JP2000507932A - 反応性液晶化合物 - Google Patents
反応性液晶化合物Info
- Publication number
- JP2000507932A JP2000507932A JP9533070A JP53307097A JP2000507932A JP 2000507932 A JP2000507932 A JP 2000507932A JP 9533070 A JP9533070 A JP 9533070A JP 53307097 A JP53307097 A JP 53307097A JP 2000507932 A JP2000507932 A JP 2000507932A
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- Japan
- Prior art keywords
- reactive liquid
- compound
- group
- liquid crystal
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/84—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
- C07C69/92—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring with etherified hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F20/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
- C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
- C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/38—Polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
- C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K2019/3095—Cyclohexane rings in which the end group is the monoterpene menthyl
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Liquid Crystal Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.式I; (式中 CH2=CH−フェニル−(O)n−であり、そしてWはH、CH3又はCl、nは0又は1で あり、 Spは、炭素原子1個から20個を有するスペーサー基であり、 Xは、−O−、−S−、−CO−、−-COO−、−OCO−、−O−COO−、−S−CO−、− CO−S−、又は単結合であり、 nは、0又は1であり、 A1及びA2は、それぞれ独立して、1,4−フェニレン(ここでさらに1又は2以上の CH基がNに置換されていてもよい)、あるいは1,4−シクロヘキセニレン又は1,4 −シクロヘキシレン(ここでさらに1又は2の隣接しないCH2をO及び/又はSで 置換されていてもよい)、あるいはナフタレン−2,6−ジイルであって、これらの 環はハロゲン、シアノ又はニトロ基あるいは炭素原子1個から7個を有するアル キル、アルコキシ又はアシル基で1又は2以上置換されていてもよく(これらの 基は1又は2以上のH原子がF又はClで置換されていてもよい)、 Zは、−OCO−、−COO−、−CH2CH2−、−CH=CH−、−C≡C−、−CH2O−、− OCH2-、又は単結合であり、 mは、0又は1、及び Rは、未置換、ハロゲン又はCNにより単置換又は多置換されてもよい炭素原子20 個までを有するアルキル基であって、1又は2以上のCH2基は、酸素原子が互い に直接結合しないように、−O−、−S−、−NH−、N(CH3)−、−CO−、−OCO −、−COO−、−S−CO−、−CO−S−、−O−COO−で置換されることができ、あ るいはRはハロゲン、シアノであるか又は独立にP−(Sp−X)n−で表される意味 の1つを有する) の反応性液晶化合物。 2.nが1、mが0及びA1が1,4−フェニレンである、請求項1に記載の反応性液晶 性化合物。 3.nが1及びSpが炭素原子1個から15個を有するアルキレンである、請求項1又 は2に記載の反応性液晶化合物。 4.Rがハロゲン、シアノ又は炭素原子1個から15個を有する任意にフッ素化され た非カイラル又はカイラルアルキル又はアルコキシ基である、請求項1、2又は3 に記載の反応性液晶性化合物。 5.RがP−(Sp−X)n−で表される意味の1つを有する、請求項1、2又は3に記載 の反応性液晶性化合物。 6.請求項1〜5に記載の化合物を少なくとも1つ含有することを特徴とする、少な くとも2つの反応性液晶性化合物を含有する組成物。 7.2つの重合性末端基を有する化合物を少なくとも1つ含有することを特徴とす る、請求項6に記載の組成物。 8.重合性末端基及びカイラル末端基を有する化合物を少なくとも1つ含有するこ とを特徴とする、請求項6又は7に記載の組成物。 9.請求項1〜8のいずれかに記載の少なくとも1つのモノマー又は組成物を(共)重 合することにより得られる、直鎖状又は網状(コ)ポリマー。 10.修飾性顔料類、化粧品類又は保護製品類、アクティブ及びパッシブ光学素子 類、例えば光学偏向子又は補償膜類、カラーフィルター類、散乱ディスプレイ類 、異方性の機械的物性を有する接着剤類又は合成樹脂類などのポリマー又はポリ マー膜の調製のための、請求項1〜8に記載の反応性液晶化合物又は組成物の使用 。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96104330.4 | 1996-03-19 | ||
EP96104330 | 1996-03-19 | ||
PCT/EP1997/000843 WO1997034862A1 (en) | 1996-03-19 | 1997-02-21 | Reactive liquid crystal compounds |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2000507932A true JP2000507932A (ja) | 2000-06-27 |
JP4496439B2 JP4496439B2 (ja) | 2010-07-07 |
Family
ID=8222575
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53307097A Expired - Lifetime JP4496439B2 (ja) | 1996-03-19 | 1997-02-21 | 反応性液晶化合物 |
Country Status (5)
Country | Link |
---|---|
US (1) | US6344154B1 (ja) |
EP (1) | EP0888281B1 (ja) |
JP (1) | JP4496439B2 (ja) |
DE (1) | DE69704704T2 (ja) |
WO (1) | WO1997034862A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005532439A (ja) * | 2002-07-06 | 2005-10-27 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 非キラル液晶材料を含むフレーク |
JP2008517077A (ja) * | 2004-10-14 | 2008-05-22 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 重合性液晶混合物 |
JP2011526296A (ja) * | 2008-06-27 | 2011-10-06 | トランジションズ オプティカル, インコーポレイテッド | メソゲン含有化合物 |
WO2013180196A1 (ja) * | 2012-05-31 | 2013-12-05 | 日立オムロンターミナルソリューションズ株式会社 | 易剥離性粘着剤およびそれを用いた粘着材料ならびに処理装置 |
WO2018003498A1 (ja) * | 2016-06-28 | 2018-01-04 | 大日本印刷株式会社 | 側鎖型液晶ポリマー、液晶組成物、位相差フィルム、位相差フィルムの製造方法、転写用積層体、光学部材、光学部材の製造方法、及び表示装置 |
US11390810B2 (en) | 2017-09-27 | 2022-07-19 | Dai Nippon Printing Co., Ltd. | Liquid crystal composition, retardation film, method for producing retardation film, transfer laminate, optical member, method for producing optical member, and display device |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69915454T2 (de) * | 1998-01-27 | 2005-03-03 | Rolic Ag | Flüssigkristalline, photovernetzbare mischung |
EP0972818B1 (en) * | 1998-07-15 | 2003-05-07 | MERCK PATENT GmbH | Polymerizable mesogenic fluorophenylenes |
DE19905394A1 (de) * | 1999-02-10 | 2000-08-17 | Basf Ag | Flüssigkristalline Stoffgemenge |
KR100955968B1 (ko) * | 1999-07-02 | 2010-05-13 | 메르크 파텐트 게엠베하 | 모노반응성 메소제닉 화합물 |
JP2001055573A (ja) * | 1999-08-17 | 2001-02-27 | Nippon Mitsubishi Oil Corp | 液晶フィルム |
DE10013507A1 (de) | 2000-03-20 | 2001-09-27 | Basf Ag | Chirale 1,3-Dioxanverbindungen |
DE10061625A1 (de) | 2000-12-11 | 2002-06-13 | Basf Ag | Verwendung von chiralen, ungeladenen Metallverbindungen als Dotierstoffe für flüssigkristalline Materialien |
DE10219202A1 (de) | 2002-04-29 | 2003-11-06 | Basf Ag | Alkinverbindungen |
DE10229530A1 (de) | 2002-07-01 | 2004-01-15 | Basf Ag | Chirale 3,4-Dihydro-2H-pyranverbindungen |
JP4637839B2 (ja) | 2003-08-08 | 2011-02-23 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 反応性メソゲンを有する、液晶分子を配向させるための配向層 |
JP4617838B2 (ja) * | 2003-12-25 | 2011-01-26 | チッソ株式会社 | 液晶性(メタ)アクリレート誘導体およびそれらを含む組成物 |
JP2005215631A (ja) * | 2004-02-02 | 2005-08-11 | Dainippon Printing Co Ltd | 光学素子及びその製造方法、並びに液晶配向用基板及び液晶表示装置 |
US7527746B2 (en) | 2005-01-28 | 2009-05-05 | Chisso Corporation | Liquid crystal polyfunctional acrylate derivative and polymer thereof |
CN102066382A (zh) | 2008-06-17 | 2011-05-18 | 巴斯夫欧洲公司 | 含有2,6-萘基及异甘露糖醇单元的可聚合手性化合物及其作为手性掺杂剂的用途 |
EP2218764B1 (en) | 2009-02-13 | 2012-01-18 | Merck Patent GmbH | Chiral reactive mesogen mixture |
US8822628B2 (en) | 2012-09-24 | 2014-09-02 | Ticona Llc | Crosslinkable liquid crystalline polymer |
US8853342B2 (en) | 2012-09-24 | 2014-10-07 | Ticona Llc | Crosslinkable liquid crystalline polymer |
US9145519B2 (en) | 2012-09-24 | 2015-09-29 | Ticona Llc | Crosslinkable aromatic polyester |
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-
1997
- 1997-02-21 JP JP53307097A patent/JP4496439B2/ja not_active Expired - Lifetime
- 1997-02-21 DE DE69704704T patent/DE69704704T2/de not_active Expired - Lifetime
- 1997-02-21 WO PCT/EP1997/000843 patent/WO1997034862A1/en active IP Right Grant
- 1997-02-21 EP EP97906107A patent/EP0888281B1/en not_active Expired - Lifetime
-
2000
- 2000-05-04 US US09/563,903 patent/US6344154B1/en not_active Expired - Lifetime
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005532439A (ja) * | 2002-07-06 | 2005-10-27 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 非キラル液晶材料を含むフレーク |
JP2008517077A (ja) * | 2004-10-14 | 2008-05-22 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 重合性液晶混合物 |
JP2011526296A (ja) * | 2008-06-27 | 2011-10-06 | トランジションズ オプティカル, インコーポレイテッド | メソゲン含有化合物 |
WO2013180196A1 (ja) * | 2012-05-31 | 2013-12-05 | 日立オムロンターミナルソリューションズ株式会社 | 易剥離性粘着剤およびそれを用いた粘着材料ならびに処理装置 |
WO2018003498A1 (ja) * | 2016-06-28 | 2018-01-04 | 大日本印刷株式会社 | 側鎖型液晶ポリマー、液晶組成物、位相差フィルム、位相差フィルムの製造方法、転写用積層体、光学部材、光学部材の製造方法、及び表示装置 |
JP2018009150A (ja) * | 2016-06-28 | 2018-01-18 | 大日本印刷株式会社 | 側鎖型液晶ポリマー、液晶組成物、位相差フィルム、位相差フィルムの製造方法、転写用積層体、光学部材、光学部材の製造方法、及び表示装置 |
US11332670B2 (en) | 2016-06-28 | 2022-05-17 | Dai Nippon Printing Co., Ltd. | Side-chain liquid crystal polymer, liquid crystal composition, retardation film, method for producing retardation film, transfer laminate, optical member, method for producing optical member, and display device |
TWI791443B (zh) * | 2016-06-28 | 2023-02-11 | 日商大日本印刷股份有限公司 | 側鏈型液晶聚合物、液晶組成物、相位差膜、相位差膜之製造方法、轉印用積層體、光學構件、光學構件之製造方法及顯示裝置 |
US11390810B2 (en) | 2017-09-27 | 2022-07-19 | Dai Nippon Printing Co., Ltd. | Liquid crystal composition, retardation film, method for producing retardation film, transfer laminate, optical member, method for producing optical member, and display device |
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DE69704704D1 (de) | 2001-06-07 |
JP4496439B2 (ja) | 2010-07-07 |
EP0888281B1 (en) | 2001-05-02 |
US6344154B1 (en) | 2002-02-05 |
EP0888281A1 (en) | 1999-01-07 |
WO1997034862A1 (en) | 1997-09-25 |
DE69704704T2 (de) | 2001-11-29 |
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