IL271950B2 - Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2-one - Google Patents

Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2-one

Info

Publication number
IL271950B2
IL271950B2 IL271950A IL27195020A IL271950B2 IL 271950 B2 IL271950 B2 IL 271950B2 IL 271950 A IL271950 A IL 271950A IL 27195020 A IL27195020 A IL 27195020A IL 271950 B2 IL271950 B2 IL 271950B2
Authority
IL
Israel
Prior art keywords
mixture
solution
composition
crystalline form
crystalline
Prior art date
Application number
IL271950A
Other languages
English (en)
Hebrew (he)
Other versions
IL271950B1 (en
IL271950A (en
Original Assignee
Adama Makhteshim Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adama Makhteshim Ltd filed Critical Adama Makhteshim Ltd
Publication of IL271950A publication Critical patent/IL271950A/en
Publication of IL271950B1 publication Critical patent/IL271950B1/en
Publication of IL271950B2 publication Critical patent/IL271950B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/47One nitrogen atom and one oxygen or sulfur atom, e.g. cytosine
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00Fungicides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/13Crystalline forms, e.g. polymorphs

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Mycology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
IL271950A 2017-07-17 2018-07-16 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2-one IL271950B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762533509P 2017-07-17 2017-07-17
PCT/IB2018/000875 WO2019038583A1 (en) 2017-07-17 2018-07-16 5-FLUORO-4-IMINO-3-METHYL-1-TOSYL-3,4-DIHYDROPYRIMIDIN-2-ONE POLYMORPHS

Publications (3)

Publication Number Publication Date
IL271950A IL271950A (en) 2020-02-27
IL271950B1 IL271950B1 (en) 2024-02-01
IL271950B2 true IL271950B2 (en) 2024-06-01

Family

ID=63517924

Family Applications (5)

Application Number Title Priority Date Filing Date
IL271950A IL271950B2 (en) 2017-07-17 2018-07-16 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2-one
IL309708A IL309708B2 (en) 2017-07-17 2018-07-16 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one
IL323268A IL323268A (en) 2017-07-17 2025-09-10 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one
IL323267A IL323267A (en) 2017-07-17 2025-09-10 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one
IL323266A IL323266A (en) 2017-07-17 2025-09-10 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one

Family Applications After (4)

Application Number Title Priority Date Filing Date
IL309708A IL309708B2 (en) 2017-07-17 2018-07-16 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one
IL323268A IL323268A (en) 2017-07-17 2025-09-10 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one
IL323267A IL323267A (en) 2017-07-17 2025-09-10 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one
IL323266A IL323266A (en) 2017-07-17 2025-09-10 Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one

Country Status (11)

Country Link
US (1) US11632954B2 (https=)
EP (1) EP3655396A1 (https=)
JP (3) JP2020527563A (https=)
CN (2) CN118515619A (https=)
AR (1) AR112276A1 (https=)
AU (1) AU2018320492C1 (https=)
CA (1) CA3069619A1 (https=)
IL (5) IL271950B2 (https=)
MA (1) MA49639A (https=)
WO (1) WO2019038583A1 (https=)
ZA (1) ZA202000411B (https=)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PE20212103A1 (es) 2018-11-05 2021-11-04 Adama Makhteshim Ltd Mezclas y composiciones que comprenden 5-fluoro-4-imino-3-metil-1-tosil-3,4-dihidropirimidin-2-ona, y metodos de uso de los mismos
CN114901073A (zh) * 2019-07-22 2022-08-12 阿达马蒂斯有限公司 杀真菌组合、混合物和组合物及其用途
PY2057637A (es) * 2019-09-23 2021-10-05 Adama Makhteshim Ltd Proceso para preparar 5-(fluoro-4-imino-3-metil)-1-tosil-3,4-dihidropirimidin-(1h)-ona y derivados del compuesto
IL297864A (en) * 2020-05-04 2023-01-01 Adama Makhteshim Ltd Mixtures and compositions comprising 5-fluoro-4-imino-3- methyl-1-tosyl-3,4-dihydropyrimidin-2-one, and methods of use thereof
CA3206570A1 (en) 2021-01-27 2022-08-04 Alexandra ROSENMUND 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2(1 h)-one for controlling plant diseases
IL308155A (en) 2021-05-04 2024-01-01 Adama Makhteshim Ltd Crystalline forms of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one and mixtures, compositions and methods of using them
UY40172A (es) 2022-03-03 2023-10-13 Adama Makhteshim Ltd Combinaciones, mezclas y composiciones fungicidas y usos de las mismas
AU2023275068A1 (en) 2022-05-26 2024-11-28 Adama Makhteshim Ltd. Fungicidal combinations, mixtures and compositions and uses thereof
TW202412625A (zh) 2022-08-03 2024-04-01 以色列商安道麥馬克西姆有限公司 用於抗殺真菌劑真菌的5-氟-4-亞胺基-3-甲基-1-甲苯磺醯基-3,4-二氫嘧啶-2(1h)-酮
CN120882310A (zh) 2023-03-09 2025-10-31 安道麦马克西姆有限公司 杀真菌组合、混合物及组合物以及其用途
EP4680029A1 (en) 2023-03-14 2026-01-21 Adama Makhteshim Ltd. Liquid compositions containing 5-(fluoro-4-imino-3-methyl)-1-tosyl-3,4 dihydropyrimidine-(1h)-one and derivatives thereof and a uv absorber
AR132381A1 (es) 2023-04-11 2025-06-18 Adama Makhteshim Ltd Compuestos y procesos relativos a flumetilsulforim
WO2025046581A1 (en) 2023-08-31 2025-03-06 Adama Makhteshim Ltd. Fungicidal combinations, mixtures and compositions and uses thereo
PY24105707A (es) 2023-11-28 2025-06-25 Adama Makhteshim Ltd Combinaciones, mezclas y composiciones fungicidas y usos de las mismas
WO2026038217A1 (en) 2024-08-15 2026-02-19 Adama Makhteshim Ltd. Mixtures and compositions comprising flumetylsulforim and methods of use thereof
WO2026083410A1 (en) 2024-10-15 2026-04-23 Adama Makhteshim Ltd. Mixtures and composition comprising thereof
WO2026083211A1 (en) 2024-10-16 2026-04-23 Adama Makhteshim Ltd. Mixtures and composition comprising thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008093325A2 (en) * 2007-02-01 2008-08-07 Makhteshim Chemical Works Ltd. Polymorphs of 3-(e)-2-{2-[6-(2-cyanophenoxy) pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate
US20150183749A1 (en) * 2013-12-31 2015-07-02 Dow Agrosciences Llc 5-fluoro-4-imino-3-(alkyl/substituted alkyl)-1-(arylsulfonyl)-3,4-dihydropyrimidin-2(1h)-one and processes for their preparation
WO2016106138A1 (en) * 2014-12-23 2016-06-30 Dow Agrosciences Llc 5-fluoro-4-imino-3-(alkyl/substituted alkyl)-1-(arylsulfonyl)-3,4-dihydropyrimidin-2(1h)-one as a seed treatment

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3309359A (en) 1965-10-22 1967-03-14 Hoffmann La Roche N-mono-acyl-5-fluorocytosine derivatives and process
US3368938A (en) 1966-01-13 1968-02-13 Hoffmann La Roche Controlling fungi with 5-fluorocytosine
US3635977A (en) 1969-11-03 1972-01-18 American Cyanamid Co Certain 6-trifluoromethylcytosines and thiocytosines their synthesis and their use in the synthesis of uracisls and thiouracil
US3868373A (en) 1970-01-27 1975-02-25 Hoffmann La Roche 4-Amino-5-fluoro-2-tri(lower alkyl) silyloxypyrimidines
US4009272A (en) 1971-10-23 1977-02-22 Bayer Aktiengesellschaft Penicillins
US4845081A (en) 1984-10-18 1989-07-04 University Of Florida Aminomethyl derivatives of biologically active substances, and enhanced delivery thereof across topical membranes
DE3821711A1 (de) 1988-06-28 1990-02-08 Bayer Ag Thiazolopyrimidin-derivate, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel
JP3217191B2 (ja) 1992-07-16 2001-10-09 ビーエーエスエフ アクチェンゲゼルシャフト ヘテロ芳香族化合物およびこれを含有する植物保護剤
JP4010563B2 (ja) 1995-07-05 2007-11-21 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー 殺菌・殺カビ性のピリミジノン類
GT199900185A (es) 1998-11-06 2001-04-18 Novedosa pirimidin-4-enamina como fungicida.
WO2003018051A1 (en) 2001-08-27 2003-03-06 Vic Jira Anti-fungal composition
JPWO2005095419A1 (ja) 2004-04-01 2008-02-21 武田薬品工業株式会社 チアゾロピリミジン誘導体
JP4887500B2 (ja) 2004-09-16 2012-02-29 国立大学法人岐阜大学 ヌクレオシド類似体またはその塩
PT1909579E (pt) 2005-07-27 2016-02-10 Basf Se Misturas fungicidas com base em azolopirimidinilaminas
TWI402034B (zh) 2005-07-28 2013-07-21 Dow Agrosciences Llc 具有被層狀液晶覆膜包覆之油球之水包油乳化劑之農用組成物
IL172137A0 (en) * 2005-11-23 2006-04-10 Maktheshim Chemical Works Ltd Process for prep aring pyridinamines
US20080004253A1 (en) 2006-06-30 2008-01-03 Bryan James Branstetter Thiazolopyrimidine modulators of TRPV1
US20100029483A1 (en) 2006-10-16 2010-02-04 Rhodia Inc. Agricultural adjuvant compositions, pesticide compositions, and methods for using such compositions
US8093245B2 (en) 2006-12-14 2012-01-10 Lexicon Pharmaceuticals, Inc. 4-amino-1H-pyrimidin-2-one based compounds, compositions comprising them and methods of their use
MX2009008531A (es) 2007-02-16 2009-08-26 Amgen Inc Cetonas de heterociclilo que contienen nitrogeno y su uso como inhibidores de c-met.
EP2562163A1 (en) 2008-01-22 2013-02-27 Dow AgroSciences LLC 5-fluoro pyrimidine derivatives as fungicides
US20100284959A1 (en) 2008-01-23 2010-11-11 Gene Arrest Ltd. Sequence specific double-stranded dna/rna binding compounds and uses thereof
KR20110042204A (ko) 2008-08-01 2011-04-25 다우 아그로사이언시즈 엘엘씨 살진균제로서의 5-플루오로시토신의 용도
WO2010145999A2 (de) 2009-06-18 2010-12-23 Basf Se Fungizide mischungen
BR112012002807B1 (pt) 2009-08-07 2018-07-10 Adama Makhteshim Ltd. Derivados de 5-flúor-2-oxopirimidina-1(2h)- caboxilato, composição e processo para controle e prevenção de ataque fúngico em uma planta de ataque fúngico em uma planta
UA106889C2 (uk) 2009-08-07 2014-10-27 ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі Похідні n1-ацил-5-фторпіримідинону
UA112284C2 (uk) 2009-08-07 2016-08-25 ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі Похідні 5-фторпіримідинону
UA107671C2 (en) 2009-08-07 2015-02-10 Dow Agrosciences Llc N1-substityted-5-fluoro-2-oxopyrimidinone-1(2h)-carboxamide derivatives
DK2462134T3 (da) 2009-08-07 2014-08-11 Dow Agrosciences Llc N1-sulfonyl-5-fluorpyrimidinonderivater
WO2011043876A1 (en) 2009-10-07 2011-04-14 Dow Agrosciences Llc Synergistic fungicidal composition containing 5-fluorocytosine for fungal control in cereals
PL2563129T3 (pl) 2010-04-26 2017-08-31 Adama Makhteshim Ltd N3-podstawione pochodne n1-sulfonylo-5-fluoropirymidynonu
US20120208700A1 (en) 2011-02-11 2012-08-16 Dow Agrosciences Llc Stable agrochemical oil dispersions
SI2775842T1 (en) 2011-08-17 2018-01-31 Adama Makhteshim Ltd. 1-substituted-5-fluoro-3,6-dihydro-6-imino-2 (1H) -pyrimidinone derivatives as fungicidal agents for use in plant protection
RU2018118951A (ru) 2012-12-28 2018-11-02 Адама Мактешим Лтд. Производные 1-(замещенный бензоил)-5-фтор-4-имино-3-метил-3,4-дигидропиримидин-2(1h)-она
KR20150100869A (ko) 2012-12-28 2015-09-02 다우 아그로사이언시즈 엘엘씨 N-(치환된)-5-플루오로-4-이미노-3-메틸-2-옥소-3,4-디히드로피리미딘-1(2h)-카르복스아미드 유도체
CN105007737A (zh) 2012-12-31 2015-10-28 美国陶氏益农公司 作为杀真菌剂的3-烷基-5-氟-4-取代的-亚氨基-3,4-二氢嘧啶-2(1h)-酮衍生物
TWI652012B (zh) * 2013-05-20 2019-03-01 杜邦股份有限公司 殺真菌吡唑的固態形式
CN114794123B (zh) 2013-12-31 2024-11-12 阿达玛马克西姆股份有限公司 用防治谷类中真菌的协同杀真菌混合物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008093325A2 (en) * 2007-02-01 2008-08-07 Makhteshim Chemical Works Ltd. Polymorphs of 3-(e)-2-{2-[6-(2-cyanophenoxy) pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate
US20150183749A1 (en) * 2013-12-31 2015-07-02 Dow Agrosciences Llc 5-fluoro-4-imino-3-(alkyl/substituted alkyl)-1-(arylsulfonyl)-3,4-dihydropyrimidin-2(1h)-one and processes for their preparation
WO2016106138A1 (en) * 2014-12-23 2016-06-30 Dow Agrosciences Llc 5-fluoro-4-imino-3-(alkyl/substituted alkyl)-1-(arylsulfonyl)-3,4-dihydropyrimidin-2(1h)-one as a seed treatment

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CAIRA ED - MONTCHAMP JEAN-LUC,, CRYSTALLINE POLYMORPHISM OF ORGANIC COMPOUNDS, 31 December 1998 (1998-12-31) *
HARWOOD L M ET AL, EXPERIMENTAL ORGANIC CHEMISTRY - PRINCIPLES AND PRACTI, 31 December 1989 (1989-12-31) *

Also Published As

Publication number Publication date
NZ761039A (en) 2023-09-29
CA3069619A1 (en) 2019-02-28
CN111094252A (zh) 2020-05-01
WO2019038583A1 (en) 2019-02-28
IL271950B1 (en) 2024-02-01
ZA202000411B (en) 2023-10-25
IL309708B1 (en) 2025-10-01
IL271950A (en) 2020-02-27
CN111094252B (zh) 2024-05-24
AR112276A1 (es) 2019-10-09
IL323266A (en) 2025-11-01
MA49639A (fr) 2020-05-27
BR112020000953A2 (pt) 2020-07-14
AU2018320492A1 (en) 2020-02-13
IL323267A (en) 2025-11-01
EP3655396A1 (en) 2020-05-27
JP2025163080A (ja) 2025-10-28
IL309708A (en) 2024-02-01
AU2018320492B2 (en) 2022-12-01
CN118515619A (zh) 2024-08-20
JP2020527563A (ja) 2020-09-10
IL323268A (en) 2025-11-01
JP2023145572A (ja) 2023-10-11
US20200229437A1 (en) 2020-07-23
AU2018320492C1 (en) 2023-07-13
US11632954B2 (en) 2023-04-25
IL309708B2 (en) 2026-02-01

Similar Documents

Publication Publication Date Title
IL323268A (en) Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-4,3-dihydropyrimidin-2-one
CA3181785A1 (en) Solid state forms of cyantraniliprole
EP1072598B9 (en) Pyrazolinone derivatives
EP4655281A2 (en) Fungicidal aryl amidines
CN112638884A (zh) 三唑磺酰胺衍生物及其制备方法和应用
CN108368047B (zh) 啶氧菌酯的晶型、其制备方法及用途
NZ761039B2 (en) Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2-one
US8580835B2 (en) Solid forms of a microbiocide
HK40115262A (zh) 5-氟-4-亚氨基-3-甲基-1-甲苯磺醯基-3,4-二氢嘧啶-2-酮的多晶型物
BR122024007351A2 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-dihidropirimidin-2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR122024007342A2 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-dihidropirimidin-2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR122024007345A2 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-dihidropirimidin-2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR122024007345B1 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-di-hidropirimidin- 2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR122024007349B1 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-di-hidropirimidin- 2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR122024007349A2 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-dihidropirimidin-2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR122024007351B1 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-di-hidropirimidin- 2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR122024007342B1 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-dihidropirimidin- 2-ona, misturas, composição, métodos para o controle de ataque fúngico e processos para a preparação da forma cristalina e da composição fungicida
BR112020000953B1 (pt) Forma cristalina de 5-fluoro-4-imino-3-metil-1-tosil-3,4-dihidropirimidin- 2-ona, sua composição, seu processo de preparação e métodos para o controle de ataque fúngico
CN104364252A (zh) 丙炔氟草胺的晶体
JP2003231672A (ja) オキシム型化合物又はその塩類及び農園芸用殺菌剤
CN112442018A (zh) 三唑-1,3-二磺酰胺衍生物及其在农业中的应用
WO2020174432A1 (en) Dioxane solvate of prothioconazole and process for preparation thereof