HU213643B - Solid pesticid formulation and process for its production - Google Patents
Solid pesticid formulation and process for its production Download PDFInfo
- Publication number
- HU213643B HU213643B HU9501022A HU9501022A HU213643B HU 213643 B HU213643 B HU 213643B HU 9501022 A HU9501022 A HU 9501022A HU 9501022 A HU9501022 A HU 9501022A HU 213643 B HU213643 B HU 213643B
- Authority
- HU
- Hungary
- Prior art keywords
- pvp
- extrusion
- temperature
- water
- solid
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000007787 solid Substances 0.000 title claims abstract description 20
- 238000009472 formulation Methods 0.000 title abstract description 34
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 63
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 61
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000011814 protection agent Substances 0.000 claims abstract 4
- 239000000463 material Substances 0.000 claims description 31
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- 239000004480 active ingredient Substances 0.000 claims description 28
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 7
- 239000000575 pesticide Substances 0.000 claims description 7
- 239000006104 solid solution Substances 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 229910000343 potassium bisulfate Inorganic materials 0.000 claims description 4
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 claims description 3
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005761 Dimethomorph Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 claims description 2
- 239000004476 plant protection product Substances 0.000 claims 1
- 239000002728 pyrethroid Substances 0.000 claims 1
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- 238000012360 testing method Methods 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
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- LQIAZOCLNBBZQK-UHFFFAOYSA-N 1-(1,2-Diphosphanylethyl)pyrrolidin-2-one Chemical compound PCC(P)N1CCCC1=O LQIAZOCLNBBZQK-UHFFFAOYSA-N 0.000 description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 5
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- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 description 2
- JTNCEQNHURODLX-UHFFFAOYSA-N 2-phenylethanimidamide Chemical compound NC(=N)CC1=CC=CC=C1 JTNCEQNHURODLX-UHFFFAOYSA-N 0.000 description 2
- SBUKOHLFHYSZNG-UHFFFAOYSA-N 4-dodecyl-2,6-dimethylmorpholine Chemical compound CCCCCCCCCCCCN1CC(C)OC(C)C1 SBUKOHLFHYSZNG-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
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- YQVMVCCFZCMYQB-SNVBAGLBSA-N Flamprop-M Chemical compound C=1C=C(F)C(Cl)=CC=1N([C@H](C)C(O)=O)C(=O)C1=CC=CC=C1 YQVMVCCFZCMYQB-SNVBAGLBSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
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- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 2
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- 238000001704 evaporation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
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- 239000008177 pharmaceutical agent Substances 0.000 description 2
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- 239000000080 wetting agent Substances 0.000 description 2
- QQODLKZGRKWIFG-CVAIRZPRSA-N (1R)-cis-(alphaS)-cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-CVAIRZPRSA-N 0.000 description 1
- QQODLKZGRKWIFG-MOXGXCLJSA-N (1S)-cis-(alphaR)-cyfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-MOXGXCLJSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 description 1
- KAATUXNTWXVJKI-WSTZPKSXSA-N (1S)-cis-(alphaR)-cypermethrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-WSTZPKSXSA-N 0.000 description 1
- OYDPVRNLLQZQFY-JBGJSGBSSA-N (1r,3s)-2,2-dimethyl-3-[(e)-(2-oxothiolan-3-ylidene)methyl]cyclopropane-1-carboxylic acid Chemical compound OC(=O)[C@H]1C(C)(C)[C@H]1\C=C/1C(=O)SCC\1 OYDPVRNLLQZQFY-JBGJSGBSSA-N 0.000 description 1
- LLMLSUSAKZVFOA-INEUFUBQSA-N (1s,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylic acid Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@@H]1C(O)=O LLMLSUSAKZVFOA-INEUFUBQSA-N 0.000 description 1
- SFHVXKNMCGSLAR-UHFFFAOYSA-N 2,2,3,3-tetramethylcyclopropanecarboxylic acid Chemical compound CC1(C)C(C(O)=O)C1(C)C SFHVXKNMCGSLAR-UHFFFAOYSA-N 0.000 description 1
- VEQMUQZKBLIXLT-UHFFFAOYSA-N 2,3-dimethylcyclopropane-1-carboxylic acid Chemical compound CC1C(C)C1C(O)=O VEQMUQZKBLIXLT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 239000005884 Beta-Cyfluthrin Substances 0.000 description 1
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- 239000005892 Deltamethrin Substances 0.000 description 1
- 239000005895 Esfenvalerate Substances 0.000 description 1
- 240000000047 Gossypium barbadense Species 0.000 description 1
- 235000009429 Gossypium barbadense Nutrition 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241000256250 Spodoptera littoralis Species 0.000 description 1
- 240000003949 Sporobolus virginicus Species 0.000 description 1
- 241001454294 Tetranychus Species 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- QQODLKZGRKWIFG-RUTXASTPSA-N [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-RUTXASTPSA-N 0.000 description 1
- FSAVDKDHPDSCTO-WQLSENKSSA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl FSAVDKDHPDSCTO-WQLSENKSSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-BWHPXCRDSA-N [cyano-(3-phenoxyphenyl)methyl] (1s,3s)-3-[(z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-BWHPXCRDSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
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- 238000005054 agglomeration Methods 0.000 description 1
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- 235000021016 apples Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
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- 238000011109 contamination Methods 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
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- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000009474 hot melt extrusion Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- RBNIGDFIUWJJEV-LLVKDONJSA-N methyl (2r)-2-(n-benzoyl-3-chloro-4-fluoroanilino)propanoate Chemical compound C=1C=C(F)C(Cl)=CC=1N([C@H](C)C(=O)OC)C(=O)C1=CC=CC=C1 RBNIGDFIUWJJEV-LLVKDONJSA-N 0.000 description 1
- GEPDYQSQVLXLEU-AATRIKPKSA-N methyl (e)-3-dimethoxyphosphoryloxybut-2-enoate Chemical compound COC(=O)\C=C(/C)OP(=O)(OC)OC GEPDYQSQVLXLEU-AATRIKPKSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004546 suspension concentrate Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- UBCKGWBNUIFUST-YHYXMXQVSA-N tetrachlorvinphos Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC(Cl)=C(Cl)C=C1Cl UBCKGWBNUIFUST-YHYXMXQVSA-N 0.000 description 1
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- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Plant Substances (AREA)
- Medicinal Preparation (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP92309173 | 1992-10-08 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| HU9501022D0 HU9501022D0 (en) | 1995-06-28 |
| HUT71858A HUT71858A (en) | 1996-02-28 |
| HU213643B true HU213643B (en) | 1997-08-28 |
Family
ID=8211512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU9501022A HU213643B (en) | 1992-10-08 | 1993-10-06 | Solid pesticid formulation and process for its production |
Country Status (28)
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL109206A (en) * | 1993-04-08 | 1999-03-12 | Shell Int Research | Solid concentrates containing pyrethroids and crop protection products |
| ZA949607B (en) * | 1993-12-23 | 1995-08-15 | Shell Int Research | Solid insecticidal formulation. |
| US5711956A (en) * | 1994-12-08 | 1998-01-27 | American Cyanamid Company | Solid insecticidal formulation |
| DE19622355A1 (de) | 1996-06-04 | 1997-12-11 | Bayer Ag | Formkörper die agrochemische Mittel freisetzen |
| EP1026946A1 (de) * | 1997-10-29 | 2000-08-16 | Basf Aktiengesellschaft | Feste zubereitung eines pflanzenschutzmittels |
| AU748494B2 (en) * | 1998-04-24 | 2002-06-06 | Basf Corporation | Improved extrusion process |
| EP0981957A1 (en) * | 1998-08-11 | 2000-03-01 | American Cyanamid Company | Method for the enhancement of the residual activity of pesticide formulations |
| AU1160500A (en) * | 1998-11-12 | 2000-06-05 | Basf Aktiengesellschaft | Plant protection agents in tablet form |
| DE10051266A1 (de) * | 2000-10-16 | 2002-04-25 | Basf Ag | Verfahren zur Filtration einer Flüssigkeit, mit einem Filterhilfsmittel und Verfahren zu deren Herstellung |
| US7491407B2 (en) * | 2001-10-31 | 2009-02-17 | North Carolina State University | Fiber-based nano drug delivery systems (NDDS) |
| DE10215147A1 (de) * | 2002-04-05 | 2003-10-16 | Basf Ag | Verwendung von Polymerisation, enthaltend thermoplastische Polymere als Filterhilfs- und/oder Stabilisierungsmittel |
| JP2006518380A (ja) * | 2003-01-31 | 2006-08-10 | スミスクライン・ビーチャム・コーポレイション | 固体分散体組成物 |
| US20050196441A1 (en) * | 2003-11-05 | 2005-09-08 | Dvorsky James E. | Quick dissolving agrochemical and animal health products |
| RU2280991C2 (ru) * | 2004-08-31 | 2006-08-10 | Федеральное государственное образовательное учреждение высшего профессионального образования Омский Государственный Аграрный Университет | Способ производства йогурта |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3247918A1 (de) * | 1982-12-24 | 1984-06-28 | Basf Ag, 6700 Ludwigshafen | Duengerstaebchen aus pflanzennaehrstoffen und poly-n-vinylpyrrolidon-(2)-haltigen polymerisation |
| FR2545325A1 (fr) * | 1983-05-06 | 1984-11-09 | Sedagri | Granules de substances solides a activite phytopharmaceutique et leur procede de preparation |
| DE3333872A1 (de) * | 1983-09-20 | 1985-03-28 | Norddeutsche Affinerie AG, 2000 Hamburg | In waessrigen medien dispergierbare granulierte zusammensetzung von in wasser schwer- oder unloeslichen wirkstoffen |
| GB8518927D0 (en) * | 1985-07-26 | 1985-09-04 | Vincent Processes Ltd | Tablets |
| DD239710A1 (de) * | 1985-08-01 | 1986-10-08 | Berlin Chemie Veb | Verwendung von harnstoff-formaldehyd-polykondensationsprodukten als zerfallshilfsmittel fuer pflanzenschutzmittelgranulate und- komprimate |
| DE3612212A1 (de) * | 1986-04-11 | 1987-10-15 | Basf Ag | Verfahren zur herstellung von festen pharmazeutischen formen |
| US4900775A (en) * | 1988-02-29 | 1990-02-13 | Gaf Chemicals Corporation | Solubilization of complexes of water-insoluble organic compounds by aqueous solutions of polyvinylpyrrolidone |
| US5180587A (en) * | 1988-06-28 | 1993-01-19 | E. I. Du Pont De Nemours And Company | Tablet formulations of pesticides |
| DE3830353A1 (de) * | 1988-09-07 | 1990-03-15 | Basf Ag | Verfahren zur kontinuierlichen herstellung von festen pharmazeutischen formen |
| GB9025372D0 (en) * | 1990-11-22 | 1991-01-09 | Nat Res Dev | Pharmaceutical dosage forms |
| RU2096955C1 (ru) * | 1991-03-01 | 1997-11-27 | Е.И.Дюпон Де Немур Энд Компани | Вододиспергируемая гранулированная пестицидная композиция, получаемая методом экструзии, и способ ее получения |
-
1993
- 1993-09-15 TW TW082107586A patent/TW246635B/zh not_active IP Right Cessation
- 1993-09-27 MY MYPI93001960A patent/MY109259A/en unknown
- 1993-10-06 KR KR1019950701362A patent/KR100318167B1/ko not_active Expired - Lifetime
- 1993-10-06 DK DK93921927T patent/DK0663795T3/da active
- 1993-10-06 MD MD96-0314A patent/MD1517G2/ro unknown
- 1993-10-06 AT AT93921927T patent/ATE169452T1/de active
- 1993-10-06 ES ES93921927T patent/ES2120514T3/es not_active Expired - Lifetime
- 1993-10-06 SK SK450-95A patent/SK281192B6/sk not_active IP Right Cessation
- 1993-10-06 AU AU51115/93A patent/AU679692B2/en not_active Expired
- 1993-10-06 EP EP93921927A patent/EP0663795B1/en not_active Expired - Lifetime
- 1993-10-06 WO PCT/EP1993/002770 patent/WO1994008455A1/en active IP Right Grant
- 1993-10-06 DE DE69320356T patent/DE69320356T2/de not_active Expired - Lifetime
- 1993-10-06 CN CN93118619A patent/CN1052378C/zh not_active Expired - Lifetime
- 1993-10-06 SG SG1996004267A patent/SG49706A1/en unknown
- 1993-10-06 CZ CZ1995817A patent/CZ286268B6/cs not_active IP Right Cessation
- 1993-10-06 HU HU9501022A patent/HU213643B/hu unknown
- 1993-10-06 PL PL93308258A patent/PL177144B1/pl unknown
- 1993-10-06 JP JP50959594A patent/JP3651804B2/ja not_active Expired - Lifetime
- 1993-10-06 RU RU95109898A patent/RU2130723C1/ru active
- 1993-10-06 IL IL107208A patent/IL107208A/xx not_active IP Right Cessation
- 1993-10-06 GE GEAP19932591A patent/GEP19981475B/en unknown
- 1993-10-06 US US08/406,988 patent/US5665369A/en not_active Expired - Lifetime
- 1993-10-06 TJ TJ96000386A patent/TJ238B/xx unknown
- 1993-10-06 NZ NZ256415A patent/NZ256415A/en not_active IP Right Cessation
- 1993-10-06 BR BR9307193A patent/BR9307193A/pt not_active IP Right Cessation
- 1993-10-06 CA CA002143867A patent/CA2143867C/en not_active Expired - Lifetime
- 1993-10-06 ZA ZA937406A patent/ZA937406B/xx unknown
-
1995
- 1995-04-06 BG BG99551A patent/BG62546B1/bg unknown
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