HRP20110641T4 - Kristalna modifikacija fipronila - Google Patents
Kristalna modifikacija fipronila Download PDFInfo
- Publication number
- HRP20110641T4 HRP20110641T4 HRP20110641TT HRP20110641T HRP20110641T4 HR P20110641 T4 HRP20110641 T4 HR P20110641T4 HR P20110641T T HRP20110641T T HR P20110641TT HR P20110641 T HRP20110641 T HR P20110641T HR P20110641 T4 HRP20110641 T4 HR P20110641T4
- Authority
- HR
- Croatia
- Prior art keywords
- crystalline modification
- mixture
- fipronil
- modification
- solid
- Prior art date
Links
- 238000012986 modification Methods 0.000 title claims 21
- 230000004048 modification Effects 0.000 title claims 21
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 title claims 14
- 239000005899 Fipronil Substances 0.000 title claims 14
- 229940013764 fipronil Drugs 0.000 title claims 14
- 239000000203 mixture Substances 0.000 claims 13
- 239000007787 solid Substances 0.000 claims 8
- 238000000034 method Methods 0.000 claims 7
- 230000000590 parasiticidal effect Effects 0.000 claims 5
- 230000000361 pesticidal effect Effects 0.000 claims 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 4
- 239000013078 crystal Substances 0.000 claims 4
- 238000002360 preparation method Methods 0.000 claims 4
- 241001465754 Metazoa Species 0.000 claims 2
- 238000002425 crystallisation Methods 0.000 claims 2
- 230000008025 crystallization Effects 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 2
- 230000008018 melting Effects 0.000 claims 2
- 229910002483 Cu Ka Inorganic materials 0.000 claims 1
- 208000030852 Parasitic disease Diseases 0.000 claims 1
- 238000002441 X-ray diffraction Methods 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 claims 1
- 239000013543 active substance Substances 0.000 claims 1
- 239000000969 carrier Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 244000045947 parasite Species 0.000 claims 1
- 230000036281 parasite infection Effects 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 claims 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/10—Anthelmintics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Organic Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Tropical Medicine & Parasitology (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Moulding By Coating Moulds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Claims (17)
1. Kristalna modifikacija IV fipronila koja sadrži ko-kristalizirani aceton, koja na snimci drifrakcije rendgenskog zračenja praška simljenog pomoću Cu-Ka zračenja na 25°C pokazuje barem sljedeće otklone:
(1) 2θ = 7.8 ± 0.2°
(2) 2θ = 9.8 ± 0.2°
(3) 2θ = 11.6 ± 0.2°
(4) 2θ = 13.7 ± 0.2°
(5) 2θ = 16.8 ± 0.2°
(6) 2θ = 19.3 ± 0.2°
(7) 2θ = 24.8 ± 0.2°
(8) 2θ = 29.4 ± 0.2°
2. Kristalna modifikacija IV prema zahtjevu 1 prisutna u trikliničkom sustavu sa centrosimetričnom prostornom skupinom P-1.
3. Kristalna modifikacija IV prema zahtjevu 1 ili zahtjevu 2 sa sadržajem fipronila od barem 98% težinski.
4. Kruti fipronil koji sadrži kristalnu modifikaciju IV prema bilo kojem od zahtjeva 1 do 3 i oblik fipronila različit od kristalne modifikacije IV.
5. Kruti fipronil prema zahtjevu 4 koji sadrži kristalnu modifikaciju IV prema bilo kojem od zahtjeva 1 do 3 barem 85% težinski.
6. Postupak pripreme kristalne modifikacije IV prema bilo kojem od zahtjeva 1 do 3, obuhvaća korake:
korak i) priprema otopine krutog oblika fipronila, koji je različit od kristalne modifikacije IV, u acetonu;
korak ii) djelovanje na kristalizaciju fipronila; i
korak iii) izdvajanje dobivenog taloga.
7. Postupak prema zahtjevu 6 gdje se, u koraku ii), na kristalizaciju fipronila djeluje dodavanjem otapala koje smanjuje topljivost.
8. Postupak prema zahtjevima 6 ili 7, gdje se korak ii) provodi u prisutnosti klice kristala kristalne modifikacije IV prema bilo kojem od zahtjeva 1 do 4.
9. Postupak pripreme kristalne modifikacije V s talištem na 202 do 203°C tako što se obrađuje kristalna modifikacija IV prema zahtjevima 1 do 3 na barem 100°C.
10. Postupak pripreme kristalne modifikacije I s talištem na 196 do 197°C tako što se obrađuje kristalna modifikacija IV prema zahtjevima 1 do 3 na 90 do 100°C.
11. Sinergijska pesticidna ili paraziticidna smjesa koja kao djelatne tvari sadrži kristalnu modifikaciju IV prema bilo kojem od zahtjeva 1 do 3 i jedan ili više pesticidnih ili paraziticidnih spojeva.
12. Pesticidna ili paraziticidna smjesa koja sadrži kristalnu modifikaciju IV prema bilo kojem od zahtjeva 1 do 3 ili smjesu kako je definirana u zahtjevu 11 te pesticidne ili paraziticidne prikladne nosače i/ili pomoćne tvari.
13. Ne-terapijska uporaba kristalne modifikacije IV prema bilo kojem od zahtjeva 1 do 3 ili krutog fipronila definiranog prema zahtjevima 4 ili 5 ili smjese definirane u zahtjevu 11 ili smjese definirane u zahtjevu 12 za kontrolu nametnika.
14. Postupak zaštite sjemena koji obuhvaća dovođenje sjemena u doticaj s kristalnom modifikacijom IV prema bilo kojem od zahtjeva 1 do 3 ili krutim fipronilom definiranim prema zahtjevima 4 ili 5 ili smjesom definiranom u zahtjevu 11 ili smjesom definiranom u zahtjevu 12 u količinama koje imaju učinkovito pesticidno djelovanje.
15. Sjeme koje sadrži kristalnu modifikaciju IV prema bilo kojem od zahtjeva 1 do 3 ili kruti fipronil prema zahtjevima 4 ili 5 ili smjesu prema zahtjevu 11 u količini od 0.1 g do 10 kg po 100 kg sjemena.
16. Kristalna modifikacija IV prema bilo kojem od zahtjeva 1 do 3 ili kruti fipronil prema zahtjevima 4 ili 5 ili smjesa prema zahtjevu 11 ili smjesa prema zahtjevu 12 za borbu protiv parazita u i na životinjama.
17. Postupak pripreme smjese za tretiranje, kontrolu, sprečavanje ili zaštitu životinja od zaraze parazitima koja sadrži učinkovitu paraziticidnu količinu kristalne modifikacije IV prema bilo kojem od zahtjeva 1 do 3 ili kruti fipronil prema zahtjevima 4 ili 5 ili smjesu prema zahtjevu 11 ili smjesu prema zahtjevu 12.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06023435 | 2006-11-10 | ||
EP07822227.0A EP2083629B2 (en) | 2006-11-10 | 2007-11-05 | Crystalline modification of fipronil |
PCT/EP2007/061898 WO2008055884A1 (en) | 2006-11-10 | 2007-11-05 | Crystalline modification of fipronil |
Publications (2)
Publication Number | Publication Date |
---|---|
HRP20110641T1 HRP20110641T1 (hr) | 2011-10-31 |
HRP20110641T4 true HRP20110641T4 (hr) | 2015-05-22 |
Family
ID=37684871
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HRP20110641TT HRP20110641T4 (hr) | 2006-11-10 | 2011-09-07 | Kristalna modifikacija fipronila |
Country Status (26)
Country | Link |
---|---|
US (1) | US8791046B2 (hr) |
EP (1) | EP2083629B2 (hr) |
JP (2) | JP5877624B2 (hr) |
KR (1) | KR101472602B1 (hr) |
CN (1) | CN101562980B (hr) |
AR (1) | AR063649A1 (hr) |
AT (1) | ATE513470T1 (hr) |
AU (1) | AU2007316641B2 (hr) |
BR (1) | BRPI0718715B8 (hr) |
CA (1) | CA2667117C (hr) |
CY (1) | CY1112602T1 (hr) |
DK (1) | DK2083629T4 (hr) |
EA (1) | EA017180B1 (hr) |
ES (1) | ES2368521T5 (hr) |
HR (1) | HRP20110641T4 (hr) |
IL (1) | IL198266A (hr) |
MA (1) | MA30927B1 (hr) |
MX (1) | MX2009004316A (hr) |
NZ (1) | NZ576524A (hr) |
PL (1) | PL2083629T5 (hr) |
PT (1) | PT2083629E (hr) |
SI (1) | SI2083629T2 (hr) |
TW (1) | TWI432141B (hr) |
UA (1) | UA95819C2 (hr) |
WO (1) | WO2008055884A1 (hr) |
ZA (1) | ZA200903971B (hr) |
Families Citing this family (12)
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EP1968578A4 (en) | 2005-12-14 | 2011-02-23 | Makhteshim Chem Works Ltd | POLYMORPHIC AND AMORPHOUS FORMS OF 5-AMINO-L- [2,6-DICHLORO-4- (TRIFLUOROMETHYL) PHENYL] -4- [(TRIFLUOROMETHYL) SULFINYL] -IH-PYRAZOLE-3-CARBONITRIL |
CA2667117C (en) * | 2006-11-10 | 2016-04-26 | Basf Se | Crystalline modification of fipronil |
US8188136B2 (en) | 2006-11-10 | 2012-05-29 | Basf Se | Crystalline modification of fipronil |
UA110598C2 (uk) | 2006-11-10 | 2016-01-25 | Басф Се | Спосіб одержання кристалічної модифікації фіпронілу |
AU2007316639B2 (en) | 2006-11-10 | 2012-12-20 | Basf Se | Crystalline modification of fipronil |
CN102160207A (zh) * | 2008-09-19 | 2011-08-17 | 巴斯夫欧洲公司 | 二苯并四苯基二茚并(1,2,3-cd:1’,2’,3’-lm)苝在有机太阳能电池中的用途 |
EP2523669B1 (en) | 2010-01-11 | 2016-12-07 | Inotek Pharmaceuticals Corporation | Combination, kit and method of reducing intraocular pressure |
AU2011230580A1 (en) | 2010-03-26 | 2012-10-11 | Inotek Pharmaceuticals Corporation | Method of reducing intraocular pressure in humans using N6 -cyclopentyladenosine (CPA), CPA derivatives or prodrugs thereof |
AU2012100035A4 (en) * | 2011-01-14 | 2012-02-09 | Keki Hormusji Gharda | Polymorphism in 5-amino-1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoro methyl sulfinyl pyrazole |
PL2807178T3 (pl) | 2012-01-26 | 2017-12-29 | Inotek Pharmaceuticals Corporation | Bezwodne polimorfy azotanu (2R,3S,4R,5R)-5-(6-(cyklopentyloamino)-9H-puryn-9-ylo)-3,4-dihydroksytetrahydrofuran-2-ylo)metylu i sposoby ich wytwarzania |
MX2015013234A (es) * | 2013-03-15 | 2016-04-15 | Inotek Pharmaceuticals Corp | Formulaciones oftalmicas. |
JP2020527567A (ja) | 2017-07-18 | 2020-09-10 | アグリメティス,エルエルシー | L−グルホシネートの精製方法 |
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