DE602005004539D1 - Verfahren zur herstellung von reaktiven polyetherpolyolen mit ethylenoxid-endblock - Google Patents

Verfahren zur herstellung von reaktiven polyetherpolyolen mit ethylenoxid-endblock

Info

Publication number
DE602005004539D1
DE602005004539D1 DE602005004539T DE602005004539T DE602005004539D1 DE 602005004539 D1 DE602005004539 D1 DE 602005004539D1 DE 602005004539 T DE602005004539 T DE 602005004539T DE 602005004539 T DE602005004539 T DE 602005004539T DE 602005004539 D1 DE602005004539 D1 DE 602005004539D1
Authority
DE
Germany
Prior art keywords
ethylene oxide
polyether polyol
catalyst
stage
propylene oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE602005004539T
Other languages
English (en)
Other versions
DE602005004539T2 (de
Inventor
Thomas Ostrowski
Raimund Ruppel
Gerd Hoeppner
Sascha Bergmann
Koen Vandewalle
Eva Baum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of DE602005004539D1 publication Critical patent/DE602005004539D1/de
Application granted granted Critical
Publication of DE602005004539T2 publication Critical patent/DE602005004539T2/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Polyurethanes Or Polyureas (AREA)
DE602005004539T 2004-04-21 2005-04-21 Verfahren zur herstellung von reaktiven polyetherpolyolen mit ethylenoxid-endblock Active DE602005004539T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US828967 2004-04-21
US10/828,967 US7186867B2 (en) 2004-04-21 2004-04-21 Process for preparing reactive polyether polyols having an ethylene oxide end block
PCT/EP2005/004295 WO2005103116A1 (en) 2004-04-21 2005-04-21 Process for preparing reactive polyether polyols having an ethylene oxide end block

Publications (2)

Publication Number Publication Date
DE602005004539D1 true DE602005004539D1 (de) 2008-03-13
DE602005004539T2 DE602005004539T2 (de) 2008-04-30

Family

ID=34968380

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602005004539T Active DE602005004539T2 (de) 2004-04-21 2005-04-21 Verfahren zur herstellung von reaktiven polyetherpolyolen mit ethylenoxid-endblock

Country Status (11)

Country Link
US (1) US7186867B2 (de)
EP (1) EP1753802B8 (de)
JP (1) JP4664970B2 (de)
KR (1) KR101172552B1 (de)
CN (1) CN100567367C (de)
AT (1) ATE384753T1 (de)
DE (1) DE602005004539T2 (de)
ES (1) ES2297714T3 (de)
MX (1) MXPA06011930A (de)
PT (1) PT1753802E (de)
WO (1) WO2005103116A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060223979A1 (en) * 2005-04-04 2006-10-05 Thomas Ostrowski Process for preparing polyether polyols
US8692030B1 (en) * 2006-04-20 2014-04-08 Pittsburg State University Biobased-petrochemical hybrid polyols
US20080132728A1 (en) * 2006-12-01 2008-06-05 Mcdaniel Kenneth G Continuous processes for the production of alkylphenol ethoxylates
US20080132729A1 (en) * 2006-12-01 2008-06-05 Mcdaniel Kenneth G Continuous process for the production of ethoxylates
US20090057608A1 (en) * 2007-06-27 2009-03-05 Michiel Barend Eleveld Alkoxylate composition and a process for preparing the same
AR073933A1 (es) 2008-05-19 2010-12-15 Dow Global Technologies Inc Procedimiento de flujo de recirculacion continuo para la produccion de poliol de polieter
CN101407730B (zh) * 2008-11-28 2012-07-04 句容市宁武化工有限公司 一种高性能破乳剂的制备方法
DE102009031584A1 (de) † 2009-07-03 2011-01-05 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetherpolyolen mit primären Hydroxyl-Endgruppen
JP5511369B2 (ja) 2009-12-28 2014-06-04 花王株式会社 カルボン酸の製造方法
KR20130094688A (ko) * 2010-04-30 2013-08-26 아사히 가라스 가부시키가이샤 폴리옥시알킬렌폴리올, 폴리머 분산 폴리올, 및 연질 폴리우레탄폼, 그리고 이들의 제조 방법
JP5609753B2 (ja) * 2010-04-30 2014-10-22 旭硝子株式会社 ポリオキシアルキレンポリオール、ポリマー分散ポリオール、および軟質ポリウレタンフォーム、ならびにこれらの製造方法
CN101921391A (zh) * 2010-09-21 2010-12-22 山东蓝星东大化工有限责任公司 低不饱和度高分子量聚醚多元醇的合成方法
DE102011005388A1 (de) 2011-03-10 2012-09-13 Wacker Chemie Ag Verfahren zur Herstellung von Polymerisaten mittels Emulsions- oder Suspensionspolymerisation
US9562134B2 (en) * 2013-03-12 2017-02-07 Covestro Llc Catalyst for the production of polyols having lower amounts of high molecular weight tail
US9051412B2 (en) 2013-03-14 2015-06-09 Bayer Materialscience Llc Base-catalyzed, long chain, active polyethers from short chain DMC-catalyzed starters
JP6598855B2 (ja) * 2014-10-22 2019-10-30 ダウ グローバル テクノロジーズ エルエルシー 高い一級ヒドロキシルポリオールのための二重触媒系
US10723830B1 (en) * 2019-03-28 2020-07-28 Covestro Llc Product-to-product process for preparation of low viscosity polyoxyalkylene polyether polyols
CN112321815B (zh) * 2020-10-28 2022-09-16 中国石油化工股份有限公司 一种低气味高活性聚醚多元醇的制备方法
JP7563168B2 (ja) 2020-12-24 2024-10-08 Ａｇｃ株式会社 ポリエーテルポリオールの製造方法、ポリウレタンの製造方法
CN114768709B (zh) * 2022-05-05 2024-02-02 万华化学集团股份有限公司 一种使连续化聚醚生产装置实现即开即停的方法
CN115181259B (zh) * 2022-08-11 2024-04-09 万华化学集团股份有限公司 一种连续化制备聚醚的方法
CN117358162A (zh) * 2023-09-26 2024-01-09 山东滨化聚禾新材料科技有限公司 高活性低气味短周期聚醚多元醇连续化生产工艺及其装置

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3016113A1 (de) * 1980-04-25 1981-10-29 Bayer Ag, 5090 Leverkusen Verfahren zur aufarbeitung von polyetherpolyolen
CA1155871A (en) * 1980-10-16 1983-10-25 Gencorp Inc. Method for treating polypropylene ether and poly-1,2- butylene ether polyols
JPH04214722A (ja) * 1990-12-14 1992-08-05 Asahi Glass Co Ltd ポリエーテル類の製造方法
JPH04314728A (ja) * 1991-04-12 1992-11-05 Asahi Glass Co Ltd ポリエーテル類の製造方法
US5563221A (en) 1995-06-21 1996-10-08 Arco Chemical Technology, L.P. Process for making ethylene oxide-capped polyols from double metal cyanide-catalyzed polyols
US5777177A (en) 1996-02-07 1998-07-07 Arco Chemical Technology, L.P. Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter
US5689012A (en) * 1996-07-18 1997-11-18 Arco Chemical Technology, L.P. Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter
US6066683A (en) * 1998-04-03 2000-05-23 Lyondell Chemical Worldwide, Inc. Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof
DE19937114C2 (de) * 1999-08-06 2003-06-18 Bayer Ag Verfahren zur Herstellung von Polyetherpolyolen
DE10008630A1 (de) * 2000-02-24 2001-09-06 Basf Ag Verfahren zur Herstellung von Polyetherpolyolen in Gegenwart eines Multimetallcyanidkomplex-Katalysators
US20040064001A1 (en) 2002-09-30 2004-04-01 Stephan Ehlers Processes for preparing ethylene oxide-capped polyols
US7005552B2 (en) * 2003-11-03 2006-02-28 Bayer Materialscience Llc Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates

Also Published As

Publication number Publication date
JP2007533809A (ja) 2007-11-22
EP1753802B8 (de) 2008-04-02
ES2297714T3 (es) 2008-05-01
CN1946765A (zh) 2007-04-11
EP1753802A1 (de) 2007-02-21
CN100567367C (zh) 2009-12-09
WO2005103116A1 (en) 2005-11-03
JP4664970B2 (ja) 2011-04-06
ATE384753T1 (de) 2008-02-15
MXPA06011930A (es) 2007-01-26
DE602005004539T2 (de) 2008-04-30
EP1753802B1 (de) 2008-01-23
US7186867B2 (en) 2007-03-06
US20050240063A1 (en) 2005-10-27
KR101172552B1 (ko) 2012-08-08
KR20070001275A (ko) 2007-01-03
PT1753802E (pt) 2008-02-28

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Legal Events

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8327 Change in the person/name/address of the patent owner

Owner name: BASF SE, 67063 LUDWIGSHAFEN, DE

8364 No opposition during term of opposition