IL311115A - Process for the production of herbicide and its intermediates - Google Patents
Process for the production of herbicide and its intermediatesInfo
- Publication number
- IL311115A IL311115A IL311115A IL31111524A IL311115A IL 311115 A IL311115 A IL 311115A IL 311115 A IL311115 A IL 311115A IL 31111524 A IL31111524 A IL 31111524A IL 311115 A IL311115 A IL 311115A
- Authority
- IL
- Israel
- Prior art keywords
- pyroxasulfone
- crystal
- powder
- alkyl
- producing
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 25
- 230000008569 process Effects 0.000 title claims description 24
- 230000002363 herbicidal effect Effects 0.000 title description 5
- 239000004009 herbicide Substances 0.000 title description 4
- CASLETQIYIQFTQ-UHFFFAOYSA-N 3-[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylsulfonyl]-5,5-dimethyl-4h-1,2-oxazole Chemical compound CN1N=C(C(F)(F)F)C(CS(=O)(=O)C=2CC(C)(C)ON=2)=C1OC(F)F CASLETQIYIQFTQ-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 16
- -1 C1-C4 alkyl C1-C4 alkyl ketones Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001868 water Inorganic materials 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims 25
- 239000012872 agrochemical composition Substances 0.000 claims 9
- 239000004094 surface-active agent Substances 0.000 claims 9
- 239000002552 dosage form Substances 0.000 claims 8
- 239000000843 powder Substances 0.000 claims 8
- 238000010298 pulverizing process Methods 0.000 claims 8
- 239000002994 raw material Substances 0.000 claims 8
- 239000003960 organic solvent Substances 0.000 claims 6
- 239000002002 slurry Substances 0.000 claims 6
- 239000007787 solid Substances 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 150000007942 carboxylates Chemical class 0.000 claims 3
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 3
- 150000001735 carboxylic acids Chemical class 0.000 claims 3
- 150000002576 ketones Chemical class 0.000 claims 3
- 238000005259 measurement Methods 0.000 claims 3
- 239000002609 medium Substances 0.000 claims 3
- 238000000634 powder X-ray diffraction Methods 0.000 claims 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 2
- 239000012296 anti-solvent Substances 0.000 claims 2
- 239000007900 aqueous suspension Substances 0.000 claims 2
- 239000012141 concentrate Substances 0.000 claims 2
- 239000002612 dispersion medium Substances 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 238000004898 kneading Methods 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- 150000002825 nitriles Chemical class 0.000 claims 2
- 239000004533 oil dispersion Substances 0.000 claims 2
- 239000004562 water dispersible granule Substances 0.000 claims 2
- 239000004563 wettable powder Substances 0.000 claims 2
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001492 aromatic hydrocarbon derivatives Chemical class 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 238000001228 spectrum Methods 0.000 claims 1
- LKACJLUUJRMGFK-UHFFFAOYSA-N methylsulfonal Chemical compound CCS(=O)(=O)C(C)(CC)S(=O)(=O)CC LKACJLUUJRMGFK-UHFFFAOYSA-N 0.000 description 143
- 229910052757 nitrogen Inorganic materials 0.000 description 120
- JOCBASBOOFNAJA-UHFFFAOYSA-N N-tris(hydroxymethyl)methyl-2-aminoethanesulfonic acid Chemical compound OCC(CO)(CO)NCCS(O)(=O)=O JOCBASBOOFNAJA-UHFFFAOYSA-N 0.000 description 108
- 150000001875 compounds Chemical class 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- AYUNIORJHRXIBJ-HTLBVUBBSA-N [(3r,5s,6r,7s,8e,10s,11s,12e,14e)-6-hydroxy-5,11-dimethoxy-3,7,9,15-tetramethyl-16,20,22-trioxo-21-(prop-2-enylamino)-17-azabicyclo[16.3.1]docosa-1(21),8,12,14,18-pentaen-10-yl] carbamate Chemical compound N1C(=O)\C(C)=C\C=C\[C@H](OC)[C@@H](OC(N)=O)\C(C)=C\[C@H](C)[C@@H](O)[C@@H](OC)C[C@H](C)CC2=C(NCC=C)C(=O)C=C1C2=O AYUNIORJHRXIBJ-HTLBVUBBSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WSMQKESQZFQMFW-UHFFFAOYSA-N 5-methyl-pyrazole-3-carboxylic acid Chemical compound CC1=CC(C(O)=O)=NN1 WSMQKESQZFQMFW-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000003457 sulfones Chemical class 0.000 description 2
- ARJPLYZBOHQOCK-UHFFFAOYSA-N 3-[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylsulfanyl]-5,5-dimethyl-4h-1,2-oxazole Chemical compound CN1N=C(C(F)(F)F)C(CSC=2CC(C)(C)ON=2)=C1OC(F)F ARJPLYZBOHQOCK-UHFFFAOYSA-N 0.000 description 1
- GXLGHGJWHZVKAD-UHFFFAOYSA-N 3-[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylsulfinyl]-5,5-dimethyl-4h-1,2-oxazole Chemical compound CN1N=C(C(F)(F)F)C(CS(=O)C=2CC(C)(C)ON=2)=C1OC(F)F GXLGHGJWHZVKAD-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Lubricants (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019198600 | 2019-10-31 | ||
| PCT/JP2020/040748 WO2021002484A2 (ja) | 2019-10-31 | 2020-10-30 | 除草剤及びその中間体の製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL311115A true IL311115A (en) | 2024-04-01 |
Family
ID=74100730
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL292532A IL292532B1 (en) | 2019-10-31 | 2020-10-30 | Process for the production of herbicide and its intermediates |
| IL311115A IL311115A (en) | 2019-10-31 | 2020-10-30 | Process for the production of herbicide and its intermediates |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL292532A IL292532B1 (en) | 2019-10-31 | 2020-10-30 | Process for the production of herbicide and its intermediates |
Country Status (15)
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR121018A1 (es) * | 2020-01-15 | 2022-04-06 | Adama Agan Ltd | Forma en estado sólido de piroxasulfona |
| WO2022137370A1 (ja) * | 2020-12-23 | 2022-06-30 | クミアイ化学工業株式会社 | スルホン誘導体の製造方法 |
| WO2022158499A1 (ja) * | 2021-01-19 | 2022-07-28 | クミアイ化学工業株式会社 | 雑草防除方法 |
| MX2023007843A (es) * | 2021-01-19 | 2023-07-07 | Kumiai Chemical Industry Co | Metodo para controlar malezas. |
| GB2603771A (en) * | 2021-02-11 | 2022-08-17 | Rotam Agrochem Int Co Ltd | Novel crystalline form of pyroxa-sulfone, methods for its preparation and use of the same |
| CA3203671A1 (en) * | 2021-03-11 | 2022-09-15 | Kumiai Chemical Industry Co., Ltd. | Method for producing sulfone derivative as herbicide |
| CN113252824B (zh) * | 2021-06-17 | 2022-04-19 | 湖南农业大学 | 测定水体中三氟苯嘧啶含量的气相色谱-电子捕获检测器法 |
| AR126775A1 (es) * | 2021-08-12 | 2023-11-15 | Upl Ltd | Un proceso para la preparación de piroxasulfona |
| CN113831333B (zh) * | 2021-10-14 | 2023-07-28 | 大连九信精细化工有限公司 | 一种砜吡草唑的合成方法 |
| TW202334128A (zh) | 2021-10-29 | 2023-09-01 | 日商組合化學工業股份有限公司 | 二硫化物化合物、多硫化物化合物及其用途 |
| CN117545741A (zh) * | 2021-10-29 | 2024-02-09 | 组合化学工业株式会社 | 二硫化物、多硫化物及其用途 |
| CN114213402A (zh) * | 2021-12-01 | 2022-03-22 | 芮城华农生物化学有限公司 | 一种砜吡草唑亚稳态、稳定态晶型、制备方法及应用 |
| AR129019A1 (es) * | 2022-04-08 | 2024-07-03 | Upl Ltd | Un proceso para la preparación de 3-[5-(difluorometoxi)-1-metil-3-(trifluorometil)pirazol-4-ilmetilsulfonil]-4,5-dihiidro-5,5-dimetil-1,2-oxazol y sus intermedios |
| CN114989157A (zh) * | 2022-06-28 | 2022-09-02 | 安徽久易农业股份有限公司 | 一种砜吡草唑的晶型a及其制备方法和应用 |
| CN118221663A (zh) * | 2024-05-24 | 2024-06-21 | 吉林凯莱英医药化学有限公司 | 砜吡草唑的连续化合成方法 |
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| JPS5661386A (en) * | 1979-10-11 | 1981-05-26 | Leo Pharm Prod Ltd | Manufacture of penicillanic acid derivative |
| JP4465133B2 (ja) * | 2001-02-08 | 2010-05-19 | クミアイ化学工業株式会社 | イソオキサゾリン誘導体及びこれを有効成分とする除草剤 |
| US7875606B2 (en) * | 2001-06-21 | 2011-01-25 | Ihara Chemical Industry Co., Ltd. | Izoxazoline derivative and herbicide |
| TWI270542B (en) | 2002-02-07 | 2007-01-11 | Sumitomo Chemical Co | Method for preparing sulfone or sulfoxide compound |
| UA79483C2 (en) | 2002-08-01 | 2007-06-25 | Ihara Chemical Ind Co | Pyrazole derivatives and processes of preparation thereof |
| UA78071C2 (en) * | 2002-08-07 | 2007-02-15 | Kumiai Chemical Industry Co | Herbicidal composition |
| JP2004195445A (ja) * | 2002-12-17 | 2004-07-15 | Toshiaki Kabe | 有機硫黄化合物を含有する液体の酸化方法、酸化触媒、酸化脱硫方法および酸化脱硫装置 |
| JP4621939B2 (ja) | 2004-03-31 | 2011-02-02 | イハラケミカル工業株式会社 | ５−ヒドロキシ−４−チオメチルピラゾール化合物の製造方法 |
| JP2007246396A (ja) | 2004-04-28 | 2007-09-27 | Ihara Chem Ind Co Ltd | ５−ジフルオロメトキシ−４−チオメチルピラゾール化合物の製造方法 |
| CA2829979A1 (en) | 2004-04-30 | 2005-11-10 | Syngenta Participations Ag | Herbicidal composition comprising an isoxazoline derivative and a safener |
| EP1789401B1 (en) * | 2004-09-03 | 2010-03-03 | Syngenta Limited | Isoxazoline derivatives and their use as herbicides |
| JP2008001597A (ja) | 2004-10-06 | 2008-01-10 | Ihara Chem Ind Co Ltd | ３−ブロモ−５，５−ジメチル−４，５−ジヒドロイソオキサゾールの製造方法 |
| PL1829868T3 (pl) | 2004-12-20 | 2015-03-31 | Ihara Chemical Ind Co | Sposób wytwarzania soli (4,5-dihydroizoksazol-3-ilo)tiokarboksyamidyny |
| AR053940A1 (es) | 2005-06-30 | 2007-05-23 | Syngenta Participations Ag | Formulaciones mejoradas |
| DE102005031583A1 (de) | 2005-07-06 | 2007-01-25 | Bayer Cropscience Gmbh | Verfahren zur Herstellung von von 3-Arylmethylthio- und 3-Heteroarylmethylthio-4,5-dihydro-isoxazolin-Derivaten |
| GB0526044D0 (en) * | 2005-12-21 | 2006-02-01 | Syngenta Ltd | Novel herbicides |
| CA2642308C (en) | 2006-02-14 | 2013-12-17 | Ihara Chemical Industry Co., Ltd. | Process for production of 5-alkoxy-4-hydroxymethylpyrazole compound |
| GB0603891D0 (en) * | 2006-02-27 | 2006-04-05 | Syngenta Ltd | Novel herbicides |
| WO2009066309A2 (en) * | 2007-07-12 | 2009-05-28 | Cadila Healthcare Limited | Process for preparation of omeprazole |
| WO2009158258A1 (en) | 2008-06-25 | 2009-12-30 | E. I. Du Pont De Nemours And Company | Herbicidal dihydro oxo six-membered azinyl isoxazolines |
| JP2010208990A (ja) * | 2009-03-10 | 2010-09-24 | Dnp Fine Chemicals Fukushima Co Ltd | スルホン化合物の製造方法 |
| DK2504322T3 (da) * | 2009-11-26 | 2014-06-16 | Basf Se | Fremgangsmåde til fremstilling af 5,5-disubstituerede 4,5-dihydroisoxazol-3-thiocarboxamidinsalte |
| HUE025730T2 (en) | 2011-01-18 | 2016-04-28 | Dsm Sinochem Pharm Nl Bv | A method for producing statins using a base |
| JP6382803B2 (ja) | 2012-06-27 | 2018-08-29 | スリーエム イノベイティブ プロパティズ カンパニー | 光学部品アレイ |
| CN105122094B (zh) | 2012-11-01 | 2018-06-12 | 依视路国际公司 | 受热影响的可改变的着色装置 |
| US10091999B2 (en) | 2014-02-28 | 2018-10-09 | Kumiai Chemical Industry Co. | Agrochemical composition for foliage treatment |
| MX2020006837A (es) | 2017-12-27 | 2020-09-03 | Kumiai Chemical Industry Co | Metodo para producir un compuesto de sal de tiocarboxamidina. |
| JP7020680B2 (ja) | 2018-05-14 | 2022-02-16 | 哲雄 水谷 | パワフルバルーン |
| BR112021006842A2 (pt) | 2018-10-31 | 2021-07-13 | Kumiai Chemical Industry Co., Ltd. | composição de microcápsula, método de fabricação da mesma, formulação agroquímica compreendendo a mesma e controle de ervas daninhas |
| CN112996388B (zh) | 2018-10-31 | 2023-05-09 | 组合化学工业株式会社 | 微胶囊组合物及其制造方法、含有所述微胶囊组合物的农药制剂和杂草防治方法 |
| WO2020168997A1 (en) * | 2019-02-18 | 2020-08-27 | Dongguan Hec Tech R&D Co., Ltd. | Isoxazoline derivatives and their uses in agriculture |
| WO2020240392A1 (en) * | 2019-05-24 | 2020-12-03 | Pi Industries Limited | Process for preparation of pyroxasulfone |
| AR121018A1 (es) | 2020-01-15 | 2022-04-06 | Adama Agan Ltd | Forma en estado sólido de piroxasulfona |
| CN111393427B (zh) * | 2020-04-30 | 2021-11-30 | 安徽久易农业股份有限公司 | 一种砜吡草唑的合成方法 |
| CN111574511A (zh) * | 2020-06-28 | 2020-08-25 | 安徽久易农业股份有限公司 | 一种砜吡草唑的合成方法及其应用 |
-
2020
- 2020-10-30 CN CN202080003718.XA patent/CN112969697A/zh active Pending
- 2020-10-30 CA CA3156419A patent/CA3156419C/en active Active
- 2020-10-30 KR KR1020227018042A patent/KR102523028B1/ko active IP Right Grant
- 2020-10-30 MX MX2022005121A patent/MX2022005121A/es unknown
- 2020-10-30 JP JP2021511003A patent/JP6920572B2/ja active Active
- 2020-10-30 KR KR1020237012619A patent/KR20230053729A/ko active Search and Examination
- 2020-10-30 MY MYPI2022002277A patent/MY197145A/en unknown
- 2020-10-30 IL IL292532A patent/IL292532B1/en unknown
- 2020-10-30 TW TW109137876A patent/TWI826741B/zh active
- 2020-10-30 WO PCT/JP2020/040748 patent/WO2021002484A2/ja active Application Filing
- 2020-10-30 AU AU2020300922A patent/AU2020300922C1/en active Active
- 2020-10-30 CA CA3217505A patent/CA3217505A1/en active Pending
- 2020-10-30 BR BR122023000998A patent/BR122023000998A8/pt not_active Application Discontinuation
- 2020-10-30 EP EP20835297.1A patent/EP4053125A4/en active Pending
- 2020-10-30 TW TW112145647A patent/TW202413350A/zh unknown
- 2020-10-30 BR BR112022008144A patent/BR112022008144A2/pt active IP Right Grant
- 2020-10-30 US US17/773,227 patent/US20230012374A1/en active Pending
- 2020-10-30 CR CR20220306A patent/CR20220306A/es unknown
- 2020-10-30 IL IL311115A patent/IL311115A/en unknown
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2021
- 2021-07-26 JP JP2021121370A patent/JP2021178843A/ja active Pending
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2022
- 2022-04-28 MX MX2022015738A patent/MX2022015738A/es unknown
- 2022-05-27 ZA ZA2022/05942A patent/ZA202205942B/en unknown
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2023
- 2023-03-30 AU AU2023201945A patent/AU2023201945A1/en active Pending
- 2023-06-30 AU AU2023100062A patent/AU2023100062B4/en active Active
- 2023-06-30 AU AU2023100061A patent/AU2023100061B4/en active Active
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