HRP20150561T1 - Postupak kristalizacije spoja topivog u vodi - Google Patents
Postupak kristalizacije spoja topivog u vodi Download PDFInfo
- Publication number
- HRP20150561T1 HRP20150561T1 HRP20150561TT HRP20150561T HRP20150561T1 HR P20150561 T1 HRP20150561 T1 HR P20150561T1 HR P20150561T T HRP20150561T T HR P20150561TT HR P20150561 T HRP20150561 T HR P20150561T HR P20150561 T1 HRP20150561 T1 HR P20150561T1
- Authority
- HR
- Croatia
- Prior art keywords
- water
- solution
- alcohol
- crystallization
- sucrose
- Prior art date
Links
- 238000002425 crystallisation Methods 0.000 title claims 23
- 238000000034 method Methods 0.000 title claims 21
- 150000001875 compounds Chemical class 0.000 title claims 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 23
- 230000008025 crystallization Effects 0.000 claims 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 20
- 239000000243 solution Substances 0.000 claims 17
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 14
- 229930006000 Sucrose Natural products 0.000 claims 14
- 239000005720 sucrose Substances 0.000 claims 14
- 239000000203 mixture Substances 0.000 claims 10
- 239000002028 Biomass Substances 0.000 claims 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 6
- 239000007787 solid Substances 0.000 claims 6
- 238000001704 evaporation Methods 0.000 claims 5
- 230000008020 evaporation Effects 0.000 claims 5
- 238000000855 fermentation Methods 0.000 claims 5
- 239000013078 crystal Substances 0.000 claims 4
- 230000004151 fermentation Effects 0.000 claims 4
- 239000002594 sorbent Substances 0.000 claims 4
- 238000001179 sorption measurement Methods 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims 2
- 235000006549 Arenga pinnata Nutrition 0.000 claims 2
- 244000208235 Borassus flabellifer Species 0.000 claims 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 239000002551 biofuel Substances 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- 239000002808 molecular sieve Substances 0.000 claims 2
- 238000004064 recycling Methods 0.000 claims 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical group [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 2
- YTAHJIFKAKIKAV-XNMGPUDCSA-N [(1R)-3-morpholin-4-yl-1-phenylpropyl] N-[(3S)-2-oxo-5-phenyl-1,3-dihydro-1,4-benzodiazepin-3-yl]carbamate Chemical compound O=C1[C@H](N=C(C2=C(N1)C=CC=C2)C1=CC=CC=C1)NC(O[C@H](CCN1CCOCC1)C1=CC=CC=C1)=O YTAHJIFKAKIKAV-XNMGPUDCSA-N 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 150000001720 carbohydrates Chemical class 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 238000003795 desorption Methods 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 238000011049 filling Methods 0.000 claims 1
- 125000000311 mannosyl group Chemical group C1([C@@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
- F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
- F02B43/12—Methods of operating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/005—Selection of auxiliary, e.g. for control of crystallisation nuclei, of crystal growth, of adherence to walls; Arrangements for introduction thereof
- B01D9/0054—Use of anti-solvent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
- C07H1/06—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
- C07H3/04—Disaccharides
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
- C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
- C12P5/023—Methane
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/06—Ethanol, i.e. non-beverage
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/16—Butanols
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B30/00—Crystallisation; Crystallising apparatus; Separating crystals from mother liquors ; Evaporating or boiling sugar juice
- C13B30/02—Crystallisation; Crystallising apparatus
- C13B30/021—Crystallisation; Crystallising apparatus using chemicals
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B30/00—Crystallisation; Crystallising apparatus; Separating crystals from mother liquors ; Evaporating or boiling sugar juice
- C13B30/02—Crystallisation; Crystallising apparatus
- C13B30/022—Continuous processes, apparatus therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/30—Use of alternative fuels, e.g. biofuels
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Biotechnology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- Microbiology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
Claims (16)
1. Postupak kristalizacije spoja topivog u vodi iz otopine koji sadrži sljedeće korake:
a) pružanje, u posudi za kristalizaciju, otopine spoja topivog u vodi u mješavini vode i otopine u kojoj spoj topiv u vodi ima slabiju topljivost nego u vodi;
b) provođenje faze isparavanja mješavine kroz sorpcijsku zonu koja sadrži sorpcijsko sredstvo za vodenu paru kako bi selektivno adsorbiralo vodu iz faze isparavanja kako bi se u fazi isparavanja izdvojila voda i povećao udio otopine i vodom zasićenog vodenog sorpcijskog sredstva;
c) obogaćivanje mješavine u posudi za kristalizaciju recikliranjem barem dijela faze isparavanja tijekom kojeg je izdvojen dio vode i povećan udio otopine u posudu za kristalizaciju ili povlačenjem faze isparavanja tijekom koje je izdvojen dio vode iz postupka i dodavanjem otopine iz vanjskog izvora u posudu za kristalizaciju;
d) omogućavanje čvrstim kristalima iz spoja topivog u vodi da se istalože iz otopine u posudi za kristalizaciju na temperature kristalizacije; i
e) ispuštanje iskristaliziranih čvrstih kristala iz otopine topive u vodi iz posude za kristalizaciju i otpuštanje nekristalizirane otopine spoja u mješavini vodene otopine iz posude za kristalizaciju.
2. Postupak sukladno Zahtjevu 1, pri čemu je otopina topiva u vodi saharid s jednom do pet jedinica manoze.
3. Postupak sukladno Zahtjevu 2, pri čemu je otopina topiva u vodi saharoza.
4. Postupak sukladno bilo kojem od prethodnih Zahtjeva, pri čemu je otopina alkohol s jednim do četiri atoma ugljika ili mješavinom od dva ili više njih.
5. Postupak sukladno Zahtjevima 3 i 4, pri čemu je alkohol etanol ili 1-butanol
6. Postupak sukladno Zahtjevu 5 pri čemu je alkohol etanol.
7. Postupak proizvodnje kristala saharoze iz soka šećerne palme koji sadrži postupak kristalizacije sukladno bilo kojem od zahtjeva 4 do 6, pri čemu je otopina saharoze u mješavini vode i alkohola u posudi za kristalizaciju pružena (korak a) otapanjem soka šećerne palme s alkoholom ili vodom i alkoholom i unošenjem razrijeđenog soka u posudu za kristalizaciju.
8. Postupak proizvodnje kristala saharoze iz biomase koja sadrži saharozu koji se sastoji od kristalizacijskog postupka sukladno bilo kojem od Zahtjeva 4 do 6, pri čemu je otopina saharoze u mješavini vode i alkohola u posudi za kristalizaciju pružena pomoću (korak a):
a1) izdvajanje zdrobljene biomase koja sadrži saharozu s vodenom tekućinom izdvojenom iz vode ili mješavine vode i alkohola kako bi se dobila otopina saharoze u vodenoj tekućini ili čvrstoj izdvojenom biomasi koja sadrži preostalu saharozu;
a2) odvajanje otopine saharoze iz čvrste izdvojene biomase; i
a3) unošenje otopine u posudu za kristalizaciju ili, u slučaju da je vodena otopina voda, unošenje vode i alkoholne pare u posudu za kristalizaciju.
9. Postupak sukladno Zahtjevu 8 pri čemu je alkohol etanol ili 1-butanol, što je postupak za proizvodnju kristalizanje saharoze i alkohola, koji se nadalje sastoji od sljedećih koraka:
f) fermentiranje najmanje dijela preostale saharoze u čvrstu izdvojenu biomasu i/ili nekristaliziranu saharozu ispuštenu iz posude za kristalizaciju u koraku e) u alkohol kako bi postigli fermentacijski spoj koji sadrži alkohol:
g) odvajanje barem dijela alkohola dobivenog fermentacijom u koraku f) iz spoja kako bi dobili alkoholni proizvod.
10. Postupak sukladno Zahtjevu 9, nadalje se sastoji od sljedećih koraka:
h) reckliranje dijela alkohola proizvedenog u koraku f) u ekstrakciju koraka a1) i/ili posudu za kristalizaciju.
11. Postupak sukladno jednom od Zahtjeva 8 do 10, nadalje sadrži sljedeće korake:
i) anaerobno fermentiranje fermentacijske smjese iz koje je izdvojen alkohol u koraku g) i/ili čvrste izdvojene biomase, po mogućnosti zajedno s lišćem i malim česticama biomase koja sadrži saharozu, kako bi se dobilo bio gorivo;
j) punjenje motora bio gorivom dobivenim u koraku i) kako bi se proizvela energija i toplina.
12. Postupak sukladno Zahtjevu 11, nadalje sadrži sljedeći korak:
k) desorpcija vode iz zasićene vodene pare sorpcijskog sredstva dobivenog u koraku b) zagrijavanjem zasićenog sorpcijskog sredstva vodene pare pomoću topline proizvedene u koraku j) kako bi se dobilo regenerirano sorpcijsko sredstvo vodene pare i para.
13. Postupak sukladno Zahtjevu 12, nadalje sadrži sljedeći korak:
l) pomoću pare dobivene u koraku k) kako bi se odvojio barem dio alkohola iz fermentacijske smjese u koraku g) pomoću skidanja ili destilacije i/ili zagrijavanjem posude za kristalizaciju na temperaturu kristalizacije.
14. Postupak sukladno bilo kojem od prethodnih Zahtjeva, pri čemu je sorpcijsko sredstvo vodene pare molekularno sito.
15. Postupak sukladno zahtjevu 14, pri čemu je sorpcijsko sredstvo vodene pare molekularno sito s porama minimalnog promjera od 3.0 do 3.5 Å
16. Postupak sukladno bilo kojem od prethodnih Zahtjeva, pri čemu je temperatura kristalizacije od 60 do 90 °C.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL2006447A NL2006447C2 (en) | 2011-03-22 | 2011-03-22 | Process for the crystallisation of a water-soluble compound. |
| EP12711986.5A EP2689039B1 (en) | 2011-03-22 | 2012-03-19 | Process for the crystallisation of a water-soluble compound |
| PCT/NL2012/050169 WO2012128624A1 (en) | 2011-03-22 | 2012-03-19 | Process for the crystallisation of a water-soluble compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20150561T1 true HRP20150561T1 (hr) | 2015-08-14 |
Family
ID=45928985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20150561TT HRP20150561T1 (hr) | 2011-03-22 | 2015-05-26 | Postupak kristalizacije spoja topivog u vodi |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US9255301B2 (hr) |
| EP (1) | EP2689039B1 (hr) |
| AU (1) | AU2012231892B2 (hr) |
| BR (1) | BR112013024121B1 (hr) |
| CA (1) | CA2830644C (hr) |
| CO (1) | CO6811871A2 (hr) |
| DK (1) | DK2689039T3 (hr) |
| ES (1) | ES2543441T3 (hr) |
| HR (1) | HRP20150561T1 (hr) |
| HU (1) | HUE025320T2 (hr) |
| NL (1) | NL2006447C2 (hr) |
| PL (1) | PL2689039T3 (hr) |
| PT (1) | PT2689039E (hr) |
| WO (1) | WO2012128624A1 (hr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2020952B1 (en) | 2018-05-17 | 2019-11-25 | Stichting Wageningen Res | Method for producing inositol and inorganic phosphate |
| DE102020210071A1 (de) * | 2020-08-07 | 2022-02-10 | Südzucker AG | Verbesserte Rübenzucker-Saccharosepräparation |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3503803A (en) * | 1968-03-22 | 1970-03-31 | Whiting Corp | Continuous production of crystalline sucrose |
| GB8406734D0 (en) * | 1984-03-15 | 1984-04-18 | Tate & Lyle Plc | Sugar process |
| ES2158419T3 (es) * | 1996-10-14 | 2001-09-01 | Bayer Ag | Procedimiento de obtencion de esteres o de alcoholatos con separacion de agua. |
| BR0103406A (pt) * | 2001-08-15 | 2004-05-04 | Getec Guanabara Quimica Ind S | Processo de produção de frutose cristalina de elevada pureza utilizando xarope com baixo teor de frutose originária de sacarose, e produto obtido |
| BRPI0705181A2 (pt) * | 2007-10-16 | 2009-06-16 | Dedini Sa Ind De Base | processo e equipamento para cristalização de açúcar por resfriamento controlado |
-
2011
- 2011-03-22 NL NL2006447A patent/NL2006447C2/en not_active IP Right Cessation
-
2012
- 2012-03-19 PT PT127119865T patent/PT2689039E/pt unknown
- 2012-03-19 AU AU2012231892A patent/AU2012231892B2/en not_active Ceased
- 2012-03-19 US US14/006,459 patent/US9255301B2/en not_active Expired - Fee Related
- 2012-03-19 EP EP12711986.5A patent/EP2689039B1/en active Active
- 2012-03-19 WO PCT/NL2012/050169 patent/WO2012128624A1/en active Application Filing
- 2012-03-19 PL PL12711986T patent/PL2689039T3/pl unknown
- 2012-03-19 HU HUE12711986A patent/HUE025320T2/en unknown
- 2012-03-19 ES ES12711986.5T patent/ES2543441T3/es active Active
- 2012-03-19 DK DK12711986.5T patent/DK2689039T3/en active
- 2012-03-19 BR BR112013024121A patent/BR112013024121B1/pt not_active IP Right Cessation
- 2012-03-19 CA CA2830644A patent/CA2830644C/en not_active Expired - Fee Related
-
2013
- 2013-09-20 CO CO13224193A patent/CO6811871A2/es active IP Right Grant
-
2015
- 2015-05-26 HR HRP20150561TT patent/HRP20150561T1/hr unknown
- 2015-12-16 US US14/971,431 patent/US9810144B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP2689039B1 (en) | 2015-05-13 |
| AU2012231892B2 (en) | 2017-04-13 |
| US20160097321A1 (en) | 2016-04-07 |
| CO6811871A2 (es) | 2013-12-16 |
| AU2012231892A1 (en) | 2013-09-26 |
| DK2689039T3 (en) | 2015-06-29 |
| BR112013024121A2 (pt) | 2017-06-06 |
| US9810144B2 (en) | 2017-11-07 |
| US20140087437A1 (en) | 2014-03-27 |
| CA2830644A1 (en) | 2012-09-27 |
| ES2543441T3 (es) | 2015-08-19 |
| PT2689039E (pt) | 2015-08-17 |
| NL2006447C2 (en) | 2012-09-25 |
| PL2689039T3 (pl) | 2015-10-30 |
| HUE025320T2 (en) | 2016-02-29 |
| WO2012128624A9 (en) | 2013-01-10 |
| CA2830644C (en) | 2020-02-18 |
| BR112013024121B1 (pt) | 2019-12-10 |
| WO2012128624A1 (en) | 2012-09-27 |
| US9255301B2 (en) | 2016-02-09 |
| EP2689039A1 (en) | 2014-01-29 |
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