IL241516B - Polymerization is combined with an assembly process - Google Patents

Polymerization is combined with an assembly process

Info

Publication number
IL241516B
IL241516B IL241516A IL24151615A IL241516B IL 241516 B IL241516 B IL 241516B IL 241516 A IL241516 A IL 241516A IL 24151615 A IL24151615 A IL 24151615A IL 241516 B IL241516 B IL 241516B
Authority
IL
Israel
Prior art keywords
compounding process
polymerization coupled
polymerization
coupled compounding
coupled
Prior art date
Application number
IL241516A
Other languages
English (en)
Hebrew (he)
Other versions
IL241516A0 (en
Original Assignee
Ascend Performance Mat Operations Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ascend Performance Mat Operations Llc filed Critical Ascend Performance Mat Operations Llc
Publication of IL241516A0 publication Critical patent/IL241516A0/en
Publication of IL241516B publication Critical patent/IL241516B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/201Pre-melted polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/29Feeding the extrusion material to the extruder in liquid form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/04Preparatory processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/28Preparatory processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/46Post-polymerisation treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24Homopolymers or copolymers of amides or imides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B29C48/402Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders the screws having intermeshing parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/505Screws
    • B29C48/625Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/76Venting, drying means; Degassing means
    • B29C48/765Venting, drying means; Degassing means in the extruder apparatus
    • B29C48/766Venting, drying means; Degassing means in the extruder apparatus in screw extruders
    • B29C48/767Venting, drying means; Degassing means in the extruder apparatus in screw extruders through a degassing opening of a barrel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0002Condition, form or state of moulded material or of the material to be shaped monomers or prepolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0094Condition, form or state of moulded material or of the material to be shaped having particular viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyamides (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Fertilizers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
IL241516A 2013-03-15 2015-09-10 Polymerization is combined with an assembly process IL241516B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361798641P 2013-03-15 2013-03-15
PCT/US2014/026353 WO2014151735A1 (en) 2013-03-15 2014-03-13 Polymerization coupled compounding process

Publications (2)

Publication Number Publication Date
IL241516A0 IL241516A0 (en) 2015-11-30
IL241516B true IL241516B (en) 2019-07-31

Family

ID=51581026

Family Applications (1)

Application Number Title Priority Date Filing Date
IL241516A IL241516B (en) 2013-03-15 2015-09-10 Polymerization is combined with an assembly process

Country Status (14)

Country Link
US (4) US10081712B2 (enExample)
EP (1) EP2970602A4 (enExample)
JP (2) JP6810605B2 (enExample)
KR (2) KR102336268B1 (enExample)
CN (1) CN105246950A (enExample)
AR (1) AR095572A1 (enExample)
BR (1) BR112015022610A2 (enExample)
CA (1) CA2907103C (enExample)
HK (1) HK1213931A1 (enExample)
IL (1) IL241516B (enExample)
SA (1) SA515361172B1 (enExample)
SG (1) SG11201507449WA (enExample)
TW (1) TWI619597B (enExample)
WO (1) WO2014151735A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11440231B2 (en) * 2016-08-23 2022-09-13 Basf Se Process for the preparation of a reinforced polyamide by extrusion
CN111225940B (zh) 2017-09-28 2023-10-10 杜邦聚合物公司 聚合方法

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GB998063A (en) 1963-02-18 1965-07-14 Du Pont Process and apparatus for the extrusion of fusible polymers
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DE1694348C3 (de) * 1967-11-21 1975-09-25 Enka Glanzstoff Ag, 5600 Wuppertal Verfahren zum kontinuierlichen Einmischen einer Pigmentdispersion in eine Polyamidschmelze
US3523331A (en) 1968-07-30 1970-08-11 Du Pont Canada Heated extrusion vent port monitoring window
US3846381A (en) 1973-05-16 1974-11-05 Du Pont Improved process for continuously producing polyhexamethylene adipamide by carrying out water removal step in a formic acid vapor containing atmosphere
US4065532A (en) 1974-04-11 1977-12-27 Basf Aktiengesellschaft Process for the admixture of additives into plastics with simultaneous removal of volatile constituents
DE3310676A1 (de) * 1983-03-24 1984-09-27 Basf Ag, 6700 Ludwigshafen Verfahren und vorrichtung zum entfernen von fluechtigen anteilen aus polymerenschmelzen oder paste
US5169582A (en) 1985-05-08 1992-12-08 Ems-Inventa Ag Method and apparatus for the production of thermoplastic caprolactam containing molding compositions
US4958006A (en) 1988-06-28 1990-09-18 Union Carbide Chemicals And Plastics Inc. Fluidized bed product discharge process
CA1338025C (en) 1988-08-29 1996-01-30 Andri Elia Elia Toughened nylons characterized by low mold deposit
US5236645A (en) 1990-09-21 1993-08-17 Basf Corporation Addition of additives to polymeric materials
CA2050612A1 (en) 1990-09-21 1992-03-22 Keith Gannon Addition of additives to polymeric materials
DE4039857A1 (de) 1990-10-19 1992-04-23 Inventa Ag Verfahren und vorrichtung zur direkten, kontinuierlichen modifizierung von polymerschmelzen
US5236652A (en) 1992-02-11 1993-08-17 E. I. Du Pont De Nemours And Company Process for making polyamide fiber useful as staple for papermaking machine felt
US5403910A (en) 1993-03-25 1995-04-04 E. I. Du Pont De Nemours & Company Low temperature nylon polymerization process
JPH07242817A (ja) 1994-03-04 1995-09-19 Showa Denko Kk ポリアミド樹脂組成物
US5502154A (en) 1994-11-30 1996-03-26 E. I. Du Pont De Nemours And Company Apparatus for processing materials
US5968429A (en) * 1997-03-20 1999-10-19 Eastman Chemical Company Apparatus and method for molding of polyester articles directly from a melt
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NL1007767C2 (nl) 1997-12-11 1999-06-14 Dsm Nv Werkwijze voor de bereiding van een polyamide nanocomposiet samenstelling.
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JP4953629B2 (ja) 2003-03-28 2012-06-13 Psジャパン株式会社 スチレン系難燃樹脂組成物
DE10356821A1 (de) 2003-12-05 2005-07-07 Bayer Materialscience Ag Verfahren zur Mischung von Polymerschmelzen mit Additiven
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US7132498B2 (en) * 2004-09-27 2006-11-07 General Electric Company Process to make polycarbonate from bismethylsalicylcarbonate (BMSC)
US7931842B2 (en) 2004-11-08 2011-04-26 Chemlink Capital Ltd. System and method for making sheets, films, and objects directly from polymerization processes
US20060118989A1 (en) 2004-12-07 2006-06-08 3M Innovative Properties Company Method of making composite material
DE102005051400A1 (de) 2005-10-25 2007-04-26 Basf Ag Polyamide aus meta-Xylylendiamin und Adipinsäure mit einem Aminoendgruppengehalt kleiner als 15 mmol/kg
CN101405329B (zh) 2006-03-13 2012-11-14 旭化成化学株式会社 玻璃纤维增强聚酰胺树脂组合物的制造方法
US20080009576A1 (en) 2006-06-30 2008-01-10 Alexander Charles W Process for manufacturing of thermoplastic composites with improved properties
DE102007029010A1 (de) 2006-08-26 2008-02-28 Bayer Materialscience Ag Verfahren zum Compoundieren von Polymeren
MX2010004009A (es) 2007-10-17 2010-04-27 Invista Tech Sarl Preparacion de filamentos de poliamida de muy alto peso molecular.
JP2009114429A (ja) * 2007-10-19 2009-05-28 Toray Ind Inc ポリアミドの連続製造方法
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PL2315794T3 (pl) 2008-08-14 2019-07-31 Basf Se Okresowy sposób wytwarzania poliamidów
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US20110015328A1 (en) 2009-07-17 2011-01-20 E.I.Du Pont De Nemours And Company Semi aromatic polyamide resin compositions, processes for their manufacture, and articles thereof
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Also Published As

Publication number Publication date
WO2014151735A1 (en) 2014-09-25
KR20150138255A (ko) 2015-12-09
JP2016512281A (ja) 2016-04-25
TW201438875A (zh) 2014-10-16
US10590245B2 (en) 2020-03-17
EP2970602A1 (en) 2016-01-20
IL241516A0 (en) 2015-11-30
US10077341B2 (en) 2018-09-18
JP6810605B2 (ja) 2021-01-06
JP6925378B2 (ja) 2021-08-25
AR095572A1 (es) 2015-10-28
CA2907103C (en) 2021-06-29
BR112015022610A2 (pt) 2017-07-18
CA2907103A1 (en) 2014-09-25
US20190177495A1 (en) 2019-06-13
EP2970602A4 (en) 2016-12-21
US10081712B2 (en) 2018-09-25
KR102336268B1 (ko) 2021-12-07
US11447609B2 (en) 2022-09-20
TWI619597B (zh) 2018-04-01
US20160319084A1 (en) 2016-11-03
US20200277452A1 (en) 2020-09-03
HK1213931A1 (zh) 2016-07-15
SG11201507449WA (en) 2015-10-29
CN105246950A (zh) 2016-01-13
JP2019131817A (ja) 2019-08-08
SA515361172B1 (ar) 2019-05-02
KR20210024235A (ko) 2021-03-04
US20160046766A1 (en) 2016-02-18

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