | CA2328453C (es) |
| DE (2) | DE19817676A1 (es) |
| ES (1) | ES2193702T3 (es) |
| HK (1) | HK1039136A1 (es) |
| HU (1) | HUP0101515A3 (es) |
| ID (1) | ID27091A (es) |
| PT (1) | PT1073689E (es) |
| TW (1) | TW446723B (es) |
| WO (1) | WO1999054383A1 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19928156A1 (de) | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
| ES2393673T3 (es) * | 2002-11-22 | 2012-12-27 | Basf Se | Síntesis enzimática de acrilatos de poliol |
| EP2501413B1 (en) * | 2009-11-18 | 2019-03-27 | Nektar Therapeutics | Acid salt forms of polymer-drug conjugates |
| BR112013015393A2 (pt) | 2010-12-20 | 2016-09-20 | Bayer Ip Gmbh | método para a preparação de poliéter polióis |
| KR101404702B1 (ko) | 2011-03-08 | 2014-06-17 | 에스케이이노베이션 주식회사 | 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법 |
| ES2539235T3 (es) | 2011-03-31 | 2015-06-29 | Dow Global Technologies Llc | Método para producir polioles de poliéter polifuncionales de cadena corta usando catálisis de superácido y cianuro de metal doble |
| EP2794711B1 (de) | 2011-12-20 | 2020-06-10 | Covestro Deutschland AG | Hydroxy-aminopolymere und verfahren zu deren herstellung |
| US9896542B2 (en) | 2014-10-22 | 2018-02-20 | Dow Global Technologies Llc | Dual catalyst system for high primary hydroxyl polyols |
| CN107200837B (zh) * | 2016-03-18 | 2019-10-18 | 淮安巴德聚氨酯科技有限公司 | 一种利用dmc催化剂循环制备聚醚多元醇的方法 |
| EP3681926B1 (en) | 2017-09-14 | 2024-05-15 | Northwestern University | Process of manufacturing surfactants and lubricants |
| EP3681932B1 (en) | 2017-09-14 | 2021-06-09 | Dow Global Technologies LLC | Lewis acid polymerization catalyst |
| BR112020004749A2 (pt) | 2017-09-14 | 2020-09-15 | Dow Global Technologies Llc | processo de fabricação de polióis |
| US11572440B2 (en) | 2020-02-18 | 2023-02-07 | Covestro Llc | Methods for purifying polyols containing oxyalkylene units to reduce 2-methyl-2-pentenal content |
| CN113754877B (zh) * | 2021-09-10 | 2023-09-22 | 山东一诺威新材料有限公司 | 低导热系数聚醚多元醇的制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3715402A (en) | 1969-08-08 | 1973-02-06 | Basf Wyandotte Corp | Removal of catalysts from polyols |
| US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| US4137398A (en) | 1978-06-09 | 1979-01-30 | Basf Wyandotte Corporation | Process for the removal of catalyst from polyether polyol |
| DE3229216A1 (de) | 1982-08-05 | 1984-02-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur reinigung von rohen polyether-polyolen |
| US4430490A (en) | 1982-08-10 | 1984-02-07 | Ppg Industries, Inc. | Polyether polyols and their method of preparation |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| EP0708794B1 (en) * | 1993-07-16 | 1999-09-22 | E.I. Du Pont De Nemours And Company | Polymerization of cyclic ethers using heterogeneous catalysts |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| DE69531072T2 (de) * | 1994-10-28 | 2004-05-06 | E.I. Du Pont De Nemours And Co., Wilmington | Polymerisation von cyclischen Ethern und unter Anwendung der Katalysatoren ausgewählten Metallverbindungen |
| US5545601A (en) | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
| US5627120A (en) | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| DE19702787A1 (de) * | 1997-01-27 | 1998-07-30 | Bayer Ag | Verfahren zur Herstellung von Polyetherpolyolen |
| DE19810269A1 (de) | 1998-03-10 | 2000-05-11 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19757574A1 (de) | 1997-12-23 | 1999-06-24 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19745120A1 (de) | 1997-10-13 | 1999-04-15 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
-
1998
- 1998-04-21 DE DE19817676A patent/DE19817676A1/de not_active Withdrawn
-
1999
- 1999-04-06 TW TW088105400A patent/TW446723B/zh not_active IP Right Cessation
- 1999-04-08 ID IDW20002156A patent/ID27091A/id unknown
- 1999-04-08 CA CA002328453A patent/CA2328453C/en not_active Expired - Fee Related
- 1999-04-08 WO PCT/EP1999/002397 patent/WO1999054383A1/de active IP Right Grant
- 1999-04-08 ES ES99920615T patent/ES2193702T3/es not_active Expired - Lifetime
- 1999-04-08 JP JP2000544721A patent/JP4361688B2/ja not_active Expired - Fee Related
- 1999-04-08 HU HU0101515A patent/HUP0101515A3/hu unknown
- 1999-04-08 DE DE59904736T patent/DE59904736D1/de not_active Expired - Lifetime
- 1999-04-08 PT PT99920615T patent/PT1073689E/pt unknown
- 1999-04-08 US US09/673,583 patent/US6482993B1/en not_active Expired - Lifetime
- 1999-04-08 KR KR1020007011635A patent/KR100567719B1/ko not_active IP Right Cessation
- 1999-04-08 EP EP99920615A patent/EP1073689B1/de not_active Expired - Lifetime
- 1999-04-08 CN CN99807670A patent/CN1117112C/zh not_active Expired - Lifetime
- 1999-04-08 AU AU38139/99A patent/AU3813999A/en not_active Abandoned
- 1999-04-08 BR BR9909752-4A patent/BR9909752A/pt not_active Application Discontinuation
-
2002
- 2002-01-28 HK HK02100643A patent/HK1039136A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010042862A (ko) | 2001-05-25 |
| HK1039136A1 (en) | 2002-04-12 |
| CN1117112C (zh) | 2003-08-06 |
| HUP0101515A3 (en) | 2002-10-28 |
| CA2328453C (en) | 2008-07-15 |
| US6482993B1 (en) | 2002-11-19 |
| BR9909752A (pt) | 2000-12-19 |
| JP2002512283A (ja) | 2002-04-23 |
| EP1073689B1 (de) | 2003-03-26 |
| JP4361688B2 (ja) | 2009-11-11 |
| AU3813999A (en) | 1999-11-08 |
| EP1073689A1 (de) | 2001-02-07 |
| HUP0101515A2 (hu) | 2001-09-28 |
| CA2328453A1 (en) | 1999-10-28 |
| WO1999054383A1 (de) | 1999-10-28 |
| PT1073689E (pt) | 2003-06-30 |
| DE19817676A1 (de) | 1999-10-28 |
| KR100567719B1 (ko) | 2006-04-05 |
| DE59904736D1 (de) | 2003-04-30 |
| ID27091A (id) | 2001-03-01 |
| CN1306551A (zh) | 2001-08-01 |
| TW446723B (en) | 2001-07-21 |
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