HRP20190717T1 - Postupci taloženja polimera i deaktiviranog organometalnog katalizatora u reakciji oligomerizacije olefina - Google Patents

Postupci taloženja polimera i deaktiviranog organometalnog katalizatora u reakciji oligomerizacije olefina Download PDF

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HRP20190717T1
HRP20190717T1 HRP20190717TT HRP20190717T HRP20190717T1 HR P20190717 T1 HRP20190717 T1 HR P20190717T1 HR P20190717T T HRP20190717T T HR P20190717TT HR P20190717 T HRP20190717 T HR P20190717T HR P20190717 T1 HRP20190717 T1 HR P20190717T1
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particles
output stream
sorbent
precipitate
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HRP20190717TT
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Timur Mikhailovich Zilbershtein
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Public Joint Stock Company "Sibur Holding"
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/10—Catalytic processes with metal oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (15)

1. Postupak taloženja polimera i deaktiviranog organometalnog katalizatora u reakciji oligomerizacije olefina, naznačen time što se sastoji u: osiguravanju izlazne struje iz reakcije oligomerizacije olefina, gdje izlazna struja sadrži polimer i organometalni katalizator, po mogućnosti organometalni katalizator, koji sadrži krom; unošenju čestice sorbensa u izlaznu struju, gdje čestice sorbensa sadrže deaktivirajuće sredstvo u količini manjoj od 20 %, težinski, gdje se navedeno deaktivirajuće sredstvo bira iz skupine koju čine voda, alkoholi, amini, aminoalkoholi i njihove kombinacije, te gdje najmanje 10 % čestica sorbensa ima veličinu čestica u rasponu od 10 µm do 60 µm; i hlađenju izlazne struje, što dovodi do taloženja polimera i deaktiviranog organometalnog katalizatora iz izlazne struje kako bi se dobilo talog koji sadrži sorbens, polimer i deaktivirani katalizator.
2. Postupak u skladu s patentnim zahtjevom 1, naznačen time što je deaktivirajuće sredstvo prisutno u količini između 5 % i 10 %, težinski.
3. Postupak u skladu s patentnim zahtjevom 1 ili 2, naznačen time što se reakcija oligomerizacije olefina sastoji u trimerizaciji etilena u 1-heksen.
4. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što čestice sorbensa sadrže čestice koje se bira iz skupine koju čine čestice aluminijevog oksida, čestice silicijevog dioksida i njihove kombinacije.
5. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što 40 % čestica sorbensa ima veličinu čestica u rasponu od 10 µm do 60 µm.
6. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što čestice sorbensa imaju površinu veću od 10 m2/g.
7. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što se čestice sorbensa unosi u izlaznu struju u obliku suspenzije u otapalu.
8. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što se čestice sorbensa unosi u izlaznu struju u količini između 0,1 g i 1,0 g čestica sorbensa po 1 kg izlazne struje.
9. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što deaktivirajuće sredstvo sadrži vodu.
10. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što se izlazna struja ohladi istodobno s unošenjem čestica sorbensa u izlaznu struju.
11. Postupak u skladu s bilo kojim od patentnih zahtjeva 1-9, naznačen time što se izlazna struja ohladi nakon unošenja čestice sorbensa u izlaznu struju.
12. Postupak u skladu s patentnim zahtjevom 1, naznačen time što talog sadrži čestice taloga veličine čestica u rasponu od 1 µm do 1000 µm.
13. Postupak u skladu s patentnim zahtjevom 12, naznačen time što manje od 8 % čestica taloga ima veličinu čestica manju od 10 µm.
14. Postupak u skladu s patentnim zahtjevom 12, naznačen time što manje od 0,8 % čestica taloga ima veličinu čestica manju od 5 µm.
15. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što dodatno uključuje odvajanje taloga od izlazne struje kako bi se dobilo pročišćeni proizvod.
HRP20190717TT 2014-12-23 2019-04-16 Postupci taloženja polimera i deaktiviranog organometalnog katalizatora u reakciji oligomerizacije olefina HRP20190717T1 (hr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14882180.4A EP3237364B1 (en) 2014-12-23 2014-12-23 Methods of precipitating polymer and deactivated organometallic catalyst in an olefin oligomerization reaction
PCT/RU2014/000972 WO2016105226A1 (en) 2014-12-23 2014-12-23 Methods of precipitating polymer and deactivated organometallic catalyst in an olefin oligomerization reaction

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HRP20190717T1 true HRP20190717T1 (hr) 2019-07-12

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US (1) US9975822B2 (hr)
EP (1) EP3237364B1 (hr)
JP (1) JP6666351B2 (hr)
KR (1) KR102113798B1 (hr)
CN (1) CN107207382B (hr)
CA (1) CA2971693C (hr)
DK (1) DK3237364T3 (hr)
EA (1) EA033757B1 (hr)
HR (1) HRP20190717T1 (hr)
MX (1) MX2017008374A (hr)
WO (1) WO2016105226A1 (hr)

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WO2016105227A1 (en) 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of preparing oligomers of an olefin
US10099970B2 (en) 2014-12-23 2018-10-16 Public Joint Stock Company “SIBUR Holding” Methods of preparing oligomers of an olefin
CN110431125A (zh) * 2017-03-14 2019-11-08 沙特阿拉伯石油公司 乙烯低聚反应生成α-烯烃的方法
SG11202108363RA (en) * 2019-02-22 2021-08-30 Sibur Holding Public Joint Stock Co A method for separating olefin oligomerization products (variants)
CN113966319B (zh) * 2019-05-01 2023-12-19 雪佛龙美国公司 通过离子催化剂低聚的基础油合成及低聚催化剂无水分离
JP7366486B2 (ja) * 2020-09-07 2023-10-23 エルジー・ケム・リミテッド オリゴマーの製造方法
KR20220104418A (ko) * 2021-01-18 2022-07-26 주식회사 엘지화학 올리고머 제조방법
CN116249580A (zh) * 2021-10-08 2023-06-09 株式会社Lg化学 反应溶液转移系统
KR20240102561A (ko) * 2022-12-26 2024-07-03 한화토탈에너지스 주식회사 올레핀의 올리고머화 반응기 내 고분자 제거방법

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KR102113798B1 (ko) 2020-05-21
US20170349509A1 (en) 2017-12-07
EA033757B1 (ru) 2019-11-22
EP3237364A1 (en) 2017-11-01
WO2016105226A1 (en) 2016-06-30
CA2971693A1 (en) 2016-06-30
EA201791447A1 (ru) 2017-10-31
CA2971693C (en) 2019-09-24
EP3237364B1 (en) 2019-03-06
JP2018502088A (ja) 2018-01-25
DK3237364T3 (da) 2019-05-13
CN107207382A (zh) 2017-09-26
JP6666351B2 (ja) 2020-03-13
US9975822B2 (en) 2018-05-22
CN107207382B (zh) 2021-06-18
KR20170098282A (ko) 2017-08-29
MX2017008374A (es) 2018-04-24

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