IN2014DN07028A - - Google Patents
Info
- Publication number
- IN2014DN07028A IN2014DN07028A IN7028DEN2014A IN2014DN07028A IN 2014DN07028 A IN2014DN07028 A IN 2014DN07028A IN 7028DEN2014 A IN7028DEN2014 A IN 7028DEN2014A IN 2014DN07028 A IN2014DN07028 A IN 2014DN07028A
- Authority
- IN
- India
- Prior art keywords
- adipic acid
- disclosed
- ammonia
- products
- caprolactam
- Prior art date
Links
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 6
- 235000011037 adipic acid Nutrition 0.000 abstract 5
- 239000001361 adipic acid Substances 0.000 abstract 5
- 238000006243 chemical reaction Methods 0.000 abstract 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 3
- 229910021529 ammonia Inorganic materials 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 3
- 239000000758 substrate Substances 0.000 abstract 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical class NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NOIZJQMZRULFFO-UHFFFAOYSA-N adipamic acid Chemical class NC(=O)CCCCC(O)=O NOIZJQMZRULFFO-UHFFFAOYSA-N 0.000 abstract 1
- -1 adipic acid di esters Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
- C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
- C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D223/08—Oxygen atoms
- C07D223/10—Oxygen atoms attached in position 2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8906—Iron and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8913—Cobalt and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261602533P | 2012-02-23 | 2012-02-23 | |
| PCT/US2013/025846 WO2013126250A1 (en) | 2012-02-23 | 2013-02-13 | Production of caprolactam from adipic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2014DN07028A true IN2014DN07028A (enrdf_load_stackoverflow) | 2015-04-10 |
Family
ID=47748790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN7028DEN2014 IN2014DN07028A (enrdf_load_stackoverflow) | 2012-02-23 | 2013-02-13 |
Country Status (12)
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013090031A2 (en) | 2011-12-14 | 2013-06-20 | Rennovia, Inc. | Water concentration reduction process |
| EP2790806A1 (en) | 2011-12-14 | 2014-10-22 | Rennovia, Inc. | Process for the separation of mono-and di-carboxylic acid compounds |
| CN104557705B (zh) * | 2013-10-15 | 2017-06-09 | 中国石油化工股份有限公司 | 一种己内酰胺精制的方法和装置 |
| CA3205339A1 (en) | 2014-09-29 | 2016-04-07 | Archer-Daniels-Midland Company | Preparation and separation of a dicarboxylic acid-containing mixture using a dicarboxylate form of an anion exchange chromatogrpahy resin |
| JP6672792B2 (ja) * | 2014-10-30 | 2020-03-25 | 東レ株式会社 | ε−カプロラクタムの製造方法 |
| WO2017043560A1 (ja) * | 2015-09-11 | 2017-03-16 | 東レ株式会社 | ε－カプロラクタムの製造方法 |
| CA3046130A1 (en) | 2016-12-06 | 2018-06-14 | Toray Industries, Inc. | Method for producing .epsilon.-caprolactam |
| KR102739203B1 (ko) * | 2018-08-28 | 2024-12-05 | 현대자동차주식회사 | 바이오 나일론 원료의 중간체 물질인 아디프아마이드 제조방법 |
| CN114160120B (zh) * | 2021-12-24 | 2024-01-26 | 郑州中科新兴产业技术研究院 | 一种用于己二酸酯生产己二腈的催化剂的制备方法 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2351939A (en) * | 1944-06-20 | Method of producing lactams | ||
| GB778253A (en) * | 1955-02-02 | 1957-07-03 | Inventa Ag | Process for the manufacture of -e-caprolactam |
| US3652549A (en) * | 1968-07-18 | 1972-03-28 | Kanegafuchi Spinning Co Ltd | Production of epsilon-caprolactam |
| JPS4919250B1 (enrdf_load_stackoverflow) * | 1969-01-09 | 1974-05-16 | ||
| JPS4919250A (enrdf_load_stackoverflow) * | 1972-06-16 | 1974-02-20 | ||
| US4042490A (en) * | 1973-12-26 | 1977-08-16 | Texaco Inc. | Hydrocarbon upgrading process |
| US4800227A (en) | 1984-08-20 | 1989-01-24 | Phillips Petroleum Company | Process for the production of lactams |
| IT1214622B (it) | 1985-07-10 | 1990-01-18 | Montedipe Spa | Processo catalitico per laproduzione di cicloesanonossima. |
| US5717089A (en) * | 1995-03-01 | 1998-02-10 | Dsm N.V. | Process for the preparation of E-caprolactam |
| DE19548289A1 (de) * | 1995-12-22 | 1997-06-26 | Basf Ag | Verfahren zur gleichzeitigen Herstellung von Caprolactam und Hexamethylendiamin |
| US5780623A (en) * | 1996-02-23 | 1998-07-14 | Dsm N.V. | Process to prepare ε-caprolactam from 6-aminocaproic acid |
| US5977356A (en) * | 1997-07-02 | 1999-11-02 | Industrial Technology Research Institute | Process for preparing caprolactam |
| EP0984002A1 (en) | 1998-09-03 | 2000-03-08 | Dsm N.V. | Process to continuously prepare an aqueous mixture of epsilon-caprolactam and epsilon-caprolactam precursors |
| DE19842900A1 (de) | 1998-09-18 | 2000-03-23 | Basf Ag | Verfahren zur gemeinsamen Herstellung eines cyclischen Lactams und eines cyclischen Amins |
| FR2785608B1 (fr) | 1998-11-05 | 2000-12-29 | Rhone Poulenc Fibres | Procede d'hemihydrogenation de dinitriles |
| JP2000229939A (ja) | 1999-02-09 | 2000-08-22 | Sumitomo Chem Co Ltd | ε−カプロラクタムの製造方法 |
| US6300496B1 (en) | 1999-10-06 | 2001-10-09 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for producing epsilon caprolactams |
| US6414179B1 (en) * | 2000-02-18 | 2002-07-02 | Bristol-Myers Squibb Company | Alpha-and beta-substituted trifluoromethyl ketones as phospholipase inhibitors |
| DE10028950A1 (de) | 2000-06-16 | 2001-12-20 | Basf Ag | Verfahren zur Herstellung von Caprolactam |
| US6372939B1 (en) | 2000-11-16 | 2002-04-16 | E.I. Du Pont De Nemours And Company | Production of 6-aminocaproic acid |
| DE10103581A1 (de) | 2001-01-26 | 2002-08-01 | Degussa | Durch Ammoniumsalze oder substituierte Ammoniumsalze cokatalysiertes Verfahren zur Herstellung von Oximen |
| EP1741699B1 (en) | 2001-02-14 | 2011-01-26 | Asahi Kasei Kabushiki Kaisha | Method for producing E-caprolactam |
| EP1251122A1 (en) | 2001-04-17 | 2002-10-23 | Dsm N.V. | Process for the preparation of epsilon-Caprolactam |
| US6479620B1 (en) * | 2001-06-01 | 2002-11-12 | E. I. Du Pont De Nemours And Company | Process for converting caprolactam to nylon 6 |
| GB0325384D0 (en) | 2003-10-30 | 2003-12-03 | Davy Process Techn Ltd | Process |
| WO2007066492A1 (ja) | 2005-12-07 | 2007-06-14 | Ube Industries, Ltd. | ラクタムの製法 |
| JP5061607B2 (ja) * | 2006-12-12 | 2012-10-31 | 東洋紡績株式会社 | ナイロン６樹脂の製造方法 |
| EP2148856B8 (en) | 2007-02-20 | 2016-04-06 | Board of Trustees of Michigan State University | Catalytic deamination for caprolactam production |
| US8669397B2 (en) | 2009-06-13 | 2014-03-11 | Rennovia, Inc. | Production of adipic acid and derivatives from carbohydrate-containing materials |
| US8501989B2 (en) | 2009-06-13 | 2013-08-06 | Rennovia, Inc. | Production of adipic acid and derivatives from carbohydrate-containing materials |
| NZ601945A (en) * | 2010-03-05 | 2014-08-29 | Rennovia Inc | Adipic acid composition |
| WO2013090031A2 (en) | 2011-12-14 | 2013-06-20 | Rennovia, Inc. | Water concentration reduction process |
| EP2790806A1 (en) | 2011-12-14 | 2014-10-22 | Rennovia, Inc. | Process for the separation of mono-and di-carboxylic acid compounds |
| WO2013173372A1 (en) | 2012-05-15 | 2013-11-21 | Rennovia, Inc. | Reduction catalysts |
| JP6209603B2 (ja) | 2012-06-11 | 2017-10-04 | レノヴィア, インコーポレイテッドRennovia, INC. | １，６‐ヘキサンジオール由来のアジピン酸製造方法 |
-
2013
- 2013-02-13 KR KR1020147024515A patent/KR20140129076A/ko not_active Withdrawn
- 2013-02-13 CN CN201380009620.5A patent/CN104169259B/zh active Active
- 2013-02-13 BR BR112014020642-2A patent/BR112014020642B1/pt active IP Right Grant
- 2013-02-13 SA SA113340296A patent/SA113340296B1/ar unknown
- 2013-02-13 JP JP2014558764A patent/JP2015517977A/ja active Pending
- 2013-02-13 WO PCT/US2013/025846 patent/WO2013126250A1/en active Application Filing
- 2013-02-13 IN IN7028DEN2014 patent/IN2014DN07028A/en unknown
- 2013-02-13 EP EP13705896.2A patent/EP2817293A1/en not_active Withdrawn
- 2013-02-13 AR ARP130100441A patent/AR089980A1/es unknown
- 2013-02-13 US US13/766,705 patent/US8946411B2/en active Active
- 2013-02-13 SG SG11201405045YA patent/SG11201405045YA/en unknown
- 2013-02-13 HK HK15105859.2A patent/HK1205121A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013126250A1 (en) | 2013-08-29 |
| BR112014020642B1 (pt) | 2020-12-29 |
| AR089980A1 (es) | 2014-10-01 |
| CN104169259B (zh) | 2016-09-21 |
| SA113340296B1 (ar) | 2015-09-06 |
| CN104169259A (zh) | 2014-11-26 |
| US20130225785A1 (en) | 2013-08-29 |
| JP2015517977A (ja) | 2015-06-25 |
| SG11201405045YA (en) | 2014-09-26 |
| US8946411B2 (en) | 2015-02-03 |
| BR112014020642A2 (pt) | 2019-09-10 |
| KR20140129076A (ko) | 2014-11-06 |
| HK1205121A1 (en) | 2015-12-11 |
| EP2817293A1 (en) | 2014-12-31 |
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