HUP0204200A2 - Eljárás vinil-klorid előállítására etánból és etilénből HCl azonnali visszanyerése mellett a reaktor kilépő áramából - Google Patents

Eljárás vinil-klorid előállítására etánból és etilénből HCl azonnali visszanyerése mellett a reaktor kilépő áramából

Info

Publication number
HUP0204200A2
HUP0204200A2 HU0204200A HUP0204200A HUP0204200A2 HU P0204200 A2 HUP0204200 A2 HU P0204200A2 HU 0204200 A HU0204200 A HU 0204200A HU P0204200 A HUP0204200 A HU P0204200A HU P0204200 A2 HUP0204200 A2 HU P0204200A2
Authority
HU
Hungary
Prior art keywords
ethylene
vinyl chloride
ethane
stream
immediate
Prior art date
Application number
HU0204200A
Other languages
English (en)
Inventor
William D. Clarke
John P. Henley
Daniel A. Hickman
Mark E. Jones
Kenric A. Marshall
Michael M. Olken
Daniel J. Reed
Lee E. Walko
Original Assignee
The Dow Chemical Co.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2000/027272 external-priority patent/WO2001038273A1/en
Application filed by The Dow Chemical Co. filed Critical The Dow Chemical Co.
Publication of HUP0204200A2 publication Critical patent/HUP0204200A2/hu
Publication of HUP0204200A3 publication Critical patent/HUP0204200A3/hu

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/158—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A találmány tárgya eljárás vinil-klorid előállítására, amely eljárásaz alábbi lépéseket tartalmazza: egy előállítási lépésben egy reaktorkilépő áramot állítanak elő etán, etilén, oxigén és legalább egy,hidrogén-klorid, klór, vagy egy klórozott szénhidrogén klórforráskatalitikus reagáltatásával, amelyben az említett etilén az említettetilénhez viszonyított mólaránya 0,02-50; az említett reaktorbólkilépő áramot hirtelen lehűtik (kvencselik) egy lényegében hidrogén-kloridtól mentes nyers termékáram biztosítására; az említett nyerstermékáramot szétválasztják egy vinil-klorid monomer termékáramra, ésegy könnyű komponenseket tartalmazó áramra; és az említett könnyűkomponenseket tartalmazó áramot recirkuláltatják a katalitikusreagáltatáshoz az említett etánnal, említett etilénnel, az említettoxigénnel és az említett klórforrással az említett előállításilépésben. A találmány tárgya továbbá a fenti eljárás kivitelezéséreszolgáló berendezés, valamint az eljárással előállított vinil-klorid. Ó
HU0204200A 1999-11-22 2000-10-06 Process for vinyl chloride manufacture from ethane and ethylene with immediate hcl recovery from reactor effluent HUP0204200A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16689799P 1999-11-22 1999-11-22
PCT/US2000/027272 WO2001038273A1 (en) 1999-11-22 2000-10-03 A process for the conversion of ethylene to vinyl chloride, and novel catalyst compositions useful for such process
PCT/US2000/027700 WO2001042176A1 (en) 1999-11-22 2000-10-06 Process for vinyl chloride manufacture from ethane and ethylene with immediate hc1 recovery from reactor effluent

Publications (2)

Publication Number Publication Date
HUP0204200A2 true HUP0204200A2 (hu) 2003-03-28
HUP0204200A3 HUP0204200A3 (en) 2003-11-28

Family

ID=26680328

Family Applications (3)

Application Number Title Priority Date Filing Date
HU0204200A HUP0204200A3 (en) 1999-11-22 2000-10-06 Process for vinyl chloride manufacture from ethane and ethylene with immediate hcl recovery from reactor effluent
HU0203915A HUP0203915A2 (en) 1999-11-22 2000-10-06 Process for vinyl chloride manufacture from ethane and ethylene with partial hc1 recovery from reactor effluent
HU0204082A HUP0204082A2 (hu) 1999-11-22 2000-10-06 Eljárás vinil-klorid előállítására etánból és etilénből HCI részleges visszanyerése mellett a reaktor kilépő áramából

Family Applications After (2)

Application Number Title Priority Date Filing Date
HU0203915A HUP0203915A2 (en) 1999-11-22 2000-10-06 Process for vinyl chloride manufacture from ethane and ethylene with partial hc1 recovery from reactor effluent
HU0204082A HUP0204082A2 (hu) 1999-11-22 2000-10-06 Eljárás vinil-klorid előállítására etánból és etilénből HCI részleges visszanyerése mellett a reaktor kilépő áramából

Country Status (10)

Country Link
EP (2) EP1235770A1 (hu)
JP (3) JP2003527344A (hu)
KR (3) KR20020056936A (hu)
AU (3) AU778118B2 (hu)
BR (3) BR0015917A (hu)
CA (3) CA2391586A1 (hu)
DE (2) DE60020390T2 (hu)
HU (3) HUP0204200A3 (hu)
MX (3) MXPA02005137A (hu)
WO (2) WO2001038272A1 (hu)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR0210049A (pt) * 2001-05-23 2004-08-17 Dow Global Technologies Inc Processo de halogenação oxidativa e deshidrogenação opcional de hidrocarbonetos c3+
WO2002094749A1 (en) * 2001-05-23 2002-11-28 Dow Global Technologies Inc. Production of vinyl halide from single carbon feedstocks
FR2902784B1 (fr) * 2006-06-23 2008-09-05 Solvay Procede de fabrication de 1,2-dichloroethane
FR2902787B1 (fr) * 2006-06-26 2008-09-05 Solvay Procede de fabrication de 1,2-dichloroethane
KR20090026381A (ko) * 2007-09-10 2009-03-13 한화석유화학 주식회사 염화수소의 저온 촉매산화법에 의한 염소의 제조방법
US9434663B2 (en) 2012-08-21 2016-09-06 Uop Llc Glycols removal and methane conversion process using a supersonic flow reactor
US8933275B2 (en) 2012-08-21 2015-01-13 Uop Llc Production of oxygenates from a methane conversion process
US9656229B2 (en) 2012-08-21 2017-05-23 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US9707530B2 (en) 2012-08-21 2017-07-18 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US9205398B2 (en) 2012-08-21 2015-12-08 Uop Llc Production of butanediol from a methane conversion process
US8937186B2 (en) 2012-08-21 2015-01-20 Uop Llc Acids removal and methane conversion process using a supersonic flow reactor
US9689615B2 (en) 2012-08-21 2017-06-27 Uop Llc Steady state high temperature reactor
US9370757B2 (en) 2012-08-21 2016-06-21 Uop Llc Pyrolytic reactor
US8927769B2 (en) 2012-08-21 2015-01-06 Uop Llc Production of acrylic acid from a methane conversion process
US9308513B2 (en) * 2012-08-21 2016-04-12 Uop Llc Production of vinyl chloride from a methane conversion process
US9327265B2 (en) 2012-08-21 2016-05-03 Uop Llc Production of aromatics from a methane conversion process
US9023255B2 (en) 2012-08-21 2015-05-05 Uop Llc Production of nitrogen compounds from a methane conversion process
CN111821832A (zh) * 2020-08-10 2020-10-27 南京佳华工程技术有限公司 一种氯醇化尾气耦合处理方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL130969C (hu) * 1964-06-01 1900-01-01
GB1039369A (en) * 1964-07-22 1966-08-17 Princeton Chemical Res Inc Catalytic conversion of ethane to vinyl chloride
FR1594693A (hu) * 1967-11-01 1970-06-08
CA943145A (en) * 1967-11-08 1974-03-05 Stauffer Chemical Company Chlorination of hydrocarbons
US4042640A (en) * 1975-11-06 1977-08-16 The Lummus Company Oxychlorination of hydrocarbons

Also Published As

Publication number Publication date
AU778120B2 (en) 2004-11-18
BR0015918A (pt) 2002-08-06
AU7868800A (en) 2001-06-04
CA2391432A1 (en) 2001-05-31
EP1235771A1 (en) 2002-09-04
EP1235770A1 (en) 2002-09-04
EP1235771B1 (en) 2006-02-08
AU1431501A (en) 2001-06-04
JP2003527349A (ja) 2003-09-16
KR20020056935A (ko) 2002-07-10
KR20020056936A (ko) 2002-07-10
KR20020056939A (ko) 2002-07-10
AU1431401A (en) 2001-06-18
AU778118B2 (en) 2004-11-18
HUP0204082A2 (hu) 2003-04-28
MXPA02005152A (es) 2002-11-07
HUP0204200A3 (en) 2003-11-28
WO2001038272A1 (en) 2001-05-31
HUP0203915A2 (en) 2003-04-28
DE60020390T2 (de) 2006-03-23
CA2391441A1 (en) 2001-06-14
BR0015920A (pt) 2002-08-06
JP2003527344A (ja) 2003-09-16
MXPA02005146A (es) 2002-11-07
BR0015917A (pt) 2002-08-06
CA2391586A1 (en) 2001-05-31
DE60020390D1 (de) 2005-06-30
WO2001038274A1 (en) 2001-05-31
MXPA02005137A (es) 2002-11-07
JP2003527343A (ja) 2003-09-16
DE60025940D1 (de) 2006-04-20

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