HUP0201496A2 - Kettős fém-cianid katalizátorok, előállításuk és alkalmazásuk poliéter-poliolok előállítására, valamint a kapott poliéter-poliol - Google Patents
Kettős fém-cianid katalizátorok, előállításuk és alkalmazásuk poliéter-poliolok előállítására, valamint a kapott poliéter-poliolInfo
- Publication number
- HUP0201496A2 HUP0201496A2 HU0201496A HUP0201496A HUP0201496A2 HU P0201496 A2 HUP0201496 A2 HU P0201496A2 HU 0201496 A HU0201496 A HU 0201496A HU P0201496 A HUP0201496 A HU P0201496A HU P0201496 A2 HUP0201496 A2 HU P0201496A2
- Authority
- HU
- Hungary
- Prior art keywords
- compounds
- carboxylic acid
- metal cyanide
- polyalkylene glycol
- polyether polyols
- Prior art date
Links
- 239000004721 Polyphenylene oxide Substances 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 5
- 239000002184 metal Substances 0.000 title abstract 5
- 229920000570 polyether Polymers 0.000 title abstract 5
- 229920005862 polyol Polymers 0.000 title abstract 4
- 150000003077 polyols Chemical class 0.000 title abstract 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 title abstract 2
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 4
- 230000000536 complexating effect Effects 0.000 abstract 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 4
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 3
- 229920000858 Cyclodextrin Polymers 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229940097362 cyclodextrins Drugs 0.000 abstract 2
- 229930182470 glycoside Natural products 0.000 abstract 2
- 150000002338 glycosides Chemical class 0.000 abstract 2
- 239000002563 ionic surfactant Substances 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 150000002825 nitriles Chemical class 0.000 abstract 2
- 150000003018 phosphorus compounds Chemical class 0.000 abstract 2
- 229920000515 polycarbonate Polymers 0.000 abstract 2
- 239000004417 polycarbonate Substances 0.000 abstract 2
- 229920000728 polyester Polymers 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A találmány tárgya kimagasló aktivitású kettős fém-cianid (DMC)-katalizátor, amely tartalmaz a) egy vagy több kettős fém-cianidvegyületetet, b) egy vagy több (d)-től különböző szerveskomplexligandumot, és c) egy vagy több komplexképző komponenst apoliéterek vegyületcsaládjából, és d) egy vagy több komplexképzőkomponenst a poliészterek, polikarbonátok, polialkilénglikol-szorbitón-észterek, polialkilénglikol-glicidil-éterek, glicidiléterek,glikozidok, többértékű alkoholok karbonsav-észterei, ciklodextrinek,foszforvegyületek, a,b-telítetlen karbonsav-észterek, vagy ionosfelületaktív vegyületek közül. A találmány további tárgya eljárás afenti katalizátor előállítására, amely eljárás szerint i) vizesoldatban reagáltatnak a) fémsókat fém-cianid sókkal, b) szerveskomplexligandumokkal, g) egy vagy több, a poliéterekvegyületcsaládjából választott komplexképző komponenssel, d) egy vagytöbb, a poliészterek, polikarbonátok, polialkilénglikol-szobitánészterek, polialkilénglikol-glicidiléterek, glicidiléterek,glikozidok, többértékű alkoholok karbonsavészterei, ciklodextrinek,foszforvegyületek, a, b-telítetlen karbonsavészterek vagy ionosfelületaktív anyagok vegyületcsaládjából választott komplexképzőkomponenssel, ii) az előző lépésben kapott katalizátort elválasztják,mossák és szárítják. A találmány további tárgyait képezi a fentieljárással előállítható poliéter-poliol, illetve a DMC-katalizátoralkalmazása poliéter-poliolok előállítására aktív hidrogénatomottartalmazó kiindulási vegyületek és alkilén-oxidok poliaddíciósreakciójával. Ó
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10122019A DE10122019A1 (de) | 2001-05-07 | 2001-05-07 | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HU0201496D0 HU0201496D0 (hu) | 2002-07-29 |
| HUP0201496A2 true HUP0201496A2 (hu) | 2002-12-28 |
Family
ID=7683832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU0201496A HUP0201496A2 (hu) | 2001-05-07 | 2002-05-06 | Kettős fém-cianid katalizátorok, előállításuk és alkalmazásuk poliéter-poliolok előállítására, valamint a kapott poliéter-poliol |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6852663B2 (hu) |
| EP (1) | EP1256596A1 (hu) |
| JP (1) | JP2002338682A (hu) |
| KR (1) | KR20020085805A (hu) |
| CN (1) | CN1383917A (hu) |
| BR (1) | BR0201623A (hu) |
| CA (1) | CA2384486A1 (hu) |
| DE (1) | DE10122019A1 (hu) |
| HU (1) | HUP0201496A2 (hu) |
| MX (1) | MXPA02004506A (hu) |
| PL (1) | PL353722A1 (hu) |
| RU (1) | RU2002111645A (hu) |
| SG (1) | SG100790A1 (hu) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19905611A1 (de) * | 1999-02-11 | 2000-08-17 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| EP1562999B1 (en) * | 2002-11-07 | 2012-12-19 | Dow Global Technologies LLC | Method for preparing metal cyanide catalysts using polymerizable complexing agents |
| WO2005084802A1 (ja) * | 2004-03-09 | 2005-09-15 | Japan Science And Technology Agency | 高分子内包ルイス酸金属触媒 |
| US7300993B2 (en) * | 2004-06-03 | 2007-11-27 | Shell Oil Company | Process for the preparation of polyether polyols |
| JP5151480B2 (ja) * | 2005-08-17 | 2013-02-27 | 旭硝子株式会社 | ポリエステルエーテルポリ（モノ）オールの製造方法およびポリウレタンの製造方法 |
| KR100908351B1 (ko) * | 2007-04-13 | 2009-07-20 | 에스케이씨 주식회사 | 랜덤 폴리올 제조용 복금속 시안계 촉매 |
| DE102007057145A1 (de) | 2007-11-28 | 2009-06-04 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyetheralkoholen mit DMC-Katalysatoren unter Verwendung von SiH-Gruppen tragenden Verbindungen als Additive |
| DE102007057147A1 (de) | 2007-11-28 | 2009-06-04 | Evonik Goldschmidt Gmbh | Verfahren zur Alkoxylierung mit DMC-Katalysatoren im Schlaufenreaktor mit Strahlsauger |
| DE102007057146A1 (de) | 2007-11-28 | 2009-06-04 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyetheralkoholen mit DMC-Katalysatoren unter Verwendung von speziellen Additiven mit aromatischer Hydroxy-Funktionalisierung |
| DE102008000360A1 (de) | 2008-02-21 | 2009-08-27 | Evonik Goldschmidt Gmbh | Neue Alkoxysilylgruppen tragende Polyetheralkohole durch Alkoxylierung epoxidfunktioneller Alkoxysilane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung |
| DE102008000903A1 (de) | 2008-04-01 | 2009-10-08 | Evonik Goldschmidt Gmbh | Neue Organosiloxangruppen tragende Polyetheralkohole durch Alkoxylierung epoxidfunktioneller (Poly)Organosiloxane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung |
| KR100941637B1 (ko) * | 2008-05-21 | 2010-02-11 | 에스케이씨 주식회사 | 반응성이 제어된, 폴리올 제조용 복금속 시안계 촉매 및이의 제조방법 |
| DE102008002713A1 (de) | 2008-06-27 | 2009-12-31 | Evonik Goldschmidt Gmbh | Neue Polyethersiloxane enthaltende Alkoxylierungsprodukte durch direkte Alkoxylierung organomodifizierter alpha, omega-Dihydroxysiloxane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung |
| DE102008043245A1 (de) | 2008-10-29 | 2010-05-06 | Evonik Goldschmidt Gmbh | Siliconpolyether-Copolymersysteme sowie Verfahren zu deren Herstellung durch Alkoxylierungsreaktion |
| DE102009002371A1 (de) | 2009-04-15 | 2010-10-21 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von geruchlosen Polyetheralkoholen mittels DMC-Katalysatoren und deren Verwendung in kosmetischen und/oder dermatologischen Zubereitungen |
| DE102010039140A1 (de) | 2010-08-10 | 2012-02-16 | Evonik Goldschmidt Gmbh | Dispergiermittel und Verfahren zu deren Herstellung |
| DE102010040517A1 (de) | 2010-09-09 | 2012-03-15 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung von Polyetherpolyolen |
| KR101866599B1 (ko) | 2010-12-27 | 2018-06-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 이중 금속 시안화물 촉매 착물 및 마그네슘, 3족-15족 금속 또는 란탄 계열 금속 화합물을 사용한 알킬렌 옥시드 중합 |
| US9334361B2 (en) | 2011-02-23 | 2016-05-10 | Council Of Scientific & Industrial Research | Process for preparing hyperbranched polyesters |
| DE102011076019A1 (de) | 2011-05-18 | 2012-11-22 | Evonik Goldschmidt Gmbh | Alkoxylierungsprodukte und Verfahren zu ihrer Herstellung mittels DMC-Katalysatoren |
| US9994672B2 (en) | 2011-12-20 | 2018-06-12 | Covestro Deutschland Ag | Hydroxy-aminopolymers and method for producing same |
| DE102013208328A1 (de) | 2013-05-07 | 2014-11-13 | Evonik Industries Ag | Polyoxyalkylene mit seitenständigen langkettigen Acyloxyresten und Verfahren zu ihrer Herstellung mittels DMC-Katalysatoren |
| DE102013215664A1 (de) | 2013-08-08 | 2015-02-12 | Evonik Industries Ag | Apparatur zur Durchführung eines ringöffnenden Polymerisationsverfahrens |
| DE102014209408A1 (de) | 2014-05-19 | 2015-11-19 | Evonik Degussa Gmbh | Ethoxylatherstellung unter Verwendung hoch aktiver Doppelmetallcyanid-Katalysatoren |
| DE102014209407A1 (de) | 2014-05-19 | 2015-11-19 | Evonik Degussa Gmbh | Hoch aktive Doppelmetallcyanid-Katalysatoren und Verfahren zu deren Herstellung |
| EP3219741A1 (de) * | 2016-03-18 | 2017-09-20 | Covestro Deutschland AG | Verfahren zur herstellung von polyethercarbonatpolyolen |
| WO2021105037A1 (de) | 2019-11-28 | 2021-06-03 | Evonik Operations Gmbh | Polyethermodifizierte polybutadiene und verfahren zu deren herstellung |
| AU2021266078A1 (en) | 2020-04-30 | 2023-01-19 | Evonik Operations Gmbh | Use of polyethers as carriers for active ingredients |
| EP4047031A1 (de) | 2021-02-17 | 2022-08-24 | Evonik Operations GmbH | Aminofunktionelle polybutadiene mit kammständigen polyetherresten und verfahren zu deren herstellung |
| EP4314111A1 (de) | 2021-03-26 | 2024-02-07 | Evonik Operations GmbH | Neue polyether auf basis von 2,3-epoxybutan und verfahren zu deren herstellung |
| JP2022183009A (ja) | 2021-05-27 | 2022-12-08 | エボニック オペレーションズ ゲーエムベーハー | ポリエステル－ポリエーテル修飾ポリブタジエンおよびその製造方法 |
| CA3219712A1 (en) | 2021-05-27 | 2022-12-01 | Matthias Lobert | Hydrogenated polyether-modified amino-functional polybutadienes and processes for preparation thereof |
| CA3219705A1 (en) | 2021-05-27 | 2022-12-01 | Matthias Lobert | Hydrogenated polyether-modified polybutadienes and processes for preparation thereof |
| WO2023061817A1 (en) | 2021-10-14 | 2023-04-20 | Evonik Operations Gmbh | Liquid composition of gram-negative bacteria |
| CN115785435B (zh) * | 2022-12-29 | 2023-08-11 | 杭州普力材料科技有限公司 | 一种一步法制备聚醚多元醇的方法 |
| CN116217913A (zh) * | 2022-12-29 | 2023-06-06 | 杭州普力材料科技有限公司 | 一种三配体双金属络合物催化剂及其制备方法 |
Family Cites Families (19)
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|---|---|---|---|---|
| GB1063525A (en) * | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3829505A (en) * | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) * | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| JP2653236B2 (ja) | 1990-10-05 | 1997-09-17 | 旭硝子株式会社 | ポリエーテル化合物の製造方法 |
| US5158922A (en) * | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5470813A (en) * | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5712216A (en) * | 1995-05-15 | 1998-01-27 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5482908A (en) * | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5545601A (en) * | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
| US5627120A (en) * | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5693584A (en) * | 1996-08-09 | 1997-12-02 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| ID24172A (id) * | 1997-10-13 | 2000-07-13 | Bayer Ag | Katalis logam ganda yang sangat aktif untuk memproduksi poliol-poliol poliester |
| US6063897A (en) * | 1998-05-05 | 2000-05-16 | Arco Chemical Technology, L.P. | Acid-treated double metal cyanide complex catalysts |
| US6013596A (en) * | 1998-05-18 | 2000-01-11 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing cyclic, bidentate complexing agents |
| DE19842383A1 (de) * | 1998-09-16 | 2000-03-23 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19906985A1 (de) * | 1999-02-19 | 2000-08-31 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19924672A1 (de) * | 1999-05-28 | 2000-11-30 | Bayer Ag | Doppelmetallcyanic-Katalysatoren für die Herstellung von Polyetherpolyolen |
| WO2000068295A1 (de) * | 1999-05-05 | 2000-11-16 | Bayer Aktiengesellschaft | Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen |
| DE19953546A1 (de) * | 1999-11-08 | 2001-05-10 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
-
2001
- 2001-05-07 DE DE10122019A patent/DE10122019A1/de not_active Withdrawn
-
2002
- 2002-04-25 EP EP02009221A patent/EP1256596A1/de not_active Withdrawn
- 2002-04-26 SG SG200202561A patent/SG100790A1/en unknown
- 2002-04-30 CN CN02118886A patent/CN1383917A/zh active Pending
- 2002-05-02 CA CA002384486A patent/CA2384486A1/en not_active Abandoned
- 2002-05-02 JP JP2002130617A patent/JP2002338682A/ja active Pending
- 2002-05-03 US US10/138,080 patent/US6852663B2/en not_active Expired - Fee Related
- 2002-05-06 KR KR1020020024667A patent/KR20020085805A/ko not_active Application Discontinuation
- 2002-05-06 RU RU2002111645/04A patent/RU2002111645A/ru not_active Application Discontinuation
- 2002-05-06 HU HU0201496A patent/HUP0201496A2/hu unknown
- 2002-05-06 PL PL02353722A patent/PL353722A1/xx not_active Application Discontinuation
- 2002-05-06 MX MXPA02004506A patent/MXPA02004506A/es unknown
- 2002-05-07 BR BR0201623-0A patent/BR0201623A/pt not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20020085805A (ko) | 2002-11-16 |
| CA2384486A1 (en) | 2002-11-07 |
| JP2002338682A (ja) | 2002-11-27 |
| MXPA02004506A (es) | 2005-08-16 |
| US6852663B2 (en) | 2005-02-08 |
| US20030119663A1 (en) | 2003-06-26 |
| CN1383917A (zh) | 2002-12-11 |
| SG100790A1 (en) | 2003-12-26 |
| HU0201496D0 (hu) | 2002-07-29 |
| EP1256596A1 (de) | 2002-11-13 |
| PL353722A1 (en) | 2002-11-18 |
| BR0201623A (pt) | 2003-03-11 |
| RU2002111645A (ru) | 2003-12-10 |
| DE10122019A1 (de) | 2002-11-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD9A | Lapse of provisional protection due to non-payment of fees |