JP2002118066A - 半導体熱処理炉用ガス導入管 - Google Patents
半導体熱処理炉用ガス導入管Info
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Abstract
により、パーティクルをなくし、半導体ウェーハの製造
歩留を向上させ、さらに、製造が容易で、使用時の洗浄
が容易な導入管を提供する。 【解決手段】L字状の石英ガラス管6Lと、この石英ガ
ラス管6Lの一端に接合されたストレート状のCVD−
SiC管6Sとを有し、接合は、少なくともCVD−S
iC管6Sの一端部に形成されたテーパ部6Stを石英
ガラス管6Lの一端部に嵌合することにより行われる半
導体熱処理炉用ガス導入管。
Description
ス導入管に係わり、特にその一部にCVD−SiC管を
用いた半導体熱処理炉用ガス導入管に関する。
等の熱処理工程は、縦型半導体熱処理炉を用いて行われ
ている。この縦型半導体熱処理炉には、縦型に配置され
た炉芯管の処理空間に処理ガスを導入するためのガス導
入管が設けられていた。図4に示すように、従来のガス
導入管21は、純度、加工性に優れていることから石英
ガラス製の管体でほぼL字形状をなし、炉芯管内に延伸
する垂直部21vと、屈曲部21cと、炉芯管の底部近
傍に配置される水平部21hを有している。
縦型ボートの縦方向に配列された半導体ウェーハへの堆
積膜の均一性を高めるために、導入管21を長くして、
開口部を高い位置に設けた導入管21を、従来の高さを
有する他の導入管と共に、配置するようになっている。
ポリシリコンの堆積膜に用いるのみならず、より厳密な
均一性を要求されるボロンやリンなどのドープドポリシ
リコン膜を半導体ウェーハ上に形成するのにも用いられ
る。
程、この導入管自身の外壁にも、堆積膜が多く堆積され
る。すると、従来の石英ガラス管であると、この石英ガ
ラス管と堆積膜を形成する材料の熱膨張係数の違いか
ら、外壁および内壁に堆積した堆積膜が部分的に剥がれ
るなどして、パーティクルの要因となり、半導体ウェー
ハの製造歩留を低下させていた。また、導入管21の使
用後にHFなどを用いて洗浄して繰返し使用するが、洗
浄時、石英ガラスが溶出し、その使用寿命を短縮する問
題もある。
て、特許第2990670号に記載されるように、CV
D−SiC膜のみからなるL字状の導入管を検討した。
この導入管の製造方法は、例えば、図5に示すように、
炭素基材をL字状の円柱体22に加工した後に、3点支
持して、CVD炉内に配置し、この外表面にCVD−S
iCコートし、炉外で、炭素基材を焼き抜く方法で行わ
れるが、このような方法によると、炭素円柱体22が撓
むことで、ストレートな導入管を得にくいという問題が
ある。また、上記焼き抜きの前には、導入管の寸法を精
度良くするために端部を加工する必要があるが、複雑形
状であるため、高精度の加工が困難であるなどの問題が
ある。
入管において、炉芯管を貫通するチューブアダプタと当
接する部分のシール性を高めるために、導入管の当該当
接部を高精度に平坦化加工する必要があるが、この加工
に多くの労力を要する。また、この導入管において、上
述のように堆積膜が外壁および内壁にも堆積し、付着す
るために、これを酸洗浄によって、除去することで、繰
返し使用されるが、L字状であるため、特に、角部内部
の洗浄が容易でなく、堆積膜が完全に除去できず、パー
ティクルが発生する危険があった。
の部分的剥離を防止することにより、パーティクルをな
くし、半導体ウェーハの製造歩留を向上させ、さらに、
製造が容易であり、使用時の洗浄が容易な導入管が要望
されていた。
もので、特に、堆積した堆積膜の部分的剥離を防止する
ことにより、パーティクルをなくし、半導体ウェーハの
製造歩留を向上させ、さらに、製造が容易であり、使用
時の洗浄が容易な導入管を提供することを目的とする。
になされた本願請求項1の発明は、L字状の石英ガラス
管と、この石英ガラス管の一端に接合されたストレート
状のCVD−SiC管とを有し、前記接合は、少なくと
もCVD−SiC管の一端部に形成されたテーパ部を石
英ガラス管の一端部に嵌合することにより行われること
を特徴とする半導体熱処理炉用ガス導入管であることを
要旨としている。
管の一端部に外周先細のテーパ部が形成され、このテー
パ部および上記CVD−SiC管の一端部の内周先太の
テーパ部は、共に1/5〜1/15のテーパを有するこ
とを特徴とする請求項1に記載の半導体熱処理炉用ガス
導入管であることを要旨としている。
管に形成された屈曲部の管壁の肉厚は全周に亘り等し
く、かつ、水平部の管壁の肉厚の1.2〜4.5倍であ
ることを特徴とする請求項1または2に記載の半導体熱
処理炉用ガス導入管であることを要旨としている。
iC管の内表面粗さがRa≦5μmであることを特徴と
する請求項1ないし3のいずれか1項に記載の半導体熱
処理炉用ガス導入管であることを要旨としている。
ガス導入管の実施形態について図面を参照して説明す
る。
り、この縦型半導体熱処理炉1は、全体的に円筒形状の
炉芯管2を有している。この炉芯管2は下方に開口3を
有し、この開口3からウェーハボート4に搭載された多
数の半導体ウェーハWが出し入れされる構成になってい
る。炉芯管2は石英ガラスで構成されており、その内部
に処理空間5が形成されている。
導入短管7が設けられており、所定の処理用ガスを処理
空間5内に導入できるようになっている。
状の石英ガラス管6Lと、図3に示すようなストレート
状のCVD−SiC管6Sとで構成されている。
置される水平部6Lhと、90°の屈曲する屈曲部6L
cと、炉芯管2に垂直に配置される垂直部6Lvとで形
成されている。石英ガラス管の一端部、すなわち、垂直
部6Lvには外周先細のテーパ部6Ltが形成され、こ
のテーパ部6Ltは1/5〜1/15のテーパを有して
いる。また、屈曲部6Lcの管壁は、各垂直断面におい
て肉厚が等しく、かつ、水平部6Lhの管壁の肉厚の
1.2〜1.4倍である。
ス管6Lとすることによって、ガス導入管をテーパ部に
嵌合した場合にも、十分耐え得る強度が得られる。水平
部6Lhの管壁の肉厚の1.4倍を超えると、かえって
重量増加を招き好ましくない。
造される。例えば、ストレートな円柱形状の炭素基材を
用意し、一端部にが外周先太のテーパ部が形成されるよ
うに外周加工し、しかる後、、通常のCVD(Chem
ical vapor deposition)によ
り、炭素基材上にSiCを0.7〜2.0mm堆積させ
る。さらに、長さ寸法合わせの加工を行なった後、酸化
性雰囲気900℃で炭素基材の焼き抜きを行い、さら
に、テーパ部内周面の研磨加工を行った後、洗浄を行う
ことにより製造される。このようにして製造されたCV
D−SiC管6SはCVD−SiC膜のみで形成され
る。なお、基材としては、モリブデン、タングステン製
のものを用いることもできる。
粗さがRa≦5μmに制御される。このように内表面粗
さがRa≦5μmにすることにより、CVD−SiC管
6Sと石英ガラス管6Lの嵌合部でのがたつきがなく、
嵌合部の熱伝達も良くなり、SiCの高熱伝導性の特性
を活かし、局部熱応力を緩和することができる。また、
外表面粗さをRa≧2μmに制御するのが好ましい。こ
れにより、CVD−SiC管6Sの外表面から例えばド
ープドポリシリコン膜が剥離し難くなり発生するダスト
を削減することができる。
は内周先太のテーパ部6Stが形成され、このテーパ部
6Stも、上記垂直部6Lvのテーパ部6Ltと同様に
1/5〜1/15のテーパを有しており、また、他端に
は処理ガス噴出口6Spが形成されている。
導入長管6の石英ガラス管6Lと同様の石英ガラス管7
Lと、この石英ガラス管7Lの一端部に嵌合し、図3に
示すようなガス導入長管6のCVD−SiC管6Sと同
様のCVD−SiC管7Sとで構成され、他端には処理
ガス噴出口7Spが設けられている。ただし、CVD−
SiC管7Sの長さは、CVD−SiC管6Sの長さが
約700〜1000mmであるのに対して、約100m
mである。
された外周先細のテーパ部に一端部が内周先太のテーパ
部を有するCVD−SiC管を上方より被せる(嵌合す
る)構造であるために、管内部にガス滞留が生じること
もなく、内表面でのポリシリコン膜の付着がほとんど生
じることがない。
各々炉芯管2を貫通するSUS製チューブアダプタ(水
冷ジャケット)8、9に石英ガラス管6L、7Lを介し
て取り付けられ、さらに、チューブアダプタ8、9を介
して、外部の処理ガス供給源(図示せず)に接続されて
いる。このガス導入長管6およびガス導入短管7をチュ
ーブアダプタ8、9に取り付ける際、石英ガラス管6
L、7Lを介して行うので、CVD−SiCに比べては
るかに加工し易い石英ガラスを加工すれば良く、その取
り付け作業も容易になる。
置であり、11は昇降装置10に載置されたボートテー
ブルであり、このボートテーブル11には上記ウェーハ
ボート4が載置される。また、12は炉芯管2を加熱す
るヒータ、13は処理ガスの排気口である。
芯管を貫通するチューブアダプタと当接する部分が、表
面が滑らかな通常の石英ガラスであるため、特別な外周
面加工を行うこともなくシール性を高めることができ
る。
導入管が設けられた縦型半導体熱処理炉を用いた半導体
ウェーハの熱処理について説明する。
ート4を、昇降装置10に載置されたボートテーブル1
1に乗せて、ヒータ12により加熱された炉芯管2に収
納する。しかる後、さらに炉芯管2内の温度を上げ、加
熱されたボロンがドープされた処理ガスをガス導入長管
6およびガス導入短管7から処理ガス噴出口6Sp、7
Spを介して炉芯管2内に導入する。導入された処理ガ
スにより、シリコン膜を半導体ウェーハW上に堆積さ
せ、その後、処理ガスを排気口13から排気する。
6S、7Sの外壁および内壁に処理ガスから生じるシリ
コン膜が堆積するが、CVD−SiC管6S、7S自身
がCVD法により形成されたSiC(膜)材料(CVD
−SiC)のみで形成されており、SiCの熱膨張係数
と堆積したシリコン膜の熱膨張係数の差が大きくないの
で、ヒートサイクルにより、熱膨張係数の差から付着し
たシリコン膜の破断、部分的剥離を防止することによ
り、炉芯管2内のパーティクルを70%減じることがで
き、半導体ウェーハの製造歩留を向上させることができ
る。また、導入管6、7の使用後にHFなどを用いて洗
浄して繰返し使用するが、洗浄時SiCは溶出せず、従
来の石英ガラス製ガス導入管に比べ約20倍の長寿命化
が図れる。
SiC管6S、7Sの接合は1/5〜1/15のテーパ
を有するテーパ部6Lt、6Stを用いた嵌合により行
われる場合、CVD−SiC管6S、7Sの重力により
気密かつ確実に接合され、さらに、取り外し時にも抜け
が良く、分解時の破損事故なども防止できる。また、接
合は熱膨張係数の差を有する石英ガラスとCVD−Si
Cの嵌合により行われるので、同一温度での熱膨張差に
より密着性が向上する。
扱い時に石英ガラス管6L、7Lが破損しても、石英ガ
ラス管6L、7LまたはCVD−SiC管6S、7Sの
破損側のみを交換すればよいので、経済的である。
熱処理炉用ガス導入管について説明したが、本発明に係
わる半導体熱処理炉用ガス導入管は、横型半導体熱処理
炉用ガス導入管としても用いることができ、この場合に
は、CVD−SiC管の処理ガス噴出口近傍を支持する
支持部材を別途設け、CVD−SiC管を安定化させる
のが好ましい。
インジェクションと、テーパまたはテーパ部内表面の表
面粗さを変化させた長さ935mmのCVD−SiCイ
ンジェクションとをテーパ嵌合して950mmの高さの
L字インジェクションを作製した。これらL字インジェ
クションのテーパ嵌合の着脱時の作業性 嵌合個所
の気密性について調べた。
際、SiCインジェクタの鉛直方向(縦型炉の場合)を
向かず、炉芯管やボートにインジェクタ先端が接触して
しまう可能性があり、また、鉛直方向から反れた場合、
テーパ嵌合部からリークの可能性があることが確認され
た。
は、嵌合した950mmインジェクタの先端が鉛直方向
から反れる幅は、最大で1mmであった。また、350
℃減圧下の使用においても、リークは検出されなかっ
た。
では、嵌合した950mmインジェクタの先端が鉛直方
向から反れる幅は、最大で0.4mmであった。また、
350℃減圧下の使用においても、リークは検出されな
かった。
では、嵌合した950mmインジェクタの先端が鉛直方
向から反れる幅は、最大で0.05mmであった。ま
た、350℃減圧下の使用においても、リークは検出さ
れなかった。しかし、冷却後の分解時に、力を加えない
と外れない状態になる場合もあったが、割れは見られな
かった。
では、容易に鉛直方向が出せるが、熱が加わったとき、
熱膨張差による焼嵌(CTE外周材料>CTE内周材料
の場合、加熱時に拡張した状態となったまま、これが冷
却されると、外周材料が内周材料を圧縮すること)が発
生し、強度の小さい石英インジェクタが抜けなくなった
り、割れたりする可能性が高いことが確認された。
パ部内表面の表面粗さをRa=10mmとした実施例6
では、350℃減圧下でインジェクタ内を通るガスのリ
ークは検出されなかった。しかし、使用後の取り外し時
にテーパ部にポリシリコンが付着する可能性が高いこと
が確認された。
実施例4を用い、そのテーパ部内表面の表面粗さをRa
=5mmとした実施例7では、いずれのインジェクタ
共、常温でも、350℃減圧下でもガスリークは検出さ
れなかった。また、プロセスガスのテーパ部への回り込
みも検出されなかった。
入管によれば、堆積した堆積膜の部分的剥離を防止する
ことにより、パーティクルをなくし、ウェーハの製造歩
留を向上させ、さらに、製造が容易で、使用時の洗浄が
容易な導入管を提供することができる。
石英ガラス管の一端に接合されたストレート状のCVD
−SiC管とを有し、接合は、少なくともCVD−Si
C管の一端部に形成されたテーパ部を石英ガラス管の一
端部に嵌合することにより行われるので、ヒートサイク
ルにより、熱膨張係数の差から付着したシリコン膜が破
断、剥離を減少させることができて、炉芯管内のパーテ
ィクルを減じることができ、半導体ウェーハの製造歩留
を向上させることができる。また、導入管の使用後にH
Fなどを用いて洗浄して繰返し使用するが、洗浄時Si
Cは溶出せず、従来に比べ長寿命化が図れる。
テーパ部が形成され、このテーパ部およびCVD−Si
C管の内周先太の一端部のテーパ部は、共に1/5〜1
/15のテーパを有するので、CVD−SiC管の重力
により気密かつ確実に接合され、さらに、取り外し時に
も抜けが良く、分解時の破損事故なども防止できる。ま
た、接合は熱膨張係数の差を有する石英ガラスとCVD
−SiCの嵌合により行われるので、熱膨張差や膜の回
り込みにより密着性が向上する。
管壁の肉厚は、全周に亘り等しく、かつ、水平部の管壁
の肉厚の1.2〜4.5倍であるので、処理ガスに対す
る流通抵抗を小さくすることができ、さらに、CVD−
SiC管の重力を十分に支えることができる。
a≦5μmであるので、CVD−SiC管と石英ガラス
管の嵌合部でのがたつきがなく、嵌合部の熱伝達も良く
なり、SiCの高熱伝導性の特性を活かし、局部熱応力
を緩和することができる。
用いた縦型半導体熱処理炉の概念図。
石英ガラス管の断面図。
CVD−SiC管の断面図。
管の断面図。
図。
Claims (4)
- 【請求項1】 L字状の石英ガラス管と、この石英ガラ
ス管の一端に接合されたストレート状のCVD−SiC
管とを有し、前記接合は、少なくともCVD−SiC管
の一端部に形成されたテーパ部を石英ガラス管の一端部
に嵌合することにより行われることを特徴とする半導体
熱処理炉用ガス導入管。 - 【請求項2】 上記石英ガラス管の一端部に外周先細の
テーパ部が形成され、このテーパ部および上記CVD−
SiC管の一端部の内周先太のテーパ部は、共に1/5
〜1/15のテーパを有することを特徴とする請求項1
に記載の半導体熱処理炉用ガス導入管。 - 【請求項3】 上記石英ガラス管に形成された屈曲部の
管壁の肉厚は、全周に亘り等しく、かつ、水平部の管壁
の肉厚の1.2〜4.5倍であることを特徴とする請求
項1または2に記載の半導体熱処理炉用ガス導入管。 - 【請求項4】 上記CVD−SiC管の内表面粗さがR
a≦5μmであることを特徴とする請求項1ないし3の
いずれか1項に記載の半導体熱処理炉用ガス導入管。
Priority Applications (1)
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