IN2014CN03490A - - Google Patents
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- Publication number
- IN2014CN03490A IN2014CN03490A IN3490CHN2014A IN2014CN03490A IN 2014CN03490 A IN2014CN03490 A IN 2014CN03490A IN 3490CHN2014 A IN3490CHN2014 A IN 3490CHN2014A IN 2014CN03490 A IN2014CN03490 A IN 2014CN03490A
- Authority
- IN
- India
- Prior art keywords
- infiltration
- strontium titanate
- doped strontium
- cgo
- backbone
- Prior art date
Links
- 230000008595 infiltration Effects 0.000 abstract 5
- 238000001764 infiltration Methods 0.000 abstract 5
- 239000002243 precursor Substances 0.000 abstract 3
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 abstract 3
- 229910002651 NO3 Inorganic materials 0.000 abstract 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 229910052688 Gadolinium Inorganic materials 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 239000010955 niobium Substances 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000002910 rare earth metals Chemical class 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
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- C—CHEMISTRY; METALLURGY
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
- C04B35/462—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
- C04B35/465—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
- C04B35/47—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on strontium titanates
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- C—CHEMISTRY; METALLURGY
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8846—Impregnation
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- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
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- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3229—Cerium oxides or oxide-forming salts thereof
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3239—Vanadium oxides, vanadates or oxide forming salts thereof, e.g. magnesium vanadate
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3279—Nickel oxides, nickalates, or oxide-forming salts thereof
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3289—Noble metal oxides
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/441—Alkoxides, e.g. methoxide, tert-butoxide
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/449—Organic acids, e.g. EDTA, citrate, acetate, oxalate
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6025—Tape casting, e.g. with a doctor blade
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
- C04B2235/6582—Hydrogen containing atmosphere
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Metallurgy (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
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Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA201100811 | 2011-10-24 | ||
PCT/EP2012/070951 WO2013060671A1 (en) | 2011-10-24 | 2012-10-23 | High performance fuel electrode for a solid oxide electrochemical cell |
Publications (1)
Publication Number | Publication Date |
---|---|
IN2014CN03490A true IN2014CN03490A (cs) | 2015-10-09 |
Family
ID=47046630
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IN3490CHN2014 IN2014CN03490A (cs) | 2011-10-24 | 2012-10-23 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20140287342A1 (cs) |
EP (1) | EP2771932A1 (cs) |
JP (1) | JP2015501515A (cs) |
KR (1) | KR20140096310A (cs) |
CN (1) | CN104025352A (cs) |
AU (1) | AU2012327278A1 (cs) |
CA (1) | CA2853169A1 (cs) |
EA (1) | EA201490860A1 (cs) |
IN (1) | IN2014CN03490A (cs) |
WO (1) | WO2013060671A1 (cs) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9181148B2 (en) * | 2013-05-22 | 2015-11-10 | Saudi Arabian Oil Company | Ni/CGO and Ni-Ru/CGO based pre-reforming catalysts formulation for methane rich gas production from diesel processing for fuel cell applications |
US9469908B2 (en) * | 2014-05-12 | 2016-10-18 | The Trustees Of The University Of Pennsylvania | Synergistic oxygen evolving activity of non-stoichiometric surfaces |
CN107210466B (zh) * | 2015-03-06 | 2020-10-20 | 株式会社Lg化学 | 电极的制造方法、电极、电极结构、燃料电池或金属-空气二次电池、电池模块及组合物 |
EP3340349A1 (de) * | 2016-12-21 | 2018-06-27 | sunfire GmbH | Schwefeltoleranter katalysator für festoxid-brennstoffzelle sowie herstellungsverfahren |
CN108390086B (zh) * | 2017-01-03 | 2020-03-20 | 清华大学 | 含氢过渡金属氧化物及其制备方法、固态燃料电池 |
US11283084B2 (en) | 2017-05-03 | 2022-03-22 | The Regents Of The University Of California | Fabrication processes for solid state electrochemical devices |
JP7076788B2 (ja) * | 2017-08-01 | 2022-05-30 | 国立研究開発法人物質・材料研究機構 | 固体酸化物形燃料電池のアノード材料及びその製造方法、並びに固体酸化物形燃料電池 |
CN108360010B (zh) * | 2018-01-26 | 2019-09-06 | 济南大学 | 一种固体氧化物电解电池电极催化涂层的制备方法 |
CN109802148A (zh) * | 2019-02-01 | 2019-05-24 | 上海亮仓能源科技有限公司 | 一种车载燃料电池用负载型铂稀土金属阴极催化剂的制备方法 |
CN109852988B (zh) * | 2019-04-12 | 2021-05-25 | 清华大学 | 一种微纳树状固体氧化物电解池阳极及其制备方法 |
JP7377051B2 (ja) | 2019-10-07 | 2023-11-09 | 太陽誘電株式会社 | 固体酸化物型燃料電池およびその製造方法 |
WO2021162975A1 (en) * | 2020-02-11 | 2021-08-19 | Phillips 66 Company | Solid oxide fuel cell cathode materials |
JP7484048B2 (ja) | 2020-03-10 | 2024-05-16 | 太陽誘電株式会社 | 固体酸化物型燃料電池およびその製造方法 |
EP4136279A4 (en) * | 2020-05-14 | 2024-06-26 | Bloom Energy Corporation | ELECTROLYTE MATERIALS FOR SOLID OXIDE ELECTROLYSIS CELLS |
US20230138222A1 (en) * | 2020-06-24 | 2023-05-04 | Korea Advanced Institute Of Science And Technology | Solid oxide fuel cell comprising anode alkaline-based promoter loaded |
KR102369060B1 (ko) * | 2020-06-24 | 2022-03-02 | 한국과학기술원 | 알칼리 기반 프로모터가 도입된 연료극을 포함하는 고체 산화물 연료전지 |
CN112647089B (zh) * | 2020-12-15 | 2021-12-07 | 中国科学院大连化学物理研究所 | 一种固体氧化物电解池三元复合阳极的制备方法 |
CN113151847A (zh) * | 2021-04-16 | 2021-07-23 | 上海大学 | 一种固体氧化物电解池工作电极的制备方法及其应用 |
GB202303469D0 (en) * | 2023-03-09 | 2023-04-26 | Ceres Ip Co Ltd | Electrode and electrochemical cell |
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Publication number | Priority date | Publication date | Assignee | Title |
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US6548203B2 (en) | 1995-11-16 | 2003-04-15 | The Dow Chemical Company | Cathode composition for solid oxide fuel cell |
US6051329A (en) | 1998-01-15 | 2000-04-18 | International Business Machines Corporation | Solid oxide fuel cell having a catalytic anode |
US6841512B1 (en) | 1999-04-12 | 2005-01-11 | Ovonic Battery Company, Inc. | Finely divided metal catalyst and method for making same |
US20040018409A1 (en) * | 2002-02-28 | 2004-01-29 | Shiqiang Hui | Solid oxide fuel cell components and method of manufacture thereof |
AU2003228791A1 (en) * | 2002-05-03 | 2003-11-17 | Battelle Memorial Institute | Cerium-modified doped strontium titanate composition for solid oxide fuel cell anodes and electrodes for other electrochemical devices |
CN101107740A (zh) * | 2003-12-02 | 2008-01-16 | 纳米动力公司 | 使用金属陶瓷电解质的阳极支撑的固体氧化物燃料电池 |
JP4620572B2 (ja) | 2005-11-25 | 2011-01-26 | 日本電信電話株式会社 | 固体酸化物形燃料電池及びその作製方法 |
CN1788841A (zh) * | 2005-12-21 | 2006-06-21 | 华东师范大学 | 一种制氢催化剂、制备及其用途 |
AU2007294812A1 (en) | 2006-09-13 | 2008-03-20 | University Of Akron | Catalysts compositions for use in fuel cells |
EP2254180A1 (en) * | 2007-08-31 | 2010-11-24 | Technical University of Denmark | Ceria and strontium titanate based electrodes |
ATE519241T1 (de) * | 2007-08-31 | 2011-08-15 | Univ Denmark Tech Dtu | Auf ceroxid und edelstahl basierende elektroden |
KR20100069492A (ko) | 2008-12-16 | 2010-06-24 | 삼성전자주식회사 | 연료전지용 전극 촉매, 상기 전극 촉매를 포함하는 전극을 구비한 연료전지 |
TWI385851B (zh) | 2009-07-03 | 2013-02-11 | Iner Aec Executive Yuan | 固態氧化物燃料電池及其製作方法 |
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- 2012-10-23 CN CN201280052264.0A patent/CN104025352A/zh active Pending
- 2012-10-23 CA CA2853169A patent/CA2853169A1/en not_active Abandoned
- 2012-10-23 EP EP12775266.5A patent/EP2771932A1/en not_active Withdrawn
- 2012-10-23 JP JP2014537578A patent/JP2015501515A/ja active Pending
- 2012-10-23 AU AU2012327278A patent/AU2012327278A1/en not_active Abandoned
- 2012-10-23 KR KR1020147014003A patent/KR20140096310A/ko not_active Withdrawn
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- 2012-10-23 WO PCT/EP2012/070951 patent/WO2013060671A1/en active Application Filing
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JP2015501515A (ja) | 2015-01-15 |
EA201490860A1 (ru) | 2014-09-30 |
US20140287342A1 (en) | 2014-09-25 |
CN104025352A (zh) | 2014-09-03 |
KR20140096310A (ko) | 2014-08-05 |
CA2853169A1 (en) | 2013-05-02 |
EP2771932A1 (en) | 2014-09-03 |
WO2013060671A1 (en) | 2013-05-02 |
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