HUP0401502A2 - Peszticid hatású 4"-dezoxi-4"-(S)-amino avermektinszármazékok, előállításuk és alkalmazásuk - Google Patents
Peszticid hatású 4"-dezoxi-4"-(S)-amino avermektinszármazékok, előállításuk és alkalmazásukInfo
- Publication number
- HUP0401502A2 HUP0401502A2 HU0401502A HUP0401502A HUP0401502A2 HU P0401502 A2 HUP0401502 A2 HU P0401502A2 HU 0401502 A HU0401502 A HU 0401502A HU P0401502 A HUP0401502 A HU P0401502A HU P0401502 A2 HUP0401502 A2 HU P0401502A2
- Authority
- HU
- Hungary
- Prior art keywords
- group
- optionally substituted
- alkyl
- alkenyl
- optionally
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title abstract 3
- 230000000361 pesticidal effect Effects 0.000 title 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 6
- 229910052799 carbon Inorganic materials 0.000 abstract 3
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 3
- 229910052717 sulfur Inorganic materials 0.000 abstract 3
- 125000004434 sulfur atom Chemical group 0.000 abstract 3
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 2
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 abstract 2
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 abstract 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 abstract 1
- -1 SH group Chemical group 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 125000004450 alkenylene group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000005647 linker group Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 150000003839 salts Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H19/00—Compounds containing a hetero ring sharing one ring hetero atom with a saccharide radical; Nucleosides; Mononucleotides; Anhydro-derivatives thereof
- C07H19/01—Compounds containing a hetero ring sharing one ring hetero atom with a saccharide radical; Nucleosides; Mononucleotides; Anhydro-derivatives thereof sharing oxygen
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Veterinary Medicine (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Tropical Medicine & Parasitology (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Saccharide Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
A jelen találmány tárgya (I) általános képletű vegyületek, amelyek a4"-helyzetben (S)-konfigurációjúak, és amely képletben R1 jelentése 1-12 szénatomos alkil-, 3-8 szénatomos cikloalkil- vagy 2-12 szénatomosalkenilcsoport; R2 jelentése hidrogénatom, adott esetbenhelyettesített 1-12 szénatomos alkilcsoport, vagy adott esetbenhelyettesített 2-12 szénatomos alkenilcsoport; R3 jelentése adottesetben helyettesített 1-12 szénatomos alkilcsoport, adott esetben 1-12 szénatomos alkoxicsoporttal helyettesített 1-12 szénatomosalkilcsoport, adott esetben helyettesített 3-12 szénatomoscikloalkilcsoport, adott esetben helyettesített 2-12 szénatomosalkenilcsoport; adott esetben helyettesített 4-12 szénatomoscikloalkenil-csoport, adott esetben helyettesített 2-12 szénatomosalkinilcsoport; vagy R2 és R3 együtt három-héttagú alkilén- vagy négy-héttagú alkenilén összekötő csoportot alkotnak, amelyek mindegyike egyCH2-csoport helyett oxigénatomot, kénatomot vagy NR4 képletű csoportottartalmazhat; X jelentése oxigénatom vagy kénatom; Z jelentése kötés,oxigénatom, NR8 képletű csoport vagy kénatom; R4 jelentése 1-8szénatomos alkil-, 3-8 szénatomos cikloalkil-, 2-8 szénatomosalkenil-, 2-8 szénatomos alkinil-, benzil- vagy C(=O)-R5 képletűcsoport; R5 jelentése például hidrogénatom, OH-csoport, SH-csoport, 1-12 szénatomos alkilcsoport, 2-8 szénatomos alkenilcsoport, 2-8szénatomos alkinililcsoport, vagy halogénatommal helyettesített 1-12szénatomos alkilcsoport, és adott esetben azok E/Z izomerjei, az E/Zizomerek keverékei és/vagy tautomerjei (minden esetben szabad formábanvagy só alakjában); A jelen találmány tárgya továbbá peszticidkészítmények, amelyekben az aktív összetevő (I) általános képletűvegyület, vagy annak tautomerje, továbbá eljárás ilyen készítményekalkalmazására kártevőirtásnál. Ó
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH15982001 | 2001-08-28 | ||
| PCT/EP2002/009315 WO2003020738A1 (en) | 2001-08-28 | 2002-08-20 | 4'-deoxy-4'-(s)-amino avermectin derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HUP0401502A2 true HUP0401502A2 (hu) | 2004-12-28 |
| HUP0401502A3 HUP0401502A3 (en) | 2005-10-28 |
Family
ID=4565605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU0401502A HUP0401502A3 (en) | 2001-08-28 | 2002-08-20 | Pesticidal 4"-deoxy-4"-(s)-amino avermectin derivatives, preparation and use thereof |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US7605134B2 (hu) |
| EP (1) | EP1421094B1 (hu) |
| JP (1) | JP2005504068A (hu) |
| KR (1) | KR20040029456A (hu) |
| CN (1) | CN1549819A (hu) |
| AR (1) | AR036486A1 (hu) |
| AT (1) | ATE411331T1 (hu) |
| BR (1) | BR0212138A (hu) |
| CA (1) | CA2457683A1 (hu) |
| CO (1) | CO5560615A2 (hu) |
| CY (1) | CY1109410T1 (hu) |
| DE (1) | DE60229402D1 (hu) |
| DK (1) | DK1421094T3 (hu) |
| EG (1) | EG23706A (hu) |
| ES (1) | ES2315398T3 (hu) |
| HU (1) | HUP0401502A3 (hu) |
| IL (1) | IL160433A0 (hu) |
| MX (1) | MXPA04001814A (hu) |
| PL (1) | PL367797A1 (hu) |
| PT (1) | PT1421094E (hu) |
| RU (1) | RU2004109165A (hu) |
| WO (1) | WO2003020738A1 (hu) |
| ZA (1) | ZA200401107B (hu) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EG23124A (en) | 2001-02-27 | 2004-04-28 | Syngenta Participations Ag | Avermectins substituted in the 4-position having pesticidal properties |
| CR6574A (es) | 2001-02-27 | 2004-10-28 | Syngenta Participations Ag | Sales de avermectinas substituidas en la posicion 4 con propiedades plaguicidas |
| AR036486A1 (es) | 2001-08-28 | 2004-09-15 | Syngenta Participations Ag | Derivados 4"-desoxi-4"-(s)-amino avermectina, composicion plaguicida, procedimiento para la preparacion de esa composicion, metodo para controlar plagas, y uso de estos derivados para preparar una composicion |
| AR040073A1 (es) * | 2002-05-07 | 2005-03-16 | Syngenta Participations Ag | Derivados de 4''-desoxi-4''-(s)-amido avermectina y su uso como plaguicidas |
| GB0302308D0 (en) | 2003-01-31 | 2003-03-05 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide derivatives substituted in the 4"- or 4'-position having pesticidal properties |
| GB0302310D0 (en) | 2003-01-31 | 2003-03-05 | Syngenta Participations Ag | Avermectin- and avermectin monosaccharide derivatives substituted in the 4"- or 4' - positionhaving pesticidal properties |
| GB0320176D0 (en) | 2003-08-28 | 2003-10-01 | Syngenta Participations Ag | Avermectins and avermectin monosaccharides substitued in the 4'-and 4"-positionhaving pesticidal properties |
| PL2568980T3 (pl) | 2010-05-12 | 2016-05-31 | Merial Inc | Pasożytobójcze preparaty lewamizolu i laktonów makrocyklicznych do wstrzykiwania |
| WO2012078605A1 (en) | 2010-12-07 | 2012-06-14 | Merial Limited | Topical combination formulations of macrocyclic lactones with synthetic pyrethroids |
| CN109485683A (zh) * | 2018-11-27 | 2019-03-19 | 齐鲁晟华制药有限公司 | 一种含氟系列阿维菌素衍生物及其制备方法 |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4206205A (en) | 1977-10-03 | 1980-06-03 | Merck & Co., Inc. | Monosaccharide and aglycone derivatives of C-076 |
| NZ188459A (en) | 1977-10-03 | 1982-09-07 | Merck & Co Inc | Derivatives of c-076 compounds and pesticidal compositions |
| US4203976A (en) | 1978-08-02 | 1980-05-20 | Merck & Co., Inc. | Sugar derivatives of C-076 compounds |
| US4427663A (en) * | 1982-03-16 | 1984-01-24 | Merck & Co., Inc. | 4"-Keto-and 4"-amino-4"-deoxy avermectin compounds and substituted amino derivatives thereof |
| US4622313A (en) | 1985-08-01 | 1986-11-11 | Merck & Co., Inc. | O-sulfate derivatives of avermectins and milbemycins having improved water solubility |
| US4886828A (en) | 1986-09-12 | 1989-12-12 | American Cyanamid Company | Δ22 -derivatives of LL-F28249 compounds |
| US4831016A (en) | 1986-10-31 | 1989-05-16 | Merck & Co., Inc. | Reduced avermectin derivatives |
| US4874749A (en) * | 1987-07-31 | 1989-10-17 | Merck & Co., Inc. | 4"-Deoxy-4-N-methylamino avermectin Bla/Blb |
| US4895837A (en) | 1988-01-29 | 1990-01-23 | Merck & Co., Inc. | Avermectin derivatives |
| NZ228866A (en) | 1988-05-02 | 1991-10-25 | Merck & Co Inc | Fluoro-substituted milbemycins and avermectins for combatting parasites and insects |
| US4873224A (en) | 1988-05-23 | 1989-10-10 | Merck & Co., Inc. | Avermectin derivatives |
| NZ231773A (en) * | 1988-12-23 | 1992-09-25 | Merck & Co Inc | Avermectin derivatives, preparation and parasiticidal pharmaceutical compositions thereof |
| US5057499A (en) | 1989-06-02 | 1991-10-15 | Merck & Co. Inc. | Avermectin derivatives |
| US5023241A (en) * | 1989-07-31 | 1991-06-11 | Merck & Co., Inc. | Avermectin derivatives |
| US5169839A (en) | 1990-05-11 | 1992-12-08 | Merck & Co., Inc. | Derivatives of 3'- and 3"-o-desmethyl avermectin compounds, compositions and methods of treating melmintic and parasitic infections |
| IL98599A (en) | 1990-06-28 | 1995-06-29 | Merck & Co Inc | Stable salts of "4-deoxy-" 4-epi-methylamino abramectin and insecticides containing them |
| US5192546A (en) | 1991-01-15 | 1993-03-09 | Mycogen Corporation | Synergistic pesticidal compositions |
| US5346698A (en) | 1991-01-15 | 1994-09-13 | Mycogen Corporation | Synergistic pesticidal compositions |
| US5208222A (en) | 1991-03-28 | 1993-05-04 | Merck & Co., Inc. | 4"-and 4'-alkylthio avermectin derivatives |
| US5262400A (en) | 1991-06-20 | 1993-11-16 | Merck & Co., Inc. | 4α-substituted avermectin derivatives |
| GB9201505D0 (en) | 1992-01-24 | 1992-03-11 | Pfizer Ltd | Antiparasitic agents |
| US5229415A (en) | 1992-03-24 | 1993-07-20 | Merck & Co., Inc. | Alkylthio alkyl avermectins are active antiparasitic agents |
| US6486195B1 (en) | 1993-08-19 | 2002-11-26 | Merck & Co., Inc. | Thermodynamically stable crystal form of 4″-deoxy-4″-epi-methylamino avermectin B1a/B1b benzoic acid salt and processes for its preparation |
| US5362863A (en) | 1993-09-29 | 1994-11-08 | Merck & Co., Inc. | Process for the preparation of 4"-amino avermectin compounds |
| US5981500A (en) | 1994-01-12 | 1999-11-09 | Pfizer Inc. | Antiparasitic agents related to the milbemycins and avermectins |
| US5436355A (en) | 1994-02-03 | 1995-07-25 | Merck & Co., Inc. | Process for making avermectin/zein compositions |
| TW327125B (en) | 1994-02-07 | 1998-02-21 | Merck & Co Inc | Composition and method for protecting against pine exhausted |
| US6875727B2 (en) | 1997-12-23 | 2005-04-05 | Syngenta Crop Protection, Inc. | Use of macrolides in pest control |
| ATE556083T1 (de) | 1999-02-09 | 2012-05-15 | Kitasato Inst | Avermectin derivate |
| JPWO2002012248A1 (ja) | 2000-08-09 | 2004-01-15 | 社団法人北里研究所 | エバーメクチン誘導体 |
| EG23124A (en) | 2001-02-27 | 2004-04-28 | Syngenta Participations Ag | Avermectins substituted in the 4-position having pesticidal properties |
| CR6574A (es) | 2001-02-27 | 2004-10-28 | Syngenta Participations Ag | Sales de avermectinas substituidas en la posicion 4 con propiedades plaguicidas |
| AR036486A1 (es) | 2001-08-28 | 2004-09-15 | Syngenta Participations Ag | Derivados 4"-desoxi-4"-(s)-amino avermectina, composicion plaguicida, procedimiento para la preparacion de esa composicion, metodo para controlar plagas, y uso de estos derivados para preparar una composicion |
| TW200301079A (en) | 2001-12-21 | 2003-07-01 | Syngenta Participations Ag | Avermectin B1 derivatives having an aminosulfonyloxy substituent in the 4"-position |
| GB0302309D0 (en) | 2003-01-31 | 2003-03-05 | Syngenta Participations Ag | Avermectin monosaccharide derivatives substituted in the 4 -position having pesticidal properties |
| GB0302308D0 (en) | 2003-01-31 | 2003-03-05 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide derivatives substituted in the 4"- or 4'-position having pesticidal properties |
| GB0302548D0 (en) | 2003-02-04 | 2003-03-12 | Syngenta Participations Ag | Avermectins substituted in the 4"- and 4' -positions having pesticidal properties |
| TW200538461A (en) | 2004-04-07 | 2005-12-01 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide substituted in the 4"-and 4'-position respectively |
-
2002
- 2002-08-16 AR ARP020103106A patent/AR036486A1/es unknown
- 2002-08-20 DK DK02767411T patent/DK1421094T3/da active
- 2002-08-20 PL PL02367797A patent/PL367797A1/xx not_active Application Discontinuation
- 2002-08-20 AT AT02767411T patent/ATE411331T1/de active
- 2002-08-20 RU RU2004109165/04A patent/RU2004109165A/ru not_active Application Discontinuation
- 2002-08-20 JP JP2003525008A patent/JP2005504068A/ja active Pending
- 2002-08-20 EP EP02767411A patent/EP1421094B1/en not_active Expired - Lifetime
- 2002-08-20 MX MXPA04001814A patent/MXPA04001814A/es unknown
- 2002-08-20 US US10/488,225 patent/US7605134B2/en active Active
- 2002-08-20 CN CNA028169018A patent/CN1549819A/zh active Pending
- 2002-08-20 KR KR10-2004-7003015A patent/KR20040029456A/ko not_active Application Discontinuation
- 2002-08-20 IL IL16043302A patent/IL160433A0/xx unknown
- 2002-08-20 ES ES02767411T patent/ES2315398T3/es not_active Expired - Lifetime
- 2002-08-20 HU HU0401502A patent/HUP0401502A3/hu unknown
- 2002-08-20 DE DE60229402T patent/DE60229402D1/de not_active Expired - Lifetime
- 2002-08-20 WO PCT/EP2002/009315 patent/WO2003020738A1/en active Application Filing
- 2002-08-20 PT PT02767411T patent/PT1421094E/pt unknown
- 2002-08-20 CA CA002457683A patent/CA2457683A1/en not_active Abandoned
- 2002-08-20 BR BR0212138-7A patent/BR0212138A/pt not_active Application Discontinuation
- 2002-08-27 EG EG2002080967A patent/EG23706A/xx active
-
2004
- 2004-02-11 ZA ZA200401107A patent/ZA200401107B/en unknown
- 2004-03-09 CO CO04021426A patent/CO5560615A2/es not_active Application Discontinuation
-
2009
- 2009-01-14 CY CY20091100034T patent/CY1109410T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0401502A3 (en) | 2005-10-28 |
| US7605134B2 (en) | 2009-10-20 |
| DE60229402D1 (de) | 2008-11-27 |
| DK1421094T3 (da) | 2009-01-12 |
| ES2315398T3 (es) | 2009-04-01 |
| CY1109410T1 (el) | 2014-07-02 |
| CN1549819A (zh) | 2004-11-24 |
| JP2005504068A (ja) | 2005-02-10 |
| EP1421094A1 (en) | 2004-05-26 |
| US20040248823A1 (en) | 2004-12-09 |
| EP1421094B1 (en) | 2008-10-15 |
| PT1421094E (pt) | 2008-11-21 |
| CA2457683A1 (en) | 2003-03-13 |
| ZA200401107B (en) | 2004-10-19 |
| CO5560615A2 (es) | 2005-09-30 |
| PL367797A1 (en) | 2005-03-07 |
| KR20040029456A (ko) | 2004-04-06 |
| RU2004109165A (ru) | 2005-10-10 |
| EG23706A (en) | 2007-05-27 |
| ATE411331T1 (de) | 2008-10-15 |
| AR036486A1 (es) | 2004-09-15 |
| IL160433A0 (en) | 2004-07-25 |
| WO2003020738A1 (en) | 2003-03-13 |
| BR0212138A (pt) | 2004-08-24 |
| MXPA04001814A (es) | 2004-07-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD9A | Lapse of provisional protection due to non-payment of fees |