JP2000500522A - 粉末化可能な反応性樹脂組成物 - Google Patents
粉末化可能な反応性樹脂組成物Info
- Publication number
- JP2000500522A JP2000500522A JP9519482A JP51948297A JP2000500522A JP 2000500522 A JP2000500522 A JP 2000500522A JP 9519482 A JP9519482 A JP 9519482A JP 51948297 A JP51948297 A JP 51948297A JP 2000500522 A JP2000500522 A JP 2000500522A
- Authority
- JP
- Japan
- Prior art keywords
- epoxy
- reaction
- composition according
- composition
- melting point
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 次の成分 (A)エポキシ樹脂またはエポキシ基含有化合物、 (B)すべてのアミノ水素原子がエポキシ基によって消費された後に、(A)と (B)のために選択された反応条件下でゲル化を生起させるのには不十分な量で 存在し、55℃より高く120℃より低いコフラーヒートバンク融点を有しそし て通常の作業場温度において少なくとも6カ月の融点安定性を有する生成物を与 えるアミン凝固系、 (C)(B)とは相違し、そして(A)と(B)のために選択された反応条件下 では(A)および(B)とは実質的に未反応のままにとどまりそして通常の作業 場温度においては最終の固体エポキシ組成物内での反応性が低い、(A)のため の、および(A)と(B)の反応生成物のための硬化剤系、および任意に、 (D)(A)と(B)のために選択された反応条件下では反応性が低く、かつ通 常の作業場温度においては最終の固体エポキシ組成物内での反応性が低い膨張剤 ,および任意に、 (E)硬化した、または未硬化の組成物の物性を変性するために必要とされうる その他の添加剤、 を混合して生成した、55℃より低くないコフラーヒートバンク融点を有する、 溶融可能な固体の、場合によっては発泡可能な熱硬化性エポキシ官能性反応生成 物である反応性樹脂組成物。 2. 硬化剤(C)または膨張剤(D)を有意的に活性化することなく(A)と (B)との間の凝固反応を速めるため該混合物を加熱する請求項1記載の組成物 。 3. 凝固反応の完遂によって到達される温度が硬化剤(C)または膨張剤(D )を有意的に活性化しないとの条件で、不完全に凝固した組成物を凝固完了を速 めるため加熱しうる請求項1または2記載の組成物。 4. 摩砕したとき、通常の作業場温度において自由流動性の粉末である請求項 1乃至3のいずれかに記載の組成物。 5. 80℃乃至260℃の範囲で硬化する前記請求項のいずれかに記載の組成 物。 6. エポキシ基の大部分がグリシジルエーテル、グリシジルアミン、グリシジ ルエステル、脂環式および他のエポキシ樹脂として存在する前記請求項のいずれ かに記載の組成物。 7. エポキシ基含有化合物(A)が120℃またはそれ以下の温度で自由流動 性の液体である前記請求項のいずれかに記載の組成物。 8. 凝固剤が、主として、芳香族脂環式または脂環式第一アミン、第二アミン またはこれら2つと任意の酸促進剤との混合物である前記請求項のいずれかに記 載の組成物。 9. 凝固性アミン基の大部分がエポキシ基に関して二官能性または二官能性と 多官能性である前記請求項のいずれかに記載の組成物。 10. 適当な硬化剤系が、44’ジアミノジフェニルスルホン、三フッ化ホウ 素アミン錯塩、潜在イミダゾール、カルボン酸、ビグアニド、ヒドラジド、ジシ アンジアミド、潜在エポキシアミン付加物および置換尿素のような芳香族アミン を包含する前記請求項のいずれかに記載の組成物。 11. 膨張剤が存在し、そしてそれが化学分解または液体の沸騰または膨張可 能なシェル内部に含有されたガスの膨張によってガス を発生させるものを包含する前記請求項のいずれかに記載の組成物。 12. 硬化した、または未硬化の組成物の物性を変性するためのさらなる物質 を含有する前記請求項のいずれかに記載の組成物。 13. ホットメルト技術によってさらに加工するための前記請求項のいずれか に記載の組成物の使用。 14. ペレット、タブレット、ロッド、スティック、粉末を含む、ホットメル ト技術によってさらに加工するための請求項13に記載の使用。 15. 溶融した状態での請求項1乃至12のいずれかに記載の組成物の使用。 16. 前記請求項のいずれかに記載の組成物を加熱することによって得られる 硬化した製品。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9523650.1 | 1995-11-18 | ||
GBGB9523648.5A GB9523648D0 (en) | 1995-11-18 | 1995-11-18 | Foaming reactive resin compositions |
GB9523648.5 | 1995-11-18 | ||
GBGB9523650.1A GB9523650D0 (en) | 1995-11-18 | 1995-11-18 | Reactive resin compositions |
PCT/GB1996/002821 WO1997019124A1 (en) | 1995-11-18 | 1996-11-18 | Powderable reactive resin compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2000500522A true JP2000500522A (ja) | 2000-01-18 |
JP3881381B2 JP3881381B2 (ja) | 2007-02-14 |
Family
ID=26308139
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51948297A Expired - Fee Related JP3881381B2 (ja) | 1995-11-18 | 1996-11-18 | 粉末化可能な反応性樹脂組成物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6121348A (ja) |
EP (1) | EP0861277B1 (ja) |
JP (1) | JP3881381B2 (ja) |
KR (1) | KR100504652B1 (ja) |
AT (1) | ATE238369T1 (ja) |
AU (1) | AU7582496A (ja) |
BR (1) | BR9611485A (ja) |
CA (1) | CA2236806C (ja) |
DE (1) | DE69627692T2 (ja) |
ES (1) | ES2198503T3 (ja) |
PT (1) | PT861277E (ja) |
WO (1) | WO1997019124A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003531264A (ja) * | 2000-04-20 | 2003-10-21 | バンティコ アクチエンゲゼルシャフト | 凝集性インサート |
WO2011102288A1 (ja) * | 2010-02-16 | 2011-08-25 | ダイセル化学工業株式会社 | 硬化性組成物及び硬化物 |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6376564B1 (en) * | 1998-08-27 | 2002-04-23 | Henkel Corporation | Storage-stable compositions useful for the production of structural foams |
DE19909270A1 (de) | 1999-03-03 | 2000-09-07 | Henkel Teroson Gmbh | Hitzehärtbarer, thermisch expandierbarer Formkörper |
NL1013179C2 (nl) * | 1999-09-30 | 2001-04-02 | Stahl Int Bv | Werkwijze voor de bereiding van een coating, een gecoat substraat, plakmiddel, film of vel, een aldus verkregen product en bekledingsmengsel ten gebruike bij de werkwijze. |
TWI279408B (en) | 2000-01-31 | 2007-04-21 | Vantico Ag | Epoxy resin composition |
US6620501B1 (en) | 2000-08-07 | 2003-09-16 | L&L Products, Inc. | Paintable seal system |
US6787579B2 (en) | 2001-05-02 | 2004-09-07 | L&L Products, Inc. | Two-component (epoxy/amine) structural foam-in-place material |
US6682818B2 (en) | 2001-08-24 | 2004-01-27 | L&L Products, Inc. | Paintable material |
US6887914B2 (en) * | 2001-09-07 | 2005-05-03 | L&L Products, Inc. | Structural hot melt material and methods |
US6890964B2 (en) * | 2001-09-24 | 2005-05-10 | L&L Products, Inc. | Homopolymerized epoxy-based form-in-place material |
GB2383009A (en) * | 2001-12-14 | 2003-06-18 | Vantico Ag | Method of making models |
US6774171B2 (en) | 2002-01-25 | 2004-08-10 | L&L Products, Inc. | Magnetic composition |
US6811864B2 (en) | 2002-08-13 | 2004-11-02 | L&L Products, Inc. | Tacky base material with powder thereon |
IE20030601A1 (en) * | 2003-08-14 | 2005-02-23 | Loctite R & D Ltd | Curable compositions having a reduced enthalpy output |
US7768405B2 (en) * | 2003-12-12 | 2010-08-03 | Semiconductor Energy Laboratory Co., Ltd | Semiconductor device and manufacturing method thereof |
US8070994B2 (en) | 2004-06-18 | 2011-12-06 | Zephyros, Inc. | Panel structure |
US20070034432A1 (en) * | 2005-07-01 | 2007-02-15 | Rosenberg Steven A | Solid thermally expansible material |
GB0806434D0 (en) | 2008-04-09 | 2008-05-14 | Zephyros Inc | Improvements in or relating to structural adhesives |
GB0905362D0 (en) | 2009-03-30 | 2009-05-13 | 3M Innovative Properties Co | Fire resistant epoxy resin based core filler material developing low exothermic heat |
GB0916205D0 (en) | 2009-09-15 | 2009-10-28 | Zephyros Inc | Improvements in or relating to cavity filling |
EP2542403B2 (en) | 2010-03-04 | 2023-08-16 | Zephyros Inc. | Structural composite laminate |
US10577523B2 (en) | 2013-07-26 | 2020-03-03 | Zephyros, Inc. | Relating to thermosetting adhesive films |
GB201417985D0 (en) | 2014-10-10 | 2014-11-26 | Zephyros Inc | Improvements in or relating to structural adhesives |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE793212A (fr) * | 1971-12-24 | 1973-06-22 | Ciba Geigy | Matieres durcissables a base de resines epoxydiques |
JPS5830910B2 (ja) * | 1977-07-30 | 1983-07-02 | 東邦天然ガス株式会社 | 一液型発泡エポキシ樹脂含浸粘着テ−プ |
NZ212747A (en) * | 1984-07-17 | 1989-01-27 | Dow Chemical Co | Partially advanced epoxy resin compositions |
JPH02218715A (ja) * | 1989-02-20 | 1990-08-31 | Mitsubishi Rayon Co Ltd | シンタクチツクフオーム用組生物 |
US5593770A (en) * | 1989-10-25 | 1997-01-14 | Thiokol Corporation | Chemorheologically tailored matrix resin formulations containing anhydride curing agents |
FR2686089B1 (fr) * | 1992-01-15 | 1995-07-13 | Brochier Sa | Composition a base de resine epoxy et applications, en particulier dans les structures composites. |
GB2280441A (en) * | 1993-07-28 | 1995-02-01 | Peter Drummond Boys White | Gelled reactive resin compositions |
-
1996
- 1996-11-18 AT AT96938375T patent/ATE238369T1/de not_active IP Right Cessation
- 1996-11-18 JP JP51948297A patent/JP3881381B2/ja not_active Expired - Fee Related
- 1996-11-18 PT PT96938375T patent/PT861277E/pt unknown
- 1996-11-18 WO PCT/GB1996/002821 patent/WO1997019124A1/en active IP Right Grant
- 1996-11-18 EP EP96938375A patent/EP0861277B1/en not_active Expired - Lifetime
- 1996-11-18 BR BR9611485A patent/BR9611485A/pt not_active IP Right Cessation
- 1996-11-18 US US09/077,048 patent/US6121348A/en not_active Expired - Lifetime
- 1996-11-18 DE DE69627692T patent/DE69627692T2/de not_active Expired - Lifetime
- 1996-11-18 ES ES96938375T patent/ES2198503T3/es not_active Expired - Lifetime
- 1996-11-18 CA CA002236806A patent/CA2236806C/en not_active Expired - Fee Related
- 1996-11-18 KR KR19980703702A patent/KR100504652B1/ko not_active IP Right Cessation
- 1996-11-18 AU AU75824/96A patent/AU7582496A/en not_active Abandoned
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003531264A (ja) * | 2000-04-20 | 2003-10-21 | バンティコ アクチエンゲゼルシャフト | 凝集性インサート |
WO2011102288A1 (ja) * | 2010-02-16 | 2011-08-25 | ダイセル化学工業株式会社 | 硬化性組成物及び硬化物 |
Also Published As
Publication number | Publication date |
---|---|
WO1997019124A1 (en) | 1997-05-29 |
US6121348A (en) | 2000-09-19 |
JP3881381B2 (ja) | 2007-02-14 |
EP0861277A1 (en) | 1998-09-02 |
KR100504652B1 (ko) | 2005-09-26 |
DE69627692T2 (de) | 2004-01-29 |
DE69627692D1 (de) | 2003-05-28 |
AU7582496A (en) | 1997-06-11 |
BR9611485A (pt) | 1999-01-12 |
EP0861277B1 (en) | 2003-04-23 |
ATE238369T1 (de) | 2003-05-15 |
CA2236806C (en) | 2006-03-14 |
PT861277E (pt) | 2003-09-30 |
ES2198503T3 (es) | 2004-02-01 |
KR19990067674A (ko) | 1999-08-25 |
CA2236806A1 (en) | 1997-05-29 |
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