SG11201809192YA - Method for carrying out a heterogeneously catalysed reaction - Google Patents

Method for carrying out a heterogeneously catalysed reaction

Info

Publication number
SG11201809192YA
SG11201809192YA SG11201809192YA SG11201809192YA SG11201809192YA SG 11201809192Y A SG11201809192Y A SG 11201809192YA SG 11201809192Y A SG11201809192Y A SG 11201809192YA SG 11201809192Y A SG11201809192Y A SG 11201809192YA SG 11201809192Y A SG11201809192Y A SG 11201809192YA
Authority
SG
Singapore
Prior art keywords
catalysed
heterogeneously catalysed
carrying
heterogeneously
catalysed reaction
Prior art date
Application number
SG11201809192YA
Inventor
Alexander Lygin
Matthias Grömping
Steffen Krill
Original Assignee
Evonik Roehm Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Roehm Gmbh filed Critical Evonik Roehm Gmbh
Publication of SG11201809192YA publication Critical patent/SG11201809192YA/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/006—Separating solid material from the gas/liquid stream by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/0084—Stationary elements inside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00858—Moving elements
    • B01J2208/00867—Moving elements inside the bed, e.g. rotary mixer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00768—Baffles attached to the reactor wall vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1946—Details relating to the geometry of the reactor round circular or disk-shaped conical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Method for carrying out a heterogeneously catalysed reaction The present invention relates to a novel process for performing a heterogeneously catalysed reaction, especially in a liquid phase. There are plentiful descriptions in the technical literature of heterogeneously catalysed reactions in a liquid phase. These include, for example, the cobalt-catalysed Fischer-Tropsch synthesis, palladium- and nickel-catalysed direct hydrogenations with hydrogen, and numerous oxidation reactions. Against this background, it has been possible by the present process according to the invention to perform such processes for longer periods without disruption, with constant or even increased activities and selectivities. This gives rise to the possibility of performing such processes in a very simple, economically viable and environmentally benign manner. (No drawing to be published)
SG11201809192YA 2016-04-22 2017-04-13 Method for carrying out a heterogeneously catalysed reaction SG11201809192YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16166606.0A EP3235560A1 (en) 2016-04-22 2016-04-22 Method for performing a heterogeneously catalysed reaction
PCT/EP2017/058903 WO2017182381A1 (en) 2016-04-22 2017-04-13 Method for carrying out a heterogeneously catalysed reaction

Publications (1)

Publication Number Publication Date
SG11201809192YA true SG11201809192YA (en) 2018-11-29

Family

ID=55862558

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201809192YA SG11201809192YA (en) 2016-04-22 2017-04-13 Method for carrying out a heterogeneously catalysed reaction

Country Status (11)

Country Link
US (1) US10596539B2 (en)
EP (2) EP3235560A1 (en)
JP (1) JP6873155B2 (en)
KR (1) KR102352909B1 (en)
CN (1) CN109070036B (en)
BR (1) BR112018071599A2 (en)
RU (1) RU2731571C2 (en)
SA (1) SA518400269B1 (en)
SG (1) SG11201809192YA (en)
TW (1) TW201806666A (en)
WO (1) WO2017182381A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11202000742QA (en) * 2017-07-28 2020-02-27 Dow Global Technologies Llc A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
SG11202000745YA (en) * 2017-07-28 2020-02-27 Rohm & Haas A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
KR102639247B1 (en) * 2017-07-28 2024-02-21 다우 글로벌 테크놀로지스 엘엘씨 Method for producing methyl methacrylate by oxidative esterification using a heterogeneous catalyst
KR102644577B1 (en) * 2017-07-28 2024-03-07 다우 글로벌 테크놀로지스 엘엘씨 Method for producing methyl methacrylate by oxidative esterification using a heterogeneous catalyst
EP3658528B1 (en) * 2017-07-28 2021-08-18 Rohm and Haas Company A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CA3071242A1 (en) * 2017-07-28 2019-01-31 Rohm And Haas Company A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
JP7268007B2 (en) * 2017-09-19 2023-05-02 ダウ グローバル テクノロジーズ エルエルシー Process for producing methyl methacrylate by oxidative esterification using heterogeneous catalysts
CN108671877B (en) * 2018-07-16 2024-02-20 山东绿色自由基科技研究中心 Heterogeneous phase flow reactor
WO2022248321A1 (en) 2021-05-28 2022-12-01 Röhm Gmbh Reactor and process for producing alkyl methacrylates
EP4347548A1 (en) 2021-05-28 2024-04-10 Röhm GmbH Reactor and process for producing alkyl (meth)acrylates
WO2023059674A1 (en) * 2021-10-08 2023-04-13 Dow Global Technologies Llc Process for low byproduct formation from an oxidative esterification reactor with base addition
US12017987B2 (en) 2021-11-12 2024-06-25 Röhm Gmbh Process for eliminating interfering by-products in the direct oxidative esterification of methacrolein
EP4371660A1 (en) * 2022-11-21 2024-05-22 Röhm GmbH Method for preparing a catalyst for the production of methyl methacrylate using clarification

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2612538B2 (en) 1991-07-29 1997-05-21 エクソン・ケミカル・パテンツ・インク Polymer reactor
US5288673A (en) 1992-12-18 1994-02-22 Exxon Research And Engineering Company Temperature control in draft tubes for catalyst rejuvenation
US5723041A (en) * 1994-10-10 1998-03-03 Amoco Corporation Process and apparatus for promoting annularly uniform flow
US5569434A (en) * 1994-10-10 1996-10-29 Amoco Corporation Hydrocarbon processing apparatus and method
US5856533A (en) * 1995-12-28 1999-01-05 Praxair Technology, Inc. High efficiency heat and mass transfer for vapor phase heterogeneous reactions
JP3874442B2 (en) 1996-03-18 2007-01-31 旭化成エンジニアリング株式会社 Liquid component continuous separator
JP3874470B2 (en) 1996-09-24 2007-01-31 旭化成エンジニアリング株式会社 Methyl methacrylate production equipment
US5962537A (en) 1997-05-06 1999-10-05 Exxon Research And Engineering Co Multizone downcomer for slurry hydrocarbon syntheses process
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
SG123723A1 (en) * 2004-12-22 2006-07-26 Sumitomo Chemical Co Process for producing cyclohexanone oxime
US8236170B2 (en) * 2005-12-16 2012-08-07 Chevron U.S.A. Inc. Reactor for use in upgrading heavy oil
CN101314120B (en) 2007-05-31 2010-05-26 中国石油化工股份有限公司 Slurry bed reactor and uses thereof
JP4803767B2 (en) 2007-10-26 2011-10-26 旭化成ケミカルズ株式会社 COMPOSITE PARTICLE CARRIER, METHOD FOR PRODUCING COMPOSITE PARTICLE CARRIER, AND METHOD FOR PRODUCING COMPOUND USING THE COMPOSITE PARTICLE CARRIER AS CATALYST FOR CHEMICAL SYNTHESIS
US8119014B2 (en) * 2008-12-23 2012-02-21 Exxonmobil Research And Engineering Company Systems and methods to remove liquid product and fines from a slurry reactor
CN102773048B (en) 2011-05-09 2017-06-06 波利玛利欧洲股份公司 Produce the Ammoximation reaction device of cyclohexanone oxime
KR102213622B1 (en) 2013-04-19 2021-02-08 룀 게엠베하 Method for producing methylmethacrylate
CN104418309B (en) 2013-09-05 2016-08-17 中国石油化工股份有限公司 A kind of preparation method of hydrogen peroxide
EP2886528A1 (en) 2013-12-20 2015-06-24 Evonik Industries AG Method for producing unsaturated esters from aldehydes by direct oxidative esterification
EP2886529A1 (en) 2013-12-20 2015-06-24 Evonik Industries AG Process for producing methyl methacrylate
CN105126710B (en) * 2015-08-28 2017-05-10 湖南百利工程科技股份有限公司 Slurry bed reactor and application of slurry bed reactor in hydrogen peroxide production

Also Published As

Publication number Publication date
EP3235560A1 (en) 2017-10-25
WO2017182381A1 (en) 2017-10-26
US20190099731A1 (en) 2019-04-04
TW201806666A (en) 2018-03-01
EP3445483A1 (en) 2019-02-27
RU2018140981A3 (en) 2020-05-22
RU2018140981A (en) 2020-05-22
US10596539B2 (en) 2020-03-24
SA518400269B1 (en) 2021-12-06
KR20180136958A (en) 2018-12-26
KR102352909B1 (en) 2022-01-18
JP6873155B2 (en) 2021-05-19
CN109070036B (en) 2022-06-03
JP2019514880A (en) 2019-06-06
RU2731571C2 (en) 2020-09-04
BR112018071599A2 (en) 2019-02-12
CN109070036A (en) 2018-12-21

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