HRP20151395T1 - Procjenjivanje katalizatora u mulju i pahuljica mulja - Google Patents
Procjenjivanje katalizatora u mulju i pahuljica mulja Download PDFInfo
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- HRP20151395T1 HRP20151395T1 HRP20151395TT HRP20151395T HRP20151395T1 HR P20151395 T1 HRP20151395 T1 HR P20151395T1 HR P20151395T T HRP20151395T T HR P20151395TT HR P20151395 T HRP20151395 T HR P20151395T HR P20151395 T1 HRP20151395 T1 HR P20151395T1
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- Prior art keywords
- metal
- catalyst
- hydrocarbon feedstock
- raw material
- hydrocarbon
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims 13
- 239000002002 slurry Substances 0.000 title 2
- 229910052751 metal Inorganic materials 0.000 claims 27
- 239000002184 metal Substances 0.000 claims 27
- 238000000034 method Methods 0.000 claims 16
- 239000004215 Carbon black (E152) Substances 0.000 claims 14
- 229930195733 hydrocarbon Natural products 0.000 claims 14
- 150000002430 hydrocarbons Chemical class 0.000 claims 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 6
- 239000002994 raw material Substances 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- 230000002378 acidificating effect Effects 0.000 claims 4
- 238000001354 calcination Methods 0.000 claims 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 229910052742 iron Inorganic materials 0.000 claims 3
- 229910052759 nickel Inorganic materials 0.000 claims 3
- 239000002244 precipitate Substances 0.000 claims 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- 238000001556 precipitation Methods 0.000 claims 2
- 239000013049 sediment Substances 0.000 claims 2
- 239000010802 sludge Substances 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- 239000002351 wastewater Substances 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910000990 Ni alloy Inorganic materials 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 230000003113 alkalizing effect Effects 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- VAWNDNOTGRTLLU-UHFFFAOYSA-N iron molybdenum nickel Chemical compound [Fe].[Ni].[Mo] VAWNDNOTGRTLLU-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B61/00—Obtaining metals not elsewhere provided for in this subclass
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/10—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles
- C10G49/12—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles suspended in the oil, e.g. slurries
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/22—Separation of effluents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/026—Obtaining nickel or cobalt by dry processes from spent catalysts
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
- C22B34/225—Obtaining vanadium from spent catalysts
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/34—Obtaining molybdenum
- C22B34/345—Obtaining molybdenum from spent catalysts
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/007—Wet processes by acid leaching
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/42—Hydrogen of special source or of special composition
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/706—Catalytic metal recovery
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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Claims (15)
1. Postupak recikliranja molibdena, vanadija i nikla koji se nalaze u potrošenom katalizatoru i/ili ugljikovodičnoj sirovini koja sadrži metal, naznačen time što se navedeni potrošeni katalizator i/ili ugljikovodična sirovina koja sadrži metal uzastopno podvrgava
(i) kalciniranju, koje se provodi kako bi se prikupilo ugljični monoksid i vodik, te uklonilo materijal koji sadrži ugljik,
(ii) ispiranju vodom sirovog plina dobivenog u koraku kalciniranja (i), uz dobivanje otpadne vode,
(iii) taloženju prvog taloga zakiseljavanjem navedene otpadne voda pod kiselim pH sumpornom kiselinom, uz dodatak (FeCl(SO4)), gdje se dobiva kisela voda, te se odvoji navedeni prvi talog od navedene kisele vode,
(iv) taloženju drugog taloga zaluživanjem navedene kisele vode pod alkalnim pH natrijevim hidroksidom, uz dodatak (FeCl(SO4)), gdje se dobiva alkalna voda, te se odvoji navedeni drugi talog,
gdje prvi i/ili drugi talog se dodaje u rastaljeno željezo, čime se dobije divanadijev pentoksid (V2O5) i reducirana legura željezo-molibden-nikal.
2. Postupak u skladu s patentnim zahtjevom 1, naznačen time što se (v) navedena alkalna voda dodatno neutralizira kiselinom.
3. Postupak u skladu s bilo kojim od patentnih zahtjeva 1 do 2, naznačen time što se navedeni potrošeni katalizator i/ili ugljikovodičnu sirovinu koja sadrži metal dobiva obradom ugljikovodične sirovine koja sadrži metal što se dobiva iz industrijske jedinice uz upotrebu katalizatora koji sadrži metal, gdje se prije koraka (i) navedeni potrošeni katalizator i/ili ugljikovodična sirovina koja sadrži metal prikuplja i obrađuje kako bi se dobilo ugljični monoksid, vodik i ostatak koji sadrži metal, gdje se navedeni ostatak koji sadrži metal obrađuje u koracima (i) do (iv).
4. Postupak u skladu s patentnim zahtjevom 3, naznačen time što je obrada navedenog potrošenog katalizatora i/ili ugljikovodična sirovina koja sadrži metal prije koraka (i) kalciniranje.
5. Postupak u skladu s patentnim zahtjevom 4, naznačen time što je obrada kalciniranje u uvjetima djelomičnog oksidiranja.
6. Postupak u skladu s bilo kojim od patentnih zahtjeva 3 do 5, naznačen time što je industrijska jedinica pogon za obradu mulja.
7. Postupak u skladu s bilo kojim od patentnih zahtjeva 3 do 6, naznačen time što se ugljikovodična sirovina koja sadrži metal dobiva iz reaktora industrijske jedinice.
8. Postupak u skladu s bilo kojim od patentnih zahtjeva 1 do 7, naznačen time što se svakog od metala koji se nalazi u katalizatoru koji sadrži metal ili u potrošenom katalizatoru koji sadrži metal i metal koji se nalazi u ugljikovodičnoj sirovini koja sadrži metal ili u preostaloj ugljikovodičnoj sirovini koja sadrži metal neovisno bira između aluminija, kositra, prijelaznih metala i njihovih kombinacija.
9. Postupak u skladu s patentnim zahtjevom 8, naznačen time što se metal koji se nalazi u katalizatoru koji sadrži metal ili u potrošenom katalizatoru koji sadrži metal bira između aluminija, željeza, molibdena, volframa, nikla, kobalta i njihovih kombinacija.
10. Postupak u skladu s patentnim zahtjevom 8, naznačen time što se metal koji se nalazi u ugljikovodičnoj sirovini koja sadrži metal ili u preostaloj ugljikovodičnoj sirovini koja sadrži metal bira između vanadija, nikla, kobalta, željeza, te njihovih kombinacija.
11. Postupak u skladu s bilo kojim od patentnih zahtjeva 3 do 10, naznačen time što se vodik upotrebljava za hidrokonverziju ugljikovodične sirovine koja sadrži metal.
12. Postupak u skladu s bilo kojim od patentnih zahtjeva 3 do 11, naznačen time što se ostatak koji sadrži metal reciklira kako bi se dobilo svježi katalizator koji sadrži metal.
13. Postupak u skladu s bilo kojim od patentnih zahtjeva 1 do 12, naznačen time što se dobiveni vodik upotrebljava za hidrokonverziju ugljikovodične sirovine u reaktorima s muljem.
14. Postupak u skladu s bilo kojim od patentnih zahtjeva 6 do 13, naznačen time što se navedeni potrošeni katalizator koji sadrži metal i preostala ugljikovodična sirovina koja sadrži metal dobiva iz ostatka nakon deasfaltiranja.
15. Postupak dobivanja vodika, naznačen time što se sastoji u upotrebi postupka u skladu s bilo kojim od patentnih zahtjeva 1 do 14.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP20100305742 EP2404981A1 (en) | 2010-07-06 | 2010-07-06 | Slurry catalyst and slurry flakes valorization |
| PCT/EP2011/061366 WO2012004284A2 (en) | 2010-07-06 | 2011-07-06 | Slurry catalyst and slurry flakes valorization |
| EP11738656.5A EP2591076B1 (en) | 2010-07-06 | 2011-07-06 | Slurry catalyst and slurry flakes valorization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20151395T1 true HRP20151395T1 (hr) | 2016-01-15 |
Family
ID=43502824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20151395TT HRP20151395T1 (hr) | 2010-07-06 | 2015-12-21 | Procjenjivanje katalizatora u mulju i pahuljica mulja |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9045814B2 (hr) |
| EP (2) | EP2404981A1 (hr) |
| JP (1) | JP5896537B2 (hr) |
| KR (1) | KR101893435B1 (hr) |
| CN (1) | CN103080277B (hr) |
| DK (1) | DK2591076T3 (hr) |
| ES (1) | ES2556753T3 (hr) |
| HR (1) | HRP20151395T1 (hr) |
| HU (1) | HUE028224T2 (hr) |
| PL (1) | PL2591076T3 (hr) |
| PT (1) | PT2591076E (hr) |
| RS (1) | RS54460B1 (hr) |
| WO (1) | WO2012004284A2 (hr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8912111B2 (en) * | 2012-08-07 | 2014-12-16 | Uop Llc | Process for catalyst recovery and optional recycle in a slurry hydrocracking process |
| FR3015514B1 (fr) | 2013-12-23 | 2016-10-28 | Total Marketing Services | Procede ameliore de desaromatisation de coupes petrolieres |
| CN104371780B (zh) * | 2014-11-03 | 2016-06-08 | 中国华能集团清洁能源技术研究院有限公司 | 风、光弃电和工业有机废水用于煤制天然气的系统及方法 |
| KR101727891B1 (ko) | 2016-05-20 | 2017-04-18 | (주)티피에스 | 정유 탈황 폐촉매로부터 몰리브덴 회수를 위한 친환경 습식공정 |
| WO2018083715A1 (en) * | 2016-11-07 | 2018-05-11 | Hindustan Petroleum Corporation Limited | Process for producing lighter distillates |
| US11732204B2 (en) * | 2019-11-04 | 2023-08-22 | Saudi Arabian Oil Company | Syngas production and recovery of active phase metals from gasifier slag containing spent catalyst |
| CN111014247B (zh) * | 2019-12-24 | 2021-04-02 | 青岛大学 | 一种重油悬浮床加氢固体废弃物的高值化利用工艺 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4592827A (en) * | 1983-01-28 | 1986-06-03 | Intevep, S.A. | Hydroconversion of heavy crudes with high metal and asphaltene content in the presence of soluble metallic compounds and water |
| GB2142930B (en) * | 1983-03-19 | 1987-07-01 | Asahi Chemical Ind | A process for cracking a heavy hydrocarbon |
| US4824821A (en) * | 1983-08-29 | 1989-04-25 | Chevron Research Company | Dispersed group VIB metal sulfide catalyst promoted with Group VIII metal |
| US6190542B1 (en) | 1996-02-23 | 2001-02-20 | Hydrocarbon Technologies, Inc. | Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds |
| JPH09263843A (ja) * | 1996-03-29 | 1997-10-07 | Taiheiyo Kinzoku Kk | Ｎｉ廃触媒からの有価金属含有液回収方法 |
| US5954945A (en) | 1997-03-27 | 1999-09-21 | Bp Amoco Corporation | Fluid hydrocracking catalyst precursor and method |
| ITMI20020197A1 (it) * | 2002-02-05 | 2003-08-05 | Francesco Corigliano | Procedimento di trattamento dei residui metalliferi negli impianti digassificazione dei tar petroliferi |
| US7915191B2 (en) * | 2005-11-16 | 2011-03-29 | Uop Llc | Three-stage counter-current FCC regenerator |
-
2010
- 2010-07-06 EP EP20100305742 patent/EP2404981A1/en not_active Withdrawn
-
2011
- 2011-07-06 PT PT117386565T patent/PT2591076E/pt unknown
- 2011-07-06 CN CN201180039132.XA patent/CN103080277B/zh not_active Expired - Fee Related
- 2011-07-06 PL PL11738656T patent/PL2591076T3/pl unknown
- 2011-07-06 US US13/808,466 patent/US9045814B2/en not_active Expired - Fee Related
- 2011-07-06 WO PCT/EP2011/061366 patent/WO2012004284A2/en active Application Filing
- 2011-07-06 DK DK11738656.5T patent/DK2591076T3/en active
- 2011-07-06 EP EP11738656.5A patent/EP2591076B1/en not_active Not-in-force
- 2011-07-06 ES ES11738656.5T patent/ES2556753T3/es active Active
- 2011-07-06 HU HUE11738656A patent/HUE028224T2/en unknown
- 2011-07-06 JP JP2013517370A patent/JP5896537B2/ja not_active Expired - Fee Related
- 2011-07-06 KR KR1020137003200A patent/KR101893435B1/ko active IP Right Grant
- 2011-07-06 RS RS20150851A patent/RS54460B1/en unknown
-
2015
- 2015-12-21 HR HRP20151395TT patent/HRP20151395T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RS54460B1 (en) | 2016-06-30 |
| EP2591076B1 (en) | 2015-09-23 |
| ES2556753T3 (es) | 2016-01-20 |
| JP5896537B2 (ja) | 2016-03-30 |
| KR20130041934A (ko) | 2013-04-25 |
| CN103080277A (zh) | 2013-05-01 |
| HUE028224T2 (en) | 2016-12-28 |
| WO2012004284A3 (en) | 2012-05-03 |
| US9045814B2 (en) | 2015-06-02 |
| PT2591076E (pt) | 2015-12-16 |
| DK2591076T3 (en) | 2016-01-11 |
| KR101893435B1 (ko) | 2018-08-31 |
| US20130150232A1 (en) | 2013-06-13 |
| WO2012004284A2 (en) | 2012-01-12 |
| CN103080277B (zh) | 2015-05-20 |
| EP2404981A1 (en) | 2012-01-11 |
| JP2013538283A (ja) | 2013-10-10 |
| EP2591076A2 (en) | 2013-05-15 |
| PL2591076T3 (pl) | 2016-03-31 |
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