JP2000299119A - 触媒層の製造方法 - Google Patents
触媒層の製造方法Info
- Publication number
- JP2000299119A JP2000299119A JP11109413A JP10941399A JP2000299119A JP 2000299119 A JP2000299119 A JP 2000299119A JP 11109413 A JP11109413 A JP 11109413A JP 10941399 A JP10941399 A JP 10941399A JP 2000299119 A JP2000299119 A JP 2000299119A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- electrolyte
- electrolyte membrane
- catalyst layer
- frame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 207
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 239000003792 electrolyte Substances 0.000 claims abstract description 173
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 86
- 239000012528 membrane Substances 0.000 claims description 146
- 239000006185 dispersion Substances 0.000 claims description 77
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 60
- 239000000446 fuel Substances 0.000 claims description 39
- 239000005518 polymer electrolyte Substances 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 53
- 150000001298 alcohols Chemical class 0.000 abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 14
- 229910052799 carbon Inorganic materials 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 4
- 238000007598 dipping method Methods 0.000 abstract 1
- 229920000557 Nafion® Polymers 0.000 description 45
- 238000000034 method Methods 0.000 description 28
- 239000008213 purified water Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- 239000011521 glass Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 9
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- 239000002612 dispersion medium Substances 0.000 description 7
- 239000008151 electrolyte solution Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 230000005588 protonation Effects 0.000 description 5
- 238000010408 sweeping Methods 0.000 description 5
- -1 -Propanol Chemical compound 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000003487 electrochemical reaction Methods 0.000 description 4
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- VMSBGXAJJLPWKV-UHFFFAOYSA-N 2-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C=C VMSBGXAJJLPWKV-UHFFFAOYSA-N 0.000 description 3
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical compound OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000003014 ion exchange membrane Substances 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11109413A JP2000299119A (ja) | 1999-04-16 | 1999-04-16 | 触媒層の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11109413A JP2000299119A (ja) | 1999-04-16 | 1999-04-16 | 触媒層の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000299119A true JP2000299119A (ja) | 2000-10-24 |
| JP2000299119A5 JP2000299119A5 (enExample) | 2006-06-08 |
Family
ID=14509627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11109413A Withdrawn JP2000299119A (ja) | 1999-04-16 | 1999-04-16 | 触媒層の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000299119A (enExample) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002373678A (ja) * | 2001-06-15 | 2002-12-26 | Toyota Motor Corp | 燃料電池および燃料電池におけるガスの供給方法 |
| JP2003086200A (ja) * | 2001-09-14 | 2003-03-20 | Matsushita Electric Ind Co Ltd | 電解質膜／電極接合体の製造方法および高分子電解質型燃料電池 |
| JP2003175340A (ja) * | 2001-09-04 | 2003-06-24 | Korea Inst Of Science & Technology | 分離能がある水素イオン交換複合膜、複合溶液、その製造方法及びこれを含む燃料電池 |
| WO2003077336A1 (en) * | 2002-03-14 | 2003-09-18 | Matsushita Electric Industrial Co., Ltd. | Method for manufacturing polymer electrolyte type fuel cell |
| JP2006513527A (ja) * | 2002-06-13 | 2006-04-20 | ゼネラル・モーターズ・コーポレーション | 膜電極アッセンブリを製作する方法 |
| WO2007061069A1 (ja) * | 2005-11-25 | 2007-05-31 | Matsushita Electric Industrial Co., Ltd. | 膜触媒層接合体、膜電極接合体、燃料電池および燃料電池スタック |
| US7425383B2 (en) | 2001-10-31 | 2008-09-16 | Hitachi, Ltd. | Electrode for polymer electrolyte fuel cell, separator therefore, and polymer electrolyte fuel cell, and generating system using them |
| JP2010086786A (ja) * | 2008-09-30 | 2010-04-15 | Dainippon Printing Co Ltd | 転写箔フィルム及びそれを用いて得られるマスク付き固体高分子電解質膜、マスク付き触媒転写フィルム、触媒層−電解質膜積層体、固体高分子形燃料電池 |
| JP2012146619A (ja) * | 2010-12-24 | 2012-08-02 | Equos Research Co Ltd | 高分子電解質溶液の製造方法 |
| JP2012226847A (ja) * | 2011-04-15 | 2012-11-15 | Honda Motor Co Ltd | 燃料電池用電解質膜・電極構造体 |
| JP2013201140A (ja) * | 2013-06-03 | 2013-10-03 | Dainippon Printing Co Ltd | 転写箔フィルム及びそれを用いて得られるマスク付き固体高分子電解質膜、転写箔フィルム付き固体高分子電解質膜、マスク付き触媒転写フィルム、触媒層−電解質膜積層体、及び固体高分子形燃料電池の製造方法 |
| JP2013206676A (ja) * | 2012-03-28 | 2013-10-07 | Toppan Printing Co Ltd | 膜電極接合体の製造方法及び膜電極接合体 |
| KR20190081380A (ko) * | 2017-12-29 | 2019-07-09 | 현대자동차주식회사 | 연료전지용 막전극접합체의 제조방법 |
-
1999
- 1999-04-16 JP JP11109413A patent/JP2000299119A/ja not_active Withdrawn
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002373678A (ja) * | 2001-06-15 | 2002-12-26 | Toyota Motor Corp | 燃料電池および燃料電池におけるガスの供給方法 |
| JP2003175340A (ja) * | 2001-09-04 | 2003-06-24 | Korea Inst Of Science & Technology | 分離能がある水素イオン交換複合膜、複合溶液、その製造方法及びこれを含む燃料電池 |
| JP2003086200A (ja) * | 2001-09-14 | 2003-03-20 | Matsushita Electric Ind Co Ltd | 電解質膜／電極接合体の製造方法および高分子電解質型燃料電池 |
| US7425383B2 (en) | 2001-10-31 | 2008-09-16 | Hitachi, Ltd. | Electrode for polymer electrolyte fuel cell, separator therefore, and polymer electrolyte fuel cell, and generating system using them |
| US7659028B2 (en) | 2001-10-31 | 2010-02-09 | Hitachi, Ltd. | Polymer electrolyte fuel cell |
| WO2003077336A1 (en) * | 2002-03-14 | 2003-09-18 | Matsushita Electric Industrial Co., Ltd. | Method for manufacturing polymer electrolyte type fuel cell |
| KR100595088B1 (ko) * | 2002-03-14 | 2006-06-30 | 마츠시타 덴끼 산교 가부시키가이샤 | 고분자 전해질형 연료전지의 제조방법 |
| US7285354B2 (en) | 2002-03-14 | 2007-10-23 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell, fuel cell electrode, method for producing electrode catalyst layer, and method for producing polymer electrolyte fuel cell |
| JP2006513527A (ja) * | 2002-06-13 | 2006-04-20 | ゼネラル・モーターズ・コーポレーション | 膜電極アッセンブリを製作する方法 |
| WO2007061069A1 (ja) * | 2005-11-25 | 2007-05-31 | Matsushita Electric Industrial Co., Ltd. | 膜触媒層接合体、膜電極接合体、燃料電池および燃料電池スタック |
| US8129073B2 (en) | 2005-11-25 | 2012-03-06 | Panasonic Corporation | Catalyst-coated membrane, membrane-electrode assembly, fuel cell and fuel cell stack |
| JP2010086786A (ja) * | 2008-09-30 | 2010-04-15 | Dainippon Printing Co Ltd | 転写箔フィルム及びそれを用いて得られるマスク付き固体高分子電解質膜、マスク付き触媒転写フィルム、触媒層−電解質膜積層体、固体高分子形燃料電池 |
| JP2012146619A (ja) * | 2010-12-24 | 2012-08-02 | Equos Research Co Ltd | 高分子電解質溶液の製造方法 |
| JP2012226847A (ja) * | 2011-04-15 | 2012-11-15 | Honda Motor Co Ltd | 燃料電池用電解質膜・電極構造体 |
| JP2013206676A (ja) * | 2012-03-28 | 2013-10-07 | Toppan Printing Co Ltd | 膜電極接合体の製造方法及び膜電極接合体 |
| JP2013201140A (ja) * | 2013-06-03 | 2013-10-03 | Dainippon Printing Co Ltd | 転写箔フィルム及びそれを用いて得られるマスク付き固体高分子電解質膜、転写箔フィルム付き固体高分子電解質膜、マスク付き触媒転写フィルム、触媒層−電解質膜積層体、及び固体高分子形燃料電池の製造方法 |
| KR20190081380A (ko) * | 2017-12-29 | 2019-07-09 | 현대자동차주식회사 | 연료전지용 막전극접합체의 제조방법 |
| KR102552145B1 (ko) | 2017-12-29 | 2023-07-05 | 현대자동차주식회사 | 연료전지용 막전극접합체의 제조방법 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3922451B2 (ja) | 燃料電池用膜−電極−ガスケット接合体の製造方法 | |
| CN101942672B (zh) | 一种聚合物电解质膜电极的制备方法 | |
| JP2004006369A (ja) | 触媒コーティングされた膜を用いる膜電極アセンブリの製造方法 | |
| JP2007528105A (ja) | プロトン交換膜燃料電池用のガス拡散電極及び膜電極アセンブリ | |
| CN102088092A (zh) | 直接甲醇燃料电池用三维网络结构膜电极的制备方法 | |
| JP2000299119A (ja) | 触媒層の製造方法 | |
| JP3504021B2 (ja) | 電気化学装置用電極とその製造方法 | |
| JP4423856B2 (ja) | 燃料電池とその製法 | |
| CN102820474A (zh) | 一种聚合物电解质膜电极的制备方法 | |
| WO2005057698A1 (ja) | 燃料電池 | |
| EP2283533A1 (en) | Activation method for membrane electrode assembly, membrane electrode assembly, and solid polymer-type fuel cell using same | |
| JP2007501496A (ja) | 界面抵抗を減少させたハイブリッド膜・電極接合体及びその作製方法 | |
| CN1913206A (zh) | 膜电极组件及其制备方法以及包含它的燃料电池系统 | |
| JP2003059511A (ja) | 燃料電池用電解質膜−電極接合体、その製造方法、および高分子電解質型燃料電池 | |
| JP4117430B2 (ja) | ガス拡散電極及びそれを備えた燃料電池 | |
| JP2001093544A (ja) | 燃料電池用電極、その製造方法並びに燃料電池 | |
| JP2003059507A (ja) | 燃料電池用電解質膜−電極接合体、その製造方法、および高分子電解質型燃料電池 | |
| JP3965666B2 (ja) | ガス拡散電極およびその製造方法 | |
| JP4919005B2 (ja) | 燃料電池用電極の製造方法 | |
| CN104505528A (zh) | 五合一聚合物电解质膜电极 | |
| JP2001126737A (ja) | 燃料電池用電極、その製造方法並びに燃料電池 | |
| JP2010170895A (ja) | 膜電極接合体の製造方法および製造装置 | |
| JP5609475B2 (ja) | 電極触媒層、電極触媒層の製造方法、この電極触媒層を用いた固体高分子形燃料電池 | |
| CN100486006C (zh) | 一种质子交换膜燃料电池的膜电极制备方法 | |
| JP2003297373A (ja) | 触媒層用塗料とこれを用いた電解質膜電極接合体の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A712 Effective date: 20051213 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20060413 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20060413 |
|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20070808 |