HUP0402518A2 - Eljárás vinil-klorid polimerizációjára nagyon gyors iniciátorok folyamatos adagolásával és a kapott vinil-klorid (ko)polimer - Google Patents

Eljárás vinil-klorid polimerizációjára nagyon gyors iniciátorok folyamatos adagolásával és a kapott vinil-klorid (ko)polimer

Info

Publication number
HUP0402518A2
HUP0402518A2 HU0402518A HUP0402518A HUP0402518A2 HU P0402518 A2 HUP0402518 A2 HU P0402518A2 HU 0402518 A HU0402518 A HU 0402518A HU P0402518 A HUP0402518 A HU P0402518A HU P0402518 A2 HUP0402518 A2 HU P0402518A2
Authority
HU
Hungary
Prior art keywords
polymerization
polymer
vinyl chloride
initiators
during polymerization
Prior art date
Application number
HU0402518A
Other languages
English (en)
Inventor
Hans Westmijze
Andreas Petrus Swieten
Lambertus Meulenbrugge
Koen Antoon Kornelis Vanduffel
Original Assignee
Akzo Nobel N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel N.V. filed Critical Akzo Nobel N.V.
Publication of HUP0402518A2 publication Critical patent/HUP0402518A2/hu
Publication of HUP0402518A3 publication Critical patent/HUP0402518A3/hu
Publication of HU229861B1 publication Critical patent/HU229861B1/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C08F4/38—Mixtures of peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Polyethers (AREA)

Abstract

A találmány tárgya vinil-klorid monomer polimerizációs vagykopolimerizációs eljárás nagyon rövid félértékidejű ún. <extrém gyorsiniciátorok< alkalmazásával. A találmány szerinti eljárást vinil-klorid monomer (VCM) és adott esetben további monomerekpolimerizációjára egy vagy több iniciátort alkalmazva úgy hajtjákvégre, hogy a polimerizálandó reakcióelegybez hozzáadott iniciátoroklegelább egy része egy olyan szerves iniciátor, melynek félértékideje0,0001-0,050 óra a polimerizáció hömérsékletén, és ezt apolimerizálási reakcióhoz az említett polimerizációs hőmérsékletenadják. A találmány további tárgyai (1) vinil-klorid-alapú (ko)polimer,amely a fenti eljárással állítható elő, és amely kevesebb mint 50 ppmmaradék iniciátort tartalmaz a (ko)polimerre vonatkoztatva, amennyibenközvetlenül a polimerizáció és az azt követő egy egyórás 60 °C-os(ko)polimer szárítás után mérik, valamint (2) a vinil-klorid(ko)polimer alkalmazása egy formaadási eljárásban, amely szerint a(ko)polimert az olvadási hőmérséklete fölé melegítik. Ó
HU0402518A 2001-12-21 2002-12-18 Continuous dosing of extremely fast initiators during polymerization reactions HU229861B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34243401P 2001-12-21 2001-12-21
PCT/EP2002/014518 WO2003054040A1 (en) 2001-12-21 2002-12-18 Continuous dosing of extremely fast initiators during polymerization reactions

Publications (3)

Publication Number Publication Date
HUP0402518A2 true HUP0402518A2 (hu) 2005-03-29
HUP0402518A3 HUP0402518A3 (en) 2008-06-30
HU229861B1 HU229861B1 (en) 2014-10-28

Family

ID=23341807

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0402518A HU229861B1 (en) 2001-12-21 2002-12-18 Continuous dosing of extremely fast initiators during polymerization reactions

Country Status (21)

Country Link
US (2) US20050054795A1 (hu)
EP (1) EP1456256A1 (hu)
JP (1) JP4508644B2 (hu)
KR (1) KR20040068290A (hu)
CN (1) CN1254491C (hu)
AR (1) AR037953A1 (hu)
AU (1) AU2002358763A1 (hu)
BR (1) BR0215232A (hu)
CA (1) CA2470839C (hu)
CO (1) CO5590965A2 (hu)
HU (1) HU229861B1 (hu)
IL (1) IL162624A0 (hu)
MX (1) MXPA04006137A (hu)
MY (1) MY154482A (hu)
NO (1) NO20043103L (hu)
PL (1) PL206298B1 (hu)
RU (1) RU2286353C2 (hu)
TW (1) TWI302152B (hu)
UA (2) UA77245C2 (hu)
WO (1) WO2003054040A1 (hu)
ZA (1) ZA200405781B (hu)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050080207A1 (en) * 2001-12-21 2005-04-14 Akzo Nobel N.V. Addition of organic initiators during the pressure drop In vinyl chloride monomer polymerization reactions
TW200424217A (en) * 2003-05-01 2004-11-16 Akzo Nobel Nv Increased polymerization reactor output by using a specific initiating system
EP1636272B2 (en) 2003-06-20 2011-08-17 Akzo Nobel N.V. Polymerization process involving the dosing initiators
CN101405308B (zh) 2006-03-24 2012-02-15 阿克佐诺贝尔股份有限公司 制备氯乙烯（共）聚合物的连续方法
US8466246B2 (en) 2006-03-24 2013-06-18 Akzo Nobel N.V. Continuous process for the production of vinyl chloride (co)polymers
SG177701A1 (en) 2009-08-06 2012-02-28 Akzo Nobel Chemicals Int Bv Storage stable and safe peroxide emulsions with a high active oxygen content
KR101303515B1 (ko) 2010-03-03 2013-09-03 주식회사 엘지화학 중합 생산성이 우수한 염화비닐계 수지의 현탁 중합방법
AR081664A1 (es) 2010-06-30 2012-10-10 Akzo Nobel Chemicals Int Bv Proceso de polimerizacion con formacion in-situ del iniciador
WO2019212217A1 (ko) 2018-04-30 2019-11-07 주식회사 엘지화학 염화비닐 중합체 및 이의 제조방법
KR102251268B1 (ko) 2018-04-30 2021-05-12 주식회사 엘지화학 염화비닐 중합체 및 이의 제조방법
CN114181336A (zh) * 2021-12-16 2022-03-15 安徽天辰化工股份有限公司 一种超小粒径pvc种子及其制备方法
WO2024047407A1 (en) * 2022-09-01 2024-03-07 Braskem S.A. Continuous process for polymerization of vinyl chloride in a tubular reactor

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2133113A5 (hu) 1971-04-08 1972-11-24 Rhone Progil
US4125695A (en) 1977-01-06 1978-11-14 Pennwalt Corporation Polymerization process with reduced cycle time employing polyfunctional free radical initiators
AU7557981A (en) 1980-10-13 1982-04-22 Ici Australia Limited Polymerisation of vinyl chloride
EP0095860B1 (en) 1982-06-01 1986-10-01 Ici Australia Limited Polymerisation of vinyl chloride monomer
EP0096365A1 (en) * 1982-06-07 1983-12-21 Air Products And Chemicals, Inc. Shortened reaction cycle times in vinyl chloride-propylene copolymerization
US4705888A (en) 1985-09-30 1987-11-10 Akzo Nv t-Alkenyl peroxy esters
NO166329C (no) * 1986-01-22 1991-07-03 Atochem Vinylklorid-kopolymer og deres fremstilling.
SE457448B (sv) 1986-12-08 1988-12-27 Kenobel Ab Dialkylestrar av monoperoxioxalsyra, deras framstaellning och anvaendning som polymerisationsinitiatorer
EP0492712A1 (en) * 1990-12-24 1992-07-01 Akzo Nobel N.V. Peroxide compositions with ethoxylated water-soluble polymers
JPH0782304A (ja) * 1993-09-13 1995-03-28 Shin Etsu Chem Co Ltd 塩化ビニル系重合体の製造方法
ES2306526T3 (es) * 1998-09-21 2008-11-01 Akzo Nobel N.V. Dosificacion en continuo de iniciadores muy rapidos en reacciones de polimerizacion.
US20050080207A1 (en) * 2001-12-21 2005-04-14 Akzo Nobel N.V. Addition of organic initiators during the pressure drop In vinyl chloride monomer polymerization reactions

Also Published As

Publication number Publication date
ZA200405781B (en) 2005-08-26
TWI302152B (en) 2008-10-21
KR20040068290A (ko) 2004-07-30
RU2004122393A (ru) 2005-03-27
CO5590965A2 (es) 2005-12-30
PL206298B1 (pl) 2010-07-30
UA77245C2 (uk) 2006-11-15
MXPA04006137A (es) 2004-11-01
WO2003054040A1 (en) 2003-07-03
JP4508644B2 (ja) 2010-07-21
CN1254491C (zh) 2006-05-03
CA2470839A1 (en) 2003-07-03
JP2005513216A (ja) 2005-05-12
HU229861B1 (en) 2014-10-28
NO20043103L (no) 2004-07-20
UA76570C2 (uk) 2006-08-15
AR037953A1 (es) 2004-12-22
US8367784B2 (en) 2013-02-05
AU2002358763A1 (en) 2003-07-09
PL370171A1 (en) 2005-05-16
BR0215232A (pt) 2004-11-16
RU2286353C2 (ru) 2006-10-27
CN1606576A (zh) 2005-04-13
US20050054795A1 (en) 2005-03-10
CA2470839C (en) 2011-08-09
US20110046328A1 (en) 2011-02-24
MY154482A (en) 2015-06-30
HUP0402518A3 (en) 2008-06-30
TW200305578A (en) 2003-11-01
IL162624A0 (en) 2005-11-20
EP1456256A1 (en) 2004-09-15

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Legal Events

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GB9A Succession in title

Owner name: AKZO NOBEL CHEMICALS INTERNATIONAL B.V., NL

Free format text: FORMER OWNER(S): AKZO NOBEL N.V., NL

FH91 Appointment of a representative

Free format text: FORMER REPRESENTATIVE(S): SBGK SZABADALMI UEGYVIVOEI IRODA, HU

Representative=s name: DANUBIA SZABADALMI ES JOGI IRODA KFT., HU

FH92 Termination of representative

Representative=s name: SBGK SZABADALMI UEGYVIVOEI IRODA, HU